JP4155863B2 - Hair rinse composition - Google Patents
Hair rinse composition Download PDFInfo
- Publication number
- JP4155863B2 JP4155863B2 JP2003122042A JP2003122042A JP4155863B2 JP 4155863 B2 JP4155863 B2 JP 4155863B2 JP 2003122042 A JP2003122042 A JP 2003122042A JP 2003122042 A JP2003122042 A JP 2003122042A JP 4155863 B2 JP4155863 B2 JP 4155863B2
- Authority
- JP
- Japan
- Prior art keywords
- acid
- hair
- oil
- poe
- sodium
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
- 239000000203 mixture Substances 0.000 title claims description 42
- 239000002253 acid Substances 0.000 claims description 14
- 206010020649 Hyperkeratosis Diseases 0.000 claims description 12
- 150000001875 compounds Chemical class 0.000 claims description 12
- 150000003242 quaternary ammonium salts Chemical class 0.000 claims description 9
- 125000004432 carbon atom Chemical group C* 0.000 claims description 8
- 239000007788 liquid Substances 0.000 claims description 8
- 239000000126 substance Substances 0.000 claims description 8
- 150000002148 esters Chemical class 0.000 claims description 6
- 239000004094 surface-active agent Substances 0.000 claims description 6
- 125000000217 alkyl group Chemical group 0.000 claims description 5
- 125000001841 imino group Chemical group [H]N=* 0.000 claims description 5
- 125000005702 oxyalkylene group Chemical group 0.000 claims description 2
- 125000005313 fatty acid group Chemical group 0.000 claims 1
- -1 alkyl ether compounds Chemical class 0.000 description 41
- 229920003171 Poly (ethylene oxide) Polymers 0.000 description 36
- 235000014113 dietary fatty acids Nutrition 0.000 description 28
- 239000000194 fatty acid Substances 0.000 description 28
- 229930195729 fatty acid Natural products 0.000 description 28
- 239000000654 additive Substances 0.000 description 24
- 230000000996 additive effect Effects 0.000 description 23
- 239000003921 oil Substances 0.000 description 21
- 235000019198 oils Nutrition 0.000 description 21
- 150000004665 fatty acids Chemical group 0.000 description 18
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 12
- 230000000694 effects Effects 0.000 description 12
- 235000002639 sodium chloride Nutrition 0.000 description 12
- 150000003839 salts Chemical class 0.000 description 9
- 238000011156 evaluation Methods 0.000 description 8
- 239000002280 amphoteric surfactant Substances 0.000 description 7
- 235000019441 ethanol Nutrition 0.000 description 7
- 238000002156 mixing Methods 0.000 description 7
- 239000011734 sodium Substances 0.000 description 7
- 229910052708 sodium Inorganic materials 0.000 description 7
- VBICKXHEKHSIBG-UHFFFAOYSA-N 1-monostearoylglycerol Chemical compound CCCCCCCCCCCCCCCCCC(=O)OCC(O)CO VBICKXHEKHSIBG-UHFFFAOYSA-N 0.000 description 6
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 6
- WYURNTSHIVDZCO-UHFFFAOYSA-N Tetrahydrofuran Chemical compound C1CCOC1 WYURNTSHIVDZCO-UHFFFAOYSA-N 0.000 description 6
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 description 6
- POULHZVOKOAJMA-UHFFFAOYSA-N dodecanoic acid Chemical compound CCCCCCCCCCCC(O)=O POULHZVOKOAJMA-UHFFFAOYSA-N 0.000 description 6
- 238000001035 drying Methods 0.000 description 6
- KWIUHFFTVRNATP-UHFFFAOYSA-N Betaine Natural products C[N+](C)(C)CC([O-])=O KWIUHFFTVRNATP-UHFFFAOYSA-N 0.000 description 5
- 244000060011 Cocos nucifera Species 0.000 description 5
- 235000013162 Cocos nucifera Nutrition 0.000 description 5
- 108010076876 Keratins Proteins 0.000 description 5
- 102000011782 Keratins Human genes 0.000 description 5
- KWIUHFFTVRNATP-UHFFFAOYSA-O N,N,N-trimethylglycinium Chemical compound C[N+](C)(C)CC(O)=O KWIUHFFTVRNATP-UHFFFAOYSA-O 0.000 description 5
- 239000002202 Polyethylene glycol Substances 0.000 description 5
- 230000003078 antioxidant effect Effects 0.000 description 5
- 229960003237 betaine Drugs 0.000 description 5
- LYCAIKOWRPUZTN-UHFFFAOYSA-N ethylene glycol Natural products OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 5
- 229920001223 polyethylene glycol Polymers 0.000 description 5
- 238000003756 stirring Methods 0.000 description 5
- 238000005406 washing Methods 0.000 description 5
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 5
- NOOLISFMXDJSKH-KXUCPTDWSA-N (-)-Menthol Chemical compound CC(C)[C@@H]1CC[C@@H](C)C[C@H]1O NOOLISFMXDJSKH-KXUCPTDWSA-N 0.000 description 4
- GVJHHUAWPYXKBD-UHFFFAOYSA-N (±)-α-Tocopherol Chemical compound OC1=C(C)C(C)=C2OC(CCCC(C)CCCC(C)CCCC(C)C)(C)CCC2=C1C GVJHHUAWPYXKBD-UHFFFAOYSA-N 0.000 description 4
- CIWBSHSKHKDKBQ-JLAZNSOCSA-N Ascorbic acid Chemical compound OC[C@H](O)[C@H]1OC(=O)C(O)=C1O CIWBSHSKHKDKBQ-JLAZNSOCSA-N 0.000 description 4
- NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 description 4
- 229920001214 Polysorbate 60 Polymers 0.000 description 4
- FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 description 4
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 4
- 235000001014 amino acid Nutrition 0.000 description 4
- 239000003963 antioxidant agent Substances 0.000 description 4
- 235000006708 antioxidants Nutrition 0.000 description 4
- 238000006243 chemical reaction Methods 0.000 description 4
- 239000003795 chemical substances by application Substances 0.000 description 4
- 239000003240 coconut oil Substances 0.000 description 4
- 235000019864 coconut oil Nutrition 0.000 description 4
- RTZKZFJDLAIYFH-UHFFFAOYSA-N ether Substances CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 4
- PCNAKWUTWPAVMZ-UHFFFAOYSA-N 2-[carboxymethyl(dodecanoyl)amino]acetic acid Chemical compound CCCCCCCCCCCC(=O)N(CC(O)=O)CC(O)=O PCNAKWUTWPAVMZ-UHFFFAOYSA-N 0.000 description 3
- FBPFZTCFMRRESA-JGWLITMVSA-N D-glucitol Chemical compound OC[C@H](O)[C@@H](O)[C@H](O)[C@H](O)CO FBPFZTCFMRRESA-JGWLITMVSA-N 0.000 description 3
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerol Natural products OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 3
- BIVBRWYINDPWKA-VLQRKCJKSA-L Glycyrrhizinate dipotassium Chemical compound [K+].[K+].O([C@@H]1[C@@H](O)[C@H](O)[C@H](O[C@@H]1O[C@H]1CC[C@]2(C)[C@H]3C(=O)C=C4[C@@H]5C[C@](C)(CC[C@@]5(CC[C@@]4(C)[C@]3(C)CC[C@H]2C1(C)C)C)C(O)=O)C([O-])=O)[C@@H]1O[C@H](C([O-])=O)[C@@H](O)[C@H](O)[C@H]1O BIVBRWYINDPWKA-VLQRKCJKSA-L 0.000 description 3
- 239000005639 Lauric acid Substances 0.000 description 3
- 229910019142 PO4 Inorganic materials 0.000 description 3
- DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 description 3
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 3
- ZMANZCXQSJIPKH-UHFFFAOYSA-N Triethylamine Chemical compound CCN(CC)CC ZMANZCXQSJIPKH-UHFFFAOYSA-N 0.000 description 3
- 150000001412 amines Chemical class 0.000 description 3
- 150000001413 amino acids Chemical class 0.000 description 3
- 230000015572 biosynthetic process Effects 0.000 description 3
- 230000000052 comparative effect Effects 0.000 description 3
- 239000002537 cosmetic Substances 0.000 description 3
- MTHSVFCYNBDYFN-UHFFFAOYSA-N diethylene glycol Chemical compound OCCOCCO MTHSVFCYNBDYFN-UHFFFAOYSA-N 0.000 description 3
- 229940101029 dipotassium glycyrrhizinate Drugs 0.000 description 3
- 239000000839 emulsion Substances 0.000 description 3
- 239000003205 fragrance Substances 0.000 description 3
- 229940075507 glyceryl monostearate Drugs 0.000 description 3
- 230000006872 improvement Effects 0.000 description 3
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 3
- 239000001788 mono and diglycerides of fatty acids Substances 0.000 description 3
- 239000010452 phosphate Substances 0.000 description 3
- 108090000765 processed proteins & peptides Proteins 0.000 description 3
- 239000008213 purified water Substances 0.000 description 3
- 239000000344 soap Substances 0.000 description 3
- 239000000243 solution Substances 0.000 description 3
- 238000003786 synthesis reaction Methods 0.000 description 3
- YLQBMQCUIZJEEH-UHFFFAOYSA-N tetrahydrofuran Natural products C=1C=COC=1 YLQBMQCUIZJEEH-UHFFFAOYSA-N 0.000 description 3
- 239000002562 thickening agent Substances 0.000 description 3
- 235000019165 vitamin E Nutrition 0.000 description 3
- 239000011709 vitamin E Substances 0.000 description 3
- YBJHBAHKTGYVGT-ZKWXMUAHSA-N (+)-Biotin Chemical compound N1C(=O)N[C@@H]2[C@H](CCCCC(=O)O)SC[C@@H]21 YBJHBAHKTGYVGT-ZKWXMUAHSA-N 0.000 description 2
- PUPZLCDOIYMWBV-UHFFFAOYSA-N (+/-)-1,3-Butanediol Chemical compound CC(O)CCO PUPZLCDOIYMWBV-UHFFFAOYSA-N 0.000 description 2
- GHOKWGTUZJEAQD-ZETCQYMHSA-N (D)-(+)-Pantothenic acid Chemical compound OCC(C)(C)[C@@H](O)C(=O)NCCC(O)=O GHOKWGTUZJEAQD-ZETCQYMHSA-N 0.000 description 2
- FDCJDKXCCYFOCV-UHFFFAOYSA-N 1-hexadecoxyhexadecane Chemical compound CCCCCCCCCCCCCCCCOCCCCCCCCCCCCCCCC FDCJDKXCCYFOCV-UHFFFAOYSA-N 0.000 description 2
- MPDGHEJMBKOTSU-YKLVYJNSSA-N 18beta-glycyrrhetic acid Chemical compound C([C@H]1C2=CC(=O)[C@H]34)[C@@](C)(C(O)=O)CC[C@]1(C)CC[C@@]2(C)[C@]4(C)CC[C@@H]1[C@]3(C)CC[C@H](O)C1(C)C MPDGHEJMBKOTSU-YKLVYJNSSA-N 0.000 description 2
- SPSPIUSUWPLVKD-UHFFFAOYSA-N 2,3-dibutyl-6-methylphenol Chemical compound CCCCC1=CC=C(C)C(O)=C1CCCC SPSPIUSUWPLVKD-UHFFFAOYSA-N 0.000 description 2
- ASKIVFGGGGIGKH-UHFFFAOYSA-N 2,3-dihydroxypropyl 16-methylheptadecanoate Chemical compound CC(C)CCCCCCCCCCCCCCC(=O)OCC(O)CO ASKIVFGGGGIGKH-UHFFFAOYSA-N 0.000 description 2
- ALYNCZNDIQEVRV-UHFFFAOYSA-N 4-aminobenzoic acid Chemical compound NC1=CC=C(C(O)=O)C=C1 ALYNCZNDIQEVRV-UHFFFAOYSA-N 0.000 description 2
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 2
- RGHNJXZEOKUKBD-SQOUGZDYSA-N D-gluconic acid Chemical compound OC[C@@H](O)[C@@H](O)[C@H](O)[C@@H](O)C(O)=O RGHNJXZEOKUKBD-SQOUGZDYSA-N 0.000 description 2
- 208000001840 Dandruff Diseases 0.000 description 2
- 241000272185 Falco Species 0.000 description 2
- DHMQDGOQFOQNFH-UHFFFAOYSA-N Glycine Chemical compound NCC(O)=O DHMQDGOQFOQNFH-UHFFFAOYSA-N 0.000 description 2
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 2
- 208000007976 Ketosis Diseases 0.000 description 2
- 239000004166 Lanolin Substances 0.000 description 2
- QZXSMBBFBXPQHI-UHFFFAOYSA-N N-(dodecanoyl)ethanolamine Chemical compound CCCCCCCCCCCC(=O)NCCO QZXSMBBFBXPQHI-UHFFFAOYSA-N 0.000 description 2
- 239000004372 Polyvinyl alcohol Substances 0.000 description 2
- KEAYESYHFKHZAL-UHFFFAOYSA-N Sodium Chemical compound [Na] KEAYESYHFKHZAL-UHFFFAOYSA-N 0.000 description 2
- PMZURENOXWZQFD-UHFFFAOYSA-L Sodium Sulfate Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=O PMZURENOXWZQFD-UHFFFAOYSA-L 0.000 description 2
- DBMJMQXJHONAFJ-UHFFFAOYSA-M Sodium laurylsulphate Chemical compound [Na+].CCCCCCCCCCCCOS([O-])(=O)=O DBMJMQXJHONAFJ-UHFFFAOYSA-M 0.000 description 2
- 229920002125 Sokalan® Polymers 0.000 description 2
- 229920002472 Starch Polymers 0.000 description 2
- VBIIFPGSPJYLRR-UHFFFAOYSA-M Stearyltrimethylammonium chloride Chemical compound [Cl-].CCCCCCCCCCCCCCCCCC[N+](C)(C)C VBIIFPGSPJYLRR-UHFFFAOYSA-M 0.000 description 2
- ULUAUXLGCMPNKK-UHFFFAOYSA-N Sulfobutanedioic acid Chemical class OC(=O)CC(C(O)=O)S(O)(=O)=O ULUAUXLGCMPNKK-UHFFFAOYSA-N 0.000 description 2
- 229930003427 Vitamin E Natural products 0.000 description 2
- 239000006096 absorbing agent Substances 0.000 description 2
- 150000005215 alkyl ethers Chemical class 0.000 description 2
- POJWUDADGALRAB-UHFFFAOYSA-N allantoin Chemical compound NC(=O)NC1NC(=O)NC1=O POJWUDADGALRAB-UHFFFAOYSA-N 0.000 description 2
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- 229910000147 aluminium phosphate Inorganic materials 0.000 description 2
- 125000000129 anionic group Chemical group 0.000 description 2
- 229940121363 anti-inflammatory agent Drugs 0.000 description 2
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- CUFNKYGDVFVPHO-UHFFFAOYSA-N azulene Chemical compound C1=CC=CC2=CC=CC2=C1 CUFNKYGDVFVPHO-UHFFFAOYSA-N 0.000 description 2
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- REZZEXDLIUJMMS-UHFFFAOYSA-M dimethyldioctadecylammonium chloride Chemical compound [Cl-].CCCCCCCCCCCCCCCCCC[N+](C)(C)CCCCCCCCCCCCCCCCCC REZZEXDLIUJMMS-UHFFFAOYSA-M 0.000 description 2
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- VAMXMNNIEUEQDV-UHFFFAOYSA-N methyl anthranilate Chemical compound COC(=O)C1=CC=CC=C1N VAMXMNNIEUEQDV-UHFFFAOYSA-N 0.000 description 2
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Landscapes
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Description
【０００１】
【発明の属する技術分野】
本発明はヘアリンス組成物に関し、更に詳しく述べるならば、乾燥後の毛髪の光沢性及び、艶に優れ、櫛どおりを滑らかにする効果を有するヘアリンス組成物に関するものである。
【０００２】
【従来の技術】
毛髪は、絶えず外部からの刺激にさらされ、毛髪・頭皮に付着した汚れを除去することを目的に行われる洗髪行為も、毛髪に物理的刺激を与えるので、その実施方法が不適切であると、毛髪を傷つけることがある。特に洗髪後のブラッシング等によって生ずる毛髪の損傷の軽減化に関しては、様々な技術が開示され種々の工夫がなされてきたが、いまだ十分な解決法が見出されていない。
【０００３】
たとえば、特開昭６０−１２３４１２号報（特許文献１）には、第四級アンモニウム塩及びアミノ酸系等のカチオン界面活性剤と、２５℃の水に対する溶解度が１重量％以下であり、かつ２５℃における粘度が１〜１０００センチストークスの疎水性シリコーンと、ケラチン物質分解誘導体及びカチオン化ケラチン化合物誘導体から選ばれるケラチン誘導体を含有する毛髪化粧料組成物が開示されており、この組成物は、毛髪の滑らかさを向上させ、毛先のぱさつきを防ぐ効果を有することが開示されている。しかしながら、その効果は不十分であって一層の改善が求められていた。
【０００４】
特開平１０−７７２１０号報（特許文献２）には、毛髪の曲げ弾性を向上させ、保湿性、抗酸化性等の機能の高いα−ケトース、又はγ−ケトースの４級化物が開示されている。この化合物は従来のカチオン化ペプチドに比較して、優れた毛髪吸着並びに保護効果を有するが、しかし、その効果は未だ十分ではなく、一層の改善が求められていた。
特開２０００−２４７８４２号公報（特許文献３）及び特開２０００−２４７８４４号公報（特許文献４）には、第４級アンモニウム塩によりカチオン化されたケラトースが記載されている。しかし、これらの特許文献には本発明で用いられる特定油溶性Ｎ−アシルアミノ酸ポリオキシアルキレンアルキルエーテル化合物類との併用によるリンス効果の向上について全く開示がなく、かつ、上記特許文献に記載されているカチオン化ケラトースによるリンス効果は、満足できるものではなかった。
【０００５】
技術文献
【特許文献１】
特開昭６０−１２３４１２号公報、第１〜２頁
【特許文献２】
特開平１０−７７２１０号公報、第２〜３頁
【特許文献３】
特開２０００−２４７８４２号公報、第１頁及び第６〜８頁
【特許文献４】
特開２０００−２４７８４４号公報、第１頁及び第７頁
【０００６】
【発明が解決しようとする課題】
本発明がシャンプー及び乾燥後の毛髪に高い光沢性及び艶を付与し、櫛とおりを滑らかにするヘアリンス組成物を提供しようとするものである。
【０００７】
【課題を解決するための手段】
本発明者は、種々のコンディショニング成分の組み合わせに関して検討の結果、特定のカチオン性ペプチド（成分（Ａ））、室温で液状の油類脂物質（成分（Ｂ））、油性Ｎ−アシルアミノカルボン酸ポリオキシアルキレンアルキルエーテルエステル化合物（成分（Ｃ））を、ヘアリンス組成物として用いること上記従来技術の問題点が解決することを見出し本発明を完成した。
【０００８】
本発明のヘアリンス組成物は、成分Ａとして、第四級アンモニウム塩によりカチオン化されているケラトースと、
成分Ｂとして、室温において液状の油脂物質と、
成分Ｃとして、下記一般式（１）で示される油溶性イミノ２塩基酸エステル型界面活性剤化合物：
【化２】
ＡＯは２乃至３個の炭素原子を有するオキシアルキレン基を表し
Ｒ 2 は２〜３０個の炭素原子を有するアルキル基を表し
Ｒ 3 は２〜３０個の炭素原子を有するアルキル基を表し、
ｋ及びｒは、それぞれ互に独立に、１又は２の整数を表し、
ｓ及びｔはそれぞれ互に独立に、０〜５の整数を表し、
但し、ｓ＋ｔは５以下である。］
を含むことを特徴とするものである。
【０００９】
【発明の実施の形態】
本発明ヘアリンス組成物の成分Ａとして用いられる第四級アンモニウム塩によりカチオン化されているケラトースとは、ケラチンの加水分解物であるケラトースを、第四級アンモニウム塩によりカチオン化して得られるケラトース誘導体を意味する。具体的には、特開２０００−２４７８４２（特許文献３）及び特開２０００−２４７８４４（特許文献４）に記載されている第四級アンモニウム塩によりカチオン化されているケラトースを用いることができる。このようなカチオン化ケラトースの市販品としては、一丸ファルコス株式会社製のプロティキュートＣガンマ（商標）、プロティキュートＣガンマ１２（商標）、プロティキュートＣアルファ（商標）等がある。
カチオン化ケラトース（成分（Ａ））の、本発明のヘアリンス組成物に対する配合量は、０．０１〜１０．０質量％であることが好ましく、より好ましくは０．１〜５．０質量％である。この配合量が０．０１質量％より少ないと、洗髪後のパサパサ感の解消効果が不十分になることがある。また、それが１０．０質量％より多いと、第四級アンモニウム塩カチオン化ケラトースに由来する感触が過剰に発現して、洗髪後の髪のさらさら感が不十分になり、髪質が重く感じさせるなどの不都合を生ずることがある。
【００１０】
本発明のヘアリンス組成物の成分Ｂとして用いられる室温で液状の油脂物質は、室温で液状を呈し、かつ化粧料に用いられるものである限り、その種類に制限はないが、その好適例を示せば、アーモンド油、オリーブ油、ツバキ油、アボカド油、グレープシード油、ミンク油、マカデミアンナッツ油、オレンジラフィー油、メドウホーム油、ヒマワリ油、ホホバ油、パーム油等の天然油。流動パラフィン、スクワラン等の炭化水素系油；
２−エチルヘキサン酸セチル、パルミチン酸イソプロピル、ミリスチン酸イソプロピル等の脂肪酸エステル。ポリアルキレングリコール等のポリアルキレン誘導体；並びにシリコーン油等である。
【００１１】
本発明のヘアリンス組成物の成分Ｃとして用いられる油溶性イミノ２塩基酸エステル型界面活性剤化合物は前記一般式（１）で示される化合物から選ばれる。
【００１２】
前記一般式（１）の化合物は油溶性イミノ２塩基酸エステル型界面活性剤化合物であって、顕著なヘアリンス効果を示す。
【００１３】
一般式（１）の化合物の好適例としては、ラウロイルイミノジ酢酸イソプロパノールジエステル、ラウロイルイミノジ酢酸オクチルドデシルエーテルジエステル、ラウロイルイミノジ酢酸ステアリルエーテルジエステル等が挙げられる。
【００１４】
成分Ｃに用いられる式（１）の油溶性油溶性エステル型界面活性剤化合物の、ヘアリンス組成物全質量に対する配合量は０．５〜２０質量％であることが好ましく、１．０〜５．０質量％であることがより好ましい。その配合量が０．５質量％を下回ると、洗髪後の乾燥毛髪のつやが不足する場合があり、またそれが２０質量％を超える場合は、すすぎ時の毛髪に対する指通りが悪くなり、乾燥後の毛髪の風合いが不満足なものになる等の問題が発生することがある。
【００１５】
本発明のヘアリンス組成物には、冷感物質及びエタノールを、それぞれ単独に、或いはその２種以上を併用して添加して、洗髪中及びすすぎ時の使用感を向上させることが好ましい。冷感物質としては、メントール、カンファー、ハッカ油及び公知のメントール誘導体等が挙げられる。
【００１６】
本発明のヘアリンス組成物には、発明の効果を損なわない範囲で、化粧品に使用可能な原料、例えばアニオン性、カチオン性、両性、及び非イオン活性剤類、保湿剤、水溶性高分子添加剤、増粘剤、皮膜形成剤、紫外線吸収剤、消炎症剤、抗フケ剤、金属封鎖剤、低級アルコール類、糖類、アミノ酸類、有機アミン類、合成樹脂エマルジョン、pH調整剤、皮膚栄養剤、酸化防止剤、酸化防止助剤などの１種以上を添加成分として添加してもよい。
【００１７】
上記添加成分を例示すれば下記の通りである。
添加成分用アニオン活性剤としては脂肪酸セッケン、たとえばセッケン用素地、ラウリン酸ナトリウム、パルミチン酸ナトリウム、ヤシカリセッケン；高級アルキル硫酸エステル塩、たとえばラウリル硫酸ナトリウム、ラウリル硫酸カリウム、ラウリル硫酸トリエタノールアミン；アルキルエーテル硫酸エステル塩、たとえば、ＰＯＥラウリル硫酸トリエタノールアミン、ＰＯＥラウリル硫酸ナトリウム；Ｎ−アシルアミノ酸塩、たとえば、ラウロイルサルコシンナトリウム、ラウロイル−β−アラニンナトリウム、ラウロイル−Ｎ−メチル−β−アラニンナトリウム、Ｎ−ラウロイルグルタミン酸モノナトリウム、Ｎ−ステアロイルグルタミン酸ジナトリウム、Ｎ−ミリストイル−Ｌ−グルタミン酸モノナトリウム、Ｎ−パルミトイルアスパラギン酸ジエタノールアミン、ヤシ脂肪酸シルクペプチド；高級脂肪酸アミドスルホン酸塩、たとえばＮ−ミリストイル−Ｎ−メチルタウリンナトリウム、ヤシ脂肪酸メチルタウリンナトリウム、ラウロイルメチルタウリンナトリウム；リン酸エステル塩、たとえばＰＯＥオレイルエーテルリン酸ナトリウム、ＰＯＥステアリルエーテルリン酸、ＰＯＥラウリルアミドエーテルリン酸ナトリウム；スルホコハク酸塩、たとえばジ−２−エチルヘキシルスルホコハク酸ナトリウム、モノラウロイルモノエタノールアミドポリオキシエチレンスルホコハク酸ナトリウム、ラウリルポリプロピレングリコールスルホコハク酸ナトリウム；
アルキルベンゼンスルホン酸塩、たとえばリニアドデシルベンゼンスルホン酸ナトリウム、リニアドデシルベンゼンスルホン酸トリエタノールアミン、リニアドデシルベンゼンスルホン酸；高級脂肪酸エステル硫酸エステル塩、たとえば硬化ヤシ油脂肪酸グリセリン硫酸ナトリウム；ロート油などの硫酸化油；並びにα−オレフィンスルホン酸塩、高級脂肪酸エステルスルホン酸塩、二級アルコール硫酸エステル塩、高級脂肪酸アルキロールアミド硫酸エステル塩、ラウロイルモノエタノールアミドコハク酸ナトリウム、及びカゼインナトリウム等が挙げられる。
【００１８】
添加成分用カチオン性界面活性剤としては、アルキルトリメチルアンモニウム塩、たとえば塩化ステアリルトリメチルアンモニウム、塩化ラウリルトリメチルアンモニウム、臭化ラウリルトリメチルアンモニウム；ジアルキルジメチルアンモニウム塩、たとえば塩化ジステアリルジメチルアンモニウム塩；アルキルピリジウム塩、たとえば塩化セチルピリジウム；並びにアルキルジメチルベンジルアンモニウム塩、塩化ベンゼトニウム、及び塩化ベンザルコニウム等があげられる。
また添加成分用両性界面活性剤としては、アミドアミン系両性界面活性剤、たとえば２−ウンデシル−Ｎ−カルボキシメチル−Ｎ−ヒドロキシエチルイミダゾリウムベタイン、Ｎ−ラウロイル−Ｎ’−カルボキシメチル−Ｎ’−ヒドロキシエチルエチレンジアミンナトリウム、Ｎ−ヤシ脂肪酸アシル−Ｎ’−カルボキシエチル−Ｎ’−ヒドロキシエチルエチレンジアミンナトリウム；アミド酢酸ベタイン型両性界面活性剤、たとえばヤシ脂肪酸アミドプロピルベタイン、ミリスチン酸アミドプロピルベタイン；アミドスルホベタイン型両性界面活性剤、たとえばラウリン酸アミドプロピルヒドロキシスルホベタイン；アミンオキサイド型両性界面活性剤、たとえばラウリルトリメチルアミンオキシド、ラウリン酸アミドプロピルアミンオキシド；並びにアルキル酢酸ベタイン型両性界面活性剤、及びアルキルスルホベタイン型両性界面活性剤等があげられる。
【００１９】
添加成分用非イオン界面活性剤としてはグリセリン脂肪酸エステル類、たとえばモノステアリン酸グリセリル、自己乳化型モノステアリン酸グリセリル、モノイソステアリン酸グリセリル；ポリオキシエチレングリセリン脂肪酸エステル類、たとえばモノステアリン酸、ＰＯＥグリセリルモノオレイン酸ＰＯＥグリセリル；ポリグリセリン脂肪酸エステル類、たとえばモノステアリン酸ジグリセリル、トリステアリン酸テトラグリセリル、ペンタステアリン酸デカグリセリル；ソルビタン脂肪酸エステル類、たとえばモノラウリン酸ソルビタン、セスキステアリン酸ソルビタン、モノオレイン酸ソルビタン；ポリオキシエチレンソルビタン脂肪酸エステル類、たとえばモノヤシ脂肪酸ＰＯＥソルビタン、トリステアリン酸ＰＯＥソルビタン、トリオレイン酸ＰＯＥソルビタン；ポリオキシエチレンソルビット脂肪酸エステル類、たとえばモノラウリン酸ＰＯＥソルビット、テトラオレイン酸ＰＯＥソルビット；ポリエチレングリコール脂肪酸エステル類、たとえば、モノラウリン酸ポリエチレングリコール、モノステアリン酸ポリエチレングリコール、モノオレイン酸ポリエチレングリコール、ジステアリン酸ポリエチレングリコール；ポリオキシエチレンアルキルエーテル類、たとえばＰＯＥラウリルエーテル、ＰＯＥセチルエーテル、ＰＯＥステアリルエーテル；ポリオキシエチレンポリオキシプロピレンアルキルエーテル類、たとえばＰＯＥ・ＰＯＰセチルエーテル、ＰＯＥ・ＰＯＰデシルテトラデシルエーテル；ポリオキシエチレンアルキルフェニルエーテル類、例えばＰＯＥノニルフェニルエーテル、ＰＯＥオクチルフェニルエーテル、ＰＯＥ分鎖オクチルフェニルエーテル；ポリオキシエチレンアルキルアミン類、たとえばＰＯＥステアリルアミン、ＰＯＥオレイルアミン；脂肪酸アルカノールアミド類、たとえばヤシ脂肪酸ジエタノールアミド、ヤシ脂肪酸モノエタノールアミド、ラウリン酸ジエタノールアミド、パーム核油脂肪酸ジエタノールアミド；ポリオキシエチレンアルカノールアミド類、たとえばＰＯＥラウリン酸モノエタノールアミド、ＰＯＥヤシ脂肪酸モノエタノールアミド、ＰＯＥ牛脂脂肪酸モノエタノールアミド；並びにアセチレングリコール、ＰＯＥアセチレングリコール、ＰＯＥラノリン、ＰＯＥラノリンアルコール、ＰＯＥヒマシ油、ＰＯＥ硬化ヒマシ油、ＰＯＥフィトステロール、ＰＯＥコレスタノール、ＰＯＥノニルフェニルホルムアルデヒド縮合物などが挙げられる。
【００２０】
添加成分用保湿剤としては、グリセリン、プロピレングリコール、１，３−ブチレングリコール、ソルビトール、乳酸ナトリウム、ピロリドンカルボン酸及びその塩、などが挙げられる。
添加成分用水溶性高分子剤としては、グァーガム、クイーンシード、ペクチン、ゼラチン、キサンタンガム、メチルセルロース、エチルセルロース、ヒドロキシエチルセルロース、ヒドロキシプロピルセルロース、カルボキシメチルセルロース及び塩、アルギン塩、ポリビニルアルコール、カルボキシビニルポリマー、ポリアクリル酸ソーダ、ベントナイト、キチン・キトサン誘導体、ヒアルロン酸及び塩、コラーゲン及びその誘導体などが挙げられ、組成物の増粘剤又は乳化助剤として添加される。
また添加成分用増粘剤としては、ヤシ油脂肪酸モノエタノールアミド、ラウリン酸ジエタノールアミド、ラウリン酸イソプロパノールアミド、ポリオキシエチレンヤシ油脂肪酸モノエタノールアマド、ポリオキシプロピレンヤシ油脂肪酸モノエタノールアミドなどが挙げられる。
【００２１】
添加成分用皮膜形成剤としては、ポリビニルアルコール、ポリビニルピロリドン、カチオン化セルロース、カチオン化セルロース、シリコーンなどが挙げられる。
添加成分用紫外線吸収剤としては、２−ヒドロキシ−４−メトキシベンゾフェノン、２−ヒドロキシ−４−メトキシベンゾフェノン−５−スルホン酸及び塩、ジヒドロキシジメトキシベンゾフェノンなどのベンゾフェノン誘導体；パラアミノ安息香酸、パラアミノ安息香酸エチルなどのパラアミノ安息香酸誘導体；パラメトキシ桂皮酸エチル、パラメトキシ桂皮酸イソプロピル、パラメトキシ桂皮酸オクチルなどのメトキシ桂皮酸誘導体；サリチル酸オクチル、サリチル酸フェニルなどのサリチル酸誘導体；ウロカニン酸及び誘導体；並びに４−ｔｅｒｔ−ブチル−４’−メトキシジベンゾイルメタン、２−（ヒドロキシ−５’−メチルフェニル）ベンゾトリアゾール、アントラニル酸メチルなどが挙げられる。
添加成分用消炎症剤としては、グリチルリチン酸及びその誘導体、グリチルレチン酸及びその誘導体、アラントイン、酢酸ヒドロコーチゾン、アズレンなどが挙げられる。
添加成分用抗フケ剤としては、ピロクトンオラミン、硝酸ミコナゾール、トリクロサン、ジンクピリチオン等が挙げられる。
【００２２】
添加成分用金属封鎖剤としては、エチレンジアミン四酢酸及びナトリウム塩、リン酸、クエン酸、アスコルビン酸、コハク酸、グルコン酸、ポリリン酸ナトリウム、メタリン酸ナトリウムなどが挙げられる。
添加成分用低級アルコールとしては、エタノール、プロピルアルコール、エチレングリコール、ジエチレングリコールなどが挙げられ、これらは組成物の粘度調整、或は、ヘアリンス組成物の使用感（冷感又は温感）を変更（温感又は冷感に）するという目的に用いられる。
添加成分用糖類としては、ブドウ糖、乳糖、白糖、デンプン、カルボキシメチルデンプン、シクロデキストリンなどが挙げられる。
添加成分用アミノ酸類としては、アスパラギン酸及び塩、アラニン、アルギニン、リジン及び塩、グリシン、シスチン、スレオニン、セリン、メチオニンなどが挙げられ、これらは毛髪に対し、補修効果がある。
添加成分用有機アミン類としては、モノエタノールアミン、ジエタノールアミン、トリエタノールアミン、ジイソプロパノールアミン、トリエチルアミンなどが挙げられ、これらも、毛髪補修の目的に用いられる。
【００２３】
添加成分用合成樹脂エマルジョンとしては、ポリアクリル酸エステル共重合体、ポリ酢酸ビニルなどが挙げられ、これらは組成物の増粘の目的に、或は乳化助剤として用いられる。
添加成分用pH調整剤としては、クエン酸、塩酸、硫酸、リン酸、水酸化ナトリウム、アンモニア、などが挙げられる。
添加成分用皮膚栄養剤としては、ビタミンＡ、Ｂ１、Ｂ２、Ｂ６、Ｅ及びその誘導体、パントテン酸及びその誘導体、ビオチンなどが挙げられる。
添加成分用酸化防止剤としては、ビタミンＥ、ジブチルヒドロキシトルエン、ブチルヒドロキシアニソール、没食子酸エステル類などが挙げられる。
添加成分用酸化防止助剤としては、アスコルビン酸、フィチン酸、ケファリン、マレイン酸などが挙げられる。本発明のヘアリンス組成物に用いられる添加成分は、上記のものに限定されるものではない。
本発明のヘアリンス組成物を製造するには、所要成分を、従来のヘアリンス組成物の調製に慣用の配合製造、配合操作及び配合条件を適宜に利用すればよい。
【００２４】
【実施例】
本発明を下記実施例により、さらに具体的に説明するが、本発明は、これらにより限定されるべきものではない。また、配合量“％”は、特に断わらない限り、目的組成物の合計質量に対する質量％である。
【００２５】
〔合成例１〕
Ｎ−カルボキシメチル−Ｎ−ラウロイルグリシン（２−オクチルドデシルアルコール）ジエステルの合成。
５００ｍｌ四つ口フラスコに、スターラーが入れられ、かつ単蒸留用の機具が組み込まれている装置中に、Ｎ−カルボキシメチル−Ｎ−ラウロイルグリシン１１０．１６ｇ（０．３４２モル）と２−オクチルドデシルアルコール２０４．３８ｇ（０．６８５モル）を仕込み、この混合物をスターラーで撹拌しながら、オイルバスで９０℃まで加熱し均一に溶解させた。この溶液に触媒として７５％硫酸１．０５ｇ（０．０１０モル）を加えた。この反応系を加熱撹拌しながらフラスコ内を徐々に減圧し、この反応中に副生する水分を十分に除去した。液温を１４０℃まで昇温した。反応系を、最終的に１４０℃、−０．１MPa （ブルドン管での相対圧力）の状態に調整し、３０分間、上記加熱減圧状態を保持した。その後、反応系を１０００mlの分液ロートに移し替え、これにテトラヒドロフラン（ＴＨＦ）４３０．２０ｇを加えて、この混合物中に油層及び水層を形成させ、これを７．８質量％炭酸水素ナトリウム水酸化ナトリウム水溶液６９．５７ｇを加えて洗浄し、その後、混合物中の水層を除去した。この処理で得られた油層に２０．０質量％塩化ナトリウム水溶液８４．０９ｇを添加して、油層を洗浄した後、混合物中に形成された水層を除去した。更に、この処理で得られた油層に２０．０質量％塩化ナトリウム水溶液８７．３３ｇを添加して、油層を洗浄し、この混合物中の水層を除去した。さらにこの処理で得られた油層に無水硫酸ナトリウム２０ｇを加え、１時間放置して油層中の水分を除去した。この混合物中に形成された芒硝をろ過により取り除き、油層に含まれるＴＨＦをエバポレーターで留去した。この結果、淡黄色液状の目的化合物２８２．１９ｇを得た。その酸価は２．２４でありケン化価は１２４．２であった。
【００２６】
実施例１及び比較例１〜４
実施例１及び比較例１〜４の各々において、表１に記載のヘアリンスを製造し、各サンプルの、使用感について官能評価を行った。
【００２７】
【表１】
調製方法
配合成分のうち、パラオキシ安息香酸メチル、１−メントール、グリチルリチン酸ジカリウム、精製水、香料を除く各成分を混合し、この混合物を８０℃まで、攪拌下に加熱して均一油相の混合物を調製した。別の容器で、パラオキシ安息香酸メチル、グリチルリチン酸ジカリウム、及び精製水を、攪拌下に８０℃に加熱して均一水相の混合物を調製した。この油相混合物に、水相混合物を８０℃、攪拌下において混合し、乳化操作を施し、この乳化物を攪拌下、６０℃まで冷却した。さらにこの乳化混合物に、温度６０℃において香料を加え、更に室温まで、攪拌下に、冷却してヘアリンス組成物を調製した。
【００２９】
評価方法
各組成物のサンプルについて、パネラー１０名により実用試験を行い、ヘアリンスのすすぎ時の毛髪の指どおり、乾燥時の毛髪の櫛どおり、乾燥後の毛髪の滑らかさ、乾燥後の毛髪の光沢について、表２に記載の基準に基いて官能評価を行った。
【００３０】
【表２】
なお、評価は表１の比較例３のヘアリンス組成物に対する各項目の評価点を、標準３点とし、５段階に相対評価し、評価結果を集計しての平均点を算出し、算出された平均値が
４．５以上の場合：非常に良好（◎）
４．５〜３．５の場合：良好（○）
３．５〜３．０の場合：普通（△）
３．０未満の場合：不良（×）
と評価した。
【００３２】
表１の試験結果から明らかなように、第四級アンモニウム塩によりカチオン化されているケラトース（成分Ａ）、液状油脂（成分Ｂ）、及び油溶性イミノ２塩基酸エステル型界面活性剤化合物（成分Ｃ）を併用した組成物は、特に乾燥後の毛髪の滑らかさ、乾燥後の毛髪の光沢に優れ、及びヘアリンスの基本性能であるすすぎ時の毛髪の指どおり、及び乾燥時の毛髪の櫛どおりにも優れている事が確認された。
【００３４】
実施例２
下記組成のヘアリンス組成物を実施例１と同様にして調製した。得られたヘアリンスの評価結果は良好であった。
【００３５】
塩化Ｎ−［２−ヒドロキシ−３−（トリメチルアンモニオ） 1.00％
プロピル］加水分解ケラチン（＊）1
スイートアーモンド油 2.00％
ラウロイルグタミン酸ＰＯＥ（５）オクチルドデシル 0.50％
エーテルジエステル（＊）3
合成例１の物質 1.00％
塩化ステアリルトリメチルアンモニウム（５０％） 1.50％
塩化ジステアリルジメチルアンモニウム（７５％） 1.50％
ポリオキシエチレン（５）ラウリルエーテル 1.00％
モノステアリン酸グリセリル 0.50％
セトステアリルアルコール 3.00％
ジブチルヒドロキシトルエン 0.01％
ビタミンＥ油 0.10％
パラオキシ安息香酸メチル 0.20％
香料 0.30％
エタノール 1.00％
グリチルリチン酸ジカリウム 0.20％
１−メントール 1.50％
精製水 全量を100％とする量
〔註〕
（＊）1 …商標：プロテキュートＣα、一丸ファルコス社製
（＊）3 …商標：アミテルＬＧＯＤ−５、日本エマルジョン社製
【００３８】
【発明の効果】
本発明のヘアリンス組成物は、洗髪及びすすぎ洗いのときの毛髪の指通りがよく、乾燥後の毛髪がしっとりしていて、光沢及び艶がよく、櫛通りも滑らかで、実用上優れたものである。[0001]
BACKGROUND OF THE INVENTION
The present invention relates to a hair rinse composition. More specifically, the present invention relates to a hair rinse composition that is excellent in gloss and gloss of hair after drying and has an effect of smoothing the comb.
[0002]
[Prior art]
The hair is constantly exposed to external stimuli, and the act of washing for the purpose of removing dirt attached to the hair and scalp also gives physical stimulation to the hair. , May damage hair. In particular, various techniques have been disclosed and various devices have been devised for reducing damage to hair caused by brushing after shampooing, but no sufficient solution has yet been found.
[0003]
For example, JP-A-60-123212 (Patent Document 1) discloses a quaternary ammonium salt and an amino acid-based cationic surfactant and a solubility in water at 25 ° C. of 1% by weight or less, and 25 A hair cosmetic composition containing a hydrophobic silicone having a viscosity of 1 to 1000 centistokes at ° C. and a keratin derivative selected from a keratin substance-degraded derivative and a cationized keratin compound derivative is disclosed. It has been disclosed that it has the effect of improving the smoothness of the hair and preventing the bristle ends. However, the effect is insufficient and further improvement has been demanded.
[0004]
Japanese Patent Application Laid-Open No. 10-77210 (Patent Document 2) discloses α-ketose, or quaternized product of γ-ketose, which improves the bending elasticity of hair and has high functions such as moisture retention and antioxidant properties. Yes. This compound has an excellent hair adsorption and protection effect as compared with conventional cationized peptides, but the effect is not yet sufficient, and further improvement has been demanded.
JP 2000-247842 (Patent Document 3) and JP 2000-247844 (Patent Document 4) describe keratose cationized with a quaternary ammonium salt. However, these patent documents disclose nothing about the improvement of the rinsing effect by the combined use with the specific oil-soluble N-acylamino acid polyoxyalkylene alkyl ether compounds used in the present invention , and are described in the above patent documents. The rinsing effect of the present cationized keratose was not satisfactory.
[0005]
Technical literature [Patent Literature 1]
Japanese Patent Application Laid-Open No. 60-123212, pages 1 and 2 [Patent Document 2]
JP-A-10-77210, pages 2 to 3 [Patent Document 3]
JP 2000-247842 A, page 1 and pages 6 to 8 [Patent Document 4]
Japanese Unexamined Patent Publication No. 2000-247844, pages 1 and 7
[Problems to be solved by the invention]
The present invention seeks to provide a hair rinse composition that imparts high gloss and gloss to shampoo and hair after drying, and smoothes the comb.
[0007]
[Means for Solving the Problems]
As a result of studies on combinations of various conditioning components, the present inventor has found that a specific cationic peptide (component (A)), an oily fat substance (component (B)) that is liquid at room temperature, and an oily N-acylaminocarboxylic acid Using the polyoxyalkylene alkyl ether ester compound (component (C)) as a hair rinse composition has found that the above-mentioned problems of the prior art are solved, and the present invention has been completed.
[0008]
The hair rinse composition of the present invention comprises, as component A, keratose cationized with a quaternary ammonium salt,
Component B is an oily substance that is liquid at room temperature,
As component C, an oil-soluble imino dibasic acid ester type surfactant compound represented by the following general formula (1) :
[Chemical 2]
AO represents an oxyalkylene group having 2 to 3 carbon atoms
R 2 represents an alkyl group having 2 to 30 carbon atoms
R 3 represents an alkyl group having 2 to 30 carbon atoms ,
k and r each independently represent an integer of 1 or 2,
s and t each independently represent an integer of 0 to 5,
However, s + t is 5 or less. ]
It is characterized by including.
[0009]
DETAILED DESCRIPTION OF THE INVENTION
The keratose cationized with the quaternary ammonium salt used as component A of the hair rinse composition of the present invention is a keratose derivative obtained by cationizing a keratin hydrolyzate keratose with a quaternary ammonium salt. means. Specifically, keratose cationized with a quaternary ammonium salt described in JP-A-2000-247842 (Patent Document 3) and JP-A-2000-247844 (Patent Document 4) can be used. Commercially available products of such cationized keratose include Proticute C gamma (trademark), Proticute C gamma 12 (trademark), and Proticute C alpha (trademark) manufactured by Ichimaru Falcos.
It is preferable that the compounding quantity with respect to the hair rinse composition of this invention of a cationized keratose (component (A)) is 0.01-10.0 mass%, More preferably, it is 0.1-5.0 mass%. is there. If the blending amount is less than 0.01% by mass, the effect of relieving the feeling of dryness after washing the hair may be insufficient. On the other hand, if it is more than 10.0% by mass, the feel derived from the quaternary ammonium salt cationized keratose is excessively expressed, the hair feels after washing is insufficient, and the hair feels heavy. May cause inconveniences such as
[0010]
The fat and oil substance which is liquid at room temperature used as Component B of the hair rinse composition of the present invention is not limited in type as long as it is liquid at room temperature and is used in cosmetics. Natural oils such as almond oil, olive oil, camellia oil, avocado oil, grape seed oil, mink oil, macadamia nut oil, orange luffy oil, meadowweed oil, sunflower oil, jojoba oil, palm oil. Hydrocarbon oils such as liquid paraffin and squalane;
Fatty acid esters such as cetyl 2-ethylhexanoate, isopropyl palmitate and isopropyl myristate. Polyalkylene derivatives such as polyalkylene glycol; and silicone oils.
[0011]
The oil-soluble imino dibasic acid ester type surfactant compound used as component C of the hair rinse composition of the present invention is selected from the compounds represented by the general formula (1).
[0012]
The compound of the general formula (1) is an oil-soluble imino dibasic acid ester type surfactant compound and exhibits a remarkable hair rinse effect .
[0013]
Preferable examples of the compound represented by the general formula ( 1 ) include lauroy liminodiacetic acid isopropanol diester, lauroy liminodiacetic acid octyldodecyl ether diester, lauroilymino diacetate stearyl ether diester, and the like.
[0014]
It is preferable that the compounding quantity with respect to the hair rinse composition total mass of the oil-soluble oil-soluble ester type | mold surfactant compound of Formula (1) used for the component C is 0.5-20 mass%, and 1.0-5. More preferably, it is 0% by mass. If the blending amount is less than 0.5% by mass, the gloss of dry hair after washing may be insufficient, and if it exceeds 20% by mass, the fingering of the hair during rinsing will be poor and dry. Problems such as unsatisfactory hair texture afterwards may occur.
[0015]
In the hair rinse composition of the present invention, it is preferable to add a cooling sensation substance and ethanol, either alone or in combination of two or more thereof, to improve the feeling of use during shampooing and rinsing. Examples of cooling substances include menthol, camphor, mint oil, and known menthol derivatives.
[0016]
The hair rinse composition of the present invention includes raw materials that can be used in cosmetics, for example, anionic, cationic, amphoteric, and nonionic active agents, humectants, and water-soluble polymer additives as long as the effects of the invention are not impaired. , Thickeners, film formers, UV absorbers, anti-inflammatory agents, anti-dandruff agents, sequestering agents, lower alcohols, sugars, amino acids, organic amines, synthetic resin emulsions, pH adjusters, skin nutrients, You may add 1 or more types, such as antioxidant and antioxidant adjuvant, as an additional component.
[0017]
Examples of the additive component are as follows.
Anionic activators for additive components include fatty acid soaps such as soap bases, sodium laurate, sodium palmitate, coconut soap, higher alkyl sulfates such as sodium lauryl sulfate, potassium lauryl sulfate, triethanolamine lauryl sulfate; alkyl Ether sulfate esters such as POE lauryl sulfate triethanolamine, POE sodium lauryl sulfate; N-acyl amino acid salts such as sodium lauroyl sarcosine, sodium lauroyl-β-alanine, sodium lauroyl-N-methyl-β-alanine, N -Lauroyl glutamate monosodium, N-stearoyl glutamate disodium, N-myristoyl-L-glutamate monosodium, N-palmitoyl aspa Laethanolate diethanolamine, palm fatty acid silk peptide; higher fatty acid amide sulfonates such as N-myristoyl-N-methyltaurine sodium, palm fatty acid methyltaurine sodium, lauroylmethyltaurine sodium; phosphate ester salts such as sodium POE oleyl ether phosphate , POE stearyl ether phosphate, POE sodium laurylamide ether phosphate; sulfosuccinates such as sodium di-2-ethylhexylsulfosuccinate, monolauroyl monoethanolamide sodium polyoxyethylenesulfosuccinate, sodium lauryl polypropylene glycol sulfosuccinate;
Alkylbenzene sulfonates such as sodium linear dodecyl benzene sulfonate, linear ethanol dodecyl benzene sulfonate triethanolamine, linear dodecyl benzene sulfonic acid; higher fatty acid ester sulfates such as hydrogenated coconut oil fatty acid sodium glycerin sulfate; Oils; and α-olefin sulfonates, higher fatty acid ester sulfonates, secondary alcohol sulfates, higher fatty acid alkylolamide sulfates, sodium lauroyl monoethanolamide succinate, and sodium caseinate.
[0018]
Cationic surfactants for additive components include alkyl trimethyl ammonium salts such as stearyl trimethyl ammonium chloride, lauryl trimethyl ammonium chloride, lauryl trimethyl ammonium bromide; dialkyl dimethyl ammonium salts such as distearyl dimethyl ammonium chloride; alkyl pyridium salts For example, cetylpyridinium chloride; and alkyldimethylbenzylammonium salt, benzethonium chloride, and benzalkonium chloride.
Examples of amphoteric surfactants for additive components include amidoamine amphoteric surfactants such as 2-undecyl-N-carboxymethyl-N-hydroxyethylimidazolium betaine, N-lauroyl-N′-carboxymethyl-N′-hydroxy. Sodium ethylethylenediamine, N-coconut fatty acid acyl-N′-carboxyethyl-N′-hydroxyethylethylenediamine sodium; Amidoacetic acid betaine type amphoteric surfactants such as palm fatty acid amidopropyl betaine, myristic acid amidopropyl betaine; Amidosulfobetaine type Amphoteric surfactants such as lauric acid amidopropyl hydroxysulfobetaine; amine oxide type amphoteric surfactants such as lauryltrimethylamine oxide, lauric acid amidopropylamine oxide; And alkyl acetate betaine type amphoteric surfactants and alkyl sulfobetaine type amphoteric surfactants.
[0019]
Nonionic surfactants for additive components include glycerin fatty acid esters such as glyceryl monostearate, self-emulsifying glyceryl monostearate, glyceryl monoisostearate; polyoxyethylene glycerin fatty acid esters such as monostearic acid, POE glyceryl mono POE glyceryl oleate; polyglyceryl fatty acid esters such as diglyceryl monostearate, tetraglyceryl tristearate, decaglyceryl pentastearate; sorbitan fatty acid esters such as sorbitan monolaurate, sorbitan sesquistearate, sorbitan monooleate; Polyoxyethylene sorbitan fatty acid esters such as mono coconut fatty acid POE sorbitan, tristearic acid POE sorbitan, Oleic acid POE sorbitan; polyoxyethylene sorbite fatty acid esters such as monolauric acid POE sorbite, tetraoleic acid POE sorbite; polyethylene glycol fatty acid esters such as polyethylene glycol monolaurate, polyethylene glycol monostearate, polyethylene glycol monooleate, Polyethylene glycol distearate; polyoxyethylene alkyl ethers such as POE lauryl ether, POE cetyl ether, POE stearyl ether; polyoxyethylene polyoxypropylene alkyl ethers such as POE · POP cetyl ether, POE · POP decyl tetradecyl ether; Polyoxyethylene alkylphenyl ethers such as P E nonylphenyl ether, POE octylphenyl ether, POE branched octylphenyl ether; polyoxyethylene alkylamines such as POE stearylamine, POE oleylamine; fatty acid alkanolamides such as coconut fatty acid diethanolamide, coconut fatty acid monoethanolamide, laurin Acid diethanolamide, palm kernel oil fatty acid diethanolamide; polyoxyethylene alkanolamides such as POE lauric acid monoethanolamide, POE coconut fatty acid monoethanolamide, POE beef tallow fatty acid monoethanolamide; and acetylene glycol, POE acetylene glycol, POE lanolin , POE lanolin alcohol, POE castor oil, POE hydrogenated castor oil, POE phytosterol , POE cholestanol, POE nonylphenyl formaldehyde condensate and the like.
[0020]
Examples of the humectant for the additive component include glycerin, propylene glycol, 1,3-butylene glycol, sorbitol, sodium lactate, pyrrolidone carboxylic acid and salts thereof.
Water-soluble polymer agents for additive components include guar gum, queen seed, pectin, gelatin, xanthan gum, methyl cellulose, ethyl cellulose, hydroxyethyl cellulose, hydroxypropyl cellulose, carboxymethyl cellulose and salts, algin salts, polyvinyl alcohol, carboxyvinyl polymer, polyacrylic acid Examples include soda, bentonite, chitin / chitosan derivatives, hyaluronic acid and salts, collagen and derivatives thereof, and the like, which is added as a thickener or an emulsifying aid for the composition.
Examples of the thickener for the additive component include coconut oil fatty acid monoethanolamide, lauric acid diethanolamide, lauric acid isopropanolamide, polyoxyethylene coconut oil fatty acid monoethanolamide, polyoxypropylene coconut oil fatty acid monoethanolamide, and the like. .
[0021]
Examples of the film forming agent for additive components include polyvinyl alcohol, polyvinyl pyrrolidone, cationized cellulose, cationized cellulose, and silicone.
Examples of ultraviolet absorbers for additive components include 2-hydroxy-4-methoxybenzophenone, 2-hydroxy-4-methoxybenzophenone-5-sulfonic acid and salts, benzophenone derivatives such as dihydroxydimethoxybenzophenone; paraaminobenzoic acid, ethyl paraaminobenzoate Paraaminobenzoic acid derivatives such as: ethyl paramethoxycinnamate, isopropyl paramethoxycinnamate, methoxycinnamic acid derivatives such as octyl paramethoxycinnamate; salicylic acid derivatives such as octyl salicylate and phenyl salicylate; urocanic acid and derivatives; and 4-tert-butyl- 4'-methoxydibenzoylmethane, 2- (hydroxy-5'-methylphenyl) benzotriazole, methyl anthranilate and the like can be mentioned.
Examples of the additive anti-inflammatory agent include glycyrrhizic acid and derivatives thereof, glycyrrhetinic acid and derivatives thereof, allantoin, hydrocortisone acetate, and azulene.
Examples of anti-dandruff agents for additive components include piroctone olamine, miconazole nitrate, triclosan, and zinc pyrithione.
[0022]
Examples of the metal sequestering agent for additive components include ethylenediaminetetraacetic acid and sodium salts, phosphoric acid, citric acid, ascorbic acid, succinic acid, gluconic acid, sodium polyphosphate, sodium metaphosphate, and the like.
Examples of the lower alcohol for the additive component include ethanol, propyl alcohol, ethylene glycol, diethylene glycol, and the like, which change the viscosity of the composition or change the feeling of use (cool feeling or warm feeling) of the hair rinse composition. It is used for the purpose of making it feel or cool).
Examples of the saccharide for the additive component include glucose, lactose, sucrose, starch, carboxymethyl starch, and cyclodextrin.
Amino acids for additive components include aspartic acid and salt, alanine, arginine, lysine and salt, glycine, cystine, threonine, serine, methionine and the like, and these have a repairing effect on the hair.
Examples of organic amines for additive components include monoethanolamine, diethanolamine, triethanolamine, diisopropanolamine, and triethylamine, which are also used for hair repair purposes.
[0023]
Synthetic resin emulsions for additive components include polyacrylate copolymers, polyvinyl acetate, and the like, and these are used for the purpose of thickening the composition or as an emulsifying aid.
Examples of the pH adjuster for the additive component include citric acid, hydrochloric acid, sulfuric acid, phosphoric acid, sodium hydroxide, ammonia, and the like.
Examples of the additive for skin nutrition include vitamins A, B1, B2, B6, E and derivatives thereof, pantothenic acid and derivatives thereof, and biotin.
Examples of the antioxidant for the additive component include vitamin E, dibutylhydroxytoluene, butylhydroxyanisole, gallic acid esters and the like.
Examples of the antioxidant for the additive component include ascorbic acid, phytic acid, kephalin, and maleic acid. The additive components used in the hair rinse composition of the present invention are not limited to those described above.
In order to produce the hair rinse composition of the present invention, the necessary components may be appropriately used in the conventional blending production, blending operation and blending conditions for the preparation of the conventional hair rinse composition.
[0024]
【Example】
The present invention will be described more specifically with reference to the following examples, but the present invention should not be limited thereto. Further, the blending amount “%” is mass% relative to the total mass of the target composition unless otherwise specified.
[0025]
[Synthesis Example 1]
Synthesis of N-carboxymethyl-N-lauroylglycine (2-octyldodecyl alcohol) diester.
In a 500 ml four-necked flask equipped with a stirrer and equipped with equipment for simple distillation, 110.16 g (0.342 mol) of N-carboxymethyl-N-lauroylglycine and 2-octyldodecyl 204.38 g (0.685 mol) of alcohol was charged, and this mixture was heated to 90 ° C. in an oil bath while being stirred with a stirrer to be uniformly dissolved. To this solution, 1.05 g (0.010 mol) of 75% sulfuric acid was added as a catalyst. While the reaction system was heated and stirred, the inside of the flask was gradually depressurized to sufficiently remove water produced as a by-product during the reaction. The liquid temperature was raised to 140 ° C. The reaction system was finally adjusted to a state of 140 ° C. and −0.1 MPa (relative pressure in a Bourdon tube), and the above-mentioned heated and reduced pressure state was maintained for 30 minutes. Thereafter, the reaction system was transferred to a 1000 ml separatory funnel, and 430.20 g of tetrahydrofuran (THF) was added thereto to form an oil layer and an aqueous layer in the mixture. An aqueous sodium oxide solution (69.57 g) was added for washing, and then the aqueous layer in the mixture was removed. 84.09 g of a 20.0 mass% sodium chloride aqueous solution was added to the oil layer obtained by this treatment to wash the oil layer, and then the aqueous layer formed in the mixture was removed. Furthermore, 87.33 g of 20.0 mass% sodium chloride aqueous solution was added to the oil layer obtained by this treatment to wash the oil layer, and the aqueous layer in this mixture was removed. Further, 20 g of anhydrous sodium sulfate was added to the oil layer obtained by this treatment, and left for 1 hour to remove moisture in the oil layer. The mirabilite formed in this mixture was removed by filtration, and the THF contained in the oil layer was distilled off with an evaporator. As a result, 282.19 g of the pale yellow liquid target compound was obtained. The acid value was 2.24 and the saponification value was 124.2.
[0026]
Example 1 and Comparative Examples 1 to 4
In each of Example 1 and Comparative Examples 1 to 4, hair rinses shown in Table 1 were produced, and sensory evaluation was performed on the feeling of use of each sample.
[0027]
[Table 1]
Preparation method Among the blending ingredients, each component except methyl paraoxybenzoate, 1-menthol, dipotassium glycyrrhizinate, purified water, and fragrance was mixed, and this mixture was heated to 80C with stirring to be uniform. A mixture of oil phases was prepared. In a separate container, methyl paraoxybenzoate, dipotassium glycyrrhizinate, and purified water were heated to 80 ° C. with stirring to prepare a homogeneous aqueous phase mixture. The oil phase mixture was mixed with the aqueous phase mixture at 80 ° C. with stirring, emulsified, and the emulsion was cooled to 60 ° C. with stirring. Further, a fragrance was added to the emulsified mixture at a temperature of 60 ° C., and further cooled to room temperature with stirring to prepare a hair rinse composition.
[0029]
Evaluation method For each sample of the composition, a practical test was conducted by 10 panelists. The hair was rinsed with a finger, the hair was combed with a hair rinse, the hair was dried, the hair was smooth, and after drying. The gloss of the hair was subjected to sensory evaluation based on the criteria described in Table 2.
[0030]
[Table 2]
The evaluation was calculated by calculating the average score of the evaluation results by summing the evaluation results, with the evaluation score of each item for the hair rinse composition of Comparative Example 3 in Table 1 as the standard, 3 points When the average value is 4.5 or more: very good (◎)
In the case of 4.5 to 3.5: Good (○)
3.5 to 3.0: Normal (△)
If less than 3.0: defective (x)
It was evaluated.
[0032]
As is apparent from the test results of Table 1, keratose (component A), liquid oil (component B), and oil-soluble imino dibasic acid ester surfactant compound (components) cationized with a quaternary ammonium salt The composition combined with C) is particularly excellent in smoothness of hair after drying, gloss of hair after drying, and as a finger of hair when rinsing, which is a basic performance of hair rinse, and as a comb of hair when dried It was confirmed that it was excellent.
[0034]
Example 2
A hair rinse composition having the following composition was prepared in the same manner as in Example 1. The evaluation result of the obtained hair rinse was good.
[0035]
N- [2-hydroxy-3- (trimethylammonio) chloride 1.00%
Propyl] hydrolyzed keratin (*) 1
Sweet almond oil 2.00%
Lauroyl glutamic acid POE (5) Octyldodecyl 0.50%
Ether diester (*) 3
Substance of Synthesis Example 1 1.00%
Stearyltrimethylammonium chloride (50%) 1.50%
Distearyldimethylammonium chloride (75%) 1.50%
Polyoxyethylene (5) lauryl ether 1.00%
Glyceryl monostearate 0.50%
Cetostearyl alcohol 3.00%
Dibutylhydroxytoluene 0.01%
Vitamin E oil 0.10%
Methyl paraoxybenzoate 0.20%
Fragrance 0.30%
Ethanol 1.00%
Dipotassium glycyrrhizinate 0.20%
1-menthol 1.50%
Purified water Amount that makes the total amount 100% [註]
(*) 1 Trademark: Protecute Cα, manufactured by Ichimaru Falcos (*) 3 ... Trademark: Amitel LGOD-5, manufactured by Nippon Emulsion Co., Ltd.
【The invention's effect】
The hair rinse composition of the present invention is excellent in practical use, with good fingering of the hair during shampooing and rinsing, moisturized hair after drying, good gloss and gloss, smooth combing, and the like. is there.
Claims (1)
成分Ｂとして、室温において液状の油脂物質と、
成分Ｃとして、下記一般式（１）で示される油溶性イミノ２塩基酸エステル型界面活性剤化合物：
ＡＯは２乃至３個の炭素原子を有するオキシアルキレン基を表し
Ｒ 2 は２〜３０個の炭素原子を有するアルキル基を表し
Ｒ 3 は２〜３０個の炭素原子を有するアルキル基を表し、
ｋ及びｒは、それぞれ互に独立に、１又は２の整数を表し、
ｓ及びｔはそれぞれ互に独立に、０〜５の整数を表し、
但し、ｓ＋ｔは５以下である。］
を含むことを特徴とするヘアリンス組成物。As component A, keratose cationized with a quaternary ammonium salt;
Component B is an oily substance that is liquid at room temperature,
As component C, an oil-soluble imino dibasic acid ester type surfactant compound represented by the following general formula (1) :
AO represents an oxyalkylene group having 2 to 3 carbon atoms
R 2 represents an alkyl group having 2 to 30 carbon atoms
R 3 represents an alkyl group having 2 to 30 carbon atoms ,
k and r each independently represent an integer of 1 or 2,
s and t each independently represent an integer of 0 to 5,
However, s + t is 5 or less. ]
A hair rinse composition comprising:
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| JP2003122042A JP4155863B2 (en) | 2003-04-25 | 2003-04-25 | Hair rinse composition |
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| JP2003122042A JP4155863B2 (en) | 2003-04-25 | 2003-04-25 | Hair rinse composition |
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| JP4155863B2 true JP4155863B2 (en) | 2008-09-24 |
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| Publication number | Priority date | Publication date | Assignee | Title |
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| JPS5123395B2 (en) * | 1972-10-23 | 1976-07-16 | ||
| JPS5612609B2 (en) * | 1975-05-02 | 1981-03-23 | ||
| JPH0761911A (en) * | 1993-08-24 | 1995-03-07 | Hoyu Co Ltd | Hair-treating agent |
| JPH1077210A (en) * | 1996-09-06 | 1998-03-24 | Nakanihon Seni Kogyo Kyodo Kumiai | Cosmetic composition, method for producing the same, and cosmetics incorporating the same |
| JP2000154112A (en) * | 1998-06-01 | 2000-06-06 | Ajinomoto Co Inc | New cosmetic composition |
| JP2000053524A (en) * | 1998-06-01 | 2000-02-22 | Ajinomoto Co Inc | Cosmetic composition |
| JP2000247844A (en) * | 1999-02-26 | 2000-09-12 | Shiseido Co Ltd | Hair cosmetic preparation |
| JP2000355516A (en) * | 1999-06-14 | 2000-12-26 | Ajinomoto Co Inc | New composition for cosmetic |
| JP2001039838A (en) * | 1999-07-30 | 2001-02-13 | Seiwa Kasei:Kk | Hair treatment agent |
| JP2002265337A (en) * | 2001-03-06 | 2002-09-18 | Nikko Seiyaku Kk | Hair cosmetic |
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