JP3850645B2

JP3850645B2 - Method for producing detergent and negative ion generator used in the method

Info

Publication number: JP3850645B2
Application number: JP2000262496A
Authority: JP
Inventors: 国男福田; 耕治中村; 鉄男佐藤
Original assignee: Individual
Current assignee: Individual
Priority date: 2000-08-31
Filing date: 2000-08-31
Publication date: 2006-11-29
Anticipated expiration: 2020-08-31
Also published as: JP2002069497A

Description

【０００１】
【発明の属する技術分野】
本発明は、各種家庭用や業務用として使用することができる洗浄剤の製造方法および該方法に使用するマイナスイオン発生装置に関するものである。
【０００２】
【従来の技術】
従来、洗浄剤の組成物として第三リン酸ナトリウム、メタケイ酸ナトリウム、硫酸ナトリウム、ホウ酸ナトリウム、ピロリン酸ナトリウムを主成分とする洗浄剤が、特許第２８７６０５４号公報に開示されている。すなわち、前記特許公報には、洗浄剤原液の製造方法として、４０〜８０℃の温度にした水約１０００重量％に、洗浄剤組成物として、第三リン酸ナトリウム１５〜４０重量％、メタケイ酸ナトリウム１５〜３５重量％、硫酸ナトリウム７〜１５重量％を加えて撹拌し、十分に溶解させた後、ホウ酸ナトリウム０.５〜１８重量％、ピロリン酸ナトリウム１２〜５０重量％を順次加えて撹拌し、溶解して洗浄剤原液を製造するようにすることが効果的である旨記載されている。
【０００３】
【発明が解決しようとする課題】
しかしながら、前記特許公報に記載された洗浄剤を用いて、特に業務用厨房における排気口にある油が付着した網状のアルミ製フィルターを実際に洗浄したが、網目の部分の油汚れが落ちず、十分な洗浄効果を得ることができないという課題があった。
【０００４】
本発明は、前記課題を解決すべくなしたもので、洗浄剤組成物を溶解する水にマイナスイオンを付与させて、該水を界面活性物質とすることにより洗浄効果が優れた洗浄剤の製造方法および該方法に使用するマイナスイオン発生装置を提供しようとするものである。
【０００５】
【課題を解決するための手段】
本発明は、第１の基材であるこんにゃくいもの精粉（こんにゃく粉）を、該精粉の重量に対して約５〜３０倍の重量の水に投入して混合撹拌して前記精粉を充分に水に溶かし、粘着性が出るまで撹拌作用を続けて粘着性を有するこんにゃく溶液を得る第１工程と、前記第１工程で得られた粘着性を有するこんにゃく溶液に、前記こんにゃく溶液の重量に対して、第２の基材であるトルマリン微粉末１０〜５０重量％および第３の基材である炭微粉末１０〜５０重量％をそれぞれ混入すると共に、添加材として遠赤外線放射特性を有するセラミックス微粉末３〜１０重量％を添加混入して混合撹拌し、前記各基材および添加材がこんにゃく溶液中に均等に分散するまで撹拌して混合溶液を得る第２工程と、前記第２工程で得られた混合溶液の重量に対して２〜５重量％の炭酸ナトリウム、もしくは木灰を固化材として前記混合溶液と共に熱湯に溶かし、該混合溶液が柔軟性を有する程度（つきたてのもちの状態）まで半固化するよう撹拌して半固化物を得る第３工程と、前記第３工程で得られた半固化物を最終使用形態の所定の形状に合わせて成型し、所定形状の成型体を得る第４工程と、前記第４工程で得られた成型体を熱湯に投入して煮沸し、前記成型体をこんにゃく程度の硬さまで固化せしめた後、該煮沸した成型体を熱湯から取り出して−４０〜−１５０℃で急冷凍し、前記急冷凍した成型体を３０〜５０℃で真空乾燥させて、前記成型体より水分を除去して固形物を得る第５工程を経て製造されたマイナスイオン生成体を用い、洗浄剤組成物を溶解する水にマイナスイオンを付与すると共に、更に前記水に超微細気泡を多数発生せしめ、然る後、前記水を８０℃程度の温水とし、該温水中に、洗浄剤組成物として炭酸ナトリウム、ピロリン酸ナトリウム、第三リン酸ナトリウム、四ホウ酸ナトリウム、硫酸ナトリウム、メタケイ酸ナトリウム、酵素およびゼオライトの各粉末を添加混入して撹拌するという手段、または、
第１の基材であるこんにゃくいもの生玉をすりつぶし、該すりつぶした生玉を水の中に投入して沈殿させ、然る後上澄みを捨てて粘着性を有するこんにゃく溶液を得る第１工程と、前記第１工程で得られた粘着性を有するこんにゃく溶液に、前記こんにゃく溶液の重量に対して、第２の基材であるトルマリン微粉末１０〜５０重量％および第３の基材である炭微粉末１０〜５０重量％をそれぞれ混入すると共に、添加材として遠赤外線放射特性を有するセラミックス微粉末３〜１０重量％を添加混入して混合撹拌し、前記各基材および添加材がこんにゃく溶液中に均等に分散するまで撹拌して混合溶液を得る第２工程と、前記第２工程で得られた混合溶液の重量に対して２〜５重量％の炭酸ナトリウム、もしくは木灰を固化材として前記混合溶液と共に熱湯に溶かし、該混合溶液が柔軟性を有する程度（つきたてのもちの状態）まで半固化するよう撹拌して半固化物を得る第３工程と、前記第３工程で得られた半固化物を最終使用形態の所定の形状に合わせて成型し、所定形状の成型体を得る第４工程と、前記第４工程で得られた成型体を熱湯に投入して煮沸し、前記成型体をこんにゃく程度の硬さまで固化せしめた後、該煮沸した成型体を熱湯から取り出して−４０〜−１５０℃で急冷凍し、前記急冷凍した成型体を３０〜５０℃で真空乾燥させて、前記成型体より水分を除去して固形物を得る第５工程を経て製造されたマイナスイオン生成体を用い、洗浄剤組成物を溶解する水にマイナスイオンを付与すると共に、更に前記水に超微細気泡を多数発生せしめ、然る後、前記水を８０℃程度の温水とし、該温水中に、洗浄剤組成物として炭酸ナトリウム、ピロリン酸ナトリウム、第三リン酸ナトリウム、四ホウ酸ナトリウム、硫酸ナトリウム、メタケイ酸ナトリウム、酵素およびゼオライトの各粉末を添加混入して撹拌するという手段、あるいは、
第１の基材であるこんにゃくいもの精粉（こんにゃく粉）を、該精粉の重量に対して約５〜３０倍の重量の水に投入して混合撹拌して前記精粉を充分に水に溶かし、粘着性が出るまで撹拌作用を続けて粘着性を有するこんにゃく溶液を得る第１工程と、前記第１工程で得られた粘着性を有するこんにゃく溶液に、前記こんにゃく溶液の重量に対して、第２の基材であるトルマリン微粉末１０〜５０重量％および第３の基材である炭微粉末１０〜５０重量％をそれぞれ混入すると共に、添加材として遠赤外線放射特性を有するセラミックス微粉末３〜１０重量％を添加混入して混合撹拌し、前記各基材および添加材がこんにゃく溶液中に均等に分散するまで撹拌して混合溶液を得る第２工程と、前記第２工程で得られた混合溶液の重量に対して２〜５重量％の炭酸ナトリウム、もしくは木灰を固化材として前記混合溶液と共に熱湯に溶かし、該混合溶液が柔軟性を有する程度（つきたてのもちの状態）まで半固化するよう撹拌して半固化物を得る第３工程と、前記第３工程で得られた半固化物を熱湯に投入して煮沸し、前記半固化物をこんにゃく程度の硬さまで固化せしめて、熱湯から取り出して−４０〜−１５０℃で急冷凍した後、３０〜５０℃で真空乾燥させて水分を除去して固形物を得る第４工程と、前記第４工程で得られた固形物を最終使用形態の所定の形状に合わせて成型し、所定形状の成型体を得る第５工程を経て製造されたマイナスイオン生成体を用い、洗浄剤組成物を溶解する水にマイナスイオンを付与すると共に、更に前記水に超微細気泡を多数発生せしめ、然る後、前記水を８０℃程度の温水とし、該温水中に、洗浄剤組成物として炭酸ナトリウム、ピロリン酸ナトリウム、第三リン酸ナトリウム、四ホウ酸ナトリウム、硫酸ナトリウム、メタケイ酸ナトリウム、酵素およびゼオライトの各粉末を添加混入して撹拌するという手段、更に、
第１の基材であるこんにゃくいもの生玉をすりつぶし、該すりつぶした生玉を水の中に投入して沈殿させ、然る後上澄みを捨てて粘着性を有するこんにゃく溶液を得る第１工程と、前記第１工程で得られた粘着性を有するこんにゃく溶液に、前記こんにゃく溶液の重量に対して、第２の基材であるトルマリン微粉末１０〜５０重量％および第３の基材である炭微粉末１０〜５０重量％をそれぞれ混入すると共に、添加材として遠赤外線放射特性を有するセラミックス微粉末３〜１０重量％を添加混入して混合撹拌し、前記各基材および添加材がこんにゃく溶液中に均等に分散するまで撹拌して混合溶液を得る第２工程と、前記第２工程で得られた混合溶液の重量に対して２〜５重量％の炭酸ナトリウム、もしくは木灰を固化材として前記混合溶液と共に熱湯に溶かし、該混合溶液が柔軟性を有する程度（つきたてのもちの状態）まで半固化するよう撹拌して半固化物を得る第３工程と、前記第３工程で得られた半固化物を熱湯に投入して煮沸し、前記半固化物をこんにゃく程度の硬さまで固化せしめて、熱湯から取り出して−４０〜−１５０℃で急冷凍した後、３０〜５０℃で真空乾燥させて水分を除去して固形物を得る第４工程と、前記第４工程で得られた固形物を最終使用形態の所定の形状に合わせて成型し、所定形状の成型体を得る第５工程を経て製造されたマイナスイオン生成体を用い、洗浄剤組成物を溶解する水にマイナスイオンを付与すると共に、更に前記水に超微細気泡を多数発生せしめ、然る後、前記水を８０℃程度の温水とし、該温水中に、洗浄剤組成物として炭酸ナトリウム、ピロリン酸ナトリウム、第三リン酸ナトリウム、四ホウ酸ナトリウム、硫酸ナトリウム、メタケイ酸ナトリウム、酵素およびゼオライトの各粉末を添加混入して撹拌するという手段、
のいずれかを採用することにより、上記課題を解決した。
【０００６】
【発明の実施の形態】
本発明者は、前記従来の特許公報に記載された洗浄剤の洗浄効果が十分でないのは、洗浄剤組成物を溶解する水に問題があるのではないかと考え種々のテストの結果本発明を完成した。すなわち、本発明は洗浄剤組成物を溶解する水にマイナスイオンを付与すると共に、前記水を超微細気泡を有するようにすることにより、水を界面活性物質に変え、該水に洗浄剤組成物を溶解して洗浄効果が優れた洗浄剤を製造することができた。
【０００７】
本発明者は、特願２０００−２５５１１４号として、「発明の名称マイナスイオン生成体の製造方法」を特許出願した。本発明は前記特許出願の「マイナスイオン生成体の製造方法」によって得られたマイナスイオン生成体を用い、洗浄剤組成物を溶解する水にマイナスイオンを付与することにより、洗浄効果の優れた洗浄剤を製造することができた。
【０００８】
前記マイナスイオン生成体は、次のようにして製造する。すなわち、本発明に使用するマイナスイオン生成体は、こんにゃくいもの精粉、またはこんにゃくの生玉、トルマリン微粉末、炭微粉末を基材とし、更に遠赤外線放射特性を有するセラミックス微粉末を添加材として製造する。以下その製造方法につき詳細に説明する。
【０００９】
第１の基材であるこんにゃくいも、またはこんにゃくの生玉は植物繊維を多く含んでいることが知られており、この植物繊維が重要な役目を果たす。そして、こんにゃくいもの水分を除いた無水物についての一般成分の組成は、種類と産地によってもあまり変わらず、平均して灰分６．１％、窒素０．５７％、糖質９５．３％、リン酸０．５４％であり、前記糖質の主体は主成分であるコンニャクマンナンで、これを急冷真空乾燥させると繊維状のスポンジ状態となる。
【００１０】
また、第２の基材であるトルマリンは、電気石と称されている誘導体であり、絶えず静電気を帯び続けるという特性を有すると共に、両端に陽極と陰極の電極を作る極性結晶体である。そして、トルマリンは陽極が周辺の大気や液体に存在する電子を引きつけて結晶内に取入れ、該取入れられた電子はトルマリン内部の電流に取込まれるが、そのために余ったマイナスイオンが陰極から放出されて、このマイナスイオンを生成し続けるという機能を有することが知られている。
【００１１】
更に、第３の基材である炭は、竹炭や木炭より成り、炭素を主成分とするものであって、電気的誘導特性を有することが知られている。
【００１２】
また更に、添加材である遠赤外線放射特性を有するセラミックスは、特に限定する必要はないが、好ましくは遠赤外線を放射することが知られている千枚石、水晶、ハモナイト、角閃石、蛇紋石、石英閃緑石、花崗班石、凝灰石、酸化カルシウム、マグネシア、シリカ等のセラミックスを使用することが推奨される。そして、前記セラミックスの放射する遠赤外線の光感現象が前記トルマリンに作用し、これにより該トルマリンからマイナスイオンを多量に放出できるよう、前記セラミックスを触媒として使用する。
【００１３】
前記各基材および添加材を用いたマイナスイオン生成体の製造方法を更に詳細に説明する。先ず、第１工程として、第１の基材であるこんにゃくいもの精粉（こんにゃく粉）を、該精粉の重量に対して約５〜３０倍、好ましくは１５倍の重量の水に投入して混合撹拌して前記精粉を充分に水に溶かし、粘着性が出るまで撹拌作用を続け、そして充分粘着性が出たところで第１工程を終了して、粘着性を有するこんにゃく溶液を得る。
【００１４】
なお、前記第１工程において、こんにゃくいもの精粉に代えてこんにゃくの生玉を使用することができる。この場合、こんにゃくの生玉をすりつぶし、該すりつぶした生玉を水の中に投入して沈殿させ、然る後上澄みを捨てると前記と同様の粘着性を有するこんにゃく溶液を得ることができる。
【００１５】
次に、第２工程として、前記第１工程で得られた粘着性を有するこんにゃく溶液に、前記こんにゃく溶液の重量に対して、第２の基材であるトルマリン微粉末１０〜５０重量％、好ましくは３０重量％および第３の基材である竹炭または木炭の炭微粉末１０〜５０重量％、好ましくは３０重量％をそれぞれ混入すると共に、添加材として千枚石、水晶、ハモナイト、角閃石、蛇紋石、石英閃緑石、花崗班石、凝灰石、酸化カルシウム、マグネシア、シリカ等の遠赤外線放射特性を有するセラミックスの単体またはその複合物より成るセラミックス微粉末３〜１０重量％、好ましくは５重量％を添加混入して混合撹拌し、前記各基材および添加材がこんにゃく溶液中に均等に分散するまで撹拌して第２工程を終了して、基材および添加材の混合溶液を得る。前記基材および添加材の粒径は、特に限定する必要はないが、１００μｍ以下、好ましくは３０μｍ以下とすることが推奨される。
【００１６】
更に、第３工程として、前記第２工程で得られた基材および添加材の混合溶液の重量に対して２〜５重量％、好ましくは３重量％の炭酸ナトリウム、もしくは木灰を固化材として前記混合溶液と共に熱湯に溶かし、該混合溶液が柔軟性を有する程度（つきたてのもちの状態）まで半固化するよう撹拌し、第３工程を終了して半固化物を得る。
【００１７】
そして、第４工程として、前記第３工程で得られた半固化物を最終使用形態、例えば球状、多角形状、円盤状等の所定の形状に合わせて、例えば型抜き等により成型し、第４工程を終了して所定形状の成型体を得る。
【００１８】
最後の第５工程として、前記第４工程で得られた成型体を熱湯に投入して約１〜３時間程度煮沸して、前記成型体をこんにゃく程度の硬さまで固化せしめた後、該煮沸した成型体を熱湯から取り出して−４０〜−１５０℃、好ましくは−１００℃で急冷凍し、然る後前記急冷凍した成型体を３０〜５０℃、好ましくは約４０℃で真空乾燥させて、前記成型体より水分を除去することにより、マイナスイオン生成体の製造工程を完了しマイナスイオン生成体を得る。
【００１９】
前記製造方法によって得られたマイナスイオン生成体は、第５工程で急冷真空乾燥させて水分を除去することにより、こんにゃくいもの繊維質が収縮して強固に絡まり合うと共に、該各繊維質間にトルマリン微粉末、炭微粉末およびセラミックス微粉末が混合した形で取り込まれて一体化され、更に前記水分除去により前記こんにゃくいもの繊維質部分のみがスポンジ状態で残るため、前記トルマリン微粉末、炭微粉末およびセラミックス微粉末を一体に取り込んだマイナスイオン生成体は多孔質となり、従ってこれにより表面積が大となると共に、該トルマリン微粉末、炭微粉末およびセラミックス微粉末と大気との接触面積が大きくなる。
【００２０】
なお、前記第４工程の成型体の製造工程は、前記第５工程の完了後に行うこともできる。すなわち、第４工程として前記第３工程で得られた半固化物を熱湯に投入して、約１〜３時間程度煮沸して前記半固化物をこんにゃく程度の硬さまで固化せしめた後、熱湯から取り出して−４０〜−１５０℃で急冷凍し、然る後３０〜５０℃で真空乾燥させて水分を除去して固形物を得る。その後、最後の第５工程として、前記第４工程で得られた固形物を最終使用形態の所定の形状に合わせて、例えば切削加工等により成型し、マイナスイオン生成体の製造工程を完了しマイナスイオン生成体を得る。
【００２１】
前記製造方法によって得られたマイナスイオン生成体によるマイナスイオン発生メカニズムは、前記したようにトルマリンはどんなに小さく砕き、粉体にしても常にその結晶状態は一定の形を保ち、その両端に陽極と陰極の電極が発生し、陽極が周辺の大気や液体に存在する電子を引きつけて結晶内に取入れ、この電子を陰極へ搬送して、陰極からマイナスイオンを放出し続けるという電気的特性を有している。そして、トルマリン原石から放出されるマイナスイオンは２０００個/ｃｃといわれている。
【００２２】
前記電気的特性によりマイナスイオンを放出し続けるトルマリンに、炭素を主成分とする竹炭または木炭が保有する電気的誘導特性、および千枚石等のセラミックスが放射する遠赤外線による光感現象が作用して、その両作用の相乗作用により、トルマリンの結晶内に周辺の大気や液体に存在する電子を更に多く引きつけて取入れ、その分多くのマイナスイオンを放出すると共に、更にはトルマリンが微粉末であるため、前記のように大気や液体との接触面積が大であるため、大気からトルマリンが取入れる電子が多くなり、従って前記トルマリンからマイナスイオンを更に多く発生させることができるのである。
【００２３】
表１は、前記製造方法によって得られたマイナスイオン生成体によるマイナスイオンの発生個数を測定した結果を示す表であり、前記したトルマリン原石からは２０００個/ｃｃしかマイナスイオンは発生しないが、本発明製造方法によって得られたマイナスイオン生成体によれば、平均９．４５７個/ｃｃのマイナスイオンが放出されたことが確認できた。なお、測定条件は次の通りである。
測定機器「ＡＩＲＩＯＮＣＯＵＮＴＥＲ」
（アメリカ、ラデションテクノロジー社製）
測定環境室温２６℃ 湿度４８％プラスイオン数９０個/ｃｃ
試料形状固形
測定方法簡易デシケータ内環境にて１０回測定（微弱送風）
測定日時平成１２年５月１３日
測定者緑化環境産業協会
【００２４】
【表１】

【００２５】
前記測定結果から、前記製造方法によって得られたマイナスイオン生成体は、商用電源を用いることなく、多量のマイナスイオンを放出していることが証明できた。
【００２６】
前記製造方法によって得られたマイナスイオン生成体は、多数の微細孔を有する多孔質となっており、該多数のマイナスイオン生成体１が、マイナスイオン発生装置２に収納されている。そして、前記マイナスイオン発生装置２に収納されるマイナスイオン生成体１は、好ましくは小球体に形成されることが推奨される。
【００２７】
前記マイナスイオン発生装置２は、両端に小径部３・４を一体に固着した円筒体５の前記小径部３・４内方寄りに通気用小孔６を多数穿設した区画壁７・８をそれぞれ固設して、該各区画壁７・８間の空隙部をマイナスイオン生成体１の収納部９とすると共に、該収納部９の内周壁面には円周方向に間隔を有して、複数本の環状マグネット１０が固着されて形成されている。なお、図中１１は区画壁７・８を保持固定する取付けボルトである。
【００２８】
そして、前記マイナスイオン発生装置２の収納部９内に多数のマイナスイオン生成体１を収納すると共に、一方の小径部３を連結チューブ１２を介してブロア１３に連結し、且つ他方の小径部４に送風チューブ１４を連結して、該送風チューブ１４の先端開口部を水槽１５の水１６内へ装入する。
【００２９】
前記マイナスイオン発生装置２の送風チューブ１４の先端開口部を水槽１５の水１６内へ装入して、ブロア１３を起動し収納部９内に送風すると、空気が各マイナスイオン生成体１の表面に接触して乱流すると共に、多孔質のマイナスイオン生成体１内の孔部分に空気が入り込んで、該空気よりマイナスイオン生成体１を構成するトルマリン微粉末に多くの電子が取り込まれることにより、マイナスイオン生成体１から多くのマイナスイオンが放出されると共に、複数の環状マグネット１０によるローレンツ力の作用により、マイナスイオン生成体１からのマイナスイオンの生成の手助けをし、前記マイナスイオン生成体１から更に多くのマイナスイオン（１００，０００個/ｃｃ程度）を放出することができる。なお、マイナスイオン生成体１が小球体に形成されておれば、空気の乱流を更に円滑に起こすことができる。
【００３０】
そして、前記マイナスイオン生成体１から放出されたマイナスイオンは、マイナスイオン発生装置２の他方の小径部４が小径に絞られているため、該他方の小径部４において風速が早くなり、その強風に乗せられて送風チューブ１４を介して水槽１５の水１６内に噴射される。そして、前記噴射を継続することにより、マイナスイオンが水槽１５中の水１６内に付与されると共に、強風が水１６内に噴射されるため、前記水槽１５内の水１６は乱流混練されて超微細気泡が多数発生する。
【００３１】
本発明は、前記マイナスイオンを付与されると共に、超微細気泡を多数発生させた水を８０℃程度の温水とし、洗浄剤組成物として塩基性塩系の無機薬品である炭酸ナトリウム、ピロリン酸ナトリウム、第三リン酸ナトリウム、四ホウ酸ナトリウム、硫酸ナトリウム、メタケイ酸ナトリウムと、更に酵素およびゼオライトの各粉末を前記温水中に添加混入して撹拌する。最初は白濁するが、３０分程度撹拌を続けると透明な洗浄剤が出来上がる。この出来上がった洗浄剤はｐＨ１３．３程度のアルカリ性で、昔木灰で洗浄したようなアルカリ洗浄剤となる。
【００３２】
前記マイナスイオンを付与されると共に、超微細気泡を多数発生した水に対し、前記洗浄剤組成物を添加混入する比率は、特に限定する必要はないが、次の通りにすることが推奨される。すなわち、マイナスイオンを付与されると共に、超微細気泡を多数発生した水１０００ｌを８０°以上の温水にした後、該温水に対して炭酸ナトリウム１０〜３０Ｋｇ、好ましくは２０Ｋｇ、ピロリン酸ナトリウム８０〜１００Ｋｇ、好ましくは９０Ｋｇ、第三リン酸ナトリウム３０〜５０Ｋｇ、好ましくは４０Ｋｇ、四ホウ酸ナトリウム１０〜３０Ｋｇ、好ましくは２０Ｋｇ、硫酸ナトリウム１０〜３０Ｋｇ、好ましくは２０Ｋｇ、メタケイ酸ナトリウム５０〜７０Ｋｇ、好ましくは６０Ｋｇ、酵素１００〜３００ｇ、好ましくは２００ｇ、ゼオライト１００〜３００ｇ、好ましくは２００ｇを添加混入して３０分程度撹拌して洗浄剤を得る。
【００３３】
前記洗浄剤組成物のうち、塩基性塩系の無機薬品である炭酸ナトリウム、ピロリン酸ナトリウム、第三リン酸ナトリウム、四ホウ酸ナトリウム、硫酸ナトリウム、メタケイ酸ナトリウムは元々洗浄剤の組成物として使用されているものであるが、ピロリン酸ナトリウムは被洗浄物の表面に薄いミクロの被膜を作り、静電気防止作用があり、更に硫酸ナトリウは被洗浄物に光沢を出す作用をを有する。更に、酵素はタンパク質および有機油を分解する作用を有し、ゼオライトは水自体にマイナスイオンを反応させることによって界面活性能力を高めると共に、水自体のクラスターをより微細にすることによって浸透力を高めるという作用を有する。
【００３４】
前記方法によって得られた洗浄剤はそれぞれ用途に応じて適宜希釈して使用する。例えば食器洗浄、野菜・果実等の洗浄は３００倍、テーブル、椅子、畳の洗浄は１００倍、ガラス製品、窓ガラス、ビニール家具の洗浄および洗車は５０倍、冷蔵庫の洗浄は３０倍、タイル、照明器具、浴槽備品、キッチン、流し台の洗浄は２０倍、ガスレンジ、換気扇の汚れや、インク、衣類の油汚れは１０倍に希釈して使用する。
【００３５】
【実施例】
本発明によって得られた洗浄剤を１０倍に希釈してファーストフード店の厨房の排気口に設置された網状のアルミ製フィルターの洗浄をしたところ、従来の洗浄剤では落ちなかった網目にこびりついた油成分まできれいに落ちた。
【００３６】
【発明の効果】
本発明は上述のようであるから、洗浄剤組成物を溶解する水に、マイナスイオン生成体を収納したマイナスイオン発生装置によりマイナスイオンを付与すると共に、前記水を多数の超微細気泡を有するようにすることにより、水を界面活性物質に変え、且つ該水を８０℃程度の温水とし、該温水に洗浄剤組成物として従来使用されている塩基性塩系の無機薬品である炭酸ナトリウム、ピロリン酸ナトリウム、第三リン酸ナトリウム、四ホウ酸ナトリウム、硫酸ナトリウム、メタケイ酸ナトリウムに加えて、タンパク質および有機油を分解する作用を有する酵素、およびマイナスイオンを反応させることによって界面活性能力を高めると共に、水自体のクラスターをより微細にすることによって浸透力を高めるという作用を有するゼオライトを添加混入しているので、従来の洗浄剤より極めて優れた洗浄効果を有する洗浄剤を得ることができる。
【図面の簡単な説明】
【図１】本発明洗浄剤の製造方法に使用するマイナスイオン発生装置の縦断面図である。
【符号の説明】
１マイナスイオン生成体、２マイナスイオン発生装置、３・４小径部、５円筒体、６通気用小孔、７・８区画壁、９収納部、１０環状マグネット、１１取付けボルト、１２連結チューブ、１３ブロア、１４送風チューブ、１５水槽、１６水。[0001]
BACKGROUND OF THE INVENTION
The present invention relates to a method for producing a cleaning agent that can be used for various households and businesses, and a negative ion generator used in the method.
[0002]
[Prior art]
Conventionally, a detergent mainly composed of trisodium phosphate, sodium metasilicate, sodium sulfate, sodium borate and sodium pyrophosphate is disclosed in Japanese Patent No. 2876054 as a detergent composition. That is, in the above patent publication, as a method for producing a detergent stock solution, about 1000% by weight of water brought to a temperature of 40 to 80 ° C., 15 to 40% by weight of trisodium phosphate as a detergent composition, metasilicic acid After adding 15 to 35% by weight of sodium and 7 to 15% by weight of sodium sulfate and stirring and dissolving sufficiently, sodium borate 0.5 to 18% by weight and sodium pyrophosphate 12 to 50% by weight were sequentially added. It is described that it is effective to stir and dissolve to produce a detergent stock solution.
[0003]
[Problems to be solved by the invention]
However, using the cleaning agent described in the above-mentioned patent publication, the net-like aluminum filter to which the oil at the exhaust port in the commercial kitchen was actually washed was actually washed, but the oil stain on the mesh portion did not fall off, There was a problem that a sufficient cleaning effect could not be obtained.
[0004]
The present invention has been made to solve the above-mentioned problems, and the production of a cleaning agent having an excellent cleaning effect by imparting negative ions to water that dissolves the cleaning composition and using the water as a surfactant. The present invention intends to provide a method and an apparatus for generating negative ions used in the method.
[0005]
[Means for Solving the Problems]
In the present invention, the first base material, konjac flour, is poured into water having a weight of about 5 to 30 times the weight of the sperm, mixed and stirred, and then Is sufficiently dissolved in water and stirred until the stickiness comes out to obtain a sticky konjac solution, and the sticky konjac solution obtained in the first step is mixed with the konjac solution. While mixing 10 to 50% by weight of tourmaline fine powder as the second base material and 10 to 50% by weight of fine carbon powder as the third base material with respect to the weight, far-infrared radiation characteristics are added as an additive. 2nd step of adding and mixing 3 to 10% by weight of the ceramic fine powder having mixing and stirring, and stirring until each base material and additive are uniformly dispersed in the konjac solution, and the second step Weight of the mixed solution obtained in the process 2-5% by weight of sodium carbonate or wood ash as a solidifying material is dissolved in hot water together with the above mixed solution, and stirred so that the mixed solution is semi-solidified to a degree of flexibility (a state of freshness). The third step of obtaining a semi-solidified product, the fourth step of molding the semi-solidified product obtained in the third step according to a predetermined shape of the final use form, and obtaining a molded body of a predetermined shape, The molded body obtained in the fourth step is poured into boiling water and boiled, and after the molded body is solidified to a konjac degree of hardness, the boiled molded body is taken out from the hot water and rapidly put at −40 to −150 ° C. Using the negative ion generator produced through the fifth step of freezing and vacuum drying the rapidly frozen molded body at 30 to 50 ° C. to remove moisture from the molded body to obtain a solid, Negative ions in water to dissolve the composition With grant, allowed further large number of ultrafine bubbles generated in the water, and thereafter, the water was as about 80 ° C. hot water, the temperature in water, sodium carbonate as a wash cleaning agent composition, sodium pyrophosphate, third Sodium phosphate, sodium tetraborate, sodium sulfate, sodium metasilicate, each means of adding and mixing each powder of enzyme and zeolite, or stirring, or
First step of grinding the raw konjac balls that are the first substrate, throwing the ground raw balls into water to precipitate, and then throwing away the supernatant to obtain a konjac solution having adhesiveness, In the konjac solution having adhesiveness obtained in the first step, 10-50% by weight of tourmaline fine powder as the second base material and charcoal fine powder as the third base material with respect to the weight of the konjac solution. 10 to 50% by weight are mixed together, and 3 to 10% by weight of ceramic fine powder having far-infrared radiation characteristics is added and mixed as an additive, mixed and stirred, and the above-mentioned base material and additive are evenly mixed in the konjac solution. A second step of obtaining a mixed solution by stirring until dispersed, and 2-5% by weight of sodium carbonate or wood ash with respect to the weight of the mixed solution obtained in the second step as a solidifying material It was obtained in the third step, which was dissolved in hot water together with the liquid, and stirred so that the mixed solution was semi-solidified to the extent that it was flexible (a state of freshness), and a semi-solidified product was obtained. The semi-solidified product is molded in accordance with the predetermined shape of the final use form, the fourth step to obtain a molded body of the predetermined shape, and the molded body obtained in the fourth step is poured into boiling water and boiled, and the molding After solidifying the body to a hardness of konjac, the boiled molded body is taken out from hot water and rapidly frozen at -40 to -150 ° C, and the rapidly frozen molded body is vacuum dried at 30 to 50 ° C. Using a negative ion product produced through the fifth step of removing water from the molded body to obtain a solid, negative ions are added to water that dissolves the cleaning composition, and the water is further ultrafine. A lot of bubbles are generated, and then the water is And 0 ℃ about hot water, the temperature in water, sodium carbonate as a wash cleaning agent composition, sodium pyrophosphate, sodium tertiary phosphate, sodium tetraborate, sodium sulfate, sodium metasilicate, each powder of the enzyme and zeolite A means of mixing and stirring, or
The first base material, konjac flour, is poured into water having a weight of about 5 to 30 times the weight of the sperm, mixed and stirred, and the sperm powder is sufficiently water. The first step of obtaining a konjac solution having a stickiness by continuing the stirring action until the solution becomes sticky, and the konjac solution having the adhesive property obtained in the first step with respect to the weight of the konjac solution Ceramic fine powder having far-infrared radiation characteristics as an additive while mixing 10 to 50% by weight of tourmaline fine powder as the second base material and 10 to 50% by weight of fine carbon powder as the third base material It is obtained in the second step and the second step, in which 3 to 10% by weight is added and mixed and stirred to stir until each base material and additive are evenly dispersed in the konjac solution to obtain a mixed solution. Against the weight of the mixed solution -5% by weight sodium carbonate or wood ash as a solidifying material is dissolved in hot water together with the above mixed solution, and stirred so that the mixed solution is semi-solidified to a degree of flexibility (a state of freshness). The third step of obtaining the product, and the semi-solidified product obtained in the third step is put into boiling water and boiled, the semi-solidified product is solidified to a konjac degree of hardness, taken out from the hot water, -40 to- After quick freezing at 150 ° C., vacuum drying at 30-50 ° C. to remove moisture to obtain a solid, and the solid obtained in the fourth step into a predetermined shape of the final use form Using the negative ion generator produced through the fifth step to obtain a molded body of a predetermined shape, and adding negative ions to the water that dissolves the cleaning composition, and further adding ultrafine bubbles to the water A large number of The water and about 80 ° C. hot water, the temperature in water, sodium carbonate as a wash cleaning agent composition, sodium pyrophosphate, sodium tertiary phosphate, sodium tetraborate, sodium sulfate, sodium metasilicate, enzymes and zeolite Means of adding and mixing each powder of, and stirring,
First step of grinding the raw konjac balls that are the first substrate, throwing the ground raw balls into water to precipitate, and then throwing away the supernatant to obtain a konjac solution having adhesiveness, In the konjac solution having adhesiveness obtained in the first step, 10-50% by weight of tourmaline fine powder as the second base material and charcoal fine powder as the third base material with respect to the weight of the konjac solution. 10 to 50% by weight are mixed together, and 3 to 10% by weight of ceramic fine powder having far-infrared radiation characteristics is added and mixed as an additive, mixed and stirred, and the above-mentioned base material and additive are evenly mixed in the konjac solution. A second step of obtaining a mixed solution by stirring until dispersed, and 2-5% by weight of sodium carbonate or wood ash with respect to the weight of the mixed solution obtained in the second step as a solidifying material It was obtained in the third step, which was dissolved in hot water together with the liquid, and stirred so that the mixed solution was semi-solidified to the extent that it was flexible (a state of freshness), and a semi-solidified product was obtained. The semi-solidified product is poured into boiling water and boiled. The semi-solidified product is solidified to a konjac hardness, taken out from the hot water, rapidly frozen at -40 to -150 ° C, and then vacuum dried at 30 to 50 ° C. A fourth step of obtaining moisture by removing water and a fifth step of molding the solid obtained in the fourth step in accordance with a predetermined shape of the final use form to obtain a molded body of a predetermined shape The negative ion product produced through the process is used to give negative ions to the water that dissolves the cleaning composition, and to generate a large number of ultrafine bubbles in the water. and hot water, the temperature in water, as wash cleaning agent composition Sodium, sodium pyrophosphate, sodium tertiary phosphate, sodium tetraborate, means that stirred mixed adding each powder sodium sulfate, sodium metasilicate, enzymes and zeolite,
By adopting any of the above, the above-mentioned problems were solved.
[0006]
DETAILED DESCRIPTION OF THE INVENTION
The present inventor considers that the cleaning effect of the cleaning agent described in the above-mentioned conventional patent publication is not sufficient, because it may be a problem with water that dissolves the cleaning agent composition. completed. That is, the present invention provides negative ions to the water that dissolves the cleaning composition, and changes the water into a surface active substance by making the water have ultrafine bubbles, and the cleaning composition is added to the water. Was able to be dissolved to produce a cleaning agent having an excellent cleaning effect.
[0007]
The present inventor has filed a patent application as “Japanese Patent Application No. 2000-255114” entitled “Method for Producing Negative Ion Product”. The present invention uses a negative ion product obtained by the “method for producing a negative ion product” of the above patent application, and imparts negative ions to water that dissolves the cleaning composition, thereby cleaning with excellent cleaning effect. The agent could be manufactured.
[0008]
The negative ion generator is produced as follows. In other words, the negative ion generator used in the present invention is made from konjac fine powder, konjac raw ball, tourmaline fine powder, charcoal fine powder as a base material, and ceramic fine powder having far infrared radiation characteristics as an additive. To manufacture. The manufacturing method will be described in detail below.
[0009]
It is known that the first base material, konjac potato or konjac raw ball, contains a lot of plant fibers, and this plant fiber plays an important role. And the composition of the general component about the anhydride except the moisture of konjac does not change so much depending on the type and the place of origin, and on average 6.1% ash, 0.57% nitrogen, 95.3% saccharides, The main component of the saccharide is konjac mannan, which is a main component, and when it is rapidly cooled and vacuum dried, it becomes a fibrous sponge state.
[0010]
Further, tourmaline as the second base material is a derivative called tourmaline, and has a characteristic of constantly being charged with static electricity, and is a polar crystal body that makes anode and cathode electrodes at both ends. Tourmaline attracts electrons present in the surrounding atmosphere and liquid by the anode and takes them into the crystal, and the taken-in electrons are taken into the current inside the tourmaline. Thus, it is known to have a function of continuously generating these negative ions.
[0011]
Furthermore, the charcoal which is the third base material is made of bamboo charcoal or charcoal, and is mainly composed of carbon, and is known to have electrical induction characteristics.
[0012]
Furthermore, the ceramics having far-infrared radiation characteristics as an additive material need not be particularly limited, but are preferably phyllite, quartz, hamonite, amphibolite, serpentine that are known to emit far-infrared radiation. It is recommended to use ceramics such as quartz diorite, granite, tuff, calcium oxide, magnesia, silica. Then, the ceramic is used as a catalyst so that a far-infrared photosensitivity radiated from the ceramic acts on the tourmaline, thereby releasing a large amount of negative ions from the tourmaline.
[0013]
The production method of the negative ion product using each of the substrates and additives will be described in more detail. First, as a first step, the first base material, konjac flour (konjac flour), is poured into water having a weight of about 5 to 30 times, preferably 15 times the weight of the fine powder. Then, the fine powder is sufficiently dissolved in water by mixing and stirring, and the stirring action is continued until the stickiness is obtained. Then, when the stickiness is sufficiently obtained, the first step is finished to obtain a sticky konjac solution.
[0014]
In the first step, konjac raw balls can be used instead of konjac potato fine powder. In this case, konjac raw balls are ground, and the ground raw balls are poured into water for precipitation, and then the supernatant is discarded to obtain a konjac solution having the same stickiness as described above.
[0015]
Next, as the second step, the adhesive konjac solution obtained in the first step is 10 to 50% by weight of tourmaline fine powder which is the second base material, based on the weight of the konjac solution, preferably Is mixed with 30% by weight and 10 to 50% by weight, preferably 30% by weight, of bamboo charcoal or charcoal fine powder as the third base material, respectively, and as an additive, staghorn, quartz, hamonite, amphibole, Ceramic fine powder of 3 to 10% by weight, consisting of a single substance of ceramics having far-infrared radiation characteristics such as serpentine, quartz diorite, granite, tuff, calcium oxide, magnesia, silica, etc., or a composite thereof, preferably Add 5% by weight, mix and stir, stir until each base material and additive are evenly dispersed in the konjac solution, finish the second step, and mix the base material and additive Get the liquid. The particle size of the base material and additive is not particularly limited, but it is recommended that the particle size is 100 μm or less, preferably 30 μm or less.
[0016]
Further, as the third step, 2 to 5% by weight, preferably 3% by weight of sodium carbonate or wood ash is used as a solidifying material based on the weight of the mixed solution of the base material and additive obtained in the second step. The mixture is dissolved in hot water together with the mixed solution, and stirred so that the mixed solution is semi-solidified to a degree of flexibility (a state of freshly prepared), and the third step is completed to obtain a semi-solid.
[0017]
Then, as the fourth step, the semi-solidified product obtained in the third step is molded according to a predetermined shape such as a spherical shape, a polygonal shape, a disc shape, etc., for example, by die cutting, etc. The process is completed to obtain a molded body having a predetermined shape.
[0018]
As the final fifth step, the molded body obtained in the fourth step was put into boiling water and boiled for about 1 to 3 hours, and the molded body was solidified to a konjac degree of hardness and then boiled. The molded body is taken out of hot water and rapidly frozen at −40 to −150 ° C., preferably −100 ° C., and then the rapidly frozen molded body is vacuum dried at 30 to 50 ° C., preferably about 40 ° C., By removing moisture from the molded body, the production process of the negative ion product is completed, and the negative ion product is obtained.
[0019]
The negative ion product obtained by the above production method is rapidly cooled and vacuum-dried in the fifth step to remove moisture, whereby the konjac fiber is contracted and tightly entangled, and between the fibers. Since tourmaline fine powder, charcoal fine powder and ceramic fine powder are incorporated and integrated in a mixed form, and only the fiber portion of the konjac is left in a sponge state by the moisture removal, the tourmaline fine powder, charcoal fine powder, The negative ion generator in which the powder and the ceramic fine powder are integrally incorporated becomes porous, so that the surface area is increased, and the contact area between the tourmaline fine powder, the fine carbon powder and the fine ceramic powder and the atmosphere is increased. .
[0020]
In addition, the manufacturing process of the molded body in the fourth step can be performed after the completion of the fifth step. That is, after the semi-solid obtained in the third step as the fourth step is put into hot water and boiled for about 1 to 3 hours to solidify the semi-solid to a konjac hardness, It is taken out and rapidly frozen at −40 to −150 ° C., and then vacuum dried at 30 to 50 ° C. to remove moisture and obtain a solid. After that, as the final fifth step, the solid material obtained in the fourth step is molded according to a predetermined shape of the final use form, for example, by cutting or the like, and the production process of the negative ion generator is completed. An ion generator is obtained.
[0021]
As described above, the mechanism of negative ion generation by the negative ion product obtained by the above manufacturing method is that tourmaline is crushed to a small size, and even if it is powdered, its crystal state always maintains a certain shape, and an anode and a cathode are provided at both ends. The electrode has an electrical property that the anode attracts electrons present in the surrounding atmosphere and liquid and takes them into the crystal, transports these electrons to the cathode, and continues to emit negative ions from the cathode. Yes. And it is said that 2000 negative ions are released from tourmaline ore.
[0022]
The tourmaline, which continues to release negative ions due to the above electrical characteristics, is affected by the electrical induction characteristics possessed by bamboo charcoal or charcoal mainly composed of carbon, and the photosensitivity phenomenon caused by far infrared rays emitted by ceramics such as slabs. As a result of the synergistic effect of these two effects, more electrons are attracted to the surrounding atmosphere and liquids in the tourmaline crystal, releasing more negative ions, and tourmaline is a fine powder. Therefore, since the contact area with the atmosphere or liquid is large as described above, the number of electrons taken in by the tourmaline from the atmosphere increases, and therefore more negative ions can be generated from the tourmaline.
[0023]
Table 1 is a table showing the result of measuring the number of negative ions generated by the negative ion product obtained by the above production method, and only 2,000 ions / cc are generated from the above tourmaline ore. According to the negative ion product obtained by the inventive production method, it was confirmed that an average of 9.457 negative ions / cc was released. The measurement conditions are as follows.
Measuring equipment "AIR ION COUNTER"
(America, Made by Radiation Technology)
Measurement environment Room temperature 26 ℃ Humidity 48% Plus number of ions 90 / cc
Sample shape Solid measurement method Measurement 10 times in a simple desiccator environment (weak air blow)
Measurement date May 13, 2000 Measurer Greening Environment Industry Association [0024]
[Table 1]

[0025]
From the measurement results, it was proved that the negative ion product obtained by the production method released a large amount of negative ions without using a commercial power source.
[0026]
The negative ion product obtained by the manufacturing method is porous having a large number of micropores, and the large number of negative ion products 1 are accommodated in the negative ion generator 2. The negative ion generator 1 housed in the negative ion generator 2 is preferably formed into a small sphere.
[0027]
The negative ion generator 2 includes partition walls 7 and 8 having a plurality of ventilation holes 6 formed inwardly of the small diameter portions 3 and 4 of the cylindrical body 5 integrally fixed with the small diameter portions 3 and 4 at both ends. The space between the partition walls 7 and 8 is used as a storage portion 9 for the negative ion generator 1, and the inner peripheral wall surface of the storage portion 9 is circumferentially spaced. A plurality of annular magnets 10 are fixedly formed. In the figure, reference numeral 11 denotes a mounting bolt for holding and fixing the partition walls 7 and 8.
[0028]
A large number of negative ion generators 1 are stored in the storage portion 9 of the negative ion generator 2, and one small diameter portion 3 is connected to the blower 13 via the connection tube 12 and the other small diameter portion 4 is connected. The blower tube 14 is coupled to the front end opening of the blower tube 14 into the water 16 of the water tank 15.
[0029]
When the leading end opening of the blower tube 14 of the negative ion generator 2 is inserted into the water 16 of the water tank 15 and the blower 13 is activated and blown into the storage 9, the air is on the surface of each negative ion generator 1. Turbulently in contact with the air, and air enters the pores in the porous negative ion generator 1, and many electrons are taken into the tourmaline fine powder constituting the negative ion generator 1 from the air. In addition to the release of many negative ions from the negative ion generator 1, the negative ion generator 1 assists in the generation of negative ions from the negative ion generator 1 by the action of Lorentz force by the plurality of annular magnets 10. One to more negative ions (about 100,000 / cc) can be released. In addition, if the negative ion production | generation body 1 is formed in the small sphere, the turbulent flow of air can be raise | generated more smoothly.
[0030]
The negative ions released from the negative ion generator 1 are reduced in the diameter of the other small-diameter portion 4 of the negative-ion generator 2. Is injected into the water 16 of the water tank 15 through the blower tube 14. And by continuing the said injection, while negative ion is provided in the water 16 in the water tank 15, and a strong wind is injected in the water 16, the water 16 in the said water tank 15 is turbulently kneaded. Many ultrafine bubbles are generated.
[0031]
In the present invention, the water to which a large number of ultrafine bubbles are generated while being provided with the negative ions is heated to about 80 ° C., and sodium carbonate and sodium pyrophosphate, which are basic salt-based inorganic chemicals, as a cleaning composition Then, tribasic sodium phosphate, sodium tetraborate, sodium sulfate, sodium metasilicate, and each powder of enzyme and zeolite are added and mixed in the warm water and stirred. At first, it becomes cloudy, but if you keep stirring for about 30 minutes, a transparent cleaning agent is completed. The finished cleaning agent is alkaline with a pH of about 13.3 and becomes an alkaline cleaning agent that has been washed with wood ash in the past.
[0032]
The ratio at which the detergent composition is added to and mixed with the negative ions and a large number of ultrafine bubbles is not particularly limited, but it is recommended that the ratio be as follows. . That is, 1000 l of water to which a large number of ultrafine bubbles are generated while being given negative ions is heated to 80 ° C. or more, and then 10-30 kg of sodium carbonate, preferably 20 kg, and 80-100 kg of sodium pyrophosphate with respect to the warm water. , Preferably 90 Kg, trisodium phosphate 30-30 Kg, preferably 40 Kg, sodium tetraborate 10-30 Kg, preferably 20 Kg, sodium sulfate 10-30 Kg, preferably 20 Kg, sodium metasilicate 50-70 Kg, preferably 60 Kg In addition, 100 to 300 g of enzyme, preferably 200 g, and 100 to 300 g of zeolite, preferably 200 g, are added and mixed and stirred for about 30 minutes to obtain a cleaning agent.
[0033]
Among the above-mentioned detergent compositions, sodium carbonate, sodium pyrophosphate, sodium triphosphate, sodium tetraborate, sodium sulfate, and sodium metasilicate, which are basic salt-based inorganic chemicals, are originally used as detergent compositions. However, sodium pyrophosphate forms a thin micro film on the surface of the object to be cleaned and has an antistatic effect, and sodium sulfate has an effect of giving the object to be cleaned a gloss. In addition, enzymes have the effect of degrading proteins and organic oils, and zeolites enhance surface activity by reacting negative ions with water itself, and also increase osmotic power by making water clusters finer. It has the action.
[0034]
The cleaning agent obtained by the above method is appropriately diluted depending on the use. For example, washing dishes, vegetables and fruits 300 times, washing tables, chairs, tatami mats 100 times, glassware, window glass, vinyl furniture washing and car washing 50 times, refrigerator washing 30 times, tiles, Wash the lighting fixtures, bath fixtures, kitchens, sinks 20 times, and dilute the gas range, ventilation fan stains, ink and clothing oil stains 10 times.
[0035]
【Example】
When the cleaning agent obtained according to the present invention was diluted 10 times and the net-like aluminum filter installed in the exhaust outlet of the kitchen of the fast food store was cleaned, it stuck to the mesh that was not removed by the conventional cleaning agent. The oil component fell cleanly.
[0036]
【The invention's effect】
Since the present invention is as described above, negative ions are imparted to water in which the detergent composition is dissolved by a negative ion generator containing a negative ion generator, and the water has a large number of ultrafine bubbles. By changing the water into a surfactant, the water is heated to about 80 ° C., and the basic salt-based inorganic chemicals sodium carbonate and pyrroline that are conventionally used as a detergent composition in the warm water are used. In addition to sodium phosphate, sodium triphosphate, sodium tetraborate, sodium sulfate, sodium metasilicate, an enzyme that has the action of degrading proteins and organic oils, and increasing the surface active ability by reacting negative ions Zeolite that has the effect of increasing osmotic power by making the water clusters finer Since the pressurized contaminated, it is possible to obtain a detergent having excellent cleaning effect than conventional detergents.
[Brief description of the drawings]
FIG. 1 is a longitudinal sectional view of a negative ion generator used in a method for producing a cleaning agent of the present invention.
[Explanation of symbols]
DESCRIPTION OF SYMBOLS 1 Negative ion production | generation body, 2 Negative ion generator, 3.4 Small diameter part, 5 Cylindrical body, 6 Small hole for ventilation, 7/8 Partition wall, 9 Storage part, 10 Ring magnet, 11 Mounting bolt, 12 Connection tube, 13 blowers, 14 blower tubes, 15 water tanks, 16 water.

Claims

The first base material, konjac flour, is poured into water having a weight of about 5 to 30 times the weight of the sperm, mixed and stirred, and the sperm powder is sufficiently water. The first step of obtaining a konjac solution having a stickiness by continuing the stirring action until the solution becomes sticky, and the konjac solution having the adhesive property obtained in the first step with respect to the weight of the konjac solution Ceramic fine powder having far-infrared radiation characteristics as an additive while mixing 10 to 50% by weight of tourmaline fine powder as the second base material and 10 to 50% by weight of fine carbon powder as the third base material It is obtained in the second step and the second step, in which 3 to 10% by weight is added and mixed and stirred to stir until each base material and additive are evenly dispersed in the konjac solution to obtain a mixed solution. Against the weight of the mixed solution -5% by weight sodium carbonate or wood ash as a solidifying material is dissolved in hot water together with the above mixed solution, and stirred so that the mixed solution is semi-solidified to a degree of flexibility (a state of freshness). A third step of obtaining a product, a fourth step of molding the semi-solidified product obtained in the third step according to a predetermined shape of a final use form, and obtaining a molded body of a predetermined shape, and the fourth step The obtained molded body was poured into boiling water and boiled, and after the molded body was solidified to a konjac degree of hardness, the boiled molded body was taken out from the hot water and rapidly frozen at -40 to -150 ° C, The rapidly frozen molded body is vacuum-dried at 30 to 50 ° C., and the detergent composition is dissolved using the negative ion product produced through the fifth step of removing moisture from the molded body to obtain a solid. When negative ions are added to the water In, it allowed generating a large number of ultrafine bubbles further to the water,
Thereafter, the water was as about 80 ° C. hot water, the temperature in water, sodium carbonate as a wash cleaning agent composition, sodium pyrophosphate, sodium tertiary phosphate, sodium tetraborate, sodium sulfate, sodium metasilicate, A method for producing a cleaning agent, comprising adding and mixing each powder of enzyme and zeolite and stirring.

First step of grinding the raw konjac balls that are the first substrate, throwing the ground raw balls into water to precipitate, and then throwing away the supernatant to obtain a konjac solution having adhesiveness, In the konjac solution having adhesiveness obtained in the first step, 10-50% by weight of tourmaline fine powder as the second base material and charcoal fine powder as the third base material with respect to the weight of the konjac solution. 10 to 50% by weight are mixed together, and 3 to 10% by weight of ceramic fine powder having far-infrared radiation characteristics is added and mixed as an additive, mixed and stirred, and the above-mentioned base material and additive are evenly mixed in the konjac solution. A second step of obtaining a mixed solution by stirring until dispersed, and 2-5% by weight of sodium carbonate or wood ash with respect to the weight of the mixed solution obtained in the second step as a solidifying material It was obtained in the third step, which was dissolved in hot water together with the liquid, and stirred so that the mixed solution was semi-solidified to the extent that it was flexible (a state of freshness), and a semi-solidified product was obtained. The semi-solidified product is molded in accordance with the predetermined shape of the final use form, the fourth step to obtain a molded body of the predetermined shape, and the molded body obtained in the fourth step is poured into boiling water and boiled, and the molding After solidifying the body to a hardness of konjac, the boiled molded body is taken out from hot water and rapidly frozen at -40 to -150 ° C, and the rapidly frozen molded body is vacuum dried at 30 to 50 ° C. Using a negative ion product produced through the fifth step of removing water from the molded body to obtain a solid, negative ions are added to water that dissolves the cleaning composition, and the water is further ultrafine. A lot of bubbles,
Thereafter, the water was as about 80 ° C. hot water, the temperature in water, sodium carbonate as a wash cleaning agent composition, sodium pyrophosphate, sodium tertiary phosphate, sodium tetraborate, sodium sulfate, sodium metasilicate, A method for producing a cleaning agent, comprising adding and mixing each powder of enzyme and zeolite and stirring.

The first base material, konjac flour, is poured into water having a weight of about 5 to 30 times the weight of the sperm, mixed and stirred, and the sperm powder is sufficiently water. The first step of obtaining a konjac solution having a stickiness by continuing the stirring action until the solution becomes sticky, and the konjac solution having the adhesive property obtained in the first step with respect to the weight of the konjac solution Ceramic fine powder having far-infrared radiation characteristics as an additive while mixing 10 to 50% by weight of tourmaline fine powder as the second base material and 10 to 50% by weight of fine carbon powder as the third base material It is obtained in the second step and the second step, in which 3 to 10% by weight is added and mixed and stirred to stir until each base material and additive are evenly dispersed in the konjac solution to obtain a mixed solution. Against the weight of the mixed solution -5% by weight sodium carbonate or wood ash as a solidifying material is dissolved in hot water together with the above mixed solution, and stirred so that the mixed solution is semi-solidified to a degree of flexibility (a state of freshness). The third step of obtaining the product, and the semi-solidified product obtained in the third step is put into boiling water and boiled, the semi-solidified product is solidified to a konjac degree of hardness, taken out from the hot water, -40 to- After quick freezing at 150 ° C., vacuum drying at 30-50 ° C. to remove moisture to obtain a solid, and the solid obtained in the fourth step into a predetermined shape of the final use form Using the negative ion generator produced through the fifth step to obtain a molded body of a predetermined shape, and adding negative ions to the water that dissolves the cleaning composition, and further adding ultrafine bubbles to the water A large number of
Thereafter, the water was as about 80 ° C. hot water, the temperature in water, sodium carbonate as a wash cleaning agent composition, sodium pyrophosphate, sodium tertiary phosphate, sodium tetraborate, sodium sulfate, sodium metasilicate, A method for producing a cleaning agent, comprising adding and mixing each powder of enzyme and zeolite and stirring.

First step of grinding the raw konjac balls that are the first substrate, throwing the ground raw balls into water to precipitate, and then throwing away the supernatant to obtain a konjac solution having adhesiveness, In the konjac solution having adhesiveness obtained in the first step, 10-50% by weight of tourmaline fine powder as the second base material and charcoal fine powder as the third base material with respect to the weight of the konjac solution. 10 to 50% by weight are mixed together, and 3 to 10% by weight of ceramic fine powder having far-infrared radiation characteristics is added and mixed as an additive, mixed and stirred, and the above-mentioned base material and additive are evenly mixed in the konjac solution. A second step of obtaining a mixed solution by stirring until dispersed, and 2-5% by weight of sodium carbonate or wood ash with respect to the weight of the mixed solution obtained in the second step as a solidifying material It was obtained in the third step, which was dissolved in hot water together with the liquid, and stirred so that the mixed solution was semi-solidified to the extent that it was flexible (a state of freshness), and a semi-solidified product was obtained. The semi-solidified product is poured into boiling water and boiled. The semi-solidified product is solidified to a konjac hardness, taken out from the hot water, rapidly frozen at -40 to -150 ° C, and then vacuum dried at 30 to 50 ° C. A fourth step of obtaining moisture by removing water and a fifth step of molding the solid obtained in the fourth step in accordance with a predetermined shape of the final use form to obtain a molded body of a predetermined shape Using the negative ion product produced through the process, the negative ion is added to the water that dissolves the cleaning composition, and a number of ultrafine bubbles are generated in the water.
Thereafter, the water was as about 80 ° C. hot water, the temperature in water, sodium carbonate as a wash cleaning agent composition, sodium pyrophosphate, sodium tertiary phosphate, sodium tetraborate, sodium sulfate, sodium metasilicate, A method for producing a cleaning agent, comprising adding and mixing each powder of enzyme and zeolite and stirring.

A cylindrical body having a small-diameter portion integrally provided at both ends is fixedly provided with partition walls each having a large number of small ventilation holes, and a space between the partition walls serves as a storage portion for the negative ion generator. A plurality of annular magnets are fixed to the inner peripheral wall surface of the storage portion in the circumferential direction, and a large number of negative ion generators are stored in the storage portion, and one small diameter portion is connected. Connected to a blower through a tube, and connected to a blower tube to the other small-diameter portion, the tip opening of the blower tube is inserted into the water of a water tank. Negative ion generator.