JP4337787B2 - Wastewater treatment method and treatment apparatus - Google Patents
Wastewater treatment method and treatment apparatus Download PDFInfo
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- JP4337787B2 JP4337787B2 JP2005226880A JP2005226880A JP4337787B2 JP 4337787 B2 JP4337787 B2 JP 4337787B2 JP 2005226880 A JP2005226880 A JP 2005226880A JP 2005226880 A JP2005226880 A JP 2005226880A JP 4337787 B2 JP4337787 B2 JP 4337787B2
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Description
本発明は排水の処理方法及び処理装置に係り、特にSS及び油分の希薄な排水(以下、「希薄排水」と称す。)とSS及び/又は油分の濃厚な排水(以下、「濃厚排水」と称す。)とをそれぞれ別々に凝集浮上分離処理するに当たり、濃厚排水処理系における凝集剤の使用量、更には浮上分離のための微細気泡量を低減して処理コストの低減を図る排水の処理方法及び処理装置に関する。 The present invention relates to a wastewater treatment method and treatment apparatus, and in particular, SS and oily lean wastewater (hereinafter referred to as “lean wastewater”) and SS and / or oily rich wastewater (hereinafter referred to as “rich wastewater”). Wastewater treatment method for reducing the processing cost by reducing the amount of flocculant used in the concentrated wastewater treatment system and further the amount of fine bubbles for flotation separation. And a processing apparatus.
従来、鉄鋼、機械、石油、繊維、金属、食品、皮革、洗濯などの工場排水や、ガソリンスタンド、レストランなどからの排水の処理方法として、排水を凝集処理した後、浮上分離する凝集浮上分離法が知られている。特に、エマルジョン化した油分や懸濁固形物質(SS)を含む含油排水は、そのままでは浮上分離することはできない。このため、凝集槽でPAC(ポリ塩化アルミニウム)等の無機凝集剤を添加して凝集処理した後、凝集処理水を浮上分離する必要がある。そして、この排水の凝集浮上分離に当たり、希薄な排水と濃厚な排水とをそれぞれ別々に凝集浮上分離する方法が知られている。 Conventionally, as a method of treating industrial wastewater such as steel, machinery, oil, fiber, metal, food, leather, laundry, etc., and wastewater from gasoline stations, restaurants, etc., the wastewater is agglomerated and then floated and separated. It has been known. In particular, oil-containing wastewater containing emulsified oil and suspended solid material (SS) cannot be floated and separated as it is. For this reason, after adding an inorganic flocculant such as PAC (polyaluminum chloride) in the coagulation tank and coagulating, it is necessary to float and separate the coagulated water. A method of coagulating, floating and separating dilute waste water and rich waste water separately is known for the coagulation floating separation of the waste water.
本出願人は先に、効率的な凝集処理を行って均一で大きな凝集フロックを得ることができる凝集処理装置として、
凝集処理槽と、液及び沈殿物が通過する通路を備え、上記凝集処理槽の内部を上下方向の複数の室に区分する少なくとも1つの仕切板と、上記仕切板で区分された夫々の室の内部を攪拌する攪拌手段と、凝集処理槽の内部に原水を上下方向に通水して処理水を取出すため該処理槽の上下一方の端部に設けられた原水の供給路と、他方の端部に設けられた処理水の取出路とを有することを特徴とする凝集処理装置(特開平10−337406号公報)
を提案した。
The present applicant first performs an efficient agglomeration process as an agglomeration processing apparatus capable of obtaining a uniform and agglomerated floc,
A coagulation treatment tank, a passage through which liquid and sediment pass, at least one partition plate that divides the interior of the coagulation treatment tank into a plurality of chambers in the vertical direction, and each chamber divided by the partition plate Stirring means for stirring the inside, raw water supply path provided at one of the upper and lower ends of the treatment tank for removing the treated water by passing the raw water up and down in the coagulation treatment tank, and the other end A coagulation treatment apparatus (Japanese Patent Laid-Open No. 10-337406) characterized by having a treated water take-out path provided in the section
Proposed.
また、加圧浮上装置として、次のような装置を提案した。
(1) 被処理水を加圧浮上分離処理する加圧浮上分離装置において、
槽体内が隔壁によって区画されることによって混合室と、浮上分離室とが設置され、
該混合室の下部であって且つ該隔壁の幅方向中央付近に向って被処理水を流出させるための流出口が設けられており、
該隔壁は、該槽体の底面から立ち上がり、その上端は槽体の水面位よりも下位に位置し、これによって、該隔壁の上側を通って、該混合室から浮上分離室へ水が流出するようになっており、
該混合室の底部のうち、該隔壁に近接して、且つ該隔壁の幅方向の中央付近の位置に、気体を溶解した加圧水を上向きに吐出する加圧水吐出口が設けられており、
該浮上分離室に浮上スラッジの取出手段が設けられていることを特徴とする加圧浮上分離装置(特願2005−33283号)。
Moreover, the following apparatus was proposed as a pressure levitation apparatus.
(1) In a pressurized flotation separation device for subjecting water to be treated to flotation separation under pressure,
By dividing the tank body by a partition wall, a mixing chamber and a floating separation chamber are installed,
An outlet for discharging the water to be treated is provided at the bottom of the mixing chamber and near the center in the width direction of the partition;
The partition wall rises from the bottom surface of the tank body, and its upper end is positioned lower than the water surface level of the tank body, whereby water flows out from the mixing chamber to the floating separation chamber through the upper side of the partition wall. And
Of the bottom of the mixing chamber, a pressurized water discharge port is provided near the partition and near the center in the width direction of the partition to discharge pressurized water in which the gas is dissolved upward.
A pressurization flotation separation device (Japanese Patent Application No. 2005-33283), wherein the flotation separation chamber is provided with a means for removing flotation sludge.
(2) 凝集反応水と加圧水とを混合室にて混合した後、浮上分離室にて浮上分離処理する加圧浮上分離装置であって、
槽体内が隔壁によって区画されることによって混合室と、浮上分離室とが設置され、
該隔壁は、該槽体の底面から立ち上がり、その上端は槽体の水面位よりも下位に位置し、これによって、該隔壁の上側を通って、該混合室から浮上分離室へ水が流出するようになっている加圧浮上分離装置において、
該混合室に気体を溶解した加圧水を吐出する加圧水吐出口が設けられており、
該混合室内に高分子凝集助剤を添加する添加手段が設けられていることを特徴とする加圧浮上分離装置(特願2005−40855号)。
(2) A pressurization flotation separation device that performs a flotation separation process in a flotation separation chamber after mixing agglomeration reaction water and pressurized water in a mixing chamber,
By dividing the tank body by a partition wall, a mixing chamber and a floating separation chamber are installed,
The partition wall rises from the bottom surface of the tank body, and its upper end is positioned lower than the water surface level of the tank body, whereby water flows out from the mixing chamber to the floating separation chamber through the upper side of the partition wall. In the pressurized flotation separation device,
A pressurized water discharge port for discharging pressurized water in which gas is dissolved in the mixing chamber;
A pressure flotation separation apparatus (Japanese Patent Application No. 2005-40855), characterized in that an addition means for adding a polymer coagulation aid is provided in the mixing chamber.
上記特願2005−33283号、特願2005−40855号の加圧浮上装置であれば、混合室で凝集処理水と凝集助剤としての高分子凝集剤及び微細気泡と混合して気泡が付着した凝集フロックを得、浮上分離室で浮上スカムと分離水とに効率的に分離することができる。即ち、上記特願2005−33283号及び特願2005−40855号に記載される装置であれば、混合室において、凝集処理水に高分子凝集剤を添加するのと同時に微細気泡を発生させて、旋回流により混合することにより、内部に強固に気泡を包含した気泡含有フロックを形成することができ、この気泡含有フロックを浮上分離室で効率的に浮上分離することができる。
排水を希薄排水と濃厚排水とで別々に凝集浮上分離処理する方法であれば、各々の排水に対して最適な条件で効率的な処理を行うことができるが、排水中のSSや油分等の汚濁物質量が多くなると排水の凝集処理に必要な凝集剤量も増大するため、SS及び/又は油分等の汚濁物質濃度の高い濃厚排水を凝集処理するために多量の凝集剤を必要とし、全体の薬剤コストが高くつくという欠点がある。また、浮上分離に当たり必要な微細気泡量は、気泡量とSS及び/又は油分等の汚濁物質量との比である気固比により決定されるため、濃厚排水を浮上分離するために多量の微細気泡を必要とし、このために大きな微細気泡発生設備が必要となり、全体の設備コスト、動力コストも高くつくという欠点がある。 If it is a method that separates and separates the wastewater into a dilute wastewater and a concentrated wastewater, it can be efficiently treated under optimum conditions for each wastewater. As the amount of pollutants increases, the amount of flocculant necessary for the agglomeration treatment of wastewater also increases, so a large amount of flocculant is required to agglomerate dense wastewater with a high concentration of pollutants such as SS and / or oil. There is a disadvantage that the cost of drugs is high. In addition, the amount of fine bubbles necessary for floating separation is determined by the gas-solid ratio, which is the ratio of the amount of bubbles and the amount of pollutants such as SS and / or oil, so a large amount of fine bubbles is required to float and separate concentrated wastewater. This requires bubbles, which necessitates a large fine bubble generating facility, and has the disadvantage that the overall facility cost and power cost are high.
本発明は上記従来の問題点を解決し、希薄排水と濃厚排水とをそれぞれ別々に凝集浮上分離処理するに当たり、濃厚排水処理系での凝集剤の使用量及び微細気泡の必要量を低減して処理コストの低減を図る排水の処理方法及び処理装置を提供することを目的とする。 The present invention solves the above-mentioned conventional problems, and reduces the amount of flocculant used in the concentrated wastewater treatment system and the necessary amount of fine bubbles when separately separating the concentrated wastewater and the concentrated wastewater. It is an object of the present invention to provide a wastewater treatment method and a treatment apparatus that reduce treatment costs.
本発明者らは、上記課題を解決すべく鋭意検討した結果、希薄排水の凝集浮上分離で得られた浮上スカムが、濃厚排水の凝集浮上分離における凝集剤として、また浮上助剤として有効に機能すること、従って、希薄排水の凝集浮上分離で得られた浮上スカムを濃厚排水に添加混合して凝集浮上分離することにより、濃厚排水処理系における凝集剤使用量及び微細気泡の必要量を大幅に削減できることを見出した。 As a result of intensive studies to solve the above-mentioned problems, the present inventors have found that the floating scum obtained by the coagulation and flotation of dilute wastewater effectively functions as a flocculant and a flotation aid in the coagulation and flotation of concentrated wastewater. Therefore, the amount of flocculant used in the concentrated wastewater treatment system and the required amount of fine bubbles are greatly increased by adding and mixing the floating scum obtained by the coagulation and floating separation of the lean wastewater to the concentrated wastewater and mixing and floating and separating. I found that it can be reduced.
本発明はこのような知見に基いてなされたものであり、以下を要旨とする。
[1] SS及び油分の希薄な排水を凝集浮上分離して浮上スカムと分離水とを得る第1の凝集浮上分離工程と、SS及び/又は油分の濃厚な排水を凝集浮上分離して浮上スカムと分離水とを得る第2の凝集浮上分離工程とを有する排水の処理方法において、前記第1の凝集浮上分離工程で得られた浮上スカムを前記SS及び/又は油分の濃厚な排水と混合して凝集浮上分離する排水の処理装置であって、前記SS及び油分の希薄な排水はSS濃度及びノルマルヘキサン抽出物質濃度がそれぞれ10〜1,000mg/L、10〜1,000mg/Lであり、前記SS及び/又は油分の濃厚な排水はSS濃度が1,000〜10,000mg/L及び/又はノルマルヘキサン抽出物質濃度が1,000mg/L〜100,000mg/Lであることを特徴とする排水の処理方法。
[2] [1]において、前記第2の凝集浮上分離工程で得られた分離水を前記SS及び油分の希薄な排水と混合して凝集浮上分離することを特徴とする排水の処理方法。
[3] [1]又は[2]において、前記第1の凝集浮上分離工程で得られた分離水を生物処理する生物処理工程と、該生物処理工程の処理水を凝集浮上分離して浮上スカムと分離水とを得る第3の凝集浮上分離工程とを有し、該第3の凝集浮上分離工程の浮上スカムを前記SS及び/又は油分の濃厚な排水と混合して凝集浮上分離することを特徴とする排水の処理方法。
[4] [1]〜[3]において、排水の凝集浮上分離に当たり、槽体内が隔壁によって区画されることによって混合室と、浮上分離室とが形成された浮上槽を用い、該混合室で排水の凝集処理水を凝集助剤及び微細気泡と混合した後、該浮上分離室で浮上スカムと分離水とに分離することを特徴とする排水の処理方法。
[5] [1]〜[4]において、前記第1の凝集浮上分離工程及び/又は前記第3の凝集浮上分離工程で得られた分離水を、微細気泡発生用水として用いることを特徴とする排水の処理方法。
[6] SS及び油分の希薄な排水を凝集浮上分離して浮上スカムと分離水とを得る第1の凝集浮上分離手段と、SS及び/又は油分の濃厚な排水を凝集浮上分離して浮上スカムと分離水とを得る第2の凝集浮上分離手段とを有する排水の処理装置において、前記第1の凝集浮上分離手段からの浮上スカムを前記第2の凝集浮上分離手段に送給する手段を有する排水の処理装置であって、前記SS及び油分の希薄な排水はSS濃度及びノルマルヘキサン抽出物質濃度がそれぞれ10〜1,000mg/L、10〜1,000mg/Lであり、前記SS及び/又は油分の濃厚な排水はSS濃度が1,000〜10,000mg/L及び/又はノルマルヘキサン抽出物質濃度が1,000mg/L〜100,000mg/Lであることを特徴とする排水の処理装置。
[7] [6]において、前記第2の凝集浮上分離手段からの分離水を前記第1の凝集浮上分離手段に送給する手段を有することを特徴とする排水の処理装置。
[8] [6]又は[7]において、前記第1の凝集浮上分離手段からの分離水を生物処理する生物処理手段と、該生物処理手段の処理水を凝集浮上分離して浮上スカムと分離水とを得る第3の凝集浮上分離手段とを有し、該第3の凝集浮上分離手段の浮上スカムを前記第2の凝集浮上分離手段に送給することを特徴とする排水の処理装置。
[9] [6]〜[8]において、前記凝集浮上分離手段が、槽体内が隔壁によって区画されることによって混合室と、浮上分離室とが形成され、該混合室で排水の凝集処理水を凝集助剤及び微細気泡と混合し、該浮上分離室で該混合水を浮上スカムと分離水とに分離する浮上槽を有することを特徴とする排水の処理装置。
[10] [6]〜[9]において、前記第1の凝集浮上分離手段及び/又は前記第3の凝集浮上分離手段で得られた分離水を微細気泡発生用水として用いることを特徴とする排水の処理装置。
This invention is made | formed based on such knowledge, and makes the following a summary.
[1] A first flocculation and separation process of flocculating and separating SS and oily lean waste water to obtain floating scum and separated water; and SS and / or oil-rich waste water is flocculated and separated to float scum. And a second flocculation and separation process for obtaining separated water, wherein the floating scum obtained in the first flocculation and separation process is mixed with the SS and / or oil-rich wastewater. The wastewater treatment apparatus that flocculates and separates by flocculation , wherein the SS and oily lean wastewaters have an SS concentration and a normal hexane extractable substance concentration of 10 to 1,000 mg / L and 10 to 1,000 mg / L, respectively. The SS and / or oil-rich wastewater has an SS concentration of 1,000 to 10,000 mg / L and / or a normal hexane extractable substance concentration of 1,000 mg / L to 100,000 mg / L. A method for treating wastewater.
[2] A wastewater treatment method according to [1], wherein the separated water obtained in the second agglomeration floating separation step is mixed with the SS and oily lean wastewater for agglomeration floating separation.
[3] In [1] or [2], a biological treatment step for biologically treating the separated water obtained in the first flocculation / floating separation step; And a third flocculating and flotation step for obtaining separated water, and the flotation scum of the third flocculating and flotation step is mixed with the SS and / or oily concentrated waste water for flocculation and separation. Characterized wastewater treatment method.
[4] In [1] to [3], a floating tank in which a mixing chamber and a floating separation chamber are formed by partitioning the inside of the tank with a partition wall is used in the mixing chamber. A wastewater treatment method comprising mixing wastewater agglomeration treatment water with agglomeration aid and fine bubbles, and separating the wastewater into a flotation scum and separation water in the flotation separation chamber.
[5] In [1] to [4], the separated water obtained in the first aggregation / floating / separation step and / or the third aggregation / floating / separation step is used as water for generating fine bubbles. Wastewater treatment method.
[6] A first agglomeration and flotation separating means for aggregating and flotation of SS and oil-lean wastewater to obtain flotation scum and separated water; and flotation and separation of SS and / or oil-rich wastewater by agglomeration and flotation. And a second flocculating / floating / separating means for obtaining separated water, and a means for feeding the floating scum from the first flocculating / floating / separating means to the second flocculated / floating / separating means. A wastewater treatment apparatus, wherein the SS and the oily lean wastewater have an SS concentration and a normal hexane extractable substance concentration of 10 to 1,000 mg / L and 10 to 1,000 mg / L, respectively, and the SS and / or Rich oily drainage is characterized by an SS concentration of 1,000 to 10,000 mg / L and / or a normal hexane extractant concentration of 1,000 mg / L to 100,000 mg / L. Wastewater treatment equipment.
[7] The wastewater treatment apparatus according to [6] , further comprising means for feeding the separated water from the second flocculating and floating separation means to the first flocculating and floating separation means.
[8] In [6] or [7] , the biological treatment means for biologically treating the separated water from the first flocculating and floating separation means, and the treated water of the biological treatment means are flocculated and floated to separate from the floating scum. 3. A wastewater treatment apparatus comprising: a third agglomeration floating separation means for obtaining water, and the floating scum of the third agglomeration floating separation means is fed to the second agglomeration separation means.
[9] In [6] to [8] , the agglomeration floating separation means forms a mixing chamber and a flotation separation chamber by partitioning the inside of the tank by a partition wall, and agglomeration treated water for drainage is formed in the mixing chamber. A wastewater treatment apparatus comprising: a floating tank that mixes the coagulant with a coagulation aid and fine bubbles and separates the mixed water into a floating scum and separated water in the floating separation chamber.
[10] In [6] to [9] , the separated water obtained by the first flocculating and separating means and / or the third flocculating and separating means is used as water for generating fine bubbles. Processing equipment.
本発明によれば、希薄排水の凝集浮上分離で得られた浮上スカムを濃厚排水と混合し、この浮上スカムを濃厚排水の凝集浮上分離工程の凝集剤及び浮上助剤として有効利用することにより、濃厚排水の凝集浮上分離に必要な凝集剤量を低減ないしは凝集剤を不要とすると共に、浮上分離のための微細気泡量も低減することができる。 According to the present invention, the floating scum obtained by the cohesive flotation separation of dilute wastewater is mixed with the concentrated drainage, and by effectively using this flotation scum as a flocculant and a flotation aid in the coagulation flotation separation step of the concentrated drainage, It is possible to reduce the amount of flocculant necessary for the flocculation and floating separation of the concentrated drainage or to eliminate the need for the flocculant and to reduce the amount of fine bubbles for the levitation separation.
即ち、希薄排水に凝集剤を添加して凝集処理して得られる凝集処理水中の汚濁物質及び凝集剤はその大部分が次の浮上分離工程で浮上スカムとなる。この浮上スカムには、排水が希薄排水である場合には、十分な汚濁物質吸着能が残されており、しかも、この浮上スカムは内部に気泡を包含した比重の小さい強固なフロックである。このため、この浮上スカムを濃厚排水に添加して混合すると、濃厚排水中の汚濁物質を効率的に吸着する。その際に、浮上スカムを凝集槽内で濃厚排水と攪拌混合しても、この浮上スカムは強固なフロックであるため、浮上スカムから気泡が放出されることはない。そして、この浮上スカムは気泡を包含した比重が小さいものであるために、汚濁物質を吸着した上で、次の浮上分離工程で容易に浮上する。 That is, most of the pollutants and flocculants in the agglomerated water obtained by adding a flocculant to dilute wastewater and agglomerating it become floating scum in the next flotation separation step. When the effluent scum is a dilute effluent, a sufficient amount of pollutant adsorbing ability remains, and the levitation scum is a strong flock having a small specific gravity and containing bubbles therein. For this reason, when this floating scum is added to and mixed with concentrated drainage, pollutants in the concentrated drainage are efficiently adsorbed. At that time, even if the floating scum is stirred and mixed with the concentrated drainage in the coagulation tank, since the floating scum is a strong flock, no bubbles are released from the floating scum. Since the levitation scum has a small specific gravity including bubbles, the levitation scum is easily levitated in the next levitation separation step after adsorbing the pollutant.
このように、希薄排水の凝集浮上分離で得られた浮上スカムを濃厚排水の凝集剤として、また浮上分離のための微細気泡に代る浮上助剤として用いることができ、これにより、濃厚排水の凝集処理工程での凝集剤使用量を大幅に低減するか、或いは凝集剤を不要とすることができ、また、次の浮上分離工程で必要とされる微細気泡量も低減することができる。 In this way, the floating scum obtained by the coagulation flotation separation of dilute wastewater can be used as a flocculant for concentrated drainage and as a flotation aid in place of fine bubbles for flotation separation. The amount of coagulant used in the coagulation treatment step can be greatly reduced, or no coagulant can be required, and the amount of fine bubbles required in the next floating separation step can be reduced.
このため、全体として必要な凝集剤量を大幅に削減して薬剤コストを低減すると共に、微細気泡発生設備の小型化により、設備コスト、動力コストの低減を図ることができる。 For this reason, the amount of coagulant required as a whole can be significantly reduced to reduce the drug cost, and the equipment cost and power cost can be reduced by downsizing the fine bubble generating equipment.
以下に図面を参照して本発明の排水の処理方法及び処理装置の実施の形態を詳細に説明する。 Embodiments of the wastewater treatment method and treatment apparatus of the present invention will be described below in detail with reference to the drawings.
図1は本発明の排水の処理方法及び処理装置の実施の形態を示す系統図である。 FIG. 1 is a system diagram showing an embodiment of the wastewater treatment method and treatment apparatus of the present invention.
希薄排水は、希薄排水処理系10で、まず凝集槽11に導入され、後述の濃厚排水処理系20からの分離水と共にPAC等の無機凝集剤が添加されて凝集処理される。凝集処理水は、浮上槽12に送給され、混合室12Aで微細気泡発生装置13からの微細気泡及び高分子凝集剤と混合された後、浮上分離室12Bで浮上分離される。浮上分離室12Bからの浮上スカムは濃厚排水処理系の凝集槽21に送給される。一方、分離水の一部は、微細気泡発生装置13及び濃厚排水処理系の微細気泡発生装置23の微細気泡発生用水として利用され、残部は生物処理系30に送給される。
The lean wastewater is first introduced into the coagulation tank 11 in the dilute wastewater treatment system 10, and an inorganic coagulant such as PAC is added to the coagulation treatment together with the separated water from the concentrated wastewater treatment system 20 described later. The agglomerated water is fed to the levitation tank 12, mixed with the fine bubbles and the polymer flocculant from the fine bubble generator 13 in the mixing
この希薄排水処理系10の微細気泡発生装置13、及び後述の濃厚排水処理系20及び生物処理系30の微細気泡発生装置23,33は、微細気泡発生用水を加圧して気体を溶解した後、減圧して、微細気泡を発生させる方式のものであり、希薄排水処理系10の浮上槽12及び後述の濃厚排水処理系20及び生物処理系30の浮上槽22,32では、微細気泡発生装置13,23,33で微細気泡を発生させるのと同時に凝集処理水に微細気泡及び凝集助剤を混合するように構成されている。 After the fine bubble generating device 13 of the diluted waste water treatment system 10 and the fine bubble generating devices 23 and 33 of the dense waste water treatment system 20 and the biological treatment system 30 described later pressurize the water for generating fine bubbles and dissolve the gas, This is a method of generating fine bubbles by reducing the pressure. In the floating tank 12 of the lean wastewater treatment system 10 and the floating tanks 22 and 32 of the concentrated wastewater treatment system 20 and the biological treatment system 30 described later, the fine bubble generator 13 is used. , 23 and 33, the fine bubbles and the coagulant aid are mixed with the coagulated water at the same time as the fine bubbles are generated.
生物処理系30では、希薄排水処理系10の浮上槽12からの分離水が生物処理槽34で生物処理された後、凝集槽31でPAC等の無機凝集剤が添加されて凝集処理される。凝集処理水は浮上槽32に送給され、混合室32Aで微細気泡発生装置33からの微細気泡及び高分子凝集剤と混合された後、浮上分離室32Bで浮上分離される。浮上分離室32Bからの浮上スカムは濃厚排水処理系20の凝集槽21に送給される。一方、分離水は、十分に水質の高いものであるため、一部は微細気泡発生装置33の微細気泡発生用水として利用され、残部は処理水として系外へ排出される。
In the biological treatment system 30, the separated water from the floating tank 12 of the diluted wastewater treatment system 10 is biologically treated in the biological treatment tank 34, and then an agglomeration tank 31 is added with an inorganic flocculant such as PAC for aggregation treatment. The agglomerated water is fed to the floating tank 32, mixed with the fine bubbles and the polymer flocculant from the fine bubble generating device 33 in the mixing
濃厚排水は、濃厚排水処理系20で、まず凝集槽22に導入され、希薄排水処理系10からの浮上スカム及び生物処理系30からの浮上スカム及び必要に応じて添加されるPAC等の無機凝集剤と共に凝集処理される。凝集処理水は、浮上槽22に送給され、混合室22Aで微細気泡発生装置23からの微細気泡及び高分子凝集剤と混合された後、浮上分離室22Bで浮上分離される。浮上分離室22Bからの浮上スカムは系外へ排出される。一方、分離水は、希薄排水処理系10に送給され、希薄排水と共に凝集処理される。
The concentrated wastewater is first introduced into the agglomeration tank 22 by the concentrated wastewater treatment system 20, and the inorganic flocculation such as levitation scum from the lean wastewater treatment system 10, levitation scum from the biological treatment system 30, and PAC added as necessary. Coagulated with the agent. The agglomerated water is fed to the floating tank 22, mixed with the fine bubbles and the polymer flocculant from the fine bubble generator 23 in the mixing
このように希薄排水処理系10の浮上スカム、更にはこの希薄排水処理系10の分離水を処理する生物処理系30の浮上スカムを濃厚排水処理系20において濃厚排水に添加することにより、前述の如く、これらの浮上スカムを濃厚排水の凝集剤及び浮上助剤として利用することができ、凝集槽21の無機凝集剤使用量を大幅に削減することができ、場合によっては無機凝集剤を添加することなく、希薄排水処理系10及び生物処理系30の浮上スカムのみで凝集処理することも可能となる。また、浮上槽22においては、浮上分離のために必要な微細気泡量を大幅に削減することができる。 By adding the floating scum of the lean wastewater treatment system 10 and the floating scum of the biological treatment system 30 for treating the separated water of the lean wastewater treatment system 10 to the concentrated wastewater treatment system 20 as described above, As described above, these floating scum can be used as a flocculant and a flotation aid for concentrated drainage, and the amount of inorganic flocculant used in the flocculant tank 21 can be greatly reduced. In some cases, an inorganic flocculant is added. It is also possible to perform the agglomeration process only with the floating scum of the diluted waste water treatment system 10 and the biological treatment system 30. In the levitation tank 22, the amount of fine bubbles necessary for levitation separation can be greatly reduced.
凝集槽11,21,31に添加する無機凝集剤としては、PAC、硫酸バンド(硫酸アルミニウム)、塩化第二鉄、硫酸第一鉄、硫酸第二鉄等の無機凝集剤を用いることができ、その添加量は、凝集処理する水中の汚濁物質濃度に対して0.1〜10倍、特に5〜10倍程度とするのが好ましい。 As the inorganic flocculant to be added to the flocculation tanks 11, 21, 31, inorganic flocculants such as PAC, sulfate band (aluminum sulfate), ferric chloride, ferrous sulfate, ferric sulfate can be used, The amount added is preferably about 0.1 to 10 times, particularly about 5 to 10 times the concentration of pollutants in the water to be agglomerated.
また、浮上槽11,21,31に添加する凝集助剤としては、通常、ポリ(メタ)アクリルアミド、その加水分解物、ポリ(メタ)アクリル酸、(メタ)アクリルアミドとアルキルアミノ(メタ)アクリルアミド共重合体等のノニオン性、アニオン性、カチオン性又は両性高分子凝集剤を使用することができる。 In addition, as coagulation aids to be added to the levitation tanks 11, 21, 31, poly (meth) acrylamide, its hydrolyzate, poly (meth) acrylic acid, (meth) acrylamide and alkylamino (meth) acrylamide are usually used. Nonionic, anionic, cationic or amphoteric polymer flocculants such as polymers can be used.
高分子凝集剤等の凝集助剤の添加量は、通常、排水量に対して0.5〜5mg/L程度とされる。 The addition amount of a coagulant aid such as a polymer flocculant is usually about 0.5 to 5 mg / L with respect to the amount of drainage.
また、凝集槽11,21,31としては、特に制限はないが前述の特開10−337406号公報に記載の凝集処理装置を用いることにより効率的な凝集処理を行うことができる。 The agglomeration tanks 11, 21, and 31 are not particularly limited, but an efficient agglomeration process can be performed by using the agglomeration apparatus described in the above-mentioned JP-A-10-337406.
浮上槽としても特に制限はないが、前述の特願2005−33283号、特願2005−40855号に記載される加圧浮上装置を用いるのが好ましい。 Although there is no restriction | limiting in particular as a levitation tank, It is preferable to use the pressurization levitation | floating apparatus described in above-mentioned Japanese Patent Application No. 2005-33283 and Japanese Patent Application No. 2005-40855.
微細気泡発生装置13,23,33としては渦流ポンプ方式のものなどを用いることができる。 As the fine bubble generators 13, 23, 33, a vortex pump type can be used.
また、生物反応槽34としては生物膜を利用したものが好ましく、特に接触曝気生物反応槽や、スポンジ担体を投入した生物反応槽が好ましい。 The biological reaction tank 34 preferably uses a biofilm, and in particular, a contact aeration biological reaction tank or a biological reaction tank into which a sponge carrier is charged is preferable.
なお、図1に示す排水の処理方法は本発明の実施の形態の一例であって、本発明はその要旨を超えない限り、何ら図示のものに限定されない。 The wastewater treatment method shown in FIG. 1 is an example of an embodiment of the present invention, and the present invention is not limited to the illustrated one as long as it does not exceed the gist thereof.
例えば、濃厚排水処理系20の分離水は、生物処理系30の生物反応槽34に送給しても良く、この生物反応槽34と希薄排水処理系10の凝集槽11との両方に送給しても良い。 For example, the separated water of the concentrated wastewater treatment system 20 may be supplied to the biological reaction tank 34 of the biological treatment system 30, and is supplied to both the biological reaction tank 34 and the coagulation tank 11 of the lean wastewater treatment system 10. You may do it.
また、生物処理系30の浮上槽32の分離水を希薄排水処理系10及び濃厚排水処理系20の微細気泡発生装置13,23の微細気泡発生用水として用いても良い。 Further, the separated water in the floating tank 32 of the biological treatment system 30 may be used as water for generating fine bubbles in the fine bubble generating devices 13 and 23 of the lean waste water treatment system 10 and the concentrated waste water treatment system 20.
このような本発明の方法及び装置が適用される希薄排水とはSS濃度及びノルマルヘキサン抽出物質濃度がそれぞれ10〜1,000mg/L、10〜1,000mg/Lのものであり、濃厚排水はSS濃度及びノルマルヘキサン抽出物質濃度がそれぞれ1,000〜10,000mg/L、1,000〜100,000mg/Lのものである。 Such book SS concentration and the method and apparatus Ru rare thin effluent apply the invention and n-hexane extractives levels respectively 10~1,000mg / L, it is of 10~1,000mg / L, the concentrated wastewater The SS concentration and the normal hexane extractable substance concentration are 1,000 to 10,000 mg / L and 1,000 to 100,000 mg / L, respectively.
このような本発明の方法は、食品工場排水、鉄鋼、機械、石油、繊維、金属、食品、皮革、洗濯などの工場排水や、ガソリンスタンド、レストランなどからの排水の処理に有効であり、このような排水のうち、例えば金属加工工場の雑用排水を希薄排水として、同工場の切削油排水を濃厚排水としてそれぞれ凝集浮上分離することができる。 Such a method of the present invention is effective for the treatment of wastewater from food factory wastewater, steel, machinery, petroleum, textile, metal, food, leather, laundry, etc., and wastewater from gas stations, restaurants, etc. Among such wastewaters, for example, miscellaneous wastewater from a metal processing factory can be used as dilute wastewater, and cutting oil wastewater from the same factory can be used as concentrated wastewater to be agglomerated and separated.
以下に実施例及び比較例を挙げて本発明をより具体的に説明する。 Hereinafter, the present invention will be described more specifically with reference to Examples and Comparative Examples.
なお、以下において処理した希薄排水はノルマルヘキサン抽出物質濃度が100mg/Lの雑用排水であり、濃厚排水はノルマルヘキサン抽出物質濃度が30,000mg/Lの切削油排水である。 In addition, the diluted waste water processed below is a miscellaneous waste water with a normal hexane extract substance concentration of 100 mg / L, and the concentrated waste water is a cutting oil waste water with a normal hexane extract substance concentration of 30,000 mg / L.
また、無機凝集剤としてはPACを用い、高分子凝集剤としてはポリアクリル酸ナトリウムを用いた。 Further, PAC was used as the inorganic flocculant, and sodium polyacrylate was used as the polymer flocculant.
実施例1
図1に示す本発明の排水の処理装置により、希薄排水と濃厚排水の凝集浮上分離を行った。各槽の仕様は次の通りである。
凝集槽11:2.1m3
浮上槽12:2.7m3
微細気泡発生装置13:ニクニ社製渦流ポンプ5.5kW
凝集槽12:0.5m3
浮上槽22:0.7m3
微細気泡発生装置23:ニクニ社製渦流ポンプ5.5kW
生物反応槽34:8m3
凝集槽31:2.1m3
浮上槽32:2.7m3
微細気泡発生装置33:ニクニ社製渦流ポンプ5.5kW
Example 1
The waste water treatment apparatus of the present invention shown in FIG. 1 was used to agglomerate and separate the lean waste water and the concentrated waste water. The specifications of each tank are as follows.
Coagulation tank 11: 2.1 m 3
Levitation tank 12: 2.7 m 3
Microbubble generator 13: Nikuni vortex pump 5.5 kW
Coagulation tank 12: 0.5 m 3
Levitation tank 22: 0.7 m 3
Microbubble generator 23: Nikuni vortex pump 5.5 kW
Biological reaction tank 34: 8 m 3
Coagulation tank 31: 2.1 m 3
Floating tank 32: 2.7 m 3
Microbubble generator 33: Nikuni vortex pump 5.5 kW
希薄排水を20m3/hrと浮上分離室22Bの分離水2.7m3/hrを凝集槽1に導入してPACを添加して凝集処理し、凝集処理水を浮上槽12で高分子凝集剤及び微細気泡を添加混合し、浮上スカム0.2m3/hrと分離水26.5m3/hrとに浮上分離した。浮上スカムは凝集槽22に送給した。 20 m 3 / hr of dilute wastewater and 2.7 m 3 / hr of the separation water in the floating separation chamber 22 B are introduced into the coagulation tank 1, PAC is added for coagulation treatment, and the coagulation treatment water is polymerized in the floatation tank 12. Then, fine bubbles were added and mixed, and floated and separated into floating scum of 0.2 m 3 / hr and separated water of 26.5 m 3 / hr. The floating scum was fed to the agglomeration tank 22.
分離水の一部4m3/hrは微細気泡発生装置13の微細気泡発生用水として用い、他の2m3/hrは微細気泡発生装置23の微細気泡発生用水として用い、残部は生物反応槽34で生物処理した。生物処理水20.5m3/hrは凝集槽31でPACを添加して凝集処理し、凝集処理水に、浮上槽32で高分子凝集剤及び微細気泡を添加混合し、浮上スカム0.2m3/hrと分離水20.3m3/hrとに浮上分離した。浮上スカムは凝集槽22に送給した。分離水の一部は微細気泡発生装置33の微細気泡発生用水として用い、残部は処理水として系外へ排出した。 A part of the separated water 4m 3 / hr is used as water for generating fine bubbles in the fine bubble generating device 13, the other 2m 3 / hr is used as water for generating fine bubbles in the fine bubble generating device 23, and the rest is in the biological reaction tank 34. Biologically processed. Biologically treated water 20.5 m 3 / hr is agglomerated by adding PAC in the agglomeration tank 31, and the polymer aggregating agent and fine bubbles are added and mixed in the agglomeration treated water in the levitation tank 32, so that the floating scum 0.2 m 3 / Hr and separation water 20.3 m 3 / hr. The floating scum was fed to the agglomeration tank 22. A part of the separated water was used as water for generating fine bubbles in the fine bubble generator 33, and the remaining part was discharged out of the system as treated water.
一方、濃厚排水を0.7m3/hrの流量で凝集槽21に導入し、浮上槽12,32からの浮上スカム及びPACを添加して凝集処理し、凝集処理水を浮上槽22で高分子凝集剤及び微細気泡を添加混合し、浮上スカム0.4m3/hrと分離水2.7m3/hrとに浮上分離した。 On the other hand, concentrated drainage is introduced into the flocculation tank 21 at a flow rate of 0.7 m 3 / hr, and flocculation scum and PAC are added from the levitation tanks 12 and 32 to perform flocculation treatment. The flocculant and fine bubbles were added and mixed, and the mixture was floated and separated into floating scum of 0.4 m 3 / hr and separated water of 2.7 m 3 / hr.
浮上スカムは系外へ排出し、分離水は凝集槽11に送給した。 The floating scum was discharged out of the system, and the separated water was fed to the coagulation tank 11.
この処理において、各槽で必要とされたPAC量、微細気泡量及び高分子凝集剤量を表1に示した。なお、微細気泡量は、加圧水量及び加圧水圧力として表した。 Table 1 shows the amount of PAC, the amount of fine bubbles, and the amount of polymer flocculant required in each tank in this treatment. In addition, the amount of fine bubbles was expressed as a pressurized water amount and a pressurized water pressure.
比較例1
実施例1において、浮上槽12,32の浮上スカムを凝集槽21に添加しなかったこと以外は同様にして処理を行い、各槽で必要とされたPAC量、微細気泡量及び高分子凝集剤量を表1に示した。
Comparative Example 1
In Example 1, the treatment was performed in the same manner except that the floating scum of the floating tanks 12 and 32 was not added to the coagulation tank 21, and the amount of PAC, the amount of fine bubbles, and the polymer coagulant required in each tank The amount is shown in Table 1.
表1より、本発明によれば、希薄排水処理系、更にはその後段の生物処理系の浮上スカムを、濃厚排水処理系に送給することにより、濃厚排水処理系での凝集剤使用量及び微細気泡必要量を大幅に削減することができることが分かる。 From Table 1, according to the present invention, the amount of flocculant used in the concentrated wastewater treatment system and the floating scum of the biological wastewater treatment system in the subsequent stage are fed to the concentrated wastewater treatment system. It can be seen that the required amount of fine bubbles can be greatly reduced.
10 希薄排水処理系
11,21,31 凝集槽
12,22,32 浮上槽
12A,22A,32A 混合室
12B,22B,32B 浮上分離室
13,23,33 微細気泡発生装置
20 濃厚排水処理系
30 生物処理系
34 生物反応槽
DESCRIPTION OF SYMBOLS 10 Diluted waste water treatment system 11, 21, 31 Coagulation tank 12, 22, 32 Floating
Claims (10)
前記第1の凝集浮上分離工程で得られた浮上スカムを前記SS及び/又は油分の濃厚な排水と混合して凝集浮上分離する排水の処理方法であって、
前記SS及び油分の希薄な排水はSS濃度及びノルマルヘキサン抽出物質濃度がそれぞれ10〜1,000mg/L、10〜1,000mg/Lであり、前記SS及び/又は油分の濃厚な排水はSS濃度が1,000〜10,000mg/L及び/又はノルマルヘキサン抽出物質濃度が1,000〜100,000mg/Lであることを特徴とする排水の処理方法。 A first agglomeration and flotation step of aggregating and flotation of SS and oil-lean waste water to obtain flotation scum and separated water; and a flotation and separation of SS and / or oil-rich waste water by flotation and separation and flotation scum and separated water In the wastewater treatment method having the second coagulation flotation separation step to obtain
A wastewater treatment method in which the floating scum obtained in the first flocculation and separation step is mixed with the SS and / or oil-rich wastewater to flocculate and separate .
The SS and oil-lean wastewater has SS concentration and normal hexane extractable substance concentration of 10 to 1,000 mg / L and 10 to 1,000 mg / L, respectively. The SS and / or oily wastewater has SS concentration. Is a method for treating waste water, wherein the concentration of the normal hexane extract is 1,000 to 100,000 mg / L.
前記第1の凝集浮上分離手段からの浮上スカムを前記第2の凝集浮上分離手段に送給する手段を有する排水の処理装置であって、
前記SS及び油分の希薄な排水はSS濃度及びノルマルヘキサン抽出物質濃度がそれぞれ10〜1,000mg/L、10〜1,000mg/Lであり、前記SS及び/又は油分の濃厚な排水はSS濃度が1,000〜10,000mg/L及び/又はノルマルヘキサン抽出物質濃度が1,000mg/L〜100,000mg/Lであることを特徴とする排水の処理装置。 First flocculating and floating separation means for flocculating and separating SS and oil-lean wastewater to obtain floating scum and separated water; and SS and / or oil-rich wastewater for flocculating and floating to separate floating scum and separated water A wastewater treatment apparatus having second agglomeration levitation separation means for obtaining
A wastewater treatment apparatus having means for feeding a floating scum from the first agglomeration floating separation means to the second agglomeration separation means ;
The SS and oil-lean wastewater has SS concentration and normal hexane extractable substance concentration of 10 to 1,000 mg / L and 10 to 1,000 mg / L, respectively. The SS and / or oily wastewater has SS concentration. Is a wastewater treatment apparatus, wherein the concentration of the normal hexane extract is 1,000 mg / L to 100,000 mg / L.
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