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JP4922153B2 - Method for reducing oil absorption of bread crumbs, method for producing bread crumbs and bread crumbs - Google Patents
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JP4922153B2 - Method for reducing oil absorption of bread crumbs, method for producing bread crumbs and bread crumbs - Google Patents

Method for reducing oil absorption of bread crumbs, method for producing bread crumbs and bread crumbs Download PDF

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JP4922153B2
JP4922153B2 JP2007501568A JP2007501568A JP4922153B2 JP 4922153 B2 JP4922153 B2 JP 4922153B2 JP 2007501568 A JP2007501568 A JP 2007501568A JP 2007501568 A JP2007501568 A JP 2007501568A JP 4922153 B2 JP4922153 B2 JP 4922153B2
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bread crumbs
bread
oil
crumbs
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美鈴 冨田
貴弘 大庭
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Nissui Corp
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Nippon Suisan Kaisha Ltd
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    • AHUMAN NECESSITIES
    • A23FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
    • A23LFOODS, FOODSTUFFS OR NON-ALCOHOLIC BEVERAGES, NOT OTHERWISE PROVIDED FOR; PREPARATION OR TREATMENT THEREOF
    • A23L7/00Cereal-derived products; Malt products; Preparation or treatment thereof
    • A23L7/10Cereal-derived products
    • A23L7/157Farinaceous granules for dressing meat, fish or the like

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Description

本発明は特別な添加物を使用することなく、パン粉の油ちょう時の吸油性を低下させる方法、その方法を用いる低吸油性を有するパン粉を製造する方法およびそのパン粉に関する。   The present invention relates to a method for reducing the oil absorbency of bread crumbs without using a special additive, a method for producing bread crumbs having low oil absorption using the method, and the bread crumbs.

トンカツ、コロッケ、えびフライ、牡蠣フライ、白身魚フライ等に代表されるフライ食品はパン粉と油脂独特の食感の良さ、香りの良さから家庭内においてはもちろん、外食産業にも幅広く受け入れられている食品である。
種々の素材にパン粉を衣付けして油ちょうするフライ食品の衣の役割として1)油脂の高温が直接材料に伝わらないように温度の緩衝作用を行う、2)うまみ成分やビタミン類などの食品成分の損失を防ぐ、3)高温短時間加熱かつ油脂を含むことにより、独特の食感を有する層を形成する、4)衣自体が吸油し、適度にこげることにより独特の香りを生じ食欲をそそる、などが挙げられる。しかし、近年のヘルシー志向の強まりにより油脂カロリーの過剰摂取が問題にされ、フライ食品のような高い油脂含量の食品は敬遠される傾向がある。油脂分を多く摂取すると血液中にコレステロールや中性脂肪が多くなって動脈硬化を引き起こす原因となり、さらに動脈硬化が進むと、狭心症や心筋梗塞が心配されるという問題がある。
そのような背景のもと、パン粉及び製粉業界では上記のフライ衣の吸油という問題点を解決するために種々の油ちょう時の吸油量が少ない、いわゆる低吸油パン粉の開発がなされてきた。例えば、豆類から抽出した食物繊維細胞膜を配合する吸油率の低いパン粉(特許文献1)、とうもろこし外皮から調整された食物繊維を含有するフライ用パン粉(特許文献2)、トウモロコシから調製された食物繊維及び大豆から調製されたタンパク質の添加を特徴とする低吸油性フライ用パン粉(特許文献3)、主原料として大豆粉および加工澱粉を添加した穀物類を用い、かつ焼成されるパン比容積を2.8〜3.6ml/gになるように醗酵を抑制して焼成することを特徴とする吸油の少ないパン粉の製造方法(特許文献4)、定法によって得られるパンブロックを圧延した後、粉砕することを特徴とするパン粉の製造方法(特許文献5)、食材本体の表面に、キトサンを含有させたパン粉を付着させたパン粉付き食品(特許文献6)、オキアミ殻粉末を添加するなどの方法により、パンの気泡数を増加し、かつ、各気泡の大きさを小さくするように制御したパンから製造した、低吸油性でありながら良好な食感を維持したパン粉(特許文献7)等がある。
Fried foods such as tonkatsu, croquettes, fried shrimp, fried oysters, and fried white fish are widely accepted not only in the home but also in the food service industry due to the good texture and fragrance unique to bread crumbs and fats and oils. It is food.
As a garment for frying foods that are made by applying bread crumbs to various ingredients, 1) it acts as a buffer to prevent the high temperature of the oil from being directly transferred to the ingredients, and 2) foods such as umami ingredients and vitamins. Prevent loss of ingredients 3) Heat and heat for a short time and contain fats and oils to form a layer with a unique texture 4) Apparel absorbs oil and moderately stiffens to produce a unique scent and appetite And so on. However, due to the recent increase in health-consciousness, excessive intake of fat and oil calories has become a problem, and foods with a high fat content such as fried foods tend to be avoided. If a large amount of oil or fat is consumed, cholesterol and neutral fat increase in the blood and cause arteriosclerosis, and if arteriosclerosis further progresses, there is a problem that angina or myocardial infarction is a concern.
Under such circumstances, so-called low oil-absorbing bread crumbs have been developed in the bread crumbs and milling industry in order to solve the above-mentioned problem of oil absorption of frying garments, which has a small amount of oil absorption during various oiling operations. For example, bread crumbs (Patent Document 1) with a low oil absorption ratio containing dietary fiber cell membranes extracted from beans, bread crumbs for frying (Patent Document 2) containing dietary fibers prepared from corn hulls, dietary fibers prepared from corn And low oil-absorbing frying bread crumbs characterized by addition of protein prepared from soybeans (Patent Document 3), grains containing soybean flour and processed starch added as main ingredients, and the bread specific volume to be baked is 2 A method for producing bread crumbs with low oil absorption (Patent Document 4), characterized in that fermentation is suppressed to 8 to 3.6 ml / g and baking, and a bread block obtained by a conventional method is rolled and then pulverized. A bread crumb manufacturing method (Patent Document 5), a food with bread crumbs in which bread crumbs containing chitosan are attached to the surface of the food body (Patent Document 6), Maintaining a good texture despite its low oil absorption, manufactured from bread that is controlled to increase the number of bubbles in the bread and reduce the size of each bubble by adding krill shell powder, etc. Bread crumbs (Patent Document 7) and the like.

しかし、これらの食物繊維及びタンパク質が低吸油衣としての効果を十分に発揮するにはかなりの量を添加しなくてはならず、添加量の増加に伴って、パン粉は大変硬くなり、食味が低下する。また、パン比容積の抑制やパンブロックの圧延といった方法に関しても、パンのメを詰まらせることによりパン粉は硬くなり、食味低下は避けられない。
最近のパン粉利用の傾向として、食感の硬いドライタイプから生のソフトタイプへ移行している点などを考慮すると、フライ衣は食感が軽い方が好ましい。すなわち、従来の低吸油フライ衣の技術ではフライ時の吸油量は低下するものの、食感が硬くなるという嗜好面での問題を残しており、そのため、それらのパン粉は広く普及していないのが現状である。
However, in order for these dietary fibers and proteins to fully exert their effects as a low oil-absorbing garment, a considerable amount must be added, and as the amount added increases, the bread crumb becomes very hard and tastes good. descend. In addition, regarding methods such as suppression of bread specific volume and rolling of bread blocks, the bread crumbs are hardened by clogging the bread, and a reduction in taste is inevitable.
Considering the recent trend of using breadcrumbs, such as the transition from a dry type with a hard texture to a raw soft type, it is preferable that the frying clothes have a light texture. In other words, the conventional oil-absorbing frying garment technique reduces the amount of oil absorption during frying, but leaves a problem in taste that the texture becomes stiff, and as a result, those breadcrumbs are not widely used. Currently.

特開平2−20258号JP-A-2-20258 特開平5−61号JP 5-61 特開平7−246072号Japanese Patent Laid-Open No. 7-246072 特開平7−250641号Japanese Patent Laid-Open No. 7-250641 特開平8−131108号JP-A-8-131108 特開平9−37749号JP-A-9-37749 特開2003−284519号JP 2003-284519 A

これまでにパン粉の吸油量を抑制する方法として、パン生地原料に各種の食物繊維やタンパク質を添加する、もしくは生地の醗酵を抑制してパン比容積を減少させること等が提案されてきた。しかしながら、各種食物繊維やタンパク質の添加、生地の発酵などを抑制して作製されたパンから調製されたパン粉は食感が硬くなり、油ちょう後の食味は著しく低下するなどの不具合が生じる。
本発明は、食感を変化させずに、すなわち食味を損なわずに油ちょう時の油の吸収を抑制することができるパン粉を提供することを目的としている。
So far, as a method for suppressing the amount of oil absorption of bread crumbs, it has been proposed to add various dietary fibers and proteins to the bread dough raw material, or to suppress the fermentation of the dough to reduce the bread specific volume. However, bread crumbs prepared from breads prepared by suppressing the addition of various dietary fibers and proteins, dough fermentation, etc., have a hard texture and have a problem that the taste after dripping is drastically reduced.
An object of this invention is to provide the bread crumbs which can suppress absorption of the oil at the time of oiling without changing a food texture, ie, without impairing taste.

通常、焼成後パンの水分は40〜42%程度であり、それを老化、粉砕したパン粉の水分量は40%以下となる。本発明はパン粉に加湿し乾燥することにより油ちょう後のパン粉の吸油量を軽減する方法であるが、通常、焼成後のパンもしくはパン粉に加湿するという行為(工程)は全く存在しない。パンに加湿したら粉砕機にかけることが困難になり、パン粉にすることがまずできない。できたパン粉に加湿した場合においても機械装置にくっついてしまうなどの不具合が生じる。そのため、パン粉工場において焼成・老化後、パンからパン粉にする工程は水分厳禁のドライエリアとなっているのが一般的である。
パン粉を食品加工(例 フライ品の製造)に用いる場合にも、パン粉水分が多いとハンドリング悪く、特に食品に機械(ブレッターマシン等)でパン粉付けをする場合には高水分のものほど機械適性が低くなる。そのため、会社によっては水分28%〜33%の半生パン粉を使用することはしばしばある。このようなことから、通常、パン粉に加水するということはパンを取り扱う当業者において考えられないことである。しかしながら、本発明者らは低吸油パン粉の開発研究の過程において、加水したパン粉を加熱乾燥することによりパン粉の吸油性が低下すること、さらにその食感が添加物により低吸油を図ったパン粉に比べて通常のパン粉に近いことを見出し本発明を完成させた。
家庭でフライ等を作るときに、ドライパン粉を用いて生パン粉の風合いを出すために、パン粉を湿らせて用いることがあるが、この加湿はせいぜいドライパン粉を生パン粉に戻す程度の加湿であり、乾燥することなくそのまま油ちょうされるものである。本発明は、低吸油のパン粉を工業規模で製造する方法である。
Usually, the moisture of bread after baking is about 40 to 42%, and the moisture content of bread crumbs obtained by aging and pulverizing the bread is 40% or less. Although the present invention is a method of reducing the oil absorption of bread crumbs after dipping by humidifying and drying the bread crumbs, there is usually no action (step) of humidifying the bread or bread crumbs after baking. When the bread is moistened, it becomes difficult to put it in a grinder and it cannot be made into bread crumbs. Even when the resulting bread crumbs are humidified, problems such as sticking to the mechanical device occur. Therefore, after baking and aging in a bread crumb factory, the process of turning bread into bread crumbs is generally a dry area where moisture is strictly prohibited.
Even when bread crumbs are used in food processing (eg, frying), handling with a large amount of bread crumbs is not easy to handle. Lower. Therefore, some companies often use half-bread crumbs with a moisture content of 28% to 33%. For this reason, adding water to bread crumbs is usually not considered by those skilled in the art of handling bread. However, in the course of research and development of low oil-absorbing bread crumbs, the present inventors reduced the oil absorption of bread crumbs by heating and drying the crushed bread crumbs. The present invention was completed by finding that it is close to ordinary bread crumbs.
When making frying etc. at home, dry bread crumbs may be used to moisten the bread crumbs to create a texture of raw bread crumbs, but this humidification is at most humidifying the dry bread crumbs back to raw bread crumbs. It is oiled without drying. The present invention is a method for producing low oil absorption bread crumbs on an industrial scale.

本発明は、原料のパン粉に水分量が45〜65重量%になるように加湿し、加湿が均一になるまで寝かせた後、パン粉に含まれる澱粉の糊化温度以上の温度で乾燥することを特徴とするパン粉の油ちょう時の吸油性を低下する方法を要旨とする。原料のパン粉はパン粉であればなんでもよいが、通常は、小麦粉、イースト、糖、食塩、水を基本原料とし、焙焼式あるいは電極式焼成方法により焼成、老化したパンを粉砕したパン粉である。
なお、本発明に用いる原料パン粉とは中種法(sponge-dough method)や直捏法(straight-dough method)、液種法(liquid
sponge-method)などの生地作製法から作製されるパン比容積(specific volume)の大きいパンから作製されるパン粉を指している。英語でbread crumbs(パン粉)という場合、その範疇にはクラッカー粉、ブレッター粉といったイーストを使用することなくベーキングパウダーで膨らませたパンやイーストを使用しているものの発酵を抑制して作製されたパンを粉砕したものについても含むことも多いが、本発明に用いる原料パン粉にはそれらは含まれない。本発明に使用される原料パン粉とはいわゆる日本式パン粉(Japanese-style PANKO)を指している。従来、日本式パン粉は日本でのみ生産されていたが、最近はアメリカ、ニュージーランド、南米など多くの地域で親しまれるようになっており、特に日本式という区別はなくなってきている。
原料のパン粉の水分量を45〜65重量%になるように加湿する。乾燥雰囲気温度は一般に糊化が始まる温度である40℃以上が好ましく、実用的には100℃以上、特に好ましいのは、150〜250℃である。パン粉の水分量は10〜40重量%になるまで乾燥するのが好ましい。本方法により、原料のパン粉(生)の油ちょう時の吸油量を30%以上低下させることができる。

In the present invention, the raw bread crumbs are moisturized so that the moisture content is 45 to 65% by weight, laid until the humidification is uniform, and then dried at a temperature equal to or higher than the gelatinization temperature of starch contained in the bread crumbs. The gist of the method is to reduce the oil absorption of the bread crumb, which is a characteristic feature. The raw bread crumbs may be anything as long as they are bread crumbs, but are usually bread crumbs obtained by pulverizing bread baked and aged by a roasting type or electrode type baking method using wheat flour, yeast, sugar, salt and water as basic raw materials.
In addition, the raw material bread crumbs used in the present invention are the sponge-dough method, straight-dough method, liquid seed method (liquid
It refers to bread crumbs made from bread with a large specific volume produced from dough making methods such as sponge-method. In English, bread crumbs (bread crumbs) are classified into bread baked with baking powder without using yeast, such as cracker powder and batter powder, or bread made with yeast that suppresses fermentation. In many cases, the crushed product is included, but they are not included in the raw bread crumbs used in the present invention. The raw material bread crumb used in the present invention refers to so-called Japanese-style PANKO. Traditionally, Japanese bread crumbs were produced only in Japan, but recently they have become popular in many regions such as the United States, New Zealand, and South America.
The raw bread crumbs are humidified so that the water content is 45 to 65% by weight . The drying atmosphere temperature is preferably 40 ° C. or higher, generally the temperature at which gelatinization begins, practically 100 ° C. or higher, and particularly preferably 150 to 250 ° C. It is preferable to dry until the water content of bread crumbs is 10 to 40% by weight. By this method, the oil absorption amount of the raw bread crumbs (raw) during oiling can be reduced by 30% or more.

本発明は、上述のパン粉の油ちょう時の吸油性を低下する方法を用いて製造した低吸油パン粉を要旨とする。上述の方法により、パン粉乾燥重量当たりの吸油量を1.2g/g以下、さらに1.0g/g以下に油ちょう時の吸油性を低下させることができる。本発明の方法で製造した低吸油パン粉は、加湿・加熱により糊化が進んでいるので、BAP法により測定した糊化度が生パン粉(水分量30〜35重量%)の状態で平均45%以上であるか、ドライパン粉(水分量10〜15重量%)の状態で平均55%以上であるか、あるいは、DSC法により測定した糊化熱量ΔHが平均2.9J/g以下の値を示し、テンシプレッサーにより測定したパン粉のHardnessは2×10dyn/cm以下である。
本発明は、上述の低吸油パン粉を使用した食品、特に油ちょう食品を要旨とする。
The gist of the present invention is a low oil-absorbing bread crumb produced by using the above-described method for reducing the oil absorption of the bread crumbs. By the above-mentioned method, the oil absorption per bread crumb dry weight can be reduced to 1.2 g / g or less, and further to 1.0 g / g or less, and the oil absorbency at the time of oiling can be reduced. Since the low oil-absorbing bread crumb produced by the method of the present invention has been gelatinized by humidification and heating, the average degree of gelatinization measured by the BAP method is 45% in the state of raw bread crumbs (water content 30 to 35 wt%). Or an average of 55% or more in the state of dry bread crumbs (moisture content of 10 to 15% by weight), or the gelatinization heat amount ΔH measured by the DSC method shows an average value of 2.9 J / g or less. The Hardness of bread crumbs measured with a tensipressor is 2 × 10 6 dyn / cm 2 or less.
The gist of the present invention is a food using the above-mentioned low oil-absorbing bread crumbs, particularly an oil-boiled food.

本発明は、小麦粉、イースト、糖、食塩、水を基本原料とし、食物繊維、タンパク質、澱粉等のパン粉の比容積を小さくする添加物あるいは食品素材を原料として含まないパンから製造されたパン粉であって、BAP法により測定した糊化度が生パン粉(水分量30〜35重量%)の状態で平均45%以上であるか、ドライパン粉(水分量10〜15重量%)の状態で平均55%以上であるか、あるいは、DSC法により測定した糊化熱量ΔHが平均2.9J/g以下であり、パン粉乾燥重量当たりの吸油量が1.2g/g以下であるパン粉を要旨とする。好ましくは、パン粉乾燥重量当たりの吸油量が1.0g/g以下であり、テンシプレッサーにより測定したパン粉のHardnessが2×10dyn/cm以下である。The present invention is a bread crumb manufactured from bread that contains wheat flour, yeast, sugar, salt, water as basic raw materials, and does not contain additives or food materials that reduce the specific volume of bread crumbs such as dietary fiber, protein, starch, etc. The average degree of gelatinization measured by the BAP method is 45% or more in the state of raw bread crumbs (water content 30 to 35% by weight), or 55 in the state of dry bread crumbs (water content 10 to 15% by weight). Or a crumb having an average heat of gelatinization ΔH measured by DSC method of 2.9 J / g or less and an oil absorption per crumb dry weight of 1.2 g / g or less. Preferably, the oil absorption per dry crumb weight is 1.0 g / g or less, and the Hardness of the crumb measured by a tensipresser is 2 × 10 6 dyn / cm 2 or less.

フライ時の吸油量が少なく、かつ優れた食感を有するパン粉を製造することができる。原料となるパン粉はどのような原料でもよく、また、どのような製造法によるものでもよい。また、ドライパン粉でも生パン粉でも原料として用いることができる。
食物繊維、タンパク質などを添加して低吸油にしたパン粉の吸油性をさらに低下させることもできる。
Bread crumbs having a small amount of oil absorption during frying and having an excellent texture can be produced. The raw material bread crumbs may be any raw material, and may be produced by any manufacturing method. Either dry bread crumbs or raw bread crumbs can be used as a raw material.
It is also possible to further reduce the oil absorbency of bread crumbs that have been made low in oil absorption by adding dietary fiber, protein, and the like.

本発明の原料となるパン粉は、パン粉として流通しているような通常のパン粉であればよいが、それらは、例えば以下のような製法で製造される。
直捏生地法や中種生地法などの従来の製パン方法に準じて、パンの原料を混合し、第一次発酵、分割、丸め、第二次発酵、成形、型詰め、最終発酵、焼成により製パンしたパンを冷却、粉砕して生パン粉、あるいはさらに乾燥してドライパン粉が製造される。焼成方法は焙焼式、電極式などがあり、それぞれ特徴があるが、いずれの方法で製造したパンでも本発明の原料パン粉として使用できる。
基本的には小麦粉、イースト、イーストフード、糖、食塩、水が原料である。主原料である小麦粉にはタンパク質含量11%程度もしくはそれ以上の強力粉が望ましいが、強力粉に薄力粉、もしくは中力粉を混合してトータルのタンパク質含量を11%程度にしても構わない。上記原料の他、乳化剤、ショートニング、色素、pH調節剤等の副原料が適宜使用される。通常のパン粉の水分は10〜40重量%(ドライパン粉10〜15重量%、セミドライパン粉15〜30重量%、生パン粉30〜35重量%)である。
低吸油パン粉を製造する目的でポリデキストロース、大豆繊維等の各種食物繊維や大豆タンパク質、卵白等のタンパク質を添加することが知られているが、本発明はそれらのパン粉を原料として使用することもできる。
本発明の低吸油パン粉は、実施例においても示すように、パン粉の原料、焼成方法、添加物を選ばず、パン粉に水分を与え、加熱乾燥することにより、吸油を抑えることができる。
Although the bread crumbs used as the raw material of the present invention may be ordinary bread crumbs that are distributed as bread crumbs, they are produced, for example, by the following production method.
In accordance with conventional bread making methods such as the straight rice dough method and the medium seed dough method, the ingredients of the bread are mixed, primary fermentation, division, rounding, secondary fermentation, molding, filling, final fermentation, baking The baked bread is cooled and ground to produce raw bread crumbs or further dried to produce dry bread crumbs. There are various baking methods, such as a roasting method and an electrode method, and any bread can be used as the raw bread crumbs of the present invention.
Basically, flour, yeast, yeast food, sugar, salt and water are the raw materials. The flour, which is the main raw material, is preferably a strong flour with a protein content of about 11% or more, but the total protein content may be about 11% by mixing the strong flour with thin flour or medium flour. In addition to the above raw materials, auxiliary raw materials such as emulsifiers, shortenings, pigments, and pH adjusters are appropriately used. The water content of normal bread crumbs is 10 to 40% by weight (10 to 15% by weight of dry bread crumbs, 15 to 30% by weight of semi-dry bread crumbs, and 30 to 35% by weight of raw bread crumbs).
It is known to add various dietary fibers such as polydextrose and soy fiber and proteins such as soy protein and egg white for the purpose of producing low oil-absorbing bread crumbs, but the present invention may use these bread crumbs as raw materials. it can.
The low oil-absorbing bread crumbs of the present invention can suppress oil absorption by giving moisture to bread crumbs and heating and drying them, regardless of the raw material, baking method, and additives of bread crumbs as shown in Examples.

本発明の低吸油パン粉は、原料パン粉にパン粉の水分量が40重量%以上になるよう加湿し、パン粉に含まれる澱粉の糊化温度以上の温度で乾燥することにより製造することができる。通常のパン粉の水分量は10〜40%程度である。生パン粉として流通しているものの多くは33%前後の水分量である。パン粉を製造するためには一度は焼成しなければならないので、わざわざ水分を外添しない限り、水分量が40%以上になることは通常ない。本発明においては原料パン粉に45〜65重量%の水分量となるよう加湿するのが好ましい。50%の水分量の加湿とはパン粉を握ると手に水がつくくらいの加湿である。本発明の低吸油効果は、一度焼きあがったパンを粉砕したパン粉に水分をしみこませることによる物理的な変化と、さらにそれを加熱することにより澱粉の糊化などの化学的な変化がおきることによると考えられる。それらの変化のために水分量40重量%以上の加湿と澱粉の糊化温度以上の加熱が必須となる。 The low oil-absorbing bread crumbs of the present invention can be produced by humidifying raw bread crumbs so that the moisture content of the bread crumbs is 40% by weight or more and drying at a temperature equal to or higher than the gelatinization temperature of starch contained in the bread crumbs. The water content of normal bread crumbs is about 10 to 40%. Most of what is distributed as raw bread crumbs has a moisture content of around 33%. In order to produce bread crumbs, they must be baked once, so the amount of water is usually not 40% or more unless the moisture is purposely added. In the present invention, it is preferable to humidify the raw bread crumbs so that the water content is 45 to 65% by weight. Humidification with a moisture content of 50% is humidification that gives water to the hand when breadcrumbs are gripped. The low oil absorption effect of the present invention is that there is a physical change caused by soaking the bread crumbs once baked bread and chemical changes such as starch gelatinization by heating the bread crumbs. It is thought that. For these changes, humidification with a moisture content of 40% by weight or more and heating above the gelatinization temperature of starch are essential.

加湿方法は、水を均一にかけることができる方法であれば水のスプレー、蒸気による加湿などが例示される。パン粉の表面だけでなく中心まで均一に加湿するために、水をスプレー等した後、均一になるまで寝かせておくのが好ましい。温度やパン粉の性質によるが、好ましくは冷蔵温度で5時間以上、より好ましくは10時間以上寝かせることにより均一に加湿することができる。加湿を均一にすることにより吸油性もより均一になる。   Examples of the humidification method include water spray and humidification with steam as long as water can be applied uniformly. In order to uniformly humidify not only the surface of bread crumbs but also the center, it is preferable to lay it until it becomes uniform after spraying water. Although it depends on the temperature and the properties of the bread crumbs, it can be uniformly humidified by aging preferably at refrigeration temperature for 5 hours or more, more preferably for 10 hours or more. By making the humidification uniform, the oil absorption becomes more uniform.

加湿する水は飲料として適した水であればよい。通常の水道水の範囲であればpHなどの差による影響は大きくない。また、水に各種添加物を添加して用いることもできる。添加物としては食品添加物として使用できるものであって、卵白等のタンパク質、コーンスターチ、デキストリン等の澱粉類、ポリデキストロース、セルロース等の水溶性繊維類、プルラン、キサンタンガム、ジェランガム等の増粘多糖類などが例示される。それぞれ添加することにより、加湿による効果を高めたり、別の物性を加えたりする効果がある。例えば、タンパク質の添加は吸油性は低下させるが、パン粉の物性を硬くする。添加量は水に溶解させることができ、噴霧することができる濃度であればよく(通常0.1〜10%程度)、目的に応じて添加する。 The water to be humidified may be water suitable as a beverage. If it is in the range of normal tap water, the effect of differences in pH is not significant. Further, various additives can be added to water for use. Additives that can be used as food additives, such as protein such as egg white, starches such as corn starch and dextrin, water-soluble fibers such as polydextrose and cellulose, polysaccharides such as pullulan, xanthan gum and gellan gum Etc. are exemplified. By adding each, there is an effect of enhancing the effect of humidification or adding another physical property. For example, the addition of protein reduces the oil absorption, but hardens the physical properties of bread crumbs. The addition amount may be a concentration that can be dissolved in water and sprayed (usually about 0.1 to 10%), and is added according to the purpose.

澱粉の糊化温度は、通常70℃以上程度であるとされているが、化工澱粉などでは70℃よりも低温で糊化するものもある。また、再糊化の場合は40℃程度以上である。本発明の製造方法における加熱乾燥は、澱粉の糊化温度以上であることが必要である。実用性を考えると、処理時間が短時間であるほうが好ましいので、乾燥雰囲気温度は100℃以上、好ましくは150〜250℃が適当である。温度が高いほど吸油率が低下する傾向があるのでパン粉が焦げない範囲の温度であれば何度でも良い。乾燥機としては、振動乾燥機、流動乾燥機などどのようなタイプのものでも良いが、均一に加熱できるものが好ましい。   The gelatinization temperature of starch is usually about 70 ° C or higher, but some modified starches and the like are gelatinized at a temperature lower than 70 ° C. Moreover, in the case of re-gelatinization, it is about 40 degreeC or more. The heat drying in the production method of the present invention needs to be equal to or higher than the gelatinization temperature of starch. Considering practicality, it is preferable that the treatment time is short, and therefore, the drying atmosphere temperature is 100 ° C. or higher, preferably 150 to 250 ° C. The higher the temperature, the lower the oil absorption rate. Therefore, the temperature may be any number as long as the bread crumb is not burnt. The dryer may be of any type such as a vibration dryer or a fluid dryer, but a dryer that can be heated uniformly is preferable.

パン粉の水分量を40重量%以上、好ましくは45〜65重量%に加湿した後、加熱乾燥するが、乾燥の程度はパン粉の使用目的によって生パン粉程度、セミドライパン粉程度、ドライパン粉程度の水分量になるように調節する。通常のパン粉は10〜40%であり、その程度の水分量がフライの衣等として使用する場合に使用しやすい。乾燥するほど、吸油性も低くなるので、目的とする低吸油性によって乾燥の程度を決めることもできる。   The moisture content of the bread crumb is moistened to 40% by weight or more, preferably 45 to 65% by weight, and then dried by heating. Adjust so that Ordinary bread crumbs are 10 to 40%, and such a moisture content is easy to use when used as frying clothes. As the oil is dried, the oil absorptivity is lowered. Therefore, the degree of drying can be determined depending on the intended low oil absorptivity.

本願発明の詳細を実施例で説明する。本願発明はこれら実施例によって何ら限定されるものではない。
本実施例において「パン粉の吸油量」、「澱粉の糊化度」は以下の方法により測定・換算した。
The details of the present invention will be described in Examples. The present invention is not limited to these examples.
In this example, “the amount of oil absorption of bread crumbs” and “the degree of gelatinization of starch” were measured and converted by the following methods.

<パン粉の吸油量測定方法>
パン粉を任意の量(約4g)秤量し、目開き0.5mm以下(パン粉がふるいから落ちない程度)のふるいに入れ、大豆白絞油175℃中で2分間油ちょうした。油ちょう後、パン粉を残らず濾紙上に移した。濾紙上で2分間油切りをし、濾紙を取り替えて再び油切りをおこない、パン粉の重さを測定した(n=3)。
<Method for measuring oil absorption of bread crumbs>
An arbitrary amount (about 4 g) of bread crumbs was weighed, put in a sieve having an opening of 0.5 mm or less (a degree where bread crumbs did not fall off from the sieve), and then oiled at 175 ° C. for 2 minutes. After dipping, all the bread crumbs were transferred onto the filter paper. The oil was drained on the filter paper for 2 minutes, the filter paper was replaced, the oil was drained again, and the weight of the bread crumb was measured (n = 3).

<固形物換算重量あたりの吸油量の算出方法>
下記にパン粉固形物換算重量当たりの吸油量等を定義し、下記式に従って算出した。
パン粉固形物換算重量(g)=秤量したパン粉の重さ(g)×(100−パン粉水分含量(%))/100
吸油量(g)=油ちょう後のパン粉の重量(g)−油ちょう前のパン粉の固形物換算重量(g)
固形物換算重量当たりの吸油量(g/g)吸油量(g)パン粉の固形物換算重量(g)
(なお、油ちょう後のパン粉の水分率は0.1%以下であったため0%とした。)
参考に家庭用に市販されているパン粉について本方法により水分量と吸油量を測定したところ、表1に示すような結果であった。
<Calculation method of oil absorption per solid equivalent weight>
The oil absorption amount per bread crumb solid weight is defined below, and calculated according to the following formula.
Bread crumb solid weight (g) = Weighed bread crumb (g) x (100-bread crumb moisture content (%)) / 100
Oil absorption (g) = Weight of bread crumbs after oiling (g)-Weight of solids of bread crumbs before oiling (g)
Oil absorption per solid equivalent weight (g / g) = Oil absorption (g) / Bread crumb solid equivalent weight (g)
(The moisture content of the bread crumbs after oiling was 0.1% or less, so it was set to 0%.)
For reference, the moisture content and oil absorption amount of bread crumbs marketed for household use were measured by this method, and the results shown in Table 1 were obtained.

また、上記吸油量の測定方法と通常食品の分析に用いられる酸分解法による脂質含量の測定値を比較したところ、表2に示すように相関性が見られた。 Moreover, when the measurement method of the said oil absorption amount and the measured value of the lipid content by the acid decomposition method normally used for the analysis of a foodstuff were compared, as shown in Table 2, the correlation was seen.

<原料パン粉の製造>
表3に示した原料配合、表4に示した製造方法により、焙焼式パン粉および電極式パン粉をそれぞれ製造した。
<Manufacture of raw bread crumbs>
By the raw material composition shown in Table 3 and the production method shown in Table 4, roasting bread crumbs and electrode bread crumbs were produced.

実施例1で製造した焙焼式生パン粉を原料パン粉として、以下の要領で加湿・乾燥処理を行い、各種の水分量のパン粉を製造し、それらの吸油量を測定した。
要領1:原料パン粉(水分量34%)を乾燥機の温度110℃で水分量1.6%まで乾燥し、その後、水分量56.1%になるまで加湿した。
要領2:原料パン粉(水分量34%)の水分量が51.2%になるまで加湿し、その後、乾燥機の温度110℃で水分量1.8%まで乾燥した。
要領3:原料パン粉(水分量34%)の水分量が61.8%になるまで加湿し、その後、乾燥機の温度110℃で水分量8.7%まで乾燥した。
Using the roasted raw bread crumb produced in Example 1 as raw material bread crumbs, humidification and drying were performed as follows to produce bread crumbs with various moisture amounts, and their oil absorption was measured.
Procedure 1: The raw bread crumbs (water content 34%) were dried to a moisture content of 1.6% at a dryer temperature of 110 ° C. and then humidified to a moisture content of 56.1%.
Procedure 2: The raw bread crumbs (34% moisture content) were humidified until the moisture content was 51.2%, and then dried to a moisture content of 1.8% at a dryer temperature of 110 ° C.
Procedure 3: The raw material bread crumbs (34% moisture content) were humidified until the moisture content was 61.8%, and then dried to a moisture content of 8.7% at a dryer temperature of 110 ° C.

上記の要領1〜3で加湿、乾燥した各種水分量のパン粉の吸油量を図1に示した。
要領1の前半の乾燥は生パン粉からドライパン粉を製造する場合に合致する。生パン粉よりもドライパン粉の方が吸油が少ないことはよく知られたことであり、本試験の結果とも一致する。乾燥後、加湿すると生パン粉と同程度の水分量までは加湿にしたがって、吸油量も増加するが、40%以上あたりから吸油量の減少が認められる。要領2、3は最大加湿量が異なっているため、吸油量が異なるが、いずれも加湿に伴い吸油量の低下が認められ、その低下は乾燥しても保持され、乾燥するにしたがって、さらに吸油量の低下が認められる。
通常のドライパン粉ではパン粉固形重量あたりの吸油量はせいぜい1.0g/g前後までにしかならないが、加湿後乾燥することによりさらに低吸油のパン粉にすることができる。
The oil absorption amount of bread crumbs of various moisture amounts humidified and dried according to the above points 1 to 3 is shown in FIG.
The drying in the first half of Procedure 1 is consistent with the production of dry bread crumbs from raw bread crumbs. It is well known that dry bread crumbs have less oil absorption than raw bread crumbs, which is consistent with the results of this test. When dried and humidified, the amount of oil absorption increases as the moisture content reaches the same level as raw bread crumbs, but a decrease in the amount of oil absorption is observed from around 40%. The points 2 and 3 differ in oil absorption because the maximum humidification amount is different, but in both cases, a decrease in the oil absorption amount is recognized with humidification, and the decrease is retained even after drying. A decrease in quantity is observed.
In ordinary dry bread crumbs, the amount of oil absorption per bread crumb solid weight is at most about 1.0 g / g, but it is possible to make bread crumbs with lower oil absorption by drying after humidification.

<市販のパン粉を原料パン粉とした場合>
市販のパン粉についても本発明の製造方法を適用し、吸油量の低下が認められることを確認した。図2にはライオンフーヅ(株)の商品名「生E2」(生パン粉、電極式2号、パン粉サイズ12mm)を原料パン粉とした結果、図3には(株)トリイパン粉の商品名「寿」(生パン粉、電極式)を原料とした結果、図4にはライオンフーヅ(株)の商品名「dryB3」(ドライパン粉、焙焼式3号、パン粉サイズ8mm)を原料パン粉とした結果を示した。
実施例2の焙焼式生パン粉と同様に電極式生パン粉でも、また、ドライパン粉でも、さらにパン粉のサイズが異なっていても、加湿後に乾燥することにより、吸油性が低下することが示された。
<When commercial bread crumbs are used as raw bread crumbs>
The production method of the present invention was also applied to commercially available bread crumbs, and it was confirmed that a decrease in oil absorption was observed. Fig. 2 shows the result of using raw bread crumbs with the product name "Raw E2" (raw bread crumbs, electrode type 2 and bread crumb size 12mm) of Lion Food Co., Ltd. As a result of using raw bread crumbs (electrode type) as raw materials, Fig. 4 shows the results of using raw food bread crumbs with the product name "dryB3" (Dry bread crumbs, roasting type No. 3, bread crumb size 8 mm) of Lion Food Co., Ltd. Indicated.
It is shown that oil-absorbing properties are reduced by drying after humidification, even with electrode-type raw bread crumbs, dry bread crumbs, and even bread crumb sizes similar to the roasted raw bread crumbs of Example 2. It was.

<加湿する水分に添加物を入れた場合の影響>
表5に示した各種添加物を水溶液とし、パン粉(ライオンフーヅ(株)の商品名「生E3」)の水分量が約50%となるよう噴霧し、その後、乾燥機温度設定150℃でパン粉の水分量が約30%程度になるまで乾燥した。各条件で製造したパン粉の水分量と吸油量を図5に示した。
図5のとおり、いずれの添加物を添加しても加湿と乾燥による吸油量低下効果が認められた。また、ポリデキストロース、プルラン、卵白、デキストリン、キサンタンガム、ローカストビーンガム、α化ワキシーコーンスターチなどを添加することにより、水添加による効果をさらに増強させることが示された。
<Effect of adding additives to moisture to be humidified>
Various additives shown in Table 5 were made into aqueous solutions and sprayed so that the moisture content of bread crumbs (trade name “Raw E3” of Lion Fu Co., Ltd.) was about 50%, and then the bread crumbs at a dryer temperature setting of 150 ° C. Was dried until the water content was about 30%. The water content and oil absorption of bread crumbs produced under each condition are shown in FIG.
As shown in FIG. 5, even when any additive was added, the effect of reducing the oil absorption by humidification and drying was recognized. Moreover, it was shown that the effect of water addition was further enhanced by adding polydextrose, pullulan, egg white, dextrin, xanthan gum, locust bean gum, pregelatinized waxy corn starch and the like.

<加湿に用いる水のpHの影響>
加湿に用いる水のpHが吸油量低下効果に影響を及ぼすかどうかについて検討した。
加湿に用いる水のpHを酢酸を用いてpH3.5に、また、炭酸カリウムを用いてpH10.0に調製して吸油量を測定した。表6に示すように多少の差が認められたが、いずれのpHでも本発明の加湿+乾燥による吸油量低下効果が認められた。また、表7に示すように通常の水道水のpH範囲であれば、ほぼ同程度の効果が得られることを確認した。
<Effect of pH of water used for humidification>
It was examined whether the pH of water used for humidification affects the oil absorption reduction effect.
The pH of water used for humidification was adjusted to pH 3.5 using acetic acid, and pH 10.0 was adjusted using potassium carbonate, and the oil absorption was measured. As shown in Table 6, a slight difference was observed, but at any pH, the effect of reducing the oil absorption by humidification + drying of the present invention was recognized. In addition, as shown in Table 7, it was confirmed that substantially the same effect was obtained within the normal tap water pH range.

<乾燥温度と吸油量の関係>
乾燥温度と吸油量の関係を確認するため、焙焼式中種法による水分量35%の生パン粉(パン粉サイズ12mm)を原料パン粉として用いて試験を行った。原料パン粉の水分量が50重量%になるまで加湿し、その後各温度で乾燥し、ふるいにかけパン粉サイズを4.0〜8.0mm程度に揃え、吸油量を測定した。
結果を表8に示す。乾燥温度が高いほど、吸油量の低下がより大きくなる傾向ことが認められた。高温のほうが乾燥時間の短縮も図れるので、パン粉が焦げるような高温でなければ高めの温度での乾燥が好ましいといえる。
<Relationship between drying temperature and oil absorption>
In order to confirm the relationship between the drying temperature and the amount of oil absorption, a test was performed using raw bread crumbs (bread crumb size 12 mm) having a water content of 35% by a roasting-type seed method as raw material bread crumbs. The raw bread crumbs were humidified until the water content reached 50% by weight, then dried at various temperatures, sieved, and the bread crumb size was adjusted to about 4.0 to 8.0 mm, and the oil absorption was measured.
The results are shown in Table 8. It was recognized that the higher the drying temperature, the greater the decrease in oil absorption. Since the drying time can be shortened at a higher temperature, it can be said that drying at a higher temperature is preferable unless the bread crumb is scorched.

<官能評価>
本発明品と通常のパン粉および繊維成分などを添加した低吸油パン粉として販売されているものの代表として大豆繊維を添加したパン粉およびオキアミ殻粉末を添加したパン粉について、吸油量と食感についての官能検査を行った。
対照品:通常の焙焼式ドライパン粉、サイズ5mm
本発明品1:通常の焙焼式生パン粉(水分33重量%)を原料パン粉とし、水分50重量%となるように加水し、再乾燥させたドライパン粉、サイズ5mm
比較品1:大豆繊維を15%添加して比容積を小さくしたパンからできたパン粉をドライパン粉にしたもの、サイズ5mm
比較品2:出願人の発明品(特開2003-284519)であるオキアミ殻粉末を5%添加した低吸油ドライパン粉、サイズ5mm
の4種のパン粉について比較した。それぞれのパン粉の配合は表9に示した。
<Sensory evaluation>
Sensory test for oil absorption and texture of bread crumbs with added soy fiber and krill husk powder as representative of those sold as low oil-absorbing bread crumbs to which the present invention product and normal bread crumbs and fiber components are added Went.
Control product: normal roasted dry bread crumb, size 5 mm
Invention product 1: Normal bread-baked raw bread crumbs (water content 33% by weight) as raw material bread crumbs, dried to a moisture content of 50% by weight and dried again, size 5 mm
Comparative product 1: Bread crumbs made from bread with 15% soy fiber added to reduce specific volume, dried bread crumbs, size 5 mm
Comparative product 2: Low oil-absorbing dry bread powder to which 5% of krill shell powder, which is the invention of the applicant (Japanese Patent Laid-Open No. 2003-284519), is added, size 5 mm
4 types of bread crumbs were compared. The composition of each bread crumb is shown in Table 9.

それぞれパン粉を約10g秤量し、目開き0.5mm以下(パン粉がふるいから落ちない程度)のふるいに入れ、大豆白絞油175℃中で2分間油ちょうした。油ちょう後、パン粉を残らず濾紙上に移した。濾紙上で2分間油切りをし、濾紙を取り替えて再び油切りをおこない、皿に移し変えて弊社官能評価パネル5名で外観、硬さ等の項目について官能評価をおこなった。
評価は対照品の通常のドライパン粉に対しての比較評価でおこなった。結果を表10に示す。本発明品はその他の製法による低吸油パン粉よりもより通常のパン粉に近い食感であった。
テンシプレッサー((有)タケトモ電機社製)は食品のテクスチャーを客観的に測定する装置で、サンプルの硬さや凝集性、付着性などを客観的に数値として表すことが可能である。油ちょう後の本発明品1のパン粉を入れたアルミ製容器(直径39mm、高さ12mm)をステージに装着し、プランジャーエリア960mmの円柱形プランジャーで上から1.5mm圧縮した(1バイト測定)。そのときのHardness(最大圧縮応力)は1.89×10dyn/cmであった。
About 10 g of bread crumbs were weighed and placed in a sieve having an opening of 0.5 mm or less (a degree where bread crumbs do not fall off from the sieve), and oiled in soybean white squeezed oil at 175 ° C. for 2 minutes. After dipping, all the bread crumbs were transferred onto the filter paper. Oil was drained on the filter paper for 2 minutes, the filter paper was replaced, oil was drained again, transferred to a dish, and sensory evaluation was performed on items such as appearance and hardness by our sensory evaluation panel.
Evaluation was performed by comparative evaluation with respect to normal dry bread crumbs as a control product. The results are shown in Table 10. The product of the present invention had a texture closer to that of ordinary bread crumbs than low oil-absorbing bread crumbs produced by other methods.
Tenshi Presser (manufactured by Taketomo Electric Co., Ltd.) is an apparatus that objectively measures the texture of food, and can objectively express the hardness, cohesiveness, adhesion, etc. of the sample as numerical values. An aluminum container (39 mm in diameter and 12 mm in height) in which the bread crumbs of the product 1 of the present invention after oil dipping was placed on the stage was compressed 1.5 mm from above with a cylindrical plunger with a plunger area of 960 mm 2 (1 Byte measurement). The Hardness (maximum compressive stress) at that time was 1.89 × 10 6 dyn / cm 2 .

官能検査により本発明のパン粉は硬さ、口どけ等の食感において、従来の添加物による低吸油パン粉と比較して優れていることが示された。これを裏付けるために本発明のパン粉と添加物による低吸油パン粉の密度測定を行った。使用したサンプルは吸油量が同程度になるように調製した以下の2サンプルである。
本発明品2:通常の焙焼式生パン粉(ライオンフーヅ(株)生パン粉「生E3」、水分33重量%)を原料パン粉とし、水分60重量%となるように加水し、水分量13.5%まで加熱乾燥させたドライパン粉、サイズ5mm
比較品3:出願人の発明品(特開2003-284519)であるオキアミ殻粉末を添加した低吸油ドライパン粉、サイズ5mmの2種のパン粉について比較した。それぞれのパン粉の配合は表11に示した。
結果を表12に示した。同程度の吸油量に調製した本発明品のパン粉は比較品のパン粉に比較し平均密度が低く、官能検査による硬さの食感の違いが裏づけられる結果であった。
The sensory test showed that the bread crumbs of the present invention were superior to the low oil-absorbing bread crumbs of conventional additives in the texture such as hardness and mouthfeel. In order to support this, the density of low oil-absorbing bread crumbs by the bread crumbs and additives of the present invention was measured. The samples used were the following two samples prepared so that the amount of oil absorption was comparable.
Invention product 2: Normal roasted raw bread crumbs (Lion Foo Co., Ltd. raw bread crumbs “raw E3”, moisture 33 wt%) are used as raw material bread crumbs, watered to a moisture content of 60 wt%, and a moisture content of 13. Dry bread crumbs dried to 5%, size 5mm
Comparative product 3: A comparison was made between low-oil-absorbing dry bread crumbs added with krill husk powder, which is the applicant's invention (Japanese Patent Laid-Open No. 2003-284519), and two types of bread crumbs of size 5 mm. The composition of each bread crumb is shown in Table 11.
The results are shown in Table 12. The bread crumbs of the product of the present invention prepared to the same amount of oil absorption had a lower average density than the bread crumbs of the comparative products, and the results confirmed the difference in the texture of hardness by sensory test.

本発明の処理をしたパン粉の構造、物性等の変化を確認するため、X線CTスキャナーによるパン粉の断面観察と3次元構築、電子顕微鏡(SEM)による表面構造撮影、および糊化度の測定を行った。
<非破壊測定 X線CTスキャナーによるパン粉の断面観察と3次元構造解析>
原料パン粉(ライオンフーヅ(株)製、生パン粉、商品名「生B2」)とそれを原料パン粉とし水分60重量%となるように加水し、水分量13.5%まで加熱乾燥させた本発明品の低吸油パン粉の油ちょう前のものと後のものについて、バイオイメージリサーチ製「ACTIS+3」と(株)東芝製イメージインテンシファイヤーを用い構造解析をおこなった(条件 管電圧:50kV、菅電流:0.13mA、拡大率15倍、スライス数:120枚、ビュー数:900、フレーム積算枚数:4枚/ビュー)。測定試料は特に調整の必要はなく、測定ステージに固定し、観察した。
図6、7の断面図の写真が示すように、原料パン粉は大きい空隙が多くありパンの梁部(空隙を構成している壁にあたる部分)が細い。一方、本発明のパン粉(図10、11)は空隙が小さく、少なくなり梁部が太くなっている。図8、9、12、13の油ちょう後の写真からこれらの空隙に油が保持されていることがわかる。これらの解析から求めた気孔率(パン粉の体積に占める空隙部分の体積)は、それぞれ92%(油ちょう前の原料パン粉)、90%(油ちょう後の原料パン粉)、64%(油ちょう前の本発明パン粉)、54%(油ちょう後の本発明パン粉)であった。図14(原料パン粉)、図15(本発明)の3次元構造を構築した写真は、図6〜13とは異なるロットのパン粉についてSKYSCAN社製1072型DESKTOP X-RAY HIGH-RESOLUTION MICROTOMOGRAPHを用いて三次元構造の構築を行った写真である。本発明のパン粉の梁部が厚くなり、油の保持される空隙が少なくなっている様子が観察される。この解析から単位体積当たりのパン粉の気孔の割合を計算すると、原料パン粉では81.3%、本発明のパン粉では58.9%であった。
Cross-sectional observation and three-dimensional construction of bread crumbs with an X-ray CT scanner, surface structure photographing with an electron microscope (SEM), and measurement of gelatinization degree to confirm changes in the structure and physical properties of the bread crumbs treated according to the present invention went.
<Non-destructive measurement Cross-sectional observation and three-dimensional structure analysis of bread crumbs by X-ray CT scanner>
Raw material bread crumbs (produced by Lion Food Co., Ltd., raw bread crumbs, trade name “Raw B2”) and the raw bread crumbs, water added to a moisture content of 60% by weight, and heat dried to a moisture content of 13.5% The structural analysis was performed using “ACTIS + 3” manufactured by Bio Image Research and Image Intensifier manufactured by Toshiba Corp. (condition tube voltage: 50 kV, の も の current). : 0.13mA, 15x magnification, number of slices: 120, number of views: 900, number of frames integrated: 4 / view). The measurement sample was not particularly required to be adjusted, and was fixed on the measurement stage and observed.
As shown in the photographs of the cross-sectional views of FIGS. 6 and 7, the raw bread crumbs have many large gaps, and the bread beams (parts corresponding to the walls constituting the gaps) are thin. On the other hand, the bread crumbs (FIGS. 10 and 11) of the present invention have a small gap, a small gap, and a thick beam. 8, 9, 12, and 13, it can be seen that oil is retained in these voids. The porosity (volume of the void portion in the bread crumb volume) obtained from these analyzes is 92% (raw bread crumbs before oil boil), 90% (raw bread crumbs after oil boil), and 64% (before oil boil) Of the present invention bread crumbs), 54% (the present invention bread crumbs after oil-cooking). 14 (raw breadcrumbs) and 15 (invention) of the three-dimensional structure of the photograph, using a 1072 type DESKTOP X-RAY HIGH-RESOLUTION MICROTOMOGRAPH made by SKYSCAN for bread crumbs different from those of FIGS. This is a photo of the construction of a three-dimensional structure. It is observed that the beam portion of the bread crumbs of the present invention is thickened and the gaps in which oil is retained are reduced. When the ratio of the pores of the bread crumb per unit volume was calculated from this analysis, it was 81.3% for the raw bread crumbs and 58.9% for the bread crumbs of the present invention.

<電子顕微鏡(SEM(Scanning Electron Microscope))による表面構造撮影>
X線CTスキャナーによる構造解析に用いたサンプルと同様のサンプルについて、HITACHI社製 S-3200Nを用い表面構造撮影を行った。測定試料は特に調整の必要はなく、測定ステージに固定した後、観察を行った。
図16、17の写真に示されるように、原料パン粉(コントロール)では表面に澱粉粒が認められるが、本発明のパン粉(調湿パン粉)では澱粉粒が糊化して糊状になり粒が見えにくくなっていた。
<Surface structure photography with an electron microscope (SEM)>
About the sample similar to the sample used for the structural analysis by X-ray CT scanner, surface structure imaging | photography was performed using HITACHI S-3200N. The measurement sample was not particularly required to be adjusted, and was observed after being fixed to the measurement stage.
As shown in the photographs of FIGS. 16 and 17, starch grains are observed on the surface of the raw bread crumbs (control), but in the bread crumbs (humidity-conditioned bread crumbs) of the present invention, the starch grains are gelatinized into a paste and visible. It was difficult.

<糊化度の測定>
糊化度の測定方法:BAP法
澱粉の糊化度測定法の一つとしては、澱粉科学(J. Jap. Soc. Starch Sci.)28 (4), p235-240に記載された「β−アミラーゼ−プルラナーゼ(BAP)系を用いた澱粉の糊化度、老化度の新測定法」にしたがって測定した。
本方法は、生デンプンを全く分解しないβ-アミラーゼとアミロペクチンの立体構造変化に非常に影響を受けるプルラナーゼの混合酵素を用い、分解度の比から糊化デンプンと老化デンプンを識別する方法である。脱脂脱水後(DSCと同様)の試料60mgと蒸留水6mlをガラスホモジナイザーに採取しよく分散させ、試料溶液とした。また、この試料溶液に10N水酸化ナトリウムを加えて完全に糊化させた完全糊化試料溶液も調製した。これら2種類の試料溶液にβ-アミラーゼ・プルラナーゼ混合溶液(β-アミラーゼ0.8IU;ナガセ生化学工業、プルラナーゼ3.4IU;林原生物化学研究所)を加えて分解させた。各試料の全糖量はフェノール・硫酸法により、還元糖量はSomogyi-Nelson法により測定した。糊化度は、完全糊化試料の分解度を100とした際に試料溶液がどの程度分解したかで表した。
<Measurement of gelatinization degree>
Method of measuring degree of gelatinization: BAP method One method of measuring the degree of gelatinization of starch is as described in “β−” described in Starch Science (J. Jap. Soc. Starch Sci.) 28 (4), p235-240. It was measured according to the “new measuring method of gelatinization degree and aging degree of starch using amylase-pullulanase (BAP) system”.
This method is a method for discriminating gelatinized starch and aging starch from the ratio of the degree of degradation, using a mixed enzyme of β-amylase and pullulanase which is highly influenced by the three-dimensional structure change of amylopectin, which does not degrade raw starch at all. A sample solution of 60 mg after degreasing and dehydration (similar to DSC) and 6 ml of distilled water were collected in a glass homogenizer and dispersed well to obtain a sample solution. In addition, a completely gelatinized sample solution was prepared by adding 10N sodium hydroxide to this sample solution and completely gelatinizing it. A β-amylase / pullulanase mixed solution (β-amylase 0.8IU; Nagase Seikagaku Corporation, pullulanase 3.4IU; Hayashibara Biochemical Laboratories) was added to these two kinds of sample solutions for decomposition. The total sugar amount of each sample was measured by the phenol / sulfuric acid method, and the reducing sugar amount was measured by the Somogyi-Nelson method. The degree of gelatinization was expressed by how much the sample solution was decomposed when the degree of decomposition of the completely gelatinized sample was 100.

各種条件で製造されたパン粉の糊化度結果を表13に示す(n=3〜5)。焙焼式パン粉、電極式パン粉のいずれも加水後、加熱乾燥することにより糊化度が高くなっており、糊化がすすんでいることがわかる。ポリデキストロースやオキアミ殻粉末などの添加物により低吸油にされているパン粉では糊化度は低い。また、最初から糊化しているアルファ化澱粉を添加したパンから製造したパン粉の糊化度は高いが、表14に示すようにこれらのパン粉は低吸油性を有さない。しかし、このようなパン粉を原料とした場合も本発明の方法、加湿後加熱乾燥処理を施すことにより、低吸油性を有するパン粉になる。 Table 13 shows the gelatinization results of bread crumbs produced under various conditions (n = 3 to 5). Both the roasted bread crumbs and the electrode bread crumbs are hydrated and then heated and dried to increase the degree of gelatinization, indicating that gelatinization is progressing. Bread crumbs with low oil absorption by additives such as polydextrose and krill shell powder have a low gelatinization degree. Moreover, although the gelatinization degree of the bread crumb manufactured from the bread | pan which added the gelatinized starch gelatinized from the beginning is high, as shown in Table 14, these bread crumbs do not have low oil absorption. However, even when such bread crumbs are used as raw materials, bread crumbs having low oil absorption can be obtained by performing the method of the present invention and heat drying after humidification.

糊化度の測定方法:DSC法
また、もう一つの糊化度測定法として、Inouchiらの方法、Differential Scanning Calorimetry;示差走査熱量測定法(DSC法)を用いて測定した(J. Appl. Glycosci., 51, 303-313 (2003)、Starch/Starke, 43, 468-472 (1991) 参照)。
温度上昇に伴う熱量変化から転移、融解、結晶化、凝固などの変化エネルギーを測定する方法であり、デンプンの糊化は吸熱を伴うので、DSC測定からデンプンの糊化特性を知ることができる。
アセトンを用いて脱脂後、水分値7%程度まで乾燥、微細に粉末化(80メッシュスルー)したものを各試料とした。密封耐圧型試料容器に脱脂脱水後の試料を乾物重量当たり50mg採取し、2.5倍量の水を加えて十分水和させた。その後Micro-DSCIII(SETRAM社製)を用いて、5℃〜80℃の範囲(一部5℃〜100℃)で熱量測定を行った。
ΔHの算出は、Inouchiらの方法によって試料澱粉の糊化温度(糊化ピーク温度;Tp、糊化温度範囲;Tc−To)と糊化熱量(ΔH)の測定を行った。昇温速度は5℃/分で測定し、吸熱曲線の編曲点より、糊化開始温度(To)、および糊化終了温度(Tc)を吸熱ピーク温度(Tp)を読み取り、吸熱曲線とベースラインによって囲まれる面積より糊化熱量(ΔH)を算出した。ベースラインは引く人によって20%程度の値の違いが生じるが、同様の手順で引けば、傾向が変わることはない。
結果を表15に示す。DSC法により測定した糊化度においても本発明の処理をすることにより、パン粉の糊化度が高くなり、糊化が進んでいることがわかる。
Measuring method of gelatinization degree: DSC method As another method of measuring gelatinization degree, it was measured using the method of Inouchi et al., Differential Scanning Calorimetry (DSC method) (J. Appl. Glycosci). ., 51 , 303-313 (2003), Starch / Starke, 43, 468-472 (1991)).
This is a method for measuring the energy of change such as transition, melting, crystallization, solidification, etc. from the change in calorie due to temperature rise. Since gelatinization of starch involves endotherm, the gelatinization characteristics of starch can be known from DSC measurement.
Each sample was degreased with acetone, dried to a moisture value of about 7%, and finely powdered (80 mesh through). In a sealed pressure-resistant sample container, 50 mg of the sample after degreasing and dehydration was collected per dry matter weight, and 2.5 times as much water was added to hydrate sufficiently. Thereafter, using Micro-DSCIII (manufactured by SETRAM), calorimetry was performed in the range of 5 ° C to 80 ° C (partially 5 ° C to 100 ° C).
For the calculation of ΔH, the gelatinization temperature (gelatinization peak temperature; Tp, gelatinization temperature range; Tc-To) and the heat of gelatinization (ΔH) of the sample starch were measured by the method of Inouchi et al. The rate of temperature increase was measured at 5 ° C / min. From the end of the endothermic curve, the gelatinization start temperature (To) and the gelatinization end temperature (Tc) were read as the endothermic peak temperature (Tp). The amount of heat for gelatinization (ΔH) was calculated from the area surrounded by. The baseline differs by about 20% depending on the person who draws it, but if the same procedure is used, the trend will not change.
The results are shown in Table 15. It can be seen that, even in the degree of gelatinization measured by the DSC method, the gelatinization degree of bread crumbs is increased by the treatment of the present invention, and gelatinization is progressing.

本発明低吸油ドライパン粉および通常パン粉を使用し油ちょう食品を製造した。通常のパン粉はライオンフーヅ社製商品名『生B2』を使用した。本発明低吸油ドライパン粉は通常パン粉に水分量が50%となるように加水後、150℃で乾燥し、水分13%へ再乾燥させたパン粉を使用した。パン粉のサイズはどちらも8mm程度に揃えて使用した。表16の配合にしたがって通常バッターおよび低吸油バッターを作製した。中種にはイモパテ(15g程度)と白身魚ブロック(12g程度)を使用した。打ち粉にはどちらも薄力粉(日東製粉社製 商品名アルプス)を使用した。どちらも衣率が45%程度となるよう、打ち粉付け→バッター付け→パン粉付け(一度つけ)をおこなった。衣付けしたフライは一端−30℃にて保管し、凍結確認後、175℃〜180℃の温度で約3分間油ちょうした。油ちょう後、各フライ10個をフードプロセッサーにかけてまんべんなくミンチ状にし、酸分解法にて製品の脂質含量を測定した。
表17に示すように本発明の低吸油パン粉を使用することにより油ちょう食品の脂質含量を低下させることができた。特に低吸油バッターとの組み合わせにより、脂質含量を効果的に低下させることができる。
Oil-dried foods were produced using the low oil-absorbing dry bread crumbs and normal bread crumbs of the present invention. The regular bread crumbs used the product name “Raw B2” manufactured by Lion Fu Co., Ltd. The low oil-absorbing dry bread crumbs of the present invention were bread crumbs that were hydrated so that the water content was usually 50%, dried at 150 ° C., and re-dried to 13% moisture. The bread crumb sizes were both adjusted to about 8 mm. A normal batter and a low oil absorption batter were prepared according to the formulation in Table 16. Imopatate (about 15 g) and white fish block (about 12 g) were used as medium species. In both cases, soft flour (Nitto Flour Mills brand name Alps) was used. In both cases, powdering → battering → breading (once) was performed so that the clothing ratio was about 45%. The dressed fly was stored at −30 ° C. for one end, and after freezing was confirmed, oiled at a temperature of 175 ° C. to 180 ° C. for about 3 minutes. After oiling, 10 fries of each fry were spread over a food processor to make it evenly minced, and the lipid content of the product was measured by an acid decomposition method.
As shown in Table 17, the use of the low oil-absorbing bread crumbs of the present invention allowed the lipid content of the oiled food to be reduced. In particular, the lipid content can be effectively reduced by combination with a low oil absorption batter.

本発明の方法により特別な添加物等を用いることなくパン粉の吸油性を低下させることができるので、吸油性の低いパン粉であって、硬すぎない食感のパン粉を提供することができる。添加物による低吸油パン粉の吸油性をさらに低下させることもできる。加湿する水に添加物を用いることでさらに低吸油性を高めることができる。このパン粉を使用することにより、低カロリー、低脂質の食品を提供することができる。   According to the method of the present invention, the oil absorbency of bread crumbs can be reduced without using any special additive or the like, and therefore bread crumbs having low oil absorbency and not too hard can be provided. The oil absorbency of the low oil-absorbing bread crumbs due to the additive can be further reduced. By using an additive in the water to be humidified, the low oil absorption can be further increased. By using this bread crumb, a low calorie, low lipid food can be provided.

実施例2のパン粉の水分量と吸油量の関係を示した図である。It is the figure which showed the relationship between the moisture content of the bread crumbs of Example 2, and the amount of oil absorption. 電極式生パン粉を原料パン粉としたときのパン粉の水分量と吸油量の関係を示した図である。It is the figure which showed the relationship between the water content of bread crumbs, and an oil absorption amount when electrode-type raw bread crumbs were used as raw material bread crumbs. 電極式生パン粉を原料パン粉としたときのパン粉の水分量と吸油量の関係を示した図である。It is the figure which showed the relationship between the water content of bread crumbs, and an oil absorption amount when electrode-type raw bread crumbs were used as raw material bread crumbs. ドライパン粉を原料パン粉としたときのパン粉の水分量と吸油量の関係を示した図である。It is the figure which showed the relationship between the moisture content and the oil absorption amount of bread crumbs when dry bread crumbs were used as raw material bread crumbs. 加湿に用いる水に各種添加物を添加した場合のパン粉の水分量と吸油量の関係を示した図である。It is the figure which showed the relationship between the moisture content of bread crumbs, and the oil absorption amount at the time of adding various additives to the water used for humidification. X線CTスキャナーにより油ちょう前の原料パン粉の断面構造を撮影した写真である。It is the photograph which image | photographed the cross-sectional structure of the raw material bread crumbs before oiling with the X-ray CT scanner. X線CTスキャナーにより油ちょう前の原料パン粉の三次元構造を構築した写真である。It is the photograph which constructed | assembled the three-dimensional structure of the raw material bread crumbs before an oil pan by X-ray CT scanner. X線CTスキャナーにより油ちょう後の原料パン粉の断面構造を撮影した写真である。It is the photograph which image | photographed the cross-sectional structure of the raw material bread crumbs after oil dripping with the X-ray CT scanner. X線CTスキャナーにより油ちょう後の原料パン粉の三次元構造を構築した写真であるThis is a photograph of the three-dimensional structure of the raw bread crumbs after oil dripping using an X-ray CT scanner. X線CTスキャナーにより油ちょう前の本発明のパン粉の断面構造を撮影した写真である。It is the photograph which image | photographed the cross-sectional structure of the bread crumbs of this invention in front of oil with an X-ray CT scanner. X線CTスキャナーにより油ちょう前の本発明のパン粉の三次元構造を構築した写真である。It is the photograph which constructed | assembled the three-dimensional structure of the bread crumbs of this invention before an oil pan by X-ray CT scanner. X線CTスキャナーにより油ちょう後の本発明のパン粉の断面構造を撮影した写真である。It is the photograph which image | photographed the cross-sectional structure of the bread crumbs of this invention after oil dripping with an X-ray CT scanner. X線CTスキャナーにより油ちょう後の本発明のパン粉の三次元構造を構築した写真である。It is the photograph which constructed | assembled the three-dimensional structure of the bread crumbs of this invention after oil dripping with an X-ray CT scanner. X線CTスキャナーにより原料パン粉の三次元構造を構築した写真である。It is the photograph which constructed | assembled the three-dimensional structure of raw material bread crumbs with the X-ray CT scanner. X線CTスキャナーにより本発明のパン粉の三次元構造を構築した写真である。It is the photograph which constructed | assembled the three-dimensional structure of the bread crumbs of this invention with the X-ray CT scanner. 電子顕微鏡により原料パン粉の表面構造を撮影した写真である(×200)。It is the photograph which image | photographed the surface structure of raw material bread crumbs with the electron microscope (* 200). 電子顕微鏡により本発明のパン粉の表面構造を撮影した写真である(×200)。It is the photograph which image | photographed the surface structure of the bread crumbs of this invention with the electron microscope (x200).

Claims (17)

原料のパン粉に水分量が45〜65重量%になるように加湿し、加湿が均一になるまで寝かせた後、パン粉に含まれる澱粉の糊化温度以上の温度で乾燥することを特徴とするパン粉の油ちょう時の吸油性を低下する方法。Bread crumbs characterized in that the raw bread crumbs are moisturized so that the moisture content is 45 to 65% by weight, laid until the humidification is uniform, and then dried at a temperature equal to or higher than the gelatinization temperature of starch contained in the bread crumbs To reduce the oil absorbency when oiling. 原料のパン粉が小麦粉、イースト、糖、食塩、水を基本原料とし、焙焼式あるいは電極式焼成方法により焼成した通常のパン粉である請求項1のパン粉の油ちょう時の吸油性を低下する方法。  The method for reducing the oil absorption of the bread crumbs of the crumbs according to claim 1, wherein the raw bread crumbs are normal bread crumbs baked by a roasting type or electrode type baking method using wheat flour, yeast, sugar, salt and water as basic materials. . 乾燥雰囲気温度が40℃以上である請求項1又は2のパン粉の油ちょう時の吸油性を低下する方法。The method for reducing the oil absorbency at the time of dipping the bread crumbs according to claim 1 or 2, wherein the drying atmosphere temperature is 40 ° C or higher. 乾燥雰囲気温度が100℃以上である請求項のパン粉の油ちょう時の吸油性を低下する方法。The method for reducing the oil absorbency at the time of dipping the bread crumbs according to claim 3 , wherein the drying atmosphere temperature is 100 ° C or higher. 乾燥雰囲気温度が150〜250℃である請求項のパン粉の油ちょう時の吸油性を低下する方法。The method for reducing the oil absorbency at the time of dipping the bread crumbs according to claim 3 , wherein the drying atmosphere temperature is 150 to 250 ° C. パン粉の水分量が10〜40重量%になるまで乾燥する請求項1ないしいずれかのパン粉の油ちょう時の吸油性を低下する方法。How the water content of the crumbs is reduced to oil absorbing during frying of claims 1 to 5 or crumb is dried to 10 to 40 wt%. 吸油性の低下が、原料パン粉(生)の油ちょう時の吸油量を30%以上低下させるものである請求項1ないしいずれかのパン粉の油ちょう時の吸油性を低下する方法。How decrease in oil resistance, decreases the oil absorbing during raw crumbs (raw) claims 1 oil absorption during frying is intended to reduce at least 30% of the 6-one of crumb frying. 請求項1ないしいずれかのパン粉の油ちょう時の吸油性を低下する方法を用いて製造した低吸油パン粉。Low oil-absorbing bread crumbs produced using the method for reducing the oil absorption of the bread crumbs according to any one of claims 1 to 7 . パン粉乾燥重量当たりの吸油量が1.2g/g以下である請求項の低吸油パン粉。The oil-absorbing bread crumbs according to claim 8 , wherein the oil absorption per dry bread crumb is 1.2 g / g or less. パン粉乾燥重量当たりの吸油量が1.0g/g以下である請求項の低吸油パン粉。The oil-absorbing bread crumbs according to claim 9 , wherein the oil absorption per dry weight of bread crumbs is 1.0 g / g or less. BAP法により測定した糊化度が生パン粉(水分量30〜35重量%)の状態で平均45%以上であるか、ドライパン粉(水分量10〜15重量%)の状態で平均55%以上であるか、あるいは、DSC法により測定した糊化熱量ΔHが平均2.9J/g以下である請求項8、9または10の低吸油パン粉。The degree of gelatinization measured by the BAP method is 45% or more on average in the state of raw bread crumbs (water content 30 to 35% by weight), or 55% or more on average in the state of dry bread crumbs (water content 10 to 15% by weight) The low oil-absorbing bread crumbs according to claim 8, 9 or 10 , wherein the gelatinization heat amount ΔH measured by the DSC method is 2.9 J / g or less on average. テンシプレッサーにより測定したパン粉のHardnessが2×106dyn/cm2以下である請求項8ないし11いずれかの低吸油パン粉。The low oil-absorbing bread crumb according to any one of claims 8 to 11 , wherein a Hardness of bread crumb measured by a tensipresser is 2 x 10 6 dyn / cm 2 or less. 請求項8ないし12いずれかの低吸油パン粉を使用した食品。A food using the low oil-absorbing bread crumb according to claim 8 . 請求項8ないし12いずれかの低吸油パン粉を使用した油ちょう食品。Oily food using the low oil-absorbing bread crumb according to any one of claims 8 to 12 . 小麦粉、イースト、糖、食塩、水を基本原料とし、食物繊維、タンパク質、澱粉等のパン粉の比容積を小さくする添加物あるいは食品素材を原料として含まないパンから製造されたパン粉であって、BAP法により測定した糊化度が生パン粉(水分量30〜35重量%)の状態で平均45%以上であるか、ドライパン粉(水分量10〜15重量%)の状態で平均55%以上であるか、あるいは、DSC法により測定した糊化熱量ΔHが平均2.9J/g以下であり、パン粉乾燥重量当たりの吸油量が1.2g/g以下であるパン粉。  Bread crumbs made from bread that contains wheat flour, yeast, sugar, salt, water as basic ingredients and does not contain additives or food ingredients that reduce the specific volume of bread crumbs such as dietary fiber, protein, starch, etc. The degree of gelatinization measured by the method is 45% or more on average in the state of raw bread crumbs (water content 30 to 35% by weight) or 55% or more in the state of dry bread crumbs (water content 10 to 15% by weight) Alternatively, bread crumbs having an average heat of gelatinization ΔH measured by DSC method of 2.9 J / g or less and an oil absorption per bread crumb dry weight of 1.2 g / g or less. パン粉乾燥重量当たりの吸油量が1.0g/g以下である請求項15のパン粉。The bread crumbs according to claim 15 , wherein the oil absorption per dry weight of the bread crumbs is 1.0 g / g or less. テンシプレッサーにより測定したパン粉のHardnessが2×106dyn/cm2以下である請求項15または16のパン粉。The bread crumbs according to claim 15 or 16 , wherein the Hardness of bread crumbs measured by a tensipresser is 2 x 10 6 dyn / cm 2 or less.
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