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JP7045831B2 - A method for manufacturing cosmetics using strongly electrolytic alkaline reduced water that maintains the reducing function for a long period of time. - Google Patents
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JP7045831B2 - A method for manufacturing cosmetics using strongly electrolytic alkaline reduced water that maintains the reducing function for a long period of time. - Google Patents

A method for manufacturing cosmetics using strongly electrolytic alkaline reduced water that maintains the reducing function for a long period of time. Download PDF

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JP7045831B2
JP7045831B2 JP2017207511A JP2017207511A JP7045831B2 JP 7045831 B2 JP7045831 B2 JP 7045831B2 JP 2017207511 A JP2017207511 A JP 2017207511A JP 2017207511 A JP2017207511 A JP 2017207511A JP 7045831 B2 JP7045831 B2 JP 7045831B2
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昌治 久保田
正治 吉崎
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本発明は、強電解アルカリ性還元水に、水和電子水を添加混合、または前記水和電子水と活性剤とを添加混合することにより、前記強電解アルカリ性還元水が少なくとも6ヶ月以上の長期に亘ってORP(酸化還元電位)がマイナス電位を持続して、その間洗浄能、浸透性、保湿性、殺菌能等の還元機能を維持せしめた強電解アルカリ性還元水を原料水とする化粧品の製造方法であって、紫外線に起因するシミ、ソバカスや老化等の肌のトラブルを防止または回復機能等の美肌効果を長期に亘って維持することができる還元機能を長期維持せしめた強電解アルカリ性還元水を原料水とするローションやクリーム等の化粧品の製造方法に関するものである。 In the present invention, the strongly electrolytic alkaline reduced water is added and mixed with hydrated electron water, or the hydrated electron water and an activator are added and mixed, so that the strongly electrolytic alkaline reduced water can be used for a long period of at least 6 months or more. Manufacture of cosmetics using strongly electrolytic alkaline reduced water as a raw material, in which the ORP (oxidation-reduction potential) maintains a negative potential throughout, and during that time, the reducing functions such as detergency, permeability, moisturizing property, and bactericidal ability are maintained. It is a method of strongly electrolytic alkaline reduced water that maintains the reducing function for a long period of time, which can prevent skin troubles such as stains, buckwheat and aging caused by ultraviolet rays, or maintain the skin-beautifying effect such as recovery function for a long period of time. It relates to a method for producing cosmetics such as lotions and creams using the raw water as a raw material.

一般的に、ORPが+200mV(vs.Ag./AgCl)以下であれば還元機能があるといわれている。一方、強電解アルカリ性還元水は、pH11以上、ORP-200~-800mV程度で優れた洗浄能、浸透性、保湿性、殺菌能等の還元機能を有する活性水であり機能水といわれている。前記優れた特性を有する強電解アルカリ性還元水は、現在多くのアストリンゼントやローション等の化粧水、またはクリーム等の化粧品の原料水として広く使用されている。そして、特に前記強電解アルカリ性還元水を、化粧水または化粧品の原料水として使用する場合は、特に、ORP値のマイナス電位が大きい方が望ましいと考えられている。前記強電解アルカリ性還元水のpHは比較的安定であるが、ORP値は時間の経過と共に容易に上昇し、マイナス電位からプラス電位に移行する。また、前記強電解アルカリ性還元水の還元機能は、主として水の電気分解により生成した水素に起因していると考えられる。このことは、実際に溶存水素計で水素濃度を測定すると、水素が検出されることからも明らかである。しかし、水素は水に溶けにくいガスであるため、容易に蒸散してしまう。そのため、ORP値は時間の経過と共に容易に上昇し、マイナス電位からプラス電位になってしまう。それに伴い、強電解アルカリ性還元水の洗浄能、浸透性、保湿性、殺菌能等の還元機能が徐々に失われてしまうので、前記強電解アルカリ性還元水を原料水とする化粧水または化粧品では、シミ、ソバカスや老化等の肌のトラブルの防止または回復機能等の美肌効果も徐々に失われてしまうという課題があった。 Generally, it is said that if the ORP is +200 mV (vs. Ag. / AgCl) or less, it has a reducing function. On the other hand, strongly electrolytic alkaline reduced water is active water having a reducing function such as excellent detergency, permeability, moisturizing property, and bactericidal ability at pH 11 or higher and ORP-200 to -800 mV, and is called functional water. The strongly electrolytic alkaline reduced water having the above-mentioned excellent properties is widely used at present as a lotion for lotions such as astringents and lotions, or as a raw material water for cosmetics such as creams. Further, particularly when the strongly electrolytic alkaline reduced water is used as a cosmetic water or a raw material water for cosmetics, it is considered that it is particularly desirable that the negative potential of the ORP value is large. The pH of the strongly electrolytic alkaline reduced water is relatively stable, but the ORP value easily increases with the passage of time and shifts from a negative potential to a positive potential. Further, it is considered that the reducing function of the strongly electrolytic alkaline reduced water is mainly caused by hydrogen generated by electrolysis of water. This is clear from the fact that hydrogen is detected when the hydrogen concentration is actually measured with a dissolved hydrogen meter. However, since hydrogen is a gas that is difficult to dissolve in water, it easily evaporates. Therefore, the ORP value easily rises with the passage of time, and changes from a negative potential to a positive potential. Along with this, the reducing functions such as detergency, permeability, moisturizing property, and bactericidal ability of the strongly electrolytic alkaline reduced water are gradually lost. There is a problem that the skin-beautifying effect such as prevention or recovery function of skin troubles such as spots, soap and aging is gradually lost.

ところで、本願出願人は、下記特許文献1に示す「発明の名称 強電解アルカリ性還元水を用いた化粧水または化粧品」につき、特許第4390125号を所有している。前記したように、前記特許の化粧水または化粧品の原料水である強電解アルカリ性還元水のpHは比較的安定であるが、ORP値は時間の経過と共に、容易に上昇しマイナス電位からプラス電位に移行してしまい、その結果強電解アルカリ性還元水の洗浄能、浸透性、保湿性、殺菌能等の還元機能が徐々に失われてしまうので、美肌効果も失われてしまうという課題があった。 By the way, the applicant of the present application owns Patent No. 4390125 for "name of invention, cosmetics or cosmetics using strongly electrolytic alkaline reduced water" shown in Patent Document 1 below. As described above, the pH of the patented cosmetic water or the strongly electrolytic alkaline reduced water which is the raw material water for cosmetics is relatively stable, but the ORP value easily increases with the passage of time from a negative potential to a positive potential. As a result, the reducing functions such as the detergency, permeability, moisturizing property, and bactericidal ability of the strongly electrolytic alkaline reduced water are gradually lost, so that there is a problem that the skin-beautifying effect is also lost.

特許第4390125号公報Japanese Patent No. 4390125

本発明は、前記課題を解決すべくなされたものであって、pH12.0~12.5程度で、且つORP-200~-900mV程度の強電解アルカリ性還元水に、水和電子水を添加混合、または前記水和電子水と活性剤とを添加混合することにより、ORPが-50mV以下のマイナス電位を持続して、少なくとも6ヶ月以上の長期に亘って還元機能を維持せしめると共に、前記長期に亘って還元機能を維持せしめた強電解アルカリ性還元水を、化粧品の原料水として使用することにより、シミ、ソバカスや老化等の肌のトラブルを防止または回復機能等の美肌効果を長期に亘って維持することができる還元機能を長期維持せしめた強電解アルカリ性還元水を原料水とする化粧品の製造方法を提供しようとするものである。 The present invention has been made to solve the above problems, and hydrated electron water is added and mixed with strongly electrolytic alkaline reduced water having a pH of about 12.0 to 12.5 and an ORP of about -200 to -900 mV. Or, by adding and mixing the hydrated electron water and the activator, the ORP maintains a negative potential of -50 mV or less, maintains the reducing function for a long period of at least 6 months or more, and maintains the reducing function for a long period of time. By using the strongly electrolytic alkaline reduced water that has maintained the reducing function for a long time as the raw material water for cosmetics, it prevents skin troubles such as stains, buckwheat and aging, or has a long-term skin-beautifying effect such as recovery function. It is an object of the present invention to provide a method for producing cosmetics using strongly electrolytic alkaline reduced water as a raw material water, which maintains a reducing function that can be maintained for a long period of time.

本発明は、第1の基材であるこんにゃくいもの精粉を水に投入して混合攪拌して、前記こんにゃくいもの精粉を水に溶かし、粘着性が出るまで攪拌作業を続けて、粘着性を有するこんにゃくいも溶液とし、且つ該粘着性を有するこんにゃくいも溶液に、該こんにゃくいも溶液の重量に対して、第2の基材であるトルマリン微粉末30重量%および第3の基材である炭微粉末30重量%をそれぞれ混入すると共に、添加材として角閃石、花崗斑岩等の遠赤外線放射特性を有するセラミックス微粉末5重量%を添加混入して混合攪拌し、且つ前記基材および添加材の混合溶液に、固化材として3重量%の炭酸ナトリウムを混入し、これを熱湯で溶かして半固化せしめて小球体状成型体とし、且つ前記成型体を熱湯に投入して約1~3時間程度煮沸して、該成型体をこんにゃく程度の硬さまで固化せしめた後、該成型体を熱湯から取り出して、-100℃程度で急冷凍し、然る後、前記急冷凍した成型体を40℃程度で真空乾燥させて、前記成型体より水分を除去することにより小球体状の電子生成体を製造する一方、
両端に小径部を備えた円筒体に、通気用小孔を多数穿設した区画壁をそれぞれ固設して、該区画壁間の空隙部を前記電子生成体の収納部とすると共に、該収納部の内周壁面に円周方向に間隔を有して、複数本の環状マグネットを固着して水和電子水生成装置が形成され、
更に、前記水和電子水生成装置の収納部内に前記多数の電子生成体を収納すると共に、一方の小径部を連結チューブを介してブロアに連結し、且つ他方の小径部に送風チューブを連結して、該送風チューブの先端開口部を水槽の水内へ装入し、前記ブロアを起動して収納部内に送風して、送風空気小球体に形成された各電子生成体の表面に接触した後、水和電子水生成装置の他方の小径部において風速を速めて前記送風チューブを介して強風を水槽の水内に噴射し、前記強風が水内に噴射されることにより、前記水槽内の水は乱流混合されて超微細気泡が多数発生して、水和電子水が生成される一方、
3室型電解槽を用いて純水を電気分解して得られた還元水であって、生成時におけるpHが12.0~12.5程度であり、且つORP-200~-900mV程度の強電解アルカリ性還元水に、該強電解アルカリ性還元水の重量に対して、前記生成された水和電子水3.0~10.0重量%を、あるいは前記強電解アルカリ性還元水に、前記水和電子水3.0~5.0重量%と、活性剤としてヤシ油脂肪酸PEG-7グリセリル1.0~5.0重量%、またはラウリルグルコシド1.0~5.0重量%のいずれかを添加混合するという手段を採用することにより、上記課題を解決した。
In the present invention, the konnyakui powder, which is the first base material, is put into water, mixed and stirred, the konnyakui powder is dissolved in water, and the stirring operation is continued until the stickiness is obtained. To make a konjac moist solution having a property, and to the konjac moth solution having the adhesiveness , with 30% by weight of tolumarin fine powder as a second base material and a third base material with respect to the weight of the konjac moth solution. 30% by weight of a certain charcoal fine powder is mixed, and 5% by weight of ceramic fine powder having far infrared radiation characteristics such as horn flash stone and granule rock is added and mixed as an additive, and the mixture is stirred and mixed. In addition, 3% by weight of sodium carbonate is mixed as a solidifying material in the mixed solution of the additive material, and this is melted in boiling water to semi-solidify to form a small spherical molded body, and the molded body is put into boiling water for about 1 After boiling for about 3 hours to solidify the molded product to a hardness of about konjac, the molded product is taken out from boiling water, rapidly frozen at about -100 ° C., and then the rapidly frozen molded product. Is vacuum-dried at about 40 ° C. to remove water from the molded body to produce a small spherical electron generator.
A partition wall having a large number of small holes for ventilation is fixed to a cylindrical body having small diameter portions at both ends, and the gap between the partition walls is used as a storage portion for the electron generator and the storage portion. A hydrated electron water generator is formed by fixing a plurality of annular magnets to the inner peripheral wall surface of the portion at intervals in the circumferential direction.
Further, the large number of electron generators are housed in the storage portion of the hydrated electron water generator, one small diameter portion is connected to the blower via a connecting tube, and the blower tube is connected to the other small diameter portion. Then, the tip opening of the blower tube is charged into the water of the water tank, the blower is activated and blown into the storage part, and the blown air comes into contact with the surface of each electron generator formed in the small sphere. After that, in the other small diameter portion of the hydrated electron water generator, the wind speed is increased and a strong wind is jetted into the water of the water tank through the blower tube, and the strong wind is jetted into the water. While the water in the water tank is turbulently mixed and a large number of ultrafine bubbles are generated , hydrated electron water is generated.
Reduced water obtained by electrolyzing pure water using a 3-chamber type electrolytic tank, having a pH of about 12.0 to 12.5 at the time of production and a strong ORP-200 to -900 mV. In the electrolytic alkaline reduced water, 3.0 to 10.0% by weight of the generated hydrated electron water with respect to the weight of the strongly electrolytic alkaline reduced water, or in the strongly electrolytic alkaline reduced water, the hydrated electrons. Add and mix 3.0 to 5.0% by weight of water and 1.0 to 5.0% by weight of coconut oil fatty acid PEG-7 glyceryl or 1.0 to 5.0% by weight of lauryl glucoside as an activator. By adopting the means of doing so, the above problem was solved.

本発明製造方法によって得られた化粧品は、pH12.0~12.5程度で、且つORP-200~-900mV程度の強電解アルカリ性還元水に、水和電子水を添加混合、または前記水和電子水と活性剤とを添加混合することにより、ORPが-50mV以下のマイナス電位を持続して、少なくとも6ヶ月以上の長期に亘って還元機能を維持せしめると共に、前記長期に亘って還元機能を維持せしめた強電解アルカリ性還元水を、ローション、クリーム等の化粧品の原料水として使用しているため、シミ、ソバカスや老化等の肌のトラブルを防止、または回復機能等の美肌効果を長期に亘って維持することができるので、化粧品として長期使用が可能で、消費者にとっては極めて有益な商品である。 The cosmetics obtained by the production method of the present invention are obtained by adding and mixing hydrated electronic water to strongly electrolytic alkaline reduced water having a pH of about 12.0 to 12.5 and an ORP of about -200 to -900 mV, or the above-mentioned hydration. By adding and mixing electronic water and an activator, the ORP maintains a negative potential of -50 mV or less, maintains the reducing function for a long period of at least 6 months or more, and exhibits the reducing function for the long period of time. Since the maintained strong electrolytic alkaline reduced water is used as the raw material water for cosmetics such as lotions and creams, it prevents skin problems such as stains, buckwheat and aging, or has a long-term skin-beautifying effect such as recovery function. Since it can be maintained for a long period of time, it can be used as a cosmetic product for a long period of time, and is an extremely beneficial product for consumers.

本発明還元機能を長期維持せしめた強電解アルカリ性還元水を原料水とする化粧品の製造方法において、その原料水となる強電解アルカリ性還元水の還元機能の長期維持化方法に使用する水和電子水の生成装置を示す縦断面図である。In the method for producing cosmetics using strongly electrolytic alkaline reduced water as a raw material water, which has maintained the reducing function for a long period of time, the hydrated electrons used in the method for maintaining the reducing function of strongly electrolytic alkaline reduced water as the raw material water for a long period of time. It is a vertical sectional view which shows the water generator. 本発明還元機能を長期維持せしめた強電解アルカリ性還元水を原料水とする化粧品の製造方法において、その原料水となる強電解アルカリ性還元水に添加混合する水和電子水の混合割合を変えて生成した水和電子水混合強電解アルカリ性還元水と、水和電子水を混合していない強電解アルカリ性還元水のORP値の経時変化を示すグラフである。In the method for producing cosmetics using strongly electrolytic alkaline reduced water that maintains the reducing function for a long period of time, the mixing ratio of hydrated electron water to be added and mixed with the strongly electrolytic alkaline reduced water used as the raw material water is changed. It is a graph which shows the time-dependent change of the ORP value of the generated hydrated electron water mixed strong electrolysis alkaline reduced water, and the strongly electrolytic alkaline reduced water which did not mix hydrated electron water. 本発明還元機能を長期維持せしめた強電解アルカリ性還元水を原料水とする化粧品の製造方法において、その原料水となる強電解アルカリ性還元水の還元機能の長期維持化方法によって製造された水和電子水混合強電解アルカリ性還元水と、比較のために汎用の精製水および水和電子水を添加混合していない強電解アルカリ性還元水とを、化粧として使用し、複数人の女性の素肌に塗布した後の美肌効果テストの評価表である。In the method for producing cosmetics using strongly electrolytic alkaline reduced water as a raw material water, which has maintained the reducing function for a long period of time, the hydration produced by the method for maintaining the reducing function of strongly electrolytic alkaline reduced water as the raw material water for a long period of time. Electronic water mixed strong electrolytic alkaline reduced water and strong electrolytic alkaline reduced water mixed with general-purpose purified water and hydrated electronic water for comparison are used as cosmetics for the bare skin of multiple women. It is an evaluation table of the skin-beautifying effect test after application.

本発明の実施例につき詳細に説明する。先ず、電子はマイナスの電荷を持ち、還元作用の基本物質である。酸化還元の定義からも明らかなように、ある物質が電子を得ることが還元であり、電子を失うことが酸化である。電子は、これが水中で水に囲まれた、所謂、水和電子水の状態ではかなり安定に存在することが知られている。このような水和電子水は、ORP計で計測すると、マイナス電位を示し、実際に還元機能があることを本発明者らは確認している。しかしながら、還元機能を有するのは水素ではないので、溶存水素計では水素は検出されない。 Examples of the present invention will be described in detail. First, electrons have a negative charge and are the basic substance of reducing action. As is clear from the definition of redox, the acquisition of electrons by a substance is reduction, and the loss of electrons is oxidation. It is known that electrons exist fairly stably in the state of so-called hydrated electron water, which is surrounded by water in water. The present inventors have confirmed that such hydrated electron water shows a negative potential when measured with an ORP meter and actually has a reducing function. However, since it is not hydrogen that has a reducing function, hydrogen is not detected by the dissolved hydrogen meter.

本発明者らは、強電解アルカリ性還元水、例えば、前記特許文献1に記載されたようなORP-200~-900mV程度の強電解アルカリ性還元水に、いろいろな方法により製造された水和電子水を添加してテストを繰り返し、少なくとも6ヶ月以上の長期に亘って還元機能を持続し、これにより強電解アルカリ性還元水の洗浄能、浸透性、保湿性、殺菌能等の還元機能を長期に亘って維持することができる水和電子水を探し求めた。そして、本発明者らは、特許第3850645号に開示されたマイナスイオン水の製造方法を利用して製造した水和電子水を、強電解アルカリ性還元水に添加混合することにより、少なくとも6ヶ月以上の長期に亘って、強電解アルカリ性還元水の洗浄能、浸透性、保湿性、殺菌能等の還元機能を長期に亘って維持できることを確認し、本発明を完成した。 The present inventors have made strong electrolytic alkaline reduced water, for example, strongly electrolytic alkaline reduced water having an ORP of about -200 to -900 mV as described in Patent Document 1, and hydrated electron water produced by various methods. Is added and the test is repeated to maintain the reducing function for a long period of at least 6 months, thereby providing the reducing function such as detergency, permeability, moisturizing property, and bactericidal ability of strongly electrolytic alkaline reduced water for a long period of time. We searched for hydrated electron water that could be maintained. Then, the present inventors add and mix the hydrated electron water produced by using the method for producing negative ionized water disclosed in Patent No. 3850645 to the strongly electrolytic alkaline reduced water for at least 6 months or more. It was confirmed that the reducing functions such as detergency, permeability, moisturizing property, and bactericidal ability of strongly electrolytic alkaline reduced water can be maintained for a long period of time, and the present invention has been completed.

本発明化粧品の原料水として使用する強電解アルカリ性還元水は、前記特許文献1記載の方法によって製造される。すなわち、特許文献1の図1記載の、カソード室1とアノード室2との間に、間隔を有して隔膜3・4を配設して中間室5を設け、且つ前記カソード室1とアノード室2の中に、それぞれカソード極6とアノード極7を配設して形成した3室型電解槽Aを使用して製造する。 The strongly electrolytic alkaline reduced water used as the raw material water for the cosmetics of the present invention is produced by the method described in Patent Document 1. That is, in FIG. 1 of Patent Document 1, an intermediate chamber 5 is provided by arranging diaphragms 3 and 4 at intervals between the cathode chamber 1 and the anode chamber 2, and the cathode chamber 1 and the anode are provided. It is manufactured by using a three-chamber type electrolytic cell A formed by arranging a cathode pole 6 and an anode pole 7 in the chamber 2, respectively.

前記カソード室1とアノード室2に純水を入れると共に、中間室5に食塩を入れて電気分解すると、カソード室1内においては還元水(アルカリイオン水)が生成され、一方アノード室2内においては酸性水が生成される。本発明においては、カソード室1内において生成された還元水を使用する。そして、前記還元水の生成時におけるpHとORPを測定すると、pHは10.5~12.5、ORPは-150~-900mVであるが、本発明においては、pH12.0~12.5程度、ORP-200~-900mV程度の強電解アルカリ性還元水を使用する。 When pure water is put into the cathode chamber 1 and the anode chamber 2 and salt is put into the intermediate chamber 5 and electrolyzed, reduced water (alkaline ionized water) is generated in the cathode chamber 1 while in the anode chamber 2. Produces acidic water. In the present invention, the reduced water generated in the cathode chamber 1 is used. Then, when the pH and ORP at the time of producing the reduced water are measured, the pH is 10.5 to 12.5 and the ORP is −150 to −900 mV, but in the present invention, the pH is about 12.0 to 12.5. , ORP-200 to -900 mV of strongly electrolytic alkaline reduced water is used.

そして、前記強電解アルカリ性還元水に添加混合することができる、水和電子水は、特許第3850645号に開示されたマイナスイオン水の製造方法を利用して製造する。前記マイナスイオン水の製造方法を利用して製造された水和電子水、または前記水和電子水と活性剤とを、前記電解アルカリ性還元水に添加混合することにより、本発明が目的とする、少なくとも6ヶ月以上の長期に亘って、強電解アルカリ性還元水の洗浄能、浸透性、保湿性、殺菌能等の還元機能を長期に亘って維持することができることを確認した。 The hydrated electron water that can be added and mixed with the strongly electrolytic alkaline reduced water is produced by using the method for producing negative ion water disclosed in Japanese Patent No. 3850645. An object of the present invention is to add and mix hydrated electron water produced by using the method for producing negative ionized water, or the hydrated electron water and an activator, to the electrolytic alkaline reduced water. It was confirmed that the reducing functions such as detergency, permeability, moisturizing property, and bactericidal ability of strongly electrolytic alkaline reduced water can be maintained for a long period of time of at least 6 months or more.

前記強電解アルカリ性還元水に添加混合することができる、水和電子水は、特許第3850645号に開示されたマイナスイオン水の製造方法を利用して生成する。すなわち、本発明において使用する水和電子水は、こんにゃくいもの精粉、トルマリン微粉末、炭微粉末を基材とし、更に遠赤外線放射特性を有するセラミックス微粉末を添加材と製造された電子生成体により生成された電子を水中に噴射することにより生成される。 The hydrated electron water that can be added and mixed with the strongly electrolytic alkaline reduced water is produced by utilizing the method for producing negative ion water disclosed in Japanese Patent No. 3850645. That is, the hydrated electron water used in the present invention is based on konjac fine powder, tolumarin fine powder, and charcoal fine powder, and further uses ceramic fine powder having far-infrared radiation characteristics as an additive to generate electrons. It is generated by injecting electrons generated by the body into water.

前記電子生成体は、前記特許第3850645号の第1工程~第4工程により製造される。すなわち、第1の基材であるこんにゃくいもの精粉(こんにゃく粉)を水に投入して混合攪拌して、前記こんにゃくいもの精粉を充分に水に溶かし、粘着性が出るまで攪拌作業を続けて、粘着性を有するこんにゃくいも溶液とし、且つ前記得られた粘着性を有するこんにゃくいも溶液に、該こんにゃくいも溶液の重量に対して、第2の基材であるトルマリン微粉末30重量%および第3の基材である炭微粉末30重量%をそれぞれ混入すると共に、添加材として角閃石、花崗斑岩等の遠赤外線放射特性を有するセラミックス微粉末5重量%を添加混入して混合攪拌し、更に前記基材および添加材の混合溶液に、固化材として3重量%の炭酸ナトリウムを混入し、これを熱湯で溶かして、つきたての餅程度まで半固化せしめて多数の小球体状の成型体に成型し、且つ前記得られた成型体を、熱湯に投入して約1~3時間程度煮沸して、該成型体をこんにゃく程度の硬さまで固化せしめた後、該煮沸した成型体を熱湯から取り出して、-100℃程度で急冷凍し、然る後、前記急冷凍した成型体を40℃程度で真空乾燥させて、前記成型体より水分を除去することにより、小球体状の電子生成体を製造する。 The electron generator is manufactured by the first step to the fourth step of the patent No. 3850645. That is, the konjac flour (konjac flour), which is the first base material, is put into water, mixed and stirred, and the konjac flour is sufficiently dissolved in water, and the stirring work is performed until the stickiness appears. Subsequently, a sticky konjac flour solution was prepared, and the obtained sticky konjac flour solution was added to 30% by weight of the second base material, tolumarin fine powder, with respect to the weight of the konjac flour solution. 30% by weight of konjac flour, which is the third base material, is mixed, and 5% by weight of konjac fine powder having far-infrared radiation characteristics such as konjac and konjac rock is added and mixed as an additive and mixed and stirred. Further, 3% by weight of sodium carbonate is mixed as a solidifying material in the mixed solution of the base material and the additive, and this is melted with boiling water to semi-solidify to the extent of a freshly made konjac flour, resulting in a large number of small spheres. The molded product is molded into the above-mentioned molded body, and the obtained molded body is put into boiling water and boiled for about 1 to 3 hours to solidify the molded body to a hardness of about konjac, and then the boiled molded body. Is taken out from boiling water and rapidly frozen at about -100 ° C., and then the rapidly frozen molded product is vacuum-dried at about 40 ° C. to remove water from the molded product to form a small sphere. Manufacture an electron generator.

前記製造された電子生成体は、前記急冷真空乾燥させて水分を除去することにより、こんにゃくいもの繊維質が収縮して強固に絡まり合うと共に、該各繊維質間にトルマリン微粉末、炭微粉末およびセラミックス微粉末が混合した形で取り込まれて一体化され、更に前記水分除去により前記こんにゃくいもの繊維質部分のみがスポンジ状態で残るため、前記トルマリン微粉末、炭微粉末およびセラミックス微粉末を一体に取り込んだ電子生成体は多孔質となり、従ってこれにより表面積が大となると共に、該トルマリン微粉末、炭微粉末およびセラミックス微粉末と大気との接触面積が大となる。 In the manufactured electron generator, the fibers of the konjac are shrunk and tightly entangled by removing water by quenching and vacuum drying, and at the same time, tolumarin fine powder and carbon fine powder are formed between the fibers. And the ceramic fine powder is taken in and integrated in a mixed form, and since only the fibrous part of the konjac remains in a sponge state due to the water removal, the tourmaline fine powder, the charcoal fine powder and the ceramic fine powder are integrated. The electron-generated material incorporated in the powder becomes porous, and thus the surface area becomes large, and the contact area between the tolumarin fine powder, the charcoal fine powder and the ceramic fine powder and the atmosphere becomes large.

前記電子生成体による電子生成メカニズムは、基材であるトルマリンはどんなに小さく砕き、粉体にしても常にその結晶状態は一定の形を保ち、その両端に陽極と陰極の電極が発生して、陽極が周辺の大気や液体に存在する電子を引きつけて結晶内に取り入れ、この電子を陰極へ搬送して、該陰極から電子を放出し続けるという電気的特性を有している。 In the electron generation mechanism by the electron generator, no matter how small the base material, tourmarin, is crushed, the crystal state always keeps a constant shape even if it is powdered, and anode and cathode electrodes are generated at both ends of the anode. Has the electrical property of attracting electrons present in the surrounding atmosphere or liquid, incorporating them into the crystal, transporting the electrons to the cathode, and continuing to emit electrons from the cathode.

前記電気特性により電子を放出し続けるトルマリンに、炭素を主成分とする炭が保有する電気的誘導特性、および角閃石および花崗斑岩等のセラミックスが放射する遠赤外線による光感現象が作用して、その両作用の相乗効果により、トルマリンの結晶内に周辺の大気や液体に存在する電子を更に多く引きつけて取り入れ、その分多くの電子を放出すると共に、前記トルマリンが微粉末であるため、前記のように大気や液体との接触面積が大となり、大気からトルマリンが取り入れる電子が多くなり、従って、前記トルマリンから更に多くの電子を多く発生させることができるのである。 Tourmaline, which continues to emit electrons due to the electrical characteristics, is affected by the electrical induction characteristics of carbon-based charcoal and the photosensitizing phenomenon of far infrared rays emitted by ceramics such as amphibole and granite. Due to the synergistic effect of both actions, more electrons existing in the surrounding atmosphere and liquid are attracted and taken into the tourmaline crystal, and more electrons are emitted by that amount, and the tourmaline is a fine powder. As described above, the contact area with the atmosphere or liquid becomes large, and the tourmaline takes in more electrons from the atmosphere. Therefore, more electrons can be generated from the tourmaline.

本発明に係る化粧品は、前記のように製造された電子生成体を使用して生成された水和電子水を使用して製造される。すなわち、本発明において使用する水和電子水は、前記特許第3850645号の図1に示すとほぼ同様に、前記こんにゃくいも成型体を急冷真空乾燥させて水分を除去することにより、こんにゃくいもの繊維質が収縮して強固に絡まり合うと共に、該各繊維質間にトルマリン微粉末、炭微粉末およびセラミックス微粉末が混合した形で取り込まれて一体化されて製造された電子生成体1を水和電子水生成装置2に収納して製造する。前記水和電子水生成装置2に収納される電子生成体1は、前記したように、多数の小球体に形成されている。 The cosmetic product according to the present invention is produced using hydrated electron water produced by using the electron generator produced as described above. That is, the hydrated electronic water used in the present invention is the fiber of konjac by removing water by quenching and vacuum-drying the konjac molded product in substantially the same manner as shown in FIG. 1 of Japanese Patent No. 3850645. The quality shrinks and is tightly entangled, and the electron generator 1 produced by incorporating and integrating tourmaline fine powder, charcoal fine powder and ceramic fine powder in a mixed form between the fibers is hydrated. It is manufactured by storing it in the electronic water generator 2. As described above, the electron generator 1 housed in the hydrated electron water generator 2 is formed into a large number of small spheres.

前記水和電子水生成装置2は、図1に示すように、両端に小径部3・4を一体に備えた円筒体5の、前記小径部3・4内方寄りに通気用小孔6を多数穿設した区画壁7・8をそれぞれ固設して、該区画壁7・8間の空隙部を電子生成体1の収納部9とすると共に、該収納部9の内周壁面には、円周方向に間隔を有して、複数本の環状マグネット10が固着されて形成されている。図中、11は区画壁7・8を保持固定する取り付けボルトである。 As shown in FIG. 1, the hydrated electron water generator 2 has a small hole 6 for ventilation inward of the small diameter portion 3.4 of a cylindrical body 5 integrally provided with small diameter portions 3 and 4 at both ends. A large number of partition walls 7 and 8 are fixedly formed, and the gap between the partition walls 7 and 8 is used as the storage portion 9 of the electron generator 1, and the inner peripheral wall surface of the storage portion 9 is formed. A plurality of annular magnets 10 are fixedly formed with an interval in the circumferential direction. In the figure, reference numeral 11 is a mounting bolt for holding and fixing the partition walls 7 and 8.

そして、前記水和電子水生成装置2の収納部9内に多数の電子生成体1を収納すると共に、一方の小径部3を、連結チューブ12を介してブロア13に連結し、且つ他方の小径部4に送風チューブ14を連結して、該送風チューブ14の先端開口部を水槽15の水16内へ装入する。 Then, a large number of electron generators 1 are housed in the storage portion 9 of the hydrated electron water generator 2, one small diameter portion 3 is connected to the blower 13 via a connecting tube 12, and the other small diameter portion 3 is connected. The blower tube 14 is connected to the portion 4, and the tip opening of the blower tube 14 is charged into the water 16 of the water tank 15.

前記水和電子水生成装置2の送風チューブ14の先端開口部を水槽15の水16内へ装入して、ブロア13を起動して収納部9内に送風すると、空気が小球体に形成された各電子生成体1の表面に接触して乱流して、前記各電子生成体1を構成するトルマリン微粉末を刺激して、該トルマリン微粉末を活性化させ、その両端に発生した陽極と陰極の電極のうち、陽極が周辺の大気や液体に存在する電子を引きつけて結晶内に取り入れ、この電子を陰極へ搬送して、該陰極から電子を放出し続けるという電気的特性により、多孔質の電子生成体1内の孔部分に空気が入り込んで、該空気より電子生成体1を構成するトルマリン微粉末に多くの電子が取り込まれて、電子生成体1から多くの電子が放出されると共に、複数本の環状マグネット10によるローレンツ力の作用により、電子生成体1からの電子の生成の手助けをし、前記電子生成体1から更に多くの電子を放出することができる。 When the tip opening of the blower tube 14 of the hydrated electron water generator 2 is charged into the water 16 of the water tank 15 and the blower 13 is activated to blow air into the storage part 9, air is formed into small spheres. It comes into contact with the surface of each electron generator 1 and turbulently flows to stimulate the tourmaline fine powder constituting each electron generator 1 to activate the tolumarin fine powder, and the anodes generated at both ends thereof. Of the electrodes of the cathode, the anode attracts electrons existing in the surrounding atmosphere and liquid and takes them into the crystal, transports these electrons to the cathode, and continues to emit electrons from the cathode, which makes it porous. Air enters the pore portion of the electron generator 1 and many electrons are taken into the tourmarin fine powder constituting the electron generator 1 from the air, and many electrons are emitted from the electron generator 1 and at the same time. By the action of the Lorentz force by the plurality of annular magnets 10, it is possible to help the generation of electrons from the electron generator 1 and emit more electrons from the electron generator 1.

前記構成より成る水和電子水生成装置2を用いて本発明方法に使用する水和電子水を生成する工程は、前記収納部9内に多数の電子生成体1を収納すると共に、一方の小径部3を連結チューブ12を介してブロア13に連結し、且つ他方の小径部4に送風チューブ14を連結して、該送風チューブ14の先端開口部を水槽15の水16内へ装入し、然る後、前記ブロア13を起動して収納部9内に送風して、送風空気を小球体に形成された各電子生成体1の表面に接触した後、水和電子水生成装置2の他方の小径部4が小径に絞られているため、該小径部4において風速を速めて、前記送風チューブ14を介して強風を水槽15の水16内に噴射し、前記強風が水16内に噴射されることにより、前記水槽15内の水16は乱流混合されて超微細気泡が多数発生して水和電子水が生成されるのである In the step of generating the hydrated electron water used in the method of the present invention by using the hydrated electron water generator 2 having the above configuration, a large number of electron generators 1 are housed in the storage portion 9, and one of the small diameters is stored. The portion 3 is connected to the blower 13 via the connecting tube 12, and the blower tube 14 is connected to the other small diameter portion 4, and the tip opening of the blower tube 14 is charged into the water 16 of the water tank 15. After that, the blower 13 is activated to blow air into the storage portion 9, and after the blown air comes into contact with the surface of each electron generator 1 formed in the small sphere, the other of the hydrated electron water generator 2 Since the small diameter portion 4 of the small diameter portion 4 is narrowed down to a small diameter, the wind speed is increased in the small diameter portion 4, strong wind is jetted into the water 16 of the water tank 15 through the blower tube 14, and the strong wind is jetted into the water 16. As a result, the water 16 in the water tank 15 is turbulently mixed and a large number of ultrafine bubbles are generated to generate hydrated electron water .

本発明者らは、前記特許文献1に記載された方法によって製造される、pH12.0~12.5で、ORP-200~-900mV程度の強電解アルカリ性還元水のうち、pH12.0でORP-750mVの強電解アルカリ性還元水、pH12.0でORP-700mVの強電解アルカリ性還元水、およびpH12.0でORP-600mVの強電解アルカリ性還元水の3種類の強電解アルカリ性還元水に、前記方法によって生成された水和電子水を添加混合する割合を種々変えて製造された3種類の水和電子水混合還元水、並びに比較のため全く水和電子水を添加混合していないpH12.0でORP-800mVの強電解アルカリ性還元水との、それぞれのORP値の経時変化を測定した結果を図2に示す。 The present inventors have a strong electrolytic alkaline reduced water having a pH of 12.0 to 12.5 and an ORP of about -200 to -900 mV, which is produced by the method described in Patent Document 1, and the ORP has a pH of 12.0. The above method is applied to three types of strongly electrolytic alkaline reduced water: -750 mV strong electrolytic alkaline reduced water, ORP-700 mV strong electrolytic alkaline reduced water at pH 12.0, and ORP-600 mV strong electrolytic alkaline reduced water at pH 12.0. Three types of hydrated electron water mixed reduced water produced by changing the ratio of adding and mixing the hydrated electron water generated by, and pH 12.0 without adding and mixing hydrated electron water at all for comparison. FIG. 2 shows the results of measuring the time course of each ORP value with the strongly electrolytic alkaline reduced water of ORP-800 mV.

図2は、平成28年4月26日から同10月23日までのORPの経時変化を示すグラフで、測定開始から終了日までいずれも緩やかにORP値が上昇して行くが、水和水素水の添加混合量が多い程、ORP値の上昇率が緩やかである。すなわち、水和電子水を添加混合していないpH12.0でORP-800mVの強電解アルカリ性還元水(図2のa)は、測定最終日である7ヶ月後にはORPは+270mVまで上昇して、還元機能がなくなった。 FIG. 2 is a graph showing the time course of ORP from April 26, 2016 to October 23, 2016. The ORP value gradually increases from the start to the end of the measurement, but hydrogen hydrated. The larger the amount of water added and mixed, the slower the rate of increase in the ORP value. That is, in the strongly electrolytic alkaline reduced water of ORP-800 mV (a in FIG. 2) at pH 12.0 and not mixed with the addition of hydrated electron water, the ORP increased to +270 mV 7 months after the final measurement day. The reduction function has disappeared.

一方、水和電子水を1重量%添加したpH12.0でORP-600mVの強電解アルカリ性還元水(図2のb)は、測定最終日である7ヶ月後にはORPは+100mVまで上昇して、還元機能がかなり低下したことを確認した。そして、水和電子水を3重量%添加したpH12.0でORP-750mVの強電解アルカリ性還元水(図2のc)は、測定最終日である7ヶ月後にはORPは-50mVまでしか上昇せず、更に、水和電子水を5重量%添加したpH12.0でORP-700mVの強電解アルカリ性還元水(図2のd)は、測定最終日である7ヶ月後にはORPは-100mVまでしか上昇せず、いずれも還元機能を維持していることを確認した。 On the other hand, in the strongly electrolytic alkaline reduced water having an ORP of -600 mV (b in FIG. 2) at pH 12.0 to which 1% by weight of hydrated electron water was added, the ORP increased to +100 mV 7 months after the final measurement day. It was confirmed that the reducing function was considerably reduced. Then, in the strongly electrolytic alkaline reduced water of ORP-750 mV (c in FIG. 2) at pH 12.0 to which 3% by weight of hydrated electron water was added, the ORP increased only to -50 mV 7 months after the final measurement day. Furthermore, the ORP-700 mV strongly electrolytic alkaline reduced water (d in FIG. 2) at pH 12.0 to which 5% by weight of hydrated electron water was added had an ORP of only up to -100 mV 7 months after the final measurement day. It was confirmed that the reduction function was maintained in all cases without increasing.

前記図2の測定結果から、図2のc~dに示すように、水和電子水の添加混合量が多い程、ORP値の上昇を低く抑え、いずれもORP値もマイナス電位を維持し、還元機能を維持していることを確認することができた。そして、前記図2のc~dに示す水和電子水混合還元水のORP値が、少なくとも6ヶ月以上の長期に亘って、-50mVから-200mVのマイナス電位で還元機能を維持できる範囲内にあるのは、前記水和電子水の製造過程において、水中に多数取り込まれた電子が、水中で水に囲まれて水和電子水となっていて、電子の蒸散が押さえられているためであると、本発明者らは推測した。更に、本発明者らは、前記テスト結果から、ORP-200~-550mV程度の強電解アルカリ性還元水であっても、前記水和電子水の添加混合量を多くすれば、ORP値の上昇を低く抑え、いずれもORP値がマイナス電位を維持し、還元機能を長期に亘って維持できると判断した。 From the measurement results of FIG. 2, as shown in c to d of FIG. 2, the larger the amount of the hydrated electron water added, the lower the increase in the ORP value was suppressed, and in each case, the ORP value maintained a negative potential. It was confirmed that the reducing function was maintained. Then, the ORP value of the hydrated electron water mixed reduced water shown in FIGS. 2 to 2 is within a range in which the reducing function can be maintained at a negative potential of -50 mV to −200 mV for a long period of at least 6 months or more. This is because, in the process of producing the hydrated electron water, a large number of electrons taken into the water are surrounded by the water to become hydrated electron water, and the evaporation of the electrons is suppressed. The present inventors speculated. Furthermore, from the above test results, the present inventors have found that even with strongly electrolytic alkaline reduced water having an ORP of about -200 to -550 mV, the ORP value can be increased by increasing the amount of the hydrated electron water added and mixed. It was judged that the ORP value maintained a negative potential and the reducing function could be maintained for a long period of time.

本発明者らは、前記測定結果を得て、複数人の女性に被験者になってもらい、本発明化粧品の製造方法の原料水となる強電解アルカリ性還元水を化粧として素肌に塗布した後の、美肌効果についてのテストを実施した。そのテスト評価表を図3に示した。テストは、図3に示すように、検体として、「1 精製水」および「2 強電解アルカリ性還元水」のみと、「3 強電解アルカリ性還元水+水和電子水1.0重量%添加混合」、「4 強電解アルカリ性還元水+水和電子水3.0重量%添加混合」、「5 強電解アルカリ性還元水+水和電子水5.0重量%添加混合」および「6 強電解アルカリ性還元水+水和電子水10.0重量%添加混合」した還元水を使用してテストした。前記各テストは、素肌に還元水等を塗布してのテストを3回ずつ繰り返して実施した。なお、前記強電解アルカリ性還元水はいずれも、pH12.0でORP-800mVの強電解アルカリ性還元水を使用し、また水和電子水は前記製造方法によって生成された水和電子水を使用した。そして、前記テストに使用した水和電子水混合強電解アルカリ性還元水は、いずれも平成26年4月26日に製造したものを使用し、8ヶ月後の平成26年12月20日にテストを実施した。 After obtaining the above measurement results, the present inventors had a plurality of women as subjects, and applied strongly electrolytic alkaline reduced water, which is the raw material water for the method for producing the cosmetics of the present invention, to the bare skin as cosmetics . We conducted a test on the skin-beautifying effect. The test evaluation table is shown in FIG. As shown in FIG. 3, in the test, as samples, only "1 purified water" and "2 strongly electrolytic alkaline reduced water" and "3 strongly electrolytic alkaline reduced water + 1.0% by weight of hydrated electron water were added and mixed". , "4 strong electrolytic alkaline reduced water + hydrated electron water 3.0% by weight added mixture", "5 strong electrolytic alkaline reduced water + hydrated electron water 5.0% by weight added mixture" and "6 strong electrolytic alkaline reduced water" + 10.0% by weight of hydrated electron water was added and mixed ”reduced water was used for the test. Each of the above tests was carried out by applying reduced water or the like to the bare skin and repeating the test three times each. As the strongly electrolytic alkaline reduced water, the strongly electrolytic alkaline reduced water having a pH of 12.0 and ORP-800 mV was used, and as the hydrated electron water, the hydrated electron water produced by the above-mentioned production method was used. The hydrated electron water mixed strong electrolytic alkaline reduced water used in the test was manufactured on April 26, 2014, and the test was conducted on December 20, 2014, eight months later. Carried out.

前記テストの結果は、図3に示すように、検体「1」と「2」が「評価1」で、シミ、ソバカスや老化等の肌のトラブル防止または回復機能等の美肌効果が劣り、検体「3」が「評価2」で美肌効果がまあまあであり、検体「4」~「6」がいずれも「評価3」で美肌効果が良いという評価であった。前記図3の評価結果から、本発明者らは、原料水である「還元水」に対して図3の検体「4」~「6」の配合比率で添加混合することにより、水和電子水混合強電解アルカリ性還元水の還元機能を長期に亘って維持するするできることを確認した。 As shown in FIG. 3, the test results show that the samples "1" and "2" are "evaluation 1", and the skin-beautifying effect such as prevention or recovery function of skin troubles such as age spots, freckles and aging is inferior. "3" was "evaluation 2" and the skin-beautifying effect was fair, and the samples "4" to "6" were all evaluated as "evaluation 3" and the skin-beautifying effect was good. From the evaluation result of FIG. 3, the present inventors added and mixed the "reduced water" which is the raw material water with the blending ratios of the samples "4" to "6" of FIG. 3 to obtain hydrated electron water. It was confirmed that the reducing function of the mixed strongly electrolytic alkaline reduced water could be maintained for a long period of time.

なお、前記図3においては、「5 強電解アルカリ性還元水+水和電子水5.0重量%添加混合」と「6 強電解アルカリ性還元水+水和電子水10.0重量%添加混合」の間の中間値である「強電解アルカリ性還元水+水和電子水7.5重量%添加混合」のテストを実施していない。前記図3のテスト結果から、前記検体「5」および「6」の美肌効果はいずれも「評価3」であるので、当然、その中間値である「強電解アルカリ性還元水+水和電子水7.5重量%添加混合」は「評価3」であることが予測できるのである。また、図3の評価結果から、水和電子水の添加量5重量%と添加量10重量%の評価はいずれも「評価3」であるので、水和電子水の添加量を多くしても、多くて10重量%までで充分であると判断した。 In addition, in FIG. 3, "5 strong electrolytic alkaline reduced water + 5.0% by weight of hydrated electron water added mixture" and "6 strongly electrolytic alkaline reduced water + 10.0% by weight of hydrated electron water added and mixed". The test of "strongly electrolytic alkaline reduced water + 7.5% by weight of hydrated electron water", which is an intermediate value between them, has not been performed. From the test results of FIG. 3, the skin-beautifying effects of the samples "5" and "6" are all "evaluation 3", so naturally, the intermediate value of "strong electrolytic alkaline reduced water + hydrated electron water 7" is obtained. It can be predicted that "0.5% by weight addition mixture" is "evaluation 3". Further, from the evaluation results of FIG. 3, the evaluation of the addition amount of 5% by weight and the addition amount of 10% by weight is "evaluation 3", so that even if the addition amount of the hydrated electron water is increased. It was judged that a maximum of 10% by weight was sufficient.

本発明者らは、前記図3のテスト結果から、pH12.0程度であって、ORP-200~-900mV程度の強電解アルカリ性還元水に、前記製造方法によって生成された水和電子水3.0~10.0重量%を添加混合して、水和電子水混合強電解アルカリ性還元水を生成し、これを化粧として使用すると、少なくとも6ヶ月程度の長期に亘って美肌効果を維持することができることを確認した。 From the test results of FIG. 3, the present inventors have added hydrated electron water produced by the above-mentioned production method to strongly electrolytic alkaline reduced water having a pH of about 12.0 and an ORP of about -200 to -900 mV. 0 to 10.0% by weight is added and mixed to generate hydrated electron water mixed strong electrolytic alkaline reduced water, and when this is used as cosmetics, the skin-beautifying effect is maintained for a long period of at least about 6 months. I confirmed that I could do it.

なお、図2のcにおいて、pH12.0でORP-700mVの強電解アルカリ性還元水に、水和電子水3.0重量%添加混合した水和電子水混合強電解アルカリ性還元水が長期に亘り還元機能を持続することを記載した。そして、本発明者らは、前記水和水素水3.0重量%より添加混合量の多い、水和電子水3.5重量%をpH12.0でORP-300mVの強電解アルカリ性還元水に添加混合すると共に、更に、活性剤としてヤシ油脂肪酸PEG-7グリセリル2.0重量%を添加混合して、活性剤入り水和電子水混合強電解アルカリ性還元水を生成し、平成28年4月26日から同10月23日までのORPの経時変化を測定し、その結果を図2のeとして示した。すなわち、図2のeに示すように、活性剤入り水和電子水混合強電解アルカリ性還元水のORP値は、測定開始時にORP-300mVであったものが、終了日にはORP-200mVで、わずかに100mV上昇したに過ぎず、前記図2のc~dの水和電子水混合強電解アルカリ性還元水より優れていることが分かった。これは水和電子水の添加混合量が少なくても、前記活性剤を更に添加することにより、洗浄能を長期に亘って維持できるのは、前記ヤシ油脂肪酸PEG-7グリセリルは洗浄剤として知られているが、これを活性剤として使用すると、前記ヤシ油脂肪酸PEG-7グリセリルが浸透性において優れているという特性により、前記水和電子水混合強電解アルカリ性還元水を活性化させ、還元機能を長期に亘って維持できるものであると推測する。なお、前記テストにおけるヤシ油脂肪酸PEG-7グリセリルの添加量は2.0重量%であるが、前記ヤシ油脂肪酸PEG-7グリセリルの添加量を1.0~5.0重量%の範囲内としても、その差は極めて微量であるので、テスト結果に大差はないものと考える。また更に、前記テストにおける水和電子水の添加量は3.5重量%であるが、前記水和電子水の添加量を3.0~5.0重量%の範囲内としても、その差は極めて微量であるので、テスト結果に大差はないものと考える。 In addition, in c of FIG. 2, the hydrated electron water mixed strong electrolytic alkaline reduced water mixed by adding 3.0% by weight of hydrated electron water to the strongly electrolytic alkaline reduced water of ORP-700 mV at pH 12.0 is reduced for a long period of time. Described that the function is sustained. Then, the present inventors added 3.5% by weight of hydrated electron water, which has a larger amount of mixed amount than 3.0% by weight of the hydrated hydrogen water, to the strongly electrolytic alkaline reduced water of ORP-300 mV at pH 12.0. Along with mixing, 2.0% by weight of coconut oil fatty acid PEG-7 glyceryl as an activator was added and mixed to generate hydrated electronic water mixed strongly electrolytic alkaline reduced water containing an activator, and April 26, 2016. The time course of ORP from the day to October 23 was measured, and the result is shown as e in FIG. That is, as shown in FIG. 2e, the ORP value of the strongly electrolytically alkaline reduced water mixed with hydrated electron water containing an activator was ORP-300 mV at the start of measurement, but was ORP-200 mV on the end date. It was found that the increase was only 100 mV, which was superior to the hydrated electron water mixed strong electrolytic alkaline reduced water of FIGS. 2C to 2 above. The coconut oil fatty acid PEG-7 glyceryl is known as a detergency because the detergency can be maintained for a long period of time by further adding the activator even if the mixed amount of hydrated electronic water is small. However, when this is used as an activator, the coconut oil fatty acid PEG-7 glyceryl is excellent in permeability, and thus activates the hydrated electron water mixed strong electrolytic alkaline reduced water and has a reducing function. Is presumed to be able to be maintained for a long period of time. The amount of coconut oil fatty acid PEG-7 glyceryl added in the test was 2.0% by weight, but the amount of coconut oil fatty acid PEG-7 glyceryl added was in the range of 1.0 to 5.0% by weight. However, since the difference is extremely small, it is considered that there is no big difference in the test results. Furthermore, the amount of hydrated electron water added in the test is 3.5% by weight, but even if the amount of hydrated electron water added is in the range of 3.0 to 5.0% by weight, the difference is still large. Since the amount is extremely small, it is considered that there is no big difference in the test results.

そして、前記平成28年4月26日に製造し、8ヶ月後の平成28年12月20日に、前記水和電子水3.5重量%をpH12.0でORP-300mVの強電解アルカリ性還元水に添加混合すると共に、更に、活性剤としてヤシ油脂肪酸PEG-7グリセリル2.0重量%を添加混合して生成された活性剤入り水和電子水混合強電解アルカリ性還元水を使用して、複数人の女性に被験者になってもらい、素肌に前記活性剤入り水和電子水混合強電解アルカリ性還元水を塗布して素肌の美肌効果のテストを実施した。前記テストは、前記活性剤入り水和電子水混合強電解アルカリ性還元水を塗布してのテストを3回ずつ繰り返して実施した。 Then, it was manufactured on April 26, 2016, and on December 20, 2016, eight months later, 3.5% by weight of the hydrated electronic water was reduced to ORP-300 mV with a strong electrolytic alkalinity at pH 12.0. Using hydrated electron water mixture strongly electrolytic alkaline reduced water containing an activator, which was produced by adding and mixing with water and further adding and mixing 2.0% by weight of coconut oil fatty acid PEG-7 glyceryl as an activator, A plurality of women were asked to be subjects, and the skin-beautifying effect of the bare skin was tested by applying the above-mentioned hydrated electron water mixed strong electrolytic alkaline reduced water containing an activator to the bare skin. The test was carried out by applying the hydrated electron water mixed strong electrolytic alkaline reduced water containing the activator and repeating the test three times each.

そして、前記テストに使用した洗浄剤入り水和電子水混合強電解アルカリ性還元水は、平成28年4月26日に製造したものを使用し、8ヶ月後の平成28年12月20日にテストを実施した。前記テストの評価表は図3の「7」に「評価3」として示した。このテスト結果により、活性剤を追加混入しても、長期に亘って美肌効果を維持していることを確認することできた。 The cleaning agent-containing hydrated electron water mixed strong electrolytic alkaline reduced water used in the test was manufactured on April 26, 2016, and was tested on December 20, 2016, eight months later. Was carried out. The evaluation table of the test is shown as "evaluation 3" in "7" of FIG. From this test result, it was confirmed that the skin-beautifying effect was maintained for a long period of time even if the activator was additionally mixed.

なお、前記図3は、活性剤として、ヤシ油脂肪酸PEG-7グリセリル2.0重量%を追加混入しているが、該ヤシ油脂肪酸PEG-7グリセリルと同等の作用を有するラウリルグルコシド2.0重量%を追加混入しても、詳細な説明は省略するが、前記ヤシ油脂肪酸PEG-7グリセリル洗浄剤2.0重量%を追加混入したものと、同一の結果が得られた。前記ラウリルグルコシドは、前記ヤシ油脂肪酸PEG-7グリセリルと同等作用を有するものであり、水和電子水の添加混合量が少なくても、前記ラウリルグルコシドを活性剤として更に添加することにより、美肌効果を長期に亘って維持できるのは、前記ラウリルグルコシドは洗浄剤として知られているが、これを活性剤として使用すると、前記ラウリルグルコシドが浸透性において優れているという特性により、前記水和電子水混合強電解アルカリ性還元水を活性化させ、還元機能を長期に亘って維持できるものであると推測する。なお、前記テストにおけるラウリルグルコシドの添加量は2.0重量%であるが、前記ラウリルグルコシドの添加量を1.0~5.0重量%の範囲内としても、その差は極めて微量であるので、テスト結果に大差はないものと考える。また更に、前記テストにおける水和電子水の添加量は3.5重量%であるが、前記水和電子水の添加量を3.0~5.0重量%の範囲内としても、その差は極めて微量であるので、テスト結果に大差はないものと考える。 In FIG. 3, coconut oil fatty acid PEG-7 glyceryl 2.0% by weight is additionally mixed as an activator, but lauryl glucoside 2.0 having the same action as the coconut oil fatty acid PEG-7 glyceryl 2.0. Although detailed description is omitted even if the weight% is additionally mixed, the same result as that in which 2.0% by weight of the coconut oil fatty acid PEG-7 glyceryl cleaning agent is additionally mixed is obtained. The lauryl glucoside has the same effect as the coconut oil fatty acid PEG-7 glyceryl, and even if the amount of hydrated electron water added is small, the lauryl glucoside can be further added as an activator to have a skin-beautifying effect. The lauryl glucoside is known as a cleaning agent, but when it is used as an activator, the lauryl glucoside is excellent in permeability, so that the hydrated electron water can be maintained for a long period of time. It is presumed that the mixed strong electrolytic alkaline reduced water can be activated and the reducing function can be maintained for a long period of time. The amount of lauryl glucoside added in the test is 2.0% by weight, but even if the amount of lauryl glucoside added is in the range of 1.0 to 5.0% by weight, the difference is extremely small. , I think there is no big difference in the test results. Furthermore, the amount of hydrated electron water added in the test is 3.5% by weight, but even if the amount of hydrated electron water added is in the range of 3.0 to 5.0% by weight, the difference is still large. Since the amount is extremely small, it is considered that there is no big difference in the test results.

前記活性剤は、光洋ファインケミカル株式会社製の商品名「ハイバーオイルHE」(商品の一般名称は、「ヤシ油脂肪酸PEG-7グリセル」で、浸透性において優れ、メイク落とし洗浄剤として使用されている)、および花王株式会社製の「マイドール12」(商品の一般名称は、「ラウリルグルコシド」で、浸透性において優れ、メイク落とし洗浄剤として使用されている)を使用した。また、前記テストは、前記活性剤入り水和電子水混合強電解アルカリ性還元水を素肌に塗布してのテストを3回ずつ繰り返して実施した。なお、前記水和電子水3.5重量%をpH12.0でORP-300mVの強電解アルカリ性還元水に添加混合すると共に、更に、活性剤としてヤシ油脂肪酸PEG-7グリセル2.0重量%を添加混合して生成された活性剤入り水和電子水混合強電解アルカリ性還元水を使用した。 The activator is the trade name "Hiber Oil HE" manufactured by Koyo Fine Chemical Co., Ltd. (The general name of the product is "Palm oil fatty acid PEG-7 glycer", which has excellent permeability and is used as a makeup remover detergent. ), And "My Doll 12" manufactured by Kao Co., Ltd. (the general name of the product is "lauryl glucoside", which has excellent permeability and is used as a makeup remover). In addition, the test was carried out by applying the hydrated electron water mixed strong electrolytic alkaline reduced water containing the activator to the bare skin and repeating the test three times each. In addition, 3.5% by weight of the hydrated electronic water was added and mixed with strongly electrolytic alkaline reduced water of ORP-300mV at pH 12.0, and 2.0% by weight of coconut oil fatty acid PEG-7 glycel was further added as an activator. A hydrated electron water mixture containing an activator, which was produced by addition and mixing, was used as a strongly electrolytic alkaline reduced water.

そして、前記図2・図3において、pH値が12.0の強電解アルカリ性還元水を使用して測定およびテストをし、pH値が12.5の強電解アルカリ性還元水を使用しての測定およびテストをしていないが、pH値が0.5上がるだけなので、前記図2・図3の示す測定およびテスト結果とほぼ同様の測定値およびテスト結果が得られるえられるものと推測する。 Then, in FIGS. 2 and 3, measurements and tests were performed using strongly electrolytic alkaline reduced water having a pH value of 12.0, and measurement using strongly electrolytic alkaline reduced water having a pH value of 12.5. And although it has not been tested, since the pH value only increases by 0.5, it is presumed that almost the same measured values and test results as those shown in FIGS. 2 and 3 can be obtained.

前記各テストの結果、強電解アルカリ性還元水に、水和電子水を添加混合、または前記水和電子水と活性剤とを添加混合した強電解アルカリ性還元水を素肌に塗布することにより、ORPが-50mV以下のマイナス電位を持続して、少なくとも6ヶ月以上の長期に亘って美肌効果を維持せしめることを確認できたので、前記pH12.0~12.5程度で、且つORP-200~-900mV程度の強電解アルカリ性還元水に、水和電子水を添加混合、または前記水和電子水と活性剤とを添加混合した強電解アルカリ性還元水を、原料水としてローションやクリーム等の化粧品に添加混合して、化粧品として使用すると、その化粧品は、シミ、ソバカスや老化等の肌のトラブルを防止または回復機能等の美肌効果を長期に亘って維持することができるものであると判断する。 As a result of each of the above tests, ORP can be obtained by adding and mixing hydrated electronic water to strongly electrolytic alkaline reduced water, or by applying strongly electrolytic alkaline reduced water in which the hydrated electronic water and an activator are added and mixed to the bare skin. Since it was confirmed that the negative potential of -50 mV or less was maintained and the skin-beautifying effect was maintained for a long period of at least 6 months or more, the pH was about 12.0 to 12.5 and ORP-200 to -900 mV. Cosmetics such as lotions and creams using strongly electrolytic alkaline reduced water obtained by adding and mixing hydrated electron water to a degree of strongly electrolytic alkaline reduced water or adding and mixing the hydrated electron water and an activator as raw material water. When used as a cosmetic by adding and mixing with water, the cosmetic can prevent skin troubles such as spots, buckwheat and aging, or maintain a skin-beautifying effect such as a recovery function for a long period of time. to decide.

Claims (2)

第1の基材であるこんにゃくいもの精粉を水に投入して混合攪拌して、前記こんにゃくいもの精粉を水に溶かし、粘着性が出るまで攪拌作業を続けて、粘着性を有するこんにゃくいも溶液とし、且つ該粘着性を有するこんにゃくいも溶液に、該こんにゃくいも溶液の重量に対して、第2の基材であるトルマリン微粉末30重量%および第3の基材である炭微粉末30重量%をそれぞれ混入すると共に、添加材として角閃石、花崗斑岩等の遠赤外線放射特性を有するセラミックス微粉末5重量%を添加混入して混合攪拌し、且つ前記基材および添加材の混合溶液に、固化材として3重量%の炭酸ナトリウムを混入し、これを熱湯で溶かして半固化せしめて小球体状成型体とし、且つ前記成型体を熱湯に投入して約1~3時間程度煮沸して、該成型体をこんにゃく程度の硬さまで固化せしめた後、該成型体を熱湯から取り出して、-100℃程度で急冷凍し、然る後、前記急冷凍した成型体を40℃程度で真空乾燥させて、前記成型体より水分を除去することにより小球体状の電子生成体を製造する一方、
両端に小径部を備えた円筒体に、通気用小孔を多数穿設した区画壁をそれぞれ固設して、該区画壁間の空隙部を前記電子生成体の収納部とすると共に、該収納部の内周壁面に円周方向に間隔を有して、複数本の環状マグネットを固着して水和電子水生成装置が形成され、
更に、前記水和電子水生成装置の収納部内に前記多数の電子生成体を収納すると共に、一方の小径部を連結チューブを介してブロアに連結し、且つ他方の小径部に送風チューブを連結して、該送風チューブの先端開口部を水槽の水内へ装入し、前記ブロアを起動して収納部内に送風して、送風空気小球体に形成された各電子生成体の表面に接触した後、水和電子水生成装置の他方の小径部において風速を速めて前記送風チューブを介して強風を水槽の水内に噴射し、前記強風が水内に噴射されることにより、前記水槽内の水は乱流混合されて超微細気泡が多数発生して、水和電子水が生成される一方、
室型電解槽を用いて純水を電気分解して得られた還元水であって、生成時におけるpHが12.0~12.5程度であり、且つORPが-200~-900mV程度の強電解アルカリ性還元水に、該強電解アルカリ性還元水の重量に対して、前記生成された水和電子水3~10重量%を添加混合することを特徴とする還元機能を長期維持せしめた強電解アルカリ性還元水を原料水とする化粧品の製造方法。
The konjac powder, which is the first base material, is put into water and mixed and stirred to dissolve the konjac powder in water, and the stirring work is continued until the powder becomes sticky. 30% by weight of tolumarin fine powder, which is the second base material, and charcoal fine powder, which is the third base material, with respect to the weight of the konnyakuimo solution, which is made into a potato solution and has the adhesiveness . In addition to mixing 30% by weight, 5% by weight of fine ceramic powder having far-infrared radiation characteristics such as horn flash stone and granulated rock is added and mixed as an additive, and the mixture is stirred and mixed, and the base material and the additive material are mixed. 3% by weight of sodium carbonate is mixed with the mixed solution as a solidifying material, and this is melted in boiling water to semi-solidify to form a small spherical molded body, and the molded body is put into boiling water for about 1 to 3 hours. After boiling to solidify the molded product to a hardness of about konjac, the molded product is taken out from boiling water and rapidly frozen at about -100 ° C., and then the rapidly frozen molded product is rapidly frozen at about 40 ° C. While vacuum-drying with the above-mentioned molded body to remove water from the molded body, a small spherical electron generator is produced.
A partition wall having a large number of small holes for ventilation is fixed to a cylindrical body having small diameter portions at both ends, and the gap between the partition walls is used as a storage portion for the electron generator and the storage portion. A hydrated electron water generator is formed by fixing a plurality of annular magnets to the inner peripheral wall surface of the portion at intervals in the circumferential direction.
Further, the large number of electron generators are housed in the storage portion of the hydrated electron water generator, one small diameter portion is connected to the blower via a connecting tube, and the blower tube is connected to the other small diameter portion. Then, the tip opening of the blower tube is charged into the water of the water tank, the blower is activated and blown into the storage part, and the blown air comes into contact with the surface of each electron generator formed in the small sphere. After that, in the other small diameter portion of the hydrated electron water generator, the wind speed is increased and a strong wind is jetted into the water of the water tank through the blower tube, and the strong wind is jetted into the water. While the water in the water tank is turbulently mixed and a large number of ultrafine bubbles are generated , hydrated electron water is generated.
Reduced water obtained by electrolyzing pure water using a 3 -chamber type electrolytic tank, having a pH of about 12.0 to 12.5 at the time of production and an ORP of about -200 to -900 mV. Strong electrolysis characterized by adding and mixing 3 to 10% by weight of the generated hydrated electron water with respect to the weight of the strongly electrolytic alkaline reduced water to the strongly electrolytic alkaline reduced water for a long period of time. A method for manufacturing cosmetics using alkaline reduced water as a raw material.
第1の基材であるこんにゃくいもの精粉を水に投入して混合攪拌して、前記こんにゃくいもの精粉を水に溶かし、粘着性が出るまで攪拌作業を続けて、粘着性を有するこんにゃくいも溶液とし、且つ該粘着性を有するこんにゃくいも溶液に、該こんにゃくいも溶液の重量に対して、第2の基材であるトルマリン微粉末30重量%および第3の基材である炭微粉末30重量%をそれぞれ混入すると共に、添加材として角閃石、花崗斑岩等の遠赤外線放射特性を有するセラミックス微粉末5重量%を添加混入して混合攪拌し、且つ前記基材および添加材の混合溶液に、固化材として3重量%の炭酸ナトリウムを混入し、これを熱湯で溶かして半固化せしめて小球体状成型体とし、且つ前記成型体を熱湯に投入して約1~3時間程度煮沸して、該成型体をこんにゃく程度の硬さまで固化せしめた後、該成型体を熱湯から取り出して、-100℃程度で急冷凍し、然る後、前記急冷凍した成型体を40℃程度で真空乾燥させて、前記成型体より水分を除去することにより小球体状の電子生成体を製造する一方、
両端に小径部を備えた円筒体に、通気用小孔を多数穿設した区画壁をそれぞれ固設して、該区画壁間の空隙部を前記電子生成体の収納部とすると共に、該収納部の内周壁面に円周方向に間隔を有して、複数本の環状マグネットを固着して水和電子水生成装置が形成され、
更に、前記水和電子水生成装置の収納部内に前記多数の電子生成体を収納すると共に、一方の小径部を連結チューブを介してブロアに連結し、且つ他方の小径部に送風チューブを連結して、該送風チューブの先端開口部を水槽の水内へ装入し、前記ブロアを起動して収納部内に送風して、送風空気小球体に形成された各電子生成体の表面に接触した後、水和電子水生成装置の他方の小径部において風速を速めて前記送風チューブを介して強風を水槽の水内に噴射し、前記強風が水内に噴射されることにより、前記水槽内の水は乱流混合されて超微細気泡が多数発生して、水和電子水が生成される一方、
室型電解槽を用いて純水を電気分解して得られた還元水であって、生成時におけるpHが12.0~12.5程度であり、且つORPが-200~-900mV程度の強電解アルカリ性還元水に、該強電解アルカリ性還元水の重量に対して、前記生成された水和電子水3.5重量%と、活性剤としてヤシ油脂肪酸PEG-7グリセリル1.0~5.0重量%、またはラウリルグルコシド1.0~5.0重量%のいずれかを添加混合することを特徴とする還元機能を長期維持せしめた強電解アルカリ性還元水を原料水とする化粧品の製造方法。
The konjac powder, which is the first base material, is put into water and mixed and stirred to dissolve the konjac powder in water, and the stirring work is continued until the powder becomes sticky. 30% by weight of tolumarin fine powder, which is the second base material, and charcoal fine powder, which is the third base material, with respect to the weight of the konnyakuimo solution, which is made into a potato solution and has the adhesiveness . In addition to mixing 30% by weight, 5% by weight of fine ceramic powder having far-infrared radiation characteristics such as horn flash stone and granulated rock is added and mixed as an additive, and the mixture is stirred and mixed, and the base material and the additive material are mixed. 3% by weight of sodium carbonate is mixed with the mixed solution as a solidifying material, and this is melted in boiling water to semi-solidify to form a small spherical molded body, and the molded body is put into boiling water for about 1 to 3 hours. After boiling to solidify the molded product to a hardness of about konjac, the molded product is taken out from boiling water and rapidly frozen at about -100 ° C., and then the rapidly frozen molded product is rapidly frozen at about 40 ° C. While vacuum-drying with the above-mentioned molded body to remove water from the molded body, a small spherical electron generator is produced.
A partition wall having a large number of small holes for ventilation is fixed to a cylindrical body having small diameter portions at both ends, and the gap between the partition walls is used as a storage portion for the electron generator and the storage portion. A hydrated electron water generator is formed by fixing a plurality of annular magnets to the inner peripheral wall surface of the portion at intervals in the circumferential direction.
Further, the large number of electron generators are housed in the storage portion of the hydrated electron water generator, one small diameter portion is connected to the blower via a connecting tube, and the blower tube is connected to the other small diameter portion. Then, the tip opening of the blower tube is charged into the water of the water tank, the blower is activated and blown into the storage part, and the blown air comes into contact with the surface of each electron generator formed in the small sphere. After that, in the other small diameter portion of the hydrated electron water generator, the wind speed is increased and a strong wind is jetted into the water of the water tank through the blower tube, and the strong wind is jetted into the water. While the water in the water tank is turbulently mixed and a large number of ultrafine bubbles are generated , hydrated electron water is generated.
Reduced water obtained by electrolyzing pure water using a 3 -chamber type electrolytic tank, having a pH of about 12.0 to 12.5 at the time of production and an ORP of about -200 to -900 mV. In the strongly electrolytic alkaline reduced water, 3.5% by weight of the generated hydrated electron water and the coconut oil fatty acid PEG-7 glyceryl 1.0 to 5. as an activator with respect to the weight of the strongly electrolytic alkaline reduced water. A method for producing cosmetics using strongly electrolytic alkaline reduced water as a raw material water, which maintains a reducing function for a long period of time, which is characterized by adding and mixing either 0% by weight or 1.0 to 5.0% by weight of lauryl glucoside. ..
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JP2002065835A (en) 2000-08-25 2002-03-05 Kunio Fukuda Method for producing negative ion generator
JP2002069497A (en) 2000-08-31 2002-03-08 Kunio Fukuda Method of manufacturing detergent and negative ion generator used in above method
JP2002348208A (en) 2001-05-25 2002-12-04 Shoji Kubota Skin lotion or cosmetic each using a reduced water
JP2004131387A (en) 2002-10-08 2004-04-30 Shigemi Sawada Liquid for removing makeup
JP2006225273A (en) 2005-02-15 2006-08-31 Natural:Kk Method for producing face washing agent using ionized alkaline water

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2002065835A (en) 2000-08-25 2002-03-05 Kunio Fukuda Method for producing negative ion generator
JP2002069497A (en) 2000-08-31 2002-03-08 Kunio Fukuda Method of manufacturing detergent and negative ion generator used in above method
JP2002348208A (en) 2001-05-25 2002-12-04 Shoji Kubota Skin lotion or cosmetic each using a reduced water
JP2004131387A (en) 2002-10-08 2004-04-30 Shigemi Sawada Liquid for removing makeup
JP2006225273A (en) 2005-02-15 2006-08-31 Natural:Kk Method for producing face washing agent using ionized alkaline water

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