Deprecated: The each() function is deprecated. This message will be suppressed on further calls in /home/zhenxiangba/zhenxiangba.com/public_html/phproxy-improved-master/index.php on line 456
JP4845490B2 - Surface coated cutting tool - Google Patents
[go: Go Back, main page]

JP4845490B2 - Surface coated cutting tool - Google Patents

Surface coated cutting tool Download PDF

Info

Publication number
JP4845490B2
JP4845490B2 JP2005338444A JP2005338444A JP4845490B2 JP 4845490 B2 JP4845490 B2 JP 4845490B2 JP 2005338444 A JP2005338444 A JP 2005338444A JP 2005338444 A JP2005338444 A JP 2005338444A JP 4845490 B2 JP4845490 B2 JP 4845490B2
Authority
JP
Japan
Prior art keywords
layer
hard coating
coating layer
outermost surface
cutting
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Fee Related
Application number
JP2005338444A
Other languages
Japanese (ja)
Other versions
JP2007144522A (en
Inventor
栄仁 谷渕
博俊 伊藤
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Kyocera Corp
Original Assignee
Kyocera Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Kyocera Corp filed Critical Kyocera Corp
Priority to JP2005338444A priority Critical patent/JP4845490B2/en
Publication of JP2007144522A publication Critical patent/JP2007144522A/en
Application granted granted Critical
Publication of JP4845490B2 publication Critical patent/JP4845490B2/en
Anticipated expiration legal-status Critical
Expired - Fee Related legal-status Critical Current

Links

Images

Landscapes

  • Cutting Tools, Boring Holders, And Turrets (AREA)
  • Chemical Vapour Deposition (AREA)

Description

本発明は、表面に硬質被覆層を被着形成した、優れた耐欠損性および耐摩耗性等の切削特性を有する表面被覆切削工具に関する。   The present invention relates to a surface-coated cutting tool having excellent cutting characteristics such as fracture resistance and wear resistance, in which a hard coating layer is formed on the surface.

従来より、基体の表面に硬質被覆層を被着形成した表面被覆切削工具として、超硬合金やサーメット、セラミックス等の硬質基体の表面に、TiC層、TiN層、TiCN層、Al層およびTiAlN層等の単層または複層の硬質被覆層を被着形成した切削工具が多用されている。 Conventionally, as a surface-coated cutting tool in which a hard coating layer is formed on the surface of a substrate, a TiC layer, a TiN layer, a TiCN layer, an Al 2 O 3 layer is formed on the surface of a hard substrate such as cemented carbide, cermet, or ceramic. Further, a cutting tool in which a single or multiple hard coating layer such as a TiAlN layer is deposited is widely used.

かかる切削工具を用いた切削加工の形態においては、環境負荷の低減が求められており、切削液を使用しない乾式切削加工が注目されてきている。かかる乾式切削加工では、切削工具の切刃が非常に高温になり易く、被削材が切刃に溶着しやすくなる傾向にある。このように被削材が工具の切刃に溶着すると、切刃が変質していわゆる構成切刃が発生してしまい、加工精度が低下したり、溶着した被削材が切刃から脱落する際に硬質被覆層の剥離やチッピング等の切刃の損傷が発生しやすくなる。そして、これが引き金となって切刃の欠損や異常摩耗が発生する等の不具合が発生して、結果的に工具の長寿命化が困難であるという問題があった。   In the form of cutting using such a cutting tool, reduction of environmental load is required, and dry cutting without using a cutting fluid has been attracting attention. In such dry cutting, the cutting blade of the cutting tool tends to be very hot, and the work material tends to adhere to the cutting blade. When the work material is welded to the cutting edge of the tool in this way, the cutting edge is altered and a so-called component cutting edge is generated, so that the machining accuracy is lowered or the welded work material falls off the cutting edge. In addition, cutting blade damage such as peeling of the hard coating layer and chipping is likely to occur. Then, this causes a problem such as a cutting edge defect or abnormal wear, resulting in a problem that it is difficult to extend the tool life.

また、表面被覆切削工具については、切刃表面の性状が切削特性に大きな影響を及ぼすことが知られており、例えば、特許文献1には、酸化物層を含む多層膜からなる硬質被覆層を成膜した表面被覆切削工具の切刃において酸化物層を含む多層膜からなる硬質被覆層の一部を除去することで、硬質被覆層の耐剥離性および耐欠損性を向上させることが開示されている。   As for surface-coated cutting tools, it is known that the properties of the cutting edge surface have a great effect on cutting characteristics. For example, Patent Document 1 discloses a hard coating layer made of a multilayer film including an oxide layer. It has been disclosed that by removing a part of the hard coating layer composed of a multilayer film including an oxide layer at the cutting blade of the surface-coated cutting tool that has been formed, the peeling resistance and fracture resistance of the hard coating layer are improved. ing.

また、特許文献2には、硬質被覆層を成膜した表面被覆切削工具の最表面を研磨して工具全体が光沢を持つほどの平滑な表面に仕上げることによって、切削の際の切刃と被削材との摩擦係数を小さくし、切刃における発熱や被削材の溶着を防ぐことが開示されている。
特開平8−11005号公報 特開2004−50385号公報
Further, Patent Document 2 discloses that a cutting edge and a coating during cutting are polished by polishing the outermost surface of a surface-coated cutting tool on which a hard coating layer has been formed so that the entire tool has a glossy surface. It is disclosed that the coefficient of friction with the work material is reduced to prevent heat generation at the cutting edge and welding of the work material.
JP-A-8-11005 JP 2004-50385 A

しかしながら、上記特許文献1および特許文献2に記載されているように硬質被覆層の切刃を含む表面を加工して表面を平滑化させるだけでは、切削抵抗が小さくなって摺動性は向上するものの、乾式切削の場合には切削によって切刃および被削材の切刃が接触する部分における温度が非常に高温となって被削材が軟化しやすくなることから被削材の溶着を抑えることができないため、溶着した被削材の脱離やこれに伴う膜剥離や切刃のチッピング等の工具損傷が発生してしまうという問題点があった。   However, as described in Patent Document 1 and Patent Document 2 described above, by simply processing the surface including the cutting edge of the hard coating layer and smoothing the surface, the cutting resistance is reduced and the slidability is improved. However, in the case of dry cutting, since the temperature at the part where the cutting edge and the cutting edge of the work material come into contact with each other becomes extremely high due to the cutting, the work material is easily softened, so the welding of the work material is suppressed. Therefore, there is a problem that tool damage such as detachment of the welded work material, film peeling and chipping of the cutting edge accompanying the work is generated.

本発明は、上記問題点を解決するためになされたものであり、その目的は、高速切削や乾式加工によって発生しやすい切刃への被削材の溶着を抑えて、高速切削や乾式切削においても優れた性能を発揮する、長寿命な表面被覆切削工具を提供することにある。   The present invention has been made to solve the above-described problems, and its purpose is to suppress welding of a work material to a cutting blade that is likely to be generated by high-speed cutting or dry processing, in high-speed cutting or dry cutting. Another object of the present invention is to provide a long-life surface-coated cutting tool that exhibits excellent performance.

本発明者は、上記課題に対し、表面被覆切削工具の表面における水に対する濡れ性を低くすることによって、乾式切削加工において発生する熱で被削材が溶着し易くなっても表面被覆切削工具の表面に溶着しにくくなり、その結果、付着した被削材が剥離する際に硬質膜の剥離や切刃のチッピング等の損傷を引き起こすことを防ぐことができ、高速切削や乾式切削においても優れた切削性能を発揮する表面被覆切削工具とすることができることを知見した。   The present inventor has solved the above problem by reducing the wettability of water on the surface of the surface-coated cutting tool even if the work material is easily welded by the heat generated in the dry cutting process. This makes it difficult to weld to the surface, and as a result, it can prevent damage such as peeling of the hard film and chipping of the cutting edge when the attached work material is peeled off, which is also excellent in high speed cutting and dry cutting It was found that a surface-coated cutting tool that exhibits cutting performance can be obtained.

すなわち、本発明の表面被覆切削工具は、基体の表面に単層または複層の硬質被覆層を被着形成した表面被覆切削工具であって、前記硬質被覆層の最表面層がX線回折分析にて検出されるピーク強度から下記の式にて算出される(200)結晶面の配向係数T が0.4〜0.9で、平均粒径が1〜3μmの窒化チタンからなるとともに、前記硬質被覆層の最表面における水の接触角θが91〜140°の範囲内にあることを特徴とするものである。
=[I(200)/I (200)][1/6Σ(I(hkl)/I (hkl))] −1
但し、
I(200) :(200)面におけるX線回折ピーク強度測定値
(200):JCPDSカード番号6−642の(200)面における標準X線回折ピーク強度
Σ(I(hkl)/I (hkl)):(111)、(200)、(220)、(311)、(222)、(400)面における[X線回折ピーク強度測定値]/[標準X線回折ピーク強度]の値の合計
That is, the surface-coated cutting tool of the present invention is a surface-coated cutting tool in which a single-layer or multi-layer hard coating layer is formed on the surface of a substrate, and the outermost surface layer of the hard coating layer is an X-ray diffraction analysis. orientation coefficient is the (200) crystal face is calculated at the following equation from the peak intensity detected at T C is 0.4 to 0.9, with an average particle size of titanium nitride of 1 to 3 [mu] m, The contact angle θ of water on the outermost surface of the hard coating layer is in the range of 91 to 140 °.
T C = [I (200) / I 0 (200)] [1 / 6Σ (I (hkl) / I 0 (hkl))] −1
However,
I (200): X-ray diffraction peak intensity measurement on (200) plane
I 0 (200): Standard X-ray diffraction peak intensity on the (200) plane of JCPDS card number 6-642
Σ (I (hkl) / I 0 (hkl)): [Measurement value of X-ray diffraction peak intensity] / [on (111), (200), (220), (311), (222), (400) plane Total value of standard X-ray diffraction peak intensity]

ここで、単層の前記硬質被覆層または複層の前記硬質被覆層のうちの最表面層が、X線回折分析にて検出されるピーク強度と下記の式にて算出される(200)結晶面の配向係数TCが0.4〜0.9の窒化チタンからなることが、硬質被覆層の最表面における界面エネルギーを小さくすることができ、硬質被覆層の最表面における水の濡れ性を本発明の範囲内に容易に最適化することができるため重要である
=[I(200)/I (200)][1/6Σ(I(hkl)/I (hkl))] −1
但し、
I(200) :(200)面におけるX線回折ピーク強度測定値
(200):JCPDSカード番号6−642の(200)面における標準X線回折ピーク強度
Σ(I(hkl)/I (hkl)):(111)、(200)、(220)、(311)、(222)、(400)面における[X線回折ピーク強度測定値]/[標準X線回折ピーク強度]の値の合計
Here, the outermost surface layer of the single hard coating layer or the multiple hard coating layers is calculated by the peak intensity detected by X-ray diffraction analysis and the following formula (200) crystal It is possible to reduce the interfacial energy on the outermost surface of the hard coating layer, and to reduce the wettability of water on the outermost surface of the hard coating layer. This is important because it can be easily optimized within the scope of the invention.
T C = [I (200) / I 0 (200)] [1 / 6Σ (I (hkl) / I 0 (hkl))] −1
However,
I (200): X-ray diffraction peak intensity measurement on (200) plane
I 0 (200): Standard X-ray diffraction peak intensity on the (200) plane of JCPDS card number 6-642
Σ (I (hkl) / I 0 (hkl)): [Measurement value of X-ray diffraction peak intensity] / [on (111), (200), (220), (311), (222), (400) plane Total value of standard X-ray diffraction peak intensity]

らに、単層の前記硬質被覆層または複層の前記硬質被覆層のうちの最表面層における平均粒径が1〜3μm、特に、1.5〜3μmとすることが、最表面における表面エネルギーを低くすることができ、最表面における被削材に対する濡れ性を低くすることができるため重要である
Et al is an average particle diameter in the outermost layer of the hard coating layer of the hard coating layer or multiple layers of a single layer is 1 to 3 [mu] m, in particular, be a 1.5~3Myuemu, surface at the outermost surface This is important because the energy can be lowered and the wettability to the work material on the outermost surface can be lowered.

また、前記硬質被覆層の最表面の最大高さRzを0.3〜1.2μmの範囲内とすることによって、水の接触角θを上記の範囲内に容易に調整することができるため望ましい。   In addition, it is preferable that the maximum height Rz of the outermost surface of the hard coating layer be in the range of 0.3 to 1.2 μm because the water contact angle θ can be easily adjusted in the above range. .

本発明の表面被覆切削工具によれば、基体の表面に被着形成した硬質被覆層の最表面における水の接触角θが91〜140°の範囲内にあることによって、切削による熱が非常に高くなる切削液を使用しない乾式切削加工、特に高速の乾式切削加工において、切削による熱で溶解した被削材が硬質被覆層の表面に溶着しにくくなる。そのため、溶着物が脱落する際に起こる膜剥離や切刃のチッピング、また、溶着物の付着による加工面粗度の低下などを防ぐことができる。その結果、特に切削加工時に切刃が高温となりやすい切削加工においても、切刃の損傷を防止できるとともに、優れた切削加工精度を発揮できるものとすることができる。   According to the surface-coated cutting tool of the present invention, the water contact angle θ on the outermost surface of the hard coating layer formed on the surface of the substrate is in the range of 91 to 140 °, so that the heat due to cutting is very high. In dry cutting that does not use a high cutting fluid, particularly high-speed dry cutting, the work material dissolved by the heat from cutting is less likely to adhere to the surface of the hard coating layer. For this reason, it is possible to prevent film peeling and chipping of the cutting edge that occur when the welded material falls off, and a decrease in roughness of the processed surface due to adhesion of the welded material. As a result, it is possible to prevent the cutting blade from being damaged and to exhibit excellent cutting accuracy even in the cutting processing in which the cutting blade is likely to become a high temperature particularly during cutting.

なお、本発明においては、硬質被覆層の最表面における水の接触角θは硬質被覆層の最表面における界面エネルギーを制御することによって調整することが可能である。したがって、硬質被覆層の最表面における水のなじみやすさを制御することによって硬質被覆層の表面における界面エネルギーを制御することが可能である。すなわち、かかる界面エネルギーは硬質被覆層の成膜履歴や研磨状態によって変化し、かつ直接測定することはできないものであるが、本発明はこれらの条件を総合的に適正化することによって硬質被覆層の最表面における界面エネルギー、すなわち水の接触角θを所定範囲に制御することを可能としたものである。より詳細には、硬質被覆層の最表面における界面エネルギーを低くすると水の接触角θが大きくなる。   In the present invention, the contact angle θ of water on the outermost surface of the hard coating layer can be adjusted by controlling the interfacial energy on the outermost surface of the hard coating layer. Therefore, it is possible to control the interfacial energy on the surface of the hard coating layer by controlling the compatibility of water on the outermost surface of the hard coating layer. That is, the interfacial energy varies depending on the film formation history and the polishing state of the hard coating layer and cannot be directly measured. However, the present invention comprehensively optimizes these conditions to provide a hard coating layer. It is possible to control the interfacial energy on the outermost surface, that is, the contact angle θ of water within a predetermined range. More specifically, when the interface energy at the outermost surface of the hard coating layer is lowered, the contact angle θ of water is increased.

水の接触角θを制御するための具体的な手法として、例えば、単層の前記硬質被覆層、または複層の硬質被覆層の最表面層に窒化チタン(TiN)を用いる場合、通常の方法で窒化チタンを成膜すると水に対する濡れ性がよくて水の接触角θは90°を下回るものであるが、本発明によれば、例えば成膜条件を制御して単層または最表面層の窒化チタンの結晶を(200)面への配向を抑えた膜質、詳細には上述した配向係数Tcを0.4〜0.9に制御することによって、理由は不明であるが、硬質被覆層の粒界エネルギーや表面エネルギーを低下させることができ、接触角θを本発明の範囲内にすることができる。   As a specific method for controlling the contact angle θ of water, for example, when titanium nitride (TiN) is used as the outermost surface layer of the single hard coating layer or the multilayer hard coating layer, a normal method is used. When the titanium nitride film is formed, the wettability with water is good and the water contact angle θ is less than 90 °. According to the present invention, for example, the film forming conditions are controlled to control the single layer or the outermost surface layer. The reason is unknown by controlling the film quality of the titanium nitride crystal in which the orientation to the (200) plane is suppressed, specifically, the above-described orientation coefficient Tc of 0.4 to 0.9. Grain boundary energy and surface energy can be reduced, and the contact angle θ can be within the range of the present invention.

このとき、単層の前記硬質被覆層または複層の硬質被覆層の最表面層における結晶粒子の粒径を大きくすることにより、結晶の界面が少なくなるため、界面エネルギーのひとつである粒界におけるエネルギー(粒界エネルギー)を低くすることができて、水の接触角θをより好適な範囲に制御することができる。単層または最表面層の平均粒径の範囲は1〜3μmである。
At this time, by increasing the grain size of the crystal grains in the outermost surface layer of the single hard coating layer or the multiple hard coating layers, the number of crystal interfaces is reduced. Energy (grain boundary energy) can be lowered, and the contact angle θ of water can be controlled in a more suitable range. Range of the average grain size of the single layer or the outermost layer is 1 to 3 [mu] m.

さらに、上記水に対する濡れ性が悪い単層または最表面層の最表面について研磨加工を施した場合には、硬質被覆層の最表面における界面エネルギーおよび水の接触角θをさらに好適な範囲に制御することができる。硬質被覆層の最表面における最大高さRzの望ましい範囲は、0.3〜1.2μmである。   Furthermore, when the outermost surface of the single layer or the outermost surface layer with poor water wettability is polished, the interfacial energy and the water contact angle θ on the outermost surface of the hard coating layer are further controlled within a suitable range. can do. A desirable range of the maximum height Rz on the outermost surface of the hard coating layer is 0.3 to 1.2 μm.

本発明の表面被覆切削工具の実施の形態の一例について、スローアウェイチップ型切削工具(以下、本発明の表面被覆切削工具を単に工具と略すことがある。)の要部拡大断面図である図1、およびその概略斜視図である図2を用いて説明する。   1 is an enlarged cross-sectional view of a main part of a throw-away tip type cutting tool (hereinafter, the surface-coated cutting tool of the present invention may be simply abbreviated as a tool) in an example of an embodiment of a surface-coated cutting tool of the present invention. 1 and FIG. 2 which is a schematic perspective view thereof.

図1、図2において、工具1は基体2の表面に硬質被覆層3を有する構成となっている。なお、図1に示す例においては、硬質被覆層3は、第1層3aが窒化チタン層、第2層3bが炭窒化チタン層、第3層3cが炭酸窒化チタン層、第4層3dが酸化アルミニウム層、第5層が最表面層4の窒化チタン層にて構成されている。   1 and 2, the tool 1 is configured to have a hard coating layer 3 on the surface of a base 2. In the example shown in FIG. 1, the hard coating layer 3 includes a first layer 3a having a titanium nitride layer, a second layer 3b having a titanium carbonitride layer, a third layer 3c having a titanium carbonitride layer, and a fourth layer 3d having a fourth layer 3d. The aluminum oxide layer and the fifth layer are composed of the titanium nitride layer of the outermost surface layer 4.

ここで、本発明の工具1によれば、硬質被覆層3の最表面5における水の接触角θを91〜140°の範囲内にすることによって、表面被覆層3の最表面5の切削によって発生する熱で工具の切刃が高温となって被削材が軟化したとしても、その一部が工具1の最表面に付着しにくくすることができる。そのため、切刃が高温となりやすい乾式切削加工でも硬質被覆層3が劣化せず、優れた工具寿命を発揮することができる。   Here, according to the tool 1 of the present invention, by making the contact angle θ of water on the outermost surface 5 of the hard coating layer 3 within the range of 91 to 140 °, by cutting the outermost surface 5 of the surface coating layer 3. Even if the cutting edge of the tool becomes hot due to the generated heat and the work material is softened, it is possible to make it difficult for a part of the tool to adhere to the outermost surface of the tool 1. Therefore, the hard coating layer 3 does not deteriorate even in the dry cutting process in which the cutting edge is likely to become high temperature, and an excellent tool life can be exhibited.

すなわち、硬質被覆層3の最表面5における水の接触角θが91°より小さいと、切刃が高温となりやすい切削加工における切削中に被削材が最表面5に溶着してしまい、その溶着によって層剥離や切刃に欠損等の損傷が発生するとともに、溶着した被削材によって加工面の精度が悪くなってしまう。   That is, if the contact angle θ of water on the outermost surface 5 of the hard coating layer 3 is smaller than 91 °, the work material is welded to the outermost surface 5 during the cutting process in which the cutting edge is likely to become high temperature. As a result, delamination and damage to the cutting edge occur, and the accuracy of the machined surface deteriorates due to the welded work material.

一方、硬質被覆層3の最表面5における水の接触角θが140°を超えると、被削材への切刃の食いつきが劣化し、工具の切れ味が低下するため切削抵抗が増大する結果、工具1の突発欠損やビビリによる加工面精度の低下等の問題が発生してしまう。なお、硬質被覆層3の最表面5における水の接触角θの望ましい範囲は、被削材の溶着を防ぎ、かつ、切削抵抗の増加を抑えることを考慮すれば93〜120°、より望ましくは95〜115°である。   On the other hand, when the contact angle θ of water on the outermost surface 5 of the hard coating layer 3 exceeds 140 °, the biting of the cutting edge to the work material is deteriorated, and the cutting resistance increases because the sharpness of the tool decreases, Problems such as sudden chipping of the tool 1 and deterioration of the machined surface accuracy due to chatter occur. In addition, the preferable range of the contact angle θ of water on the outermost surface 5 of the hard coating layer 3 is 93 to 120 °, more preferably in consideration of preventing welding of the work material and suppressing an increase in cutting resistance. It is 95-115 degrees.

ここで、硬質被覆層3の最表面5における水の接触角θの測定方法としては、メニスコグラフ法や毛細管法などの測定方法を使用することもできるが、図3に模式図で示すように、蒸留水からなる液滴6を被測定物である硬質被覆層3(最表面層4)の最表面5に置き、その液滴6が被測定物と接触している領域の周縁部における液滴6の接線Lと被測定物の最表面5とのなす角θを測定する静滴法をJIS R3257に準拠して用いることにより、容易かつ正確に測定できる。   Here, as a method for measuring the contact angle θ of water on the outermost surface 5 of the hard coating layer 3, a measuring method such as a meniscograph method or a capillary method can be used, but as shown schematically in FIG. A droplet 6 made of distilled water is placed on the outermost surface 5 of the hard coating layer 3 (outermost surface layer 4), which is the object to be measured, and the droplet 6 is in the periphery of the region in contact with the object to be measured. 6 can be easily and accurately measured by using a sessile drop method for measuring the angle θ formed by the tangent L of 6 and the outermost surface 5 of the object to be measured in accordance with JIS R3257.

なお、硬質被覆層3の最表面5における水の接触角θの制御は、硬質被覆層3の表面および粒界によるエネルギーを総合的に適正化することによって達成することができる。界面エネルギーを構成する表面エネルギーおよび粒界エネルギーは、硬質被覆層3の最表面層4の膜質、粒径、表面粗さ等の物性に加えて、成膜時の熱履歴、原料ガスの流量、成膜時間等の製法に関する条件などの総合的な性状により変化するため、物性、製法等の条件を総合的に考慮する必要がある。   Control of the water contact angle θ on the outermost surface 5 of the hard coating layer 3 can be achieved by comprehensively optimizing the energy of the surface of the hard coating layer 3 and the grain boundaries. The surface energy and grain boundary energy constituting the interfacial energy, in addition to the physical properties such as the film quality, particle size, and surface roughness of the outermost surface layer 4 of the hard coating layer 3, the heat history during film formation, the flow rate of the source gas, Since it varies depending on the overall properties such as conditions relating to the manufacturing method such as the film formation time, it is necessary to comprehensively consider the conditions such as physical properties and manufacturing method.

また、最表面層4をX線回折分析にて検出されるピーク強度値と下記に示される式にて算出される(200)結晶面の配向係数TCが0.4〜0.9の窒化チタンからなる場合には、理由は不明であるが、最表面層4の界面エネルギーが小さくなって最表面層における水の濡れ性を本発明の範囲内にできる。窒化チタンの配向係数TCの望ましい範囲は0.5〜0.8、より望ましくは0.6〜0.8である。
=[I(200)/I (200)][1/6Σ(I(hkl)/I (hkl))] −1
但し、
I(200) :(200)面におけるX線回折ピーク強度測定値
(200):JCPDSカード番号6−642の(200)面における標準X線回折ピーク強度
Σ(I(hkl)/I (hkl)):(111)、(200)、(220)、(311)、(222)、(400)面における[X線回折ピーク強度測定値]/[標準X線回折ピーク強度]の値の合計
Further, the titanium nitride having the (200) crystal plane orientation coefficient TC of 0.4 to 0.9 calculated from the peak intensity value detected by the X-ray diffraction analysis of the outermost surface layer 4 and the following formula: If made of the reason is unknown, as possible out to the interface energy of the outermost layer 4 is reduced wettability of water in the outermost layer within the scope of the present invention. The desirable range of the orientation coefficient TC of titanium nitride is 0.5 to 0.8, more desirably 0.6 to 0.8.
T C = [I (200) / I 0 (200)] [1 / 6Σ (I (hkl) / I 0 (hkl))] −1
However,
I (200): X-ray diffraction peak intensity measurement on (200) plane
I 0 (200): Standard X-ray diffraction peak intensity on the (200) plane of JCPDS card number 6-642
Σ (I (hkl) / I 0 (hkl)): [Measurement value of X-ray diffraction peak intensity] / [on (111), (200), (220), (311), (222), (400) plane Total value of standard X-ray diffraction peak intensity]

らに、上記配向係数Tの窒化チタンの最表面層4について、最表面層4の平均粒径を1〜3μm、特に1.2〜2μmの範囲内とすることによって、工具1の硬質被覆層3の最表面5の粒界エネルギーを適正化することができ、硬質被覆層3の水の濡れ角を所定の範囲に制御できて、乾式切削加工のように切刃に被削材が溶着しやすい加工においても被削材が切刃に溶着することを抑制し、膜剥離等の溶着に起因する工具損傷を防ぐことができる。
Et al is, the outermost layer 4 of titanium nitride of the orientation coefficient T C, an average particle diameter of the outermost layer 4 1 to 3 [mu] m, particularly by the range of 1.2~2Myuemu, the tool 1 hard The grain boundary energy of the outermost surface 5 of the coating layer 3 can be optimized, the water wetting angle of the hard coating layer 3 can be controlled within a predetermined range, and the work material can be applied to the cutting edge as in dry cutting. It is possible to prevent the work material from being welded to the cutting edge even in the process of being easily welded, and to prevent tool damage due to welding such as film peeling.

なお、本発明の工具1における硬質被覆層3の最表面層4の平均粒径とは、最表面層4の表面または断面について走査型電子顕微鏡または透過型電子顕微鏡を用いた組織観察を行ない、100nm×100nm以上の視野領域にて観察される画像において、最表面層4を構成している粒子のそれぞれの面積を画像解析法にて算出して、それらの平均面積を見積もった後、この平均面積を有する円に換算して求められる円の直径を意味する。   In addition, the average particle diameter of the outermost surface layer 4 of the hard coating layer 3 in the tool 1 of the present invention is a structure observation using a scanning electron microscope or a transmission electron microscope for the surface or cross section of the outermost surface layer 4, In an image observed in a visual field region of 100 nm × 100 nm or more, each area of the particles constituting the outermost surface layer 4 is calculated by an image analysis method, and the average area thereof is estimated. It means the diameter of a circle obtained by converting to a circle having an area.

さらには、最表面層4の表面である硬質被覆層3の最表面5における最大高さRzを0.3〜1.2μmの範囲内にすることによって、硬質被覆層3の表面全体にわたって特性バラツキを抑制して水の接触角θをさらに好適な範囲内に容易に調整することができるため望ましい。さらにまた、この最大高さRzの範囲内においても、とりわけ、最表面層4の表面である硬質被覆層3の最表面5における算術平均粗さRaを0.05〜0.3μmの範囲内にすることが表面エネルギーを適正化して水の接触角θを最適化できるとともに、摺動性が増し、より被削材の溶着を防ぐことができる状態に容易に調整することができるため望ましい。   Further, by setting the maximum height Rz at the outermost surface 5 of the hard coating layer 3 that is the surface of the outermost surface layer 4 within a range of 0.3 to 1.2 μm, characteristic variation over the entire surface of the hard coating layer 3 is achieved. This is desirable because it is possible to easily adjust the water contact angle θ within a more preferable range. Furthermore, even within the range of the maximum height Rz, the arithmetic average roughness Ra on the outermost surface 5 of the hard coating layer 3 that is the surface of the outermost surface layer 4 is in the range of 0.05 to 0.3 μm. This is desirable because it can optimize the surface energy and optimize the water contact angle θ, and can be easily adjusted to a state where the slidability is increased and the welding of the work material can be further prevented.

ここで、硬質被覆層3(最表面層4)の最表面5の算術平均粗さRaおよび最大高さRzを測定する方法としては、JIS B0601’01に準拠して触針式表面粗さ測定器を用いて測定すればよく、かかる測定が困難な場合には、レーザー顕微鏡や原子間力顕微鏡等の測定器を用い、硬質被覆層3の最表面5における凹凸形状を走査しながら見積もることによって測定することが可能である。この表面粗さ(Rz、Ra)の測定においては、触針式表面粗さ測定器を用いる場合には、カットオフ値:0.25mm、基準長さ:0.8mm、走査速度:0.1mm/秒にて測定する。   Here, as a method of measuring the arithmetic average roughness Ra and the maximum height Rz of the outermost surface 5 of the hard coating layer 3 (outermost surface layer 4), a stylus type surface roughness measurement is performed in accordance with JIS B0601'01. If such a measurement is difficult, use a measuring instrument such as a laser microscope or an atomic force microscope to estimate while scanning the uneven shape on the outermost surface 5 of the hard coating layer 3. It is possible to measure. In the measurement of the surface roughness (Rz, Ra), when a stylus type surface roughness measuring device is used, a cut-off value: 0.25 mm, a reference length: 0.8 mm, a scanning speed: 0.1 mm Measured at / second.

また、硬質被覆層3を構成する材質としては、周期律表の第4、5、6族金属元素、AlおよびSiから選ばれる1種以上の元素と、酸素、窒素、炭素、硼素から選ばれる1種以上の元素との化合物の単層または複層が切削性能の面で好適に使用でき、特に、最表面層4は窒化チタンからなることが、硬質被覆層3の水の接触角を本発明の範囲内に容易に制御できるため望ましい。   The material constituting the hard coating layer 3 is selected from one or more elements selected from Group 4, 5, 6 metal elements of the periodic table, Al and Si, and oxygen, nitrogen, carbon, and boron. A single layer or multiple layers of a compound with one or more elements can be suitably used in terms of cutting performance, and in particular, the outermost surface layer 4 is made of titanium nitride. This is desirable because it can be easily controlled within the scope of the invention.

なお、本発明の工具1に使用する基体2としては、炭化タングステン(WC)、炭化チタン(TiC)または炭窒化チタン(TiCN)と、所望により周期律表第4、5、6族金属の炭化物、窒化物、炭窒化物の群から選ばれる少なくとも1種からなる硬質相をコバルト(Co)および/またはニッケル(Ni)の鉄族金属から成る結合相にて結合させた超硬合金やサーメット、または窒化珪素(Si)や酸化アルミニウム(Al)質セラミック焼結体、立方晶窒化ホウ素(cBN)、ダイヤモンドを主体とした超硬質焼結体等の硬質材料、または炭素鋼、高速度鋼、合金鋼等の金属等の高硬度材料を用いるとよい。図1に示す例では、炭化タングステン(WC)を主成分とした硬質相とコバルト(Co)からなる結合相とで構成される超硬合金にて基体2が構成されている。基体2が超硬合金からなる場合には、硬度および靭性のバランスが良くて高速湿式切削加工用として安定した切削加工をすることができる。 In addition, as the base | substrate 2 used for the tool 1 of this invention, tungsten carbide (WC), titanium carbide (TiC), or titanium carbonitride (TiCN), and the carbide | carbonized_material of the 4th, 5th, 6th group metal of a periodic table depending on necessity. A cemented carbide or cermet in which a hard phase composed of at least one selected from the group of nitrides and carbonitrides is bonded with a binding phase composed of an iron group metal of cobalt (Co) and / or nickel (Ni), Or hard materials such as silicon nitride (Si 3 N 4 ), aluminum oxide (Al 2 O 3 ) ceramic sintered body, cubic boron nitride (cBN), ultra-hard sintered body mainly composed of diamond, or carbon steel High hardness materials such as metals such as high-speed steel and alloy steel may be used. In the example shown in FIG. 1, the substrate 2 is made of a cemented carbide composed of a hard phase mainly composed of tungsten carbide (WC) and a binder phase composed of cobalt (Co). When the base 2 is made of a cemented carbide, the balance between hardness and toughness is good and stable cutting can be performed for high-speed wet cutting.

(本発明の表面被覆切削工具の製造方法)
また、上述した本発明の表面被覆切削工具1を製造するには、まず、上述した硬質合金を焼成によって形成しうる金属炭化物、窒化物、炭窒化物、酸化物等の無機物粉末に、金属粉末、カーボン粉末等を適宜添加して混合し、プレス成形、鋳込成形、押出成形、冷間静水圧プレス成形等の公知の成形方法によって所定の工具形状に成形した後、真空中または非酸化性雰囲気中にて焼成することによって、上述した硬質材料からなる基体2を作製する。
(Method for producing surface-coated cutting tool of the present invention)
In order to manufacture the above-described surface-coated cutting tool 1 of the present invention, first, a metal powder is added to an inorganic powder such as a metal carbide, nitride, carbonitride, or oxide that can be formed by firing the hard alloy described above. , Carbon powder, etc., are added and mixed as appropriate, and after molding into a predetermined tool shape by a known molding method such as press molding, cast molding, extrusion molding, cold isostatic pressing, etc., in vacuum or non-oxidizing By baking in an atmosphere, the substrate 2 made of the hard material described above is produced.

次に、基体2の表面に例えば化学気相蒸着(CVD)法によって硬質被覆層3を成膜する。ここで、例えば、硬質被覆層3の最表面層4を成膜する際に、反応炉内の圧力を1〜30kPaと低く設定することで、反応炉内の原子数が少なくなり、原料原子・分子が表面拡散するときに十分に拡散し、欠陥を生成することなく結晶化することができ、表面エネルギーが低くなる。そのため、最表面5における界面エネルギーを小さくすることができるため、水の接触角θを本発明の範囲内にコントロールすることができる。   Next, the hard coating layer 3 is formed on the surface of the substrate 2 by, for example, chemical vapor deposition (CVD). Here, for example, when forming the outermost surface layer 4 of the hard coating layer 3, by setting the pressure in the reaction furnace as low as 1 to 30 kPa, the number of atoms in the reaction furnace decreases, When the molecules diffuse on the surface, the molecules diffuse sufficiently and can be crystallized without generating defects, resulting in low surface energy. Therefore, since the interfacial energy at the outermost surface 5 can be reduced, the contact angle θ of water can be controlled within the scope of the present invention.

例えば、混合ガスに対する原料ガス濃度を0.05〜1.0体積%とし、かつ、成膜温度を880〜950℃の範囲にすることで、最表面層4における配向結晶性を制御することができ、その結果、最表面層の表面エネルギーを小さくすることができて水の接触角θを本発明の範囲内にコントロールすることができる。   For example, the oriented crystallinity in the outermost surface layer 4 can be controlled by setting the source gas concentration with respect to the mixed gas to 0.05 to 1.0% by volume and setting the film forming temperature to a range of 880 to 950 ° C. As a result, the surface energy of the outermost surface layer can be reduced, and the contact angle θ of water can be controlled within the range of the present invention.

より具体的には、例えば、最表面層4として窒化チタン(TiN)層を成膜するには、原料ガスとして塩化チタン(TiCl)ガスが0.05〜0.5体積%、反応ガスとして窒素(N)ガスが25〜50体積%、残りがキャリアガスとして水素(H)ガスからなる混合ガスを調整し、チャンバ内を炉内温度880〜950℃、圧力7〜10kPaとする。この条件で成膜するとTiN層の(200)結晶面の配向係数Tが0.4〜0.9となる可能性が高くなる。 More specifically, for example, in order to form a titanium nitride (TiN) layer as the outermost surface layer 4, titanium chloride (TiCl 4 ) gas is used as a raw material gas in an amount of 0.05 to 0.5% by volume, and as a reaction gas. A mixed gas composed of 25 to 50% by volume of nitrogen (N 2 ) gas and the remaining hydrogen (H 2 ) gas as a carrier gas is adjusted, and the temperature in the chamber is set to 880 to 950 ° C. and the pressure is set to 7 to 10 kPa. Orientation coefficient T C of (200) crystal face of the TiN layer when deposited under this condition is likely to be 0.4 to 0.9.

次に、硬質被覆層3を成膜後に、硬質被覆層3の表面をブラシ、弾性砥石、ブラスト、等の研磨方法によって研磨することによって、工具1の表面粗さを小さくして最表面層4の濡れ性を制御する。ここで、研磨方法としては、ブラシ研磨を行うことが望ましい。この時、最表面層4を成膜する層厚とその後に研磨する研磨比率を制御することによって、最表面層4を構成するTiN粒子の平均粒径を制御することができる。接触角θを調整するとともに最表面層4の最表面5における局所的な濡れ性のばらつきをなくして均一化することができる。   Next, after the hard coating layer 3 is formed, the surface of the hard coating layer 3 is polished by a polishing method such as brush, elastic grindstone, blasting, etc., so that the surface roughness of the tool 1 is reduced and the outermost surface layer 4 To control the wettability. Here, it is desirable to perform brush polishing as a polishing method. At this time, the average particle diameter of the TiN particles constituting the outermost surface layer 4 can be controlled by controlling the layer thickness for forming the outermost surface layer 4 and the polishing ratio for subsequent polishing. It is possible to adjust the contact angle θ and uniformize the local wettability variation on the outermost surface 5 of the outermost surface layer 4.

なお、上記の実施の形態の例では化学気相蒸着(CVD)法にて硬質被覆層3の成膜を行なう方法について説明したが、本発明の工具1の製造方法はこれに限定されるものではなく、物理気相蒸着(PVD)法等のその他の成膜方法にて硬質被覆層3を成膜したものであってもよい。この場合でも成膜ガス流量を制御すること等によって最表面層4の膜質を制御した条件にて成膜すること、さらに上述した加工方法にて硬質被覆層3の最表面5を研磨加工して硬質被覆層3の最表面5における水の接触角を制御することができる。   In the example of the above embodiment, the method for forming the hard coating layer 3 by the chemical vapor deposition (CVD) method has been described. However, the method for manufacturing the tool 1 of the present invention is limited to this. Instead, the hard coating layer 3 may be formed by other film forming methods such as physical vapor deposition (PVD). Even in this case, the film formation is performed under the condition that the film quality of the outermost surface layer 4 is controlled by controlling the flow rate of the film forming gas, and the outermost surface 5 of the hard coating layer 3 is polished by the processing method described above. The contact angle of water on the outermost surface 5 of the hard coating layer 3 can be controlled.

また、上記の実施の形態の例では、硬質被覆層3が5層の複層からなる場合について説明したが、本発明の工具1では硬質被覆層3が4層以下、または6層以上の複層からなる場合について硬質被覆層3が単層からなるものであっても発明の効果を失わない。   In the example of the above-described embodiment, the case where the hard coating layer 3 is composed of five layers has been described. However, in the tool 1 of the present invention, the hard coating layer 3 is composed of four layers or less, or six layers or more. Even when the hard coating layer 3 is composed of a single layer, the effects of the invention are not lost.

平均粒径1.1μmの炭化タングステン(WC)粉末に対して、平均粒径1.2μmの金属コバルト(Co)粉末を5質量%、平均粒径2.0μmの炭化チタン(TiC)粉末を0.5質量%、平均粒径2.0μmのCr粉末を0.5質量%の割合で添加、混合して、プレス成形により切削工具形状(CNMA120412)に成形した後、脱バインダ処理を施し、0.01Paの真空中、1450℃で1時間焼成して超硬合金を作製した。さらに、作製した超硬合金にブラシ加工にてすくい面より切刃処理(ホーニングR)を施した。 5% by mass of metallic cobalt (Co) powder with an average particle size of 1.2 μm and 0% of titanium carbide (TiC) powder with an average particle size of 2.0 μm with respect to tungsten carbide (WC) powder with an average particle size of 1.1 μm. 0.5% by mass of Cr 3 C 2 powder having an average particle size of 2.0 μm was added and mixed at a ratio of 0.5% by mass, and after forming into a cutting tool shape (CNMA1204112) by press molding, the binder removal treatment was performed. Applied and fired at 1450 ° C. for 1 hour in a vacuum of 0.01 Pa to produce a cemented carbide. Further, the manufactured cemented carbide was subjected to cutting edge processing (Honing R) from the rake face by brushing.

次に、上記超硬合金に対して、化学気相蒸着(CVD)法により各種の硬質被覆層を表2に示す構成の多層膜からなる硬質被覆層を成膜した。なお、表2の各層の成膜条件は表1に示した。そして、硬質被覆層を被覆した後、表2に示す研磨方法によって試料の表面を研磨して最表面層の層厚を表2に記載の値に調整し、試料No.1〜9の表面被覆切削工具を作製した。

Figure 0004845490
Next, a hard coating layer composed of a multilayer film having a structure shown in Table 2 was formed on the cemented carbide alloy by a chemical vapor deposition (CVD) method. The deposition conditions for each layer in Table 2 are shown in Table 1. And after coat | covering a hard coating layer, the surface of a sample is grind | polished by the grinding | polishing method shown in Table 2, and the layer thickness of the outermost surface layer is adjusted to the value of Table 2, and sample No. 1 to 9 surface-coated cutting tools were produced.
Figure 0004845490

得られた工具のすくい面の平坦部について、表面における水の接触角θの測定を図1に示すようなJIS R3257に準拠した静滴法を用いて行なった。結果は表2に示した。   About the flat part of the rake face of the obtained tool, the contact angle θ of water on the surface was measured using a sessile drop method based on JIS R3257 as shown in FIG. The results are shown in Table 2.

また、工具の切刃近くのランド等の平坦部における最表面の表面粗さ(最大高さRz、算術平均粗さRa)を触針式の表面粗さ測定器にて、JIS B0601’01に準拠して触針式表面粗さ測定器を用い、カットオフ値0.25mm、基準長さ:0.8mm、走査速度:0.1mm/秒にて測定した。結果は表2に示した。   In addition, the surface roughness (maximum height Rz, arithmetic average roughness Ra) of the flat surface such as a land near the cutting edge of the tool is changed to JIS B0601'01 using a stylus type surface roughness measuring instrument. The measurement was performed using a stylus type surface roughness measuring instrument in accordance with a cutoff value of 0.25 mm, a reference length of 0.8 mm, and a scanning speed of 0.1 mm / second. The results are shown in Table 2.

さらに、得られた工具の硬質被覆層を透過型電子顕微鏡(TEM)にて500,000倍の倍率で観察し、画像解析法を用いて最表面層の粒径を測定した。結果は表2に示した。具体的には、個々の粒子について面積を算出し、その平均値を同じ面積の円に換算した時の円の直径を最表面層の平均粒径として算出した。   Furthermore, the hard coating layer of the obtained tool was observed with a transmission electron microscope (TEM) at a magnification of 500,000 times, and the particle size of the outermost surface layer was measured using an image analysis method. The results are shown in Table 2. Specifically, the area of each particle was calculated, and the diameter of the circle when the average value was converted into a circle having the same area was calculated as the average particle diameter of the outermost surface layer.

また、管球にCuを用いて最表面のTiN層のX線回折分析を行い、得られたピーク強度から、(200)面における配向係数Tを求めた。結果は表2に示した。

Figure 0004845490
Further, the outermost TiN layer was subjected to X-ray diffraction analysis using Cu as a tube, and the orientation coefficient Tc on the (200) plane was determined from the obtained peak intensity. The results are shown in Table 2.
Figure 0004845490

そして、この工具を用いて下記の条件により切削試験を行い、性能を評価した。   Then, using this tool, a cutting test was performed under the following conditions to evaluate the performance.

(切削条件)
被削材 :SCM440 円柱材
工具形状:CNMA120408
切削速度:300m/分
送り速度:0.2mm/rev
切り込み:1.5mm
切削状態:乾式
評価項目:顕微鏡にて切刃を観察し、フランク摩耗量・先端摩耗量を測定

Figure 0004845490
(Cutting conditions)
Work material: SCM440 Cylindrical tool shape: CNMA120408
Cutting speed: 300 m / min Feeding speed: 0.2 mm / rev
Cutting depth: 1.5mm
Cutting condition: Dry evaluation item: Observe the cutting edge with a microscope and measure the amount of flank wear and tip wear
Figure 0004845490

表1〜3より、接触角θが91°よりも小さくなった試料No.7,8では、被削材が切刃に溶着してしまったために、チッピングや層剥離が発生し、耐摩耗性、耐欠損性が共に悪く、工具寿命の非常に短いものであった。   From Tables 1 to 3, Sample No. with a contact angle θ smaller than 91 ° was obtained. In Nos. 7 and 8, since the work material was welded to the cutting edge, chipping and delamination occurred, both wear resistance and fracture resistance were poor, and the tool life was very short.

また、接触角θが140°を超えた試料No.9では、被削材への工具切刃の食いつきが悪いため、切削抵抗が高くなってしまい、切刃のチッピングや膜剥離が発生して耐摩耗性および耐欠損性がともに悪く、工具寿命の短いものであった。   Sample No. with a contact angle θ exceeding 140 ° was used. In No. 9, since the cutting edge of the tool on the work material is poor, cutting resistance increases, chipping of the cutting edge and film peeling occur, and both wear resistance and chipping resistance are deteriorated. It was short.

それに対し、接触角θを91°〜140°の範囲内とした試料No.1〜6では、上記切削条件において耐摩耗性、耐欠損性共に優れ、切刃の損傷もほとんどなかった。   On the other hand, Sample No. with a contact angle θ in the range of 91 ° to 140 °. Nos. 1 to 6 were excellent in wear resistance and fracture resistance under the above cutting conditions, and there was almost no damage to the cutting edge.

本発明の表面被覆切削工具の実施の形態の一例における硬質被覆層の層構成を示した要部拡大断面図である。It is a principal part expanded sectional view which showed the layer structure of the hard coating layer in an example of embodiment of the surface covering cutting tool of this invention. 本発明の表面被覆切削工具の実施の形態の好適例であるスローアウェイチップの外観を示す概略斜視図である。It is a schematic perspective view which shows the external appearance of the throw away tip which is a suitable example of embodiment of the surface covering cutting tool of this invention. 硬質被覆層の最表面における水の接触角を測定する方法を説明するための模式図である。It is a schematic diagram for demonstrating the method to measure the contact angle of water in the outermost surface of a hard coating layer.

符号の説明Explanation of symbols

1:工具(表面被覆切削工具)
2:基体
3:硬質被覆層
4:最表面層
5:硬質被覆層の最表面
6:液滴
7:すくい面
8:逃げ面
9:切刃
θ:接触角
1: Tool (surface coated cutting tool)
2: Substrate 3: Hard coating layer 4: Outermost surface layer 5: Outermost surface of the hard coating layer 6: Droplet 7: Rake face 8: Flank 9: Cutting edge θ: Contact angle

Claims (2)

基体の表面に単層または複層の硬質被覆層を被着形成した表面被覆切削工具であって、前記硬質被覆層の最表面層がX線回折分析にて検出されるピーク強度から下記の式にて算出される(200)結晶面の配向係数T が0.4〜0.9で、平均粒径が1〜3μmの窒化チタンからなるとともに、前記硬質被覆層の最表面における水の接触角θが91〜140°の範囲内にあることを特徴とする表面被覆切削工具。
=[I(200)/I (200)][1/6Σ(I(hkl)/I (hkl))] −1
但し、
I(200) :(200)面におけるX線回折ピーク強度測定値
(200):JCPDSカード番号6−642の(200)面における標準X線回折ピーク強度
Σ(I(hkl)/I (hkl)):(111)、(200)、(220)、(311)、(222)、(400)面における[X線回折ピーク強度測定値]/[標準X線回折ピーク強度]の値の合計
A surface-coated cutting tool in which a single-layer or multiple-layer hard coating layer is formed on the surface of a substrate, wherein the outermost surface layer of the hard coating layer is expressed by the following formula from the peak intensity detected by X-ray diffraction analysis in the the (200) orientation coefficient T C of the crystal plane is 0.4 to 0.9 calculated by, with an average particle size of titanium nitride of 1 to 3 [mu] m, the contact of water on the outermost surface of the hard coating layer A surface-coated cutting tool having an angle θ in the range of 91 to 140 °.
T C = [I (200) / I 0 (200)] [1 / 6Σ (I (hkl) / I 0 (hkl))] −1
However,
I (200): X-ray diffraction peak intensity measurement on (200) plane
I 0 (200): Standard X-ray diffraction peak intensity on the (200) plane of JCPDS card number 6-642
Σ (I (hkl) / I 0 (hkl)): [Measurement value of X-ray diffraction peak intensity] / [on (111), (200), (220), (311), (222), (400) plane Total value of standard X-ray diffraction peak intensity]
前記硬質被覆層の最表面の最大高さRzが0.3〜1.2μmの範囲内にあることを特徴とする請求項に記載の表面被覆切削工具。 2. The surface-coated cutting tool according to claim 1 , wherein a maximum height Rz of the outermost surface of the hard coating layer is in a range of 0.3 to 1.2 μm.
JP2005338444A 2005-11-24 2005-11-24 Surface coated cutting tool Expired - Fee Related JP4845490B2 (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP2005338444A JP4845490B2 (en) 2005-11-24 2005-11-24 Surface coated cutting tool

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP2005338444A JP4845490B2 (en) 2005-11-24 2005-11-24 Surface coated cutting tool

Publications (2)

Publication Number Publication Date
JP2007144522A JP2007144522A (en) 2007-06-14
JP4845490B2 true JP4845490B2 (en) 2011-12-28

Family

ID=38206537

Family Applications (1)

Application Number Title Priority Date Filing Date
JP2005338444A Expired - Fee Related JP4845490B2 (en) 2005-11-24 2005-11-24 Surface coated cutting tool

Country Status (1)

Country Link
JP (1) JP4845490B2 (en)

Families Citing this family (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP2965842B1 (en) * 2013-03-04 2018-12-12 Tungaloy Corporation Coated cutting tool
JP2020157176A (en) * 2019-03-25 2020-10-01 セイコーエプソン株式会社 Crusher and crushing classifier

Family Cites Families (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2668581B2 (en) * 1989-06-06 1997-10-27 日本電気ホームエレクトロニクス株式会社 Magnetic tape sliding member
JPH06346246A (en) * 1993-06-10 1994-12-20 Sekisui Chem Co Ltd Production of formed body
JPH10263903A (en) * 1997-03-28 1998-10-06 Hitachi Metals Ltd Titanium carbide coating tool
JP2004050385A (en) * 2002-07-24 2004-02-19 Sumitomo Electric Ind Ltd Coated cemented carbide tool

Also Published As

Publication number Publication date
JP2007144522A (en) 2007-06-14

Similar Documents

Publication Publication Date Title
JP5872747B1 (en) Surface coated cutting tool
JP5295325B2 (en) Surface coated cutting tool
JP4994367B2 (en) CUTTING TOOL, MANUFACTURING METHOD THEREOF, AND CUTTING METHOD
CN101790594B (en) Ti-based cermet and coated cermet and cutting tool
CN103282147B (en) Cutting tool
JP5884004B1 (en) Surface coated cutting tool
JP5890594B2 (en) Coated tool
JP6507456B2 (en) Method of manufacturing surface coated cutting tool
US10744568B2 (en) Coated tool
WO2015030073A1 (en) Coated tool
JP5918457B1 (en) Coated tool
JP4854359B2 (en) Surface coated cutting tool
WO2007049785A1 (en) Surface-coated member, method for manufacture thereof, and cutting tool
JP6556246B2 (en) Coated tool
JP4991244B2 (en) Surface coated cutting tool
JP2022138563A (en) Surface-coated machining tool
JP4845490B2 (en) Surface coated cutting tool
JP2011093003A (en) Surface-coated member
JP5898394B1 (en) Coated tool
JP2015085417A (en) Coated tool
CN112839761B (en) cutting tool
JP4845615B2 (en) Surface coated cutting tool
CN112839760B (en) cutting tool
JP4936742B2 (en) Surface coating tools and cutting tools
JP2006205300A (en) Surface covering member and cutting tool

Legal Events

Date Code Title Description
A621 Written request for application examination

Free format text: JAPANESE INTERMEDIATE CODE: A621

Effective date: 20080519

A131 Notification of reasons for refusal

Free format text: JAPANESE INTERMEDIATE CODE: A131

Effective date: 20110531

A521 Request for written amendment filed

Free format text: JAPANESE INTERMEDIATE CODE: A523

Effective date: 20110714

TRDD Decision of grant or rejection written
A01 Written decision to grant a patent or to grant a registration (utility model)

Free format text: JAPANESE INTERMEDIATE CODE: A01

Effective date: 20110913

A01 Written decision to grant a patent or to grant a registration (utility model)

Free format text: JAPANESE INTERMEDIATE CODE: A01

A61 First payment of annual fees (during grant procedure)

Free format text: JAPANESE INTERMEDIATE CODE: A61

Effective date: 20111011

FPAY Renewal fee payment (event date is renewal date of database)

Free format text: PAYMENT UNTIL: 20141021

Year of fee payment: 3

R150 Certificate of patent or registration of utility model

Ref document number: 4845490

Country of ref document: JP

Free format text: JAPANESE INTERMEDIATE CODE: R150

Free format text: JAPANESE INTERMEDIATE CODE: R150

LAPS Cancellation because of no payment of annual fees