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JP3583566B2 - Vulcanization method for rubber products - Google Patents
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JP3583566B2 - Vulcanization method for rubber products - Google Patents

Vulcanization method for rubber products Download PDF

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Publication number
JP3583566B2
JP3583566B2 JP29577796A JP29577796A JP3583566B2 JP 3583566 B2 JP3583566 B2 JP 3583566B2 JP 29577796 A JP29577796 A JP 29577796A JP 29577796 A JP29577796 A JP 29577796A JP 3583566 B2 JP3583566 B2 JP 3583566B2
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Japan
Prior art keywords
mold
molds
pressurizing
vulcanization
rubber
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JP29577796A
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Japanese (ja)
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JPH10119083A (en
Inventor
伸夫 井上
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Bridgestone Corp
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Bridgestone Corp
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Description

【0001】
【発明の属する技術分野】
この発明は、例えば自動車用防振ゴムや産業用小型ゴム製品、或いはその他のゴム製品の加硫方法に係り、特に所定の金型内のキャビテイへゴムを射出し、その後、熱と圧力とを所定の時間加えて加硫させるゴム製品の加硫方法に関するものである。
【0002】
【従来の技術】
一般にゴム製品の加硫方法としては、例えば1個のモールド内にゴム材料を射出し、そのまま加硫の終了まで熱と圧力を加えて一定時間保持することが広く行われている。
【0003】
しかしながら、加硫に要する時間が長い場合には、熱と圧力を加えるためのプレス装置の回転率が低下するから、製造コストの増大につながっている。
【0004】
そこで、生産性を高めるために、例えば図8に示すように、ターンテーブル100の適宜部位に設けた射出ステーション101でモールド102内にゴム材料を射出したならば、そのモールド102をターンテーブル100に載置するとともに、そのターンテーブル100を毎回適宜角度量(ピッチ)ずつ回転し、送り出していくロータリ形式のものが開発されている。
【0005】
このロータリ形式のものでは、次々に送り出されていくモールド102内のゴム製品は、所定の加熱・加圧工程等を経たのち、最後に分解・取り出しステーションにおいて、ターンテーブル100上のモールド102内から順次取り出されていくのである。
【0006】
【発明が解決しようとする課題】
しかしながら、このようなロータリ形式のものでは、加硫時間がターンテーブルの分割(ピッチ)数と1ピッチ送り出すのに要するサイクル時間とに拘束(制限)され、自由に変更調節することができないから、初期設定した加硫時間を変動させることは実際問題として、難しいものである。
【0007】
即ち、このような構成のものにあっては、所定の(単位時間当たりの)生産量を確保したまま加硫時間を短縮するのは現実には無理であるから、加硫時間を伸ばそうとするとどうしても時間当たりの生産量をセーブしなければならない。
【0008】
また、一定のサイクルタイムに比べて加硫時間が長いとき場合には、必然的にターンテーブルの分割(ピッチ)数が増大し、その分ターンテーブルの半径も増大するから、設置スペースが余分に大きく必要となり、これに伴って設備投資費用も上昇する。
【0009】
さらに、ターンテーブルの各々のユニットでモールドの加圧と加熱とを続行するために、これに対応する適宜のユニットにはそれぞれ加圧装置と加熱装置との双方を設置せねばならず、その分の駆動(運転)費用も多大となる。
【0010】
そこで、この発明は、上記した事情に鑑み、所定の生産量を確保するのに要する設備投資とプレス装置等の運転(電力)費用を大幅に削減することができるとともに、設置スペースを従来の半分以下に抑えることができ、しかも加硫時間の延長・短縮を自由に変更することができるゴム製品の加硫方法を提供することを目的とするものである。
【0011】
【課題を解決するための手段】
即ち、この請求項1に記載の発明は、所定の金属金型内のキャビテイへゴム材料を射出した後、熱と圧力とを所定時間加えて加硫させるゴム製品の加硫方法であって、射出装置の内部にセットした前記金型内部にゴム材料を毎回射出し、この射出後の金型を前記射出装置の内部若しくは射出装置の外部に設けた加圧・加熱装置に順次射出した順番に直列に複数積み重ねていき、その加圧・加熱装置において、金型の自重及び外部からの加圧力を利用して射出したゴム材料に圧力をかけるとともに、積み重ねた金型を加熱・保温することによって金型内のゴムの加硫を促進・進行させ、直列に積み重ねた方向へは加圧用シリンダによる加圧力を加え、金型両側に設けた溝に一対のホルダを取付けて複数の金型への加圧力を補助し、次の金型でのゴム材料の射出動作のたびに、積み重ねてある金型のうち加硫経過時間の長いものを前記直列に積み重ねた複数の前記金型部分から取り外していくものである。また、請求項2に記載の発明は、前記加圧・加熱装置は、一方に断熱板を介してヒータを固定し、他方に断熱板に設けたヒータを加圧用シリンダで移動可能に設け、両ヒータ間に複数の金型を積み重ねるように構成されているものである。さらに、請求項3に記載の発明は、前記加圧・加熱装置を射出装置の外部に設け、射出動作と加硫動作とを一部同時進行で行うようにしたものである。
【0012】
【発明の実施の形態】
以下、この発明の好適な一実施例について添付図面を参照しながら説明する。図1はこの発明に係るゴム製品の加硫方法に使用する加硫装置を示すものであり、この実施例では説明を分かりやすくするため、ゴム製品の加硫方法について説明するのに先立ちこの加硫装置から説明する。
【0013】
この実施例に係る加硫装置1は、複数(この実施例では常時4個)の適宜の金属製の金型(以下、モールド2と略す)に所定の圧力を印加する加圧用シリンダ3と、この加圧条件下でこれらのモールド2を適宜の温度に加熱する複数のヒータ4とを備えている。なお、この図1において、符号5は断熱板を示すものである。
【0014】
また、この実施例では、ゴム材料が射出されたモールド2のうち、射出時間の早いものから順(1、2、3、4の順番、なお図面上の表示はM1,M2,M3,M4とした)に、上から先に直列配置したものであり、またこのゴム材料の射出はこの加硫装置とは別に設けた図示外の射出装置によって予め先に行っておく。
【0015】
さらに、この加硫装置には、図2に示す左右一対のホルダ6を備えており、このホルダ6を用いて加圧力を側方側から補助的に高めている。そのため、このモールド2には、両側方にホルダ6の腕が入り込む溝を設けている。
【0016】
なお、ここで使用するモールドは外形寸法が同じならキャビティ寸法は勿論種々異なるものであっても何ら問題ない。従って、異サイズの生産方式が行える。
【0017】
次に、この発明に係るゴム製品の加硫方法について、先の実施例に係る加硫装置を参照しつつ説明する。
この実施例の加硫方法では、射出機の外部で加硫させるものであり、第1ステップS1から第6ステップS6で構成されている。即ち、この実施例の加硫方法では、射出機内にセットしたモールド2に向けゴム材料を射出したならば、この射出装置からモールド2ごと取り出し、加硫装置1内の所定部位に下から順次セットしていく。なお、ここで最初のモールド2について既に4個のもの(番号1から4まで)が射出されて加硫装置にセットされたところから説明する。
【0018】
この実施例の第1ステップS1では、図3に示すように、加硫装置1に4個のモールド2を直列配置する。
即ち、図1において、モールド2が上下方向直列に4個セットされ、この4個のモールドは最上部の上面がヒータ4及び断熱板5を介して(不動状態に設けた)適宜の固定部に当接している。また最下部の下面は、同様のヒータ4及び断熱板5を介して加圧用シリンダ3と当接している。
【0019】
なお、この実施例では、例えば図2に示すように、モールド2のうち番号2から4の3個のものがホルダ6でクランプされており、これらのモールド2を同時に直列方向に加圧している。また、この実施例では加熱方向は上下ばかりでなく、図示外の前後左右に少なくとも4か所設けた他のヒータによって、同時に加熱されている。
【0020】
次に、第2ステップS2では、これらのモールド2を加熱・加圧させて加硫するが、この加熱・加圧時間は、加硫装置に装着してから取り出すまでの時間、つまり4個分のモールド2を装着するのに要する時間である。この加硫後に、加圧用シリンダ3及びヒータ4の加圧動作を停止するとともに、ホルダ6によるホールド動作を停止する。
【0021】
次に、第3ステップS3では、加圧動作の停止後に、図3に示すように、最も加硫経過時間の長いモールド2、つまり番号1(図面上M1)のものを加硫装置から取り外す。
【0022】
次に、第4ステップS4では、その加硫装置から取り出していたモールド(番号1)2のものについてアフタ加硫時間の経過を確認したならば、そのモールド2からゴム製品を取り出す。
【0023】
さらに、第5ステップS5では、製品取り出し後のモールド(番号1のもの)2の型内に適宜の離型剤を塗布するとともに、射出機にセットし、ゴム材料を型内に射出する。
【0024】
第6ステップS6では、このようにしてゴム材料を射出したモールド(番号1のもの)2は、射出機から取り出して、図3に示すように加硫装置内の直列配置された複数のモールド2の最下部に挿入セットする。
【0025】
このようにして、モールド(番号1)2をセットしたならば、図4に示すように、ホルダ6を付け替えてモールド(番号3、4、1)2をクランプさせ、第2ステップS2から再度同一の工程を繰り返していく。
【0026】
なお、この実施例では、モールド2として都合4個のものを用い、繰り返し使用するようになっているが、これ以外に、例えば図6に示すように、5個以上のモールド(この場合には8個)を用い、射出動作と加硫動作とが一部同時進行で行われるような構成であっても構わない。
【0027】
また、この実施例のような射出機の外部での積み重ね加硫動作の他に、例えば図7に示すように、射出機7の内部で行う場合にも適用可能であり、この場合には下側から積み重ねるか、上側から積み重ねるかは、射出用ノズル71が上下どちらに配設されているかによるが、基本原理は同じである。
【0028】
また、これらの実施例では、説明を分かりやすくするために、上下方向にモールド2を積み重ねたが、これを90度横倒しにした水平方向への適用も可能である。
【0029】
また、これらの実施例において、加硫に要する時間は、モールドが積み重ねられている時間が最小加硫時間である。
【0030】
また逆に、加硫に長時間を要する場合には、第4ステップS4のアフタ加硫時間を必要なだけ確保すれば、容易に加硫時間が延長できる。
【0031】
【発明の効果】
以上説明してきたようにこの発明によれば、従来のモールドを個別に加圧・加熱する方式に比べて、直列配置による加圧・加熱方式によれば、以下に列記する効果が得られる。
▲1▼加圧・加熱に要するプレス部分若しくはターンテーブル部分の設備投資費用が大幅に削減できること、
▲2▼また、プレス装置を運転するための電力も大幅に節減できること、
▲3▼設置スペース的にも、従来のものに比べて凡そ半分程度ですむこと、
▲4▼加硫時間の増減を弾力的に対応することができること。
【図面の簡単な説明】
【図1】この発明に係るゴム製品の加硫方法に使用する加硫装置を示す説明図。
【図2】同説明図。
【図3】同説明図。
【図4】同説明図。
【図5】この発明に係るゴム製品の加硫方法を示すフローチャート。
【図6】この発明に係る他のゴム製品の加硫方法を示す説明図。
【図7】この発明に係るさらに他のゴム製品の加硫方法を示す説明図。
【図8】従来例を示す説明図。
【符号の説明】
1 加硫装置
2 モールド(金型)
3 加圧用シリダ
4 ヒータ
6 ホルダ
[0001]
TECHNICAL FIELD OF THE INVENTION
The present invention relates to, for example, a method of vulcanizing automobile anti-vibration rubber, industrial small rubber products, or other rubber products. In particular, the rubber is injected into a cavity in a predetermined mold, and then heat and pressure are reduced. The present invention relates to a method for vulcanizing a rubber product which is vulcanized for a predetermined time.
[0002]
[Prior art]
In general, as a vulcanizing method of rubber products, for example, a method of injecting a rubber material into a single mold and applying heat and pressure until the end of the vulcanization and holding the rubber material for a certain period of time is widely used.
[0003]
However, when the time required for vulcanization is long, the rotation rate of a press device for applying heat and pressure is reduced, which leads to an increase in manufacturing costs.
[0004]
Therefore, in order to increase the productivity, as shown in FIG. 8, for example, when a rubber material is injected into the mold 102 at an injection station 101 provided at an appropriate portion of the turntable 100, the mold 102 is transferred to the turntable 100. A rotary type in which the turntable 100 is rotated by an appropriate amount of angle (pitch) every time when it is mounted and sent out is developed.
[0005]
In this rotary type, the rubber products in the mold 102 that are successively sent out go through a predetermined heating / pressing step and the like, and finally, in the disassembling / removing station, the rubber products are removed from the mold 102 on the turntable 100. They are taken out sequentially.
[0006]
[Problems to be solved by the invention]
However, in such a rotary type, the vulcanization time is restricted (limited) by the number of divisions (pitch) of the turntable and the cycle time required to feed out one pitch, and cannot be freely changed and adjusted. Varying the initially set vulcanization time is difficult in practice.
[0007]
That is, in such a configuration, it is actually impossible to shorten the vulcanization time while securing a predetermined (per unit time) production amount. You must save the hourly production.
[0008]
Also, when the vulcanization time is longer than a certain cycle time, the number of divisions (pitch) of the turntable inevitably increases, and the radius of the turntable also increases accordingly. This will require a large amount of money, which will increase capital investment costs.
[0009]
Further, in order to continue the pressurization and heating of the mold in each unit of the turntable, both the pressurizing device and the heating device must be installed in the appropriate units corresponding thereto, respectively. Driving (operation) cost is also large.
[0010]
In view of the above circumstances, the present invention can significantly reduce capital investment and operation (electric power) costs of a press device and the like required to secure a predetermined production amount, and reduce installation space by half compared to the conventional case. It is an object of the present invention to provide a method for vulcanizing a rubber product which can be suppressed to the following and can freely change the extension / reduction of the vulcanization time.
[0011]
[Means for Solving the Problems]
That is, the invention according to claim 1 is a method for vulcanizing a rubber product, comprising injecting a rubber material into a cavity in a predetermined metal mold, and then applying heat and pressure for a predetermined time to vulcanize the rubber product. Each time a rubber material is injected into the mold set inside the injection device, the injected mold is sequentially injected into a pressurizing / heating device provided inside the injection device or outside the injection device. By stacking multiple in series and applying pressure to the injected rubber material using the own weight of the mold and external pressure in the pressurizing and heating device, heating and keeping the stacked molds warm Accelerates and advances the vulcanization of the rubber in the mold, applies pressure by a pressurizing cylinder in the direction of stacking in series, attaches a pair of holders to the grooves provided on both sides of the mold, the pressure assist, in the next mold Each of the injection operation of the arm material, in which we removed from a plurality of said mold portions stacked long ones vulcanization elapsed time on the series of molds are stacked. Further, in the invention according to claim 2, in the pressurizing / heating device, a heater is fixed to one side via a heat insulating plate, and a heater provided on the other side of the heat insulating plate is movably provided by a pressurizing cylinder. It is configured such that a plurality of molds are stacked between heaters. Further, in the invention according to claim 3, the pressurizing / heating device is provided outside the injection device, and the injection operation and the vulcanization operation are partially performed simultaneously.
[0012]
BEST MODE FOR CARRYING OUT THE INVENTION
Hereinafter, a preferred embodiment of the present invention will be described with reference to the accompanying drawings. FIG. 1 shows a vulcanizing apparatus used in the method for vulcanizing a rubber product according to the present invention. In this embodiment, in order to make the explanation easy to understand, the vulcanizing method is described before the method for vulcanizing a rubber product. The description starts with the sulfurizing device.
[0013]
The vulcanizing apparatus 1 according to the present embodiment includes a pressurizing cylinder 3 for applying a predetermined pressure to a plurality of (always four in this embodiment) metal molds (hereinafter abbreviated as mold 2). A plurality of heaters 4 for heating these molds 2 to an appropriate temperature under the pressurizing condition are provided. In FIG. 1, reference numeral 5 denotes a heat insulating plate.
[0014]
Further, in this embodiment, among the molds 2 into which the rubber material has been injected, the injection time of the mold 2 is shortest (in order of 1, 2, 3, 4 ; the indications on the drawing are M1, M2, M3, M4). in the) are those in series arranged ahead from the top, also they are processed in advance before the separately provided unillustrated injection device the injection of the rubber material and the vulcanizing apparatus.
[0015]
Further, the vulcanizing apparatus is provided with a pair of right and left holders 6 shown in FIG. 2, and the pressing force is supplementarily increased from the side using the holders 6. Therefore, the mold 2 has grooves on both sides into which the arms of the holder 6 enter.
[0016]
It should be noted that if the mold used here has the same outer dimensions, there is no problem even if the cavity dimensions are of course different. Therefore, production systems of different sizes can be performed.
[0017]
Next, a method for vulcanizing a rubber product according to the present invention will be described with reference to a vulcanizing apparatus according to the previous embodiment.
In the vulcanization method of this embodiment, vulcanization is performed outside of the injection machine, and comprises a first step S1 to a sixth step S6. That is, in the vulcanization method of this embodiment, when the rubber material is injected toward the mold 2 set in the injection machine, the entire mold 2 is taken out from the injection device and set in a predetermined portion in the vulcanization device 1 sequentially from below. I will do it. Here, the first mold 2 will be described from the point where four molds (numbers 1 to 4) have already been injected and set in the vulcanizing apparatus.
[0018]
In the first step S1 of this embodiment, as shown in FIG. 3, four molds 2 are arranged in series in a vulcanizing apparatus 1.
That is, in FIG. 1, four molds 2 are set in series in the up-down direction, and the upper surfaces of the four molds are mounted on an appropriate fixed portion (provided in a stationary state) via a heater 4 and a heat insulating plate 5. Abut. The lowermost lower surface is in contact with the pressurizing cylinder 3 via the same heater 4 and heat insulating plate 5.
[0019]
In this embodiment, for example, as shown in FIG. 2, three molds 2 to 4 of the molds 2 are clamped by the holder 6, and these molds 2 are simultaneously pressed in series. . In this embodiment, the heaters are heated not only vertically but also simultaneously by other heaters provided at least at four positions in the front, rear, left and right directions (not shown).
[0020]
Next, in a second step S2, these molds 2 are heated and pressurized for vulcanization. The heating and pressurizing time is the time from mounting to the vulcanizing apparatus to removal, that is, four molds. This is the time required to mount the mold 2. After the vulcanization, the pressurizing operation of the pressurizing cylinder 3 and the heater 4 is stopped, and the holding operation by the holder 6 is stopped.
[0021]
Next, in a third step S3, after the pressurizing operation is stopped, as shown in FIG. 3, the mold 2 having the longest vulcanization elapsed time, that is, the mold 1 (M1 in the drawing) is removed from the vulcanization apparatus.
[0022]
Next, in a fourth step S4, if it is confirmed that the after vulcanization time has elapsed for the mold (No. 1) 2 removed from the vulcanizing apparatus, the rubber product is removed from the mold 2.
[0023]
Further, in a fifth step S5, an appropriate release agent is applied to the mold of the mold (having the number 1) 2 after the product is taken out, and is set in an injection machine to inject the rubber material into the mold.
[0024]
In the sixth step S6, the mold (number 1) into which the rubber material has been injected in this manner is taken out of the injection machine, and a plurality of molds 2 arranged in series in a vulcanizing apparatus as shown in FIG. Insert and set at the bottom of.
[0025]
When the mold (No. 1) 2 is set in this way, as shown in FIG. 4, the holder 6 is replaced to clamp the mold (No. 3, 4, 1) 2, and the same operation is performed again from the second step S2. Steps are repeated.
[0026]
In this embodiment, four molds 2 are used for convenience and are repeatedly used. In addition, for example, as shown in FIG. 6, five or more molds (in this case, 8), and the injection operation and the vulcanization operation may be partially performed simultaneously.
[0027]
In addition to the stacking vulcanization operation outside the injection machine as in this embodiment, for example, as shown in FIG. Whether to stack from the side or from above depends on whether the injection nozzle 71 is arranged above or below, but the basic principle is the same.
[0028]
Further, in these embodiments, the molds 2 are stacked in the up-down direction for easy understanding of the description. However, it is also possible to apply the mold 2 in the horizontal direction by turning the mold 2 down by 90 degrees.
[0029]
In these examples, the time required for vulcanization is the minimum vulcanization time during which the molds are stacked.
[0030]
Conversely, when a long time is required for vulcanization, if the after-vulcanization time in the fourth step S4 is as long as necessary, the vulcanization time can be easily extended.
[0031]
【The invention's effect】
As described above, according to the present invention, the following effects can be obtained according to the pressurizing / heating method in which the molds are arranged in series, as compared with the conventional method of individually pressing and heating the molds.
(1) Significant reduction in capital investment costs for the press part or turntable part required for pressurization and heating;
(2) In addition, the power for operating the press device can be greatly reduced,
(3) The installation space is about half that of the conventional one,
(4) Being able to flexibly respond to changes in vulcanization time.
[Brief description of the drawings]
FIG. 1 is an explanatory view showing a vulcanizing apparatus used in a method for vulcanizing a rubber product according to the present invention.
FIG. 2 is an explanatory view of the same.
FIG. 3 is an explanatory view of the same.
FIG. 4 is an explanatory view of the same.
FIG. 5 is a flowchart showing a method for vulcanizing a rubber product according to the present invention.
FIG. 6 is an explanatory diagram showing a method for vulcanizing another rubber product according to the present invention.
FIG. 7 is an explanatory view showing a method for vulcanizing still another rubber product according to the present invention.
FIG. 8 is an explanatory view showing a conventional example.
[Explanation of symbols]
1 Vulcanizer 2 Mold (die)
3 Pressing cylinder 4 Heater 6 Holder

Claims (3)

所定の金属金型内のキャビテイへゴム材料を射出した後、熱と圧力とを所定の加硫時間加えて加硫させるゴム製品の加硫方法であって、
射出装置の内部にセットした前記金型内部にゴム材料を毎回射出し、
この射出後の金型を前記射出装置の内部若しくは射出装置の外部に設けた加圧・加熱装置に射出した順番に直列に複数積み重ねていき、
その加圧・加熱装置において、金型の自重及び外部からの加圧力を利用して射出したゴム材料に圧力をかけるとともに、積み重ねた金型を加熱・保温することによって金型内のゴムの加硫を促進・進行させ、
直列に積み重ねた方向へは加圧用シリンダによる加圧力を加え、金型両側に設けた溝に一対のホルダを取付けて複数の金型への加圧力を補助し、
次の金型でのゴム材料の射出動作のたびに、積み重ねてある金型のうち加硫経過時間の長いものを前記直列に積み重ねた複数の前記金型部分から取り外していくことを特徴とするゴム製品の加硫方法。
After injecting the rubber material into the cavity in a predetermined metal mold, a method of vulcanizing a rubber product to be vulcanized by applying heat and pressure for a predetermined vulcanization time,
Inject the rubber material into the mold set inside the injection device every time,
A plurality of molds after this injection are stacked in series in the order of injection into a pressurizing / heating device provided inside the injection device or outside the injection device,
In the pressurizing and heating device, pressure is applied to the injected rubber material using the weight of the mold and external pressure, and the stacked molds are heated and kept warm to apply the rubber in the mold. Promotes and advances sulfuric acid,
In the direction of stacking in series, pressurizing force is applied by a pressurizing cylinder, and a pair of holders are attached to the grooves provided on both sides of the mold to assist the pressing force on multiple molds.
Each time the rubber material is injected in the next mold, a mold having a long vulcanization elapsed time among the stacked molds is removed from the plurality of mold parts stacked in series. Vulcanization method for rubber products.
前記加圧・加熱装置は、一方に断熱板を介してヒータを固定し、他方に断熱板に設けたヒータを加圧用シリンダで移動可能に設け、両ヒータ間に複数の金型を積み重ねるように構成されていることを特徴とする請求項1に記載のゴム製品の加硫方法。In the pressurizing / heating device, a heater is fixed on one side via a heat insulating plate, and a heater provided on the heat insulating plate is movably provided by a pressing cylinder on the other side, and a plurality of molds are stacked between the two heaters. The method for vulcanizing a rubber product according to claim 1, wherein the method is configured. 前記加圧・加熱装置を射出装置の外部に設け、射出動作と加硫動作とを一部同時進行で行うようにしたことを特徴とする請求項1又は2に記載のゴム製品の加硫方法。The vulcanizing method for a rubber product according to claim 1 or 2, wherein the pressurizing / heating device is provided outside the injection device, and the injection operation and the vulcanization operation are partially performed simultaneously. .
JP29577796A 1996-10-17 1996-10-17 Vulcanization method for rubber products Expired - Fee Related JP3583566B2 (en)

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2012111122A (en) * 2010-11-24 2012-06-14 Bridgestone Corp Vulcanizing apparatus

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2012111122A (en) * 2010-11-24 2012-06-14 Bridgestone Corp Vulcanizing apparatus

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