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DE1504393B2 - Process for the biaxial stretching of tubular films made of linear thermoplastics - Google Patents
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DE1504393B2 - Process for the biaxial stretching of tubular films made of linear thermoplastics - Google Patents

Process for the biaxial stretching of tubular films made of linear thermoplastics

Info

Publication number
DE1504393B2
DE1504393B2 DE19621504393 DE1504393A DE1504393B2 DE 1504393 B2 DE1504393 B2 DE 1504393B2 DE 19621504393 DE19621504393 DE 19621504393 DE 1504393 A DE1504393 A DE 1504393A DE 1504393 B2 DE1504393 B2 DE 1504393B2
Authority
DE
Germany
Prior art keywords
stretching
hose
temperature
stretched
films
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Withdrawn
Application number
DE19621504393
Other languages
German (de)
Other versions
DE1504393A1 (en
Inventor
Anthony Graham Marshall WeI wyn Last (Großbritannien)
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Imperial Chemical Industries Ltd
Original Assignee
Imperial Chemical Industries Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority claimed from GB13192/61A external-priority patent/GB954254A/en
Application filed by Imperial Chemical Industries Ltd filed Critical Imperial Chemical Industries Ltd
Publication of DE1504393A1 publication Critical patent/DE1504393A1/en
Publication of DE1504393B2 publication Critical patent/DE1504393B2/en
Withdrawn legal-status Critical Current

Links

Classifications

    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C49/00Blow-moulding, i.e. blowing a preform or parison to a desired shape within a mould; Apparatus therefor
    • B29C49/02Combined blow-moulding and manufacture of the preform or the parison
    • B29C49/04Extrusion blow-moulding
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C48/00Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor
    • B29C48/03Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor characterised by the shape of the extruded material at extrusion
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C55/00Shaping by stretching, e.g. drawing through a die; Apparatus therefor
    • B29C55/02Shaping by stretching, e.g. drawing through a die; Apparatus therefor of plates or sheets
    • B29C55/10Shaping by stretching, e.g. drawing through a die; Apparatus therefor of plates or sheets multiaxial
    • B29C55/12Shaping by stretching, e.g. drawing through a die; Apparatus therefor of plates or sheets multiaxial biaxial
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C71/00After-treatment of articles without altering their shape; Apparatus therefor
    • B29C71/0072After-treatment of articles without altering their shape; Apparatus therefor for changing orientation
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C48/00Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor
    • B29C48/001Combinations of extrusion moulding with other shaping operations
    • B29C48/0017Combinations of extrusion moulding with other shaping operations combined with blow-moulding or thermoforming
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C48/00Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor
    • B29C48/001Combinations of extrusion moulding with other shaping operations
    • B29C48/0018Combinations of extrusion moulding with other shaping operations combined with shaping by orienting, stretching or shrinking, e.g. film blowing
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C48/00Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor
    • B29C48/001Combinations of extrusion moulding with other shaping operations
    • B29C48/0019Combinations of extrusion moulding with other shaping operations combined with shaping by flattening, folding or bending
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C48/00Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor
    • B29C48/03Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor characterised by the shape of the extruded material at extrusion
    • B29C48/09Articles with cross-sections having partially or fully enclosed cavities, e.g. pipes or channels
    • B29C48/10Articles with cross-sections having partially or fully enclosed cavities, e.g. pipes or channels flexible, e.g. blown foils

Landscapes

  • Engineering & Computer Science (AREA)
  • Mechanical Engineering (AREA)
  • Manufacturing & Machinery (AREA)
  • Shaping By String And By Release Of Stress In Plastics And The Like (AREA)
  • Lubricants (AREA)

Description

Hierzu 1 Blatt Zeichnungen1 sheet of drawings

Claims (1)

1 21 2 Die Erfindung betrifft ein Verfahren zum biaxialen rer Festigkeit und Schrumpfung erhalten werden kön-Strecken von Schlauchfolien aus linearen Thermo- nen, wenn hohe Innendrücke zum Ausdehnen des plasten, bei welchen der Schlauch durch Innengas- Schlauches angewendet werden. Höhere Drücke köndruck bei einer Temperatur unterhalb des Kristallit- nen angewendet werden, wenn mit niedrigen Streckschmelzpunktes ausgedehnt, gekühlt und abgezogen 5 temperaturen gearbeitet wird, jedoch muß die Temwird. peratur des Schlauches an dem Punkt, wo die Strek-The invention relates to a method for biaxial rer strength and shrinkage can be obtained stretching of tubular films made of linear thermons when high internal pressures cause the plasten in which the hose are applied through internal gas hose. Higher pressures köndruck be used at a temperature below the crystallite, if with a low stretch melting point extended, cooled and deducted 5 temperatures is worked, but the Temwird. temperature of the hose at the point where the stretch Es ist schon vorgeschlagen worden, Filme aus kung beginnt, genau eingestellt werden, um eineIt has been suggested that films from kung starts to be precisely adjusted to one Thermoplasten dadurch herzustellen, daß ein gleichmäßige Verstreckung sicherzustellen.Manufacture thermoplastics by ensuring that they are stretched evenly. Schlauch durch einen Luftdruck im Innern bei einer Der Film wird durch gleichförmig angewendeteHose through an air pressure inside at a The film is applied through uniformly Temperatur oberhalb des Schmelzpunktes der Ther- io Luftmedien während der Verstreckung auf eine Tem-Temperature above the melting point of the thermal air media during stretching to a temperature moplaste gestreckt wird. Hierbei wird der Schlauch peratur gekühlt, welche wesentlich unterhalb derje-moplastic is stretched. Here, the hose is cooled to a temperature which is significantly below the während der Streckbehandlung gekühlt, um das nigen liegt, bei welcher die Verstreckung beginnt; aufcooled during the stretching treatment to the nigen at which the stretching starts; on thermoplastische Material zu verfestigen, wodurch diese Weise können hohe Innendrücke und Umfangs-solidify thermoplastic material, whereby this way high internal pressures and circumferential die Ausdehnung des Schlauches unterbrochen wird. spannungen erzielt werden, wodurch ein wesentlicherthe expansion of the hose is interrupted. tensions are achieved, creating an essential Der Schlauch wird hierbei aber bei einer Tempera- 15 maximaler Orientierungsgrad erteilt wird. Beim bi-In this case, however, the hose is given at a temperature of the maximum degree of orientation. At the bi- tur oberhalb des Schmelzpunktes des betreffenden axialen Strecken von Schlauchfolien aus Polyolefinenture above the melting point of the relevant axial stretching of tubular films made of polyolefins Materials gestreckt, so daß also keine Orientierung ist es vorteilhaft die Folien so zu kühlen, daß ihreMaterial stretched so that there is no orientation, it is advantageous to cool the foils so that their der Moleküle stattfindet. Die Streckung dient somit Temperatur bei Beendigung des Streckvorganges zwi-of the molecules takes place. The stretching thus serves temperature at the end of the stretching process between lediglich zur Ausdehnung des Schlauches auf den sehen 60 und 100° C liegt,only to expand the hose to see 60 and 100 ° C, gewünschten Durchmesser. 20 Das Verfahren nach der Erfindung wird an Handdesired diameter. The method according to the invention is illustrated by hand Es ist weiterhin bekannt, daß, wenn kristalline der Zeichnung näher erläutert:
Thermoplaste bei einer Temperatur unterhalb ihres Eine Schlauchfolie 1, hergestellt durch Schmelz- ~ Schmelzpunktes gestreckt werden, deren Moleküle in extrusion mittels einer Ringschlitzdüse 2 und Küh- '' der Ebene der Folie orientiert werden und daß hier- lung in einer Kalibriervorrichtung 3, wird auf die durch eine beträchtliche Vergrößerung der Festigkeit 25 Verstreckungstemperatur durch Infraroterhitzer 4 erder Folien stattfindet und die Folie unter Umständen hitzt. Die Schlauchfolie 1 wird in den Verstreckungseine Neigung zum Schrumpfen erhält. Bei diesem bereich durch Abquetschwalzen 5 geleitet, wobei der Verfahren ist es erforderlich, die Temperatur des aufweitende bzw. verstreckende Gasdruck durch eine Schlauches auf eine Temperatur unterhalb des Sonde 6 zugeführt wird. Zur Kühlung wird Luft durch Schmelzpunktes des betreffenden Materials einzustel- 30 Rohre und Schlitze 9 und/oder 10 zugeführt, die len, bei der der Schlauch gleichmäßig gestreckt wer- durch Rohre 11 wieder abgeführt wird, so daß sie die den kann. Dieses Verfahren weist jedoch den Nach- Infraroterhitzer 4 nicht durch Kühlung stören könteil auf, daß die erreichten Festigkeiten der Folien nen. Die fertig verstreckte Schlauchfolie 1 wird durch und deren Schrumpfneigung in manchen Fällen noch eine Zusammenfallführung 7 und durch Abziehwalnicht ausreichend sind, da keine maximale Orientie- 35 zen 8 geleitet,
rung der Moleküle erzielt werden kann. Patentanspruch·
It is also known that when crystalline the drawing is explained in more detail:
Thermoplastics are stretched at a temperature below their melting point, the molecules of which are oriented in extrusion by means of an annular slot nozzle 2 and cooling '' the plane of the film and that this is done in a calibration device 3 which takes place due to a considerable increase in the strength 25 stretching temperature by infrared heater 4 of the films and heats the film under certain circumstances. The tubular film 1 will tend to shrink in the stretching process. In this area it is passed through squeezing rollers 5, the method requiring the temperature of the expanding or stretching gas pressure to be fed through a hose to a temperature below the probe 6. For cooling, air is fed through the melting point of the relevant material to be set 30 tubes and slits 9 and / or 10, the points at which the tube is evenly stretched through tubes 11, so that it can be removed again. However, this method does not interfere with the post infrared heater 4 by cooling könteil that the strengths of the films achieved NEN. The fully stretched tubular film 1 is, due to its tendency to shrink, in some cases still a collapse guide 7 and a peel roll is not sufficient, since no maximum orientation 8 is guided,
tion of the molecules can be achieved. Claim
Der Erfindung liegt die Aufgabe zugrunde, ein Verfahren zum biaxialen Strecken von Schlauchfolien zu Verfahren zum biaxialen Strecken von schaffen, bei dem die Moleküle der verwendeten Schlauchfolien aus linearen Thermoplasten, bei Thermoplasten annähernd maximal orientiert werden. 40 welchem der Schlauch durch Innengasdruck beiThe invention is based on the object of a method for the biaxial stretching of tubular films to processes for the biaxial stretching of create, in which the molecules of the tubular films used made of linear thermoplastics, at Thermoplastics are almost maximally oriented. 40 which the hose is subjected to by internal gas pressure Die Aufgabe wird dadurch gelöst, daß der Schlauch einer Temperatur unterhalb des Kristallitschmelz-The object is achieved in that the hose has a temperature below the crystallite melting während des Streckens und vor der Erreichung seines punktes ausgedehnt, gekühlt und abgezogen wird,is stretched, cooled and peeled off during stretching and before reaching its point, maximalen Durchmessers durch auf die äußere dadurch gekennzeichnet, daß dermaximum diameter through to the outer characterized in that the Schlauchoberfläche gerichtete Luftstrahlen gekühlt während des Streckens und vor Erreichung seinesAir jets directed towards the surface of the hose are cooled during stretching and before reaching its surface wird. 45. maximalen Durchmessers durch auf die äußerewill. 45. maximum diameter through to the outer Es wurde nämlich gefunden, daß Filme mit einem Schlauchoberfläche gerichtete Luftstrahlen gehöheren Grad der Orientierung und somit mit höhe- kühlt wird.Namely, it has been found that films with a tube surface have higher directed air jets Degree of orientation and thus also with height is cooled.
DE19621504393 1961-04-12 1962-04-11 Process for the biaxial stretching of tubular films made of linear thermoplastics Withdrawn DE1504393B2 (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
GB13192/61A GB954254A (en) 1961-04-12 1961-04-12 Improvements in or relating to linear organic thermoplastic film manufacture
GB4603861 1961-12-22

Publications (2)

Publication Number Publication Date
DE1504393A1 DE1504393A1 (en) 1969-02-06
DE1504393B2 true DE1504393B2 (en) 1971-01-07

Family

ID=26249613

Family Applications (1)

Application Number Title Priority Date Filing Date
DE19621504393 Withdrawn DE1504393B2 (en) 1961-04-12 1962-04-11 Process for the biaxial stretching of tubular films made of linear thermoplastics

Country Status (8)

Country Link
AT (1) AT247595B (en)
CH (1) CH405681A (en)
DE (1) DE1504393B2 (en)
DK (1) DK111539B (en)
ES (1) ES276416A1 (en)
FI (1) FI41605B (en)
NO (1) NO115358B (en)
SE (1) SE211592C1 (en)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0109944A1 (en) * 1982-10-18 1984-05-30 Unifos Kemi Ab Process for blowing film from linear thermoplastic material

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0109944A1 (en) * 1982-10-18 1984-05-30 Unifos Kemi Ab Process for blowing film from linear thermoplastic material

Also Published As

Publication number Publication date
CH405681A (en) 1966-01-15
DE1504393A1 (en) 1969-02-06
DK111539B (en) 1968-09-09
FI41605B (en) 1969-09-01
ES276416A1 (en) 1962-06-16
NO115358B (en) 1968-09-23
AT247595B (en) 1966-06-10
SE211592C1 (en) 1967-03-14

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Legal Events

Date Code Title Description
E77 Valid patent as to the heymanns-index 1977
EHJ Ceased/non-payment of the annual fee