JP5621376B2 - Image forming apparatus - Google Patents
Image forming apparatus Download PDFInfo
- Publication number
- JP5621376B2 JP5621376B2 JP2010163952A JP2010163952A JP5621376B2 JP 5621376 B2 JP5621376 B2 JP 5621376B2 JP 2010163952 A JP2010163952 A JP 2010163952A JP 2010163952 A JP2010163952 A JP 2010163952A JP 5621376 B2 JP5621376 B2 JP 5621376B2
- Authority
- JP
- Japan
- Prior art keywords
- image
- image carrier
- image forming
- voltage
- transfer
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Active
Links
- 238000012546 transfer Methods 0.000 claims description 131
- 125000004432 carbon atom Chemical group C* 0.000 claims description 38
- 229920005989 resin Polymers 0.000 claims description 33
- 239000011347 resin Substances 0.000 claims description 33
- 230000015572 biosynthetic process Effects 0.000 claims description 30
- 239000000463 material Substances 0.000 claims description 24
- 239000011230 binding agent Substances 0.000 claims description 17
- 125000000217 alkyl group Chemical group 0.000 claims description 13
- 125000003118 aryl group Chemical group 0.000 claims description 13
- 229920001577 copolymer Polymers 0.000 claims description 9
- 125000005843 halogen group Chemical group 0.000 claims description 9
- 238000011144 upstream manufacturing Methods 0.000 claims description 9
- 125000000753 cycloalkyl group Chemical group 0.000 claims description 6
- 125000004435 hydrogen atom Chemical group [H]* 0.000 claims description 6
- 125000003545 alkoxy group Chemical group 0.000 claims description 3
- 125000001424 substituent group Chemical group 0.000 claims description 3
- 125000002023 trifluoromethyl group Chemical group FC(F)(F)* 0.000 claims description 3
- 238000007599 discharging Methods 0.000 claims description 2
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical group [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims 1
- 150000001721 carbon Chemical group 0.000 claims 1
- 229910052799 carbon Inorganic materials 0.000 claims 1
- 125000001183 hydrocarbyl group Chemical group 0.000 claims 1
- 239000010410 layer Substances 0.000 description 62
- 238000004519 manufacturing process Methods 0.000 description 27
- 239000011248 coating agent Substances 0.000 description 26
- 238000000576 coating method Methods 0.000 description 26
- 238000005259 measurement Methods 0.000 description 17
- 239000000243 solution Substances 0.000 description 14
- 238000010586 diagram Methods 0.000 description 12
- 238000000034 method Methods 0.000 description 11
- 239000007788 liquid Substances 0.000 description 10
- 238000004140 cleaning Methods 0.000 description 8
- 230000000052 comparative effect Effects 0.000 description 7
- 150000001875 compounds Chemical class 0.000 description 7
- ZWEHNKRNPOVVGH-UHFFFAOYSA-N 2-Butanone Chemical compound CCC(C)=O ZWEHNKRNPOVVGH-UHFFFAOYSA-N 0.000 description 6
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 6
- WYURNTSHIVDZCO-UHFFFAOYSA-N Tetrahydrofuran Chemical compound C1CCOC1 WYURNTSHIVDZCO-UHFFFAOYSA-N 0.000 description 6
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 6
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 description 6
- 238000011161 development Methods 0.000 description 6
- 238000011156 evaluation Methods 0.000 description 6
- 239000002245 particle Substances 0.000 description 6
- 230000005684 electric field Effects 0.000 description 5
- 239000011241 protective layer Substances 0.000 description 5
- IISBACLAFKSPIT-UHFFFAOYSA-N bisphenol A Chemical compound C=1C=C(O)C=CC=1C(C)(C)C1=CC=C(O)C=C1 IISBACLAFKSPIT-UHFFFAOYSA-N 0.000 description 4
- -1 dimethylaminophenyl Chemical group 0.000 description 4
- 239000006185 dispersion Substances 0.000 description 4
- 230000008030 elimination Effects 0.000 description 4
- 238000003379 elimination reaction Methods 0.000 description 4
- 239000000203 mixture Substances 0.000 description 4
- 229920005668 polycarbonate resin Polymers 0.000 description 4
- 239000004431 polycarbonate resin Substances 0.000 description 4
- 239000000523 sample Substances 0.000 description 4
- 230000003068 static effect Effects 0.000 description 4
- 229920002554 vinyl polymer Polymers 0.000 description 4
- KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 description 3
- LRHPLDYGYMQRHN-UHFFFAOYSA-N N-Butanol Chemical compound CCCCO LRHPLDYGYMQRHN-UHFFFAOYSA-N 0.000 description 3
- 239000000470 constituent Substances 0.000 description 3
- 238000006386 neutralization reaction Methods 0.000 description 3
- 229920003227 poly(N-vinyl carbazole) Polymers 0.000 description 3
- 229920002037 poly(vinyl butyral) polymer Polymers 0.000 description 3
- 238000012360 testing method Methods 0.000 description 3
- YLQBMQCUIZJEEH-UHFFFAOYSA-N tetrahydrofuran Natural products C=1C=COC=1 YLQBMQCUIZJEEH-UHFFFAOYSA-N 0.000 description 3
- 239000011787 zinc oxide Substances 0.000 description 3
- 229920000178 Acrylic resin Polymers 0.000 description 2
- 239000004925 Acrylic resin Substances 0.000 description 2
- 229930185605 Bisphenol Natural products 0.000 description 2
- 239000006087 Silane Coupling Agent Substances 0.000 description 2
- YTPLMLYBLZKORZ-UHFFFAOYSA-N Thiophene Chemical compound C=1C=CSC=1 YTPLMLYBLZKORZ-UHFFFAOYSA-N 0.000 description 2
- 239000007983 Tris buffer Substances 0.000 description 2
- 229920001893 acrylonitrile styrene Polymers 0.000 description 2
- RGCKGOZRHPZPFP-UHFFFAOYSA-N alizarin Chemical compound C1=CC=C2C(=O)C3=C(O)C(O)=CC=C3C(=O)C2=C1 RGCKGOZRHPZPFP-UHFFFAOYSA-N 0.000 description 2
- 150000001412 amines Chemical class 0.000 description 2
- MWPLVEDNUUSJAV-UHFFFAOYSA-N anthracene Chemical compound C1=CC=CC2=CC3=CC=CC=C3C=C21 MWPLVEDNUUSJAV-UHFFFAOYSA-N 0.000 description 2
- 239000011324 bead Substances 0.000 description 2
- 229920006026 co-polymeric resin Polymers 0.000 description 2
- 230000007547 defect Effects 0.000 description 2
- 238000003618 dip coating Methods 0.000 description 2
- 229920001971 elastomer Polymers 0.000 description 2
- 239000010419 fine particle Substances 0.000 description 2
- 239000011521 glass Substances 0.000 description 2
- 150000002430 hydrocarbons Chemical group 0.000 description 2
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 description 2
- 229920002382 photo conductive polymer Polymers 0.000 description 2
- 229920002492 poly(sulfone) Polymers 0.000 description 2
- 229920002401 polyacrylamide Polymers 0.000 description 2
- 229920001230 polyarylate Polymers 0.000 description 2
- 239000004645 polyester resin Substances 0.000 description 2
- 229920001225 polyester resin Polymers 0.000 description 2
- 229920000642 polymer Polymers 0.000 description 2
- 229920001296 polysiloxane Polymers 0.000 description 2
- 229920005990 polystyrene resin Polymers 0.000 description 2
- 229920000915 polyvinyl chloride Polymers 0.000 description 2
- 239000004800 polyvinyl chloride Substances 0.000 description 2
- SCUZVMOVTVSBLE-UHFFFAOYSA-N prop-2-enenitrile;styrene Chemical compound C=CC#N.C=CC1=CC=CC=C1 SCUZVMOVTVSBLE-UHFFFAOYSA-N 0.000 description 2
- BBEAQIROQSPTKN-UHFFFAOYSA-N pyrene Chemical compound C1=CC=C2C=CC3=CC=CC4=CC=C1C2=C43 BBEAQIROQSPTKN-UHFFFAOYSA-N 0.000 description 2
- 239000005060 rubber Substances 0.000 description 2
- 239000004576 sand Substances 0.000 description 2
- 229920002050 silicone resin Polymers 0.000 description 2
- 238000003860 storage Methods 0.000 description 2
- 239000000758 substrate Substances 0.000 description 2
- 239000002344 surface layer Substances 0.000 description 2
- BFKJFAAPBSQJPD-UHFFFAOYSA-N tetrafluoroethene Chemical group FC(F)=C(F)F BFKJFAAPBSQJPD-UHFFFAOYSA-N 0.000 description 2
- QLUXVUVEVXYICG-UHFFFAOYSA-N 1,1-dichloroethene;prop-2-enenitrile Chemical compound C=CC#N.ClC(Cl)=C QLUXVUVEVXYICG-UHFFFAOYSA-N 0.000 description 1
- NWUYHJFMYQTDRP-UHFFFAOYSA-N 1,2-bis(ethenyl)benzene;1-ethenyl-2-ethylbenzene;styrene Chemical compound C=CC1=CC=CC=C1.CCC1=CC=CC=C1C=C.C=CC1=CC=CC=C1C=C NWUYHJFMYQTDRP-UHFFFAOYSA-N 0.000 description 1
- FBNAYEYTRHHEOB-UHFFFAOYSA-N 2,3,5-triphenyl-1,3-dihydropyrazole Chemical compound N1N(C=2C=CC=CC=2)C(C=2C=CC=CC=2)C=C1C1=CC=CC=C1 FBNAYEYTRHHEOB-UHFFFAOYSA-N 0.000 description 1
- AXSVCKIFQVONHI-UHFFFAOYSA-N 2,3-bis(4-methoxyphenyl)-1-benzofuran-6-ol Chemical compound C1=CC(OC)=CC=C1C1=C(C=2C=CC(OC)=CC=2)C2=CC=C(O)C=C2O1 AXSVCKIFQVONHI-UHFFFAOYSA-N 0.000 description 1
- JOERSAVCLPYNIZ-UHFFFAOYSA-N 2,4,5,7-tetranitrofluoren-9-one Chemical compound O=C1C2=CC([N+]([O-])=O)=CC([N+]([O-])=O)=C2C2=C1C=C([N+](=O)[O-])C=C2[N+]([O-])=O JOERSAVCLPYNIZ-UHFFFAOYSA-N 0.000 description 1
- VHQGURIJMFPBKS-UHFFFAOYSA-N 2,4,7-trinitrofluoren-9-one Chemical compound [O-][N+](=O)C1=CC([N+]([O-])=O)=C2C3=CC=C([N+](=O)[O-])C=C3C(=O)C2=C1 VHQGURIJMFPBKS-UHFFFAOYSA-N 0.000 description 1
- FEOWMMORTLDJTA-UHFFFAOYSA-N 2-[(diphenylhydrazinylidene)methyl]aniline Chemical compound NC1=CC=CC=C1C=NN(C=1C=CC=CC=1)C1=CC=CC=C1 FEOWMMORTLDJTA-UHFFFAOYSA-N 0.000 description 1
- KXGFMDJXCMQABM-UHFFFAOYSA-N 2-methoxy-6-methylphenol Chemical compound [CH]OC1=CC=CC([CH])=C1O KXGFMDJXCMQABM-UHFFFAOYSA-N 0.000 description 1
- OMXSHNIXAVHELO-UHFFFAOYSA-N 2-phenyl-4-(2-phenylethenyl)quinazoline Chemical compound C=1C=CC=CC=1C=CC(C1=CC=CC=C1N=1)=NC=1C1=CC=CC=C1 OMXSHNIXAVHELO-UHFFFAOYSA-N 0.000 description 1
- MRVRWOCUNTYWHG-UHFFFAOYSA-N 3-(3,4-dimethylphenyl)-4-phenylaniline Chemical compound C1=C(C)C(C)=CC=C1C1=CC(N)=CC=C1C1=CC=CC=C1 MRVRWOCUNTYWHG-UHFFFAOYSA-N 0.000 description 1
- OGGKVJMNFFSDEV-UHFFFAOYSA-N 3-methyl-n-[4-[4-(n-(3-methylphenyl)anilino)phenyl]phenyl]-n-phenylaniline Chemical compound CC1=CC=CC(N(C=2C=CC=CC=2)C=2C=CC(=CC=2)C=2C=CC(=CC=2)N(C=2C=CC=CC=2)C=2C=C(C)C=CC=2)=C1 OGGKVJMNFFSDEV-UHFFFAOYSA-N 0.000 description 1
- UZGVMZRBRRYLIP-UHFFFAOYSA-N 4-[5-[4-(diethylamino)phenyl]-1,3,4-oxadiazol-2-yl]-n,n-diethylaniline Chemical compound C1=CC(N(CC)CC)=CC=C1C1=NN=C(C=2C=CC(=CC=2)N(CC)CC)O1 UZGVMZRBRRYLIP-UHFFFAOYSA-N 0.000 description 1
- 125000000590 4-methylphenyl group Chemical group [H]C1=C([H])C(=C([H])C([H])=C1*)C([H])([H])[H] 0.000 description 1
- PLAZXGNBGZYJSA-UHFFFAOYSA-N 9-ethylcarbazole Chemical compound C1=CC=C2N(CC)C3=CC=CC=C3C2=C1 PLAZXGNBGZYJSA-UHFFFAOYSA-N 0.000 description 1
- SDDLEVPIDBLVHC-UHFFFAOYSA-N Bisphenol Z Chemical compound C1=CC(O)=CC=C1C1(C=2C=CC(O)=CC=2)CCCCC1 SDDLEVPIDBLVHC-UHFFFAOYSA-N 0.000 description 1
- KAKZBPTYRLMSJV-UHFFFAOYSA-N Butadiene Chemical class C=CC=C KAKZBPTYRLMSJV-UHFFFAOYSA-N 0.000 description 1
- NLZUEZXRPGMBCV-UHFFFAOYSA-N Butylhydroxytoluene Chemical compound CC1=CC(C(C)(C)C)=C(O)C(C(C)(C)C)=C1 NLZUEZXRPGMBCV-UHFFFAOYSA-N 0.000 description 1
- 239000004952 Polyamide Substances 0.000 description 1
- 239000004793 Polystyrene Substances 0.000 description 1
- 229920002433 Vinyl chloride-vinyl acetate copolymer Polymers 0.000 description 1
- XQBCVRSTVUHIGH-UHFFFAOYSA-L [dodecanoyloxy(dioctyl)stannyl] dodecanoate Chemical compound CCCCCCCCCCCC(=O)O[Sn](CCCCCCCC)(CCCCCCCC)OC(=O)CCCCCCCCCCC XQBCVRSTVUHIGH-UHFFFAOYSA-L 0.000 description 1
- 239000011354 acetal resin Substances 0.000 description 1
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 1
- 229910052782 aluminium Inorganic materials 0.000 description 1
- 239000003963 antioxidant agent Substances 0.000 description 1
- 230000003078 antioxidant effect Effects 0.000 description 1
- NTXGQCSETZTARF-UHFFFAOYSA-N buta-1,3-diene;prop-2-enenitrile Chemical compound C=CC=C.C=CC#N NTXGQCSETZTARF-UHFFFAOYSA-N 0.000 description 1
- 150000001716 carbazoles Chemical class 0.000 description 1
- 239000003054 catalyst Substances 0.000 description 1
- 229920001429 chelating resin Polymers 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- QJNYIFMVIUOUSU-UHFFFAOYSA-N chloroethene;ethenyl acetate;furan-2,5-dione Chemical compound ClC=C.CC(=O)OC=C.O=C1OC(=O)C=C1 QJNYIFMVIUOUSU-UHFFFAOYSA-N 0.000 description 1
- 238000007334 copolymerization reaction Methods 0.000 description 1
- 150000001907 coumarones Chemical class 0.000 description 1
- 239000013078 crystal Substances 0.000 description 1
- 239000004205 dimethyl polysiloxane Substances 0.000 description 1
- 235000013870 dimethyl polysiloxane Nutrition 0.000 description 1
- 239000012153 distilled water Substances 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 239000000428 dust Substances 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 150000002081 enamines Chemical class 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- GVEPBJHOBDJJJI-UHFFFAOYSA-N fluoranthrene Natural products C1=CC(C2=CC=CC=C22)=C3C2=CC=CC3=C1 GVEPBJHOBDJJJI-UHFFFAOYSA-N 0.000 description 1
- 150000008376 fluorenones Chemical class 0.000 description 1
- 150000007857 hydrazones Chemical class 0.000 description 1
- 230000007062 hydrolysis Effects 0.000 description 1
- 238000006460 hydrolysis reaction Methods 0.000 description 1
- 230000001771 impaired effect Effects 0.000 description 1
- 239000003456 ion exchange resin Substances 0.000 description 1
- 229920003303 ion-exchange polymer Polymers 0.000 description 1
- 239000012948 isocyanate Substances 0.000 description 1
- 150000002513 isocyanates Chemical class 0.000 description 1
- 125000000040 m-tolyl group Chemical group [H]C1=C([H])C(*)=C([H])C(=C1[H])C([H])([H])[H] 0.000 description 1
- 239000000113 methacrylic resin Substances 0.000 description 1
- 239000011259 mixed solution Substances 0.000 description 1
- PRMHOXAMWFXGCO-UHFFFAOYSA-M molport-000-691-708 Chemical compound N1=C(C2=CC=CC=C2C2=NC=3C4=CC=CC=C4C(=N4)N=3)N2[Ga](Cl)N2C4=C(C=CC=C3)C3=C2N=C2C3=CC=CC=C3C1=N2 PRMHOXAMWFXGCO-UHFFFAOYSA-M 0.000 description 1
- ISGXOWLMGOPVPB-UHFFFAOYSA-N n,n-dibenzylaniline Chemical compound C=1C=CC=CC=1CN(C=1C=CC=CC=1)CC1=CC=CC=C1 ISGXOWLMGOPVPB-UHFFFAOYSA-N 0.000 description 1
- 150000004866 oxadiazoles Chemical class 0.000 description 1
- 229920001568 phenolic resin Polymers 0.000 description 1
- 108091008695 photoreceptors Proteins 0.000 description 1
- DOIRQSBPFJWKBE-UHFFFAOYSA-N phthalic acid di-n-butyl ester Natural products CCCCOC(=O)C1=CC=CC=C1C(=O)OCCCC DOIRQSBPFJWKBE-UHFFFAOYSA-N 0.000 description 1
- 229920000435 poly(dimethylsiloxane) Polymers 0.000 description 1
- 229920002647 polyamide Polymers 0.000 description 1
- 229920006122 polyamide resin Polymers 0.000 description 1
- 229920000515 polycarbonate Polymers 0.000 description 1
- 239000004417 polycarbonate Substances 0.000 description 1
- 229920001470 polyketone Polymers 0.000 description 1
- 238000006116 polymerization reaction Methods 0.000 description 1
- 229920006324 polyoxymethylene Polymers 0.000 description 1
- 229920002223 polystyrene Polymers 0.000 description 1
- 239000011118 polyvinyl acetate Substances 0.000 description 1
- 229920002689 polyvinyl acetate Polymers 0.000 description 1
- 229920006215 polyvinyl ketone Polymers 0.000 description 1
- 239000011148 porous material Substances 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 238000012545 processing Methods 0.000 description 1
- 230000001681 protective effect Effects 0.000 description 1
- 150000003219 pyrazolines Chemical class 0.000 description 1
- 150000003246 quinazolines Chemical class 0.000 description 1
- 150000004053 quinones Chemical class 0.000 description 1
- 239000011134 resol-type phenolic resin Substances 0.000 description 1
- 229920002545 silicone oil Polymers 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 229920003048 styrene butadiene rubber Polymers 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 238000004381 surface treatment Methods 0.000 description 1
- 239000000725 suspension Substances 0.000 description 1
- UGNWTBMOAKPKBL-UHFFFAOYSA-N tetrachloro-1,4-benzoquinone Chemical compound ClC1=C(Cl)C(=O)C(Cl)=C(Cl)C1=O UGNWTBMOAKPKBL-UHFFFAOYSA-N 0.000 description 1
- 229930192474 thiophene Natural products 0.000 description 1
- 230000007704 transition Effects 0.000 description 1
- ODHXBMXNKOYIBV-UHFFFAOYSA-N triphenylamine Chemical compound C1=CC=CC=C1N(C=1C=CC=CC=1)C1=CC=CC=C1 ODHXBMXNKOYIBV-UHFFFAOYSA-N 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
- 150000007964 xanthones Chemical class 0.000 description 1
Classifications
-
- G—PHYSICS
- G03—PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
- G03G—ELECTROGRAPHY; ELECTROPHOTOGRAPHY; MAGNETOGRAPHY
- G03G15/00—Apparatus for electrographic processes using a charge pattern
- G03G15/14—Apparatus for electrographic processes using a charge pattern for transferring a pattern to a second base
- G03G15/16—Apparatus for electrographic processes using a charge pattern for transferring a pattern to a second base of a toner pattern, e.g. a powder pattern, e.g. magnetic transfer
-
- G—PHYSICS
- G03—PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
- G03G—ELECTROGRAPHY; ELECTROPHOTOGRAPHY; MAGNETOGRAPHY
- G03G21/00—Arrangements not provided for by groups G03G13/00 - G03G19/00, e.g. cleaning, elimination of residual charge
Landscapes
- Physics & Mathematics (AREA)
- General Physics & Mathematics (AREA)
- Control Or Security For Electrophotography (AREA)
- Electrostatic Charge, Transfer And Separation In Electrography (AREA)
Description
本発明は、画像形成装置に関する。 The present invention relates to an image forming apparatus.
特許文献1には、接触帯電式の帯電装置を備えた画像形成装置において、画像形成前に画像形成期間に印加する帯電電圧とは逆極性の帯電電圧を印加することが提案されている。
また、特許文献2には、接触帯電式の帯電装置を備えた画像形成装置において、非画像形成期間に、画像形成期間に印加する帯電電圧より絶対値の小さい電圧値の帯電電圧を印加することが提案されている。
Japanese Patent Application Laid-Open No. 2004-228561 proposes that in an image forming apparatus including a contact charging type charging device, a charging voltage having a polarity opposite to a charging voltage applied during an image forming period is formed before image formation.
Further, in Patent Document 2, in an image forming apparatus including a contact charging type charging device, a charging voltage having an absolute value smaller than a charging voltage applied during the image forming period is applied during a non-image forming period. Has been proposed.
本発明は、非画像形成期間中に、該非画像形成期間から画像形成期間への切替え時まで、少なくとも像保持体が1回転する期間継続して第1の電圧値の転写電圧を印加し、該非画像形成期間の後に連続する画像形成期間に、該切替え時から連続して第2の電圧値の転写電圧を印加しない場合に比べて、形成対象の画像とは異なる線画像の発生が抑制された画像形成装置を提供することを目的とする。 In the present invention, during the non-image forming period, the transfer voltage having the first voltage value is applied continuously during at least one rotation of the image carrier from the non-image forming period to the image forming period. The generation of a line image different from the image to be formed is suppressed compared to the case where the transfer voltage having the second voltage value is not applied continuously during the image forming period after the image forming period. An object is to provide an image forming apparatus.
請求項1に係る発明は、回転する像保持体と、前記像保持体の表面に接触して配置され、直流電圧が印加されることによって前記像保持体の表面を帯電させる帯電部材と、前記帯電部材によって帯電された前記像保持体の表面に静電潜像を形成する潜像形成装置と、前記像保持体の表面に形成された前記静電潜像をトナーによって現像する現像装置と、前記現像装置によって前記像保持体の表面に形成されたトナー像を被転写体へ転写すると共に、前記像保持体を除電する転写部材と、前記転写部材の転写電位が、前記像保持体の表面に形成されたトナー像のトナーとは逆極性の転写電位となるように、該転写部材に転写電圧を印加する電圧印加装置と、非画像形成期間中に、該非画像形成期間から画像形成期間への切替え時まで、少なくとも前記像保持体が1回転する期間継続して、前記像保持体の表面に形成されたトナー像のトナーとは逆極性で且つ0V以外の第1の電圧値の前記転写電圧を印加し、該非画像形成期間の後に連続する画像形成期間に、前記切替え時から連続して第2の電圧値の前記転写電圧を印加するように、前記電圧印加装置を制御する制御手段と、を備えた画像形成装置である。 According to a first aspect of the present invention, there is provided a rotating image carrier, a charging member disposed in contact with the surface of the image carrier, and charging the surface of the image carrier by applying a DC voltage ; A latent image forming device that forms an electrostatic latent image on the surface of the image carrier charged by a charging member; a developing device that develops the electrostatic latent image formed on the surface of the image carrier with toner; The toner image formed on the surface of the image holding member by the developing device is transferred to the transfer target member, and the transfer member for discharging the image holding member, and the transfer potential of the transfer member is the surface of the image holding member. A voltage applying device that applies a transfer voltage to the transfer member so that the transfer potential has a polarity opposite to that of the toner of the toner image formed on the toner image, and from the non-image formation period to the image formation period during the non-image formation period. At least until switching And period continues the image carrier is rotated 1, applying the transfer voltage of the first voltage value other than and 0V to the toner of the toner image formed on the surface of the image carrier in the reverse polarity, non An image forming unit including: a control unit that controls the voltage applying device so as to apply the transfer voltage having the second voltage value continuously from the switching time in an image forming period continuous after the image forming period. Device.
請求項2に係る発明は、前記像保持体は、支持体上に、電荷発生層、及び下記一般式(1)で表される構造を有する電荷輸送性材料を含む電荷輸送層をこの順に有し、前記像保持体の表面における、前記帯電部材によって帯電される領域より該像保持体の回転方向上流側で、且つ前記転写部材によって前記トナー像が前記被転写体へ転写される領域より該像保持体の回転方向下流側の領域の表面電位の絶対値Vinと、前記像保持体の表面における、前記帯電部材よって帯電される領域より該像保持体の回転方向下流側で、且つ前記潜像形成装置によって静電潜像の形成される領域より該像保持体の回転方向上流側の領域の表面電位の絶対値Vhと、前記像保持体の前記電荷輸送層及び前記電荷輸送層より表面側に設けられた層の厚みの合計T(μm)と、の画像形成期間における関係が、7T+50≦Vh−Vinを満たす請求項1に記載の画像形成装置である。 The invention according to claim 2, before Symbol image holding member comprises a support, a charge generation layer, and a charge transport layer containing a charge-transporting material having a structure represented by the following general formula (1) in this order And an area on the surface of the image carrier that is upstream of the image carrier in the rotational direction from the region charged by the charging member, and a region where the toner image is transferred to the transfer medium by the transfer member. The absolute value Vin of the surface potential of the region downstream in the rotation direction of the image carrier and the downstream of the image carrier in the rotation direction of the image carrier from the region charged by the charging member on the surface of the image carrier. The absolute value Vh of the surface potential of the region upstream of the rotation direction of the image carrier from the region where the electrostatic latent image is formed by the latent image forming device, and the charge transport layer and the charge transport layer of the image carrier Total thickness of layers provided on the surface side And ([mu] m), the relationship of the image formation period, an image forming apparatus according to claim 1 satisfying 7T + 50 ≦ Vh-Vin.
一般式(1)中、R1、R2、R3、R4、R5、及びR6はそれぞれ独立して水素原子、ハロゲン原子、炭素数1以上20以下のアルキル基、炭素数1以上20以下のアルコキシ基、又は、炭素数6以上30以下のアリール基を表し、隣接する2つの置換基同士が結合して炭化水素環構造を形成してもよい。n及びmはそれぞれ独立して0又は1を表す。 In General Formula (1), R 1 , R 2 , R 3 , R 4 , R 5 , and R 6 are each independently a hydrogen atom, a halogen atom, an alkyl group having 1 to 20 carbon atoms, or 1 or more carbon atoms. It represents an alkoxy group having 20 or less or an aryl group having 6 to 30 carbon atoms, and two adjacent substituents may be bonded to form a hydrocarbon ring structure. n and m each independently represents 0 or 1.
請求項3に係る発明は、前記電荷輸送層が、下記一般式(2)で表される構造単位を含有した結着樹脂を含む請求項2に記載の画像形成装置である。 The invention according to claim 3 is the image forming apparatus according to claim 2, wherein the charge transport layer includes a binder resin containing a structural unit represented by the following general formula (2).
一般式(2)中、R7及びR8は、各々独立にハロゲン原子、炭素数1以上6以下のアルキル基、炭素数5以上7以下のシクロアルキル基、又は炭素数6以上12以下のアリール基であり、e,fは、各々独立に0以上4以下の整数を表す。 In General Formula (2), R 7 and R 8 are each independently a halogen atom, an alkyl group having 1 to 6 carbon atoms, a cycloalkyl group having 5 to 7 carbon atoms, or an aryl having 6 to 12 carbon atoms. E and f each independently represents an integer of 0 or more and 4 or less.
請求項4に係る発明は、前記結着樹脂が、前記一般式(2)で表される構造単位と、下記一般式(3)で表される構造単位と、を有する共重合体を含有した請求項3に記載の画像形成装置である。 In the invention according to claim 4, the binder resin contains a copolymer having a structural unit represented by the general formula (2) and a structural unit represented by the following general formula (3). An image forming apparatus according to claim 3.
一般式(3)中、R9及びR10は、各々独立にハロゲン原子、炭素数1以上6以下のアルキル基、炭素数5以上7以下のシクロアルキル基、又は炭素数6以上12以下のアリール基であり、g,hは、各々独立に0以上4以下の整数を表す。Xは、−CR11R12−(但し、R11及びR12は、各々独立に水素原子、トリフルオロメチル基、炭素数1以上6以下のアルキル基、又は炭素数6以上12以下のアリール基のいずれかを表す。)、炭素数5以上11以下の1,1−シクロアルキレン基、炭素数2以上10以下のα,ω−アルキレン基、−O−、−S−、−SO−、または−SO2−を表す。 In general formula (3), R 9 and R 10 are each independently a halogen atom, an alkyl group having 1 to 6 carbon atoms, a cycloalkyl group having 5 to 7 carbon atoms, or an aryl having 6 to 12 carbon atoms. And g and h each independently represent an integer of 0 or more and 4 or less. X is —CR 11 R 12 — (wherein R 11 and R 12 are each independently a hydrogen atom, a trifluoromethyl group, an alkyl group having 1 to 6 carbon atoms, or an aryl group having 6 to 12 carbon atoms) Or a 1,1-cycloalkylene group having 5 to 11 carbon atoms, an α, ω-alkylene group having 2 to 10 carbon atoms, —O—, —S—, —SO—, or -SO 2 - represents a.
請求項1に係る発明によれば、非画像形成期間中に、該非画像形成期間から画像形成期間への切替え時まで、少なくとも像保持体が1回転する期間継続して第1の電圧値の転写電圧を印加し、該非画像形成期間の後に連続する画像形成期間に、該切替え時から連続して第2の電圧値の転写電圧を印加しない場合に比べて、形成対象の画像とは異なる線画像の発生が抑制された画像形成装置が提供される。 According to the first aspect of the present invention, during the non-image forming period, the first voltage value is continuously transferred for at least one rotation of the image carrier until the switching from the non-image forming period to the image forming period. Compared to the case where a voltage is applied and the transfer voltage of the second voltage value is not applied continuously in the image forming period subsequent to the non-image forming period, the line image is different from the image to be formed. An image forming apparatus in which the occurrence of the above is suppressed is provided.
請求項2に係る発明によれば、帯電部材として、像保持体の表面に接触して配置され、直流電圧が印加されることによって像保持体の表面を帯電させる帯電部材を用いた場合であっても、本発明における電荷輸送性材料を用いず且つ本発明における式(7T+50≦Vh−Vin)の関係を満たさない場合に比べて、形成対象の画像とは異なる線画像の発生が抑制された画像形成装置が提供される。 According to the second aspect of the present invention, the charging member is a charging member that is disposed in contact with the surface of the image carrier and charges the surface of the image carrier by applying a DC voltage. However, compared with the case where the charge transporting material in the present invention is not used and the relationship of the formula (7T + 50 ≦ Vh−Vin) in the present invention is not satisfied, generation of a line image different from the image to be formed is suppressed. An image forming apparatus is provided.
請求項3に係る発明によれば、本発明における結着樹脂を含まない場合に比べて、形成対象の画像とは異なる線画像の発生が抑制された画像形成装置が提供される。 According to the third aspect of the present invention, there is provided an image forming apparatus in which the generation of a line image different from the image to be formed is suppressed as compared with the case where the binder resin in the present invention is not included.
請求項4に係る発明によれば、電荷輸送層に含まれる結着樹脂が、本発明における共重合体を含有しない場合に比べて、形成対象の画像とは異なる線画像の発生が抑制された画像形成装置が提供される。 According to the invention of claim 4, the generation of a line image different from the image to be formed is suppressed as compared with the case where the binder resin contained in the charge transport layer does not contain the copolymer in the present invention. An image forming apparatus is provided.
以下、図面を参照して本実施の形態の画像形成装置の一の形態を詳細に説明する。
図1に示すように、本実施の形態に係る画像形成装置10には、像保持体12が設けられている。像保持体12は、円柱状とされ、図示を省略するモータにより、回転駆動(図1中の矢印A方向)される。
Hereinafter, an embodiment of the image forming apparatus of the present embodiment will be described in detail with reference to the drawings.
As shown in FIG. 1, an image carrier 12 is provided in the image forming apparatus 10 according to the present exemplary embodiment. The image carrier 12 has a cylindrical shape, and is rotationally driven (in the direction of arrow A in FIG. 1) by a motor (not shown).
像保持体12は、図2に示すように、支持体60と、この支持体60上に形成された下引層62と、この下引層62の上に形成された感光層63と、から構成されている。この感光層63は、電荷発生層65と電荷輸送層66との2層構造とされている。
なお、本実施の形態では、像保持体12の感光層63は、電荷発生層65と電荷輸送層66との2層構造とされている場合を説明するが、1層構造とされていてもよく、また、電荷輸送層66上に(電荷輸送層66より外側に)、さらに保護層(図示省略)等の他の層を設けた構成であってもよい。
また、この像保持体12の構成材料は、公知の材料を用いればよく、支持体60、感光層63、保護層(図示省略)の構成材料としては、例えば、特願2007−333308に記載の基体、下引層、感光層、及び保護層に用いられる材料が挙げられる。
As shown in FIG. 2, the image carrier 12 includes a support 60, an undercoat layer 62 formed on the support 60, and a photosensitive layer 63 formed on the undercoat layer 62. It is configured. The photosensitive layer 63 has a two-layer structure of a charge generation layer 65 and a charge transport layer 66.
In the present embodiment, the case where the photosensitive layer 63 of the image carrier 12 has a two-layer structure of the charge generation layer 65 and the charge transport layer 66 will be described. Alternatively, a configuration in which another layer such as a protective layer (not shown) is provided on the charge transport layer 66 (outside the charge transport layer 66) may be used.
The constituent material of the image carrier 12 may be a known material. Examples of constituent materials of the support 60, the photosensitive layer 63, and the protective layer (not shown) are described in Japanese Patent Application No. 2007-333308. Examples include materials used for the substrate, the undercoat layer, the photosensitive layer, and the protective layer.
像保持体12の周辺には、帯電装置15、潜像形成装置16、現像装置18、転写装置31、及び清掃部材22が、像保持体12の回転方向に沿って順に配設されている。 Around the image carrier 12, a charging device 15, a latent image forming device 16, a developing device 18, a transfer device 31, and a cleaning member 22 are sequentially arranged along the rotation direction of the image carrier 12.
帯電装置15は、像保持体12表面を帯電する。帯電装置15は、帯電部材14及び電源28を含んで構成されている。本実施の形態では、この帯電部材14は、円柱状とされており、像保持体12の回転に伴って回転するように像保持体12の表面に接触して配置されている。電源28は、帯電部材14に帯電電圧を印加する電源28であり、帯電部材14に電気的に接続されている。
なお、帯電部材14は、像保持体12の表面に接触して設けられていてもよいし、非接触で設けられていてもよい。また、電源28から帯電部材14に印加される帯電電圧は、直流電圧に交流電圧を重畳した重畳電圧であってもよいし、直流電圧であってもよい。
The charging device 15 charges the surface of the image carrier 12. The charging device 15 includes a charging member 14 and a power source 28. In the present embodiment, the charging member 14 has a cylindrical shape, and is arranged in contact with the surface of the image carrier 12 so as to rotate as the image carrier 12 rotates. The power source 28 is a power source 28 that applies a charging voltage to the charging member 14, and is electrically connected to the charging member 14.
Note that the charging member 14 may be provided in contact with the surface of the image carrier 12 or may be provided in a non-contact manner. The charging voltage applied from the power supply 28 to the charging member 14 may be a superimposed voltage obtained by superimposing an AC voltage on a DC voltage, or may be a DC voltage.
また、電源28は、画像形成装置10に設けられた制御部36に電気的に接続されており、制御部36の制御によって、帯電部材14に帯電電圧を印加する。この帯電部材14から帯電電圧を印加された帯電部材14は、印加された帯電電圧に応じた帯電電位に、像保持体12を帯電させる。このため、電源28から印加される帯電電圧が調整されることで、像保持体12は、異なる帯電電位に帯電される。 The power source 28 is electrically connected to a control unit 36 provided in the image forming apparatus 10, and applies a charging voltage to the charging member 14 under the control of the control unit 36. The charging member 14 to which the charging voltage is applied from the charging member 14 charges the image carrier 12 to a charging potential corresponding to the applied charging voltage. Therefore, the image holding body 12 is charged to a different charging potential by adjusting the charging voltage applied from the power source 28.
潜像形成装置16は、帯電部材14により帯電された像保持体12の表面に、形成する対象となる画像の画像情報に基づいて変調した光Lを照射して、像保持体12上に画像情報の画像(形成対象の画像)に応じた静電潜像を形成する。 The latent image forming device 16 irradiates the surface of the image carrier 12 charged by the charging member 14 with the light L modulated based on the image information of the image to be formed, and the image on the image carrier 12. An electrostatic latent image corresponding to an image of information (image to be formed) is formed.
現像装置18内には、トナーを含む公知の現像剤が貯留されている。トナーは、現像装置18内で帯電された状態で貯留されている。現像剤に含まれるトナーとしては、例えば、重合法により得られる体積平均粒子径3μm以上9μm以下のトナーが挙げられる。 A known developer containing toner is stored in the developing device 18. The toner is stored in a charged state in the developing device 18. Examples of the toner contained in the developer include a toner having a volume average particle diameter of 3 μm or more and 9 μm or less obtained by a polymerization method.
また、現像装置18は、像保持体12上に形成された静電潜像を現像剤に含まれるトナーにより現像する現像部材18Aと、電源32と、を含んで構成されている。この現像部材18Aには、電源32が電気的に接続されている。この電源32は、画像形成装置10に設けられた制御部36にも電気的に接続されており、制御部36の制御によって電源32から現像部材18Aに現像電圧が印加される。現像電圧を印加された現像部材18Aは、該現像電圧に応じた現像電位に帯電される。 The developing device 18 includes a developing member 18A that develops the electrostatic latent image formed on the image carrier 12 with toner contained in the developer, and a power source 32. A power source 32 is electrically connected to the developing member 18A. The power source 32 is also electrically connected to a control unit 36 provided in the image forming apparatus 10, and a development voltage is applied from the power source 32 to the developing member 18 </ b> A under the control of the control unit 36. The developing member 18A to which the developing voltage is applied is charged to a developing potential corresponding to the developing voltage.
現像電位に帯電された現像部材18Aは、現像装置18内に貯留された現像剤を表面に保持して、該現像剤に含まれるトナーを現像装置18内から像保持体12表面へと供給する。像保持体12上に供給されたトナーは、像保持体12上の静電潜像に静電力により付着する。詳細には、像保持体12と現像部材18Aとの向かい合う領域における電位差、すなわち、該領域における像保持体12の表面の電位と現像部材18Aの現像電位との電位差によって、現像剤に含まれるトナーが像保持体12の静電潜像の形成された領域に供給され、現像剤にキャリアが含まれている場合には、該キャリアは現像部材18Aに保持されたまま現像装置18内に戻る。これにより、像保持体12上の静電潜像は、現像部材18Aから供給されたトナーによって現像されて、像保持体12上には、静電潜像に応じたトナー像が形成される。 The developing member 18A charged to the developing potential holds the developer stored in the developing device 18 on the surface, and supplies the toner contained in the developer from the developing device 18 to the surface of the image carrier 12. . The toner supplied onto the image carrier 12 adheres to the electrostatic latent image on the image carrier 12 by electrostatic force. Specifically, the toner contained in the developer is determined by the potential difference in the area where the image carrier 12 and the developing member 18A face each other, that is, the potential difference between the surface potential of the image carrier 12 and the developing potential of the developing member 18A in the area. Is supplied to the area where the electrostatic latent image is formed on the image carrier 12, and the carrier is contained in the developer, the carrier returns to the developing device 18 while being held by the developing member 18A. As a result, the electrostatic latent image on the image carrier 12 is developed by the toner supplied from the developing member 18 </ b> A, and a toner image corresponding to the electrostatic latent image is formed on the image carrier 12.
像保持体12周辺の、現像部材18Aの配設位置より像保持体12の回転方向下流側には、転写装置31が設けられている。転写装置31は、転写部材20と電源30とを含んで構成されている。転写部材20は、円柱状とされており、像保持体12との間で記録媒体30Aを挟んで搬送する。転写部材20には、転写部材20に転写電圧を印加する電源30が電気的に接続されている。この電源30は、制御部36にも電気的に接続されている。 A transfer device 31 is provided around the image carrier 12 and downstream of the position where the developing member 18 </ b> A is disposed in the rotation direction of the image carrier 12. The transfer device 31 includes a transfer member 20 and a power supply 30. The transfer member 20 has a cylindrical shape, and is conveyed with the recording medium 30 </ b> A interposed between the transfer member 20 and the image carrier 12. A power supply 30 that applies a transfer voltage to the transfer member 20 is electrically connected to the transfer member 20. The power supply 30 is also electrically connected to the control unit 36.
電源30から転写部材20に、像保持体12上に形成されたトナー像を構成するトナーとは逆極性の転写電圧が印加されると、像保持体12と転写部材20との向かい合う領域(図1中、転写領域32A参照)には、像保持体12上のトナー像を構成する各トナーを静電力により像保持体12から転写部材20側へと移動させる電界強度の電界が形成される。 When a transfer voltage having a polarity opposite to that of the toner constituting the toner image formed on the image carrier 12 is applied from the power supply 30 to the transfer member 20, a region where the image carrier 12 and the transfer member 20 face each other (see FIG. 1 (see the transfer region 32A), an electric field having an electric field strength is formed to move each toner constituting the toner image on the image carrier 12 from the image carrier 12 to the transfer member 20 side by electrostatic force.
記録媒体30Aは、図示を省略する貯留部に貯留されており、この貯留部から図示を省略する複数の搬送部材によって搬送経路34にそって搬送(図1中矢印B方向)され、像保持体12と転写部材20との向かい合う領域である転写領域32Aに到る。該転写領域32Aに到った記録媒体30Aには、転写部材20に転写電圧が印加されることにより該領域に形成された電界によって、像保持体12上のトナー像を構成するトナーが転写される。すなわち、像保持体12表面から記録媒体30Aへのトナーの移動により、記録媒体30A上に、トナー像が転写される。 The recording medium 30A is stored in a storage unit (not shown), and is transported (in the direction of arrow B in FIG. 1) along the transport path 34 by a plurality of transport members (not shown) from the storage unit. 12 reaches a transfer region 32 </ b> A which is a region where the transfer member 20 faces the transfer member 20. The toner constituting the toner image on the image carrier 12 is transferred to the recording medium 30A reaching the transfer area 32A by an electric field formed in the area when a transfer voltage is applied to the transfer member 20. The That is, the toner image is transferred onto the recording medium 30A by the movement of the toner from the surface of the image carrier 12 to the recording medium 30A.
また、この転写部材20から、上述のようにトナー像を構成するトナーとは逆極性の転写電圧が印加されることで、像保持体12の表面が除電されて除電電位(例えば、0V)とされる。 Further, the transfer member 20 is applied with a transfer voltage having a polarity opposite to that of the toner constituting the toner image as described above, so that the surface of the image carrier 12 is neutralized and a neutralization potential (for example, 0 V) is obtained. Is done.
記録媒体30Aの搬送経路34の、上記転写領域32Aより搬送方向下流側には、定着装置26が設けられている。定着装置26は、記録媒体30A上に転写されたトナー像を熱または熱及び圧力によって記録媒体30Aに定着させる。
搬送経路34にそって搬送されて像保持体12と転写部材20との向かい合う領域(転写領域32A)を通過することによりトナー像を転写された記録媒体30Aは、図示を省略する搬送部材によってさらに搬送経路34に沿って定着装置26の設置位置に到り、記録媒体30A上のトナー像の定着が行われる。トナー像の定着によって、形成対象の画像の形成された記録媒体30Aは、図示を省略する複数の搬送部材によって画像形成装置10の外部へと排出される。
A fixing device 26 is provided on the conveyance path 34 of the recording medium 30A downstream of the transfer area 32A in the conveyance direction. The fixing device 26 fixes the toner image transferred onto the recording medium 30A to the recording medium 30A by heat or heat and pressure.
The recording medium 30 </ b> A to which the toner image is transferred by being conveyed along the conveyance path 34 and passing through the area (transfer area 32 </ b> A) where the image carrier 12 and the transfer member 20 face each other is further transferred by a conveyance member (not shown). The fixing device 26 is reached along the conveyance path 34, and the toner image on the recording medium 30A is fixed. By fixing the toner image, the recording medium 30A on which the image to be formed is formed is discharged to the outside of the image forming apparatus 10 by a plurality of conveyance members (not shown).
像保持体12の回転方向(図1中矢印A方向)の、転写領域32Aより像保持体12の回転方向下流側には、清掃部材22が配設されている。 A cleaning member 22 is disposed downstream of the transfer region 32A in the rotation direction of the image carrier 12 in the rotation direction of the image carrier 12 (in the direction of arrow A in FIG. 1).
清掃部材22は、像保持体12上の残留トナーや紙粉等の付着物を除去する。清掃部材22としては、像保持体12に対して線圧10g/cm以上150g/cm以下で接触する板状部材を有する構成が挙げられる。 The cleaning member 22 removes deposits such as residual toner and paper dust on the image carrier 12. Examples of the cleaning member 22 include a configuration having a plate-like member that comes into contact with the image carrier 12 at a linear pressure of 10 g / cm to 150 g / cm.
トナー像を記録媒体30Aに転写すると共に除電電位とされた像保持体12は、清掃部材22によって付着物を除去された後に、再度、帯電装置15によって帯電電位に帯電される。 The image carrier 12 that has transferred the toner image to the recording medium 30 </ b> A and has been set to the charge removal potential is again charged to the charge potential by the charging device 15 after the adhering matter is removed by the cleaning member 22.
上述のようにして、画像形成装置10では、記録媒体30Aに、形成対象の画像が形成される。 As described above, in the image forming apparatus 10, an image to be formed is formed on the recording medium 30A.
なお、本実施の形態の画像形成装置10が、本発明の画像形成装置に相当し、帯電部材14が、本発明の画像形成装置における帯電部材に相当し、潜像形成装置16が、本発明の画像形成装置における潜像形成装置に相当し、現像装置18が、本発明の画像形成装置における現像装置に相当する。また、転写部材20が本発明の画像形成装置の転写部材に相当し、電源30が本発明の画像形成装置の電圧印加装置に相当する。また、制御部36が、本発明の画像形成装置の制御装置に相当する。 The image forming apparatus 10 of the present embodiment corresponds to the image forming apparatus of the present invention, the charging member 14 corresponds to the charging member in the image forming apparatus of the present invention, and the latent image forming apparatus 16 is the present invention. The developing device 18 corresponds to the developing device in the image forming apparatus of the present invention. The transfer member 20 corresponds to the transfer member of the image forming apparatus of the present invention, and the power source 30 corresponds to the voltage applying device of the image forming apparatus of the present invention. The control unit 36 corresponds to a control device of the image forming apparatus of the present invention.
ここで、本実施の形態の画像形成装置10において、記録媒体30Aに画像の形成される画像形成期間には、上述のように、像保持体12は、回転(図1中、矢印A方向)によって、帯電部材14による帯電電位への帯電、潜像形成装置16による露光(静電潜像の形成)、静電潜像のトナーによる現像、及び転写部材20によるトナー像の転写及び除電が行われ、記録媒体30Aに画像が形成される。 Here, in the image forming apparatus 10 of the present embodiment, during the image forming period in which an image is formed on the recording medium 30A, as described above, the image carrier 12 rotates (in the direction of arrow A in FIG. 1). Thus, charging to the charging potential by the charging member 14, exposure by the latent image forming device 16 (formation of an electrostatic latent image), development of the electrostatic latent image with toner, and transfer and neutralization of the toner image by the transfer member 20 are performed. Thus, an image is formed on the recording medium 30A.
詳細には、本実施の形態の画像形成装置10の制御部36は、記録媒体30Aに画像の形成される画像形成期間には、像保持体12を所定の帯電電位VH1(0V以外)に帯電させるように帯電装置15の電源28を制御し、現像部材18Aを該帯電電位VH1との電位差が現像部材18A側のトナーが像保持体12側へ移行する最小電位差P以上となる現像電位Vdeve1に帯電させるように電源32を制御する。さらに、制御部36は、像保持体12と転写部材20との向かい合う領域(転写領域32A)に、像保持体12上に保持されたトナーが記録媒体30A側へ移動する電界が形成され、且つ該電界によって像保持体12の表面が除電されるような、転写電位Rp2(Rp2≠0)とされた転写部材20となるように、電源30から転写部材20へ印加する転写電圧の電圧値を制御する。これによって、像保持体12は、帯電部材14によって帯電電位VH1に帯電され、潜像形成装置16によって静電潜像が形成されて、この静電潜像が現像部材18Aに保持されたトナーによって現像されて、トナー像が記録媒体30Aに転写され、像保持体12が転写部材20によって除電される。 Specifically, the control unit 36 of the image forming apparatus 10 of the present embodiment charges the image carrier 12 to a predetermined charging potential VH1 (other than 0 V) during the image forming period in which an image is formed on the recording medium 30A. The power supply 28 of the charging device 15 is controlled so that the developing member 18A has a developing potential Vdev1 at which the potential difference from the charging potential VH1 is equal to or larger than the minimum potential difference P at which the toner on the developing member 18A side moves to the image carrier 12 side. The power supply 32 is controlled so as to be charged. Further, the control unit 36 forms an electric field in which the toner held on the image carrier 12 moves to the recording medium 30A side in a region (transfer region 32A) where the image carrier 12 and the transfer member 20 face each other. The voltage value of the transfer voltage applied from the power source 30 to the transfer member 20 is set so that the transfer member 20 has a transfer potential Rp2 (Rp2 ≠ 0) such that the surface of the image carrier 12 is neutralized by the electric field. Control. As a result, the image carrier 12 is charged to the charging potential VH1 by the charging member 14, an electrostatic latent image is formed by the latent image forming device 16, and the electrostatic latent image is formed by the toner held on the developing member 18A. The toner image is developed and transferred to the recording medium 30 </ b> A, and the image carrier 12 is neutralized by the transfer member 20.
なお、この画像形成期間に、電源30から転写部材20へ印加される転写電圧の電圧値を第2の電圧値と称して説明する。なお、この第2の電圧値は、0V以外の値である。また、転写電圧は、像保持体12上に形成されたトナー像を構成するトナーと逆極性の電圧である。このため、第2の電圧値の転写電圧とは、画像形成期間に転写部材20に印加される電圧であって、該トナーとは逆極性で、且つ転写部材20の表面が上記転写電位Rp2となる電圧値の電圧である。 The voltage value of the transfer voltage applied from the power supply 30 to the transfer member 20 during this image formation period will be referred to as a second voltage value. The second voltage value is a value other than 0V. The transfer voltage is a voltage having a polarity opposite to that of the toner constituting the toner image formed on the image carrier 12. For this reason, the transfer voltage of the second voltage value is a voltage applied to the transfer member 20 during the image formation period, and has a polarity opposite to that of the toner, and the surface of the transfer member 20 has the transfer potential Rp2. It is the voltage of the voltage value which becomes.
このように、本実施の形態の画像形成装置10では、画像形成期間における像保持体12の表面の除電を、トナー像を記録媒体30Aへ転写する転写部材20によって行っており、像保持体12の表面を除電する専用の除電装置を備えない構成とされている。 As described above, in the image forming apparatus 10 of the present embodiment, the surface of the image carrier 12 is neutralized during the image formation period by the transfer member 20 that transfers the toner image to the recording medium 30A. It is set as the structure which is not equipped with the exclusive static elimination apparatus which neutralizes the surface.
ここで、従来の画像形成装置10では、記録媒体30Aに画像の形成されない非画像形成期間には、図3の線図51A、線図51B、及び線図51Cに示すように、帯電部材14への帯電電圧の印加、現像部材18Aへの現像電圧の印加、及び転写部材20への転写電圧の印加を解除(非画像形成期間は全て0Vとする)することが行われており、画像形成から非画像形成へ切り替えた後に画像形成が再開された時においても、前回の画像形成期間における像保持体12の電位ムラが残存している場合があった。そして、この電位ムラに起因して、形成対象の画像以外の線画像が記録媒体30A上に形成される場合があった。 Here, in the conventional image forming apparatus 10, during the non-image forming period in which no image is formed on the recording medium 30A, as shown in the diagrams 51A, 51B, and 51C in FIG. The application of the charging voltage, the development voltage to the developing member 18A, and the transfer voltage to the transfer member 20 are canceled (all non-image forming periods are set to 0 V). Even when image formation is resumed after switching to non-image formation, potential unevenness of the image carrier 12 may remain in the previous image formation period. In some cases, line images other than the image to be formed are formed on the recording medium 30A due to the potential unevenness.
なお、図3、及び後述する図4は、本実施の形態の画像形成装置10においてトナーがマイナス極性を有するものとして説明したものである。 Note that FIG. 3 and FIG. 4 to be described later are explained assuming that the toner has a negative polarity in the image forming apparatus 10 of the present embodiment.
なお、非画像形成期間とは、記録媒体30Aへの画像形成の行われない期間を示している。この「非画像形成期間」には、潜像形成装置16による画像情報に基づいた光の照射は行われず、記録媒体30Aには画像は形成されない。具体的には、非画像形成期間とは、前回の画像形成(画像形成期間)が終了してから、次の画像形成(画像形成期間)が始まるまでの期間に相当する。詳細には、「画像形成期間」は、画像形成装置10において、制御部36に入力された印刷ジョブに基づいて画像を記録媒体30Aに形成する画像形成処理の行われる期間を示し、「非画像形成期間」は、画像形成装置10において、該画像形成処理のおこなわれない期間を示す。 Note that the non-image forming period indicates a period during which no image is formed on the recording medium 30A. During this “non-image forming period”, light irradiation based on image information by the latent image forming device 16 is not performed, and no image is formed on the recording medium 30A. Specifically, the non-image formation period corresponds to a period from the end of the previous image formation (image formation period) to the start of the next image formation (image formation period). Specifically, the “image forming period” indicates a period during which an image forming process for forming an image on the recording medium 30A based on a print job input to the control unit 36 in the image forming apparatus 10 is performed. The “formation period” indicates a period during which the image forming process is not performed in the image forming apparatus 10.
本実施の形態の画像形成装置10では、該非画像形成期間中に、非画像形成期間から画像形成期間への切替え時まで、少なくとも像保持体12が1回転する期間継続して第1の電圧値の転写電圧を転写部材20に印加し、該非画像形成期間の後に連続する画像形成期間に、該切替え時から連続して上記第2の電圧値の転写電圧を転写部材20に印加するように、制御部36が電源28を制御する。 In the image forming apparatus 10 according to the present embodiment, during the non-image forming period, the first voltage value continues for at least a period in which the image carrier 12 rotates once until the switching from the non-image forming period to the image forming period. The transfer voltage is applied to the transfer member 20, and the transfer voltage having the second voltage value is continuously applied to the transfer member 20 in the image forming period that continues after the non-image forming period. The control unit 36 controls the power supply 28.
この第1の電圧値の転写電圧は、非画像形成期間において、非画像形成期間から画像形成期間への切替え時まで継続して印加される電圧であって、0V以外の値である。また、上述のように、転写電圧は、像保持体12上に形成されたトナー像を構成するトナーと逆極性の電圧である。このため、第1の電圧値の転写電圧とは、非画像形成期間に転写部材20に印加される電圧であって、該トナーとは逆極性で且つ0V以外の電圧値の電圧である。 The transfer voltage of the first voltage value is a voltage that is continuously applied during the non-image forming period until switching from the non-image forming period to the image forming period, and is a value other than 0V. Further, as described above, the transfer voltage is a voltage having a polarity opposite to that of the toner constituting the toner image formed on the image carrier 12. For this reason, the transfer voltage of the first voltage value is a voltage applied to the transfer member 20 during the non-image forming period, and is a voltage having a polarity opposite to that of the toner and a voltage value other than 0V.
非画像形成期間における制御部36の上記の制御によって、図4の線図50Aに示されるように、非画像形成期間42には、電源30から転写部材20に、非画像形成期間42から画像形成期間40への切替え時Pまでの間、少なくとも像保持体12が1回転する期間44、継続して第1の電圧値(図4中、電圧値a参照)の転写電圧が印加される。なお、この非画像形成期間42における第1の電圧値(図4中、電圧値a参照)の印加される期間44は、少なくとも像保持体12が1回転する期間以上であればよく、像保持体12が2回転以上回転する期間であってもよい。すなわち、この非画像形成期間42における第1の電圧値(図4中、電圧値a参照)の印加される期間44は、像保持体12がN回転(Nは、1以上の整数)する期間であればよい。
なお、このN回転のNの値としては、1以上の整数であればよいが、プリント生産性向上や摩耗サイクル数抑制による長寿命化の理由から、1以上5以下が望ましく、1以上2以下がより望ましい。
By the above control of the control unit 36 in the non-image forming period, as shown in a diagram 50A of FIG. 4, in the non-image forming period 42, the image is formed from the power source 30 to the transfer member 20 and from the non-image forming period 42. The transfer voltage of the first voltage value (see voltage value a in FIG. 4) is continuously applied for at least the period 44 in which the image carrier 12 makes one rotation until the switching P to the period 40. The period 44 during which the first voltage value (see voltage value a in FIG. 4) is applied in the non-image forming period 42 may be at least longer than the period during which the image carrier 12 rotates once. It may be a period in which the body 12 rotates two or more times. That is, the period 44 during which the first voltage value (see voltage value a in FIG. 4) is applied in the non-image forming period 42 is a period in which the image carrier 12 rotates N times (N is an integer of 1 or more). If it is.
The N value of the N rotation may be an integer of 1 or more, but is preferably 1 or more and 5 or less for the purpose of improving print productivity or extending the life by suppressing the number of wear cycles. Is more desirable.
そして、この非画像形成期間42の後に連続する画像形成期間40には、この切替え時Pから連続して、第2の電圧値(図4中、電圧値b参照)の転写電圧が、電源30から転写部材20に印加される。 In the image forming period 40 that continues after the non-image forming period 42, the transfer voltage of the second voltage value (see voltage value b in FIG. To the transfer member 20.
このため、非画像形成期間42から画像形成期間40へ切替えられる時には、転写部材20には、像保持体12が少なくとも1回転する期間継続して第1の電圧値の転写電圧が印加され、該第1の電圧値の転写電圧に連続して、第2の電圧値の転写電圧が印加されることとなる。なお、この「連続して」とは、転写電圧が、非画像形成期間42から画像形成期間40に切替えられるときに、一度も解除される(0Vとされる)ことがなく、転写部材20に継続して印加されることを示している。 For this reason, when switching from the non-image forming period 42 to the image forming period 40, the transfer voltage of the first voltage value is continuously applied to the transfer member 20 for a period during which the image carrier 12 rotates at least once. The transfer voltage having the second voltage value is applied continuously to the transfer voltage having the first voltage value. Note that “continuously” means that the transfer voltage is never released (set to 0 V) when the transfer voltage is switched from the non-image forming period 42 to the image forming period 40, and is applied to the transfer member 20. It shows that it is continuously applied.
なお、この非画像形成期間42に印加される転写電圧の電圧値である第1の電圧値(図4中、電圧値a参照)の値は、上記特性を満たせばよく、画像形成期間に転写部材20に印加される転写電圧である第2の電圧値(図4中、電圧値b参照)と同じ電圧値であってもよく、異なる電圧値であってもよい。なお、画像形成装置10において、非画像形成期間42中に、像保持体12の抵抗値(転写抵抗値)を測定するために、転写部材20から像保持体12側に電圧を印加する場合には、この抵抗値の測定に用いる電圧と同じ電圧値(絶対値)を、第1の電圧値として用いてもよい。また、この第1の電圧値の転写電圧の印加時に流れる電流の測定結果により、像保持体12の抵抗値の測定を行ってもよい。こように、第1の電圧値を、像保持体12の抵抗値の測定に用いる電圧の電圧値と同じ値とすることで、画像形成装置10の機械的及び電気的な構成を大幅に変更することなく、図4に示す転写電圧の印加が実行される。 Note that the value of the first voltage value (see voltage value a in FIG. 4), which is the voltage value of the transfer voltage applied during the non-image forming period 42, only needs to satisfy the above characteristics and is transferred during the image forming period. The voltage value may be the same as the second voltage value (see voltage value b in FIG. 4) that is the transfer voltage applied to the member 20, or may be a different voltage value. In the image forming apparatus 10, when a voltage is applied from the transfer member 20 to the image carrier 12 side in order to measure the resistance value (transfer resistance value) of the image carrier 12 during the non-image formation period 42. May use the same voltage value (absolute value) as the voltage used for the measurement of the resistance value as the first voltage value. Further, the resistance value of the image carrier 12 may be measured based on the measurement result of the current that flows when the transfer voltage having the first voltage value is applied. Thus, by making the first voltage value the same value as the voltage value used for measuring the resistance value of the image carrier 12, the mechanical and electrical configuration of the image forming apparatus 10 is significantly changed. Without application, application of the transfer voltage shown in FIG. 4 is executed.
この非画像形成期間42には、制御部36の制御によって、図4の線図50Cに示されるように、電源28から帯電部材14への帯電電圧の印加が解除(0V)される。また、非画像形成期間42には、制御部36の制御によって、図4の線図50Bに示されるように、電源32から現像部材18Aへの現像電圧の印加が解除(0V)される。
そして、画像形成期間40には、制御部36の制御によって、図4の線図50Cに示されるように、電源28から帯電部材14へ帯電電圧が印加され、電源32から現像部材18Aへ現像電圧が印加される。
During the non-image forming period 42, the application of the charging voltage from the power supply 28 to the charging member 14 is canceled (0 V) as shown by a diagram 50C in FIG. Further, during the non-image forming period 42, the application of the developing voltage from the power source 32 to the developing member 18A is canceled (0 V) as shown in the diagram 50B of FIG.
Then, during the image forming period 40, the control unit 36 controls the charging voltage from the power source 28 to the charging member 14 and the developing voltage from the power source 32 to the developing member 18A as shown in a diagram 50C of FIG. Is applied.
以上説明したように、本実施の形態の画像形成装置10では、非画像形成期間42には、帯電電圧の印加が解除されて像保持体12の帯電電位への帯電が行われず、潜像形成装置16による静電潜像の形成も行われず(露光電位とされず)、且つ現像部材18Aの現像電圧の印加も行われないが、該非画像形成期間42中に、非画像形成期間42から画像形成期間40への切替え時Pまで、像保持体12が少なくとも1回転する期間以上継続して第1の電圧値の転写電圧が印加される。このため、該非画像形成期間42における非画像形成期間42から画像形成期間40への切替え時Pまで、像保持体12が少なくとも1回転する期間以上継続して第1の電圧値の転写電圧を印加しない場合に比べて、画像形成期間40の切替え時Pまでに、転写部材20による像保持体12の表面の除電が行われることとなる。そして、非画像形成期間42に転写部材20による除電の行われた状態で、該非画像形成期間42に連続する画像形成期間40には、該切替え時から連続して第2の電圧の転写電圧が転写部材20に印加されて、転写部材20による除電が継続されることとなる。
このため、画像形成装置10において、画像形成から非画像形成へ切り替えた後に画像形成が再開された時においても、前回の画像形成期間における像保持体12の電位ムラの残存が抑制され、この電位ムラに起因する、形成対象の画像以外の線画像の形成が抑制されると考えられる。
As described above, in the image forming apparatus 10 of the present embodiment, in the non-image forming period 42, the application of the charging voltage is canceled and the charging of the image carrier 12 to the charging potential is not performed, so that the latent image is formed. The electrostatic latent image is not formed by the apparatus 16 (the exposure potential is not set), and the developing voltage of the developing member 18A is not applied, but during the non-image forming period 42, the image from the non-image forming period 42 is displayed. The transfer voltage of the first voltage value is continuously applied for a period of at least one rotation of the image carrier 12 until switching P to the formation period 40. For this reason, the transfer voltage of the first voltage value is continuously applied for a period of at least one rotation of the image carrier 12 from the non-image forming period 42 to the image forming period 40 during the non-image forming period 42. As compared with the case where the image forming period 40 is not performed, the surface of the image carrier 12 is neutralized by the transfer member 20 before the switching P of the image forming period 40. Then, in a state in which static elimination has been performed by the transfer member 20 in the non-image forming period 42, the transfer voltage of the second voltage is continuously applied in the image forming period 40 following the non-image forming period 42 from the time of the switching. The charge is applied to the transfer member 20, and the charge removal by the transfer member 20 is continued.
For this reason, even when image formation is resumed after switching from image formation to non-image formation in the image forming apparatus 10, residual potential unevenness of the image carrier 12 during the previous image formation period is suppressed, and this potential is reduced. It is considered that the formation of line images other than the image to be formed due to unevenness is suppressed.
すなわち、本実施の形態の画像形成装置10では、上記の非画像形成期間42における転写電圧の調整が実行されることによって、形成対象の画像以外の線画像の発生が抑制されると考えられる。 That is, in the image forming apparatus 10 of the present embodiment, it is considered that the generation of line images other than the image to be formed is suppressed by executing the adjustment of the transfer voltage in the non-image forming period 42 described above.
なお、以上説明した本実施の形態の画像形成装置10では、帯電部材14は、像保持体12の表面に接触して設けられていてもよいし、非接触で設けられていてもよいものとして説明した。また、電源28から帯電部材14に印加される帯電電圧は、直流電圧に交流電圧を重畳した重畳電圧であってもよいし、直流電圧であってもよいものとして説明した。
しかし、帯電部材14が像保持体12の表面に接触して設けられ、帯電電圧として直流電圧を用いる場合には、像保持体12上の電位ムラに起因する、形成対象の画像以外の線画像の形成の更なる抑制の観点から、画像形成装置10における非画像形成期間42における上記転写電圧の調整に加えて、像保持体12を、支持体60上に、少なくとも電荷発生層65と電荷輸送層66とをこの順に有する構成とし、且つ、この電荷輸送層66を、結着樹脂と、下記一般式(1)で表される構造を有する電荷輸送性材料と、を含んだ構成とすることが望ましい。
In the image forming apparatus 10 of the present embodiment described above, the charging member 14 may be provided in contact with the surface of the image carrier 12 or may be provided in a non-contact manner. explained. Further, the charging voltage applied from the power source 28 to the charging member 14 may be a superimposed voltage obtained by superimposing an AC voltage on a DC voltage, or may be a DC voltage.
However, when the charging member 14 is provided in contact with the surface of the image carrier 12 and a DC voltage is used as the charging voltage, a line image other than the image to be formed due to potential unevenness on the image carrier 12 is obtained. In addition to the adjustment of the transfer voltage in the non-image forming period 42 in the image forming apparatus 10, at least the charge generation layer 65 and the charge transport are provided on the support 60 from the viewpoint of further suppressing the formation of the image. The layer 66 is configured to include the layer 66 in this order, and the charge transporting layer 66 includes a binder resin and a charge transporting material having a structure represented by the following general formula (1). Is desirable.
電荷輸送層66が、下記一般式(1)で表される構造を有する電荷輸送性材料を含んだ構成とされていることで、電荷輸送層66の電荷の移動度が、該材料を用いない場合に比べて大きくなり、転写部材20により除電された後の像保持体12の表面の電位ムラ(以下、除電ムラと称する場合がある)が更に抑制される、と考えられる。 Since the charge transport layer 66 includes a charge transport material having a structure represented by the following general formula (1), the charge mobility of the charge transport layer 66 does not use the material. It is considered that the unevenness of the potential of the surface of the image carrier 12 after being neutralized by the transfer member 20 (hereinafter sometimes referred to as unevenness of neutralization) is further suppressed.
一般式(1)中、R1、R2、R3、R4、R5、及びR6はそれぞれ独立して水素原子、ハロゲン原子、炭素数1以上20以下のアルキル基、炭素数1以上20以下のアルコキシ基、又は、置換もしくは未置換の炭素数6以上30以下のアリール基を表し、隣接する2つの置換基同士が結合して炭化水素環構造を形成してもよい。n及びmはそれぞれ独立して0又は1を表す。 In General Formula (1), R 1 , R 2 , R 3 , R 4 , R 5 , and R 6 are each independently a hydrogen atom, a halogen atom, an alkyl group having 1 to 20 carbon atoms, or 1 or more carbon atoms. It represents an alkoxy group having 20 or less, or a substituted or unsubstituted aryl group having 6 to 30 carbon atoms, and two adjacent substituents may be bonded to form a hydrocarbon ring structure. n and m each independently represents 0 or 1.
なお、機能を損ねない範囲で、上記一般式(1)で表される電荷輸送性材料以外の他の電荷輸送性材料を用いても良い。この他の電荷輸送性材料としては、例えば、2,5−ビス(p−ジエチルアミノフェニル)−1,3,4−オキサジアゾール等のオキサジアゾール誘導体、1,3,5−トリフェニル−ピラゾリン、1−[ピリジル−(2)]−3−(p−ジエチルアミノスチリル)−5−(p−ジエチルアミノスチリル)ピラゾリン等のピラゾリン誘導体、トリフェニルアミン、トリ(p−メチルフェニル)アミニル−4−アミン、ジベンジルアニリン等の芳香族第3級アミノ化合物、N,N’−ビス(3−メチルフェニル)−N,N’−ジフェニルベンジジン等の芳香族第3級ジアミノ化合物、3−(4’−ジメチルアミノフェニル)−5,6−ジ−(4’−メトキシフェニル)−1,2,4−トリアジン等の1,2,4−トリアジン誘導体、4−ジエチルアミノベンズアルデヒド−1,1−ジフェニルヒドラゾン等のヒドラゾン誘導体、2−フェニル−4−スチリル−キナゾリン等のキナゾリン誘導体、6−ヒドロキシ−2,3−ジ(p−メトキシフェニル)ベンゾフラン等のベンゾフラン誘導体、p−(2,2−ジフェニルビニル)−N,N−ジフェニルアニリン等のα−スチルベン誘導体、エナミン誘導体、ブタジエン化合物、N−エチルカルバゾール等のカルバゾール誘導体、ポリ−N−ビニルカルバゾールおよびその誘導体などの正孔輸送物質、クロラニル、ブロアントラキノン等のキノン系化合物、テトラアノキノジメタン系化合物、2,4,7−トリニトロフルオレノン、2,4,5,7−テトラニトロ−9−フルオレノン等のフルオレノン化合物、キサントン系化合物、チオフェン化合物等の電子輸送物質、および上記した化合物からなる基を主鎖または側鎖に有する重合体などが挙げられる。これらの電荷輸送材料は、1種を単独で又は2種以上を組み合わせて使用すればよい。なお、電荷輸送層66における電荷輸送材料と結着樹脂との含有量の比(質量比)は10:1以上1:5以下が挙げられる。 It should be noted that other charge transport materials other than the charge transport material represented by the general formula (1) may be used as long as the function is not impaired. Other charge transport materials include, for example, oxadiazole derivatives such as 2,5-bis (p-diethylaminophenyl) -1,3,4-oxadiazole, 1,3,5-triphenyl-pyrazoline 1- [pyridyl- (2)]-3- (p-diethylaminostyryl) -5- (p-diethylaminostyryl) pyrazoline and other pyrazoline derivatives, triphenylamine, tri (p-methylphenyl) aminyl-4-amine Aromatic tertiary amino compounds such as dibenzylaniline, aromatic tertiary diamino compounds such as N, N′-bis (3-methylphenyl) -N, N′-diphenylbenzidine, 3- (4′- 1,2,4-triazine derivatives such as dimethylaminophenyl) -5,6-di- (4′-methoxyphenyl) -1,2,4-triazine, 4-diethy Hydrazone derivatives such as aminobenzaldehyde-1,1-diphenylhydrazone, quinazoline derivatives such as 2-phenyl-4-styryl-quinazoline, benzofuran derivatives such as 6-hydroxy-2,3-di (p-methoxyphenyl) benzofuran, p Α-stilbene derivatives such as-(2,2-diphenylvinyl) -N, N-diphenylaniline, enamine derivatives, butadiene compounds, carbazole derivatives such as N-ethylcarbazole, poly-N-vinylcarbazole and derivatives thereof Pore transport materials, quinone compounds such as chloranil and broanthraquinone, tetraanoquinodimethane compounds, fluorenone compounds such as 2,4,7-trinitrofluorenone, 2,4,5,7-tetranitro-9-fluorenone, Xanthone compounds, thiophene And an electron transporting material such as a polymer, and a polymer having a group composed of the above-described compound in the main chain or side chain. These charge transport materials may be used alone or in combination of two or more. In addition, the ratio (mass ratio) of the content of the charge transport material and the binder resin in the charge transport layer 66 is 10: 1 or more and 1: 5 or less.
この電荷輸送層66に含まれる結着樹脂としては、アクリル樹脂、ポリアリレート等のポリエステル樹脂、ポリカーボネート樹脂、ポリスチレン、アクリロニトリル−スチレン共重合体、アクリロニトリル−ブタジエン共重合体、ポリビニルブチラール等のポリビニルアセタール樹脂、ポリケトン樹脂、ポリビニルケトン樹脂、ポリスチレン樹脂、ポリスルホン、ポリアクリルアミド、ポリアミド、塩素ゴム等の絶縁性樹脂、およびポリビニルカルバゾール、ポリビニルアントラセン、ポリビニルピレン等の有機光導電性ポリマー等があげられる。 Examples of the binder resin contained in the charge transport layer 66 include acrylic resins, polyester resins such as polyarylate, polycarbonate resins, polystyrene, acrylonitrile-styrene copolymers, acrylonitrile-butadiene copolymers, and polyvinyl acetal resins such as polyvinyl butyral. Insulating resins such as polyketone resins, polyvinyl ketone resins, polystyrene resins, polysulfones, polyacrylamides, polyamides, and chlorinated rubbers, and organic photoconductive polymers such as polyvinyl carbazole, polyvinyl anthracene, and polyvinyl pyrene.
中でも、像保持体12の除電ムラを更に抑制する観点から、結着樹脂としては、下記一般式(2)で表される構造単位を含むことが望ましい。 Among these, it is desirable that the binder resin includes a structural unit represented by the following general formula (2) from the viewpoint of further suppressing the charge removal unevenness of the image carrier 12.
一般式(2)中、R7及びR8は、各々独立にハロゲン原子、炭素数1以上6以下のアルキル基、炭素数5以上7以下のシクロアルキル基、又は炭素数6以上12以下のアリール基であり、e,fは、各々独立に0以上4以下の整数を表す。 In General Formula (2), R 7 and R 8 are each independently a halogen atom, an alkyl group having 1 to 6 carbon atoms, a cycloalkyl group having 5 to 7 carbon atoms, or an aryl having 6 to 12 carbon atoms. E and f each independently represents an integer of 0 or more and 4 or less.
このように、電荷輸送層66の結着樹脂が、上記一般式(2)で表される構造単位を含む構成とされていることで、電荷輸送層66の電荷の移動度が該材料を用いない場合に比べて更に大きくなり、また、該移動度の環境による変動も抑制されると考えられる。
このため、転写部材20による除電効果が更に向上する、と考えられる。
As described above, since the binder resin of the charge transport layer 66 includes the structural unit represented by the general formula (2), the charge mobility of the charge transport layer 66 uses the material. It is considered that the mobility is further increased as compared with the case where the mobility is not present, and fluctuations in the mobility due to the environment are suppressed.
For this reason, it is thought that the static elimination effect by the transfer member 20 further improves.
また更に、像保持体12の除電ムラの更なる抑制の観点から、電荷輸送層66に含まれる結着樹脂は、上記一般式(2)で表される構造単位と、下記一般式(3)で表される構造単位と、を有する共重合体を含むことが望ましい。 Furthermore, from the viewpoint of further suppressing unevenness in static elimination of the image carrier 12, the binder resin contained in the charge transport layer 66 includes a structural unit represented by the above general formula (2) and the following general formula (3). It is desirable to include a copolymer having a structural unit represented by:
一般式(3)中、R9及びR10は、各々独立にハロゲン原子、炭素数1以上6以下のアルキル基、炭素数5以上7以下のシクロアルキル基、又は炭素数6以上12以下のアリール基であり、g,hは、各々独立に0以上4以下の整数を表す。Xは、−CR11R12−(但し、R11及びR12は、各々独立に水素原子、トリフルオロメチル基、炭素数1以上6以下のアルキル基、又は炭素数6以上12以下のアリール基のいずれかを表す。)、炭素数5以上11以下の1,1−シクロアルキレン基、炭素数2以上10以下のα,ω−アルキレン基、−O−、−S−、−SO−、または−SO2−を表す。 In general formula (3), R 9 and R 10 are each independently a halogen atom, an alkyl group having 1 to 6 carbon atoms, a cycloalkyl group having 5 to 7 carbon atoms, or an aryl having 6 to 12 carbon atoms. And g and h each independently represent an integer of 0 or more and 4 or less. X is —CR 11 R 12 — (wherein R 11 and R 12 are each independently a hydrogen atom, a trifluoromethyl group, an alkyl group having 1 to 6 carbon atoms, or an aryl group having 6 to 12 carbon atoms) Or a 1,1-cycloalkylene group having 5 to 11 carbon atoms, an α, ω-alkylene group having 2 to 10 carbon atoms, —O—, —S—, —SO—, or -SO 2 - represents a.
上記の一般式(2)で表される構造単位と、上記の一般式(3)で表される構造単位と、を有する共重合体の共重合比(下記具体例におけるm:n比に相当)は、例えば、m:n=95:5以上5:95以下の範囲、50:50以上5:95以下の範囲、30:70以上10:90以下の範囲が挙げられる。 Copolymerization ratio of a copolymer having the structural unit represented by the above general formula (2) and the structural unit represented by the above general formula (3) (corresponding to the m: n ratio in the following specific examples) ) Includes, for example, m: n = 95: 5 to 5:95, 50:50 to 5:95, and 30:70 to 10:90.
上記の一般式(2)で表される構造単位と、上記の一般式(3)で表される構造単位と、を有する共重合体の具体例としては、以下の構造式(A1)〜構造式(A3)が挙げられるが、これらに限定されるものではない。 Specific examples of the copolymer having the structural unit represented by the general formula (2) and the structural unit represented by the general formula (3) include the following structural formula (A1) to structure: A formula (A3) is mentioned, but it is not limited to these.
なお、機能を損ねない範囲で、上記一般式(2)で表される構造単位や、上記一般式(2)で表される構造単位と上記一般式(3)で表される構造単位とを有する共重合体を含む結着樹脂以外の他の結着樹脂を用いてもよい。当該他の結着樹脂としては、例えば、ビスフェノールAタイプあるいはビスフェノールZタイプ等のポリカーボネート樹脂、アクリル樹脂、メタクリル樹脂、ポリアリレート樹脂、ポリエステル樹脂、ポリ塩化ビニル樹脂、ポリスチレン樹脂、アクリロニトリル−スチレン共重合体樹脂、アクリロニトリル−ブタジエン共重合体樹脂、ポリビニルアセテート樹脂、ポリビニルホルマール樹脂、ポリスルホン樹脂、スチレン−ブタジエン共重合体樹脂、塩化ビニリデン−アクリルニトリル共重合体樹脂、塩化ビニル−酢酸ビニル−無水マレイン酸樹脂、シリコーン樹脂、フェノール−ホルムアルデヒド樹脂、ポリアクリルアミド樹脂、ポリアミド樹脂、塩素ゴム等の絶縁性樹脂、及びポリビニルカルバゾール、ポリビニルアントラセン、ポリビニルピレン等の有機光導電性ポリマー等が挙げられる。これらの結着樹脂は、単独又は2種以上混合して用いてもよい。 In addition, the structural unit represented by the general formula (2), the structural unit represented by the general formula (2), and the structural unit represented by the general formula (3) within a range that does not impair the function. A binder resin other than the binder resin containing the copolymer may be used. Examples of the other binder resin include polycarbonate resin such as bisphenol A type or bisphenol Z type, acrylic resin, methacrylic resin, polyarylate resin, polyester resin, polyvinyl chloride resin, polystyrene resin, acrylonitrile-styrene copolymer. Resin, acrylonitrile-butadiene copolymer resin, polyvinyl acetate resin, polyvinyl formal resin, polysulfone resin, styrene-butadiene copolymer resin, vinylidene chloride-acrylonitrile copolymer resin, vinyl chloride-vinyl acetate-maleic anhydride resin, Insulating resins such as silicone resin, phenol-formaldehyde resin, polyacrylamide resin, polyamide resin, chlorinated rubber, and polyvinylcarbazole, polyvinylanthracene, polyvinyl chloride Organic photoconductive polymers such as Rupiren like. These binder resins may be used alone or in combination of two or more.
なお、電荷輸送層66は、上記の構成材料を溶剤に加えた塗布液を用いて形成すればよい。 The charge transport layer 66 may be formed using a coating liquid in which the above constituent materials are added to a solvent.
ここで、帯電部材14を、像保持体12の表面に接触して配置し(所謂、接触帯電方式)、電源28から直流の帯電電圧が印加されることで、像保持体12を帯電させる場合には、上記非画像形成期間42における転写電圧の調整に加えて、電荷輸送層66を、少なくとも上記一般式(1)で表される構造を有する電荷輸送性材料を含んだ構成とし、且つ像保持体12の表面電位の絶対値Vhと、像保持体12の表面電位の絶対値Vinと、厚みT(μm)と、の画像形成期間における関係が、少なくとも下記第1の条件のときに、式(A) 7T+50≦Vh−Vinを満たす関係であることが望ましい。 Here, the charging member 14 is disposed in contact with the surface of the image carrier 12 (so-called contact charging method), and the image carrier 12 is charged by applying a DC charging voltage from the power supply 28. In addition to the adjustment of the transfer voltage in the non-image forming period 42, the charge transport layer 66 includes at least a charge transport material having a structure represented by the general formula (1), and an image. When the relationship between the absolute value Vh of the surface potential of the holder 12, the absolute value Vin of the surface potential of the image holder 12, and the thickness T (μm) in the image formation period is at least the following first condition: It is desirable that the relationship satisfy the formula (A) 7T + 50 ≦ Vh−Vin.
なお、上記「像保持体12の表面電位の絶対値Vin」とは、転写部材20によって像保持体12上のトナー像が記録媒体30Aへ転写された後で且つ帯電部材14によって帯電される前の像保持体12の表面電位の絶対値を示している。すなわち、表面電位の絶対値Vinとは、像保持体12の表面における、帯電部材14によって帯電される領域より像保持体12の回転方向上流側で、且つ転写部材20によって転写される領域より像保持体12の回転方向下流側の領域の、表面電位の絶対値を示している。さらに、詳細には、表面電位の絶対値Vinとは、像保持体12の表面における、帯電部材14によって帯電される領域より像保持体12の回転方向上流側で、且つ清掃部材22によって清掃される領域より像保持体12の回転方向下流側の領域の表面電位の絶対値を示している。 The “absolute value Vin of the surface potential of the image carrier 12” is the value after the toner image on the image carrier 12 is transferred to the recording medium 30A by the transfer member 20 and before being charged by the charging member 14. The absolute value of the surface potential of the image carrier 12 is shown. That is, the absolute value Vin of the surface potential is an image on the surface of the image carrier 12 upstream of the region charged by the charging member 14 in the rotation direction of the image carrier 12 and from the region transferred by the transfer member 20. The absolute value of the surface potential of the region downstream of the holder 12 in the rotation direction is shown. More specifically, the absolute value Vin of the surface potential is cleaned by the cleaning member 22 on the surface of the image carrier 12 upstream of the region charged by the charging member 14 in the rotation direction of the image carrier 12. The absolute value of the surface potential of the area downstream of the image holding body 12 in the rotation direction of the image holding area 12 is shown.
また、上記「像保持体12の表面電位の絶対値Vh」とは、帯電部材14によって帯電された後で且つ潜像形成装置16によって静電潜像が形成される前の像保持体12の表面電位の絶対値を示している。すなわち、表面電位の絶対値Vhとは、像保持体12の表面における、帯電部材14よって帯電される領域より像保持体12の回転方向下流側で、且つ潜像形成装置16によって静電潜像の形成される領域より像保持体12の回転方向上流側の領域の表面電位の絶対値を示している。 Further, the “absolute value Vh of the surface potential of the image carrier 12” means that the image carrier 12 is charged by the charging member 14 and before the electrostatic latent image is formed by the latent image forming device 16. The absolute value of the surface potential is shown. That is, the absolute value Vh of the surface potential is the electrostatic latent image formed by the latent image forming device 16 on the surface of the image carrier 12 on the downstream side in the rotation direction of the image carrier 12 from the region charged by the charging member 14. The absolute value of the surface potential of the region upstream of the image carrier 12 in the rotation direction from the region where the image is formed is shown.
なお、上記式(A)中における、表面電位の絶対値Vin及び表面電位の絶対値Vhの各々は、上記各々の領域において、像保持体12の幅方向(回転軸方向)の一端側から他端側に向かって10mm毎に、像保持体12の周方向1周分について、表面電位を測定した平均値の絶対値を示している。この各測定領域における表面電位の測定は、表面電位計(例えば、トレック社製、トレック334)を用いて、測定対象の領域に表面電位プローブを設けて(像保持体12の表面から1mm離れた位置)表面電位を測定した測定結果を読取ることによって得られる。 In the above formula (A), the absolute value Vin of the surface potential and the absolute value Vh of the surface potential are different from one end side in the width direction (rotation axis direction) of the image carrier 12 in each of the above regions. The absolute value of the average value obtained by measuring the surface potential is shown for one round in the circumferential direction of the image carrier 12 every 10 mm toward the end side. For the measurement of the surface potential in each measurement region, a surface potential probe (for example, Trek 334, manufactured by Trek) was used to provide a surface potential probe in the measurement target region (1 mm away from the surface of the image carrier 12). Position) Obtained by reading the measurement result of measuring the surface potential.
また、上記厚みT(μm)とは、像保持体12における、電荷輸送層66の厚みと、該電荷輸送層66より表面側に設けられた層(例えば、図示を省略する保護層)と、の厚みの合計の厚みの平均値を示している。この厚みの測定は、像保持体12の断面図を観察し、像保持体12の幅方向の一端側から他端側に向かって10mm毎に、像保持体12の周方向1周分について、測定した測定結果の平均値を求めることによって得られる。 The thickness T (μm) is the thickness of the charge transport layer 66 in the image carrier 12 and a layer (for example, a protective layer not shown) provided on the surface side of the charge transport layer 66. The average value of the total thickness is shown. This thickness measurement is performed by observing a cross-sectional view of the image carrier 12 and for every 10 mm in the circumferential direction of the image carrier 12 from one end side in the width direction of the image carrier 12 toward the other end side. It is obtained by calculating the average value of the measured measurement results.
また、上記第1の条件とは、上記式(A)が成り立つときの条件を示しており、具体的には、電荷輸送層66における、上記一般式(1)で表される構造を有する電荷輸送性材料の含有量が8質量%以上50質量%以下であり、優れた電荷輸送能を示し、かつ均一帯電を妨げる欠陥サイトの量が少ないこと、および長期に渡り良好な画像を維持するために不可欠な表層の機械強度の低下を引き起こさない範囲の含有量であることを示している。 The first condition indicates a condition when the above formula (A) is satisfied. Specifically, the charge transport layer 66 has a charge represented by the above general formula (1). The content of the transportable material is 8% by mass or more and 50% by mass or less, exhibits excellent charge transporting ability, has a small amount of defect sites that prevent uniform charging, and maintains a good image over a long period of time. This indicates that the content is in a range that does not cause a decrease in mechanical strength of the surface layer, which is indispensable for the surface layer.
なお、上記第1の条件下において、上記式(A)の関係が満たされるように調整するためには、非画像形成期間42において、転写部材20に印加する転写電圧の第1の電圧値の値を、像保持体12の構成や狙いとする帯電電位に応じて調整すればよい。 In order to adjust the relationship of the above formula (A) to be satisfied under the first condition, the first voltage value of the transfer voltage applied to the transfer member 20 in the non-image forming period 42 is set. The value may be adjusted according to the configuration of the image carrier 12 and the target charging potential.
ここで、像保持体12においては、電荷輸送層66の厚みと、該電荷輸送層66より表面側に設けられた層と、の合計の厚みT(μm)が大きくなるほど、均一帯電を妨げる欠陥サイトの生成量が大きくなるため、形成対象の画像以外の線画像の発生が生じやすくなると考えられる。 Here, in the image carrier 12, as the total thickness T (μm) of the thickness of the charge transport layer 66 and the layer provided on the surface side of the charge transport layer 66 is larger, the defect that hinders uniform charging. Since the amount of site generation increases, it is considered that line images other than the image to be formed are likely to occur.
また、帯電部材14を像保持体12の表面に接触して配置し(所謂、接触帯電方式)、電源28から直流の帯電電圧が印加されることで、像保持体12を帯電させる場合には、帯電部材14の帯電電位が不均一となる場合があり、結果的に、像保持体12における、帯電部材14によって帯電された領域の表面電位に、像保持体12の回転軸方向に電位ムラが生じると考えられる。そして、この像保持体12の表面電位の電位ムラは、特に、温度や湿度等の環境変化によって、特に発生しやすく、この電位ムラに起因して、形成対象の画像以外の線画像が記録媒体30A上に形成されると考えられる。 Further, when the charging member 14 is disposed in contact with the surface of the image carrier 12 (so-called contact charging method) and a DC charging voltage is applied from the power source 28, the image carrier 12 is charged. As a result, the charging potential of the charging member 14 may become non-uniform. As a result, the surface potential of the area of the image holding member 12 charged by the charging member 14 becomes uneven in the direction of the rotation axis of the image holding member 12. Is considered to occur. The potential unevenness of the surface potential of the image carrier 12 is particularly likely to occur due to environmental changes such as temperature and humidity, and line images other than the image to be formed are recorded on the recording medium due to the potential unevenness. It is thought that it is formed on 30A.
特に、従来の画像形成装置のように、記録媒体30Aに画像の形成されない非画像形成期間には、図3の線図51A、線図51B、及び線図51Cに示すように、帯電部材14への帯電電圧の印加の解除、現像部材18Aへの現像電圧の印加の解除、及び転写部材20への転写電圧の印加を解除(非画像形成期間は全て0Vとする)が行われると、非画像形成期間42から画像形成期間40に切替えられた直後の該画像形成期間40に、帯電部材14によって像保持体12の表面電位が乱されて、像保持体12の電位ムラが増加し、形成対象の画像以外の線画像の発生が顕著となると考えられる。 In particular, during the non-image forming period in which no image is formed on the recording medium 30A as in the conventional image forming apparatus, as shown in the diagram 51A, the diagram 51B, and the diagram 51C in FIG. When the application of the charging voltage is canceled, the application of the developing voltage to the developing member 18A is canceled, and the application of the transfer voltage to the transfer member 20 is canceled (all non-image forming periods are set to 0 V), In the image forming period 40 immediately after switching from the forming period 42 to the image forming period 40, the surface potential of the image carrier 12 is disturbed by the charging member 14, the potential unevenness of the image carrier 12 increases, and the object to be formed It is considered that the generation of line images other than the above image becomes remarkable.
そこで、帯電部材14を像保持体12の表面に接触して配置し、電源28から直流の帯電電圧が印加されることで像保持体12を帯電させる場合には、上記像保持体12の表面電位の絶対値Vhと、像保持体12の表面電位の絶対値Vinと、厚みT(μm)と、の関係が、少なくとも上記第1の条件のときに、式(A) 7T+50≦Vh−Vinを満たす関係であれば、更に、形成対象の画像以外の線画像の発生が抑制されると考えられる。 Therefore, when the charging member 14 is disposed in contact with the surface of the image carrier 12 and the image carrier 12 is charged by applying a DC charging voltage from the power supply 28, the surface of the image carrier 12 is used. When the relationship between the absolute value Vh of the potential, the absolute value Vin of the surface potential of the image carrier 12 and the thickness T (μm) is at least the first condition, the formula (A) 7T + 50 ≦ Vh−Vin If the relationship satisfies the above, generation of line images other than the image to be formed is further suppressed.
以下、本実施の形態の画像形成装置を実施例によって具体的に説明するが、これらの実施例によって限定されるものではない。また、以下において特に指定のない場合「部」は「質量部」を表し、「%」は「質量%」を表す。
なお、以下に示す実施例中、接触帯電方式であり、且つ、帯電電圧が直流である以外の態様は、参考例に該当する。
Hereinafter, the image forming apparatus of the present embodiment will be specifically described with reference to examples, but the present invention is not limited to these examples. Further, unless otherwise specified, “part” represents “part by mass” and “%” represents “mass%”.
In the following examples, aspects other than the contact charging method and the charging voltage being direct current correspond to reference examples.
<像保持体A1〜像保持体Dの作製>
−像保持体A1の作製−
酸化亜鉛(平均粒子径:70nm、テイカ社製、比表面積値:15m2/g)100質量部をメタノール500質量部と攪拌混合し、シランカップリング剤として、KBM603(信越化学社製)1.25質量部を添加し、2時間攪拌した。その後、メタノールを減圧蒸留にて留去し、120℃で3時間焼き付けを行い、シランカップリング剤表面処理酸化亜鉛微粒子を得た。
<Preparation of image carrier A1 to image carrier D>
-Production of image carrier A1-
100 parts by mass of zinc oxide (average particle size: 70 nm, manufactured by Teica, specific surface area value: 15 m 2 / g) is stirred and mixed with 500 parts by mass of methanol, and KBM603 (manufactured by Shin-Etsu Chemical Co., Ltd.) is used as a silane coupling agent. 25 parts by mass was added and stirred for 2 hours. Thereafter, methanol was distilled off under reduced pressure, and baking was performed at 120 ° C. for 3 hours to obtain silane coupling agent surface-treated zinc oxide fine particles.
前記表面処理を施した酸化亜鉛微粒子60質量部と、アリザリン0.6質量部と、硬化剤としてブロック化イソシアネート(スミジュール3173、住友バイエルンウレタン社製)13.5質量部と、ブチラール樹脂(BM−1、積水化学社製)15質量部とを、メチルエチルケトン85質量部に溶解した溶液38質量部と、メチルエチルケトン25質量部とを混合し、直径1mmのガラスビーズを用いてサンドミルにて4時間の分散を行い、分散液を得た。得られた分散液に、触媒としてジオクチルスズジラウレート0.005質量部と、シリコーン樹脂粒子(トスパール145、GE東芝シリコーン社製)4.0質量部とを添加し、下引層形成用塗布液を得た。この塗布液を、浸漬塗布法にて直径30mmのアルミニウム基材上に塗布し、180℃、40分の乾燥硬化を行い厚さ25μmの下引層を得た。 60 parts by mass of the zinc oxide fine particles subjected to the surface treatment, 0.6 parts by mass of alizarin, 13.5 parts by mass of blocked isocyanate (Sumidule 3173, manufactured by Sumitomo Bayern Urethane Co., Ltd.) as a curing agent, and butyral resin (BM -1, manufactured by Sekisui Chemical Co., Ltd.) 15 parts by mass of 38 parts by mass of a solution obtained by dissolving 85 parts by mass of methyl ethyl ketone and 25 parts by mass of methyl ethyl ketone, and 4 hours in a sand mill using glass beads having a diameter of 1 mm. Dispersion was performed to obtain a dispersion. To the obtained dispersion, 0.005 parts by mass of dioctyltin dilaurate and 4.0 parts by mass of silicone resin particles (Tospearl 145, manufactured by GE Toshiba Silicone) are added as a catalyst, and a coating liquid for forming an undercoat layer is added. Obtained. This coating solution was applied on an aluminum substrate having a diameter of 30 mm by a dip coating method, followed by drying and curing at 180 ° C. for 40 minutes to obtain an undercoat layer having a thickness of 25 μm.
次に、電荷発生材料として、CuKα特性X線に対するブラッグ角(2θ±0.2゜)の少なくとも7.4゜、16.6゜、25.5゜及び28.3゜に強い回折ピークを有するクロロガリウムフタロシアニン結晶15質量部、塩化ビニル−酢酸ビニル共重合体樹脂(VMCH、日本ユニオンカーバイト社製)10質量部およびn−ブチルアルコール300質量部からなる混合物を、直径1mmのガラスビーズを用いてサンドミルにて4時間分散して電荷発生層形成用の塗布液を得た。この塗布液を前記下引層上に浸漬塗布し、乾燥して、厚みが0.2μmの電荷発生層を得た。 Next, as a charge generation material, it has strong diffraction peaks at Bragg angles (2θ ± 0.2 °) with respect to CuKα characteristic X-rays of at least 7.4 °, 16.6 °, 25.5 ° and 28.3 °. Using a glass bead having a diameter of 1 mm, a mixture of 15 parts by mass of chlorogallium phthalocyanine crystal, 10 parts by mass of vinyl chloride-vinyl acetate copolymer resin (VMCH, manufactured by Nippon Union Carbide) and 300 parts by mass of n-butyl alcohol was used. Then, it was dispersed in a sand mill for 4 hours to obtain a coating solution for forming a charge generation layer. This coating solution was dip-coated on the undercoat layer and dried to obtain a charge generation layer having a thickness of 0.2 μm.
次に、4フッ化エチレン樹脂粒子8質量部(平均粒径:0.2μm)と、フッ化アルキル基含有メタクリルコポリマー(重量平均分子量30000)0.01質量部とを、テトラヒドロフラン4質量部、トルエン1質量部とともに20℃の液温に保ち、48時間攪拌混合し、4フッ化エチレン樹脂粒子懸濁液Aを得た。 Next, 8 parts by mass of tetrafluoroethylene resin particles (average particle size: 0.2 μm) and 0.01 parts by mass of a fluorinated alkyl group-containing methacrylic copolymer (weight average molecular weight 30000), 4 parts by mass of tetrahydrofuran, toluene The mixture was kept at a liquid temperature of 20 ° C. together with 1 part by mass and stirred for 48 hours to obtain a tetrafluoroethylene resin particle suspension A.
次に、電荷輸送物質として下記構造式(1)(一般式(1)において、n=1、m=1、R1、R2、R3、R4、R5、及びR6が全てHのもの)を持つ化合物である、トリス[4−(4,4−ジフェニル−1,3−ブタジエニル)フェニル]アミンを4質量部、結着樹脂としてビスフェノールZ型ポリカーボネート樹脂(粘度平均分子量:40000)6質量部、酸化防止剤として2,6−ジ−t−ブチル−4−メチルフェノール0.1質量部を混合して、テトラヒドロフラン24質量部及びトルエン11質量部を混合溶解して、混合溶解液Bを得た。 Next, as a charge transport material, the following structural formula (1) (in the general formula (1), n = 1, m = 1, R 1 , R 2 , R 3 , R 4 , R 5 , and R 6 are all H 4 parts by weight of tris [4- (4,4-diphenyl-1,3-butadienyl) phenyl] amine, a compound having a bisphenol Z-type polycarbonate resin (viscosity average molecular weight: 40000) 6 parts by mass, 0.1 part by mass of 2,6-di-t-butyl-4-methylphenol as an antioxidant are mixed, 24 parts by mass of tetrahydrofuran and 11 parts by mass of toluene are mixed and dissolved, and mixed solution B was obtained.
このB液に前記A液を加えて攪拌混合した後、微細な流路を持つ貫通式チャンバーを装着した高圧ホモジナイザー(吉田機械興行株式会社製)を用いて、500kgf/cm2まで昇圧しての分散処理を6回繰り返した液に、フッ素変性シリコーンオイル(商品名:FL−100 信越シリコーン社製)を5ppm添加し、十分に撹拌して電荷輸送層形成用塗布液を得た。この塗布液Cを電荷発生層上に、28μmの厚みとなるように塗布して135℃で25分間乾燥し、厚さが28μmの電荷輸送層を形成し、目的の電子写真感光体を得た。このようにして得た電子写真感光体を像保持体A1とした。なお、この厚みの測定は、上述した方法を用いて行った。以下、同様とする。 After the A liquid was added to the B liquid and stirred and mixed, the pressure was increased to 500 kgf / cm 2 using a high-pressure homogenizer (manufactured by Yoshida Kikai Kogyo Co., Ltd.) equipped with a through-type chamber having a fine flow path. 5 ppm of fluorine-modified silicone oil (trade name: FL-100 manufactured by Shin-Etsu Silicone Co., Ltd.) was added to the solution obtained by repeating the dispersion treatment six times, and the mixture was sufficiently stirred to obtain a coating solution for forming a charge transport layer. This coating solution C was applied on the charge generation layer so as to have a thickness of 28 μm, and dried at 135 ° C. for 25 minutes to form a charge transport layer having a thickness of 28 μm. Thus, an intended electrophotographic photosensitive member was obtained. . The electrophotographic photoreceptor thus obtained was designated as an image carrier A1. The thickness was measured using the method described above. The same shall apply hereinafter.
―像保持体A2の作製―
上記像保持体A1の作製において、塗布液Cの塗布量を、12μmの厚みとなるように塗布することによって、厚さが12μmの電荷輸送層を形成した以外は、像保持体A1と同じ条件及び製法で像保持体A2を作製した。
-Production of image carrier A2-
In the production of the image carrier A1, the same conditions as those for the image carrier A1 except that the charge transport layer having a thickness of 12 μm was formed by coating the coating solution C so that the coating liquid C had a thickness of 12 μm. And image carrier A2 was produced by the manufacturing method.
―像保持体A3の作製―
上記像保持体A1の作製において、塗布液Cの塗布量を、40μmの厚みとなるように塗布することによって、厚さが40μmの電荷輸送層を形成した以外は、像保持体A1と同じ条件及び製法で像保持体A3を作製した。
-Production of image carrier A3-
In the production of the image carrier A1, the same conditions as in the image carrier A1 except that the charge transport layer having a thickness of 40 μm was formed by coating the coating solution C so that the coating amount was 40 μm. And image carrier A3 was produced by the manufacturing method.
―像保持体A4の作製―
上記像保持体A1の作製において用いた、電荷輸送性物質である、上記構造式(1)を持つ化合物である、トリス[4−(4,4−ジフェニル−1,3−ブタジエニル)フェニル]アミンを、1.5質量部用いた以外は、像保持体A1と同じ条件及び製法で像保持体A4を作製した。
-Production of image carrier A4-
Tris [4- (4,4-diphenyl-1,3-butadienyl) phenyl] amine, which is a compound having the structural formula (1), which is a charge transporting substance, used in the production of the image carrier A1 The image carrier A4 was produced under the same conditions and production method as the image carrier A1 except that 1.5 parts by mass was used.
―像保持体B1の作製―
上記像保持体A1で、電荷輸送層の結着樹脂として用いたビスフェノールZ型ポリカーボネート樹脂(粘度平均分子量:40000)に代えて、下記構造式(A3)で示され、該構造式(A3)中のmが0.25,nが0.75であるポリカーボネート共重合体6質量部を用いた以外は、像保持体A1と同じ条件及び製法で像保持体B1を作製した。
-Production of image carrier B1-
In the image carrier A1, instead of the bisphenol Z-type polycarbonate resin (viscosity average molecular weight: 40000) used as the binder resin for the charge transport layer, it is represented by the following structural formula (A3), and in the structural formula (A3) An image carrier B1 was produced under the same conditions and production method as the image carrier A1, except that 6 parts by mass of a polycarbonate copolymer having an m of 0.25 and n of 0.75 was used.
―像保持体B2の作製―
上記像保持体B1の作製において、塗布液Cの塗布量を、12μmの厚みとなるように塗布することによって、厚さが12μmの電荷輸送層を形成した以外は、像保持体B1と同じ条件及び製法で像保持体B2を作製した。
-Production of image carrier B2-
In the production of the image carrier B1, the same conditions as the image carrier B1 except that the charge transport layer having a thickness of 12 μm was formed by coating the coating solution C so that the coating liquid C had a thickness of 12 μm. Then, an image carrier B2 was produced by the production method.
―像保持体B3の作製―
上記像保持体B1の作製において、塗布液Cの塗布量を、40μmの厚みとなるように塗布することによって、厚さが40μmの電荷輸送層を形成した以外は、像保持体B1と同じ条件及び製法で像保持体B3を作製した。
-Production of image carrier B3-
In the production of the image carrier B1, the same conditions as those for the image carrier B1 except that a charge transport layer having a thickness of 40 μm was formed by coating the coating solution C so that the coating liquid C had a thickness of 40 μm. Then, an image carrier B3 was produced by the production method.
−像保持体C1の作製−
上記像保持体A1で、電荷輸送層における電荷輸送物質として用いた上記一般式(1)において上記構造式(1)の構造を有する化合物に代えて、N,N’−ビス(3−メチルフェニル)−N,N’−ジフェニルベンジジン2質量部及びN,N’−ビス(3,4−ジメチルフェニル)ビフェニル−4−アミン2質量部を用いた以外は、像保持体A1と同じ条件及び同じ製法を用いて、像保持体C1を作製した。
-Production of image carrier C1-
Instead of the compound having the structure of the structural formula (1) in the general formula (1) used as the charge transport material in the charge transport layer in the image carrier A1, N, N′-bis (3-methylphenyl) ) The same conditions and the same as the image carrier A1 except that 2 parts by mass of -N, N'-diphenylbenzidine and 2 parts by mass of N, N'-bis (3,4-dimethylphenyl) biphenyl-4-amine were used. Image carrier C1 was produced using the production method.
―像保持体C2の作製―
上記像保持体C1の作製において、塗布液Cの塗布量を、12μmの厚みとなるように塗布することによって、厚さが12μmの電荷輸送層を形成した以外は、像保持体C1と同じ条件及び製法で像保持体C2を作製した。
-Production of image carrier C2-
In the production of the image carrier C1, the same conditions as those for the image carrier C1 except that the charge transport layer having a thickness of 12 μm was formed by coating the coating solution C so that the coating liquid C had a thickness of 12 μm. And the image carrier C2 was produced by the production method.
―像保持体C3の作製―
上記像保持体C1の作製において、塗布液Cの塗布量を、40μmの厚みとなるように塗布することによって、厚さが40μmの電荷輸送層を形成した以外は、像保持体C1と同じ条件及び製法で像保持体C3を作製した。
-Production of image carrier C3-
In the production of the image carrier C1, the same conditions as the image carrier C1 except that a charge transport layer having a thickness of 40 μm was formed by coating the coating solution C so that the coating liquid C had a thickness of 40 μm. And the image carrier C3 was produced by the production method.
―像保持体Dの作製―
次に、上記像保持体A1と同様に形成した電荷輸送層上に、下記式(A4)で表される化合物を6部、イソプロピルアルコールを15部、テトラヒドロフランを9部、及び蒸留水を0.9部混合し、それにイオン交換樹脂(アンバーリスト15E)を0.5部加え、室温で攪拌することにより2時間加水分解を行った。さらに、ブチラール樹脂を0.5部、レゾール型フェノール樹脂(PL−2818、群栄化学社製)を4部、ジメチルポリシロキサンを0.2部加え得た保護層形成用塗布液を、電荷輸送層の上にリング型浸漬塗布法により塗布し、室温で30分風乾した後、155℃で35分加熱処理して硬化させ、膜厚約7μmの保護層を形成し、像担時体Dを作製した。
-Production of image carrier D-
Next, 6 parts of a compound represented by the following formula (A4), 15 parts of isopropyl alcohol, 9 parts of tetrahydrofuran, and 0.1 part of distilled water are formed on the charge transport layer formed in the same manner as the image carrier A1. Nine parts were mixed, 0.5 part of ion exchange resin (Amberlyst 15E) was added thereto, and the mixture was stirred at room temperature for hydrolysis for 2 hours. Furthermore, 0.5 parts of butyral resin, 4 parts of resol type phenolic resin (PL-2818, manufactured by Gunei Chemical Co., Ltd.) and 0.2 part of dimethylpolysiloxane were added to form a protective layer-forming coating solution for charge transport. It is coated on the layer by a ring-type dip coating method, air-dried at room temperature for 30 minutes, and then heated and cured at 155 ° C. for 35 minutes to form a protective layer having a thickness of about 7 μm. Produced.
(実施例1〜実施例16,比較例1〜比較例4)
画像形成装置として、DocuCentre 505aにおける帯電部材14へ印加する帯電電圧、現像部材18Aへ印加する現像電圧、及び転写部材20へ印加する転写電圧を制御する制御装置において、図4に示す電圧印加シーケンス等を実行するためのプログラムを実行するように装置を改造した。
そして、搭載する像保持体の種類、非画像形成期間及び画像形成期間において転写部材へ印加する転写電圧の電圧値(第1の電圧値及び第2の電圧値)、非画像形成期間における第1の電圧値の転写電圧の印加時間(像保持体N回転分)、非画像形成期間及び画像形成期間における帯電電圧、帯電電圧の種類、非画像形成期間及び画像形成期間における現像電圧等を、表1に示す組合せとなるように装置を改良して、下記評価試験を行った。
(Examples 1 to 16, Comparative Examples 1 to 4)
In the control apparatus for controlling the charging voltage applied to the charging member 14 in the DocuCenter 505a, the developing voltage applied to the developing member 18A, and the transferring voltage applied to the transfer member 20 as an image forming apparatus, a voltage application sequence shown in FIG. The device was modified to run a program to run.
The type of the image carrier to be mounted, the voltage value of the transfer voltage applied to the transfer member in the non-image forming period and the image forming period (first voltage value and second voltage value), and the first in the non-image forming period. The transfer voltage application time (for the image carrier N rotation), the charging voltage in the non-image forming period and the image forming period, the type of charging voltage, the developing voltage in the non-image forming period and the image forming period, etc. The apparatus was improved so that the combination shown in 1 was obtained, and the following evaluation test was performed.
なお、上記表1中、表面電位の絶対値Vinは、上述したように、像保持体12の表面における、帯電部材14によって帯電される領域より像保持体12の回転方向上流側で、且つ転写部材20によって転写される領域より像保持体12の回転方向下流側の領域の、表面電位の平均値の絶対値を示している。本実施例及び比較例では、この表面電位の絶対値Vinの測定対象領域として、上記の画像形成装置DocuCentre 505aに搭載された像保持体の表面における、帯電部材によって帯電される領域と、清掃部材(クリーニング部材)によって像保持体上の付着物の除去される領域と、の中間の領域を、表面電位の絶対値Vinの測定対象領域とした。そして、この表面電位の絶対値Vinの測定対象領域について、像保持体の幅方向(回転軸方向)の一端側から他端側に向かって10mmおきに、表面電位プローブを設け(像保持体の表面から1mm離れた位置)、像保持体の周方向1周分について、表面電位計(トレック社製、トレック334)により測定された表面電位の測定結果の平均値の絶対値を、表面電位の絶対値Vinとして用いた。 In Table 1, the absolute value Vin of the surface potential is, as described above, on the upstream side in the rotation direction of the image carrier 12 from the region charged by the charging member 14 on the surface of the image carrier 12 and the transfer. The absolute value of the average value of the surface potential of the area downstream of the image transfer body 12 in the rotation direction from the area transferred by the member 20 is shown. In the present example and the comparative example, as the measurement target area of the absolute value Vin of the surface potential, an area charged by the charging member on the surface of the image holding body mounted on the image forming apparatus DocuCenter 505a, and a cleaning member An intermediate region between the region where the deposit on the image carrier is removed by the (cleaning member) is set as a measurement target region of the absolute value Vin of the surface potential. For the measurement target region of the absolute value Vin of the surface potential, a surface potential probe is provided every 10 mm from one end side to the other end side in the width direction (rotation axis direction) of the image holding body (the image holding body The absolute value of the average value of the measurement results of the surface potential measured by a surface potentiometer (Trek, Trek 334) for one circumference in the circumferential direction of the image holding member Used as the absolute value Vin.
また、上記表1中、表面電位の絶対値Vhは、上述したように、像保持体12の表面における、帯電部材14によって帯電される領域より像保持体12の回転方向下流側で、且つ潜像形成装置16によって静電潜像の形成される領域より像保持体12の回転方向上流側の領域の、表面電位の平均値の絶対値を示している。本実施例及び比較例では、この表面電位の絶対値Vhの測定対象領域として、上記の画像形成装置DocuCentre 505aに搭載された像保持体の表面における、帯電部材によって帯電される領域と、潜像形成装置(露光装置)によって静電潜像の形成される領域と、の中間の領域を、表面電位の絶対値Vhの測定対象領域とした。そして、この表面電位の絶対値Vhの測定対象領域について、像保持体の幅方向(回転軸方向)の一端側から他端側に向かって10mmおきに、表面電位プローブを設け(像保持体の表面から1mm離れた位置)、像保持体の周方向1周分について、表面電位計(トレック社製、トレック334)により測定された表面電位の測定結果の平均値の絶対値を、表面電位の絶対値Vhとして用いた。 In Table 1, the absolute value Vh of the surface potential is, as described above, on the downstream side in the rotation direction of the image carrier 12 from the region charged by the charging member 14 on the surface of the image carrier 12 and the latent potential Vh. The absolute value of the average value of the surface potential in the region upstream of the rotation direction of the image carrier 12 from the region where the electrostatic latent image is formed by the image forming device 16 is shown. In the present example and the comparative example, as the measurement target area of the absolute value Vh of the surface potential, an area charged by the charging member on the surface of the image holding body mounted on the image forming apparatus DocuCenter 505a, and a latent image An intermediate area between the area where the electrostatic latent image is formed by the forming apparatus (exposure apparatus) was set as the measurement target area of the absolute value Vh of the surface potential. For the measurement target area of the absolute value Vh of the surface potential, a surface potential probe is provided every 10 mm from one end side to the other end side in the width direction (rotation axis direction) of the image holding body (the image holding body The absolute value of the average value of the measurement results of the surface potential measured by a surface potentiometer (Trek, Trek 334) for one circumference in the circumferential direction of the image holding member Used as absolute value Vh.
なお、上記表面電位の絶対値Vh及び表面電位の絶対値Vinの測定における、上記「像保持体の周方向1周分」とは、非画像形成期間から画像形成期間へ切替えられた(図4中、切替え時P参照)直後の像保持体の最初の1回転目(画像形成期間に移行して最初の1回転目)を示している。 In the measurement of the absolute value Vh of the surface potential and the absolute value Vin of the surface potential, the “one circumferential direction of the image carrier” is switched from the non-image forming period to the image forming period (FIG. 4). The first rotation of the image carrier immediately after the switching (refer to P at the time of switching) (the first rotation after the transition to the image forming period) is shown.
上記表1中、シーケンスA〜シーケンスDとは、非画像形成期間の電圧印加方式が、図4に示す方式であり、詳細には、試験環境を高温高湿(28℃、85RH%)環境とした場合の帯電電圧の電圧値、現像電圧の電圧値、転写電圧の電圧値(第1の電圧値)、第1の電圧値の転写電圧の継続電圧印加時間を、表2に示す値とした場合を示している。 In Table 1 above, Sequence A to Sequence D are the voltage application method during the non-image forming period as shown in FIG. 4. Specifically, the test environment is a high temperature and high humidity (28 ° C., 85 RH%) environment. The voltage value of the charging voltage, the voltage value of the developing voltage, the voltage value of the transfer voltage (first voltage value), and the continuous voltage application time of the transfer voltage of the first voltage value are the values shown in Table 2. Shows the case.
また、表1中、シーケンスFは、非画像形成期間の電圧印加方式において、第1の電圧値の転写電圧の継続電圧印加時間を、像保持体12が1回転する時間未満としたものであり、詳細には、試験環境を高温高湿(28℃、85RH%)環境とした場合の帯電電圧の電圧値、現像電圧の電圧値、転写電圧の電圧値(第1の電圧値)、第1の電圧値の転写電圧の継続電圧印加時間を、表2に示す値とした場合を示している。 Further, in Table 1, the sequence F is a voltage application method during a non-image forming period in which the duration of applying the transfer voltage of the first voltage value is less than the time for which the image carrier 12 rotates once. Specifically, when the test environment is a high temperature and high humidity (28 ° C., 85 RH%) environment, the voltage value of the charging voltage, the voltage value of the developing voltage, the voltage value of the transfer voltage (first voltage value), the first The case where the continuous voltage application time of the transfer voltage of the voltage value is the value shown in Table 2 is shown.
また、表1中、シーケンスFは、非画像形成期間において、転写電圧、帯電電圧、現像電圧の全てを0V(解除)した場合を示している(表2参照)。 In Table 1, the sequence F indicates a case where all of the transfer voltage, the charging voltage, and the development voltage are 0V (released) in the non-image forming period (see Table 2).
上記表1に示す組合せとした実施例1〜実施例16及び比較例1〜比較例5について、下記評価を行った。 The following evaluation was performed on Examples 1 to 16 and Comparative Examples 1 to 5 which were combinations shown in Table 1 above.
(評価)
−形成対象の画像以外の線画像−
実施例1〜実施例16及び比較例1〜比較例5の上記改造機の各々について、高温高湿環境下(28℃、85RH%)において、画像形成期間における画像形成処理として、画像密度30%のA4ハーフトーン画像を10000枚連続してA4の記録媒体に出力した後に、表1及び表2に示す各々の実施例及び比較例の条件で非画像形成期間における非画像形成処理を行った。そして、この非画像形成期間の後に連続して、非画像形成期間の直前の画像形成期間と同じ条件で、画像形成処理(画像形成期間)を行った。
そして、この画像形成期間において出力した1枚目(非画像形成期間から画像形成期間に切替えられた直後に形成された画像を1枚目として換算)の記録媒体について、形成対象のハーフトーン画像ではない線画像の数を数えることによって、線画像の有無の評価を行った。評価基準は、以下の評価基準とした。評価結果を表3に示した。
(Evaluation)
-Line images other than the image to be formed-
For each of the modified machines of Examples 1 to 16 and Comparative Examples 1 to 5, the image density is 30% as an image forming process in the image forming period in a high temperature and high humidity environment (28 ° C., 85 RH%). After continuously outputting 10,000 A4 halftone images to an A4 recording medium, non-image forming processing was performed in the non-image forming period under the conditions of the examples and comparative examples shown in Tables 1 and 2. Then, after this non-image forming period, an image forming process (image forming period) was performed under the same conditions as the image forming period immediately before the non-image forming period.
In the halftone image to be formed on the recording medium of the first sheet output in this image forming period (the image formed immediately after switching from the non-image forming period to the image forming period is converted to the first sheet) The presence or absence of a line image was evaluated by counting the number of line images that were not present. The evaluation criteria were as follows. The evaluation results are shown in Table 3.
評価基準
G1:線画像が未発生
G2:線画像が1個以上5個未満発生
G3:線画像が5個以上10個未満発生
G4:線画像が10個以上発生
Evaluation criteria G1: No line image is generated G2: One or more line images are generated and less than five G3: Five or more line images are generated and less than ten G4: Ten or more line images are generated
上記表3に示すように、実施例では、比較例に比べて、画像形成期間における、形成対象の画像以外の線画像の発生の抑制がみられた。 As shown in Table 3 above, in the example, generation of line images other than the image to be formed was suppressed during the image formation period as compared with the comparative example.
10 画像形成装置,12 像保持体,14 帯電部材,16 潜像形成装置,18A 現像部材,20 転写部材,28 電源,30 電源,32 電源,36 制御装置 DESCRIPTION OF SYMBOLS 10 Image forming apparatus, 12 Image holding body, 14 Charging member, 16 Latent image forming apparatus, 18A Developing member, 20 Transfer member, 28 Power supply, 30 Power supply, 32 Power supply, 36 Control apparatus
Claims (4)
前記像保持体の表面に接触して配置され、直流電圧が印加されることによって前記像保持体の表面を帯電させる帯電部材と、
前記帯電部材によって帯電された前記像保持体の表面に静電潜像を形成する潜像形成装置と、
前記像保持体の表面に形成された前記静電潜像をトナーによって現像する現像装置と、
前記現像装置によって前記像保持体の表面に形成されたトナー像を被転写体へ転写すると共に、前記像保持体を除電する転写部材と、
前記転写部材の転写電位が、前記像保持体の表面に形成されたトナー像のトナーとは逆極性の転写電位となるように、該転写部材に転写電圧を印加する電圧印加装置と、
非画像形成期間中に、該非画像形成期間から画像形成期間への切替え時まで、少なくとも前記像保持体が1回転する期間継続して、前記像保持体の表面に形成されたトナー像のトナーとは逆極性で且つ0V以外の第1の電圧値の前記転写電圧を印加し、該非画像形成期間の後に連続する画像形成期間に、前記切替え時から連続して第2の電圧値の前記転写電圧を印加するように、前記電圧印加装置を制御する制御手段と、
を備えた画像形成装置。 A rotating image carrier;
A charging member disposed in contact with the surface of the image carrier and charging the surface of the image carrier by applying a DC voltage ;
A latent image forming apparatus that forms an electrostatic latent image on the surface of the image carrier charged by the charging member;
A developing device for developing the electrostatic latent image formed on the surface of the image carrier with toner;
A transfer member for transferring a toner image formed on the surface of the image carrier by the developing device to a transfer target member and discharging the image carrier;
A voltage applying device that applies a transfer voltage to the transfer member so that the transfer potential of the transfer member is a transfer potential having a polarity opposite to that of the toner of the toner image formed on the surface of the image carrier;
During the non-image forming period, the toner of the toner image formed on the surface of the image holding member is continuously used for at least one rotation of the image holding member until the switching from the non-image forming period to the image forming period. Applies the transfer voltage having a first voltage value other than 0 V having a reverse polarity, and the transfer voltage having the second voltage value continuously from the time of the switching in the image forming period subsequent to the non-image forming period. Control means for controlling the voltage application device to apply
An image forming apparatus.
前記像保持体の表面における、前記帯電部材によって帯電される領域より該像保持体の回転方向上流側で、且つ前記転写部材によって前記トナー像が前記被転写体へ転写される領域より該像保持体の回転方向下流側の領域の表面電位の絶対値Vinと、前記像保持体の表面における、前記帯電部材よって帯電される領域より該像保持体の回転方向下流側で、且つ前記潜像形成装置によって静電潜像の形成される領域より該像保持体の回転方向上流側の領域の表面電位の絶対値Vhと、前記像保持体の前記電荷輸送層及び前記電荷輸送層より表面側に設けられた層の厚みの合計T(μm)と、の画像形成期間における関係が、7T+50≦Vh−Vinを満たす請求項1に記載の画像形成装置。
(一般式(1)中、R1、R2、R3、R4、R5、及びR6はそれぞれ独立して水素原子、ハロゲン原子、炭素数1以上20以下のアルキル基、炭素数1以上20以下のアルコキシ基、又は、炭素数6以上30以下のアリール基を表し、隣接する2つの置換基同士が結合して炭化水素環構造を形成してもよい。n及びmはそれぞれ独立して0又は1を表す。) Before Symbol image holding member comprises a support, a charge generation layer, and a charge transport layer containing a charge-transporting material having a structure represented by the following general formula (1) in this order,
On the surface of the image carrier, on the upstream side of the rotation direction of the image carrier from the region charged by the charging member, and from the region where the toner image is transferred to the transfer member by the transfer member. The absolute value Vin of the surface potential of the region downstream in the rotation direction of the body and the formation of the latent image on the surface of the image carrier on the downstream side in the rotation direction of the image carrier from the region charged by the charging member The absolute value Vh of the surface potential of the region upstream of the image carrier in the rotation direction from the region where the electrostatic latent image is formed by the apparatus, and the surface side of the charge transport layer and the charge transport layer of the image carrier The image forming apparatus according to claim 1, wherein a relationship between the total thickness T (μm) of the provided layers and an image forming period satisfies 7T + 50 ≦ Vh−Vin.
(In General Formula (1), R 1 , R 2 , R 3 , R 4 , R 5 , and R 6 are each independently a hydrogen atom, a halogen atom, an alkyl group having 1 to 20 carbon atoms, or 1 carbon atom. It represents an alkoxy group having 20 or less or an aryl group having 6 to 30 carbon atoms, and two adjacent substituents may be bonded to form a hydrocarbon ring structure, where n and m are independent of each other. Represents 0 or 1.
(一般式(2)中、R7及びR8は、各々独立にハロゲン原子、炭素数1以上6以下のアルキル基、炭素数5以上7以下のシクロアルキル基、又は炭素数6以上12以下のアリール基であり、e,fは、各々独立に0以上4以下の整数を表す。) The image forming apparatus according to claim 2, wherein the charge transport layer includes a binder resin containing a structural unit represented by the following general formula (2).
(In the general formula (2), R 7 and R 8 are each independently a halogen atom, an alkyl group having 1 to 6 carbon atoms, a cycloalkyl group having 5 to 7 carbon atoms, or a group having 6 to 12 carbon atoms. An aryl group, and e and f each independently represent an integer of 0 or more and 4 or less.)
(一般式(3)中、R9及びR10は、各々独立にハロゲン原子、炭素数1以上6以下のアルキル基、炭素数5以上7以下のシクロアルキル基、又は炭素数6以上12以下のアリール基であり、g,hは、各々独立に0以上4以下の整数を表す。Xは、−CR11R12−(但し、R11及びR12は、各々独立に水素原子、トリフルオロメチル基、炭素数1以上6以下のアルキル基、又は炭素数6以上12以下のアリール基のいずれかを表す。)、炭素数5以上11以下の1,1−シクロアルキレン基、炭素数2以上10以下のα,ω−アルキレン基、−O−、−S−、−SO−、または−SO2−を表す。) The image formation according to claim 3, wherein the binder resin contains a copolymer having a structural unit represented by the general formula (2) and a structural unit represented by the following general formula (3). apparatus.
(In General Formula (3), R 9 and R 10 are each independently a halogen atom, an alkyl group having 1 to 6 carbon atoms, a cycloalkyl group having 5 to 7 carbon atoms, or a carbon group having 6 to 12 carbon atoms. Each is an aryl group, and g and h each independently represent an integer of 0 or more and 4 or less, X is —CR 11 R 12 — (wherein R 11 and R 12 are each independently a hydrogen atom, trifluoromethyl; A group, an alkyl group having 1 to 6 carbon atoms, or an aryl group having 6 to 12 carbon atoms), a 1,1-cycloalkylene group having 5 to 11 carbon atoms, and 2 to 10 carbon atoms. The following α, ω-alkylene group, —O—, —S—, —SO—, or —SO 2 — is represented.)
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2010163952A JP5621376B2 (en) | 2010-07-21 | 2010-07-21 | Image forming apparatus |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2010163952A JP5621376B2 (en) | 2010-07-21 | 2010-07-21 | Image forming apparatus |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JP2012027128A JP2012027128A (en) | 2012-02-09 |
| JP5621376B2 true JP5621376B2 (en) | 2014-11-12 |
Family
ID=45780148
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2010163952A Active JP5621376B2 (en) | 2010-07-21 | 2010-07-21 | Image forming apparatus |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JP5621376B2 (en) |
Family Cites Families (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH03238484A (en) * | 1990-02-16 | 1991-10-24 | Canon Inc | Transfer device for image forming device |
| JP3154629B2 (en) * | 1994-11-24 | 2001-04-09 | キヤノン株式会社 | Electrophotographic photoreceptor, electrophotographic apparatus and apparatus unit using the same |
| JP3525198B2 (en) * | 1995-03-01 | 2004-05-10 | 高砂香料工業株式会社 | Triphenylamine derivative, charge transport material using the same, and electrophotographic photoreceptor |
| JP5544117B2 (en) * | 2008-06-30 | 2014-07-09 | ゼロックス コーポレイション | Photoconductor containing tris (enylaryl) arylamine and / or bis (enylaryl) arylamine |
-
2010
- 2010-07-21 JP JP2010163952A patent/JP5621376B2/en active Active
Also Published As
| Publication number | Publication date |
|---|---|
| JP2012027128A (en) | 2012-02-09 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| JP6403586B2 (en) | Electrophotographic photosensitive member, process cartridge, and electrophotographic apparatus | |
| JP4456954B2 (en) | Electrophotographic photosensitive member, process cartridge, and electrophotographic apparatus | |
| JP5807507B2 (en) | Electrophotographic photosensitive member, process cartridge, and image forming apparatus | |
| JP2013190494A (en) | Image formation device and process cartridge | |
| JP5589491B2 (en) | Electrophotographic photosensitive member, process cartridge, and image forming apparatus | |
| JP6003760B2 (en) | Method for producing electrophotographic photosensitive member | |
| JP2007322996A (en) | Electrophotographic photoreceptor, process cartridge, and image forming apparatus | |
| JP5499782B2 (en) | Image forming apparatus | |
| JP2007219087A (en) | Electrifying device and image forming apparatus | |
| JP2008096923A (en) | Image forming apparatus and process cartridge | |
| JP4223671B2 (en) | Electrophotographic photosensitive member, electrophotographic method, electrophotographic apparatus, and process cartridge for electrophotographic apparatus | |
| JP4339197B2 (en) | Electrophotographic photosensitive member, electrophotographic method using the same, electrophotographic apparatus and process cartridge | |
| JP2007086202A (en) | Image forming apparatus | |
| JPH09236938A (en) | Electrophotographic photoreceptor and image forming device using the photoreceptor | |
| JP5621376B2 (en) | Image forming apparatus | |
| JP5434105B2 (en) | Electrophotographic photosensitive member, process cartridge, and image forming apparatus | |
| JP2010204561A (en) | Process cartridge and image forming apparatus | |
| JPH1165139A (en) | Electrophotographic photoreceptor and image forming method using the same | |
| JP5935700B2 (en) | Image forming apparatus, image forming method, and process cartridge | |
| CN117590716A (en) | image forming device | |
| JP2004109920A (en) | Image forming apparatus | |
| JP2012093382A (en) | Electrophotographic photoreceptor, process cartridge, image forming apparatus and method for manufacturing electrophotographic photoreceptor | |
| JP2012022256A (en) | Image forming apparatus and electrophotographic photoreceptor | |
| JP2007086209A (en) | Image forming apparatus and image forming method | |
| JP2010066670A (en) | Method of manufacturing electrophotographic photoreceptor |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| A621 | Written request for application examination |
Free format text: JAPANESE INTERMEDIATE CODE: A621 Effective date: 20130617 |
|
| A977 | Report on retrieval |
Free format text: JAPANESE INTERMEDIATE CODE: A971007 Effective date: 20140307 |
|
| A131 | Notification of reasons for refusal |
Free format text: JAPANESE INTERMEDIATE CODE: A131 Effective date: 20140311 |
|
| A521 | Written amendment |
Free format text: JAPANESE INTERMEDIATE CODE: A523 Effective date: 20140512 |
|
| TRDD | Decision of grant or rejection written | ||
| A01 | Written decision to grant a patent or to grant a registration (utility model) |
Free format text: JAPANESE INTERMEDIATE CODE: A01 Effective date: 20140826 |
|
| A61 | First payment of annual fees (during grant procedure) |
Free format text: JAPANESE INTERMEDIATE CODE: A61 Effective date: 20140908 |
|
| R150 | Certificate of patent or registration of utility model |
Ref document number: 5621376 Country of ref document: JP Free format text: JAPANESE INTERMEDIATE CODE: R150 |
|
| S533 | Written request for registration of change of name |
Free format text: JAPANESE INTERMEDIATE CODE: R313533 |
|
| R350 | Written notification of registration of transfer |
Free format text: JAPANESE INTERMEDIATE CODE: R350 |