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JP4766802B2 - Agricultural multi-film and crop cultivation method - Google Patents
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JP4766802B2 - Agricultural multi-film and crop cultivation method - Google Patents

Agricultural multi-film and crop cultivation method Download PDF

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Publication number
JP4766802B2
JP4766802B2 JP2001280667A JP2001280667A JP4766802B2 JP 4766802 B2 JP4766802 B2 JP 4766802B2 JP 2001280667 A JP2001280667 A JP 2001280667A JP 2001280667 A JP2001280667 A JP 2001280667A JP 4766802 B2 JP4766802 B2 JP 4766802B2
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film
ground
soil
agricultural multi
crop
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JP2003088255A (en
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邦彦 角田
正之 江上
直樹 藤野
和代 稲葉
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みかど化工株式会社
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Description

【0001】
【発明の属する技術分野】
本発明は、マルチフィルム使用後の廃棄処理が不要になる農業用マルチフィルムに関する。
【0002】
【従来の技術】
従来、マルチ栽培の実情を見ると、図2に示すように、帯状のフィルム10が、畝11(通常長さが約50〜100m程度、高さが10〜15cm程度)の上面から側面にかけて被覆するようにしてあり、側面はフィルムが風等で飛散しないように土12が載せられている。従って、マルチフィルム10を長手方向に沿って見ると、栽培作物が植生される地上部域13(地表列域)と、飛散防止用の土中部域14(土中列域)に分けられていることになる。
【0003】
かかるマルチフィルムでは、植物栽培後のフィルムの取り外し作業やフィルムの再生処理の問題があり、かかる問題を解消するために、本発明者は先に特願平10−193694号において、ポリエチレン樹脂等の熱可塑性樹脂フィルムの両側を生分解性の樹脂で形成してなる農業用マルチフィルムを提案した。
【0004】
しかし、かかるマルチフィルムは、一般的なフィルム成形法であるインフレーション成形法により一体成形した場合、例えば地上部域(地表列域)の樹脂として低密度ポリエチレンを用い、土中部域(土中列域)の樹脂に生分解性樹脂を用いる場合に、低密度ポリエチレンの極性が小さく、生分解性樹脂の極性が大きいため、地表列域とその両側の土中列域の接着が難しい課題がある。また低密度ポリエチレンと生分解性樹脂の溶融張力に差があり、均一なブローアップができず、厚みコントロールができない課題がある。
【0005】
また、地上部域と土中部域の樹脂を全て同じ生分解樹脂を用いて形成すると、土中と地表でのフィルム分解、劣化速度に差が生じ、以下のような問題がある。
【0006】
生分解性の早い樹脂を用いた場合、土中部域のフィルムは土中微生物によって生分解され、1作終了時(2〜6ヶ月)にはほとんど消失するが、地上部域のフィルムも2〜3ヶ月で破れると言う問題がある。
【0007】
また生分解性の遅い樹脂を用いた場合は、土中部域のフィルムの土中微生物による生分解が進まず、土中にフィルムが残存すると、次の作付け、生育に不都合となる問題があり、地上部域のフィルムも残存強度が強いため、ロータリー耕耘機でフィルムを土中にすき込む際にローターにからみつく問題がある。
【0008】
特に地上部域フィルムは、土中にすき込んでも、短期(1〜2週間)に消失することはなく、直ぐ次作に移り難い。即ち、藩種、定植作業で残存フィルムが邪魔になり、作業上問題となる。そして何より心配なのは、畑地の生態系に負荷を掛けることであり、畑地をゴミ捨て場にしていることである。
【0009】
【発明が解決しようとする課題】
そこで、本発明は、地上部と土中部でフィルムライフを異ならせて、作物栽培の実情に合致させ、しかも栽培終了後にフィルム廃棄物処理が容易になる農業用マルチフィルム及び作物栽培方法を提供することを課題とする。
【0010】
【課題を解決するための手段】
上記課題を解決する本発明に係る農業用マルチフィルムは、帯状の農業用マルチフィルムにおいて、該フィルムの長手方向に沿って中央に地上部域を有し、該地上部域の一側または両側に土中部域を有し、前記地上部域のフィルムと前記土中部域のフィルムとは互いに生分解性能が異なる生分解性樹脂であり、且つ前記土中部域のフィルムは前記地上部域のフィルムよりも早く生分解される生分解性樹脂であることを特徴とし、好ましくは、前記土中部域のフィルムは作物栽培開始から2ヶ月間生分解させずに維持しその後生分解される生分解樹脂製であることを特徴とし、より好ましくは、前記地上部域のフィルムは、コンポスト化する温度及び湿度条件下で生分解する生分解樹脂製であることを特徴とする。
【0011】
また上記課題を解決する本発明に係る作物栽培方法は、上記の農業用マルチフィルムを用いた作物栽培方法であって、前記土中部域のフィルムが生分解された後、作物そのものによって前記地上部域のフィルムが飛散するのを防止することを特徴とする。又は、上記の農業用マルチフィルムを用いた作物栽培方法であって、前記土中部域のフィルムが生分解された後、作物そのものによって前記地上部域のフィルムが飛散するのを防止すると共に、作物栽培終了後、前記地上部域のフィルムを所定の温度及び湿度でコンポスト化することを特徴とする。
【0012】
【発明の実施の形態】
以下、本発明の実施の形態を説明する。
【0013】
本発明に係る農業用マルチフィルムは、図1に示すように、フィルムの長手方向に沿って中央に地上部域1を有し、地上部域1の両側に土中部域2、2を有している。
【0014】
地上部域1のフィルムの第1の特徴は、作物栽培終了まで劣化破損しない生分解樹脂製であり、第2の特徴は作物栽培終了まで劣化破損せず、作物栽培終了後回収したフィルムは、コンポスト原料(ワラ、野菜残渣、家畜糞尿等)と混合し、コンポスト化する温度及び湿度条件下で生分解する生分解樹脂製であることである。
【0015】
第1の特徴における作物栽培終了までというのは、栽培開始から2〜6ヶ月である。栽培期間(フィルム使用期間)は、作物種類、栽培時期、栽培方法(露地、トンネル、ハウス栽培か等)や、栽培地域等により異なる。即ち、同一作物でも栽培期間には幅がある。具体的には2型(栽培開始から2ヶ月)、3型(栽培開始から3ヶ月)、4型(栽培開始から4ヶ月)、5型(栽培開始から5ヶ月)、6型(栽培開始から6ヶ月)のように耐用期間ごとにタイプを用意しておくことが好ましい。また月別でなく、3.5型(栽培開始から3.5ヶ月)のように0.5ヶ月ごとにタイプ分けして用意しておくこともできる。
【0016】
劣化破損というのは、ロータリー耕耘機でフィルムを土中にすき込む際に残存強度を失い、ローターにからみつかなくなる程度に劣化破損されていることを意味しており、具体的には第2の特徴で規定したように、作物栽培終了後コンポスト化する条件下で生分解する程度である。
【0017】
フィルムの特性としては、地上部に存在している際に紫外線による劣化破損の影響もあるので、その劣化を見込んで、第2の特徴の生分解を生起させる特性とすることが好ましい。
【0018】
コンポスト化する温度及び湿度とは、例えば生ごみ等がコンポスト化される温度及び湿度であり、温度は例えば60〜90℃程度が好ましく、湿度(相対湿度)は例えば50%RH〜100%RHの範囲が好ましい。従って、生ごみ等を原料としてコンポスト肥料を製造する際に、当該原料に地上部域1のフィルムを混ぜてコンポストを同条件で製造できるような地上部域1のフィルム特性であることが好ましい。即ち、地上部域1のフィルムはコンポスタブル特性を有していることが好ましい。
【0019】
以下に、地上部域1のフィルムを製造する際の原料となる生分解樹脂を挙げると、ポリ乳酸、ポリカプロラクトン、ポリエチレンサクシネート、ポリブチレンサクシネート、ポリブチレンサクシネートアジペート、ポリヒドロキシブチレート、ポリエステルカーボネート、ポリヒドロキシブチレート/ヒドロキシバリレート、等の脂肪族ポリエステルや脂肪族芳香族ポリエステル共重合体、ポリセルロースアセテート等のセルロース系樹脂、変性ポリビニールアルコール、さらにこれらと澱粉や木粉、椰子殻粉等の有機微粉末との混合物、炭酸カルシウムや二酸化珪素等無機微粉末との混合物、二酸化チタン、カーボンブラック、アルミ粉等着色顔料を配合した物が挙げられる。
【0020】
次に、土中部域2、2のフィルムは、作物栽培開始から2ヶ月間生分解させずに維持しその後生分解される特性を有する。地上部域1のフィルムがマルチ効果を発揮するのは生育初期の2ヶ月間である。従って、生育当初2ヶ月は土で土中部域のフィルムを抑え、地上部域1のフィルムがしっかりと畦面に展張されている必要がある。
【0021】
そして2ヶ月以降は土中部域2のフィルムが生分解されても、作物そのものが大きくなり、風等でフィルムが飛散するのを防止する。つまり畦面上に浮いた状態でかけられた状態、所謂ベタガケ状態になる。一方、土中部域2はいち早く生分解されフィルム残存の問題もなく、土中部域2のみで少なく、土壌への負荷や汚染の問題もなくなり好ましい。
【0022】
以下に、土中部域2のフィルムを製造する際の原料となる生分解樹脂を挙げると、地上部域1と同じ樹脂から目的の分解性のものが選ばれる。分解性の遅い樹脂は有機微粉末や無機微粉末との混合物にして目的の分解性に設計される。
【0023】
本発明において、地上部域1のフィルムに着色顔料を配合して、土中部域2のフィルムは無配合あるいは有機、無機微粉末を配合した物が好ましく、特に地上部域1のフィルムにカーボンブラックを配合した物が好ましい。
【0024】
本発明の農業用マルチフィルムの製造法としては、上記の原料を用い、インレフレダイやTダイ等を用いて3列同時押し出し成形によって形成できる。
【0025】
本発明の農業用マルチフィルムの厚みは、3〜50μm程度が好ましく、より好ましくは5〜35μmの範囲である。
【0026】
更に、本発明の農業用マルチフィルムにおいては、従来公知の界面活性剤、耐候安定剤、紫外線吸収剤、滑剤、アンチブロッキング剤等を添加することもできる。
【0027】
また、本発明の農業用マルチフィルムは、適当な色濃度の黒色系や銀色系等の着色フィルム層としてもよい。特に黒色顔料としてのカーボンブラック粉体はその表面構造が多孔質でしかも化学的にも活性を有しており、各種生分解樹脂の耐光性や生分解性を改変できる。具体的には、太陽光のエネルギーを吸収して無害な熱エネルギーにして生分解性樹脂の劣化を防ぎ、配合量を調整することで元々の生分解性樹脂の耐候性を数割から数倍に向上させることができる。土中においては分解性を遅らせることができる。機構は明らかではないが、分解を促進する酵素を吸着して徐々に分解させるよう制御していると推定される。
【0028】
また、各種害虫の飛来を抑制する手段を施してもよい。
【0029】
以上、本発明の農業用マルチフィルムの実施の形態において、地上部域1の両側に土中部域2、2を有している例を説明したが、土中部域2が地上部域1の一側である場合にも本発明の効果を発揮し得る。
【0030】
【発明の効果】
本発明によれば、地上部と土中部でフィルムライフを異ならせて、作物栽培の実情に合致させ、しかも栽培終了後にフィルム廃棄物処理が容易になる農業用マルチフィルム及び作物栽培方法を提供することができる。
【図面の簡単な説明】
【図1】本発明の農業用マルチフィルムの一例を示す断面図
【図2】農業用マルチフィルムの使用例を示す断面図
【符号の説明】
1:地上部域
2:土中部域
[0001]
BACKGROUND OF THE INVENTION
The present invention relates to an agricultural multi-film that does not require disposal after the use of the multi-film.
[0002]
[Prior art]
Conventionally, when looking at the actual situation of multi-cultivation, as shown in FIG. 2, a strip-shaped film 10 is covered from the upper surface to the side surface of the ridge 11 (usually about 50 to 100 m in length and about 10 to 15 cm in height). The soil 12 is placed on the side surface so that the film is not scattered by wind or the like. Therefore, when the multi-film 10 is viewed along the longitudinal direction, the multi-film 10 is divided into a ground region 13 (ground surface region) where cultivated crops are vegetated and a soil subregion 14 (ground region) for preventing scattering. It will be.
[0003]
In such a multi-film, there are problems of film removal work after plant cultivation and film regeneration processing. In order to solve such problems, the present inventor previously disclosed a polyethylene resin or the like in Japanese Patent Application No. 10-193694. An agricultural multi-film was proposed in which both sides of a thermoplastic resin film were formed from a biodegradable resin.
[0004]
However, when such a multi-film is integrally formed by an inflation molding method, which is a general film forming method, for example, low-density polyethylene is used as a resin for the ground region (surface row region), and the soil region (soil row region) In the case of using a biodegradable resin for the resin (1), since the polarity of the low-density polyethylene is small and the polarity of the biodegradable resin is large, there is a problem that it is difficult to bond the ground row region and the soil row region on both sides thereof. In addition, there is a difference in melt tension between low-density polyethylene and biodegradable resin, and there is a problem that uniform blow-up cannot be performed and thickness control cannot be performed.
[0005]
In addition, if all the resin in the ground region and the soil region are formed using the same biodegradable resin, there is a difference in the film decomposition and deterioration rates between the soil and the ground surface, and there are the following problems.
[0006]
In the case of using a biodegradable resin, the soil region film is biodegraded by microorganisms in the soil, and almost disappears at the end of one crop (2 to 6 months). There is a problem of being broken in 3 months.
[0007]
In addition, when using a resin with slow biodegradability, biodegradation by soil microorganisms does not proceed in the soil region, and if the film remains in the soil, there is a problem that inconveniences the next cropping and growth, Since the film in the ground area has a high residual strength, there is a problem of entanglement with the rotor when the film is squeezed into the soil with a rotary tiller.
[0008]
In particular, the above-ground film does not disappear in a short period (1 to 2 weeks) even if it penetrates into the ground, and it is difficult to immediately move on to the next film. That is, the remaining film becomes an obstacle in the seeding and planting work, which causes a problem in work. What is most worrisome is that it puts a burden on the ecosystem in the field and makes the field a garbage dump.
[0009]
[Problems to be solved by the invention]
Therefore, the present invention provides an agricultural multi-film and a crop cultivation method that make film life different between the above-ground part and the soil part, match the actual situation of crop cultivation, and facilitate film waste disposal after the cultivation is completed. This is the issue.
[0010]
[Means for Solving the Problems]
The agricultural multi-film according to the present invention that solves the above-mentioned problems is a strip-shaped agricultural multi-film, having a ground area in the center along the longitudinal direction of the film, on one side or both sides of the ground area. The ground region film and the soil region film are biodegradable resins having different biodegradability, and the soil region film is more than the ground region film. It is characterized in that it is a biodegradable resin that is biodegraded as soon as possible. Preferably, the film in the soil middle region is made of a biodegradable resin that is maintained without being biodegraded for two months from the start of crop cultivation and then biodegraded. More preferably, the above-mentioned film in the above-ground region is made of a biodegradable resin that biodegrades under conditions of temperature and humidity for composting.
[0011]
The crop cultivation method according to the present invention for solving the above-mentioned problems is a crop cultivation method using the above-described agricultural multi-film, wherein after the film in the subterranean area is biodegraded, It is characterized by preventing the film in the region from scattering. Or a method for cultivating a crop using the above-described agricultural multi-film, wherein after the film in the soil region is biodegraded, the film in the ground region is prevented from being scattered by the crop itself, After the cultivation, the above-mentioned film in the above-ground area is composted at a predetermined temperature and humidity.
[0012]
DETAILED DESCRIPTION OF THE INVENTION
Embodiments of the present invention will be described below.
[0013]
As shown in FIG. 1, the agricultural multi-film according to the present invention has a ground area 1 at the center along the longitudinal direction of the film, and has soil areas 2, 2 on both sides of the ground area 1. ing.
[0014]
The first characteristic of the film in the ground area 1 is made of biodegradable resin that does not deteriorate and break until the end of crop cultivation, and the second characteristic does not deteriorate and break until the end of crop cultivation. It is made of biodegradable resin that is mixed with compost raw materials (eg, straw, vegetable residues, livestock manure, etc.) and biodegraded under composting temperature and humidity conditions.
[0015]
Until the end of crop cultivation in the first feature, it is 2 to 6 months from the start of cultivation. The cultivation period (film use period) varies depending on the type of crop, the cultivation period, the cultivation method (such as open field, tunnel, and house cultivation), the cultivation area, and the like. In other words, the cultivation period varies even with the same crop. Specifically, type 2 (2 months from the start of cultivation), type 3 (3 months from the start of cultivation), type 4 (4 months from the start of cultivation), type 5 (5 months from the start of cultivation), type 6 (from the start of cultivation) It is preferable to prepare a type for each service life, such as 6 months). Moreover, it is also possible to prepare by type every 0.5 months, such as 3.5 type (3.5 months from the start of cultivation), not monthly.
[0016]
Deterioration damage means that the film has been deteriorated and damaged to such an extent that it loses its residual strength when it is rubbed into the soil with a rotary tiller and cannot be entangled with the rotor. As specified in the characteristics, it is a degree of biodegradation under the conditions of composting after the end of crop cultivation.
[0017]
As characteristics of the film, there is also an influence of deterioration and damage due to ultraviolet rays when it is present on the ground part. Therefore, it is preferable to allow for the deterioration and to cause the second characteristic biodegradation.
[0018]
The temperature and humidity for composting are, for example, the temperature and humidity at which food waste is composted, and the temperature is preferably about 60 to 90 ° C., and the humidity (relative humidity) is, for example, 50% RH to 100% RH. A range is preferred. Therefore, when compost fertilizer is produced using raw garbage or the like as raw material, it is preferable that the film characteristics of the above-ground region 1 are such that compost can be produced under the same conditions by mixing the raw material 1 film with the raw material. That is, it is preferable that the film of the ground area 1 has a compostable property.
[0019]
Hereinafter, biodegradable resins that are raw materials for producing the film of the above-ground region 1 are polylactic acid, polycaprolactone, polyethylene succinate, polybutylene succinate, polybutylene succinate adipate, polyhydroxybutyrate, Aliphatic polyesters such as polyester carbonate, polyhydroxybutyrate / hydroxyvalerate, aliphatic aromatic polyester copolymers, cellulosic resins such as polycellulose acetate, modified polyvinyl alcohol, and starch, wood flour, and insulator The mixture with organic fine powders, such as shell powder, the mixture with inorganic fine powders, such as calcium carbonate and silicon dioxide, the thing which mix | blended coloring pigments, such as titanium dioxide, carbon black, and aluminum powder.
[0020]
Next, the films in the subterranean regions 2 and 2 have the property of being maintained without being biodegraded for 2 months from the start of crop cultivation and then biodegraded. It is during the first two months of growth that the film in the ground area 1 exhibits the multi-effect. Therefore, it is necessary to suppress the film in the soil middle region with soil for the first two months of growth, and the film in the ground region 1 should be firmly spread on the surface.
[0021]
And after 2 months, even if the film in the subterranean area 2 is biodegraded, the crop itself becomes large and prevents the film from being scattered by wind or the like. In other words, it is in a state where it is hung on the surface, that is, a so-called sticky state. On the other hand, the subterranean region 2 is biodegraded quickly and has no problem of remaining film, and only in the subterranean region 2, it is preferable because there are no problems on the soil and contamination.
[0022]
Below, when the biodegradable resin used as a raw material at the time of manufacturing the film of the soil subregion 2 is given, the target decomposable one is selected from the same resin as the ground region 1. A resin having a slow degradability is designed to have a desired degradability by mixing it with an organic fine powder or an inorganic fine powder.
[0023]
In the present invention, the ground region 1 film is preferably blended with a color pigment, and the soil region 2 film is preferably unblended or blended with organic and inorganic fine powders. The thing which mix | blended was preferable.
[0024]
As a manufacturing method of the agricultural multifilm of this invention, it can form by three rows simultaneous extrusion using the above-mentioned raw material and using an inflection die, a T die, etc.
[0025]
As for the thickness of the agricultural multi-film of this invention, about 3-50 micrometers is preferable, More preferably, it is the range of 5-35 micrometers.
[0026]
Furthermore, in the agricultural multifilm of the present invention, conventionally known surfactants, weathering stabilizers, ultraviolet absorbers, lubricants, antiblocking agents and the like can be added.
[0027]
The agricultural multi-film of the present invention may be a black or silver colored film layer having an appropriate color density. In particular, carbon black powder as a black pigment has a porous surface structure and is chemically active, and can modify the light resistance and biodegradability of various biodegradable resins. Specifically, it absorbs sunlight energy to make it harmless heat energy, prevents deterioration of the biodegradable resin, and adjusts the blending amount to increase the weather resistance of the original biodegradable resin by several tens to several times Can be improved. Degradability can be delayed in the soil. Although the mechanism is not clear, it is presumed that an enzyme that promotes decomposition is adsorbed and controlled to gradually decompose.
[0028]
Moreover, you may give a means to suppress the flying of various pests.
[0029]
As described above, in the embodiment of the agricultural multi-film of the present invention, the example in which the soil sub-regions 2 and 2 are provided on both sides of the ground sub-region 1 has been described. The effect of the present invention can be exerted even when it is on the side.
[0030]
【The invention's effect】
According to the present invention, there are provided an agricultural multi-film and a crop cultivation method in which film life is made different between the above-ground part and the soil part to match the actual situation of crop cultivation, and the film waste treatment is facilitated after the cultivation is completed. be able to.
[Brief description of the drawings]
FIG. 1 is a cross-sectional view showing an example of an agricultural multi-film according to the present invention. FIG. 2 is a cross-sectional view showing an example of use of an agricultural multi-film.
1: Ground area 2: Soil area

Claims (5)

帯状の農業用マルチフィルムにおいて、該フィルムの長手方向に沿って中央に地上部域を有し、該地上部域の一側または両側に土中部域を有し、
前記地上部域のフィルムと前記土中部域のフィルムとは互いに生分解性能が異なる生分解性樹脂であり、
且つ前記土中部域のフィルムは前記地上部域のフィルムよりも早く生分解される生分解性樹脂であることを特徴とする農業用マルチフィルム。
In a strip-shaped agricultural multi-film, it has a ground area in the center along the longitudinal direction of the film, and has a soil area on one side or both sides of the ground area,
The above ground region film and the above soil region film are biodegradable resins having different biodegradable performances from each other,
The agricultural multi-film is a biodegradable resin that is biodegradable faster than the above-ground film.
前記土中部域のフィルムは作物栽培開始から2ヶ月間生分解させずに維持しその後生分解される生分解樹脂製であることを特徴とする請求項1記載の農業用マルチフィルム。The agricultural multi-film according to claim 1, wherein the film in the subterranean region is made of a biodegradable resin that is maintained without being biodegraded for two months from the start of crop cultivation and then biodegraded. 前記地上部域のフィルムは、コンポスト化する温度及び湿度条件下で生分解する生分解樹脂製であることを特徴とする請求項1又は2記載の農業用マルチフィルム。The agricultural multi-film according to claim 1 or 2, wherein the film of the above-ground area is made of a biodegradable resin that biodegrades under composting temperature and humidity conditions. 請求項1〜3の何れかに記載の農業用マルチフィルムを用いた作物栽培方法であって、A crop cultivation method using the agricultural multi-film according to claim 1,
前記土中部域のフィルムが生分解された後、作物そのものによって前記地上部域のフィルムが飛散するのを防止することを特徴とする作物栽培方法。A method for cultivating a crop, comprising preventing the above-ground film from being scattered by the crop itself after the soil film is biodegraded.
請求項3記載の農業用マルチフィルムを用いた作物栽培方法であって、A crop cultivation method using the agricultural multi-film according to claim 3,
前記土中部域のフィルムが生分解された後、作物そのものによって前記地上部域のフィルムが飛散するのを防止すると共に、After the film of the subterranean area is biodegraded, the film of the ground area is prevented from scattering by the crop itself,
作物栽培終了後、前記地上部域のフィルムを所定の温度及び湿度でコンポスト化することを特徴とする作物栽培方法。A crop cultivation method comprising composting the above-ground film at a predetermined temperature and humidity after completion of crop cultivation.
JP2001280667A 2001-09-14 2001-09-14 Agricultural multi-film and crop cultivation method Expired - Fee Related JP4766802B2 (en)

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JP2009077646A (en) * 2007-09-26 2009-04-16 Achilles Corp Multi-film repair tape for biodegradable agriculture

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JP5925994B2 (en) * 2011-03-30 2016-05-25 シーアイ化成株式会社 Biodegradable multifilm

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JP3295217B2 (en) * 1994-02-08 2002-06-24 株式会社トクヤマ Poly (2-oxetanone) composition
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JPH11275985A (en) * 1998-03-27 1999-10-12 Okura Ind Co Ltd Multi film
JP2000327847A (en) * 1999-05-17 2000-11-28 Mitsubishi Gas Chem Co Inc Resin composition
JP2000342083A (en) * 1999-06-02 2000-12-12 Tomoe Engineering Co Ltd Degradable mulching film and its production
JP2001017008A (en) * 1999-07-06 2001-01-23 Daicel Chem Ind Ltd Non-uniform biodegradable agricultural film in the width direction

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JP2009077646A (en) * 2007-09-26 2009-04-16 Achilles Corp Multi-film repair tape for biodegradable agriculture

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