EP0300070B2 - Matières extinctrices dutype à mousse - Google Patents
Matières extinctrices dutype à mousse Download PDFInfo
- Publication number
- EP0300070B2 EP0300070B2 EP87110532A EP87110532A EP0300070B2 EP 0300070 B2 EP0300070 B2 EP 0300070B2 EP 87110532 A EP87110532 A EP 87110532A EP 87110532 A EP87110532 A EP 87110532A EP 0300070 B2 EP0300070 B2 EP 0300070B2
- Authority
- EP
- European Patent Office
- Prior art keywords
- foam
- und
- bis
- alkyl
- ist
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 239000006260 foam Substances 0.000 title claims description 33
- 125000004432 carbon atom Chemical group C* 0.000 claims abstract description 15
- 150000002191 fatty alcohols Chemical class 0.000 claims abstract description 9
- 239000003795 chemical substances by application Substances 0.000 claims description 22
- 239000000203 mixture Substances 0.000 claims description 15
- 229920001282 polysaccharide Polymers 0.000 claims description 9
- 239000005017 polysaccharide Substances 0.000 claims description 8
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 8
- 150000004676 glycans Chemical class 0.000 claims description 6
- 239000007798 antifreeze agent Substances 0.000 claims description 5
- RWNUSVWFHDHRCJ-UHFFFAOYSA-N 1-butoxypropan-2-ol Chemical compound CCCCOCC(C)O RWNUSVWFHDHRCJ-UHFFFAOYSA-N 0.000 claims description 4
- WMDZKDKPYCNCDZ-UHFFFAOYSA-N 2-(2-butoxypropoxy)propan-1-ol Chemical compound CCCCOC(C)COC(C)CO WMDZKDKPYCNCDZ-UHFFFAOYSA-N 0.000 claims description 3
- 125000000217 alkyl group Chemical group 0.000 description 21
- 239000004094 surface-active agent Substances 0.000 description 13
- -1 Ethylen, Propylen Chemical class 0.000 description 7
- 230000002528 anti-freeze Effects 0.000 description 5
- XSQUKJJJFZCRTK-UHFFFAOYSA-N Urea Chemical compound NC(N)=O XSQUKJJJFZCRTK-UHFFFAOYSA-N 0.000 description 4
- MTHSVFCYNBDYFN-UHFFFAOYSA-N diethylene glycol Chemical compound OCCOCCO MTHSVFCYNBDYFN-UHFFFAOYSA-N 0.000 description 4
- 238000005187 foaming Methods 0.000 description 4
- 125000003976 glyceryl group Chemical group [H]C([*])([H])C(O[H])([H])C(O[H])([H])[H] 0.000 description 4
- 229920006254 polymer film Polymers 0.000 description 4
- 125000006273 (C1-C3) alkyl group Chemical group 0.000 description 3
- 125000003545 alkoxy group Chemical group 0.000 description 3
- 239000004088 foaming agent Substances 0.000 description 3
- 125000001165 hydrophobic group Chemical group 0.000 description 3
- 239000007788 liquid Substances 0.000 description 3
- 239000013535 sea water Substances 0.000 description 3
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 2
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 2
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 description 2
- QQONPFPTGQHPMA-UHFFFAOYSA-N Propene Chemical compound CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 description 2
- 239000002253 acid Substances 0.000 description 2
- 150000007513 acids Chemical class 0.000 description 2
- 125000001931 aliphatic group Chemical group 0.000 description 2
- 125000005037 alkyl phenyl group Chemical group 0.000 description 2
- 125000000129 anionic group Chemical group 0.000 description 2
- 150000001720 carbohydrates Chemical class 0.000 description 2
- 150000007942 carboxylates Chemical class 0.000 description 2
- 125000002091 cationic group Chemical group 0.000 description 2
- 125000004435 hydrogen atom Chemical group [H]* 0.000 description 2
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 2
- 230000001771 impaired effect Effects 0.000 description 2
- 230000009021 linear effect Effects 0.000 description 2
- 229920006395 saturated elastomer Polymers 0.000 description 2
- 239000002904 solvent Substances 0.000 description 2
- 241000251468 Actinopterygii Species 0.000 description 1
- 108010053481 Antifreeze Proteins Proteins 0.000 description 1
- 239000005977 Ethylene Substances 0.000 description 1
- KMTRUDSVKNLOMY-UHFFFAOYSA-N Ethylene carbonate Chemical compound O=C1OCCO1 KMTRUDSVKNLOMY-UHFFFAOYSA-N 0.000 description 1
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 1
- MHAJPDPJQMAIIY-UHFFFAOYSA-N Hydrogen peroxide Chemical compound OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 description 1
- 239000005905 Hydrolysed protein Substances 0.000 description 1
- 230000032683 aging Effects 0.000 description 1
- 150000001336 alkenes Chemical group 0.000 description 1
- 150000001408 amides Chemical class 0.000 description 1
- 150000001412 amines Chemical class 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- 230000001580 bacterial effect Effects 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 239000004202 carbamide Substances 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 239000012141 concentrate Substances 0.000 description 1
- 230000007797 corrosion Effects 0.000 description 1
- 238000005260 corrosion Methods 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 239000004872 foam stabilizing agent Substances 0.000 description 1
- 230000008014 freezing Effects 0.000 description 1
- 238000007710 freezing Methods 0.000 description 1
- 210000001035 gastrointestinal tract Anatomy 0.000 description 1
- 150000002334 glycols Chemical class 0.000 description 1
- 229930195733 hydrocarbon Natural products 0.000 description 1
- 150000002430 hydrocarbons Chemical class 0.000 description 1
- 239000001257 hydrogen Substances 0.000 description 1
- 229910052739 hydrogen Inorganic materials 0.000 description 1
- 238000010348 incorporation Methods 0.000 description 1
- 239000003960 organic solvent Substances 0.000 description 1
- 125000000963 oxybis(methylene) group Chemical group [H]C([H])(*)OC([H])([H])* 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 239000003495 polar organic solvent Substances 0.000 description 1
- 125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 description 1
- 239000003531 protein hydrolysate Substances 0.000 description 1
- 108090000623 proteins and genes Proteins 0.000 description 1
- 102000004169 proteins and genes Human genes 0.000 description 1
- 210000002023 somite Anatomy 0.000 description 1
- 239000003381 stabilizer Substances 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- BDHFUVZGWQCTTF-UHFFFAOYSA-M sulfonate Chemical compound [O-]S(=O)=O BDHFUVZGWQCTTF-UHFFFAOYSA-M 0.000 description 1
- 150000003871 sulfonates Chemical class 0.000 description 1
- 150000003467 sulfuric acid derivatives Chemical class 0.000 description 1
- 230000001988 toxicity Effects 0.000 description 1
- 231100000419 toxicity Toxicity 0.000 description 1
- 229920003169 water-soluble polymer Polymers 0.000 description 1
- 239000004711 α-olefin Substances 0.000 description 1
Classifications
-
- A—HUMAN NECESSITIES
- A62—LIFE-SAVING; FIRE-FIGHTING
- A62D—CHEMICAL MEANS FOR EXTINGUISHING FIRES OR FOR COMBATING OR PROTECTING AGAINST HARMFUL CHEMICAL AGENTS; CHEMICAL MATERIALS FOR USE IN BREATHING APPARATUS
- A62D1/00—Fire-extinguishing compositions; Use of chemical substances in extinguishing fires
- A62D1/0071—Foams
Definitions
- the invention relates to a fire extinguishing foam agent.
- fire extinguishing foam agents which consists of a foam-forming component, an anti-freeze component, possibly a foam stabilizer and a solvent, such as Water, and in which a highly effective shielding of the oxygen supply to the fire object is achieved on the basis of proteins or surfactants.
- Hydrolysed proteins e.g. Protein hydrolyzates, possibly combined with fluorosurfactants or surfactants at all. Wildfires can also be fought alone with water film-forming foaming agents (AFFF).
- the foaming agents are added in amounts of approximately 2% to 6% to the extinguishing water, which forms the foam mechanically when mixed with air.
- the invention is therefore based on the object to provide an improved fire extinguishing foam agent with improved fire protection properties, which has a very good compatibility with a wide variety of polymer film formers, which are otherwise not compatible with conventional surfactants, and which allows the incorporation of a wide variety of antifreeze agents, at the same time improved seawater resistance is to be achieved, so that the fire extinguishing foam agent polar even in fires Liquids and water-miscible hydrocarbons can be used at sea. Furthermore, the suction behavior at low temperatures should be achieved in addition to an improvement in the stability of the foam against acids and alkalis.
- a fire extinguishing foam agent which as an foam-forming component, an alkyl polyglycoside of the formula where n is an integer from 2 to 10 and R represents the remainder of a fatty alcohol having 6 to 12 carbon atoms, which has the advantages indicated above, it being possible to incorporate the various known antifreeze agents into the fire extinguishing foam agent without the excellent Effect of the fire extinguishing foam agent is impaired in any way, and there is also the good compatibility of this foam-forming component with water film and polymer film formers, so that foams can be formed, the stability and fine bubbles are not impaired.
- the fire extinguishing foam composition is composed as follows: Alkyl polyglycoside 8-30%, preferably 15% Polysaccharide 0.3-1.5%, preferably 0.5% Fluorosurfactant 1-7%, preferably 3% Water, replenished 100%, preferably 47.5% Antifreeze amount depending on the desired frost resistance 5-35%
- the propylene glycol n-butyl ether and / or di-propylene glycol n-butyl ether can also be added to any known fire extinguishing foam agent.
- a fire extinguishing foam agent with the foam-forming component as recipe 3 is compared with a fire extinguishing foam agent as recipes 1 and 2, recipe 1 as foaming agent containing no alkyl polyglycoside, and recipe 2 containing no ether.
- the concentrations given in% are% by weight.
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Business, Economics & Management (AREA)
- Emergency Management (AREA)
- Fire-Extinguishing Compositions (AREA)
- Emulsifying, Dispersing, Foam-Producing Or Wetting Agents (AREA)
Claims (2)
- Matière extinctrice du type à mousse avec un agent moussant composé d'un alkylpolyglycoside de la formule
n étant un nombre entier de 2 à 10 et R le reste d'un alccol gras avec 6 à 12 atomes de C, en particulier un alcool gras du groupe des alcools gras primaires, caractérisé en ce que la matière extinctrice du type à mousse contient, en plus de l'alkylpolyglycoside, un polysaccharide, un fluorure d'un dérivé tensio-actif et un antigel connu et un propylèneglycol-n-butyléther et/ou dipropylèneglycol-n-butyléther. - Matière extinctrice du type à mousse selon la revendication 1, caractérisé en ce que la matière extinctrice du type à mousse se compose comme suit:
alkylpolyglycoside de la formule indiquée dans la revendication 1 de 8 à 30%, de préférence 15% polysaccharide de 0,3 à 1,5%, de préférence 0,5% fluorure d'un dérivé tensio-actif d'1 à 7%, de préférence 3% quantité d'antigel selon la résistance au gel souhaitée de 5 à 35% eau, remplie pour 100%, de préférence 47,5%
Priority Applications (5)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| ES198787110532T ES2031094T3 (es) | 1987-07-21 | 1987-07-21 | Agente espumante para la extincion de incendios. |
| AT87110532T ATE75960T1 (de) | 1987-07-21 | 1987-07-21 | Feuerloeschschaummittel. |
| DE8787110532T DE3779121D1 (de) | 1987-07-21 | 1987-07-21 | Feuerloeschschaummittel. |
| EP87110532A EP0300070B2 (fr) | 1987-07-21 | 1987-07-21 | Matières extinctrices dutype à mousse |
| GR920400803T GR3004598T3 (en) | 1987-07-21 | 1992-05-14 | Foam fire-extinguishing agents. |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| EP87110532A EP0300070B2 (fr) | 1987-07-21 | 1987-07-21 | Matières extinctrices dutype à mousse |
Publications (3)
| Publication Number | Publication Date |
|---|---|
| EP0300070A1 EP0300070A1 (fr) | 1989-01-25 |
| EP0300070B1 EP0300070B1 (fr) | 1992-05-13 |
| EP0300070B2 true EP0300070B2 (fr) | 1995-12-06 |
Family
ID=8197143
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| EP87110532A Expired - Lifetime EP0300070B2 (fr) | 1987-07-21 | 1987-07-21 | Matières extinctrices dutype à mousse |
Country Status (5)
| Country | Link |
|---|---|
| EP (1) | EP0300070B2 (fr) |
| AT (1) | ATE75960T1 (fr) |
| DE (1) | DE3779121D1 (fr) |
| ES (1) | ES2031094T3 (fr) |
| GR (1) | GR3004598T3 (fr) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE19708733B4 (de) * | 1997-03-04 | 2007-05-31 | Cognis Ip Management Gmbh | Flüssigschaumlöschmittel auf Wasserbasis |
Families Citing this family (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4999119A (en) * | 1989-07-20 | 1991-03-12 | Chubb National Foam, Inc. | Alcohol resistant aqueous film forming firefighting foam |
| DE4011487A1 (de) * | 1990-04-09 | 1991-10-10 | Henkel Kgaa | Tensidmischung fuer die verwendung in wasch- und reinigungsmitteln |
| IT1264588B1 (it) * | 1993-06-11 | 1996-10-04 | Silvani Antincendi Spa Ora San | Composizione schiumogena per ridurre la pressione associata all'onda d'urto generata da esplosioni |
| US5981452A (en) * | 1995-12-04 | 1999-11-09 | Henkel Kommanditgesellschaft Auf Aktien | Syndet soaps comprising alkyl and/or alkenyl oligoglycosides |
| DE19545136C1 (de) * | 1995-12-04 | 1997-04-10 | Henkel Kgaa | Syndetstückseifen |
| US5882541A (en) * | 1996-11-04 | 1999-03-16 | Hans Achtmann | Biodegradable foam compositions for extinguishing fires |
| US6814880B1 (en) | 1999-02-25 | 2004-11-09 | Cognis Deutschland Gmbh & Co. Kg | Water based liquid foam extinguishing formulation |
| CN104117176A (zh) * | 2014-07-23 | 2014-10-29 | 安徽天元消防科技有限公司 | 灭火弹及投掷式灭火器专用水成膜泡沫灭火剂 |
| CN116948750B (zh) * | 2023-09-20 | 2023-12-15 | 广州洁宜日化用品有限公司 | 一种扫地机器人用地板水的制备方法 |
Family Cites Families (11)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US1431789A (en) * | 1921-09-01 | 1922-10-10 | Samuel H Hamilton | Fire-extinguishing liquid and method of using same |
| DE686645C (de) * | 1936-04-18 | 1940-01-13 | Burckhardt Helferich Dr | Wasch-, Reinigungs-, Netz-, Emulgier- und Schaummittel |
| US3422011A (en) * | 1966-05-03 | 1969-01-14 | Kidde & Co Walter | Foam producing material |
| GB1435200A (en) * | 1973-06-21 | 1976-05-12 | Ici Ltd | Fire-fighting foam compositions and method of fire-fighting |
| EP0049958B1 (fr) * | 1980-09-30 | 1986-11-05 | Angus Fire Armour Limited | Compositions pour la lutte contre les incendies |
| DE3275201D1 (en) * | 1981-07-13 | 1987-02-26 | Procter & Gamble | Foaming surfactant compositions |
| ATE15498T1 (de) * | 1981-10-08 | 1985-09-15 | Rohm & Haas France | Verfahren zur herstellung von oberflaechenaktiven glykosiden und ihre verwendung in kosmetischen, pharmazeutischen und haushaltsprodukten. |
| WO1984001302A1 (fr) * | 1982-09-27 | 1984-04-12 | New Japan Chem Co Ltd | Composition de mousse extinctrice |
| LU84753A1 (fr) * | 1983-04-15 | 1984-11-28 | Oreal | Composition lavante et moussante a base d'agents tensio-actifs non ioniques et de polymeres anioniques |
| US4488981A (en) * | 1983-09-06 | 1984-12-18 | A. E. Staley Manufacturing Company | Lower alkyl glycosides to reduce viscosity in aqueous liquid detergents |
| GB2166153A (en) * | 1984-10-25 | 1986-04-30 | Procter & Gamble | No-rinse hard surface cleaning composition |
-
1987
- 1987-07-21 EP EP87110532A patent/EP0300070B2/fr not_active Expired - Lifetime
- 1987-07-21 ES ES198787110532T patent/ES2031094T3/es not_active Expired - Lifetime
- 1987-07-21 DE DE8787110532T patent/DE3779121D1/de not_active Expired - Lifetime
- 1987-07-21 AT AT87110532T patent/ATE75960T1/de not_active IP Right Cessation
-
1992
- 1992-05-14 GR GR920400803T patent/GR3004598T3/el unknown
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE19708733B4 (de) * | 1997-03-04 | 2007-05-31 | Cognis Ip Management Gmbh | Flüssigschaumlöschmittel auf Wasserbasis |
Also Published As
| Publication number | Publication date |
|---|---|
| ATE75960T1 (de) | 1992-05-15 |
| EP0300070B1 (fr) | 1992-05-13 |
| DE3779121D1 (de) | 1992-06-17 |
| GR3004598T3 (en) | 1993-04-28 |
| ES2031094T3 (es) | 1992-12-01 |
| EP0300070A1 (fr) | 1989-01-25 |
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