JP5024955B2 - Manufacturing method of penetrating stamp with reinforcing cloth and penetrating stamp with reinforcing cloth - Google Patents
Manufacturing method of penetrating stamp with reinforcing cloth and penetrating stamp with reinforcing cloth Download PDFInfo
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- JP5024955B2 JP5024955B2 JP2008014525A JP2008014525A JP5024955B2 JP 5024955 B2 JP5024955 B2 JP 5024955B2 JP 2008014525 A JP2008014525 A JP 2008014525A JP 2008014525 A JP2008014525 A JP 2008014525A JP 5024955 B2 JP5024955 B2 JP 5024955B2
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本発明は、多孔性シートの裏側にインキ流通性のある補強布が添着一体化された補強布付き浸透印用印材の製造法およびこの製造法により製造されたの製造法および補強布付き浸透印用印材に関するものである。 The present invention relates to a method for producing a printing material for penetrating stamps with a reinforcing cloth in which a reinforcing cloth having ink flowability is attached and integrated on the back side of a porous sheet, and a method for producing the stamping material and a penetrating stamp with a reinforcing cloth. It relates to a stamp material.
多孔性シート材料の裏側にインキ流通性のある補強布が添着一体化されている補強布付き浸透印用印材は、特許文献1として挙げた特開昭61ー295041号公報などにも記載されているように、金型上で多孔性シート材料と補強布とを重ねて両者を加熱・加圧して一体化して製造されているが、従来のこの種の補強布付き浸透印用印材は、金型上で多孔性シート材料と補強布とを重ねて両者を加熱・加圧したときに溶融した多孔性シート材料の一部が補強布の布目を通じて金型面にまで達してその一部がこの金型面に沿って浸出し、補強布の裏面に薄い皮膜を形成することとなり、この皮膜が織布面を覆ってインク吸収効率を悪くするという問題があった。
このようにして補強布の裏面に薄い皮膜が残されている補強布付き浸透印用印材においては、補強布の裏面に形成された薄い皮膜がインキ供給力を低下させることとなり、このような補強布付き浸透印用印材を用いて浸透印を作成する時点で補強布側から印字面側にインキを自然浸透させようとするための時間が長く、これが短時間で製品を提供できない要因とされているという問題があった。 In the printing material for penetrating stamps with a reinforcing cloth in which a thin film is left on the back surface of the reinforcing cloth in this way, the thin film formed on the back surface of the reinforcing cloth reduces the ink supply capability, and such reinforcement At the time of making a penetrating mark using a penetrating stamp material with cloth, it takes a long time to allow the ink to naturally penetrate from the reinforcing cloth side to the printing surface side. There was a problem of being.
本発明が解決しようとするところは、前記のような問題を解決して、多孔性シートの裏側にインキ流通性のある補強布が添着一体化された補強布付き浸透印用印材において、単に強靱で滑り止め効果にも優れているだけではなく、浸透印用印材の全裏面が優れたインキ吸収能を有するものとした補強布付き浸透印用印材を安価に提供できるようにすることにある。 The problem to be solved by the present invention is to solve the above-mentioned problems, and in a printing material for penetrating printing with a reinforcing cloth in which a reinforcing cloth having ink flowability is attached and integrated on the back side of the porous sheet, In addition to being excellent in the anti-slip effect, it is also possible to provide a low cost penetrating stamp material with a reinforcing cloth in which the entire back surface of the penetrating stamp material has an excellent ink absorption capability.
前記のような課題を解決した本発明は、発泡用材料を混在させてある多孔性シート材料の裏側にインキ流通性のある補強布を重ねて両者を加熱・加圧して一体化する補強布付き浸透印用印材の製造法において、前記した補強布の裏側に剥離用シートを重ねた状態で前記した加熱・加圧処理を行なって、加熱により溶融される多孔性シート材料の一部を補強布の布目を通じ剥離用シートに含浸させて多孔性シート材料と補強布と剥離用シートの三者が一体化された成形印材シートとし、その後この成形印材シートの裏側から剥離用シートを剥除することを特徴とする補強布付き浸透印用印材の製造法と、このような方法により得られた補強布付き浸透印用印材、すなわち、多孔性シートの裏側にインキ流通性のある補強布が添着一体化された補強布付き浸透印用印材において、浸透印用印材の全裏面が前記した補強布を構成する織糸よりなる織布面と、前記した多孔性シートの一部が補強布の布目を通じて裏側に露呈されてその端部が剥離用シートの剥離により引き千切りられた無数の斑点状部とよりなるインキ吸収粗面に形成されていることを特徴とする補強布付き浸透印用印材とよりなるものである。 The present invention that has solved the above-mentioned problems is provided with a reinforcing cloth that integrates a reinforcing cloth having ink flowability on the back side of the porous sheet material in which the foaming material is mixed and heats and pressurizes both. In the method for producing a penetrating stamp material, the heating and pressurizing treatment is performed in a state where the peeling sheet is stacked on the back side of the reinforcing cloth, and a part of the porous sheet material melted by heating is used as the reinforcing cloth. The sheet for release is impregnated into a sheet of release material to form a molded stamp material sheet in which the porous sheet material, the reinforcing cloth and the sheet for release are integrated, and then the sheet for release is peeled off from the back side of the sheet of molded stamp material A method for producing a printing material for penetrating marks with a reinforcing cloth, and a penetrating stamp material with a reinforcing cloth obtained by such a method, that is, a reinforcing cloth having ink flowability is attached integrally to the back side of a porous sheet. Complemented In the osmotic marking material with cloth, the entire back surface of the osmotic marking material is exposed on the back side through a woven fabric surface made of the woven yarn constituting the reinforcing cloth and a part of the porous sheet described above through the cloth of the reinforcing cloth. The end portion of the pendant is formed of an ink-absorbing rough surface formed of an innumerable spot-like portion that has been stripped off by peeling of the peeling sheet, and is made of a penetrating stamp material with a reinforcing cloth. .
なお、前記した補強布付き浸透印用印材の製造法においては、多孔性シート材料と補強布と剥離用シートの三者を重ねて加熱・加圧処理することにより成形印材シートとした後、この多孔性シート材料の表面に印字部を形成するようにしてもよいが、加熱・加圧処理するときに蓋型や一方の加圧用ローラ側に印字形成用の凹凸部を形成しておき、加熱・加圧処理により三者が一体化された成形印材シートとするときに多孔性シート材料表面に印字部を形成するようにしてもよく、これを請求項2の発明とし、また、発泡用材料を加熱により発泡される発泡剤とせずに塩化ナトリウム粒子などの洗い出し物質とするときは、この洗い出し物質の洗除を剥離用シートの剥除の後に行なって多孔性シート材料を無数の連続気孔を有する多孔性シートとしても、洗い出し物質の洗除を剥離用シートの剥除前に行なって多孔性シート材料を無数の連続気孔を有する多孔性シートとしておき、必要に応じて多孔性シートの表面に印字部を型押しや彫刻により形成するようにしてもよく、これらを請求項3、4の発明とする
In the above-described method for producing a penetrating stamp with a reinforcing cloth, after forming a stamped sheet by heating and pressing the three layers of a porous sheet material, a reinforcing cloth and a peeling sheet, The printed part may be formed on the surface of the porous sheet material. However, when heating / pressurizing treatment, an uneven part for printing is formed on the lid type or one pressure roller side, and heating is performed. -When forming a stamping sheet integrated with the three by pressurization, a printing portion may be formed on the surface of the porous sheet material. This is the invention of
前記したような請求項1〜4のいずれかの製造法によれば、多孔性シートの裏側にインキ流通性のある補強布が添着一体化された補強布付き浸透印用印材において、浸透印用印材の全裏面が前記した補強布を構成する織糸よりなる織布面と、前記した多孔性シートの一部が補強布の布目を通じて裏側に露呈されてその端部が剥離用シートの剥離により引き千切りられた無数の斑点状部とよりなるインキ吸収粗面に形成されていることを特徴とする補強布付き浸透印用印材を容易に得ることができ、このようにして得られる補強布付き浸透印用印材は、多孔性シートの裏側に添着一体化された補強布が多孔性シートの強度を補うので全体強度を増大させることとなって強靱で耐久性に優れたものとなることは従来のこの種の補強布付き浸透印用印材と殆ど変わることはないが、特に、本発明では浸透印用印材の全裏面が前記した補強布を構成する織糸の裏面である織布面と、前記した多孔性シートの一部が補強布の布目を通じて裏側に細脚状に浸出してその端部が織布面と略同一面で引き千切られた無数の斑点状部とよりなるインキ吸収粗面とされていることにより次のような効果を発揮する。
According to the manufacturing method of any one of
本発明における浸透印用印材は、その全裏面が前記した補強布を構成する織糸の裏面である織布面と、前記した多孔性シートの一部が補強布の均整に形成されている布目を通じて裏側に細脚状に浸出したうえその端部が剥離用シートの剥離により引き千切られた無数の斑点状部とよりなるインキ吸収粗面に形成されているものであって、、従来品のように加熱・加圧時に溶融した多孔性シート材料の一部が薄い皮膜となって補強布の裏面の一部を覆った状態で残されていることがないので、このインキ吸収粗面のインキ吸収効率が極めて優れたものとなる。その理由は、加熱・加圧時に溶融した多孔性シート材料の一部が補強布の布目を通じて裏側に浸出したとしても、金型面にあるのは補強布ではなくその裏面に添わせた剥離用シートであるため、補強布の布目を通じて裏側に浸出した全ての溶融物がこの剥離用シートに含浸された状態で多孔性シート材料と補強布と剥離用シートの三者が一体化された状態の成形印材シートに成形されて、その後この成形印材シートの裏側より剥離用シートを剥除すると補強布と剥離用シート間に介在された多孔性シート材料の一部は剥離用シートとともに補強布裏面から取り除かれると同時にこの補強布の布目を通じて剥離用シートに達した部分が引き千切られることとなって、得られた浸透印用印材の全裏面は、前記した補強布を構成する織糸の裏面である織布面と、端部が剥離用シートの剥離により引き千切られている均整に配設された無数の斑点状部とよりなるインキ吸収粗面となっており、補強布のインキ吸収力を妨げる皮膜類がなくなるので補強布を通じて成形印材シートへのインキの供給を阻害されることがなく、補強布のインキ吸収能が劣化することのなくて効率的なインキ供給が行なわれることとなるのである。さらに、補強布からのインキ供給性がよくなることにより捺印時における印字面への過度な加圧の必要がなくなり、その結果連続捺印性も向上することとなる。さらに、補強布を構成する織糸の裏面である織布面と、端部が剥離用シートの剥離により引き千切られている均整に配設された無数の斑点状部とよりなるインキ吸収粗面とは滑り止め効果にもすぐれたものとなる。 The penetrating stamp material in the present invention has a woven fabric surface, the entire back surface of which is the back surface of the woven yarn constituting the above-described reinforcing fabric, and a fabric in which a part of the above-described porous sheet is formed evenly of the reinforcing fabric. The end portion of the ink is squeezed into a thin leg shape on the back side, and its end portion is formed on an ink-absorbing rough surface consisting of innumerable spot-like portions that are torn off by peeling of the peeling sheet, In this ink-absorbing rough surface ink, the porous sheet material melted at the time of heating / pressing is not left as a thin film covering a part of the back surface of the reinforcing cloth. Absorption efficiency is extremely excellent. The reason for this is that even if part of the porous sheet material melted during heating and pressurization leaches out to the back side through the fabric of the reinforcing cloth, the mold surface is not for the reinforcing cloth but for the peeling. Since the sheet is a sheet, the porous sheet material, the reinforcing cloth, and the peeling sheet are integrated in a state where all the melt leached to the back side through the cloth of the reinforcing cloth is impregnated in the peeling sheet. When the release sheet is peeled from the back side of the molded stamp sheet after being molded into the molded stamp sheet, a part of the porous sheet material interposed between the reinforcing cloth and the release sheet is removed from the back side of the reinforcing cloth together with the release sheet. As soon as it is removed, the part that has reached the peeling sheet through the stitches of the reinforcing cloth is torn off, and the entire back surface of the obtained seal material for penetration marking is the back surface of the woven yarn that constitutes the reinforcing cloth. Ah It has an ink-absorbing rough surface consisting of a woven fabric surface and countless spots arranged in an orderly manner that have been trimmed by peeling off the release sheet, hindering the ink-absorbing power of the reinforcing fabric. Since the coatings are eliminated, the ink supply to the molded stamping sheet through the reinforcing cloth is not hindered, and the ink absorption ability of the reinforcing cloth is not deteriorated, and the ink is efficiently supplied. . Furthermore, since the ink supply property from the reinforcing cloth is improved, it is not necessary to apply excessive pressure to the printing surface at the time of printing, and as a result, the continuous printing property is also improved. Further, an ink-absorbing rough surface comprising a woven fabric surface which is the back surface of the woven yarn constituting the reinforcing fabric, and countless spots arranged in an orderly manner where the ends are chopped off by peeling of the peeling sheet. It has excellent anti-slip effect.
次に、本発明を図面を参考にしながら詳細に説明する。
図1は本発明で得られた補強布付き浸透印用印材の端面図、図2は多孔性シート材料の裏側にインキ流通性のある補強布と剥離用シートとを重ねて加熱・加圧することにより溶融して、多孔性シート材料の一部が補強布の布目を通じて剥離用シートの布目に介入された状態で三者が一体化された成形印材用シートの端面図、図3は図2に示す印材用シートから剥離用シートを剥除している状態を示す端面図である。
Next, the present invention will be described in detail with reference to the drawings.
FIG. 1 is an end view of an osmotic stamping material with a reinforcing cloth obtained in the present invention, and FIG. 2 is a heating / pressurizing process in which a reinforcing cloth having ink flowability and a peeling sheet are stacked on the back side of a porous sheet material. FIG. 3 is an end view of the sheet for molded stamping material in which the three members are integrated in a state where a part of the porous sheet material is intervened in the cloth of the peeling sheet through the cloth of the reinforcing cloth. It is an end view which shows the state which has peeled the peeling sheet from the sheet | seat for printing materials shown.
本発明では従来のこの種の補強布付き浸透印用印材を製造する場合と同様、図示しない周知の受型と蓋型よりなる加熱可能なプレス型や、成形ロールを用いて成形するので、これらの詳細は省略し、以下にプレス型を用いた場合のみについて簡単に記す。
まず、型開状態で図示しない受型の型面上に、溶融された多孔性シート材料を吸収することのできる剥離用シートと、インキ流通性のある補強布と、塩化ナトリウム粒子のような洗い出し物質や発泡剤などの周知の発泡用材料を混在させてある多孔性シート材料の三者を重ねてセットし、必要に応じて印字形成用の凹凸部を形成してある蓋型で上面より加熱しながら加圧することにより溶融した多孔性シート材料の一部が補強布の布目を通じて剥離用シートに達するようにして剥離用シートと補強布と多孔性シート材料の三者が一体化された成形印材シートとする。なお、この工程は発泡用材料を混在させてある多孔性シート材料の裏側にインキ流通性のある補強布を重ねて両者を加熱・加圧して一体化する従来のこの種の補強布付き浸透印用印材の製造法とは、補強布の裏側に剥離用シートを重ねる部分を除いて変わることがないので、剥離用シートを重ねる部分を除き発泡用材料や成形条件などの詳細は省略する。
In the present invention, as in the case of manufacturing a conventional penetrating stamp material with a reinforcing cloth of this type, since it is molded using a heatable press mold comprising a well-known receiving mold and a lid mold (not shown) and a molding roll, these are used. The details of are omitted, and only a case where a press die is used will be briefly described below.
First, on a mold surface of a receiving mold (not shown) in a mold open state, a release sheet capable of absorbing the molten porous sheet material, a reinforcing cloth with ink flowability, and washing out such as sodium chloride particles Set three layers of porous sheet material mixed with known foaming materials such as substances and foaming agents, and heat from the top with a lid mold with uneven parts for printing as necessary A stamping material in which the peeling sheet, the reinforcing cloth, and the porous sheet material are integrated so that a part of the porous sheet material melted by pressurizing while pressing reaches the peeling sheet through the reinforcing cloth. A sheet. In this process, this type of conventional penetrating seal with a reinforcing cloth is used, in which a reinforcing cloth with ink flowability is stacked on the back side of the porous sheet material mixed with foaming material, and both are heated and pressed to integrate them. The manufacturing method of the printing material does not change except for the portion where the peeling sheet is stacked on the back side of the reinforcing cloth, and details such as the foaming material and molding conditions are omitted except for the portion where the peeling sheet is stacked.
次に、型開きして受型上で多孔性シート材料と補強布と剥離用シートの三者が一体に成形されている成形印材シートを脱型する。そして、この成形印材シートの裏側から剥離用シートを引き外せば、多孔性シートの一部が補強布の布目を通じて裏側の剥離用シートに達している部分のうち布目を埋めて剥離用シートに達している細脚状の浸出部分は補強布と剥離用シートとの境界面で端部が引き千切りられて無数の斑点状部が形成されるとともに、補強布の布目を通じて裏側に浸出して補強布と剥離用シートとの境界面間に介入されて薄い皮膜を形成している溶融物は剥離用シート側に含浸された状態で補強布裏面から剥除され、結果として、浸透印用印材の全裏面は前記した補強布を構成する織糸の裏面である織布面と、多孔性シートの一部が補強布の布目を通じて裏側に露呈されてその端部が剥離用シートの剥離により引き千切りられた無数の斑点状部とよりなるインキ吸収粗面に形成されることとなる。なお、剥離用シートを剥除したときに補強布と剥離用シートとの境界面間に介入されて薄い皮膜を形成している溶融物が全て剥離用シート側に含浸させた状態となるようにするためには、剥離用シートの方が補強布よりも溶融物の浸透力の大きい材料を用いればよい。 Next, the mold is opened, and the molded stamp material sheet in which the three members of the porous sheet material, the reinforcing cloth, and the peeling sheet are integrally formed on the receiving mold is removed. Then, if the release sheet is pulled off from the back side of the molded stamp material sheet, the porous sheet partly fills the fabric of the part that reaches the back side release sheet through the reinforcing fabric and reaches the release sheet. The thin leg-shaped leached part is chopped at the boundary between the reinforcing cloth and the peeling sheet to form countless spot-like parts, and leached to the back side through the cloth of the reinforcing cloth. The melt that forms a thin film by intervening between the interface between the release sheet and the release sheet is peeled off from the back of the reinforcing fabric while being impregnated on the release sheet side. The back side is the woven fabric surface that is the back side of the woven yarn constituting the reinforcing fabric, and a part of the porous sheet is exposed to the back side through the fabric of the reinforcing fabric, and the end portion is shredded by peeling off the release sheet. It is made up of countless spots It will be formed in the key absorption rough surface. It should be noted that when the release sheet is peeled off, the melt that forms a thin film by being intervened between the boundary surfaces of the reinforcing cloth and the release sheet is impregnated on the release sheet side. In order to do this, the release sheet may be made of a material having a greater melt penetration than the reinforcing cloth.
また、多孔性シート材料と補強布と剥離用シートとを重ねて加熱・加圧処理するときに蓋型や受型の型面に印字部形成用の凹凸部を形成しておけば、多孔性シート材料と補強布と剥離用シートの三者を一体化する工程で多孔性シートの表面に印字部を同時に形成できるので規格品の製造にはこの方法が好ましいが、別注品用の補強布付き浸透印用印材とするときは、レーザ加工や彫刻または型押など周知の手段で印字部を形成できるように多孔性シートの表面を平面状として成形してもよいことは勿論であり、さらに、発泡用材料としては塩化ナトリウム粒子などの周知の洗い出し物質を用いても、加熱により発泡される発泡剤の添加の2法が一般的であるが、洗い出し物質を用いるときはこの洗い出し物質の洗除を剥離用シートの剥除後に行なっても、剥離用シートの剥除前に行なってもよい。 In addition, if the porous sheet material, the reinforcing cloth, and the release sheet are overlaid and heated / pressurized, if the concave and convex portions for forming the printing portion are formed on the mold surface of the lid mold or receiving mold, This method is preferable for the production of standard products because the printing part can be simultaneously formed on the surface of the porous sheet in the process of integrating the three of the sheet material, the reinforcing cloth and the release sheet. When using as a penetrating marking material, it is a matter of course that the surface of the porous sheet may be formed into a flat shape so that the printing portion can be formed by known means such as laser processing, engraving or embossing, Even if a well-known washing substance such as sodium chloride particles is used as the foaming material, two methods of adding a foaming agent that is foamed by heating are generally used. However, when the washing substance is used, the washing substance should be washed out. After removing the peeling sheet Also made by, it may be performed before 剥除 of the release sheet.
以下に、多孔性シート材料がゴム系の場合を実施例1とし、熱可塑性樹脂系の場合を実施例2として記す。
(実施例1)
合成ゴム(NBR)100部(以下、重量部)に対し、重量比で、硫黄3.5部、亜鉛華5部、加硫促進剤5部、液状ゴム(低重合NBR)ワセリン、DBP等からなる軟化剤30部、カーボンブラック50部、老化防止剤2部、発泡用材料として粒径0.149〜0.176mmの塩化ナトリウム微粉末800部、粒径0.062〜0.103mmの馬鈴薯澱粉微粉末およびサッカロース各100部と、長さ1mm、繊度3dのアラミド繊維5部を加圧ニーダーに投入して混練し、これをカレンダーロールにかけて5mm厚の角形の未加硫シートを作成した。これを型面に1mm深さの文字を彫った周知のプレス成形用の金型に収容し、補強布として、前記した角形の浸透印用印材の大きさに見合う大きさで、120番手の双糸を打ち込み本数250本として平織りした綿布を載せたうえ、さらにその上に40番手の単糸を打ち込み本数60本として平織した綿布を剥離用シートとして載せて、蓋型を介して200kg/cm2 の圧力を加えながら150°cの温度下で15分間加硫してこの間における加熱で溶融される多孔性シート材料の一部を補強布の布目を通じ剥離用シートに含浸させた。その結果、図示するように、多孔性シート材料1と補強布2と剥離用シート3の三者が積層一体化された成形印材シート4が得られるから、これを脱型したうえ全体を水洗して前記した多孔性シート材料1に含まれていた全ての塩化ナトリウム微粉末を溶出させて多孔性シート材料1を無数の連続気孔を有するNBR系の多孔性シート11とする。そして、図2に示すように、この多孔性シート11と補強布2と剥離用シート3との三者が一体化された成形印材シート4の裏側から剥離用シート3を剥除してゆけば、前記した多孔性シート材料1が溶融されたときに補強布2の布目を通じて裏側に細脚状に浸出して剥離用シート3に含浸した多孔性シート11の一部が引き千切りられて無数の斑点状部12が形成されるとともに、補強布2と剥離用シート3との間に浸出して薄膜状として介在されている多孔性シート11の一部が剥離用シート3と共に補強布2の裏側から取り除かれ、図3に示すように、全裏面が前記した補強布2を構成する織糸よりなるきれいな織布面と、前記した多孔性シート11の一部が補強布2の布目を通じて裏側に露呈されてその端部が剥離用シートの剥離により引き千切りられた無数の斑点状部12とよりなるインキ吸収粗面に形成されたシート状の補強布付き浸透印用印材5が得られた。
Hereinafter, a case where the porous sheet material is a rubber type is referred to as Example 1, and a case where the porous sheet material is a thermoplastic resin type is described as Example 2.
Example 1
From 100 parts by weight of synthetic rubber (NBR) (hereinafter, parts by weight), 3.5 parts by weight, 5 parts by zinc, 5 parts by vulcanization accelerator, liquid rubber (low polymerization NBR) petrolatum, DBP, etc. 30 parts of softening agent, 50 parts of carbon black, 2 parts of anti-aging agent, 800 parts of fine sodium chloride powder having a particle size of 0.149 to 0.176 mm as foaming material, potato starch having a particle size of 0.062 to 0.103 mm 100 parts each of fine powder and saccharose and 5 parts of aramid fibers having a length of 1 mm and a fineness of 3 d were put into a pressure kneader and kneaded, and this was placed on a calender roll to prepare a 5 mm thick rectangular unvulcanized sheet. This is housed in a well-known press-molding die with a 1 mm deep character on the mold surface, and is used as a reinforcing cloth in a size suitable for the size of the above-mentioned square penetrating stamping material. A cotton cloth woven into plain yarn with 250 yarns is placed on it, and a cotton cloth plain with woven 40 yarns is placed on it as a peeling sheet, and 200 kg / cm 2 is placed through a lid mold. The release sheet was impregnated with a part of the porous sheet material, which was vulcanized at a temperature of 150 ° C. for 15 minutes while being heated and melted by heating during this period, through the cloth of the reinforcing cloth. As a result, as shown in the figure, a molded
この補強布付き浸透印用印材5を周長100mm、幅5mmに裁断し、レーザー彫刻機を用いて文字駒数16コマを刻印したうえ環状に連繋して回転印用印字ベルトとし、その補強布側から印字面側にインキを自然浸透させる時間を測定したところ、2時間で全文字部分へインキを完全に浸透させることができた。これは、従来法により得られた回転印用印字ベルトが24時間であるのに対して大幅の時間短縮ができたこととなり、本発明が極めて有効であることが確認できた。
This penetrating
(実施例2)
ポリエチレン樹脂100部(以下、重量部)に分子量400のポリエチレングリコール20部、発泡用材料として粒径0.010〜0.060mmの塩化ナトリウム微粉末350部を配合したものにカーボンブラックを加えて混練してこれをローラ間を通して1.0mm厚のシート材料を作成した。そして、このシート材料の裏側に補強布として、これと略同大の120番手の双糸を打ち込み本数250本として平織りした綿布を重ねたうえ、さらに、撚って120デニールとしたポリエステル繊維を用いて打ち込み本数100本として平織したポリエステル系化繊布を剥離用シートとして重ねて、文字の刻印されていない周知の加圧ロールにより200kg/cm2 の圧力を加えながら140°cに加熱して三者を一体化し、この間における加熱で溶融される多孔性シート材料であるポリエチレン樹脂の一部を補強布の布目を通じ剥離用シートに含浸させ、これにより実施例1と同様、多孔性シート材料と補強布と剥離用シートの三者が積層一体化された成形印材シートが得られるから、その後は、実施例1の場合と同様にして多孔性シート材料に含まれていた全ての塩化ナトリウム微粉末を溶出させて多孔性シート材料を無数の連続気孔を有するポリエチレン樹脂系の多孔性シートとする。そして、所要の文字や図形が黒地で、余白を透明地としたポジフィルムを多孔性シート面に添わせてフィルム側から赤外線を照射すると、黒地の部分は赤外線を通さないので透明地部分のみに赤外線が照射されて多孔性シートに無組まれているカーボンブラックが発熱して多孔性シートのうちこの部分が溶融し、硬化後にはインキを透過させない非多孔質皮膜となり、黒地で覆われていた部分に印字用凸部が残された成形印材シートを得た。この多孔性シートと補強布と剥離用シートとの三者が一体化された成形印材シートの裏側から剥離用シートを剥除したところ、前記した実施例1の場合と同様、全裏面が前記した補強布を構成する織糸よりなるきれいな織布面と、前記した多孔性シートの一部が補強布の布目を通じて裏側に露呈されてその端部が剥離用シートの剥離により引き千切りられた無数の斑点状部とよりなるインキ吸収粗面に形成された補強布付きシートが得られた。このようにして得られた補強布付きシートを実施例1の場合と同様の長さおよび幅となるように切断したうえ環状に連繋して回転印用印字ベルトとし、その補強布側から印字面側にインキを自然浸透させる時間を測定したところ、10分間で全文字部分へインキを完全に浸透させることができた。これは、従来法により得られた回転印用印字ベルトが2時間であるのに対して大幅の時間短縮ができたこととなり、本発明が極めて有効であることが確認できた。
(Example 2)
Carbon black is added to 100 parts of polyethylene resin (hereinafter referred to as "parts by weight"), 20 parts of polyethylene glycol having a molecular weight of 400, and 350 parts of fine sodium chloride powder having a particle size of 0.010 to 0.060 mm as a foaming material, and kneaded. Then, a sheet material having a thickness of 1.0 mm was formed through the rollers. Then, as a reinforcing cloth on the back side of this sheet material, a double-woven cotton cloth is piled up by placing a double yarn of approximately the same number of 120 as the number of yarns, and further using polyester fibers twisted to 120 denier Three layers of polyester fabrics that were plain woven with 100 punches were stacked as a release sheet and heated to 140 ° C. while applying a pressure of 200 kg / cm 2 with a well-known pressure roll not marked with characters. And a part of polyethylene resin, which is a porous sheet material that is melted by heating in the meantime, is impregnated into the peeling sheet through the cloth of the reinforcing cloth, and as in Example 1, the porous sheet material and the reinforcing cloth are thus impregnated. Since a molded stamping sheet in which the three members of the sheet and the peeling sheet are laminated and integrated is obtained, the porous sheet is processed in the same manner as in Example 1. The porous sheet of polyethylene resin having all of the sodium chloride powder countless continuous pores of porous sheet material eluted contained in cost. And, if the required characters and figures are black, and a positive film with a blank transparent area is attached to the porous sheet surface and irradiated with infrared rays from the film side, the black background part does not pass infrared rays, so only the transparent background part The carbon black that was not assembled in the porous sheet when irradiated with infrared rays generated heat and this part of the porous sheet melted, and after curing, a non-porous film that did not allow ink to pass through was covered with a black background A molded stamp material sheet in which printing convex portions were left in the portion was obtained. When the peeling sheet was peeled from the back side of the molded stamping sheet in which the porous sheet, the reinforcing cloth, and the peeling sheet were integrated, the entire back surface was the same as in the case of Example 1 described above. Innumerable woven fabric surface made of woven yarn constituting the reinforcing fabric, and a part of the porous sheet described above are exposed to the back side through the fabric of the reinforcing fabric, and its end portions are shredded by peeling of the release sheet. The sheet | seat with a reinforcement cloth formed in the ink absorption rough surface which consists of a spot-like part was obtained. The sheet with the reinforcing cloth thus obtained was cut so as to have the same length and width as in the case of Example 1 and connected to the ring to form a printing belt for rotary stamping. When the time for allowing the ink to naturally permeate was measured, the ink could be completely permeated into all character portions in 10 minutes. This means that the time required for the rotary stamping print belt obtained by the conventional method is significantly shorter than that of 2 hours, and it has been confirmed that the present invention is extremely effective.
1 多孔性シート材料 2 補強布 3 剥離用シート 4 成形印材シート 5 補強布付き浸透印用印材 11 多孔性シート 12 斑点状部
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