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JP4259340B2 - Construction method of compressed bentonite materials in radioactive waste disposal tunnels - Google Patents
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JP4259340B2 - Construction method of compressed bentonite materials in radioactive waste disposal tunnels - Google Patents

Construction method of compressed bentonite materials in radioactive waste disposal tunnels Download PDF

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JP4259340B2
JP4259340B2 JP2004038626A JP2004038626A JP4259340B2 JP 4259340 B2 JP4259340 B2 JP 4259340B2 JP 2004038626 A JP2004038626 A JP 2004038626A JP 2004038626 A JP2004038626 A JP 2004038626A JP 4259340 B2 JP4259340 B2 JP 4259340B2
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humidity
temperature
moisture content
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bentonite material
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JP2005227226A (en
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幹雄 畔柳
史浩 佐原
博之 日野
一三 小林
剛 笹倉
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Kajima Corp
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この発明は放射性廃棄物を地中に埋設して処分する放射性廃棄物処分坑道において、放射性廃棄物の周囲に緩衝材として設置される圧縮ベントナイト材の性能を長期に亘って維持できるように圧縮ベントナイト材を設置する圧縮ベントナイト材の施工方法に関するものである。   The present invention relates to a compressed bentonite so that the performance of the compressed bentonite material installed as a buffer material around the radioactive waste can be maintained for a long time in a radioactive waste disposal tunnel for burying radioactive waste in the ground and disposing it. It is related with the construction method of the compression bentonite material which installs material.

放射性廃棄物は放射能レベルの程度に応じ、セメント等により固められてドラム缶等の容器に封入された状態で、またはガラスと混合されたガラス固化体として炭素鋼等からなる容器内に封入された状態で、地下数10m〜1000m程度の深度に構築されるトンネル(処分坑道)の内部に埋設されて処分される。具体的には放射能レベルの比較的高い廃棄物は地下数100m〜1000m程度の深度に、比較的低い廃棄物は地下数10m〜100m程度の深度に埋設される。   Depending on the level of radioactivity, the radioactive waste is hardened with cement or the like and sealed in a container such as a drum can, or sealed in a container made of carbon steel or the like as a vitrified material mixed with glass. In the state, it is buried inside the tunnel (disposal tunnel) constructed at a depth of about 10m to 1000m underground and disposed of. Specifically, waste with a relatively high radioactivity level is buried at a depth of about several hundred meters to 1,000 m, and relatively low waste is buried at a depth of about several tens of meters to 100 m.

トンネル内に構築される鉄筋コンクリート造の構造躯体等と廃棄体との間には廃棄体を固定し、安定させるためのモルタル等の充填材が充填され、構造躯体等と周辺地盤との間には地下水の浸入や放射性物質の移動を抑制するために人工バリアとしての緩衝材が設置される。   Filling material between reinforced concrete structures built in the tunnel and the waste and the waste is filled with fillers such as mortar to fix and stabilize the waste, and between the structure and the surrounding ground In order to suppress the ingress of groundwater and the movement of radioactive materials, a buffer material is installed as an artificial barrier.

緩衝材には透水性が小さく、水の浸透を抑える性質を有するベントナイトが利用されるが(特許文献1、特許文献2参照)、緩衝材としてのベントナイトは透水性をより低下させるために単独で、または砂と混合された状態で締め固められ、圧縮された形で使用され、背面は地盤に密着し、表面はコンクリート等によって被覆され、外気に接触しない状態に置かれる(特許文献3、特許文献4参照)。
特開2003-279689号公報 特開2003-255087号公報 特開平9-304596号公報 特開2002-6089号公報
Bentonite having low water permeability and a property of suppressing water permeation is used as the buffer material (see Patent Document 1 and Patent Document 2), but bentonite as the buffer material alone is used to further reduce water permeability. Or, it is compacted in a state of being mixed with sand and used in a compressed form, the back surface is in close contact with the ground, the surface is covered with concrete or the like, and is not in contact with the outside air (Patent Document 3, Patent Reference 4).
JP 2003-279689 A Japanese Patent Laid-Open No. 2003-255087 JP-A-9-304596 JP 2002-6089 A

圧縮ベントナイト材は設置完了後の使用中には外気に接触しない環境下に置かれるため、設置完了後には圧縮ベントナイト材の性能の変状は抑制されると考えられるが、外気に接触する環境下に置かれたときには乾燥収縮や吸水膨潤を生じ、いずれの場合にもひび割れや変形、強度低下等の性能の変状が生ずるため、圧縮ベントナイト材の製作時から最終的な地中への設置完了までの施工中に性能が変状する可能性がある。   Compressed bentonite materials are placed in an environment that does not come into contact with outside air during use after the installation is completed, so it is considered that the deformation of the performance of compressed bentonite materials will be suppressed after the installation is completed. When it is placed on the floor, it causes drying shrinkage and water absorption swelling, and in all cases, cracks, deformation, deterioration of performance, such as strength reduction, occur, so the installation of the compressed bentonite material from the production to the final underground is completed There is a possibility that the performance will be changed during construction.

この発明は上記背景より、施工中に性能の変状を招かない施工方法を提案するものである。   This invention proposes the construction method which does not cause the deformation | transformation of a performance during construction from the said background.

請求項1ではベントナイト、またはベントナイトと砂の混合材料を高密度に圧縮して製作された圧縮ベントナイト材に、それが設置される地中の処分坑道内の温度と湿度の条件下で変動を生じにくい範囲に設定された含水比の水分を予め与えておき、その圧縮ベントナイト材を、廃棄物を包囲するように処分坑道の壁面に沿い、処分坑道の周方向に連続的に設置することにより、圧縮ベントナイト材と大気との水分のやり取りを回避し、施工中に圧縮ベントナイト材の性能が変状することを抑制する。   In claim 1, the bentonite material produced by compressing bentonite or a mixed material of bentonite and sand at high density is subject to fluctuations under the conditions of temperature and humidity in the underground disposal tunnel where it is installed. By providing moisture with a moisture content ratio set in a difficult range in advance, the compressed bentonite material is continuously installed in the circumferential direction of the disposal tunnel along the wall of the disposal tunnel so as to surround the waste, It avoids the exchange of moisture between the compressed bentonite material and the atmosphere, and suppresses the deformation of the performance of the compressed bentonite material during construction.

請求項3では設置完了後に任意の含水比を有する圧縮ベントナイト材を、廃棄物を包囲するように処分坑道の壁面に沿い、周方向に連続的に設置し、その直後に圧縮ベントナイト材の大気との接触面を、処分坑道内における温度と湿度の条件下で含水比に変動を生じにくい範囲に、予め温度毎の湿度と最適な含水比の関係から決められた初期含水比を有する捨て圧縮ベントナイト材で覆うことにより、圧縮ベントナイト材の大気との接触を回避し、施工中に圧縮ベントナイト材の性能が変状することを抑制する。   In claim 3, after the installation is completed, the compressed bentonite material having an arbitrary water content ratio is continuously installed in the circumferential direction along the wall of the disposal mine so as to surround the waste. Abandoned compressed bentonite having an initial moisture content determined in advance from the relationship between the humidity at each temperature and the optimum moisture content within a range where the moisture content does not easily fluctuate under the temperature and humidity conditions in the disposal tunnel By covering with the material, the contact of the compressed bentonite material with the atmosphere is avoided, and the performance of the compressed bentonite material is prevented from changing during construction.

請求項3の場合、圧縮ベントナイト材は捨て圧縮ベントナイト材で覆われるため、圧縮ベントナイト材の初期含水比は任意である。圧縮ベントナイト材の含水比は製作時の締固め易さ(圧縮し易さ)、運搬や設置時に必要な強度、処分坑道閉鎖後の廃棄体の熱を放出させるための熱伝導性の確保等に影響するため、上記圧縮ベントナイト材の「任意の含水比」はこれらの条件から決められる。   In the case of claim 3, since the compressed bentonite material is discarded and covered with the compressed bentonite material, the initial moisture content of the compressed bentonite material is arbitrary. The moisture content of the compressed bentonite material is easy to compact during production (easy to compress), necessary strength during transportation and installation, ensuring heat conductivity to release the heat of waste after disposal tunnel closure, etc. Therefore, the “arbitrary water content ratio” of the compressed bentonite material is determined from these conditions.

請求項1における圧縮ベントナイト材と請求項3における捨て圧縮ベントナイト材はそれが実際に設置される処分坑道内の温度と湿度の条件下で含水比に変動を生じにくい範囲に、予め温度毎の湿度と最適な含水比の関係から決められた初期含水比を有した状態で製作され、この初期含水比は後述するように一定温度と一定湿度の環境下での長期に亘る曝露試験の結果から得られた、温度毎の、すなわち温度をパラメータとする湿度と最終含水比の関係を示す図9の直線から決められる。   The compressed bentonite material according to claim 1 and the discarded compressed bentonite material according to claim 3 are preliminarily subjected to humidity at each temperature within a range in which the water content ratio hardly changes under the temperature and humidity conditions in the disposal tunnel in which the compressed bentonite material is actually installed. The initial moisture content is determined from the results of long-term exposure tests in a constant temperature and humidity environment, as will be described later. It is determined from the straight line of FIG. 9 showing the relationship between the humidity and the final water content ratio for each temperature, that is, using temperature as a parameter.

最終含水比は異なる初期含水比を与えて製作された複数の圧縮ベントナイト材がその後、一定温度と一定湿度の環境下で一定期間以上曝露を受けた結果として収束する含水比の大きさであるから、一定温度と一定湿度の環境下での長期に亘る曝露を受けても変動を生じない初期含水比の値であると言える。   The final moisture content is the size of the moisture content that converges as a result of exposure to a plurality of compressed bentonite materials with different initial moisture content after being exposed for a certain period of time in a constant temperature and humidity environment. It can be said that it is a value of the initial moisture content which does not change even if it is exposed for a long period of time in a constant temperature and constant humidity environment.

よって初期含水比としてこの最終含水比を有するように請求項1における圧縮ベントナイト材と請求項3における捨て圧縮ベントナイト材を予め製作しておき、最終含水比を決めた一定温度と一定湿度と同じ条件下にある処分坑道内にその圧縮ベントナイト材や捨て圧縮ベントナイト材を置くことで、圧縮ベントナイト材や捨て圧縮ベントナイト材と大気との間で水分のやり取りがなくなるため、圧縮ベントナイト材や捨て圧縮ベントナイト材の性能の変状が抑制されることになる。請求項3の場合は捨て圧縮ベントナイト材と大気との間での水分のやり取りがなくなる結果、それに覆われた圧縮ベントナイト材と大気との間での水分のやり取りもなくなるため、施工中に圧縮ベントナイト材の性能が変状することが抑制される。   Therefore, the compressed bentonite material in claim 1 and the discarded compressed bentonite material in claim 3 are prepared in advance so as to have this final moisture content as the initial moisture content, and the final moisture content is determined under the same conditions as the constant temperature and constant humidity. By placing the compressed bentonite material or discarded compressed bentonite material in the disposal tunnel below, there is no exchange of moisture between the compressed bentonite material or discarded compressed bentonite material and the atmosphere, so compressed bentonite material or discarded compressed bentonite material The deformation of the performance is suppressed. In the case of claim 3, since there is no exchange of moisture between the discarded compressed bentonite material and the atmosphere, there is no exchange of moisture between the compressed bentonite material covered with the atmosphere and the compressed bentonite material during construction. It is possible to suppress the deformation of the material performance.

請求項1では処分坑道内に圧縮ベントナイト材を設置した時点で初期含水比が調整された圧縮ベントナイト材と大気との間では水分の出入りがなく、請求項3では初期含水比が調整された捨て圧縮ベントナイト材で圧縮ベントナイト材の大気との接触面が覆われることで、捨て圧縮ベントナイト材を設置した時点で捨て圧縮ベントナイト材と大気との間で水分の出入りがないため、いずれの場合も圧縮ベントナイト材の水分量に変動は生じない。   In claim 1, there is no moisture in and out of the compressed bentonite material whose initial moisture content is adjusted at the time of installation of the compressed bentonite material in the disposal mine, and in claim 3, the discarding whose initial moisture content is adjusted Since the contact surface of the compressed bentonite material with the atmosphere is covered with the compressed bentonite material, there is no moisture in and out of the discarded compressed bentonite material and the atmosphere when the discarded compressed bentonite material is installed. There is no fluctuation in the water content of the bentonite material.

例えば図9にプロットした点のように処分坑道内の温度が20℃、湿度(絶対湿度量)が約8.6g/m3であるとすれば、最終含水比を示す縦軸から圧縮ベントナイト材に約4.6%の初期含水比を与えれば、圧縮ベントナイト材の含水比に変動が生じにくいことになる。同様に処分坑道内の温度が20℃、湿度(絶対湿度量)が約20.0g/m3であるとすれば、最終含水比を示す縦軸から圧縮ベントナイト材に約11.6%の初期含水比を与えればよいことになる。 For example, if the temperature in the disposal tunnel is 20 ° C and the humidity (absolute humidity) is about 8.6g / m 3 as plotted in Fig. 9, the vertical axis indicating the final moisture content is changed to the compressed bentonite material. If an initial moisture content of about 4.6% is given, fluctuations in the moisture content of the compressed bentonite material are less likely to occur. Similarly, if the temperature in the disposal tunnel is 20 ° C and the humidity (absolute humidity) is about 20.0 g / m 3 , the initial moisture content of the compressed bentonite material is about 11.6% from the vertical axis indicating the final moisture content. Give it.

最終含水比は一定温度の下では絶対湿度にほぼ比例すると考えられるから、図9のように温度をパラメータとして横軸に絶対湿度量を取り、縦軸に最終含水比を取ることで、直線上の横座標(絶対湿度量)が分かれば、縦座標(最終含水比)が求まるため、処分坑道内の温度と湿度から、圧縮ベントナイト材に与えるべき最適な初期含水比を決めることができる。   Since the final moisture content is considered to be almost proportional to the absolute humidity at a fixed temperature, the absolute humidity is plotted on the horizontal axis with the temperature as a parameter, and the final moisture content is plotted on the vertical axis. If the abscissa (absolute humidity amount) is known, the ordinate (final moisture content) can be obtained, and the optimum initial moisture content to be given to the compressed bentonite material can be determined from the temperature and humidity in the disposal tunnel.

逆に縦座標(最終含水比)を決めれば、横座標(絶対湿度量)を決めることもできるため、圧縮ベントナイト材に与えた初期含水比から、その含水比を維持させるのに最適な環境となる処分坑道内の温度と湿度を決めることができる。請求項2、請求項4ではこの関係に基づいて処分坑道内の温度と湿度を一定範囲に維持するための空調管理が行われる。   Conversely, if the ordinate (final moisture content) is determined, the abscissa (absolute humidity) can also be determined. Therefore, the optimum moisture content can be maintained from the initial moisture content given to the compressed bentonite material. The temperature and humidity in the disposal mine can be determined. In claims 2 and 4, air conditioning management is performed based on this relationship to maintain the temperature and humidity in the disposal tunnel within a certain range.

請求項2、請求項4では圧縮ベントナイト材や捨て圧縮ベントナイト材の設置開始から設置完了までの施工中、圧縮ベントナイト材の製作時の初期含水比を決めた温度と湿度となるように処分坑道内の温度と湿度を一定範囲に維持することにより、施工中に圧縮ベントナイト材や捨て圧縮ベントナイト材の性能が変状することを回避する。   In claim 2 and claim 4, during construction from the start of installation of compressed bentonite material and discarded compressed bentonite material to completion of installation, the initial moisture content at the time of production of compressed bentonite material is set to a temperature and humidity within the disposal tunnel. By maintaining the temperature and humidity within a certain range, the performance of the compressed bentonite material or the discarded compressed bentonite material is prevented from changing during construction.

処分坑道内の温度と湿度の管理は地上から取り入れた外気の温度と湿度を処分坑道内において空調機を用いて制御することにより行われる。   The temperature and humidity in the disposal tunnel are managed by controlling the temperature and humidity of the outside air taken from the ground using an air conditioner in the disposal tunnel.

圧縮ベントナイト材の初期含水比は処分坑道内の温度及び湿度と最終含水比の関係から決められていることから、施工期間中の処分坑道内の温度と湿度が圧縮ベントナイト材の初期含水比を決めた温度と湿度となるように一定範囲に保たれることで、設置開始から設置完了までの施工中に圧縮ベントナイト材や捨て圧縮ベントナイト材の初期含水比に変動が生ずるような環境の変化がないため、施工中に圧縮ベントナイト材や捨て圧縮ベントナイト材の性能が変状することが回避されることになる。   Since the initial moisture content of the compressed bentonite material is determined from the relationship between the temperature and humidity in the disposal tunnel and the final moisture content, the temperature and humidity in the disposal tunnel during the construction period determine the initial moisture content of the compressed bentonite material. By maintaining the temperature and humidity within a certain range, there is no change in the environment that causes fluctuations in the initial moisture content of the compressed bentonite material or the discarded compressed bentonite material during construction from the start of installation to the completion of installation. Therefore, it is avoided that the performance of the compressed bentonite material or the discarded compressed bentonite material changes during the construction.

請求項1ではベントナイト、またはベントナイトと砂の混合材料を高密度に圧縮して製作され、地中の処分坑道内の温度と湿度の条件下で変動を生じにくい範囲に設定された初期含水比の水分を予め与えておいた圧縮ベントナイト材を処分坑道内に設置するため、圧縮ベントナイト材と大気との間での水分のやり取りがなくなり、施工中に圧縮ベントナイト材の性能が変状することを抑制することができる。   In claim 1, bentonite or a mixed material of bentonite and sand is manufactured to a high density, and the initial moisture content is set within a range that does not easily fluctuate under conditions of temperature and humidity in the underground disposal tunnel. Since the compressed bentonite material that has been given moisture is installed in the disposal tunnel, there is no exchange of moisture between the compressed bentonite material and the atmosphere, and the performance of the compressed bentonite material is prevented from changing during construction. can do.

請求項2では請求項1において圧縮ベントナイト材の設置開始から設置完了までの施工中、圧縮ベントナイト材の製作時の初期含水比を決めた温度と湿度となるように処分坑道内の温度と湿度を一定範囲に維持するため、設置開始から設置完了までの施工中に圧縮ベントナイト材の初期含水比に変動が生ずるような環境の変化がなく、施工中に圧縮ベントナイト材の性能が変状することを回避することができる。   In claim 2, the temperature and humidity in the disposal tunnel are set so that the initial moisture content ratio at the time of production of the compressed bentonite material is determined during the construction from the start of installation of the compressed bentonite material to the completion of installation. In order to maintain a certain range, there is no change in the environment that causes a change in the initial moisture content of the compressed bentonite material during the construction from the start of installation to the completion of the installation, and the performance of the compressed bentonite material changes during construction. It can be avoided.

請求項3では任意の含水比を有する圧縮ベントナイト材を設置した直後に圧縮ベントナイト材の大気との接触面を、処分坑道内における温度と湿度の条件下で含水比に変動を生じにくい範囲に、予め温度毎の湿度と最適な含水比の関係から決められた初期含水比を有する捨て圧縮ベントナイト材で覆うため、捨て圧縮ベントナイト材と大気との間での水分のやり取りがなくなる結果、それに覆われた圧縮ベントナイト材と大気との間での水分のやり取りもなくなり、施工中に圧縮ベントナイト材の性能が変状することを抑制することができる。   In claim 3, immediately after installing the compressed bentonite material having an arbitrary water content, the contact surface of the compressed bentonite material with the atmosphere is within a range in which the water content ratio is less likely to change under the conditions of temperature and humidity in the disposal tunnel, Since it is covered with a discarded compressed bentonite material having an initial moisture content determined in advance from the relationship between the humidity at each temperature and the optimum moisture content, there is no exchange of moisture between the discarded compressed bentonite material and the atmosphere, which is covered by it. Further, there is no exchange of moisture between the compressed bentonite material and the atmosphere, and the performance of the compressed bentonite material can be prevented from changing during construction.

請求項4では請求項3において捨て圧縮ベントナイト材の設置開始から設置完了までの施工中、捨て圧縮ベントナイト材の製作時の初期含水比を決めた温度と湿度となるように処分坑道内の温度と湿度を一定範囲に維持するため、設置開始から設置完了までの施工中に捨て圧縮ベントナイト材の初期含水比に変動が生ずるような環境の変化がなく、施工中の捨て圧縮ベントナイト材と大気との間での水分のやり取りがなくなる結果、それに覆われた圧縮ベントナイト材と大気との間での水分のやり取りもなくなり、圧縮ベントナイト材の性能が変状することを抑制、または回避することができる。   In claim 4, during the construction from the start of installation of the discarded compressed bentonite material to the completion of installation in claim 3, the temperature in the disposal tunnel is determined so that the initial moisture content at the time of production of the discarded compressed bentonite material is determined. In order to maintain the humidity within a certain range, there is no change in the environment that causes a change in the initial moisture content of the compressed compressed bentonite material during the construction from the start of installation to the completion of the installation. As a result, there is no exchange of moisture between the compressed bentonite material covered with the atmosphere and the atmosphere, and it is possible to suppress or prevent the performance of the compressed bentonite material from changing.

[1]温度毎の湿度と最適な含水比の関係の導出
初めに表1〜表15、図1〜図9により、温度毎の湿度と最適な含水比の関係を導くために、表1に示す仕様のベントナイトから、一定温度と一定湿度の条件下で異なる初期含水比を有する複数の圧縮ベントナイト材の供試体を作成し、初期含水比の異なる複数の供試体群(グループ)毎に、それぞれ異なる温度と湿度の環境下で曝露試験を実施した結果を説明する。
[1] Derivation of the relationship between the humidity at each temperature and the optimum moisture content First, in order to derive the relationship between the humidity at each temperature and the optimum moisture content from Tables 1 to 15 and FIGS. From the bentonite with the specifications shown, we created specimens of multiple compressed bentonite materials with different initial moisture content under conditions of constant temperature and constant humidity, and for each of multiple specimen groups (groups) with different initial moisture contents, Explain the results of exposure tests under different temperature and humidity conditions.

[2]供試体の作成方法
供試体はベントナイト粉末と砂(ケイ砂3号+5号)を質量比7対3(ベントナイト:砂=7:3)で配合し、水分を加えて初期含水比の調整をした後、アムスラーを用い、密度1.6Mg/m3を目標に締固めて作成した。締固め容器としてVP管製モールド(φ=100mm、H=100mm)を用い、締固め後の供試体寸法は直径φ=100mm、高さH=50mmとした。
[2] Specimen preparation method The test specimen was bentonite powder and sand (silica sand No. 3 + No. 5) in a mass ratio of 7 to 3 (bentonite: sand = 7: 3), and water was added to adjust the initial moisture content. After adjustment, the density was set to 1.6Mg / m 3 using an Amsler. A VP tube mold (φ = 100 mm, H = 100 mm) was used as the compaction container, and the specimen dimensions after compaction were such that the diameter was φ = 100 mm and the height was H = 50 mm.

Figure 0004259340
Figure 0004259340

[3]実験ケース
実験ケースの一覧を表2に示す。
[3] Experimental cases Table 2 shows a list of experimental cases.

Figure 0004259340
Figure 0004259340

実験は供試体の暴露条件(温度、湿度)と拘束条件、供試体の初期含水比をパラメータとして実施した。   The experiment was performed using the exposure conditions (temperature, humidity) and restraint conditions of the specimen and the initial moisture content of the specimen as parameters.

温度は比較的高温の40℃と室温として20℃の2通りに設定し、湿度は多湿条件である95%と80%、及び自然雰囲気相当として約50%(20℃一定で、湿度管理なし)の3通りに設定した。供試体の初期含水比は自然含水比に相当する7%と、比較的飽和度の高い21%(飽和度Sr=82.2%)、及びその中間の14%の3通りに設定した。   The temperature is set in two ways: 40 ° C, which is a relatively high temperature, and 20 ° C, which is a room temperature. Humidity is 95% and 80%, which are humid conditions, and approximately 50%, which is equivalent to the natural atmosphere (constant at 20 ° C, without humidity control). Were set in three ways. The initial moisture content of the specimen was set to 3%, 7% corresponding to the natural moisture content, 21% with relatively high saturation (saturation Sr = 82.2%), and 14% in between.

含水比設定に際しては、ケイ砂30質量%混合の静的締固めにおける最適含水比(ωopt)10.4%(20MPa:2000年レポート「わが国における高レベル放射性廃棄物 地層処分の技術的信頼性」核燃料サイクル開発機構)、及び動的締固めにおける最適含水比(ωopt)17.0%(1Ec:2000年レポート(前掲))を参考にした。 When setting the water content, the optimum water content (ω opt ) 10.4% (20MPa: 2000 report “Technical reliability of high-level radioactive waste in geological disposal in Japan”) Cycle Development Organization) and the optimum water content ratio (ω opt ) in dynamic compaction 17.0% (1Ec: 2000 report (supra)).

供試体の拘束条件としては、実施工を想定した場合、緩衝材は側部および底部を拘束される状態で放置されることが想定されるため、ベントナイトが吸水し易いと予想される供試体の初期含水比7%と14%の2通りについて温度40℃、湿度95%の条件で供試体の側部、底部を拘束した実験を実施した。   As for the restraint condition of the specimen, since it is assumed that the cushioning material is left in a state where the side and bottom are restrained when the execution work is assumed, the bentonite is expected to absorb water easily. An experiment was conducted in which the side and bottom of the specimen were restrained under the conditions of a temperature of 40 ° C. and a humidity of 95% for two types of initial water content ratios of 7% and 14%.

表2中、No.1〜3が温度40℃、湿度80%の環境下に拘束なしで放置したグループ、No.4〜6が温度40℃、湿度95%の環境下に拘束なしで放置したグループ、No.7、8が温度40℃、湿度95%の環境下に拘束ありで放置したグループ、No.9〜11が温度20℃、湿度48%の環境下に拘束なしで放置したグループである。   In Table 2, groups No. 1 to 3 were left unconstrained in an environment with a temperature of 40 ° C. and humidity 80%, and Nos. 4 to 6 were left unconstrained in an environment with a temperature of 40 ° C. and humidity 95%. Groups No. 7 and 8 are groups left unconstrained in an environment with a temperature of 40 ° C and 95% humidity, and Nos. 9 to 11 are groups left unconstrained in an environment with a temperature of 20 ° C and humidity of 48%. is there.

[4]測定
表2に示す条件でのそれぞれの実験ケース(No.1〜11)で供試体を下記のように0.5日から3ヵ月の期間放置し、その期間における膨張、収縮、ひび割れ等の変化を把握するため、表3に示す測定を実施した。供試体の高さ方向には図1に示すように供試体を高さ方向に1cmの高さ毎にスライスして含水比分布を測定し、半径方向には図2に示すように高さ方向の中心部分において半径方向の中心寄り、外周寄り、中間部分の3箇所で含水比分布を測定した。
[4] In each experimental case (No. 1 to 11) under the conditions shown in Measurement Table 2, the specimen is left for a period of 0.5 to 3 months as shown below, and the expansion, contraction, cracking, etc. In order to grasp the change, the measurement shown in Table 3 was performed. In the height direction of the specimen, as shown in FIG. 1, the specimen is sliced every 1 cm in height, and the moisture content distribution is measured. In the radial direction, the height direction is as shown in FIG. The water content distribution was measured at three locations in the center portion of each of the center portion, the outer periphery portion, and the intermediate portion in the radial direction.

Figure 0004259340
Figure 0004259340

含水比の測定は供試体の放置後、No.1〜11の各ケースにつき、0.5日、1日、3日、1週、2週、1ヵ月、2ヵ月、3ヵ月が経過した時点で行ったが、測定は供試体を解体して試料を採取する必要があり、含水比測定を行った供試体はその後、継続して高さ、直径、質量等の測定に使用できないことから、各ケースの測定日(0.5日、1日、3日、1週、2週、1ヵ月、2ヵ月、3ヵ月後)用に供試体を作成した。供試体作成とそれぞれの測定間隔を表4に示す。   The moisture content is measured at the time when 0.5 days, 1 day, 3 days, 1 week, 2 weeks, 1 month, 2 months, 3 months have passed for each case of No. 1 to 11 after leaving the specimen. However, the measurement requires dismantling the specimen and collecting the sample, and the specimen that has been subjected to the moisture content measurement cannot subsequently be used for measurement of height, diameter, mass, etc. Specimens were prepared for the measurement days (0.5 days, 1 day, 3 days, 1 week, 2 weeks, 1 month, 2 months, 3 months later). Table 4 shows the specimen preparation and the measurement intervals.

Figure 0004259340
Figure 0004259340

[5]供試体作成状況
表4における供試体セット1〜8毎の供試体作成状況を表5〜表12に、3ヵ月後までの測定を実施した供試体セット8の高さ、直径、質量の変化を表13に示す。供試体セット8は供試体作成後、0.5日経過時から3ヵ月経過時まで含水比分布を測定したセットである。
[5] Specimen creation status Table 5 shows the specimen creation status for each of the specimen sets 1 to 8 in Table 5 to Table 12, and the height, diameter, and mass of the specimen set 8 measured up to 3 months later. Table 13 shows the changes. Specimen set 8 is a set in which the moisture content distribution was measured from 0.5 days to 3 months after the specimen was created.

Figure 0004259340
Figure 0004259340

Figure 0004259340
Figure 0004259340

Figure 0004259340
Figure 0004259340

Figure 0004259340
Figure 0004259340

Figure 0004259340
Figure 0004259340

Figure 0004259340
Figure 0004259340

Figure 0004259340
Figure 0004259340

Figure 0004259340
Figure 0004259340

Figure 0004259340
Figure 0004259340

[6]実験結果
図3〜図5にNo.1〜11のケース毎の供試体質量、直径、高さの経時変化を示す。ここでは測定期間が長期に渡る供試体セット6(1ヶ月間測定)、7(2ヶ月間測定)、8(3ヶ月間測定)の経時変化のみを示している。図3は初期含水比が7%のケースNo.1、4、7、9の結果を、図4は初期含水比が14%のケースNo.2、5、8、10の結果を、図5は初期含水比が21%のケースNo.3、6、11の結果を示す。
[6] Experimental Results FIGS. 3 to 5 show the changes over time in the specimen mass, diameter, and height for each of No. 1 to No. 11 cases. Here, only changes over time of specimen sets 6 (measured for one month), 7 (measured for two months), and 8 (measured for three months) over a long measurement period are shown. 3 shows the results of cases No. 1, 4, 7, and 9 with an initial moisture content of 7%, and FIG. 4 shows the results of cases No. 2, 5, 8, and 10 with an initial moisture content of 14%. Shows the results of cases Nos. 3, 6, and 11 with an initial moisture content of 21%.

図6、表14は全ケースNo.1〜11の鉛直方向(供試体の高さ方向)の含水比分布の経時変化を、図7、表15は全ケースNo.1〜11の水平方向(供試体の半径方向)の含水比分布の経時変化をそれぞれ示す。   Fig. 6 and Table 14 show the time-dependent changes in the moisture content distribution in the vertical direction (the height direction of the specimen) for all cases No. 1 to 11, and Fig. 7 and Table 15 show the horizontal direction for all cases No. 1 to 11 ( The time-dependent changes in the moisture content distribution in the radial direction of the specimen are shown.

Figure 0004259340
Figure 0004259340

Figure 0004259340
Figure 0004259340

[7]まとめ
(1) 質量、高さ、直径の経時変化について
1) 表13、図3〜図5から、初期含水比7%で、温度40℃、湿度80%の環境下及び温度40℃、湿度95%の環境下(No.1、4、7)では、供試体が吸水・膨潤し、質量が増加することが確認された。但し、同じ初期含水比でも、温度20℃、湿度約50%の環境下(No.9)では、供試体が乾燥・収縮し、質量が減少した。
[7] Summary
(1) Changes in mass, height, and diameter over time
1) From Table 13 and Figs. 3 to 5, the initial moisture content is 7%, the temperature is 40 ° C, the humidity is 80%, and the temperature is 40 ° C, the humidity is 95% (No. 1, 4, 7). It was confirmed that the specimen absorbed and swelled, and the mass increased. However, even under the same initial moisture content, the specimen dried and contracted and the mass decreased under the environment of temperature 20 ° C. and humidity about 50% (No. 9).

2) その他のケース(No.2、3、5、6、8、10、11)では、供試体の質量は減少傾向にあり、供試体は乾燥・収縮側に推移することが確認された。   2) In the other cases (No. 2, 3, 5, 6, 8, 10, 11), it was confirmed that the mass of the specimen was decreasing and that the specimen moved to the dry / shrink side.

3) 吸水・膨潤による質量の増加は初期含水比7%、温度40℃、湿度95%(No.4)の場合が最も大きく、質量、直径、高さの変化量はそれぞれ28.3g(4.2%)、0.38cm(3.8%)、0.38cm(7.5%)であった。( )内は初期値に対する変化割合を示す。   3) Mass increase due to water absorption / swelling is greatest when the initial moisture content is 7%, temperature is 40 ° C, and humidity is 95% (No. 4). The amount of change in mass, diameter, and height is 28.3 g (4.2% ), 0.38 cm (3.8%), and 0.38 cm (7.5%). Figures in parentheses indicate the rate of change relative to the initial value.

4) 乾燥・収縮による質量の減少は初期含水比21%、温度20℃、湿度約50%(No.11)の場合が最も大きく、質量、直径、高さの変化量はそれぞれ-108.6g(-14.2%)、-0.17cm(-1.7%)、-0.12cm(-2.4%)であった。   4) Mass loss due to drying / shrinkage is greatest when the initial moisture content is 21%, temperature is 20 ° C, and humidity is about 50% (No. 11). The amount of change in mass, diameter, and height is -108.6g ( -14.2%), -0.17 cm (-1.7%), and -0.12 cm (-2.4%).

(2) 含水比分布の経時変化について
1) 吸水・膨潤による平均含水比の増加は初期含水比7%、温度40℃、湿度95%(No.4)の場合が最も大きく、含水比の変化量は3.8%であった(表13)。
(2) Change in moisture content distribution over time
1) The increase in the average water content due to water absorption / swelling is greatest when the initial water content is 7%, the temperature is 40 ° C, and the humidity is 95% (No. 4), and the change in the water content is 3.8% (Table 13). ).

2) 乾燥・収縮による平均含水比の減少は初期含水比21%、温度20℃、湿度(約50%)(No.11)の場合が最も大きく、平均含水比の変化量は-16.3%であった(表13)。   2) The decrease in the average moisture content due to drying / shrinkage is greatest when the initial moisture content is 21%, the temperature is 20 ° C, and the humidity (about 50%) (No. 11). The change in the average moisture content is -16.3%. (Table 13).

3) 鉛直方向の含水比分布の経時変化より、大気と接している供試体上面から吸水及び乾燥の変化が始まり、徐々に下部へと影響が及ぶ傾向が見られた(表14、図6)。   3) As the moisture content distribution in the vertical direction changed with time, the water absorption and drying started to change from the upper surface of the specimen in contact with the atmosphere, and gradually tended to affect the lower part (Table 14, Fig. 6). .

4) 水平方向の含水比分布の経時変化より、大気と接している供試体表面から吸水及び乾燥の変化が始まり、徐々に中心部へと影響が及ぶ傾向が見られた(表15、図7)。   4) From the time-dependent change in the moisture content distribution in the horizontal direction, changes in water absorption and drying started from the surface of the specimen in contact with the atmosphere, and there was a tendency to gradually affect the center (Table 15, Fig. 7). ).

(3) ひび割れの状況について
1) 吸水・膨潤が生じたNo.1、4、7の場合、ひび割れの程度は供試体の含水比と大気条件によって異なるが、条件の厳しい初期含水比7%、温度40℃、湿度95%(No.4)の場合、最もひび割れが顕著に発生した。ひび割れは供試体表面全体に亀甲状に発生し、上面の隅角部では、隅角部がはがれるように円形状に発生した。また吸水・膨潤が生じたケースでは、供試体内部の含水比も上昇することが確認された。したがってひび割れが発生していない供試体内部に関しても、ある程度強度が低下することが予想される。
(3) About the crack situation
1) In the case of No. 1, 4 and 7 where water absorption / swelling occurred, the degree of cracking varies depending on the moisture content of the specimen and the atmospheric conditions, but the severe moisture initial moisture content is 7%, temperature is 40 ° C, and humidity is 95%. In the case of (No. 4), the most cracking occurred. Cracks occurred in the shape of a turtle shell on the entire surface of the specimen, and in the corners on the top surface, they occurred in a circular shape so that the corners were peeled off. In the case of water absorption / swelling, it was confirmed that the water content ratio inside the specimen also increased. Therefore, it is expected that the strength will decrease to some extent even within the specimen where cracks have not occurred.

2) 乾燥・収縮が生じたNo.2、3、5、6、9〜11では、ひび割れは主に供試体表面に亀甲状に発生した。ひび割れの程度は供試体の含水比と大気条件によって異なるが、条件の厳しい初期含水比21%、温度20℃、湿度(約50%)のNo.11では、供試体を貫通するひび割れも観察された。貫通ひび割れは供試体の底面の方においてひび割れ幅が大きく発生していることが観察された。供試体の大気と接触している表面部分から乾燥収縮し、この現象は徐々に供試体内部に達する(図8)。   2) In Nos. 2, 3, 5, 6, 9 to 11 where drying / shrinkage occurred, cracks occurred mainly in the shape of a turtle shell on the surface of the specimen. The degree of cracking varies depending on the moisture content of the specimen and the atmospheric conditions. However, cracks penetrating the specimen were also observed at No. 11 with a severe initial moisture content of 21%, temperature of 20 ℃, and humidity (about 50%). It was. It was observed that the through crack had a large crack width at the bottom of the specimen. The surface of the specimen that is in contact with the atmosphere is dried and contracted, and this phenomenon gradually reaches the inside of the specimen (FIG. 8).

3) 各大気条件の中では、ひび割れの発生が顕著ではない供試体も確認された。温度40℃、湿度80%の条件下ではNo.1(初期含水比7%)、温度40℃、湿度95%の条件下ではNo.5(初期含水比14%)、温度20℃、湿度約50%の条件下ではNo.9(初期含水比7%)のケースがこれに該当する。これらのケースは含水比の変化量が、同条件下での他のケースと比較して小さいと言える(表14)。   3) In each atmospheric condition, specimens where cracking was not noticeable were also confirmed. No.1 under conditions of 40 ℃ and humidity 80% (initial moisture content 7%), No.5 under conditions of temperature 40 ℃ and humidity 95% (initial moisture content 14%), temperature 20 ℃, humidity approx. This corresponds to the case of No. 9 (initial water content ratio 7%) under the condition of 50%. In these cases, the amount of change in water content is small compared to other cases under the same conditions (Table 14).

(4) 拘束の影響について
1) 温度40℃、湿度95%において、初期含水比7%の拘束なしのNo.4と、拘束ありのNo.7では、共に吸水・膨潤側に推移し、供試体の質量や平均含水比の変化に大きな違いは見られなかった。しかし、ひび割れに関しては、拘束ありのNo.7においてひび割れが抑制されることが観察された(質量変化量はNo.4:28.3g、No.7:28.7g、平均含水比の変化はNo.4:3.8%、No.7:3.7%)(表13)。
(4) Influence of restraint
1) At a temperature of 40 ° C and a humidity of 95%, both No. 4 with an initial moisture content of 7% and No. 7 with a constraint are on the water-absorbing / swelling side. There was no significant difference in changes. However, with regard to cracking, it was observed that cracking was suppressed in No. 7 with restraint (mass change was No. 4: 28.3 g, No. 7: 28.7 g, and the change in average moisture content was No. 7. 4: 3.8%, No. 7: 3.7%) (Table 13).

2) 温度40℃、湿度95%において、供試体初期含水比14%の拘束なしのNo.5と、拘束ありのNo.8では、共に乾燥・収縮側に推移し、No.8の方が供試体質量や平均含水比の変化が若干小さかった(質量変化量はNo.5:-14.2g、No.8:-9.5g、平均含水比の変化量はNo.5:-3.5%、No.8:-2.8%)が、大きな差異はないと考えられる(表13)。   2) At a temperature of 40 ° C and a humidity of 95%, both No. 5 with no initial restraint of 14% moisture content and No. 8 with restraint moved to the dry / shrink side. Changes in specimen mass and average water content were slightly small (mass change was No. 5: -14.2 g, No. 8: -9.5 g, change in average water content was No. 5: -3.5%, No 0.8: -2.8%), but there seems to be no significant difference (Table 13).

[8]温度毎の湿度と最終含水比(初期含水比)の関係
上記(4)より拘束ありと拘束なしとでは最終含水比に大きな差異がないと考えられることから、表14の供試体セット8におけるケースNo.1〜3(温度40℃、湿度80%)、No.4〜6(温度40℃、湿度95%)、No.9〜11(温度20℃、湿度48%)の3ヶ月経過時点での含水比の平均値から、図9に示す温度(20℃、40℃)毎の湿度と最終含水比の関係を求めた。
[8] Relationship between humidity at each temperature and final moisture content (initial moisture content) From the above (4), it can be considered that there is no significant difference in the final moisture content between restrained and unconstrained. Cases No. 1 to 3 (temperature 40 ° C., humidity 80%), No. 4 to 6 (temperature 40 ° C., humidity 95%), No. 9 to 11 (temperature 20 ° C., humidity 48%) From the average value of the water content ratio at the time, the relationship between the humidity and the final water content for each temperature (20 ° C., 40 ° C.) shown in FIG. 9 was determined.

表14より温度20℃、湿度48%のときの平均最終含水比は4.6%、湿度(相対湿度)48%は絶対湿度に換算すれば約8.6g/m3であり、含水比は絶対湿度に比例すると考えられるから、図9に示す温度20℃の場合の絶対湿度と含水比の関係が正比例すると仮定した場合、同図に表す直線が描かれる。 From Table 14, the average final moisture content at a temperature of 20 ° C and a humidity of 48% is 4.6%, and the humidity (relative humidity) of 48% is approximately 8.6 g / m 3 when converted to absolute humidity. Since it is considered proportional, if it is assumed that the relationship between the absolute humidity and the water content ratio at the temperature of 20 ° C. shown in FIG.

同様に温度40℃、湿度80%のときの平均最終含水比は9.3%、温度40℃、湿度95%のときの平均最終含水比は10.8%、湿度(相対湿度)80%と湿度(相対湿度)95%の絶対湿度はそれぞれ約40.8g/m3、48.0g/m3であるから、図9に示す温度40℃の場合の絶対湿度と含水比の関係を表す直線が描かれる。これらの直線は圧縮ベントナイト材の設置環境下における温度毎の絶対湿度量に対する最適含水比を示している。 Similarly, when the temperature is 40 ° C and the humidity is 80%, the average final moisture content is 9.3%. When the temperature is 40 ° C and the humidity is 95%, the average final moisture content is 10.8%, and the humidity (relative humidity) is 80% and the humidity (relative humidity). ) respectively 95% of the absolute humidity of about 40.8 g / m 3, because it is 48.0 g / m 3, the straight line representing the relationship between the absolute humidity and the water content ratio in the case of the temperature 40 ° C. as shown in FIG. 9 is drawn. These straight lines show the optimum water content ratio with respect to the absolute humidity at each temperature in the installation environment of the compressed bentonite material.

図9に示すグラフから、例えば地中の処分坑道内の温度が20℃で、湿度(絶対湿度)が約8.6g/m3の場合には圧縮ベントナイト材に4.6%の初期含水比を与えておけば、圧縮ベントナイト材の含水比に変動が生じにくいと言えるため、少なくとも施工期間中に圧縮ベントナイト材の性能が変状することを抑制することができる。 From the graph shown in FIG. 9, for example, when the temperature in the underground disposal tunnel is 20 ° C. and the humidity (absolute humidity) is about 8.6 g / m 3 , an initial moisture content of 4.6% is given to the compressed bentonite material. If this is the case, it can be said that the moisture content of the compressed bentonite material is unlikely to vary, so that it is possible to suppress the performance of the compressed bentonite material from changing at least during the construction period.

また圧縮ベントナイト材に4.6%の初期含水比を与えながらも、地中の処分坑道内の温度が20℃以外で、湿度(絶対湿度)が約8.6g/m3以外の場合には圧縮ベントナイト材の設置開始時から設置完了までの間、処分坑道内の温度が20℃で、湿度(絶対湿度)が約8.6g/m3となるように処分坑道内の温度と湿度を管理することにより(請求項2)、施工期間中に圧縮ベントナイト材の性能が変状することを回避することができる。 Compressed bentonite material when the initial moisture content of 4.6% is given to the compressed bentonite material, but the temperature in the underground disposal tunnel is other than 20 ° C and the humidity (absolute humidity) is other than about 8.6 g / m 3 By controlling the temperature and humidity in the disposal tunnel so that the temperature in the disposal tunnel is 20 ° C and the humidity (absolute humidity) is about 8.6 g / m 3 from the start of installation to the completion of installation ( (2) The performance of the compressed bentonite material can be prevented from changing during the construction period.

圧縮ベントナイト材に4.6%の初期含水比を与えながらも、地中の処分坑道内の温度が20℃以外で、湿度(絶対湿度)が約8.6g/m3以外の場合にはまた、圧縮ベントナイト材を設置した直後に、圧縮ベントナイト材の大気との接触面を、処分坑道内の温度、湿度条件によって定められる、圧縮ベントナイト材の含水比に変状が生じない範囲の含水比を有する捨て圧縮ベントナイト材で覆うことで(請求項3)、施工期間中に圧縮ベントナイト材の性能が変状することを回避することができる。 Compressed bentonite is also used when the temperature in the underground disposal tunnel is other than 20 ° C and the humidity (absolute humidity) is other than about 8.6 g / m 3 while giving the initial moisture content of 4.6% to the compressed bentonite material. Immediately after installing the material, the compression contact of the compressed bentonite material with the atmosphere has a moisture content ratio that is determined by the temperature and humidity conditions in the disposal tunnel and does not cause a change in the moisture content of the compressed bentonite material. By covering with the bentonite material (Claim 3), it is possible to avoid the deformation of the performance of the compressed bentonite material during the construction period.

[9]圧縮ベントナイト材の施工手順
図10−(a)〜(e)は放射性廃棄物を地中に埋設して処分する廃棄物処分坑道において、上記のように処分坑道(以下単に坑道と言う)1内における温度と湿度の条件下で変動を生じにくい範囲に決められた初期含水比となる水分を予め与えておいた圧縮ベントナイト材の施工手順例を示す。坑道(処分坑道)1は廃棄物を封入した廃棄体4を定置するための処分坑道のことを言い、後述の、図13に示す送風側立坑8と処分坑道1をつなぐ主要坑道1Aとは区別される。図10は低レベル放射性廃棄物を対象とした場合を示している。
[9] Construction procedure of compressed bentonite materials Figures 10- (a) to (e) are waste disposal tunnels for burying radioactive waste in the ground and disposing of it as described above. 1) An example of a construction procedure of a compressed bentonite material in which moisture having an initial water content ratio determined in a range in which fluctuation is not likely to occur under conditions of temperature and humidity in 1 is given in advance. A mine tunnel (disposal mine) 1 is a disposal mine for placing a waste body 4 enclosing waste, and is distinguished from a main mine 1A connecting a blower side shaft 8 and a disposal mine 1 shown in FIG. Is done. FIG. 10 shows the case where low-level radioactive waste is targeted.

圧縮ベントナイト材は廃棄体4を包囲するように設置されるため、坑道1内の部位、例えば底部、側部、上部毎に分割された形で製作される。   Since the compressed bentonite material is installed so as to surround the waste body 4, the compressed bentonite material is manufactured in a form divided into parts in the mine shaft 1, for example, the bottom, the side, and the upper part.

掘削・覆工による坑道1の構築後、圧縮ベントナイト材の設置に先立ち、坑道1の底部と側部には埋戻し土、またはコンクリート等の埋戻し材5が充填される。   After the construction of the mine 1 by excavation and lining, prior to the installation of the compressed bentonite material, the bottom and sides of the mine 1 are filled with a backfill material 5 such as backfill soil or concrete.

底部と側部への埋戻し材5の充填後に、底部の埋戻し材5上に底部圧縮ベントナイト材61が設置され(a)、底部圧縮ベントナイト材61上に、側部の埋戻し材5の内周に沿って側部圧縮ベントナイト材62が設置される(c)。側部圧縮ベントナイト材62の設置と並行し、底部圧縮ベントナイト材61上と側部圧縮ベントナイト材62の内側にはコンクリートの打設やプレキャストコンクリートの設置等によりコンクリートピット2が構築される(b、c)。   After filling the bottom and side backfill materials 5, a bottom compressed bentonite material 61 is installed on the bottom backfill material 5 (a), and the side backfill material 5 is placed on the bottom compressed bentonite material 61. Side compressed bentonite material 62 is installed along the inner circumference (c). In parallel with the installation of the side compression bentonite material 62, a concrete pit 2 is constructed by placing concrete or precast concrete on the bottom compression bentonite material 61 and inside the side compression bentonite material 62 (b, c).

コンクリートピット2の構築後(c)、その内側に、廃棄体4を固定し、安定させるモルタル等、セメント系材料の充填材3を充填しながら充填材3の内側に廃棄体4が設置される(d)。廃棄体4の設置が完了し、その上部を充填材3で覆った後、その上に上部圧縮ベントナイト材63が設置される(d)。上部圧縮ベントナイト材63は坑道1の幅方向両側の側部圧縮ベントナイト材62、62に跨るように設置される。   After the construction of the concrete pit 2 (c), the waste body 4 is placed inside the filler 3 while filling the filler 4 with a cement-based material such as mortar that fixes and stabilizes the waste body 4 inside the concrete pit 2. (D). After the installation of the waste body 4 is completed and the upper part is covered with the filler 3, the upper compressed bentonite material 63 is installed thereon (d). The upper compressed bentonite material 63 is installed so as to straddle the side compressed bentonite materials 62 and 62 on both sides in the width direction of the tunnel 1.

上部圧縮ベントナイト材63の設置後(d)、その上に埋戻し土やコンクリート等の埋戻し材5を充填して圧縮ベントナイト材の設置作業が終了する(e)。   After the upper compressed bentonite material 63 is installed (d), the backfill material 5 such as backfill soil or concrete is filled thereon, and the installation work of the compressed bentonite material is completed (e).

図11は坑道1内の空調(温度と湿度)を管理しながら、圧縮ベントナイト材61〜63を設置する場合(請求項2)の圧縮ベントナイト材の施工要領を示す。圧縮ベントナイト材61〜63の設置手順は図10と同様である。空調の管理は圧縮ベントナイト材61〜63の設置開始から設置完了まで継続して行われる。   FIG. 11 shows a construction procedure of the compressed bentonite material when the compressed bentonite materials 61 to 63 are installed while controlling the air conditioning (temperature and humidity) in the tunnel 1 (Claim 2). The installation procedure of the compressed bentonite materials 61 to 63 is the same as that shown in FIG. The management of air conditioning is continuously performed from the start of installation of the compressed bentonite materials 61 to 63 to the completion of the installation.

地上の外気は地上と坑道1を連通させる送風側立坑8、または送風側立坑8内に配置される送風用ダクト9を通じて坑道1内まで送られ、坑道1内には坑道1に配置される空調用ダクト10を通じて供給され、坑道1内からは排気側立坑11、または排気用ダクト12を通じて地上へ排出される。   Outside air on the ground is sent to the inside of the tunnel 1 through the ventilation side shaft 8 that communicates the ground with the tunnel 1 or the ventilation duct 9 that is arranged in the ventilation side shaft 8, and the air conditioning that is arranged in the tunnel 1 in the tunnel 1 It is supplied through the duct 10 and discharged from the tunnel 1 to the ground through the exhaust side shaft 11 or the exhaust duct 12.

送風側立坑8側の地上においては送風側立坑8の地上部分に設置された外気導入装置13から送風用ダクト9内に外気が導入される。外気の温度、または温度と湿度は外気導入装置13に接続した空調機14で一旦調節され、温度調節、または温湿度調節された空気が送風側立坑8や送風用ダクト9を通じて坑道1まで送風される。   On the ground on the ventilation side shaft 8 side, outside air is introduced into the ventilation duct 9 from the outside air introduction device 13 installed on the ground portion of the ventilation side shaft 8. The temperature of the outside air, or the temperature and humidity are once adjusted by an air conditioner 14 connected to the outside air introducing device 13, and the air whose temperature is adjusted or temperature and humidity is adjusted is blown to the tunnel 1 through the ventilation side shaft 8 or the ventilation duct 9. The

送風された空気の温度と湿度は送風側立坑8や送風用ダクト9を通過する間に地温により上昇、または降下することが想定されるため、坑道1の入口では温湿度が変化した空気の温度と湿度が送風側立坑8や送風用ダクト9の下端位置に設置された空調機15により改めて調節され、温湿度調節された空気が空調用ダクト10の吹出口10aから坑道1内に供給される。図11、図12のように送風側立坑8の下端部の坑道1の入口において湿度調節を行う場合には地上での湿度調節は必ずしも必要とされない。   Since the temperature and humidity of the blown air are assumed to rise or fall due to the ground temperature while passing through the ventilation side shaft 8 and the ventilation duct 9, the temperature of the air whose temperature and humidity have changed at the entrance of the tunnel 1. And the humidity are adjusted again by the air conditioner 15 installed at the lower end position of the blower side shaft 8 or the blower duct 9, and the temperature and humidity adjusted air is supplied into the tunnel 1 from the outlet 10 a of the air conditioning duct 10. . When the humidity is adjusted at the entrance of the tunnel 1 at the lower end of the blower side shaft 8 as shown in FIGS. 11 and 12, the humidity adjustment on the ground is not necessarily required.

例えば温度が9℃、相対湿度が100%RH(絶対湿度量8.818 g/m3)の外気を坑道1内において温度20℃、相対湿度50%RH(絶対湿度量8.642 g/m3)の空気に調節して供給しようとする場合、外気導入装置13から送風用ダクト9内に導入された外気は坑道1に到達するまでの間に地温により15℃程度まで上昇し、相対湿度は60%RH(絶対湿度量7.694 g/m3)程度まで低下すると考えられるため、送風用ダクト9の下端部における空調機15では送風された空気の温度を5℃程度上昇させ、絶対湿度を僅かに上昇させる空調を行えばよいことになる。 For example, outside air with a temperature of 9 ° C and relative humidity of 100% RH (absolute humidity 8.818 g / m 3 ) in tunnel 1 is 20 ° C and relative humidity 50% RH (absolute humidity 8.642 g / m 3 ). When the air is to be adjusted and supplied, the outside air introduced into the air duct 9 from the outside air introduction device 13 rises to about 15 ° C. due to the ground temperature before reaching the tunnel 1, and the relative humidity is 60% RH. Since the air conditioner 15 at the lower end of the air duct 9 is considered to decrease to about (absolute humidity amount 7.694 g / m 3 ), the temperature of the blown air is increased by about 5 ° C., and the absolute humidity is slightly increased. Air conditioning should be performed.

図12は図11より詳細に空調管理する方法の例を示す。
地上では外気導入装置13により外気が取り入れられ、加熱用ヒーターと冷却用クーラーを備える温度調節器16(図11の空調機14に相当)により外気の温度調節が行われ、地上送風機18から温度調節された空気が送風側立坑8、または送風用ダクト9を通じて坑道1の入り口まで送風される。送風の際には温度調節器16に接続した温度センサー17により送風される空気の温度が監視され、温度が一定範囲内に保たれるよう管理される。一定範囲を外れれば空気は温度調節器16にフィードバックされる。
FIG. 12 shows an example of a method for air conditioning management in more detail than FIG.
On the ground, outside air is taken in by the outside air introduction device 13, and the temperature of the outside air is adjusted by a temperature controller 16 (corresponding to the air conditioner 14 in FIG. 11) including a heater and a cooling cooler, and the temperature is adjusted from the ground fan 18. The air thus blown is blown to the entrance of the mineway 1 through the blower side shaft 8 or the blower duct 9. When the air is blown, the temperature of the blown air is monitored by the temperature sensor 17 connected to the temperature controller 16, and the temperature is managed so as to be maintained within a certain range. The air is fed back to the temperature controller 16 if it falls outside a certain range.

温度調節器16で調節すべき空気の温度は外気温と送風側立坑8内の地温から、坑道1に到達するまでの間の温度変化を予測した上で、図11における坑道1入口の空調機15に相当し、坑道1内に設置された、加熱用ヒーターと冷却用クーラーを備える温度調節器20及び加湿器と除湿器を備える湿度調節器21による効率的な温湿度調節が行えるように設定される。   The air temperature to be adjusted by the temperature controller 16 is predicted from the outside air temperature and the ground temperature in the ventilation side shaft 8 until reaching the tunnel 1, and then the air conditioner at the entrance of the tunnel 1 in FIG. Equivalent to 15 and set up in the tunnel 1 so that efficient temperature and humidity adjustment can be performed by the temperature controller 20 equipped with a heater and cooling cooler and a humidity controller 21 equipped with a humidifier and dehumidifier Is done.

地上の温度調節器16によって坑道1内に供給すべき空気の温度を地温による変化を見込んで正確に調節しておくことができれば、坑道1内の温度調節器20は必ずしも設置される必要がない。   If the temperature of the air to be supplied into the tunnel 1 can be accurately adjusted with the temperature controller 16 on the ground in view of changes due to the ground temperature, the temperature controller 20 in the tunnel 1 does not necessarily have to be installed. .

但し、図13に示すように1本の送風側立坑8に付き、複数本の坑道1が構築され、送風側立坑8と各坑道1が主要坑道1Aで結ばれ、送風側立坑8の下端から各坑道1の入口までの距離が相違する場合には、送風側立坑8から各坑道1の入口に到達するまでの間の温度変化の程度に差が生ずるため、各坑道1内に温度調節器20が設置されることが適当である。   However, as shown in FIG. 13, a plurality of mine shafts 1 are constructed on one blast side shaft 8, and the blast side shaft 8 and each mine channel 1 are connected by a main mine channel 1A. When the distances to the entrances of the mine shafts 1 are different, there is a difference in the degree of temperature change from the blower side shaft 8 to the entrance of the mine shafts 1. It is appropriate that 20 is installed.

前記のように坑道1の入口まで送風された空気の温度と湿度は送風側立坑8、または送風用ダクト9を通過する間に地温による熱の供給や放出により変化することが想定されるため、温度調節器20と湿度調節器21による最終的な温湿度調節に先立ち、それらの手前に設置された温湿度センサー19により坑道1に送られる空気の温湿度が測定される。   As described above, the temperature and humidity of the air blown to the entrance of the tunnel 1 are assumed to change due to the supply and release of heat due to the ground temperature while passing through the ventilation side shaft 8 or the ventilation duct 9. Prior to the final temperature / humidity adjustment by the temperature controller 20 and the humidity controller 21, the temperature / humidity of the air sent to the tunnel 1 is measured by the temperature / humidity sensor 19 installed in front of them.

温湿度センサー19を通過した空気は温湿度センサー19による測定結果に基づき、坑道1内に供給すべき温度と湿度が温度調節器20と湿度調節器21により調節された状態で、これらに接続した送風機22から空調用ダクト10に送られ、その各所に接続した吹出口10aから坑道1内に供給される。   The air that passed through the temperature / humidity sensor 19 was connected to the temperature and humidity to be supplied into the tunnel 1 based on the measurement result of the temperature / humidity sensor 19 with the temperature controller 20 and the humidity controller 21 adjusted. The air is sent from the blower 22 to the air conditioning duct 10 and supplied into the tunnel 1 from the outlet 10a connected to each place.

坑道1内に供給された空気の温度と湿度は坑道1内の、圧縮ベントナイト材の設置箇所周辺に設置された温湿度センサー23により監視され、空気は圧縮ベントナイト材の設置作業期間中、温度調節器20と湿度調節器21のいずれか、または両者を経由して再度送風機22から空調用ダクト10に送られる。坑道1内の温度調節器20を設置しない場合は、温湿度センサー23により測定されたデータが地上の温度調節器16にフィードバックされ、そのデータに基づき、温度調節器16で調節すべき空気の温度が設定される。   The temperature and humidity of the air supplied into the tunnel 1 are monitored by a temperature / humidity sensor 23 installed around the installation site of the compressed bentonite material in the tunnel 1, and the air is adjusted during the installation period of the compressed bentonite material. The air is sent again from the blower 22 to the air conditioning duct 10 via either or both of the air conditioner 20 and the humidity controller 21. When the temperature controller 20 in the tunnel 1 is not installed, the data measured by the temperature / humidity sensor 23 is fed back to the temperature controller 16 on the ground, and the temperature of the air to be adjusted by the temperature controller 16 based on the data Is set.

吹出口10aから坑道1内に供給された空気は坑道1の出口付近に設置された排気装置24により排気側立坑11、または排気用ダクト12を通じて地上へ排出される。   Air supplied into the tunnel 1 from the outlet 10a is discharged to the ground through the exhaust side shaft 11 or the exhaust duct 12 by the exhaust device 24 installed near the exit of the tunnel 1.

坑道1内に供給される空気の温度が送風側立坑8、または送風用ダクト9を通過するときと同様に地温により変化し、その変化が圧縮ベントナイト材に影響することが想定される場合には、坑道1内に排気ダクト25を設置し、吹出口10aから坑道1内に供給された空気を強制的に排出することが必要となる場合がある。   When the temperature of the air supplied into the mine shaft 1 is changed by the ground temperature in the same manner as when passing through the ventilation side shaft 8 or the ventilation duct 9, and it is assumed that the change affects the compressed bentonite material. In some cases, it is necessary to install an exhaust duct 25 in the tunnel 1 and forcibly discharge the air supplied into the tunnel 1 from the outlet 10a.

図14は図10における圧縮ベントナイト材61〜63と同様に、坑道1内における温度と湿度の条件下で変動を生じにくい範囲に決められた初期含水比となる水分を予め与えておいた捨て圧縮ベントナイト材7を用いて圧縮ベントナイト材を覆う場合(請求項3)の圧縮ベントナイト材の施工手順を示す。   FIG. 14 shows the same compression bentonite materials 61 to 63 as shown in FIG. 10, abandoned compression in which moisture having an initial water content ratio determined in a range in which fluctuations are unlikely to occur under conditions of temperature and humidity in the tunnel 1 is given in advance. The construction procedure of the compressed bentonite material in the case of covering the compressed bentonite material with the bentonite material 7 (Claim 3) is shown.

この場合、図10の場合と同様に坑道1の構築、坑道1の底部と側部への埋戻し材5の充填後、底部の埋戻し材5上に底部圧縮ベントナイト材61を設置すると共に、その直後に底部圧縮ベントナイト材61の表面(上面)を捨て圧縮ベントナイト材7で覆い(a)、底部圧縮ベントナイト材61上に、側部の埋戻し材5の内周に沿って側部圧縮ベントナイト材62を設置すると共に(b)、その直後に側部圧縮ベントナイト材62の表面(側面)を捨て圧縮ベントナイト材7で覆うことが行われる(b、c)。   In this case, as in the case of FIG. 10, after the construction of the mine 1 and the filling of the backfill material 5 to the bottom and sides of the mineway 1, the bottom compressed bentonite material 61 is installed on the bottom backfill material 5, Immediately after that, the surface (upper surface) of the bottom compression bentonite material 61 is discarded and covered with the compression bentonite material 7 (a), and the side compression bentonite material 61 is formed on the bottom compression bentonite material 61 along the inner periphery of the side backfilling material 5. The material 62 is installed (b), and immediately thereafter, the surface (side surface) of the side compressed bentonite material 62 is discarded and covered with the compressed bentonite material 7 (b, c).

一方、底部圧縮ベントナイト材61上と側部圧縮ベントナイト材62の内側にコンクリートピット2を構築し(b、c)、更にコンクリートピット2の内側にモルタル等の充填材3を充填しながら廃棄体4を設置し(c、d)、廃棄体4の上部に充填材3を充填してその上に上部圧縮ベントナイト材63を設置すると共に、その直後に上部圧縮ベントナイト材63の表面(上面)を捨て圧縮ベントナイト材7で覆い(d)、その後、その上に埋戻し土やコンクリート等の埋戻し材5を充填する、という要領で圧縮ベントナイト材の設置作業が行われる。   On the other hand, a concrete pit 2 is constructed on the bottom compressed bentonite material 61 and on the inner side of the side compressed bentonite material 62 (b, c), and further, the waste material 4 while filling the concrete pit 2 with a filler 3 such as mortar. (C, d), and the upper part of the waste body 4 is filled with the filler 3 and the upper compressed bentonite material 63 is installed thereon, and immediately after that, the surface (upper surface) of the upper compressed bentonite material 63 is discarded. The installation work of the compressed bentonite material is performed in the manner of covering (d) with the compressed bentonite material 7 and then filling the backfill material 5 such as backfill soil or concrete.

図15は圧縮ベントナイト材61〜63の設置が完了した後の坑道1の内部を示す。(a)は坑道1の縦断面図、(b)は横断面図である。   FIG. 15 shows the inside of the tunnel 1 after the installation of the compressed bentonite materials 61 to 63 is completed. (a) is a longitudinal sectional view of the mine shaft 1 and (b) is a transverse sectional view.

請求項4に記載の発明は図14に示す請求項3に記載の発明の方法において図11、図12に示す請求項2に記載の発明の方法と同じく、坑道1内の空調(温度と湿度)を管理しながら、圧縮ベントナイト材61〜63と捨て圧縮ベントナイト材7を設置する方法である。   The invention of claim 4 is the same as the method of the invention of claim 3 shown in FIG. 14 and the method of the invention of claim 2 shown in FIG. 11 and FIG. ), The compressed bentonite materials 61 to 63 and the discarded compressed bentonite material 7 are installed.

高さ方向の含水比分布の測定箇所を示した供試体の斜視図である。It is the perspective view of the test body which showed the measurement location of the moisture content distribution of a height direction. 半径方向の含水比分布の測定箇所を示した供試体の平面図である。It is a top view of the specimen which showed the measurement location of the moisture content distribution of radial direction. 初期含水比が7%の供試体の1〜3ヶ月経過時の質量、直径、高さの変化を示したグラフである。It is the graph which showed the change of the mass, diameter, and height at the time of 1-3 months progress of the specimen with an initial moisture content of 7%. 初期含水比が14%の供試体の1〜3ヶ月経過時の質量、直径、高さの変化を示したグラフである。It is the graph which showed the change of the mass, diameter, and height at the time of 1-3 months progress of the specimen with an initial moisture content of 14%. 初期含水比が21%の供試体の1〜3ヶ月経過時の質量、直径、高さの変化を示したグラフである。It is the graph which showed the change of the mass, diameter, and height at the time of 1-3 months progress of the specimen with an initial moisture content of 21%. 全供試体の鉛直方向の含水比分布の経時変化を示したグラフである。It is the graph which showed the time-dependent change of the moisture content distribution of the perpendicular direction of all the test bodies. 全供試体の水平方向の含水比分布の経時変化を示したグラフである。It is the graph which showed the time-dependent change of the moisture content distribution of the horizontal direction of all the test bodies. 供試体のひび割れ発生状況を示した立面図である。It is the elevation which showed the crack generation situation of the specimen. 20℃下と40℃下での空気中の水分量と最終含水比の関係を示したグラフである。It is the graph which showed the relationship between the moisture content in the air under 20 degreeC and 40 degreeC, and a final moisture content. (a)〜(e)は請求項1に記載の方法の施工手順を示した坑道の断面図である。(a)-(e) is sectional drawing of the mine shaft which showed the construction procedure of the method of Claim 1. FIG. 請求項2に記載の方法での空調管理方法を示した概念図である。It is the conceptual diagram which showed the air-conditioning management method by the method of Claim 2. 図11より詳細に空調管理する方法を示した概念図である。FIG. 12 is a conceptual diagram showing a method for air conditioning management in more detail than FIG. 1本の送風側立坑に複数本の処分坑道が接続する場合の送風側立坑と処分坑道の関係を示した鳥瞰図である。It is the bird's-eye view which showed the relationship between the ventilation side shaft and a disposal tunnel when a plurality of disposal shafts connect to one ventilation side shaft. (a)〜(e)は請求項3に記載の方法の施工手順を示した坑道の断面図である。(a)-(e) is sectional drawing of the mine shaft which showed the construction procedure of the method of Claim 3. FIG. (a)は圧縮ベントナイト材の設置がし完了した坑道の内部を示した縦断面図、(b)は横断面図である。(a) is a longitudinal sectional view showing the inside of a mine shaft where the installation of the compressed bentonite material is completed, and (b) is a transverse sectional view.

符号の説明Explanation of symbols

1……処分坑道、1A……主要坑道、2……コンクリートピット、3……充填材、4……廃棄体、5……埋戻し材、
61……底部圧縮ベントナイト材、62……側部圧縮ベントナイト材、63……上部圧縮ベントナイト材、7……捨て圧縮ベントナイト材、
8……送風側立坑、9……送風用ダクト、10……空調用ダクト、10a……吹出口、11……排気側立坑、12……排気用ダクト、13……外気導入装置、14……空調機(地上)、15……空調機(坑道内)、
16……温度調節器、17……温度センサー、18……地上送風機、19……温湿度センサー、20……温度調節器、21……湿度調節器、22……送風機、23……温湿度センサー、24……排気装置、25……排気ダクト。
1 ... Disposal tunnel, 1A ... Main tunnel, 2 ... Concrete pit, 3 ... Filler, 4 ... Waste body, 5 ... Backfill material,
61 …… Bottom compression bentonite material, 62 …… Side compression bentonite material, 63 …… Top compression bentonite material, 7 …… Discarded compression bentonite material,
8 ... Blower side shaft, 9 ... Blower duct, 10 ... Air conditioning duct, 10a ... Air outlet, 11 ... Exhaust side shaft, 12 ... Exhaust duct, 13 ... Outside air introduction device, 14 ... ... air conditioner (ground), 15 ... air conditioner (in the tunnel),
16 …… Temperature controller, 17 …… Temperature sensor, 18 …… Ground blower, 19 …… Temperature and humidity sensor, 20 …… Temperature controller, 21 …… Humidity regulator, 22 …… Blower, 23 …… Temperature and humidity Sensor, 24 …… Exhaust device, 25 …… Exhaust duct.

Claims (4)

地中に埋設されて処分される放射性廃棄物の周囲に緩衝材として使用され、ベントナイト、またはベントナイトと砂の混合材料を高密度に圧縮して製作された圧縮ベントナイト材を地中の処分坑道内に設置する方法であり、予め得られている、一定温度と一定湿度の環境下で一定期間以上曝露を受けたときの温度毎の湿度と最終含水比の関係を用いて、処分坑道内における温度と湿度の条件下での最終含水比を求め、この最終含水比を初期含水比として製作された圧縮ベントナイト材を、前記放射性廃棄物を包囲するように処分坑道の壁面に沿い、周方向に連続的に設置する放射性廃棄物処分坑道における圧縮ベントナイト材の施工方法。 Compressed bentonite material made by compressing bentonite or a mixture of bentonite and sand with high density is used around radioactive waste that is buried and disposed of in the ground. The temperature in the disposal tunnel is obtained by using the relationship between the humidity and the final moisture content at each temperature when exposed for a certain period of time in a constant temperature and constant humidity environment. The final moisture content under the conditions of humidity and humidity is obtained, and the compressed bentonite material produced with this final moisture content as the initial moisture content is continuously circumferentially along the wall of the disposal tunnel so as to surround the radioactive waste. Of compressed bentonite material in a radioactive waste disposal mine installed in an industrial environment. 圧縮ベントナイト材の設置開始から設置完了までの施工中、圧縮ベントナイト材の製作時の初期含水比を決めた温度と湿度となるように処分坑道内の温度と湿度を一定範囲に維持する請求項1記載の放射性廃棄物処分坑道における圧縮ベントナイト材の施工方法。   2. During the construction from the start of installation of compressed bentonite material to the completion of installation, the temperature and humidity in the disposal tunnel are maintained within a certain range so that the initial moisture content at the time of production of the compressed bentonite material becomes the determined temperature and humidity. Construction method of compressed bentonite material in the radioactive waste disposal mine described. 地中に埋設されて処分される放射性廃棄物の周囲に緩衝材として使用され、ベントナイト、またはベントナイトと砂の混合材料を高密度に圧縮して製作された圧縮ベントナイト材を地中の処分坑道内に設置する方法であり、設置完了後に任意の含水比を有する圧縮ベントナイト材を、前記放射性廃棄物を包囲するように処分坑道の壁面に沿い、周方向に連続的に設置し、その直後に前記圧縮ベントナイト材の大気との接触面を、予め得られている、一定温度と一定湿度の環境下で一定期間以上曝露を受けたときの温度毎の湿度と最終含水比の関係を用いて、処分坑道内における温度と湿度の条件下での最終含水比を求め、この最終含水比を初期含水比として製作された捨て圧縮ベントナイト材で覆う放射性廃棄物処分坑道における圧縮ベントナイト材の施工方法。 Compressed bentonite material made by compressing bentonite or a mixture of bentonite and sand with high density is used around radioactive waste that is buried and disposed of in the ground. A compressed bentonite material having an arbitrary water content ratio after installation is installed along the wall of the disposal tunnel so as to surround the radioactive waste, and continuously installed in the circumferential direction immediately after that, Dispose of the contact surface of compressed bentonite with the atmosphere using the relationship between the humidity at each temperature and the final moisture content when the exposure surface is exposed for a certain period of time in a constant temperature and humidity environment. seeking final moisture ratio under conditions of temperature and humidity in the tunnel, the compression vent in radioactive waste disposal tunnel covering that the final water content in the initial water content ratio discarded compacted bentonite material was made as Construction method of the thread material. 捨て圧縮ベントナイト材の設置開始から設置完了までの施工中、捨て圧縮ベントナイト材の製作時の初期含水比を決めた温度と湿度となるように処分坑道内の温度と湿度を一定範囲に維持する請求項3記載の放射性廃棄物処分坑道における圧縮ベントナイト材の施工方法。   Request to maintain the temperature and humidity in the disposal tunnel within a certain range so that the initial moisture content at the time of production of the discarded compressed bentonite material will be the temperature and humidity during the construction from the start of installation of the discarded compressed bentonite material to the completion of the installation The construction method of the compression bentonite material in the radioactive waste disposal tunnel of claim | item 3.
JP2004038626A 2004-02-16 2004-02-16 Construction method of compressed bentonite materials in radioactive waste disposal tunnels Expired - Lifetime JP4259340B2 (en)

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