Deprecated: The each() function is deprecated. This message will be suppressed on further calls in /home/zhenxiangba/zhenxiangba.com/public_html/phproxy-improved-master/index.php on line 456
JP3368434B2 - Powder application method - Google Patents
[go: Go Back, main page]

JP3368434B2 - Powder application method - Google Patents

Powder application method

Info

Publication number
JP3368434B2
JP3368434B2 JP08144093A JP8144093A JP3368434B2 JP 3368434 B2 JP3368434 B2 JP 3368434B2 JP 08144093 A JP08144093 A JP 08144093A JP 8144093 A JP8144093 A JP 8144093A JP 3368434 B2 JP3368434 B2 JP 3368434B2
Authority
JP
Japan
Prior art keywords
powder
coating
particle size
coated
applying
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
JP08144093A
Other languages
Japanese (ja)
Other versions
JPH06262137A (en
Inventor
正文 松永
Original Assignee
ノードソン株式会社
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by ノードソン株式会社 filed Critical ノードソン株式会社
Priority to JP08144093A priority Critical patent/JP3368434B2/en
Priority to AU63652/94A priority patent/AU6365294A/en
Priority to PCT/US1994/002743 priority patent/WO1994021385A1/en
Priority to DE69413809T priority patent/DE69413809T2/en
Priority to EP94910938A priority patent/EP0689480B1/en
Priority to US08/513,893 priority patent/US5747106A/en
Publication of JPH06262137A publication Critical patent/JPH06262137A/en
Application granted granted Critical
Publication of JP3368434B2 publication Critical patent/JP3368434B2/en
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

Links

Classifications

    • BPERFORMING OPERATIONS; TRANSPORTING
    • B05SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05DPROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05D7/00Processes, other than flocking, specially adapted for applying liquids or other fluent materials to particular surfaces or for applying particular liquids or other fluent materials
    • B05D7/50Multilayers
    • B05D7/52Two layers
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B05SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05DPROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05D1/00Processes for applying liquids or other fluent materials
    • B05D1/36Successively applying liquids or other fluent materials, e.g. without intermediate treatment
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B05SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05DPROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05D2451/00Type of carrier, type of coating (Multilayers)

Landscapes

  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Wood Science & Technology (AREA)
  • Application Of Or Painting With Fluid Materials (AREA)
  • Paints Or Removers (AREA)

Description

【発明の詳細な説明】Detailed Description of the Invention

【0001】[0001]

【産業上の利用分野】本発明は、被塗物への粉体の塗布
方法に関するものである。本発明での粉体とは、あらゆ
る形状の粉体物を意味し、リンペン状のものをも含むも
のとし、またそれらの材質は限定されない。
BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to a method for coating powder on an article to be coated. The powder in the present invention means a powder material having any shape, including a rhenpen-like material, and the material thereof is not limited.

【0002】[0002]

【従来の技術】従来、接着剤として塗布したり、塗装と
して塗布する粉体は、目的に応じて平均粒径を変えて使
用されてきた。例えば厚塗りを必要とする場合には大き
な粒径の粉体を、また薄塗りの場合には小さい粒径の粉
体を用いるという概念が、当業界では一般的であった。
2. Description of the Related Art Heretofore, powders applied as an adhesive or as a coating have been used by changing the average particle size depending on the purpose. For example, the concept of using powder with a large particle size when thick coating is required and using powder with a small particle size when thin coating has been common in the art.

【0003】[0003]

【発明が解決しようとする課題】ところが、大きな粒径
の粉体を用いる場合には、加熱した後のレベリングが悪
く、また熱硬化性の場合にはオレンジピールと称され
る、ゆずのはだ状の仕上り面がそのまま残り、美粧性が
失われるなどの問題があった。
However, when powder having a large particle size is used, leveling after heating is poor, and when it is thermosetting, it is called orange peel, which is called yuzunoha. There was a problem that the finished surface of the shape remained as it was and the cosmetic appearance was lost.

【0004】一方、小さい粒径の粉体を用いる場合に
は、レベリングはよいが、粉体を構成する1粒子当りの
重量に対する表面積の比が大きくなるため、かさ密度が
低く搬送能力が低下し、またスプレイしたときに空気中
の抵抗を受けて直進性を長く維持することがむずかし
く、くぼみ部や奥まって狭くなった部分等の形状を有す
る被塗物では粉体の入り込み性が悪かった。従ってくぼ
み部や奥まって狭くなった部分等への粉体の入り込み性
をよくするため、エジェクターエアの圧力を高くし、粉
体の吐出量を多くしてやる必要があるが、エジェクター
エアの圧力を高くすると、それに伴ってエア流量も増加
することから塗着効率が極めて低かった。また粒径が小
さい粉体は、製造コストが高くその良さがわかっていて
もランニングコストの増加につながることから、市場で
は敬遠されがちだつた。
On the other hand, when powder having a small particle size is used, leveling is good, but since the ratio of the surface area to the weight per particle constituting the powder is large, the bulk density is low and the carrying capacity is lowered. Further, when sprayed, it is difficult to maintain the straightness due to resistance in the air for a long time, and the intrusion of the powder is poor in the object to be coated having a shape such as a recess or a part which is narrowed in the back. Therefore, it is necessary to increase the pressure of the ejector air and increase the discharge amount of the powder in order to improve the ability of the powder to enter the recesses and the narrowed part at the back. As a result, the air flow rate also increased, and the coating efficiency was extremely low. Further, powders having a small particle size tend to be shunned in the market because they have high manufacturing costs and increase running costs even if their goodness is known.

【0005】本発明は、上記した問題点に鑑みてなされ
たもので、レベリングがよく美粧性が優れ、粉体の直進
性も確保しつつ塗着効率もよい、高品質の塗布膜が得ら
れる粉体の塗布方法を提供することを目的とする。
The present invention has been made in view of the above-mentioned problems. A high-quality coating film having good leveling, excellent cosmetic properties, and good powder advancing efficiency and good coating efficiency can be obtained. It is an object to provide a powder coating method.

【0006】[0006]

【課題を解決するための手段】前記した課題を解決する
ために本発明では次のような粉体の塗布方法とした。 (1)被塗物にA及びBの粉体を別々に塗布する方法で
あって、平均粒径が15ミクロン以上120ミクロン未
満のAの粉体を最初に塗布し、しかる後、該Aの粉体よ
り小さい粒径の平均粒径が0.1ミクロン以上15ミク
ロン未満のBの粉体を塗布することにより、該粒径の大
きいAの粉体で直進性を確保して塗着効率を高めて塗布
するようにし、該粒径の小さいBの粉体でレベリングを
補うようにして、高品質の塗布膜を得る粉体の塗布方法
とした。 (2)上記(1)の粉体の塗布方法において、Aの粉体
を塗布し、仮加熱により溶融させ、しかる後、Bの粉体
を塗布して、次いで加熱により溶融又は硬化させる粉体
の塗布方法とした。 (3)上記(1)の粉体の塗布方法において、A及びB
の粉体が各々同一樹脂を主成分とする粉体の塗布方法と
した。 (4)上記(1)の粉体の塗装方法において、Aの粉体
とBの粉体の塗布後又は溶融後の単位面積当りの塗膜厚
体積比が、Aの粉体はBの粉体の1.1倍以上である粉
体の塗布方法とした。 (5)上記(1)の粉体の塗装方法において、最初にA
の粉体を塗布し、次にBの粉体を塗布することを複数回
繰り返して行う粉体の塗布方法とした。
In order to solve the above-mentioned problems, the present invention employs the following powder coating method. (1) A method of separately applying powders of A and B to an object to be coated, wherein powder of A having an average particle size of 15 μm or more and less than 120 μm is first applied, and then the powder of A By coating the powder of B having an average particle size smaller than the powder of 0.1 micron or more and less than 15 microns, the powder of A having a large particle size can ensure straightness and improve the coating efficiency. The powder was coated at a higher level, and the powder of B having a smaller particle diameter was used to compensate the leveling, whereby a powder coating method for obtaining a high quality coating film was obtained. (2) In the powder coating method of (1) above, the powder of A is coated and melted by temporary heating, and then the powder of B is coated and then melted or cured by heating. Was applied. (3) In the powder coating method of (1) above, A and B are used.
Each of the powders was a coating method in which the same resin was the main component. (4) In the coating method of powder according to the above (1), the powder volume volume ratio per unit area after coating or melting the powder of A and the powder of B is such that the powder of A is the powder of B. The method of applying powder was 1.1 times or more of the body. (5) In the powder coating method of (1) above, first, A
This is a method of applying a powder in which the application of the powder of No. 1 and the application of the powder of B are repeated several times.

【0007】[0007]

【作用】前記した本発明の方法よれば、平均粒径の大き
な粉体を最初に塗布することにより、塗着高率を高めて
塗膜厚をかせぐことができ、次いで塗布する平均粒径の
小さい粉体でレベリングを補うことができる。
According to the above-mentioned method of the present invention, the coating rate can be increased and the coating thickness can be increased by first applying the powder having a large average particle size. Leveling can be supplemented with a small powder.

【0008】[0008]

【実施例】以下実施例について図面を参照しながら具体
的に説明する。図1は本発明による粉体の塗布状態を示
す図であり、図において符号1は被塗物を示し、該被塗
物1の表面に最初に大きな粒径の粉体2を塗布し、次に
小さい粒径の粉体3を塗布した様子を示したものであ
る。これにより大きな粒径の粉体2によって塗着高率を
高めて塗膜厚をかせぐことができ、次いで塗布する小さ
い粒径の粉体3でレベリングを補うことができる。従っ
て重防目的でも表面仕上げを向上させることができ、付
加価値を高めることができる。さらにくぼみ部や奥まっ
て狭くなった部分等の形状を有する被塗物、例えばスチ
ール家具のような被塗物の場合、くぼみ部や奥まって狭
くなった部分等の形状の箇所には、大きな粒径の粉体が
方向性をもって到達し、防錆効果が高まり、また美観が
要求される外表面箇所には、主に小さい粒径の粉体が塗
着表面を覆うことになるのできれいな仕上げ面が得られ
る。その様子を図2に示す。図において符号1は被塗物
を示し、該被塗物1には、くぼみ部5が形成されてお
り、最初に大きな粒径の粉体2を塗布し、次に小さい粒
径の粉体3を塗布した様子を示したものである。
EXAMPLES Examples will be specifically described below with reference to the drawings. FIG. 1 is a view showing a coating state of a powder according to the present invention. In the figure, reference numeral 1 indicates an object to be coated, and the surface of the object to be coated 1 is first coated with a powder 2 having a large particle diameter, and then, 3 shows a state in which the powder 3 having a small particle size is applied to the. As a result, the coating rate can be increased by increasing the coating rate with the powder 2 having a large particle size, and the leveling can be supplemented by the powder 3 having a small particle size to be applied next. Therefore, the surface finish can be improved and the added value can be increased even for the purpose of serious prevention. In addition, in the case of an object to be coated that has a shape such as a recess or a part that becomes narrower in the back, for example, an object to be coated such as steel furniture, a large grain is found in the shape of the recess or the part that becomes narrower in the back. Since the powder with a small diameter arrives in a direction, the rust prevention effect is enhanced, and the outer surface where aesthetics are required, the powder with a small particle size mainly covers the coating surface, so a clean finished surface. Is obtained. The situation is shown in FIG. In the figure, reference numeral 1 indicates an article to be coated, in which a depression 5 is formed, the powder 2 having a large particle size is first applied, and then the powder 3 having a small particle size is applied. It shows a state of applying.

【0009】また一般的に、体質顔料等が多いほど粉体
塗料のコストは安くできることから、被塗物の下層側に
比較的大きな粒径のしかも体質顔料が多く含まれた粉体
を塗布し、上層部へは比較的小さい粒径の着色顔料を多
く含んだ粉体あるいは樹脂のみのクリヤー粉体を塗布す
ることにより、ランニングコストを安くかつ付加価値を
上げることができる。
[0009] Generally, since the cost of the powder coating material can be reduced as the amount of the extender pigment is large, a powder having a relatively large particle size and containing a large amount of the extender pigment is applied to the lower layer side of the object to be coated. By applying a powder containing a large amount of a color pigment having a relatively small particle size or a clear powder containing only a resin to the upper layer, the running cost can be reduced and the added value can be increased.

【0010】また後加工をするようなPCM工法(鋼板
等に曲げ加工等を行う前に予め塗装を行うこと)におい
ては、強靱な厚い塗膜の場合クラックを生じることがあ
るので、下層側を加工性や密着性等に優れた粉体を用い
比較的厚めの塗膜にして、上層側を強靱で、耐薬品製、
耐候性等を考慮した材質の粉体を用いて比較的薄めの塗
膜を形成させることもできる。
Further, in the PCM method in which post-processing is performed (coating is performed in advance before bending of a steel plate etc.), cracks may occur in the case of a tough and thick coating film, so the lower layer side A relatively thick coating made of powder with excellent workability and adhesion, the upper layer is tough and made of chemical resistance,
It is also possible to form a relatively thin coating film by using a powder of a material in consideration of weather resistance and the like.

【0011】また昨今、つや消しやスウェード調あるい
はハンマートーン系等、意匠性の優れた塗装が市場で好
まれているが、本発明の方法によれば、ウレタン、ポリ
スチレンあるいはガラスなどのビーズを必要に応じカラ
ー化したもの又はそれらの成分を主体とした比較的小さ
い粒径の粉体を上層部に塗布することにより、つや消し
やスウェード調の塗膜が容易に得られ、また相溶性の悪
い樹脂や成分を添加した比較的小さい粒径の粉体を上層
部に分散させることにより、ハンマートーン系の塗膜が
容易に得られる。またそれらのものは異なった粉体に変
更するとき、しばしば粉体の流路内に残留し、品質上の
問題を起こすが、本発明の方法によれば流路を独立して
設けることにより、そのような問題を起こすことはな
い。
[0011] In recent years, coatings having a good design such as matte, suede tone and hammer tone type have been favored in the market, but according to the method of the present invention, beads such as urethane, polystyrene or glass are required. By applying a colored material or a powder having a relatively small particle size mainly composed of those components to the upper layer, a matte or suede-like coating film can be easily obtained, and a resin having poor compatibility or By dispersing the powder having a relatively small particle size to which the components are added in the upper layer portion, a hammertone type coating film can be easily obtained. Also, when they are changed to different powders, they often remain in the flow path of the powder, causing quality problems, but by providing the flow path independently according to the method of the present invention, It does not cause such a problem.

【0012】また高分子量でかつ大きな粒径の粉体は、
加熱溶融時のレベリングの悪さに加えて、粒子のまわり
に存在するエアが一層レベリングを邪魔し、また表面が
早く溶融すると粒子のまわりに存在したエアは気泡とな
って残存する。そのような問題を解決する方法として、
本発明では大きな粒径の粉体を塗布した後、仮加熱によ
り粉体を溶融させ、その後小さい粒径の粉体を塗布し
て、ピンホールや塗膜の薄い部分をカバーして、ピンホ
ールがなくしかもレベリングのよい高品質の塗膜を得る
ことができる。その様子を図3に示す。図において符号
1は被塗物を示し、該被塗物1に最初に大きな粒径の粉
体を塗布し、仮加熱によって溶融状態にある被膜6の上
に、小さい粒径の粉体3を塗布した様子を示したもので
ある。
Further, a powder having a high molecular weight and a large particle size is
In addition to poor leveling at the time of heating and melting, air existing around the particles further hinders leveling, and when the surface melts quickly, the air existing around the particles remains as bubbles. As a way to solve such problems,
In the present invention, after applying a powder having a large particle size, the powder is melted by temporary heating, and then a powder having a small particle size is applied to cover a pinhole or a thin portion of the coating film, It is possible to obtain a high-quality coating film that is free from defects and has good leveling. The situation is shown in FIG. In the figure, reference numeral 1 indicates an object to be coated. First, a powder having a large particle size is first applied to the object to be coated 1, and a powder 3 having a small particle size is applied onto a coating film 6 in a molten state by temporary heating. It shows the state of application.

【0013】また下層部と上層部の粉体の種類は特に限
定されるものではないが、下層部には有機系の粉体が密
着性の点から好ましく、無機系と有機系との混合又は無
機系のものを有機系のカプセルで包囲した物でもよい。
特に高付加価値を持たせることが出来るフッ素系粉体や
ポリイミド系粉体は高価なため、本発明によりランニン
グコストを押えかつ高性能を発揮させることが出来る。
また熱硬化性の場合には触媒や硬化剤あるいは官能基の
違い等によって、相溶性が悪く、はじき現象を起こすこ
ともあるため、同一樹脂系のものを使用することが望ま
しい。
The type of powder in the lower layer and the upper layer is not particularly limited, but organic powder is preferable in the lower layer from the viewpoint of adhesion, and a mixture of inorganic and organic powders or It may be an inorganic material surrounded by an organic capsule.
In particular, since fluorine-based powders and polyimide-based powders, which can have high added value, are expensive, the present invention can suppress running costs and exhibit high performance.
Further, in the case of thermosetting, compatibility may be poor due to a difference in catalyst, curing agent, functional group, or the like, and a repelling phenomenon may occur. Therefore, it is desirable to use the same resin system.

【0014】更に、レベリング現象は、各々の粉体材料
が溶融したときの表面張力に大きく依存するため、粉体
の溶融時の表面張力は40dyne/cm以上が好まし
い。また前述したように経済的にも生産性の面からも、
大きな粒径の粉体を多く用いて下層側の量を多くするこ
とが優位性を発揮できる。また官能基を持たせた樹脂か
らなる大きな粒径の粉体と、硬化剤からなる小さい粒径
の粉体を、順次塗り重ねることにより、塗膜のポットラ
イフを気にせず、塗膜性能を向上させることができる。
例えばポリエステルにイソシアネート官能基を持たせた
大きな粒径の粉体と、ブロックイソシアネートをカプセ
ル化した小さい粒径の粉体の、塗り重ねや分散塗布を複
数回繰り返した後、加熱溶融ないし架橋させることによ
り、目的を達成できる。
Furthermore, since the leveling phenomenon largely depends on the surface tension when each powder material is melted, the surface tension when the powder is melted is preferably 40 dyne / cm or more. Also, as mentioned above, from the economical and productivity perspectives,
The advantage can be exhibited by increasing the amount of the lower layer by using a large amount of powder having a large particle size. Also, by coating a large particle size powder made of a resin having a functional group and a small particle size powder made of a curing agent in order, the coating film performance can be improved without worrying about the pot life of the coating film. Can be improved.
For example, heating and melting or crosslinking after repeating coating and dispersion coating multiple times with a large particle size powder that has an isocyanate functional group in polyester and a small particle size powder that encapsulates blocked isocyanate By this, the purpose can be achieved.

【0015】[0015]

【発明の効果】本発明では、以上説明したような粉体の
塗布方法としたので、レベリングがよく美粧性が優れ、
粉体の直進性も確保しつつ塗着効率もよく、しかも高品
質の塗布膜が得られる。
According to the present invention, since the powder coating method as described above is used, the leveling is good and the cosmetic appearance is excellent.
It is possible to obtain a high-quality coating film while ensuring the linearity of the powder and also having good coating efficiency.

【図面の簡単な説明】[Brief description of drawings]

【図1】本発明による粉体の塗布状態を示す図。FIG. 1 is a view showing a coating state of powder according to the present invention.

【図2】くぼみ部を持った被塗物に本発明により粉体を
塗布した状態を示す図。
FIG. 2 is a diagram showing a state in which powder is applied according to the present invention to an object to be coated having a hollow portion.

【図3】本発明による粉体の塗布状態の他の態様を示す
図。
FIG. 3 is a diagram showing another embodiment of a powder coating state according to the present invention.

【符号の説明】[Explanation of symbols]

1 被塗物 2 大きな粒
径の粉体 3 小さい粒径の粉体 5 くぼみ部 6 溶融状態にある被膜
1 Object to be coated 2 Powder with large particle size 3 Powder with small particle size 5 Recessed portion 6 Film in molten state

Claims (5)

(57)【特許請求の範囲】(57) [Claims] 【請求項1】 被塗物にA及びBの粉体を別々に塗布す
る方法であって、平均粒径が15ミクロン以上120ミ
クロン未満のAの粉体を最初に塗布し、しかる後、該A
の粉体より小さい粒径の平均粒径が0.1ミクロン以上
15ミクロン未満のBの粉体を塗布することにより、該
粒径の大きいAの粉体で直進性を確保して途着効率を高
めて塗布するようにし、該粒径の小さいBの粉体でレベ
リングを補うようにして、高品質の塗布膜を得ることを
特徴とする粉体の塗布方法。
1. A method of separately applying powders of A and B to an object to be coated, wherein powder of A having an average particle size of 15 μm or more and less than 120 μm is first applied, and then the powder is applied. A
By applying a powder of B having an average particle size smaller than the powder of 0.1 to 0.1 μm and less than 15 μm.
A straight particle is ensured by the powder of A with a large particle size, and the transfer efficiency is improved.
The powder of B having a small particle size is applied as a level.
A powder coating method, characterized in that a high quality coating film is obtained by supplementing the ring .
【請求項2】 Aの粉体を塗布し、仮加熱により溶融さ
せ、しかる後、Bの粉体を塗布して、次いで加熱により
溶融又は硬化させることを特徴とする請求項1記載の粉
体の塗布方法。
2. A powder of A is applied and melted by temporary heating.
Then, after applying the powder of B, by heating
The powder coating method according to claim 1, wherein the powder coating is performed by melting or curing .
【請求項3】 A及びBの粉体が各々同一樹脂を主成分
とすることを特徴とする請求項記載の粉体の塗布方
法。
3. The powders A and B each contain the same resin as a main component.
Powder method of coating according to claim 1, characterized in that a.
【請求項4】 Aの粉体とBの粉体の塗布後又は溶融後
の単位面積当りの塗膜厚体積比が、Aの粉体はBの粉体
の1.1倍以上であることを特徴とする請求項1記載の
粉体の塗布方法。
4. After coating or melting the powder of A and the powder of B
Of the coating film thickness volume ratio per unit area of A, the powder of A is the powder of B
It is 1.1 times or more of the above .
【請求項5】最初にAの粉体を塗布し、次にBの粉体を
塗布することを、複数回繰り返して行うことを特徴とす
る請求項記載の粉体の塗布方法。
5. A powder of A is applied first, and then a powder of B is applied.
The powder coating method according to claim 1, wherein the coating is repeated a plurality of times .
JP08144093A 1993-03-15 1993-03-15 Powder application method Expired - Lifetime JP3368434B2 (en)

Priority Applications (6)

Application Number Priority Date Filing Date Title
JP08144093A JP3368434B2 (en) 1993-03-15 1993-03-15 Powder application method
AU63652/94A AU6365294A (en) 1993-03-15 1994-03-14 Two stage powder application method
PCT/US1994/002743 WO1994021385A1 (en) 1993-03-15 1994-03-14 Two stage powder application method
DE69413809T DE69413809T2 (en) 1993-03-15 1994-03-14 TWO-STAGE POWDER COATING PROCESS
EP94910938A EP0689480B1 (en) 1993-03-15 1994-03-14 Two stage powder application method
US08/513,893 US5747106A (en) 1993-03-15 1994-03-14 Two stage powder application method

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP08144093A JP3368434B2 (en) 1993-03-15 1993-03-15 Powder application method

Publications (2)

Publication Number Publication Date
JPH06262137A JPH06262137A (en) 1994-09-20
JP3368434B2 true JP3368434B2 (en) 2003-01-20

Family

ID=13746460

Family Applications (1)

Application Number Title Priority Date Filing Date
JP08144093A Expired - Lifetime JP3368434B2 (en) 1993-03-15 1993-03-15 Powder application method

Country Status (5)

Country Link
EP (1) EP0689480B1 (en)
JP (1) JP3368434B2 (en)
AU (1) AU6365294A (en)
DE (1) DE69413809T2 (en)
WO (1) WO1994021385A1 (en)

Families Citing this family (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP4079935A3 (en) * 2012-03-21 2023-01-25 Swimc Llc Two-coat single cure powder coating
US9751107B2 (en) 2012-03-21 2017-09-05 Valspar Sourcing, Inc. Two-coat single cure powder coating
NL2019197B1 (en) * 2017-07-07 2019-01-16 Stahl Int B V Powder coating method and coated article

Family Cites Families (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3348995A (en) * 1964-03-09 1967-10-24 American Cast Iron Pipe Co Method of coating metal surfaces with polyethylene utilizing a polyethylene primer and articles produced thereby
DE8816295U1 (en) * 1988-03-02 1989-07-06 Heinzel, Winfried, 7758 Meersburg Coated plate for household appliances

Also Published As

Publication number Publication date
EP0689480A1 (en) 1996-01-03
AU6365294A (en) 1994-10-11
EP0689480B1 (en) 1998-10-07
DE69413809T2 (en) 1999-03-04
DE69413809D1 (en) 1998-11-12
WO1994021385A1 (en) 1994-09-29
JPH06262137A (en) 1994-09-20

Similar Documents

Publication Publication Date Title
GB2361439A (en) Adhesive decorative film used to colour surfaces
CA2137207A1 (en) Transparent Functional Membrane Containing Functional Ultrafine Particles, Transparent Functional Film, and Process for Producing the Same
CA2145828A1 (en) Material and process for manufacturing plastic parts
CA2180158A1 (en) Decorative Material Having Abrasion Resistance
JPS60238183A (en) Method of applying thermoplastic or thermo-setting coating to surface of article
JPH07316782A (en) Island coating containing primer/base coat layer
JP3368434B2 (en) Powder application method
JPH07295487A (en) Photo-recursive reflecting paint film, and its formation method
EP1286788A2 (en) Electrostatic powder coating on non-conductive plastics
US5747106A (en) Two stage powder application method
CN102470571B (en) Method of making an elastomeric skin and skin obtained by that method
US20030083147A1 (en) Golf club head
JPS602194B2 (en) decorative board
JPH06278261A (en) Decorative sheet with uneven appearance inside and manufacture of the same
JP7811241B2 (en) Coated metal sheet and method for manufacturing coated metal sheet
JP2005119021A (en) Decorative sheet
JP2519528B2 (en) Plasticized soft synthetic resin product having transparent conductive layer and transfer member for forming transparent conductive layer
CN220298155U (en) Customizable spray painting color drawing board
JP2025538432A5 (en)
CN219489898U (en) Ultra-matte carborundum car body color-changing film
JPS58205568A (en) Painting of metallic structure excellent in shock resistance
JP3302325B2 (en) Method of manufacturing wall panels
KR101228214B1 (en) Injection molding simultaneous decorating transfer sheet having stereoscopic deposited layer and preparation method thereof
JPH06220878A (en) Manhole cover and manufacture thereof
JPH03267173A (en) Brightening method

Legal Events

Date Code Title Description
R250 Receipt of annual fees

Free format text: JAPANESE INTERMEDIATE CODE: R250

R250 Receipt of annual fees

Free format text: JAPANESE INTERMEDIATE CODE: R250

FPAY Renewal fee payment (event date is renewal date of database)

Free format text: PAYMENT UNTIL: 20081115

Year of fee payment: 6

FPAY Renewal fee payment (event date is renewal date of database)

Free format text: PAYMENT UNTIL: 20091115

Year of fee payment: 7

FPAY Renewal fee payment (event date is renewal date of database)

Free format text: PAYMENT UNTIL: 20091115

Year of fee payment: 7

FPAY Renewal fee payment (event date is renewal date of database)

Free format text: PAYMENT UNTIL: 20101115

Year of fee payment: 8

FPAY Renewal fee payment (event date is renewal date of database)

Free format text: PAYMENT UNTIL: 20111115

Year of fee payment: 9

FPAY Renewal fee payment (event date is renewal date of database)

Free format text: PAYMENT UNTIL: 20111115

Year of fee payment: 9

FPAY Renewal fee payment (event date is renewal date of database)

Free format text: PAYMENT UNTIL: 20121115

Year of fee payment: 10

FPAY Renewal fee payment (event date is renewal date of database)

Free format text: PAYMENT UNTIL: 20131115

Year of fee payment: 11