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JP2662560B2 - Method for forming automotive coatings including lightweight chipping resistant coatings - Google Patents
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JP2662560B2 - Method for forming automotive coatings including lightweight chipping resistant coatings - Google Patents

Method for forming automotive coatings including lightweight chipping resistant coatings

Info

Publication number
JP2662560B2
JP2662560B2 JP15072089A JP15072089A JP2662560B2 JP 2662560 B2 JP2662560 B2 JP 2662560B2 JP 15072089 A JP15072089 A JP 15072089A JP 15072089 A JP15072089 A JP 15072089A JP 2662560 B2 JP2662560 B2 JP 2662560B2
Authority
JP
Japan
Prior art keywords
chipping
coating film
weight
paint
vinyl chloride
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
JP15072089A
Other languages
Japanese (ja)
Other versions
JPH0316680A (en
Inventor
春樹 石塚
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
NIPPON TOKUSHU TORYO KK
Original Assignee
NIPPON TOKUSHU TORYO KK
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by NIPPON TOKUSHU TORYO KK filed Critical NIPPON TOKUSHU TORYO KK
Priority to JP15072089A priority Critical patent/JP2662560B2/en
Publication of JPH0316680A publication Critical patent/JPH0316680A/en
Application granted granted Critical
Publication of JP2662560B2 publication Critical patent/JP2662560B2/en
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

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Description

【発明の詳細な説明】 (産業上の利用分野) 本発明は、中空状の充填材を含有する塩化ビニルプラ
スチゾル系耐チッピング塗料を含む自動車の塗膜形成方
法に関する。
Description: TECHNICAL FIELD The present invention relates to a method for forming a coating film of an automobile including a polyvinyl chloride plastisol-based anti-chipping paint containing a hollow filler.

(従来の技術) 自動車の耐チッピング材として、自動車走行中の飛び
石により生ずる損傷を保護するために塩化ビニルプラス
チゾル(以下「塩ビゾル」ということがある)系耐チッ
ピング材を塗装している。
(Prior Art) As a chipping-resistant material for automobiles, a vinyl chloride plastisol (hereinafter sometimes referred to as "chlorinated sol")-based chipping-resistant material is coated in order to protect damage caused by stepping stones while the vehicle is running.

(発明が解決しようとする課題) 近時、自動車の一層の防錆性能の向上のため、上記塩
ビゾル系耐チッピング塗料の塗布面積の拡大、塗膜厚の
増加が必要になってきた。しかしながら塗料の使用料を
多くするという対策では、車両重量の増加が大きく、走
行性能の低下および省エネルギー化に逆行するという問
題点がある。そこで、塗膜重量の軽量化のために充填材
の一部として、中空状の充填材を使用すれば、塗膜重量
は軽くなるものの、従来使用されている中空状の充填材
は一般に耐熱性に劣り、高温での焼き付けで溶融するた
め従来の塗装、焼き付けラインでの塗膜形成がむづかし
く、新たにライン条件、温度条件等を変更した塗装、焼
き付けラインを設置する必要があるという問題点があっ
た。
(Problems to be Solved by the Invention) In recent years, in order to further improve the rust prevention performance of automobiles, it has become necessary to increase the application area of the above-mentioned PVC-based anti-chipping paint and increase the coating film thickness. However, measures to increase the use fee of the paint have a problem that the weight of the vehicle is largely increased, and the running performance is lowered and energy saving is countered. Therefore, if a hollow filler is used as a part of the filler to reduce the weight of the coating film, the weight of the coating film is reduced, but the conventionally used hollow filler is generally heat resistant. It is difficult to form the coating on the conventional coating and baking line because it is melted by baking at a high temperature, and it is necessary to install a new coating and baking line with changed line conditions and temperature conditions. There was a point.

(課題を解決するための手段) そこで本発明者は、塗膜重量の軽量化を目的として中
空状充填材を含有した塩化ビニルプラスチゾル系耐チッ
ピング塗料を使用するにもかかわらず、従来の比較的高
温の塗装、焼き付けラインで満足な塗膜を形成する方法
を顕現すべく鋭意研究の結果、電着塗膜上に耐熱性に優
れる中空状充填材を含有する塩化ビニルプラスチゾル系
耐チッピング塗料を塗布した後、予備乾燥するかまたは
予備乾燥することなく中塗塗料を塗布し、120〜160℃で
15〜25分間焼き付け、更に上塗塗料を塗布し、120〜160
℃で15〜25分間焼き付けることによる軽量耐チッピング
塗料を含む自動車の塗膜形成方法によれば、上記欠点を
ことごとく解決し得ることを知見し、本発明を達成する
に至ったものである。
(Means for Solving the Problems) The inventor of the present invention, despite the use of a vinyl chloride plastisol-based chipping-resistant paint containing a hollow filler for the purpose of reducing the weight of the coating film, uses a conventional comparatively. As a result of intensive research to reveal a method of forming a satisfactory coating film at a high-temperature coating and baking line, a polyvinyl chloride plastisol-based chipping-resistant paint containing a hollow filler with excellent heat resistance is applied on the electrodeposition coating film. After pre-drying or applying the intermediate coating without pre-drying, at 120-160 ℃
Bake for 15 to 25 minutes, apply a top coat, and 120 to 160
According to the method for forming a coating film of an automobile including a light-weight chipping-resistant paint by baking at 15 ° C. for 15 to 25 minutes, the inventors have found that all the above-mentioned disadvantages can be solved, and have accomplished the present invention.

本発明で特徴とする塗膜焼き付け条件は、中空状充填
材を含有する塩化ビニルプラスチゾル系耐チッピング塗
料を含む塗膜形成方法であることに起因して特徴を有す
るのであり、従来の焼き付け条件とは大きな変更がない
ものである。本発明は、従来の塗膜焼き付け条件より一
段と低い温度に設定した新たなラインを設置する必要の
あった中空状充填材を含有する塩化ビニルプラスチゾル
系耐チッピング塗料の塗膜形成方法を著しく改善したも
のである。即ち、本発明は現在使用されている中空状充
填材を含有しない塩化ビニルプラスチゾル系耐チッピン
グ塗料の塗膜形成方法から軽量化を目的として、耐熱性
に優れる中空状充填材を含有する塩化ビニルプラスチゾ
ル系耐チッピング塗料への変更が、塗装条件及びライン
条件の変更なく、そのまま実施できるところに大きな特
徴を有する。
The coating baking conditions characterized by the present invention are characterized by being a coating film forming method including a vinyl chloride plastisol-based anti-chipping paint containing a hollow filler, the conventional baking conditions and Is without major changes. The present invention has significantly improved the method for forming a coating film of a vinyl chloride plastisol-based chipping-resistant coating material containing a hollow filler, which required the installation of a new line at a lower temperature than conventional coating film baking conditions. Things. That is, the present invention is a vinyl chloride plastisol containing a hollow filler excellent in heat resistance for the purpose of weight reduction from a method of forming a coating film of a vinyl chloride plastisol-based chipping-resistant paint not containing a hollow filler currently used. A major feature is that a change to a chipping-resistant paint can be carried out as it is without changing the coating conditions and line conditions.

従って、上記耐チッピング塗料を塗布した後予備乾燥
するかまたは予備乾燥することなく中塗塗料を塗布し、
120〜160℃で15〜25分間焼き付け、更に上塗塗料を塗布
し、120〜160℃で15〜25分間焼き付けることによる自動
車の塗膜形成方法は、従来の中空状充填材を含有しない
塩化ビニルプラスチゾル系耐チッピング塗料の塗膜形成
方法とは大きな変更のない焼き付け条件である。尚上記
耐チッピング塗料を塗布した後、予備乾燥を行う場合に
は100〜140℃で8〜12分間の条件で行うのが好ましい。
Therefore, after applying the chipping-resistant paint, pre-drying or applying an intermediate coating without pre-drying,
Baking at 120 to 160 ° C for 15 to 25 minutes, further applying a top coat, and baking at 120 to 160 ° C for 15 to 25 minutes is a conventional method of forming a coating film for automobiles. The baking conditions are not largely changed from the method of forming a coating film of the anti-chipping paint. When pre-drying is performed after the application of the above-mentioned chipping-resistant paint, it is preferable to perform the pre-drying at 100 to 140 ° C. for 8 to 12 minutes.

本発明の必須成分として配合する中空状充填材は、15
0℃程度の耐熱性を有するものであることを必須とし、
フェノール系プラスチック、アクリル系プラスチック等
の中空状充填材が好ましく使用でき、反対に耐熱性に劣
る塩化ビニル、塩化ビニリデン、スチレン、酢酸ビニル
等の中空状充填材の使用は避けるべきである。
Hollow filler to be blended as an essential component of the present invention, 15
Indispensable to have a heat resistance of about 0 ℃,
Hollow fillers such as phenolic plastics and acrylic plastics can be preferably used. Conversely, hollow fillers such as vinyl chloride, vinylidene chloride, styrene, and vinyl acetate, which are inferior in heat resistance, should be avoided.

本発明で使用する中空状の充填材は、120kg/cm2程度
の強度が必要であり、耐チッピング塗料をエアレススプ
レー等で塗布する場合にも、少なくともプラスチック中
空状充填材がつぶれないくらいの強度が必要である。し
かしながら、塗布するに際しては、エアレススプレーの
みならずハケによっても差し支えなく、ハケ塗りの場
合、中空状充填材の強度は考慮する必要はない。
Hollow fillers for use in the present invention must 120 kg / cm 2 about strength, strength enough not to be collapsed at least a plastic hollow filler when applying the chipping paint airless spray, etc. is required. However, when applying, not only airless spray but also brush may be used. In the case of brush application, it is not necessary to consider the strength of the hollow filler.

プラスチック中空状充填材の粒径は塗膜厚との関係で
200μ以下であれば使用可能であり、150メッシュに全体
の95%が通過する程度(約100μ以下)の大きさが好ま
しい。粒径が大き過ぎるとエアレススプレーの場合、パ
ターン幅のバラつきや、ガン詰まりの恐れがあり、仕上
がり表面も粗くなる場合がある。また粒径が小さ過ぎる
と軽量化の効果が発揮できなくなるためなるべく避けた
ほうが良い。
The particle size of the hollow plastic filler depends on the coating thickness.
A size of 200 μm or less can be used, and a size that allows 95% of the whole to pass through 150 mesh (about 100 μm or less) is preferable. If the particle size is too large, in the case of airless spraying, there is a possibility that the pattern width will vary, the gun may be clogged, and the finished surface may be rough. If the particle size is too small, the effect of weight reduction cannot be exhibited, so that it is better to avoid as much as possible.

プラスチック中空状充填材の嵩比重は0.1以下であれ
ば使用可能であり、好ましくは0.02〜0.05である。すな
わち、プラスチック中空状充填材は強度がともなえば嵩
比重は小さい方がより好ましい。
The bulk specific gravity of the plastic hollow filler can be used as long as it is 0.1 or less, and is preferably 0.02 to 0.05. That is, it is more preferable that the bulk specific gravity of the plastic hollow filler be small if it has strength.

本発明において、塩化ビニルプラスゾルとは、塩化ビ
ニル系の樹脂を可塑剤中に分散せしめ、充填材、添加剤
を配合してなるものであり、塩化ビニル系の樹脂として
は、ポリ塩化ビニル、ポリ塩化ビニリデン等のモホポリ
マー、塩化ビニル、酢酸ビニル、塩化ビニリデン等のモ
ノマーの共重合体の使用が好ましい。
In the present invention, a vinyl chloride plus sol is obtained by dispersing a vinyl chloride resin in a plasticizer and compounding a filler and an additive. Examples of the vinyl chloride resin include polyvinyl chloride, It is preferable to use a copolymer of a monomer such as a mophopolymer such as polyvinylidene chloride or vinyl chloride, vinyl acetate, or vinylidene chloride.

可塑剤としては、フタル酸エステル、二塩基性酸エス
テル、燐酸エステル、ポリエステル系可塑剤などを使用
し、特にはフタル酸ジオクチル(DOP)の使用が推奨で
きる。
As the plasticizer, a phthalic acid ester, a dibasic acid ester, a phosphoric acid ester, a polyester plasticizer, or the like is used. In particular, the use of dioctyl phthalate (DOP) can be recommended.

中空状充填材以外の充填材としては、タルク、炭酸カ
ルシウム、硅藻土、マイカ、カオリン、硫酸バリウム、
炭酸マグネシウム、エロジール、ヒル石、グラファイ
ト、アルミナ、シリカ等を使用し、更に酸化チタン、カ
ーボンブラック等の着色剤も使用し得る。
Fillers other than hollow fillers include talc, calcium carbonate, diatomaceous earth, mica, kaolin, barium sulfate,
Magnesium carbonate, elixir, hillite, graphite, alumina, silica and the like can be used, and further, a coloring agent such as titanium oxide and carbon black can be used.

さらに、本発明の中空状充填材の好適な含有量範囲
は、塗料の比重が0.8〜1.0の時、塗料に対して重量比で
0.5〜2.2である。
Further, the preferred content range of the hollow filler of the present invention is, when the specific gravity of the paint is 0.8 to 1.0, by weight ratio to the paint.
It is 0.5 to 2.2.

(実施例) 以下に実施例を挙げ本発明のより詳細な理解に供す
る。当然のことながら本発明は以下の実施例のみに限定
されるものではない。
(Examples) The following examples are provided to provide a more detailed understanding of the present invention. As a matter of course, the present invention is not limited only to the following examples.

実施例 塩化ビニル−酢酸ビニル共重合樹脂100重量部、アク
リル樹脂から成る直径20〜40μm程度の中空状充填材4
重量部、DOP90重量部、炭酸カルシウム100重量部、硫酸
バリウム50重量部、カーボンブラック1重量部、分散剤
アンチテラーU(ビック ケミ ジャパン(株)製)4
重量部からなる塩化ビニルプラスチゾル系耐チッピング
塗料を得た。
Example 100 parts by weight of a vinyl chloride-vinyl acetate copolymer resin, an acrylic resin and a hollow filler 4 having a diameter of about 20 to 40 μm 4
Parts by weight, 90 parts by weight of DOP, 100 parts by weight of calcium carbonate, 50 parts by weight of barium sulfate, 1 part by weight of carbon black, Dispersant Antiteller U (manufactured by BYK Japan KK) 4
A vinyl chloride plastisol-based chipping-resistant paint consisting of parts by weight was obtained.

次いで上記塗料を、電着塗料を塗布してあるテストパ
ネルに塗布した後、120℃で10分間予備乾燥し、次いで
中塗塗料としてオルガー41(日本ペイント(株)製)を
塗布し、140℃で20分間焼き付け、更に上塗塗料として
ルーガベーク#531(関西ペイント(株)製)を塗布
し、130℃で20分間焼き付け、塗膜を形成した。
Next, the paint was applied to a test panel coated with an electrodeposition paint, preliminarily dried at 120 ° C. for 10 minutes, and then Olger 41 (manufactured by Nippon Paint Co., Ltd.) was applied as an intermediate paint, and the paint was applied at 140 ° C. After baking for 20 minutes, Lugabake # 531 (manufactured by Kansai Paint Co., Ltd.) was further applied as a top coat and baked at 130 ° C. for 20 minutes to form a coating film.

比較例 塩化ビニル−酢酸ビニル共重合樹脂100重量部、塩化
ビニリデン樹脂製中空状充填剤4重量部、DOP90重量
部、炭酸カルシウム100重量部、硫酸バリウム50重量
部、カーボンブラック1重量部、分散剤アンチテラーU4
重量部からなる塩化ビニルプラスチゾル系耐チッピング
塗料を得た。
Comparative Example 100 parts by weight of vinyl chloride-vinyl acetate copolymer resin, 4 parts by weight of vinylidene chloride resin hollow filler, 90 parts by weight of DOP, 100 parts by weight of calcium carbonate, 50 parts by weight of barium sulfate, 1 part by weight of carbon black, dispersant Anti-Teller U4
A vinyl chloride plastisol-based chipping-resistant paint consisting of parts by weight was obtained.

次いで上記塗料を実施例と同様のテストパネルに塗布
し、同様の中塗塗料、上塗塗料を塗布して塗膜を形成し
た。
Next, the above paint was applied to the same test panel as in the example, and the same intermediate paint and top coat were applied to form a coating film.

上記実施例および比較例で得た各々の塗膜の拡大断層
写真を影響し、比較した結果、実施例になる塗膜は、球
状の形状を保持していたが、比較例になる塗膜は、表面
付近で著しく溶融し、変形していた。
Influence the enlarged tomographic photograph of each coating film obtained in the above Examples and Comparative Examples, and as a result of comparison, the coating film of the Example retained a spherical shape, but the coating film of the Comparative Example , Remarkably melted and deformed near the surface.

(発明の効果) 本発明になる軽量耐チッピング塗料を含む自動車の塗
膜形成方法によれば、耐熱性に優れる中空状充填材を含
有した塩化ビニルプラスチゾル系耐チッピング塗料を使
用するにもかかわらず、従来の比較的高温の塗装、焼き
付けラインで満足な塗膜が形成されることがあきらかに
なった。
(Effect of the Invention) According to the method for forming a coating film of an automobile including a light-weight chipping-resistant paint according to the present invention, despite using a vinyl chloride plastisol-based chipping-resistant paint containing a hollow filler excellent in heat resistance, It has become clear that satisfactory coating films can be formed by conventional relatively high-temperature coating and baking lines.

Claims (1)

(57)【特許請求の範囲】(57) [Claims] 【請求項1】塩化ビニルプラスチゾル系耐チッピング塗
料を含む自動車の塗膜形成方法に於いて、電着塗膜上に
耐熱性に優れる中空状充填材を含有する塩化ビニルプラ
スチゾル系耐チッピング塗料を塗布した後、予備乾燥す
るかまたは予備乾燥することなく中塗塗料を塗布し、12
0〜160℃で15〜25分間焼き付け、更に上塗塗料を塗布
し、120〜160℃で15〜25分間焼き付けることを特徴とす
る軽量耐チッピング塗料を含む自動車の塗膜形成方法。
1. A method for forming a coating film for an automobile containing a vinyl chloride plastisol-based chipping-resistant paint, wherein a vinyl chloride plastisol-based chipping-resistant paint containing a hollow filler having excellent heat resistance is applied on an electrodeposition coating film. After pre-drying or applying the intermediate coating without pre-drying, 12
A baking method at 0 to 160 ° C. for 15 to 25 minutes, further applying a top coat, and baking at 120 to 160 ° C. for 15 to 25 minutes.
JP15072089A 1989-06-14 1989-06-14 Method for forming automotive coatings including lightweight chipping resistant coatings Expired - Lifetime JP2662560B2 (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP15072089A JP2662560B2 (en) 1989-06-14 1989-06-14 Method for forming automotive coatings including lightweight chipping resistant coatings

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP15072089A JP2662560B2 (en) 1989-06-14 1989-06-14 Method for forming automotive coatings including lightweight chipping resistant coatings

Publications (2)

Publication Number Publication Date
JPH0316680A JPH0316680A (en) 1991-01-24
JP2662560B2 true JP2662560B2 (en) 1997-10-15

Family

ID=15502937

Family Applications (1)

Application Number Title Priority Date Filing Date
JP15072089A Expired - Lifetime JP2662560B2 (en) 1989-06-14 1989-06-14 Method for forming automotive coatings including lightweight chipping resistant coatings

Country Status (1)

Country Link
JP (1) JP2662560B2 (en)

Families Citing this family (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2782396B2 (en) * 1992-01-30 1998-07-30 スタンレー電気株式会社 Automotive obstacle sensor

Also Published As

Publication number Publication date
JPH0316680A (en) 1991-01-24

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