JP3645236B2 - Fiber reinforced cement board and manufacturing method thereof - Google Patents
Fiber reinforced cement board and manufacturing method thereof Download PDFInfo
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- JP3645236B2 JP3645236B2 JP2002237989A JP2002237989A JP3645236B2 JP 3645236 B2 JP3645236 B2 JP 3645236B2 JP 2002237989 A JP2002237989 A JP 2002237989A JP 2002237989 A JP2002237989 A JP 2002237989A JP 3645236 B2 JP3645236 B2 JP 3645236B2
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- fiber
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- cement board
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02W—CLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
- Y02W30/00—Technologies for solid waste management
- Y02W30/50—Reuse, recycling or recovery technologies
- Y02W30/91—Use of waste materials as fillers for mortars or concrete
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- Press-Shaping Or Shaping Using Conveyers (AREA)
- Curing Cements, Concrete, And Artificial Stone (AREA)
- Producing Shaped Articles From Materials (AREA)
Description
【0001】
【発明の属する技術分野】
この出願の発明は、繊維補強セメント板とその製造方法に関するものである。さらに詳しくは、この出願の発明は、強度等の品質、成形性等に優れ、再生繊維を利用することができる繊維補強セメント板とその製造方法に関するものである。
【0002】
【従来の技術】
従来より、建物の外壁材、屋根材等の外装材として、セメント板をはじめとする各種の無機質板が用いられており、表面に深い凹凸模様を備えつつ、表面の耐久性、耐侯性、対磨耗性および耐凍害性等に優れた無機質板として、2層以上の構造を有し、表層に補強繊維が配設された繊維補強セメント板が知られている。
【0003】
この繊維補強セメント板は、一般的には、セメントを主成分とするセメントスラリーを抄造して得た抄造シート上に、セメントを主成分とし補強繊維を含む半乾式材料を散布して、たとえば任意の凹凸模様に加圧成形したのち、養生硬化することで製造されている。そして、補強繊維としては、強度等の品質、成形性等の観点から、通常は、新品の短繊維パルプ(L材パルプ)を用いるようにしている。
【0004】
一方で、このL材パルプ等の解繊パルプは、原料の中で最も高価な材料であり、また、リサイクルの観点から、近年では、工場で発生する繊維補強セメント板の端材および不良品を粉砕して得られる再生L材パルプを、他の無機質板における補強繊維として再利用することがなされている。
【0005】
【発明が解決しようとする課題】
しかしながら、この再生L材パルプは、上記のような表面に凹凸模様を有する繊維補強セメント板の表層の補強繊維として再利用した場合、加圧成形時に凹部に圧力をとられて凸部には圧力がかかりにくく、全体に均一に加圧することができない傾向が見られ、意匠性に劣るという問題があった。そのため、表層ではなく、基材等に限定して再利用されているのが現状である。
【0006】
最近では、工場だけでなく現場で発生する端材および不良品の再利用が望まれており、再生L材パルプを含めてより多量の再生材を消費することのできるリサイクルシステムの開発が急務となっている。
【0007】
そこで、この出願の発明は、以上の通りの事情に鑑みてなされたものであり、従来技術の問題点を解消し、表層に再生繊維を利用することができるとともに、強度等の品質、成形性等に優れた繊維補強セメント板とその製造方法を提供することを課題としている。
【0008】
【課題を解決するための手段】
そこで、この出願の発明は、以上の通りの事情に鑑みてなされたものであり、従来技術の問題点を解消し、以下の通りの発明を提供する。
【0009】
すなわち、まず第1には、この出願の発明は、2層以上の構造を有し、表層に補強繊維が配設された繊維補強セメント板であって、この補強繊維が、繊維補強セメント板を粉砕して得られる繊維で、繊維長0.4〜1.2mmのものが繊維全体の70重量%以上である再生繊維であることを特徴とする繊維補強セメント板を提供する。
【0010】
そしてこの出願の発明は、上記の発明について、第2には、補強繊維が、長繊維パルプ(N材パルプ)を含む繊維補強セメント板を粉砕して得られる繊維であって、繊維長0.4〜1.2mmのものが繊維全体の70重量%以上となる再生N材パルプであることを特徴とする繊維補強セメント板を、第3には、表層に、任意の凹凸模様が設けられていることを特徴とする繊維補強セメント板を提供する。
【0011】
また、この出願の発明は、第4には、セメントを主成分とするセメントスラリーを抄造して得た抄造シート上に、セメントを主成分とし補強繊維を含む半乾式材料を散布して、加圧成形および養生硬化する工程を含む製造方法であって、補強繊維として、繊維補強セメント板を粉砕して得られる繊維であって、繊維長0.4〜1.2mmのものが繊維全体の70重量%以上である再生繊維を用いることを特徴とする繊維補強セメント板の製造方法を提供し、第5には、その補強繊維として、長繊維パルプ(N材パルプ)を含む繊維補強セメント板を粉砕して得られる繊維であって、繊維長0.4〜1.2mmのものが繊維全体の70重量%以上である再生N材パルプを用いることを特徴とする繊維補強セメント板の製造方法を提供する。
【0012】
【発明の実施の形態】
この出願の発明は、上記の通りの特徴を持つものであるが、以下にその実施の形態について詳しく説明する。
【0013】
この出願の発明が提供する繊維補強セメント板は、2層以上の構造を有し、表層に補強繊維が配設された繊維補強セメント板であって、この補強繊維が、繊維補強セメント板を粉砕して得られる繊維で、繊維長0.4〜1.2mmのものが繊維全体の70重量%以上である再生繊維であることを特徴としている。
【0014】
従来は、このような多層構造を有する繊維補強セメント板においては、基材の補強繊維として再生繊維を用いることができたが、この出願の発明においては、表層に再生繊維を用いるようにしている。そして、表層の成形性、強度等の品質を十分なものとするために、再生繊維の繊維長およびその配合量に着目し、繊維全体の70重量%以上が繊維長0.4〜1.2mmのものとなるように規定している。この再生繊維において、繊維長0.4mm未満のものが多すぎると繊維が短かすぎ、加圧成形時に繊維補強セメント板全体に均一に圧力が加わりにくくなるために好ましくない。また、繊維長1.2mmを超えるものが多すぎると繊維が長すぎ、繊維補強セメント板の製造において表層を構成する半乾式材料への分散性が悪くダマになりやすく、シャープな表面意匠が得られないのに加え、強度も劣ってしまうために好ましくない。そのため、上記のとおり、繊維長0.4〜1.2mmのものが繊維全体の70重量%以上となるようにしている。
【0015】
このような繊維全体の70重量%以上が繊維長0.4〜1.2mmとなるような再生繊維として、繊維補強セメント板に配合されている各種の天然繊維、合成繊維等を用いることができるが、この出願の発明においては、長繊維パルプ(N材パルプ)を含む繊維補強セメント板を粉砕して得られる再生N材パルプを用いることを好ましい例として示すことができる。一般に、再生繊維としては再生短繊維パルプ(再生L材パルプ)がより多く使用されているが、得られるままの再生L材パルプは繊維長0.4〜1.2mmのものが全体の70重量%未満で上記の規定を満たすことができず、さらに分級等の操作が必要となってしまう。一方、再生N材パルプについては、もともとN材パルプの繊維長が長いため、粉砕して得られる再生N材パルプがそのままで上記の規定を満たすために簡便に利用できる。また、N材パルプは繊維径も太いため、より高い補強効果および強度向上効果を得ることができる。
【0016】
このようなこの出願の発明の繊維補強セメント板は、表層に再生繊維を用いることができリサイクル性に優れており、さらに表層には深い凹凸模様をシャープに実現することも可能とされる。
【0017】
このようなこの出願の発明が提供する繊維補強セメント板は、たとえば以下のこの出願の発明の繊維補強セメント板の製造方法により製造することができる。すなわち、この出願の発明の製造方法は、セメントを主成分とするセメントスラリーを抄造して得た抄造シート上に、セメントを主成分とし補強繊維を含む半乾式材料を散布して、加圧成形および養生硬化する工程を含む製造方法であって、補強繊維として、繊維補強セメント板を粉砕して得られる繊維であって、繊維長0.4〜1.2mmのものが繊維全体の70重量%以上である再生繊維を用いることを特徴としている。
【0018】
この出願の発明において、セメントスラリーの配合については特に制限はなく、目的に応じて所望のものとすることができる。具体的には、たとえば、セメントに、パルプ、シラスバルーン、パーライト等の軽量骨材、ビニロン、ポリプロピレン等の繊維、必要に応じて遅延剤等の添加剤を配合したもの等が例示される。このセメントスラリーは、たとえば、含水率50〜150%程度の抄造シートが得られるように抄造する。
【0019】
そして、この抄造シート上に半乾式材料を散布する。この半乾式材料についても、上記のとおりの補強繊維を用いること意外は特に制限はなく、所望の配合とすることができ、たとえば、セメントスラリーと同様の配合となるように調整してもよいし、異なる配合としてもよい。また、半乾式材料の散布量も、任意に設定することができる。この半乾式材料の含水率は、抄造シートの含水率に応じて、0〜50%程度の範囲で調整することができる。
【0020】
この出願の発明においては、半乾式材料に用いる再生繊維として、繊維長0.4〜1.2mmのものが繊維全体の70重量%以上となるように調整すること以外は、その材質等に特に制限はなく、たとえば、補強繊維を含む各種の無機質板の端材や不良品を粉砕し、分級して得られる繊維分から、繊維長0.4〜1.2mmのものが繊維全体の70重量%以上となるように調整したものを用いることができる。粉砕には、たとえば、ペルベライザー式粉砕方式、ローラーミル式粉砕方式、ピンミル式粉砕方式の粉砕装置等を利用することが、粉砕物の分級には、たとえば、ロータリーシフター方式、振動方式のふるい装置等を利用することが簡便な例として示される。分級の際には、おおよその目安として、100メッシュのふるいを用いることで、粉砕物を繊維分と固形分とに適切に分けることができる。
【0021】
このような再生繊維について、この出願の発明では、N材パルプ含む繊維補強セメント板を粉砕して得られる再生N材パルプを用いることを好ましいものとしている。再生N材パルプは、繊維長0.4〜1.2mmのものが繊維全体の70重量%以上のものとして得られるため、繊維長の調整が不要となるために簡便である。また、再生N材パルプは、繊維径が比較的太く、高い補強効果が得られる点でも好ましい。
【0022】
このような半乾式材料を抄造シート上に散布したのち、所定の大きさに切断する等し、たとえば、任意の凹凸模様を備えた金型等を用いて加圧成形し、養生硬化することで、繊維補強セメント板を得ることができる。
【0023】
このようなこの出願の発明によると、表層にも再生繊維を用いることができるためにリサイクル性が向上されるだけでなく、たとえば2〜3mmあるいはそれ以上の深い凹凸模様を施す場合であっても、その模様をシャープに付与することができる。
【0024】
以下に実施例を示し、この出願の発明の実施の形態についてさらに詳しく説明する。
【0025】
【実施例】
L材パルプあるいはN材パルプを含む繊維補強セメント板をそれぞれピンミル式粉砕機で粉砕し、100メッシュのふるいにかけ、ふるい上に得られた繊維分を再生L材パルプ、再生N材パルプとした。ふるい上に得られたこれらの再生繊維は、分級比5〜30重量%で、含有繊維分は40〜70%であった。
【0026】
この再生繊維と新品のL材パルプおよびN材パルプについて、繊維長等を調べて表1に示した。
【0027】
【表1】
【0028】
これらの繊維を表層に用いて2層構造の繊維補強セメント板を製造した。まず、セメント100重量部に対し、フライアッシュ100重量部、珪石粉25重量部およびL材パルプ(新品)25重量部の配合のセメントスラリーを抄造して抄造シートを作成し、この抄造シート上に、表2に示した配合の半乾式材料を散布した後、凹凸模様を有する金型にて加圧成形し、前養生およびオートクレーブ養生を施した。なお、表2の比較例1の配合は、従来の繊維補強セメント板における半乾式材料の配合である。
【0029】
得られた繊維補強セメント板は、何れも抄造シート部(基材)の厚さが12mm、半乾式材料部(表層)の厚さが3mmであった。これらの繊維補強セメント板の品質を評価し、併せて表2に示した。
【0030】
【表2】
【0031】
なお、評価欄の比重、曲げ強度、引張り強度は、比較例1の従来品の値を100とした相対値で示している。
【0032】
実施例1は、再生L材パルプおよび再生N材パルプを組み合わせて、実施例2は、再生N材パルプのみを用いて、繊維長0.4〜1.2mmのものが繊維全体の70重量%以上となるようにしたものであり、いずれも比較例1の従来品と比較して、比重、曲げ強度、引張り強度が向上され、外観がシャープで優れたものとなることが分かった。
【0033】
一方の比較例2は、新品のN材パルプを用いたものであり、繊維長0.4〜1.2mmのものが繊維全体の50重量%しかなく、全体的により長い繊維が多かったため、半乾式材料の混練時にダマになりやすくて分散性が悪く、比較例1の従来品と比較して、基材の比重が上がらず強度が低下してしまった。また、繊維が長いため、凹凸模様にキレが生じてしまい、意匠性に劣るものとなってしまった。
【0034】
比較例3は、再生L材パルプのみを用いたものであり、繊維長0.4〜1.2mmのものが繊維全体の65重量%しかなく、全体的により短い繊維が多かった。そのため、加圧成形において圧力ムラが見られ、比較例1の従来品と比較して、やや強度が低下するとともに、はっきりとした凹凸模様が得られなかった。
【0035】
以上のことから、この出願の発明のとおり補強繊維の繊維長を調整することで、繊維補強セメント板の表層に再生繊維を用いることができ、成形性および外観が向上されることが確認された。特に、再生N材パルプを用いた場合は、繊維長が適切な範囲となるのに加え、繊維径が太くなるため、強度向上の効果も得られることが確認された。
【0036】
もちろん、この出願の発明は以上の例に限定されるものではなく、細部については様々な態様が可能であることは言うまでもない。
【0037】
【発明の効果】
以上詳しく説明した通り、この出願の発明によって、表層に再生繊維を利用することができるとともに、強度等の品質、成形性等に優れた繊維補強セメント板とその製造方法が提供される。[0001]
BACKGROUND OF THE INVENTION
The invention of this application relates to a fiber-reinforced cement board and a manufacturing method thereof. More specifically, the invention of this application relates to a fiber-reinforced cement board that is excellent in quality such as strength, formability, etc., and can use regenerated fibers, and a method for producing the same.
[0002]
[Prior art]
Conventionally, various types of inorganic boards such as cement boards have been used as exterior materials for building exterior walls and roofing materials. A fiber-reinforced cement board having a structure of two or more layers and having reinforcing fibers arranged on the surface layer is known as an inorganic board having excellent wear resistance and frost damage resistance.
[0003]
This fiber reinforced cement board is generally prepared by spraying a semi-dry material containing cement fiber as a main component and a reinforcing fiber on a paper sheet obtained by making a cement slurry mainly containing cement. It is manufactured by curing and curing after pressing into an uneven pattern. As the reinforcing fibers, new short fiber pulp (L material pulp) is usually used from the viewpoints of quality such as strength and moldability.
[0004]
On the other hand, the defibrated pulp such as L-material pulp is the most expensive material among the raw materials, and from the viewpoint of recycling, in recent years, end materials and defective products of fiber reinforced cement boards generated in factories are used. Recycled L material pulp obtained by pulverization is reused as reinforcing fibers in other inorganic boards.
[0005]
[Problems to be solved by the invention]
However, when this recycled L-material pulp is reused as the reinforcing fiber for the surface layer of the fiber-reinforced cement plate having the uneven surface on the surface as described above, pressure is applied to the concave portion during pressure molding, and pressure is applied to the convex portion. There was a problem that it was difficult to apply, and there was a tendency that pressure could not be uniformly applied to the whole, resulting in poor design. Therefore, the current situation is that the material is reused only for the base material and the like, not the surface layer.
[0006]
Recently, it is desired to reuse scraps and defective products generated not only in factories but also in the field, and there is an urgent need to develop a recycling system that can consume a larger amount of recycled materials including recycled L-wood pulp. It has become.
[0007]
Therefore, the invention of this application has been made in view of the circumstances as described above, solves the problems of the prior art, can use regenerated fiber for the surface layer, quality such as strength, moldability It is an object of the present invention to provide a fiber-reinforced cement board and a method for producing the same.
[0008]
[Means for Solving the Problems]
Accordingly, the invention of this application has been made in view of the circumstances as described above, solves the problems of the prior art, and provides the following invention.
[0009]
That is, first of all, the invention of this application is a fiber-reinforced cement board having a structure of two or more layers and having reinforcing fibers arranged on the surface layer, and the reinforcing fibers are made of fiber-reinforced cement boards. Provided is a fiber-reinforced cement board characterized in that the fiber obtained by pulverization is a regenerated fiber whose fiber length is 0.4 to 1.2 mm is 70% by weight or more of the whole fiber.
[0010]
The invention of this application relates to the above invention, and secondly, the reinforcing fiber is a fiber obtained by pulverizing a fiber-reinforced cement board containing long fiber pulp (N-material pulp), and the fiber length is 0. A fiber-reinforced cement board characterized by 4 to 1.2 mm of recycled N-wood pulp that is 70% by weight or more of the entire fiber. Third, an arbitrary uneven pattern is provided on the surface layer. A fiber-reinforced cement board is provided.
[0011]
The invention of this application is, fourthly, a semi-dry type material containing cement as a main component and containing reinforcing fibers is sprayed on a paper sheet obtained by making a cement slurry containing cement as a main component. It is a manufacturing method including the steps of pressure forming and curing and curing, and is a fiber obtained by pulverizing a fiber-reinforced cement board as a reinforcing fiber, and a fiber length of 0.4 to 1.2 mm is 70% of the whole fiber. A method for producing a fiber reinforced cement board characterized by using regenerated fibers having a weight% or more is provided. Fifth, a fiber reinforced cement board containing long fiber pulp (N-material pulp) as the reinforcing fiber is provided. A method for producing a fiber-reinforced cement board, characterized by using recycled N-material pulp, which is a fiber obtained by pulverization and having a fiber length of 0.4 to 1.2 mm is 70% by weight or more of the whole fiber. provide.
[0012]
DETAILED DESCRIPTION OF THE INVENTION
The invention of this application has the features as described above, and the embodiment thereof will be described in detail below.
[0013]
The fiber reinforced cement board provided by the invention of this application is a fiber reinforced cement board having a structure of two or more layers and having reinforcing fibers arranged on the surface layer, and the reinforcing fibers pulverize the fiber reinforced cement board. Of the fibers obtained in this manner, those having a fiber length of 0.4 to 1.2 mm are regenerated fibers that are 70% by weight or more of the total fibers.
[0014]
Conventionally, in the fiber reinforced cement board having such a multilayer structure, the regenerated fiber can be used as the reinforcing fiber of the base material. However, in the invention of this application, the regenerated fiber is used for the surface layer. . And in order to make the quality such as moldability and strength of the surface layer sufficient, paying attention to the fiber length of the regenerated fiber and its blending amount, 70% by weight or more of the whole fiber is a fiber length of 0.4 to 1.2 mm. It is stipulated to be a thing. In this regenerated fiber, if the fiber length is less than 0.4 mm, the fiber is too short, and it is not preferable because it is difficult to apply pressure uniformly to the entire fiber reinforced cement board during pressure molding. Also, if the fiber length exceeds 1.2 mm, the fiber is too long, the dispersibility to the semi-dry material constituting the surface layer is poor in the production of the fiber reinforced cement board, and it is easy to get rid of it, and a sharp surface design is obtained. In addition to this, the strength is also inferior. Therefore, as described above, the fiber length of 0.4 to 1.2 mm is 70% by weight or more of the entire fiber.
[0015]
Various natural fibers and synthetic fibers blended in the fiber-reinforced cement board can be used as the regenerated fiber in which 70% by weight or more of the whole fiber has a fiber length of 0.4 to 1.2 mm. However, in the invention of this application, it can be shown as a preferable example that recycled N-material pulp obtained by pulverizing a fiber-reinforced cement board containing long fiber pulp (N-material pulp) is used. Generally, more recycled short fiber pulp (recycled L pulp) is used as the recycled fiber, but the recycled L pulp with a fiber length of 0.4 to 1.2 mm is 70 wt. If it is less than%, the above-mentioned regulations cannot be satisfied, and further operations such as classification are required. On the other hand, since the fiber length of the N-material pulp is originally long, the recycled N-material pulp can be easily used because the recycled N-material pulp obtained by pulverization satisfies the above regulations as it is. In addition, since the N-material pulp has a large fiber diameter, a higher reinforcing effect and a strength improving effect can be obtained.
[0016]
Such a fiber-reinforced cement board of the invention of this application can use regenerated fibers for the surface layer and is excellent in recyclability, and it is also possible to realize a deep uneven pattern sharply on the surface layer.
[0017]
Such a fiber-reinforced cement board provided by the invention of this application can be produced, for example, by the following method for producing a fiber-reinforced cement board of the invention of this application. That is, the manufacturing method of the invention of this application is such that a semi-dry type material containing cement as a main component and containing reinforcing fibers is sprayed on a paper sheet obtained by making a cement slurry containing cement as a main component, and pressure forming. And a curing method comprising a step of curing and curing, which is a fiber obtained by pulverizing a fiber-reinforced cement board as a reinforcing fiber, and a fiber length of 0.4 to 1.2 mm is 70% by weight of the whole fiber It is characterized by using the above regenerated fiber.
[0018]
In the invention of this application, the mixing of the cement slurry is not particularly limited, and can be set as desired according to the purpose. Specifically, for example, cement and light weight aggregates such as pulp, shirasu balloon, and pearlite, fibers such as vinylon and polypropylene, and additives such as retarders as necessary are exemplified. This cement slurry is made, for example, so as to obtain a paper sheet having a water content of about 50 to 150%.
[0019]
And a semi-dry type material is spread | dispersed on this papermaking sheet | seat. The semi-dry material is not particularly limited except that the reinforcing fiber as described above is used, and can be made into a desired composition, for example, it may be adjusted to have the same composition as the cement slurry. Different blends may be used. Moreover, the application amount of the semi-dry material can be arbitrarily set. The water content of the semi-dry material can be adjusted in the range of about 0 to 50% depending on the water content of the paper sheet.
[0020]
In the invention of this application, the recycled fiber used for the semi-dry type material is not particularly limited to its material, except that the fiber having a fiber length of 0.4 to 1.2 mm is adjusted to 70% by weight or more of the entire fiber. There is no limit, for example, from the fiber content obtained by pulverizing and classifying the end materials and defective products of various inorganic plates including reinforcing fibers, the fiber length of 0.4 to 1.2 mm is 70% by weight of the total fiber What was adjusted so that it may become the above can be used. For pulverization, for example, a pelletizer type pulverization method, a roller mill type pulverization method, a pin mill type pulverization type pulverization device or the like can be used. It is shown as a simple example to use. At the time of classification, as a rough guide, a pulverized product can be appropriately divided into a fiber content and a solid content by using a 100 mesh sieve.
[0021]
With regard to such regenerated fibers, in the invention of this application, it is preferable to use regenerated N material pulp obtained by pulverizing a fiber reinforced cement board containing N material pulp. Since recycled N-wood pulp having a fiber length of 0.4 to 1.2 mm is obtained as 70% by weight or more of the whole fiber, adjustment of the fiber length is not necessary, which is convenient. Further, recycled N-wood pulp is preferable in that the fiber diameter is relatively large and a high reinforcing effect can be obtained.
[0022]
After such a semi-dry material is spread on a papermaking sheet, it is cut into a predetermined size, for example, pressure-molded using a mold having an arbitrary uneven pattern, and cured and cured. A fiber-reinforced cement board can be obtained.
[0023]
According to the invention of this application, recycled fibers can be used for the surface layer, so that not only the recyclability is improved, but even when a deep concavo-convex pattern of 2 to 3 mm or more is applied, for example. The pattern can be sharply applied.
[0024]
Examples will be shown below, and the embodiment of the invention of this application will be described in more detail.
[0025]
【Example】
The fiber reinforced cement board containing L material pulp or N material pulp was each grind | pulverized with the pin mill type grinder, and it sifted through a 100 mesh sieve, and the fiber content obtained on the sieve was made into the reproduction | regeneration L material pulp and the reproduction | regeneration N material pulp. These recycled fibers obtained on the sieve had a classification ratio of 5 to 30% by weight and a contained fiber content of 40 to 70%.
[0026]
The regenerated fibers and the new L and N pulps were examined for fiber lengths and shown in Table 1.
[0027]
[Table 1]
[0028]
Using these fibers as the surface layer, a fiber-reinforced cement board having a two-layer structure was produced. First, a paper sheet is prepared by making a cement slurry containing 100 parts by weight of fly ash, 100 parts by weight of fly ash, 25 parts by weight of silica stone powder, and 25 parts by weight of L pulp (new article). After spraying the semi-dry material of the composition shown in Table 2, it was pressure-molded with a mold having a concavo-convex pattern and subjected to pre-curing and autoclave curing. In addition, the mixing | blending of the comparative example 1 of Table 2 is mixing | blending of the semi-dry type material in the conventional fiber reinforced cement board.
[0029]
In each of the obtained fiber reinforced cement boards, the thickness of the papermaking sheet part (base material) was 12 mm, and the thickness of the semi-dry material part (surface layer) was 3 mm. The quality of these fiber reinforced cement boards was evaluated and is shown in Table 2 together.
[0030]
[Table 2]
[0031]
The specific gravity, bending strength, and tensile strength in the evaluation column are shown as relative values with the value of the conventional product of Comparative Example 1 as 100.
[0032]
Example 1 is a combination of recycled L material pulp and recycled N material pulp, and Example 2 uses only recycled N material pulp, and a fiber length of 0.4 to 1.2 mm is 70% by weight of the total fiber. As described above, it was found that the specific gravity, bending strength, and tensile strength were improved and the appearance was sharp and excellent as compared with the conventional product of Comparative Example 1.
[0033]
On the other hand, Comparative Example 2 uses a new N-wood pulp, and the fiber length of 0.4 to 1.2 mm is only 50% by weight of the whole fiber, and the whole has a lot of longer fibers. Compared with the conventional product of Comparative Example 1, the strength of the base material was not increased and the strength was reduced. Moreover, since the fiber is long, the uneven pattern is crisp and the design is inferior.
[0034]
In Comparative Example 3, only the recycled L material pulp was used, and the fiber length of 0.4 to 1.2 mm was only 65% by weight of the total fiber, and there were more overall shorter fibers. For this reason, pressure unevenness was observed in the pressure molding, and the strength was slightly reduced as compared with the conventional product of Comparative Example 1, and a clear uneven pattern was not obtained.
[0035]
From the above, it was confirmed that by adjusting the fiber length of the reinforcing fiber as in the invention of this application, the regenerated fiber can be used for the surface layer of the fiber-reinforced cement plate, and the moldability and appearance are improved. . In particular, when recycled N-wood pulp was used, it was confirmed that, in addition to the fiber length being in an appropriate range, the fiber diameter was increased, so that the effect of improving the strength was also obtained.
[0036]
Of course, the invention of this application is not limited to the above examples, and it goes without saying that various aspects are possible in detail.
[0037]
【The invention's effect】
As described above in detail, the invention of this application provides a fiber-reinforced cement board that can use regenerated fibers for the surface layer and is excellent in quality such as strength and formability, and a method for producing the same.
Claims (5)
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