JP6027663B2 - Plant pest control composition - Google Patents

Description

  The present invention relates to a novel combination of plant pest control compositions and a method for controlling plant pests using the composition.

  Conventionally, many chemical agents are used for controlling plant diseases. In order to control various plant pests that occur, it is common to use multiple drugs, but for reasons such as saving labor for users, drugs containing two or more active ingredients (mixtures) In some cases, a plurality of chemicals may be treated simultaneously, such as by treating several chemicals in a farmer's field using a tank mix method.

  Torprocarb according to the present invention is a diamine derivative that exhibits a plant disease control action, and has been found to exhibit a high control effect especially against rice blast (Pyricularia oryzae) (Patent Document 1). In Patent Document 2, a pest control composition containing a diamine derivative containing tolprocarb and one or more compounds selected from the group consisting of other fungicides, insecticides and acaricides, and pests using them. A control method is disclosed.

  Further, triflumezopyrim related to the present invention is a known compound and is a mesoionic pyrimidinium compound that exhibits high effects on pests such as planthoppers and leafhoppers (Patent Document 3). Patent Document 4 discloses a composition containing a pyrimidinium compound containing triflumezopyrim, its N-oxide and salt, and at least one other harmful invertebrate controlling agent, and a method for using the same.

WO2005 / 042474 WO2006 / 106811 WO2012 / 092115 WO2011 / 017351

However, in the case of the treatment using the above-mentioned mixed agent or mixed use, for example, in the case of a combination of drugs that are not compatible, there are many risks that the effects of each other's drugs may be reduced or that phytotoxicity may be caused to plants. To do.
Under such circumstances, a plant pest control composition comprising a combination that exhibits a high effect with a lower amount of active ingredient and does not cause phytotoxicity to plants is desired.

  As a result of intensive studies on the combination of tolprocarb and triflumezopyrim, the present inventors have, for example, an excellent control effect (synergistically) that cannot be predicted from a single component of tolprocarb or triflumezopyrim against plant pests such as rice blast. The present invention was completed. The present invention was completed.

  That is, the object of the present invention is a new combination that exhibits a high control effect against plant pests, exhibits high activity even when the amount of active ingredient administered to the pest habitat is low, and further, no generation of phytotoxicity is observed in plants. It is to provide a method for controlling plant pests and a method for controlling plant pests using the composition.

The combination of the present invention is a novel invention which is not disclosed in any of Patent Documents 1 to 4.
The present invention has a high control effect against plant pests, exhibits high activity even when the amount of active ingredients administered to the pest habitat is low, and further prevents plant diseases and pests in a new combination where no phytotoxicity is observed in the plant. The present invention relates to a composition and a method for controlling plant pests to which the composition is applied.

The present invention
1) A plant pest control composition comprising tolprocarb and triflumezopyrim as active ingredients,
2) A plant pest control composition characterized by further containing chlorantraniprole and / or cimeconazole in the plant pest control composition as described in 1),
3) The plant pest control composition according to any one of 1) and 2), wherein the plant is rice.
4) The plant pest control composition according to any one of 1) to 3), wherein the plant pest is rice blast;
5) The plant pest control composition according to any one of 1) to 4), wherein the plant pest is Pyricularia oryzae.
6) A method for controlling plant pests by applying the plant pest control composition according to any one of 1) to 5),
7) The method according to 6), wherein the plant is rice.
8) The method according to any one of 6) and 7), wherein the plant pest is rice blast
9) The method according to any one of 6) to 8), wherein the plant pest is Pyricularia oryzae, and 10) The plant pest control composition containing tolprocarb and triflumezopyrim as active ingredients is applied, or tolprocarb is effective The present invention relates to a method for controlling plant pests, which comprises applying one of a plant pest control composition containing as an ingredient and a plant pest control composition containing triflumezopyrim as an active ingredient, and then applying the other composition.

  The plant pest control composition of the present invention has an excellent control effect (synergistic control effect) that cannot be expected from a single component of tolprocarb or triflumezopyrim against, for example, plant pests such as rice blast (Pyricularia oryzae). Is expressed. Furthermore, the plant pest control composition does not cause any phytotoxicity in plants.

Next, the plant pest control composition which is the first invention of this patent application will be described.
The plant pest control composition of the present invention is characterized by combining tolprocarb and triflumezopyrim.
Tolprocarb and triflumezopyrim are known compounds and can be produced, for example, according to the methods described in WO2005 / 042474A1 and WO2012 / 092115, respectively, or the methods thereof.

  The plant pest control composition of the present invention can be produced according to a conventional method. That is, the plant disease control composition can be prepared by mixing a composition containing one active ingredient of tolprocarb and triflumezopyrim to produce a composition containing both active ingredients. Other active ingredients may be added to the composition containing the ingredients to produce a composition containing both active ingredients. Usually, the said plant pest control composition is manufactured using the mixture which mixed both active ingredients. The plant pest control composition of the present invention can be used by further mixing a carrier with the obtained plant pest control composition, and if necessary, a surfactant, a wetting agent, a sticking agent, a thickener. Add formulation adjuvants such as preservatives, coloring agents, stabilizers, etc., and formulate into wettable powders, flowable powders, granular wettable powders, powders, emulsions, granules, etc. in a timely manner according to conventional methods. Can do.

  The content of tolprocarb as an active ingredient in these preparations is usually 0.005 to 99% by weight, preferably 0.1 to 90%, and more preferably, It is in the range of 0.3 to 80%. In addition, the content of triflumezopyrim as an active ingredient in these preparations is usually in the range of 0.005 to 99% by weight, preferably in the range of 0.1 to 90%. More preferably, it is 0.3 to 80%.

  The total content of tolprocarb and triflumezopyrim is usually in the range of 0.01 to 99% by weight, preferably in the range of 0.1 to 90%, more preferably in the range of 0.3 to The range is 80%. The mixing ratio of tolprocarb and triflumezopyrim is usually a ratio by weight of triflumezopyrim with respect to tolprocarb, 0.01 to 1000, preferably 0.02 to 100, and more preferably, The ratio is 0.05-10.

  In the plant pest control composition of the present invention, the content of tolprocarb and triflumezopyrim varies depending on the preparation form, and is appropriately selected, but is usually 0.01 to 30% by weight in a powder, Is 0.1 to 80% by weight, granule is 0.5 to 20% by weight, emulsion is 2 to 50% by weight, flowable preparation is 1 to 50% by weight, In the flowable preparation, it is 1 to 80% by weight.

  The preferred contents of tolprocarb and triflumezopyrim are 0.05 to 10% by weight for powders, 5 to 60% by weight for wettable powders, 2 to 15% by weight for granules, and emulsions. Is 5 to 50% by weight, 5 to 50% by weight for the flowable preparation, and 5 to 60% by weight for the dry flowable preparation.

  More preferably, it is 0.1 to 10% by weight for powders, 5 to 50% by weight for wettable powders, 2 to 10% by weight for granules, and 5 to 20% by weight for emulsions. And 5 to 40% by weight for flowable formulations and 5 to 50% by weight for dry flowable formulations. The content of the auxiliary agent is 0 to 80% by weight, and the content of the carrier is an amount obtained by subtracting the content of the active ingredient compound and the auxiliary agent from 100% by weight.

  The carrier used in the above composition is a synthetic or natural inorganic or organic compounded to help the active ingredient reach the site to be treated and to facilitate the storage, transportation and handling of the active ingredient compound. It means a substance and can be used as a solid or liquid as long as it is usually used in agricultural and horticultural medicines, and is not limited to a specific one.

  Specific examples of the solid carrier include, for example, bentonite, montmorillonite, kaolinite, diatomaceous earth, white clay, talc, clay, vermiculite, gypsum, calcium carbonate, amorphous silica, and ammonium sulfate; soy flour, wood flour, sawdust Plant organic substances such as wheat flour, lactose, sucrose, and glucose; or urea.

  Specific examples of the liquid carrier include aromatic hydrocarbons and naphthenes such as toluene, xylene and cumene; paraffinic hydrocarbons such as n-paraffin, iso-paraffin, liquid paraffin, kerosene, mineral oil and polybutene; Ketones such as acetone and methyl ethyl ketone; Ethers such as dioxane and diethylene glycol dimethyl ether; Alcohols such as ethanol, propanol and ethylene glycol; Carbonates such as ethylene carbonate, propylene carbonate and butylene carbonate; Non-protons such as dimethylformamide and dimethyl sulfoxide An organic solvent; or water.

  Further, in order to enhance the efficacy of the active ingredient in the composition of the present invention, an adjuvant is used either alone or in combination depending on the purpose, taking into consideration the dosage form, processing method, etc. of the preparation. You can also. Examples of the auxiliary agent include surfactants, binders, disintegrants, stabilizers, pH adjusters, antibacterial / antifungal agents, thickeners, antifoaming agents, and antifreeze agents.

  Usually, surfactants used for the purpose of emulsifying, dispersing, spreading and / or wetting agricultural chemical formulations are, for example, sorbitan fatty acid ester, polyoxyethylene sorbitan fatty acid ester, sucrose fatty acid ester, polyoxyethylene fatty acid Formalin condensation of ester, polyoxyethylene resin acid ester, polyoxyethylene fatty acid diester, polyoxyethylene castor oil, polyoxyethylene alkyl ether, polyoxyethylene alkyl phenyl ether, polyoxyethylene dialkyl phenyl ether, polyoxyethylene alkyl phenyl ether , Polyoxyethylene polyoxypropylene block polymer, alkyl polyoxyethylene polyoxypropylene block polymer ether, alkylphenyl polyoxye Len polyoxypropylene block polymer ether, polyoxyethylene alkylamine, polyoxyethylene fatty acid amide, polyoxyethylene bisphenyl ether, polyoxyalkylene benzyl phenyl ether, polyoxyalkylene styryl phenyl ether, polyoxyalkylene adduct of higher alcohol and Nonionic surfactants such as polyoxyethylene ether and ester type silicone and fluorine-based surfactants; alkyl sulfates, polyoxyethylene alkyl ether sulfates, polyoxyethylene alkyl phenyl ether sulfates, polyoxyethylene benzyl phenyl ether sulfates, poly Oxyethylene styryl phenyl ether sulfate, polyoxyethylene polyoxy Propylene block polymer sulfate, paraffin sulfonate, alkane sulfonate, AOS, dialkyl sulfosuccinate, alkyl benzene sulfonate, naphthalene sulfonate, dialkyl naphthalene sulfonate, formalin condensate of naphthalene sulfonate, alkyl diphenyl ether disulfonate, lignin sulfonate, polyoxyethylene alkyl phenyl ether sulfonate , Polyoxyethylene alkyl ether sulfosuccinic acid half ester, fatty acid salt, N-methyl-fatty acid sarcosinate, resin acid salt, polyoxyethylene alkyl ether phosphate, polyoxyethylene phenyl ether phosphate, polyoxyethylene dialkyl phenyl ether phosphate, polyoxyethylene Be Benzylated phenyl ether phosphate, polyoxyethylene benzylated phenyl phenyl ether phosphate, polyoxyethylene styrylated phenyl ether phosphate, polyoxyethylene styrylated phenyl phenyl ether phosphate, polyoxyethylene polyoxypropylene block polymer phosphate, phosphatidylcholine, phosphatidylethanolimine , Alkyl phosphate, anionic surfactant such as sodium tripolyphosphate; polyanionic polymer surfactant derived from acrylic acid and acrylonitrile, acrylamidomethylpropane sulfonic acid, alkyltrimethylammonium chloride, methylpolyoxyethylenealkylammonium chloride, alkyl N-methylpyridinium bromide Id, monomethylated ammonium chloride, dialkylmethylated ammonium chloride, alkylpentamethylpropylamine amine dichloride, alkyldimethylbenzalkonium chloride, benzethonium chloride and other cationic surfactants; or dialkyldiaminoethylbenthine, amphoteric such as alkyldimethylbenzylbentine Surfactant etc. are mentioned.

Examples of the binder include sodium alginate, polyvinyl alcohol, gum arabic, CMC sodium or bentonite.
Examples of the disintegrant include CMC sodium or croscarmellose sodium, and examples of the stabilizer include hindered phenol-based antioxidants, benzotriazole-based and hindered amine-based ultraviolet absorbers, and the like. .

Examples of the pH adjuster include phosphoric acid, acetic acid, and sodium hydroxide. Examples of the antibacterial and antifungal agent include industrial bactericides such as 1,2-benzisothiazolin-3-one. It is done.
Examples of the thickener include xanthan gum, guar gum, CMC sodium, gum arabic, polyvinyl alcohol, or montmorillonite. Examples of the antifoaming agent include silicone compounds. Examples of the antifreezing agent include , Propylene glycol, ethylene glycol and the like. However, these adjuvants are not limited to the above.

  Examples of the method of applying the composition of the present invention include, for example, foliage spraying treatment to plant individuals, seedling box treatment, spraying treatment to the soil surface, soil mixing after spraying treatment to the soil surface, injection treatment into soil, Soil admixture after infusion treatment in soil, soil irrigation treatment, soil admixture after soil irrigation treatment, spraying treatment on plant seeds, smearing treatment on plant seeds, immersion treatment in plant seeds or powder on plant seeds For example, clothing processing. The compositions of the present invention usually exhibit sufficient efficacy in any application method utilized by those skilled in the art.

Next, a plant pest control method, which is the second invention of this patent application, will be described.
In order to control plant pests, (1) a plant pest control composition containing tolprocarb and triflumezopyrim as active ingredients is applied, or (2) a plant pest control composition and triflu containing tolprocarb as active ingredients After applying any one of the plant pest control compositions containing mesopyrim as an active ingredient, the other composition may be applied.

  After applying one of the plant pest control composition containing tolprocarb as an active ingredient and the plant pest control composition containing triflumezopyrim as an active ingredient, the time (period) until the other composition is sprayed is Although it is not particularly limited as long as it has an effect of controlling plant pests, for example, it is 1 minute to 2 weeks after applying any one of the compositions, preferably after applying any one of the compositions It is 5 minutes to 1 week, and more preferably 10 minutes to 3 days after applying any one of the compositions. Which plant pest control composition is used first is not particularly limited as long as it has an effect of controlling plant pests, but it is appropriately selected depending on the target plant pest, plant, and other environment related to application. Can be determined.

  Further, a plant pest control composition containing tolprocarb and triflumezopyrim as active ingredients, a plant pest control composition containing tolprocarb as an active ingredient, and a plant pest control composition containing triflumezopyrim as an active ingredient in combination It can be used to control plant pests. The order of application, the order of application, the time until application (period), and the number of applications are not particularly limited as long as they have the effect of controlling plant pests, but the target plant pests, plants, and other environments related to application Depending on the situation, it can be appropriately selected and determined.

  Furthermore, the plant pest control composition of the present invention can be prepared by containing tolprocarb and triflumezopyrim in high concentrations. This high-concentration composition can be diluted with water and used as a spray liquid. The plant pest control composition of the present invention can also be prepared as a mixture by mixing a composition containing tolprocarb at a high concentration and a composition containing triflumezopyrim at a high concentration at the time of use. This high concentration composition can be diluted with water and used as a spray liquid (tank mix method).

  The application amount and concentration of the plant pest control composition containing tolprocarb and triflumezopyrim as active ingredients are not particularly limited as long as they have the effect of controlling plant pests, and the extent of target crops, target pests, and pests Depending on the dosage form of the compound, the application method, various environmental conditions, and the like, it can be appropriately selected and determined.

  When spraying the composition, the amount of active ingredient is usually 10 to 10,000 g per hectare, and preferably 25 to 5,000 g per hectare. When the wettable powder, flowable agent or emulsion of the composition is diluted with water and sprayed, the dilution ratio is usually 5 to 50,000 times, preferably 10 to 20,000 times. Yes, more preferably 15 to 10,000 times. Moreover, when performing seed disinfection using the said composition, the usage-amount is 0.001-50g per kg of seeds normally, Preferably, it is 0.01-10g.

  In the case where the composition is subjected to foliage spraying treatment, plant surface spraying treatment, soil injection treatment, soil irrigation treatment, etc., the composition is applied to an appropriate carrier at an appropriate concentration. After dilution, the treatment can be performed. When contacting the said composition with a plant seed, you may immerse a plant seed in the said composition as it is. In addition, the composition can be used after being diluted to an appropriate concentration in an appropriate carrier and then dipped, dressed, sprayed or smeared on plant seeds. The amount of the composition used in the case of powder coating, spraying and smearing treatment is usually about 0.05 to 50% of the dry plant seed weight, preferably 0.1 to 30%. The amount used is not limited to these ranges, and can be determined by appropriately selecting according to the type of plant seed to be treated.

  Suitable carriers include, for example, liquid carriers in organic solvents such as water or ethanol; inorganics such as bentonite, montmorillonite, kaolinite, diatomaceous earth, white clay, talc, clay, vermiculite, gypsum, calcium carbonate, amorphous silica, ammonium sulfate, etc. Substances, vegetable organic substances such as soybean flour, wood flour, sawdust, wheat flour, lactose, sucrose, and glucose: or solid carriers such as urea can be mentioned, but are not limited thereto.

  In the present specification, the plant individual means one that lives without exercising by photosynthesis. Specifically, for example, rice, wheat, barley, corn, grape, apple, pear, peach, sweet cherry, oyster , Citrus, soybean, green beans, strawberry, potato, cabbage, lettuce, tomato, cucumber, eggplant, watermelon, sugar beet, spinach, sweet pea, pumpkin, sugar cane, tobacco, sweet pepper, sweet potato, taro, konjac, oilseed rape, cotton, sunflower, A tulip, chrysanthemum, turf, etc. are mentioned, but are not limited thereto.

  The plant seed in the present specification means one that stores nutrients for seedlings to germinate and is used for agricultural reproduction. Specifically, for example, corn, soybean, cotton, rice, sugar beet, wheat, Seeds such as barley, sunflower, tomato, cucumber, eggplant, spinach, sweet pea, pumpkin, sugar cane, tobacco, pepper, rapeseed; seeds such as taro, potato, sweet potato, konjac; edible lily, bulbs such as tulip, and raccoon Seed ball, etc .; or plants produced by artificial manipulation of genes, etc., for example, soy, corn, cotton, etc. that have given herbicide resistance that does not exist in nature; cold regions Adapted, rice, tobacco, etc .; corn, cotton, burley, with the ability to produce insecticides ® Although like seeds undergone transformation, such as, but not limited thereto.

  The composition of the present invention can be used in combination with other pesticides, acaricides, nematicides, fungicides, herbicides, plant growth regulators, and other agricultural chemicals, soil conditioners or fertilizers. It is also possible to prepare a mixed preparation with these.

  Specific fungicides, insecticides, acaricides, nematicides include, for example, allethrin, tetramethrin, resmethrin, phenothrin, framethrin, permethrin, cypermethrin, deltamethrin, cyhalothrin, cyfluthrin, fenpropatrin, tralomethrin, cyclo Protorin, flucitrinate, fulvalinate, acrinatrin, tefluthrin, bifenthrin, enpentrin, beta cyfluthrin, cypermethrin, fenvalerate, esfenvalerate, flubrocitrinate, methfluthrin, profluthrin, dimefluthrin, fulbrocis phosphate, Silafluophene, insect repellent extract, etofenprox, halfenprox, DDVP, cyanophos, phenthion, fenitrothion, tetrachlor Phosphine, dimethylvinphos, propaphos, methylparathion, temefos, phoxime, acephate, isofenphos, salicione, DEP, EPN, ethion, mecarbam, pyridafenthion, diazinon, pyrimifosmethyl, etrimphos, isoxathion, quinalphos, chlorpyrifos methyl, chlorpyrifos, hosarone , Phosmet, methidathion, oxydebrofos, bamidione, malathion, phentoate, dimethoate, formothione, thiomethone, ethylthiomethone, folate, terbufos, profenophos, prothiophos, sulfophos, pyracrofos, monocrotophos, nared, phostiazeto, trichlorfone, thoprofosca , Diclofenthion, ethyl thiometh , Methamidophos, dichlorvos, tebupyrimphos, ometoate, triazophos, oxydemeton-methyl, azinephos-methyl, chloroethoxyphos, dicrotophos, disulfoton, fanamiphos, phosphamidone, trichlorfone, chlormefos, demeton-S-methyl, mevinphos, parathion, tebuprimalphos, ME , DCIP, MPP, NAC, MTMC, MIPC, BPMC, XMC, PHC, MPMC, etiophen carb, bendio carb, pirimicarb, carbosulfan, benfuracarb, mesomil, oxamyl, aldicarb, thiodicarb, alanic carb, carbofuran, methiocarb, fenothiocarb , Xylyl methyl carbamate, propoxal, isoprocarb, furthiocarb, Dacloprid, nitenpyram, acetamiprid, dinotefuran, thiamethoxam, thiacloprid, clothianidin, bromopropylate, dicophor, endosulfan, lindane, diflubenzuron, chlorfluazuron, teflubenzuron, triflumuron, flufenoxuron, full cycloxuron, hexaflumuuron, Fluazuron, diafenthiuron, novallon, nobiflumuron, bistrifluron, chromafenozide, halofenozide, methoxyphenozide, lufenuron, cyromazine, triazamate, tebufenozide, buprofen, isoprothiolane, nicotine sulfate, polynactin complex, abamectin, milbemectin, remebe , Rotenone, cartap, thiocyclam, bensultat , Tifluzamide, flutolanil, mepronil, pencyclon, ethaboxam, oxycarboxin, carboxin, silthiofam, carpropamide, diclocimet, tricyclazole, pyroxylone, phenoxanyl, fusalide, azoxystrobin, methinostrobin, orissastrobin, cresoximemethyl, fluoxastrobin , Trifloxystrobin, dimoxystrobin, pyraclostrobin, picoxystrobin, kasugamycin, validamycin, blasticidin S benzylaminobenzenesulfonate, polyoxin, teclophthalam, oxytetracycline, streptomycin, blasticidin S, Mildiomycin, Polyoxins, Ferimzone, Phenarimol, Pyrifenox, Nuali , Bupyrimeto, cimeconazole, furametopir, ipconazole, triflumizole, prochloraz, pefrazoate, imazalil, imibenconazole, etridiazole, epoxiconazole, oxpoconazole fumarate, dinicoazole, difenoconazole, cyproconazole, tetraconazole, Tebuconazole, triadimenol, triadimethone, triticonazole, viteltanol, hymexazole, fenbuconazole, fluquinconazole, flusilazole, flutriaphor, prothioconazole, propiconazole, bromconazole, hexaconazole, penconazole, metconazole, Copper, copper nonylphenol sulfonate, basic copper chloride, basic copper sulfate, oxine copper, DBEDC, anhydrous copper sulfate, Cupric oxide, thiophanate methyl, benomyl, thiabendazole, thiophanate, carbendazim, fuberidazole, EDDP, IBP, tolcrofosmethyl, fosetyl, dinocap, pyrazophos, metalaxyl, oxadixyl, benalaxyl, metalaxyl-M, iprodione, procymidone, vinclozolinate Thiuram, manzeb, propineb, dineb, metyram, manneb, ziram, ambam, hydroxyisoxazole, metasulfocarb, chlorpicrin, fursulfamide, dazomet, methylisothiocyanate, hydroxyisoxazole potassium, echromezole, 1,3-dichloropropene, TPN, captan, mepanipyrim, cyprodinil, pyrimethanil, rapeseed oil, machine oil, sulfur, stone Ash-sulfur mixture, zinc sulfate, fentin, sodium hydrogen carbonate, potassium hydrogen carbonate, hypochlorite, dimethomorph, fenpropidin, fenpropimorph, spiroxamine, tridemorph, dodemorph, full morph, chlorbenzilate, phenisobromolate , Tetradiphone, CPCBS, BPPS, quinomethionate, amitraz, benzomate, hexothiazox, fenbutazin oxide, cyhexatin, dienochlor, clofentezine, pyridaben, fenpyroximate, phenazaquin, tebufenpyrad, pyrimidifene, acequinosyl, bifenazeto, fenfensito, clofexazole, etofazole Amidoflumet, difluvidazine, kelsen, pymetrozine, fipronil, phenoxycarb, pyriproxy , Metoprene, hydroprene, quinoprene, endosulfan, triazuron, benzoepin, emamectin benzoate, emamectin benzoate, flupirazophos, fluacrylpyrim, flufendine, indoxacarb, tolfenpyrad, gamma cyhalothrin, ethiprole, acetoprole, amideflumethyr, chlorfenamide , Flufenerim, pyridalyl, sodium oleate, potassium oleate, azadirachtin, carbam, sodium carbam, propargite, azocyclotin, benzoximate, metaldehyde, methotrephen boot, bencrothiaz, fulvendiamide, metaflumizole, nicotine sulfate, lime Nitrogen, machine oil, bensultap, flubenzamide, chloranthra Liprol, cyantraniliprole, pyrifluquinazone, metaflumizone, oxolinic acid, Pseudomonas CAB-02, Trichoderma atrobide, fludioxonil, DPC, 4- [3- (3,4-dimethoxyphenyl) -3- (4-fluorophenyl) acryloyl ] Morpholine, anilazine, iprovalicarb, imazalil, iminotadine albesylate, quinoxyphene, quinomethionate, silver metal, quintozine, guazatine, chlorothalonil, chloroneb, cyazofamide, dietofencarb, diclofluranide, dichlorane, dithianon, diflumethycimol, dimethymol Spiroxamine, zoxamide, thiadiazine, dodine, trifolin, tolylfluanide, nitrotal isop Lopyr, famoxadone, fenamidone, fenitropan, fenpiclonil, fenhexamide, phorpet, fluazinam, fluorimide, propamocarb, propamocarb hydrochloride, propylene glycol fatty acid ester, prohexadione calcium salt, benazole, benava carbcarb isopropyl, microbutanyl, Organic nickel, resveratrol, penthiopyrad, dichromedin, iminotadine acetate, thianidyl, thiazinyl, probenazole, acibenzoral-S-methyl, mandipropamide, pyribencarb, amisulbrom, isothianyl, tebufloquine, fluopicolide and the like. Furthermore, when applying the plant pest control composition characterized by containing tolprocarb of the present invention as an active ingredient to rice pests, other pesticides and fungicides exhibiting high effects on the main rice pests, Since mixing is useful for exerting an effect on a wider range of plant pests, tricyclazole, fusalide, kasugamycin, ferimzone, EDDP, isoprothiolane, penthiopyrad, tebufloquine, metminostrobin, orisatrobin, diclosimet , Thianidyl, probenazole, acibenzoral-S-methyl, isotianil, flutolanil, mepronil, pencyclon, azoxystrobin, validamycin, furametopil, dichromedin, tifluzamide, chlorantraniliprole, simecona , Benomyl, fludioxonil, iprodione, TPN, hydroxyisoxazole, oxolinic acid, MEP, MPP, BPMC, silafluophene, etofenprox, clothianidin, dinotefuran, buprofezin, ethiprole, cartap, tebufenozide, flubenzamide, metaflumizone, diazinon, Propafos, benfuracarb, imidacloprid, thiamethoxam, fipronil, pymetrozine, spinosad and the like can be mentioned, and more preferred examples include chlorantraniliprole and cimeconazole, and one or more can be used in combination.

The composition and control method of the present invention are effective against, for example, the following types of plant pests. Examples of specific pests to be controlled by the present invention are shown below.
Plant diseases include, for example, rice blast (Pyricularia oryzae), blight (Thanatephorus cucumeris), sesame leaf blight (Cochliobolus miyabeanus), idiotic seedling (Gibberella fujikurum seedling) spp., Trichoderma spp., Rhizopus spp., Rhizoctonia solani, etc., rice mildew (Claviceps virens), smut (Tilletia barelayana); tritici), rust (Puccinia striformis); Pu ccinia graminis, Puccinia recondita, Puccinia hordei), Madarahabyo (Pyrenophora graminea), net blotch (Pyrenophora teres), Fusarium head blight (Fusarium graminearum, Fusarium culmorum, Fusarium avenaceum, Microdochium nivale), snow mold (Typhula incarnata, Typhula ishikariiensis, Micronetriella nivalis), naked scab (Ustilago nuda, Ustilago tritici, Ustilago nigra, Ustilago avenae), Tuna gules , Tilletia panicicii), eye spot disease (Pseudocercosporella herpotrichoides), strain rot (Rhizoctonia ceralis), cloud disease (Rhynosporium secalis), leaf blight (Septor disease) spp., Pythium spp., Rhizoctonia spp., Septoria nodorum, Pyrenophora spr., Gaemannomyces graminis disease, Colletotrichum olamine disease liobolus sativus); corn Fusarium head blight (such as Fusarium graminearum), seedling blight (Fusarium avenaceum, Penicillium spp, Pythium spp. , Rhizoctonia spp, rust disease (Puccinia sorghi), sesame leaf blight (Cochliobolus heterostrohus), smut (Ustilago Mayolism), anthracnose (Colletotrichum gram) viticola), rust disease (Phakopsora ampelopsidis), powdery mildew (Uncinula necator), black rot (Elsinoe ampelina), late rot (Glomerella cinulata), black rot (Guibivalh disease) soot Spot disease (Zygophiala jamaicensis), gray mold disease (Botrytis cinereaa), shoot blight (Diaporthedium medusaea), purple leaf blight (Helicobasidium mumpa), white scab (Reselliria cinerea) disease , Black spot disease (Venturia inaequalis), spotted leaf defoliation (Alternaria alternata), red star disease (Gymnosporadium yamadae), Monilia disease (speech) Colletotrichum accutatum, soot spot disease (Zygophiala jamaicensis), soot spot disease (Gloodes pomigena), black spot disease (Mycosphaerella pomigen), purple herb disease Diseases (Phomopsis mary, Diaporthe tanakae), Brown spot disease (Diplocarpon mary); Pear black spot disease (Alternaria alternata (Japan) pear pathotype), Black streak disease (V) Physalospo a piricola), blight (Diaporthe medusaea, Diaporthe eres), pears of late blight (Phytophthora cactorum); peach scab (Cladosporium carpophilum), Phomopsis rot (Phomopsis sp. ), Plague (Phytophthora sp.), Anthracnose (Gloeosporium laeticcolor); sweet potato anthracnose (Glomerella kunuano), larvae (Monilinia kurokki); ), Deciduous leaf disease (Cercospora kaki; Mycosphaerella nawae), powdery mildew (Phyllactinia kakikora); citrus black spot disease (Diaportheum citrus), green mold disease (Penicillium, ginger disease) ); Tomato, ki Botrytis cinerea, such as cucumber, beans, strawberry, potato, cabbage, eggplant, lettuce; Sclerotinia sclerotiorum, such as tomato, cucumber, legume, strawberry, potato, rapeseed, cabbage, eggplant, lettuce; Seedling blight of various vegetables such as tomato, cucumber, beans, radish, watermelon, eggplant, rapeseed, green pepper, spinach, sugar beet (Rhizoctonia spp., Phythium spp., Phythophthora spp., Phythophthora spp., Sclerotiri) Downy mildew (Pseudoperonospora cubensis), powdery mildew (Sphaerotheca fuliginea), charcoal Disease (Colletotrichum lagenarium), vine blight (Mycosphaerella melonis), Fusarium disease (Fusarium oxysporum), plague (Phytophthora parasitica, Phytophthora melonis, Phytophthora nicotianae, Phytophthora drechsleri, Phytophthora capsici, etc.); tomato early blight (Alternaria solani) , Leaf mold (Cladosporium fulvam), plague (Phytophthora infestans), wilt (Fusarium oxysporum), root rot (Phythium myriotylum), Pythium diss tocum), anthracnose (Colletotrichum phomoides); powdery mildew of eggplant (such as Sphaerotheca furiginea); brassicae), cruciferous vegetable black spot (Alternaria brassicae, etc.), white spot (Cercosporella brassicae), root rot (Leptospheria maculasansa), root-knot (Plasmodiophora brasicaceae) Rot of cabbage (Rhizoctonia solani), yellow rot (Fusarium oxysporum); cabbage buttocks rot (Rhizoctonia solani); yellow rot (Verticillium dahlie); porri), white silk disease (Sclerotium olfsii.). Sclerotium rolfsiii, Phytophthora porrii; Soybean purpura (Cercospora kikutrophii), black spot (Elsinoe glycolnes), black spot (Diaporthe phlothonia) , Downy mildew (Peronospora manchurica), rust (Phakopsora pachyrhizi), anthracnose (Colletotrichum truncatum), anthracnose of green beans (Colletotrichum lindemuerium blackberry) tum), brown spot disease (Cercospora arachidicola); Pea powdery mildew (Erysiphe pisi); downy mildew (Peronospora vicii); broad bean downy mildew (Peronospora viciiae); plague Alternaria solani), black rot (Rhizoctonia solani), plague (Phytophthora infestans), silver scab (Sponyloclaium atrosor, sorghum), dry rot (Fusarium oxysporum, sorghum) Spot disease (Cercosp ra beticola), downy mildew (Peronospora schachtii), black root disease (Aphanomices cochioides), potato batter (Alternaria dauci); strawberry powdery mildew (Alternaria dauci); (Phytophthora nicotianae), Anthracnose (Glomerella singulata), Fruit rot (Phythium ultramum Trow var.ultimum); Chamodium rice rot (Exobasidium reticulatum), White scab (Elisco) Disease (Pestalo iopsis longiseta), tobacco red leaf disease (Alternaria alterata (Tobacco pathotype)), powdery mildew (Erysiphe cichoacearum), anthracnose (Colletotrichum tabacum), plague Sclerotinia sclerotiorum; Rose scab (Diplocarpon rosae),
Powdery mildew (Sphaerotheca pannosa), plague (Phytophthora megaspersa), downy mildew (Peronospora sparsa); chrysanthemia indci (h) Brown patch disease (Rhizoctonia solani), Dollar spot disease (Sclerotinia homoeocarpa), Curvularia leaf blight (Curvularia geniculata), Rust disease (Puccinia zoisiae), Helmintosporichos s. secalis), withering disease (Gaemannomyces graminis), anthrax (Colletotrichum graminicola), snow rot brown granule sclerotia (Typhula incarnata), snow rot black granule sclerotia (Typhala ishikariensis nuclei) borealis), fairy rings (such as Marasmius oreades), pisium disease (such as Pythium aphanidermatum), and the like, and particularly preferred diseases include rice blast (Pyricularia oryzae).

In addition, examples of the pests include, for example, Hari nematode: ANGUINIDAE, Bengrass nematode (Anguina agritis), Wheat nematode (Anguina tritici), Imogusaresenchu (Dylenchus destructor), and YL. Pratylenchenidae, such as Tyrenchorhynchus martini and Tyrenchorhynchus sp., Hirschmanniella imamuri, Rice Henrimuchu schmanniella oryzae), South Negu Saleh nematode (Pratylenchus coffeae), lily of the valley Negu Saleh nematode (Pratylenchus convallariae), chrysanthemum Negu Saleh nematode (Pratylenchus fallax), tea Negu Saleh nematode (Pratylenchus loosi), wheat Negu Saleh nematode (Pratylenchus neglectus), Northern Negu Saleh nematode (Pratylenchus penntrans), Negusaresenchu (Pratylenchus sp.), Etc., as HOPLOLAMIDAE, Namila nematode (Helicotyrenchus dihystera), Chara nematode (Helicotyl) chus erythrinae), helix nematode (Helicotylenchus sp.), spider nematode (Hopolaimus sp.), narcissus nematode (Rotylenchulus reniformis), ER Cistode nematode (Cactodera cacti), Nematocyst nematode (Cryphodera sp.), Potato cyst nematode (Globodera rostochiensis), Rice cyst nematode (heterodera elachista), Soybean cyst nematode (heter) dera glycines), such as clover cyst nematode (heterodera trifolii), as MELOIDOGYNIDAE, Arena rear root-knot nematode (Meloidogyne arenaria), camellia root-knot nematode (Meloidogyne camelliae), grass root-knot nematode (Meloidogyne graminis), northern root-knot nematode (Meloidogyne hapla), sweet potato root-knot nematode (Meloidogyne incognita ), Meloidogyne sp. ), Etc., DOLYLAIMIDA: As LONGIDORIDAE, Klongagarus nematode (Longidorus martini), Nagaridorisu sp., American oak nematode (Xiphinema sp.), Etc. , TRICHODORIDAE, Trichodorus sp., Etc., Acarina: TARSONEMIDAE, Polyphagotarsononemus latus, Stenotarsalemus Tau, A. tei), etc., as PYEMOTIDAE, such as Shiramidani (Pyemotes ventricosus), as EUPODIDAE, such as Mugidani (Penthaleus major), as TENUIPALPIDAE, grapes Hime spider mite (Brevipalpus lewisi), Chanohimehadani (Brevipalpus obovatus), Pineapple Princess spider mite (Dolichotetranychus florodanus), Kakihimehadani (Tenuipalpus zhizhilashivilia), etc., as TUCKERELLIDAE, Nukekena spider mite (Tuckerella pavoniformis), etc., as TETRANYCHIDAE, Clover spider mite (Bryobia pr) etiosa), fake clover mites (Bryobia rubrioculus), Anzuhadani (Eotetranychus boreus), Michinokuhadani (Eotetranychus geniculatus), Kurihadani (Eotetranychus pruni), Kono white spider mites (Eotetranychus sexmanaculatus), Smith spider mites (Eotetranychus smithi), Kurumihadani (Eotetranychus uncatus) , Oligonychus handoensis, Oligonychus ilicis, Oligonychus karamatus, Panonychus cit i), apple tick (Penonychus ulmi), tetanychus cinnabarinus, kanazawa tick (Tetanychus kanzawai), mite spider mite (Tetanychus urticae), mite spider mite (T) Aceria tulipae, Acarops pelekassi, Prunus mite (Aculus fockei), Acarus schlettendali, Calacarus carinata lepitrimerus vitis), Nashisabidani (Epitrimerus pyri), such as false pear rust mite (Eriophyes chibaensis), as ACARIDAE, Ashibutokonadani (Acarus siro), Mugikonadani (Aleuroglyphus ovatus), the bulb mite, Rhizoglyphus (Rhizoglyphus robini), such as Tyrophagus (Tyrophagus putrescentiae), Thysanura ( THYSANURA): LEPISMATIDAE, Yamato Shimi (Ctenolepisma villosa), Seimitsu Shimi (Lepisma saccharina), Spotted Shirami (Thermobia domestica), etc. As TIDAE, American cockroach (Periplaneta americana), black cockroach (Periplaneta fuliginosa), such as Yamato cockroach (Periplaneta japonica), as BLATTELLIDAE, German cockroach (Blattella germanica), such as Princess German cockroach (Blattella lituricollis), as TETTIGONIIDAE, Himekusakiri (Homorocoryphus jezoensis), As GRYLLOTALPIDAE such as Homocoryophys lineeosus, Kelly (Gryllotalpa sp. ), Etc. As ACIDIDAE, white ant (Oxya estroensis), termite (us), ant territory (ISO), ant territory (Coptermes domesticus), Formosanus, etc., THYSANOPTERA: As THRIPIDA, Asahitrips obscurus, Chirophips manicatus, Drosophila thrips hrips minowai), Hirazuhanaazamiuma (Frankliniella intonsa), lily flower thrips (Frankliniella lilivora), Croton thrips (Heliothrips haemorrhoidalis), Cosmos thrips (Microcephalothrips abdominalis), soybean thrips (Mycterothrips glycines), mulberry thrips (Pseudodendrothrips mori), yellow tea thrips ( Scirtotrips dorsalis), Acacia thrips (Selenotrips rubricinctus), Rice thrips (Stenchaetrips biformis), Ne Black thrips (Thrips alliorum), loquat Hana thrips (Thrips coloratus), Yellow Hana thrips (Thrips Flavas), Hana thrips (Thrips hawaiiensis), Japanese black Hana thrips (Thrips nigropilosus), Thrips palmi (Thrips palmi), western flower thrips ( Frankliniella occidentalis), Thrips setosus, Trips tabici, and Thulus thipidae. Kuda thrips (Haplothrips chinensis), Hana Kedah thrips (Haplothrips kurdjumovi), clover Kedah thrips (Haplothrips nigar), CHILLY tailed Kedah thrips ((Leeuwania pasanii), box Kedah thrips (Liothrips flordensis), Yuri Nokuda thrips (Liothrips vaneeckei), CHILLY Hemi IPTERA: PENTATOMIDAE, Carpocuris puroporispuris, Carpocurispuropurispuris, Carpocurispuropurispas Chihigekamemushi (Dolycoris baccarum), Himenagame (Eurydema pulchrum), longer (Eurydema rugosum), Mar Shirahoshi stink bug (Eysarcoris guttiger), giant thorns Shirahoshi bug (Eysarcoris lewisi), thorns Shirahoshi bug (Eysarcoris parvus), Shirahoshi stink bug (Eysarcoris ventralis), Blue-headed stink bug (Glaucias subpunctus), Red-headed bug (Graphosoma rubrolineatum), Red-headed bug (Halomomorpha mistula), Lagynotomus zea tennata), southern green stink bug (Nezara viridula), Piezodorus stink bug (Piezodorus hybneri), Plautia crossota stali (Plautia stali), rice black bug (Scotinophara lurida),
Such as Iwasaki stink bug (Stariodes iwasakii), as COREIDAE, nightshade stink bug (Acanthocoris sordidus), giant spiders helicopter stink bug (Anacanthocoris striicornis), bombardier Hari bug (Cletus punctiger), Hime Hari stink bug (Cletus trigonus), giant helicopter stink bug (Molipteryx fulginosa) ALYDIDAE, Leptocorisa acuta, Leptocorisa chinensis, Leptocorisa oratorius, Riptoratus, etc. , As RHOPALIDAE, red Hime helicopter stink bug (Aeschynteles maculatus), such as keyhole Hime helicopter stink bug (Liorhyssus hyalinus), as LYGAEIDAE, Kan mantis shrimp spring Naga bug (Cavelerius saccharivorus), bombardier co-spring Naga bug (Macropes obnubilus), Hirata gourd Naga stink bug (Pachybrachius luridus PYRRHOCORIDAE, Dysdercus cingulatus, Dyderdercus cingulatus D, etc. s poecilus), etc., as TINGIDAE, Kikugunbai (Galeatus spinifrons), Yanagigunbai (Metasalis populi), Kusugunbai (Stephanitis fasciicarina), Nashigunbai (Stephanitis sashi), Tsutsujigunbai (Stephanitis pyrioides), Himegunbai (Uhlerites debile), Kurumigunbai (Uhlerites latius), MIRIDAE, Adelphocoris lineolatus, Spotted brown turtle (Adelphocoris trianulatus), Coreo luculum (Apolygus lucorum), Tsumaguroa Kasumikame (Apolygus spinolai), red Hoshi Kasumi turtle (Creontiades pallidifer), tobacco Miridae (Cyrtopeltis tennuis), giant black Tobi Miridae (Ectometopterus micantulus), Black Kite Kasumi turtle (Halticiellus insularis), apple black Kasumi turtle (Heterocordylus flavipes), Makiba Miridae (Lygus disponsi ), Spotted turtle (Lygus saundersi), sugar beet turtle (orthotylus flavosparsus), wheat turtle (Stenodema calcaratum), stag beetle turtle (Stenotos binotat) us), red streaks Kasumi turtle (Stenotus rubrovittatus), mouse Mont green Miridae (Taylorilygus pallidulus), Trigonotylus caelestialium (Trigonotylus coelestialium), etc., as CICADIDAE, such as the large brown cicada (Graptopsaltria nigrofuscata), as APHROPHORIDAE, Maekiawafuki (Aphrophora costalis), Matsuawafuki (Aphrophora flavipes), grape awafuki (Aphrophora intermedia), himefutentenagawafuki (Clovia punctata), Hosoawafuki (Philaenus spumarius), etc., TET IGELLIDAE, such as Bothrogonia japonica and Cicellaella viridis, and CICADELLIDAE, Aguriahana cucumber, Ane, H. Arboridia apicaris, Edwardsiana flavescens, Edwardsiana roseae, Empoasca abietis, Emposca ai i Fences (Thaia subrufa), oranges Hime such as leafhoppers (Zyginella citri), as DELTOCEPHALIDAE, lid Ten leafhopper (Macrosteles fascifrons), green rice leafhopper (Nephotettix cincticeps), cross di leafhopper (Nephotettix nigropictus), Taiwan green rice leafhopper (Nephotettix virescens), apple spotted leafhopper (Orientus ishidai), Inazuma Dorsalis, Sorhoanus tritici, Swanusetixix subfusculus, etc., and DELPHACIDAE Te, small brown planthopper (Laodelphax striatellus), brown planthopper (Nilaparvata lugens), sugar Roh Humpback planthopper (Numata muiri), corn planthopper (Peregrinus maidis), Crofts Roh planthoppers (Perkinsiella saccharicida), Sejirounka (Sogatella furcifera), Hieunka (Sogatella panicicola), etc. , PSYLLIDAE, Anomeura mori, Calophia nigridorsalis, Diaphorina citri, Mesohomomomoto Todokijirami (Psylla abieti), Han'nokijirami (Psylla alni), Yamatokijirami (Psylla jamatonica), Ringokijirami (Psylla mali), black apple pheasant Rami (Psylla malivorella), Nashijikirami (Psylla pyrisuga), Toberakijirami (Psylla tobirae), hex Kurtosis pheasant Lami (Trioza camphorae), Tritoza quarcicola, and other ALEYRODIDAEs, Alecananthus spiniferus, Grape whitefly (Aleolobusus mirabilae) Lice (Dialeurodes citri), Onitsunajirami (Trialeurodes vaporiarum), Silverleaf whiteflies, etc. (Geoica lucifuga) and other APHIDIDAEs include pea aphid, Aphis citricola, Aphis caccivora, and Aphid aphid. farinose yanagicola), cotton aphid (Aphis gossypii), potato aphid (Aulacorthum solani), wheat straw chrysanthemum Omar aphid (Brachycaudus helichrysi), radish aphid (Brevicoryne brassicae), Tulip phylloxera (Dysaphis tulipae), birch cotton butterbur spotted aphid (Euceraphis punctipennis ), Hypotterus pruni, Yellow pea aphid (Lipaphis erysimi), Chrysanthemum aphid (Macrosifoniella samboni), Tulip genus aphid Shi (Macrosiphum euphorbiae), broad bean aphid (Megoura crassicauda), without Coffs key aphid (Melanaphis siphonella), apple Cobb aphid (Myzus malisuctus), plum Cobb aphid (Myzus mumecola), green peach aphid (Myzus persicae), green onion aphid (Neotoxoptera formosana), apple midori aphids (Ovatus malicolens), husubirea aphid (Rhopalosophum nymphaeae), rhinobola aphid (Rhopalosophum padi), rhodopodophyllum inalis, Aphid (Sappaphis piri), Nashiburamushi (Schizophis piricola), Aphidia aphid (Sitobion akebiae), tera aphid Peach aphids (Tuberocephalus momonis), Taiwancega aphids (Uroeucon formosanum), MARGARODIDAE, Dwarfia corporenta, Iceria scales (Icerasia, etc.) As DOCOCCIDAE, Matsumoto mealybugs (Crisicoccus matsumotoi), pine mealybug (Crisicoccus pini), without mealybugs (Dysmicoccus wistariae), mandarin orange mealybug (Planococcus citri), mealybug (Planococcus kranuhiae), mandarin orange Hime mealybugs (Pseudococcus citriculus ), Pseudococcus comstock, etc., as COCCIDAE, horned beetle (Ceroplastes ceriferus), ruby weevil (Ceroplastes rubens), citrus larvae (C) occus discrepans), Hirata Kata scale insects (Coccus hesperidum), citrus Kata scale insects (Coccus pseudomagnoliarum), Ibotaroumushi (Ericerus pela), Mizuki Kata scale insects (Lecanium corni), tea Roh Kata scale insects (Lecanium persicae), mandarin orange cotton scale insects (Pulvinaria aurantii), DIASPIDIDAE, such as citrus scale insects (Pulvinaria citricola), scallop scales (Pulvinaria kuwacola), and the like aurantii),
Aphidial cigarette (Aonidiella citrus), Asperiotus destructor, Asperiodus aphidus os moth Aphididae, scalloped moth, Spicy spider moth claviger), citrus scale insect (Lepidosaphes beckii), apple oyster scale scale (Lepidosaphes ulmi), white scale scale insect (Lepholeucaspis japonica), nacyclotype scale scale oreopsis pyri), camellia pteridae (Parlatoria camellia), pteroleum aphididae (Parlatoria zeiphi) Pseudaonidia paeonia), stag beetle (Pseudauracapsis pentagona), beetle scale (Pseudalucaspis punicola), worm scale (Unaspis yanonsis) A): bat moth (Endoclyta excrecens), yellow bat (Endoclyta sinensis), white bat (Palpifer sexota or physic physica) Ringworm (Archips brevipicanus), Midarekakumonmonmakaki (Archips fuscocuppreanus), Kakimon-ohamiki (Archips xylostaneus), Rabbitfish (Pactula furfurana), Hosobai cyprus Miga (Cydia kurokoi), chestnut green sink bur (Eucoenogenes aestuosa), oriental fruit moth (Grapholita molesta), Chahamaki (Homona magnanima), apple fruit moth (Hoshimoa adumbratana), soybean pod borer, Leguminivora glycinivorella (Leguminivora glycinivorella), Azukisayamushiga (Matsumuraeses azukivora), Daizusayamushiga ( Matsumuraeses falcana, Matsumuraeses phaseli, Apples, Spilonota lechriaspis, Spironota ocellana, Bud Eupoecilia ambiguella, Kwaihoso umami (Phalonidia mesotypa), Artemisia vulgaris (Pheochloroides clinestina), Minoga (Bambalina sp. ), Oominoga (Eumeta japonica), Chaminoga (Eumeta minuscule), carvings (Nemapogon granellus), clothes moth (Tinea translucens), Nashichibiga (Bucculatrix pyricorella), Momohamoguriga (Lyonetia clerkella), Gin Mont leafminer (Lyonetia prunifoliella), Mamehosoga (Caloptilia soyella ), Chalothosiga (Caloptilia zeivosa), Oyster hosoga (Choptipes diospyrosella), Kinmonhosoga (Phyllonolycter lingonella), Nashihoso (Spulerina astaurota), mandarin orange leafminer (Phyllocnistis citrella), grape leafminer (Phyllocnistis toparcha), Negikoga (Acrolepiopsis sapporensis), yam Koga (Acrolepiopsis suzukiella), diamondback moth (Plutella xylostella), apple Hime sink Lee (Argyresthia conjugella), grapes Sukashiba ( Paranthrene regalis, Cosca shiba (Synanthedon hector), Kakinoheta mushiga (Stathmopoda masinissa), Japanese mosquito (Brachimia triannulella), Peach tiger moth (Ca posina niponensis), apple moth black bar (Illiberis pruni), Kuroshitaaoiraga (Lotoia sinica), monema flavescens (Monema flavescens), Nashiiraga (Narosoideus flavidorsalis), Aoiraga (Parasa consocia), Himekuroiraga (Scopelodes contracus), rice stem borer (Chilo suppressalis), leaf roller ( Cnaphalocrosis medinalis), Conogethes puntiferials, Cotton moth, Diaphania indica, Ectomyelois pyrivorella Ephestia kühniella, Eleuella zinkkenella, iexa algae, eu, Mera, Glyphodes pyloalis Maruca testulalis, Cotton moth (Nottarcha derogate), Green moth (Ostrinia furnacalis), Azukino moth (Ostrinia scapularis), Ostrinia zapa tei Tega rella), Ukon'nomeiga (Pleuroptya ruralis), Sankameiga (Scirpophaga incertulas), parnara guttata (Parnara guttata), Papilio Helenus (Papilio helenus), the common yellow swallowtail (Papilio machaon hippocrates), swallowtail (Papilio xuthus), Colias erate (Colias erate poliographus), cabbage butterfly ( Pieris rapae crucivora, Lampids boeticus, Prunus serrata (Agerona prunaria), Ascotis sennaria, squirrel buoy tum), Umeedashaku (Cystidia couaggaria), pine moth (Dendrolimus spectabilis), lackey moth (Malacosoma neustria testacea), Ringokareha (Odonestis pruni japonensis), Cephonodes Hylas (Cephonodes hylas), grapes sparrows (Acosmeryx castanea), Tsuyama red killer whale pike (Clostera anachoreta) , Crestera anastomosis, Monarch killer whale (Phalera flavescens), Greater tiger killer whale (Phalerodonta mannleyi), Orchard moth (Stauropus fagi persi) ilis), Arna Pseudoconspersa (Euproctis pseudoconspersa), Monshirodokuga (Euproctis similes), tussock (Euproctis subflava), gypsy moth (Lymantria dispar), orgyia thyellina (Orgyia thyellina), the United States white Arctiidae (Hyphantria cunea), mulberry tiger moth (Spilosoma imparilis), Honey beetle (Acanthoplusia agnata), akajiroshitaba (Aedia leucomelas), agaricus (Agrotis sipetum), cabbage moth (Agrotis segetum), red-bellied moth (Anomis estagona) grapha nigrisigna), Trichoplusia ni (Trichoplusia ni), cotton bollworm (Helicoverpa armigera), tobacco budworm (Helicoverpa assulta), Heliothis maritima (Heliothis maritime), cabbage armyworm (Mamestra brassicae), Futaobikoyaga (Naranga aenescens), armyworm (Pseudaletia separata), Ineyotou ( Sesamia inferens, Spodoptera deprava, Spodoptera exigua, Spodoptera litura, Trikenea teredain a), Nashikenmon (Vimnia rumicis), Shiromonagaga (Xestia c-nigurum), Coleoptera (Coleoptera), Adoretus tenamua cucumber (Anoretus tenumuculatus), Douganebububu (Anomala cucumber) Eumetonia roelofsi, Heptophylla picea, Melonthonia japonica, Mimela splendens, Oxycetoniae Main circle beetle (Anthrenus verbasci), Hime beetle (Attagenus unicolor japonicus), cigarette beetle (Lasioderma serricorne), Hirata beetle (Lyctus brunneus), Guy My Deo kiss Lee (Carpophilus dimidiatus), clear Keshikisui (Carpophilus hemipterus), giant beetle, Epilachna ya Hoshi Tento (Epilachna vigintioctomacula), Nijuya hoshi tentou (Epilachna vigintioctopuncta), Japanese algae (Alphitobius laevigatatus), Nearumidae , Princess red flour beetle (Palorus ratzeburgii), co-Hime red flour beetle (Palorus subdepressus), Chai Loco Meno mealworm (Tenebrio molitor), red flour beetle (Tribolium castaneum), Hirata red flour beetle (Tribolium confusum), beans Beetle (Epicauta gorhami), macular Beetle (Aeolesthes chrysothrix),
Gomadarakamikiri (Anoplophora malasiaca), Japanese pine sawyer (Monochamus alternatus), Kiboshi beetle (Psacothea hilaris), grapes tiger beetle (Xylotrechus pyrrhoderus), Blue streaks Beetle (Xystrocena globosa), adzuki bean weevil (Callosobruchus chinensis), cucurbit leaf beetle (Aulacophara femoralis), brown Monkey potato beetle (Basilepta balii), potato beetle (Cassida nebulosa), beetle potato beetle (Chaetocnema concinna), tuber beetle (Colasosoma dauricum) Binagahamushi (Crioceris quatuordecimpunctata), Inenekuihamushi (Donacia provosti), Rurihamushi (Linaeidea aenea), Kiashinomihamushi (Luperomorpha tunebrosa), lid streaks Anthrenus Beetle (Medythia nigrobilineata), Inedorooimushi (Oulema oryzae), Anthrenus key spring monkey Beetle (Pagria signata), Japanese radish beetle (Phaedon brassicae), Phyllotretta striola, Japanese beetle weevil (Involvulus cupreus), Japanese beetle weevil (Rhynchites heros), Arimodoki weevil las formicarius), apple weevil (Anthonomus pomorum), die consulting weevil (Ceuthorhynchidius albosuturalis), chestnut weevil (Curculio sikkimenesis), rice weevil (Echinocnemus squameus), Imozoumushi (Euscepes postfasciatus), clover weevil (Hypera nigrirostris), alfalfa weevil (Hypera postica), Rice weevil (Lissohoptrus oryzophilus), Yasai weevil (Listroderes costirostris), Apple weevil (Phyllobius ar Masuus, Citrobium weevil (Sitona japonicus), Butterflies weevil (Sitophilus oryzae), Butterfly weevil (Sitophilus zeamais), Bamboo weevil (Sphaphirus venatas) Rosae tuficornis, Arge mary, Arge paganas, Dripotesmus kuriphilus, etc. Diptera: Dipterae tis), soybean pod gall midge (Asphondylia sp. ), Melon fly (Dacus cucurbitae), oriental fruit fly (Dacus dorsalis), Mikanbae (Dacus tsuneonis), cherry Leaf Spot fruit fly (Rhacochlaena japonica), Inemigiwabae (Hydrellia griseola), rice click Kimi Giwa fly (Hydrellia sasakii), cherry fruit fly (Drosophila suzukii), Rice fly (Chlorops oryzae), Wheat fly (Meromuza nigriventris), Rice fly (Agromyza oryzae), Brown fly (Chromatomia horticola), Eggplant Formic leafminer (Liriomyza chinensis), legume leafminer (Liriomyza trifolii), tomato leafminer (Liriomyza sativae), reed Gros leafminer (Liriomyza huidobrensis), onion maggot (Delia antiqua), seedcorn maggot (Delia platura), sugar beet diving Hana fly (Pegomya cunicularia), House flies (Musca domestica), Black flies (Formia regina), Culex pipiens parallels quillett, Chikae pikenes (Culex pipiens molestus Forscal) eles) sinensis Wiedemann), Aedes albopictus (Aedes albopictus (Skuse)) but the like, but is not limited thereto.

  Hereinafter, the present invention will be described more specifically with reference to formulation examples and test examples. However, the present invention is not limited only to formulation examples and test examples. In addition, all the compounding parts of each component described in the following formulation examples mean parts by weight.

Formulation Example 1 Flowable agent (a1)
Toluprocarb (2 parts), triflumezopyrim (10 parts), propylene glycol (7 parts), sodium lignin sulfonate (4 parts), dioctyl sulfosuccinate sodium salt (2 parts) and water (to a total of 100 parts) , Used as the remainder) was wet-ground with a sand grinder to obtain a flowable agent (a1).

Formulation Example 2 Flowable Agent (b1)
A flowable agent (b1) was obtained in the same manner as in Preparation Example 1, except that the content of tolprocarb was 4 parts.

Formulation Example 3 Granule (c1)
Toluprocarb (4 parts), triflumezopyrim (0.75 parts), bentonite 23 parts, calcium carbonate 70.25 parts and Solpol 5060 (anionic surfactant: Toho Chemical Industries, Ltd., trade name) 2 parts water And kneaded uniformly, granulated with a basket type granulator and dried to obtain granules (c1).

Formulation Example 4 Granule (c2)
Toluprocarb (4 parts), triflumezopyrim (0.75 parts), chlorantraniliprole (0.75 parts), bentonite 66 parts, talc 24.5 parts, sodium dodecylbenzenesulfonate 1 part, polyoxyethylene alkyl Water was added to 1 part of aryl ether and 2 parts of sodium lignin sulfonate, and the mixture was uniformly kneaded, granulated with a basket type granulator and dried to obtain granules (c2).

Formulation Example 5 Granule (c3)
Toluprocarb (4 parts), triflumezopyrim (0.75 parts), chlorantraniliprole (0.75 parts), cimeconazole (4.5 parts), bentonite 66 parts, talc 20 parts, sodium dodecylbenzenesulfonate 1 Water, 1 part of polyoxyethylene alkylaryl ether and 2 parts of sodium lignin sulfonate were added and kneaded uniformly, granulated with a basket type granulator and dried to obtain granules (c3). .

Comparative Formulation Example 1 Flowable agent (a2 and a3)
A flowable agent (a2 and a3, respectively) was obtained in the same manner as in Formulation Example 1 except that only one of tolprocarb and triflumezopyrim was included.

Comparative Formulation Example 2 Flowable Agent (b2)
A flowable agent (b2) was obtained in the same manner as in Formulation Example 2, except that only tolprocarb was contained.
Comparative Formulation Example 3 Granules (c4 and c5)
Granules (c4 and c5, respectively) were obtained by the same method as in Formulation Example 3, except that only one of tolprocarb and triflumezopyrim was included.

Test Example 1 Rice Blast Prevention Test (Spray Test)
In a greenhouse, rice (cultivar: Kofu) planted in a plastic pot having a diameter of 5 cm was grown to the 3-4 leaf stage. The flowable agents a1, b1, a2, b2 and a3 prepared in Formulation Examples 1 and 2 and Comparative Formulation Examples 1 and 2 were diluted and sprayed, respectively. After the drug solution was dried, a conidial spore suspension prepared from blast fungus previously cultured on oatmeal medium was spray-inoculated. Then, the pot was put in the humidity chamber of the artificial inoculation room (20-23 ° C.), taken out the next day, and moved to the greenhouse. The control effect was investigated 7 days after the inoculation. In the investigation, the number of lesions per one pot of rice was counted, and the control value and the theoretical value by the Colby equation were calculated. The results are shown in Table 1.
The control value was calculated from the following formula.
Control value = (1−number of lesions in treated area / number of lesions in untreated area) × 100
The synergistic effect was determined by the Colby formula (see Weeds 15 (1967), 2022). The Colby equation is X = P + Q−P × Q / 100, where X is the theoretical value of the control value, P is the control value when a certain agent is sprayed alone, and Q is This is the control value when the drug used in combination is sprayed alone. When the actually measured effect was larger than the effect X (theoretical value) calculated by the above Colby equation, it was determined that the action of the combination of the two active ingredients was synergistic.

  From the results in Table 1 above, it was found that when tolprocarb and triflumezopyrim were used in combination, a synergistic effect was obtained. In addition, even if tolprocarb and triflumezopyrim were used in combination, no phytotoxic symptoms were observed in plant rice (variety: Kofu).

Test Example 2 Rice Blast Prevention Test (Granule Treatment Test)
After transplanting rice seedlings (variety: Koshihikari) into a 1 / 10,000 are plastic pot in a greenhouse and growing for 10 days, the granules c1, c4 and c5 of Preparation Example 3 and Comparative Preparation Example 3 were respectively The pot was processed and grown for another 9 days. After spray-inoculating a conidial spore suspension prepared from a blast fungus to be cultured on an oatmeal medium in advance, a pot was placed in a humid chamber in an artificial inoculation chamber (20 to 23 ° C.). The control effect was investigated 7 days after the inoculation. In the survey, the number of lesions per one pot of rice was counted, and the control value and the theoretical value by Colby's formula were also calculated in the same manner as in Test Example 1. The results are shown in Table 2.

  From the results of Table 2 above, it was found that when tolprocarb and triflumezopyrim were used in combination, a synergistic effect was obtained. In addition, even if tolprocarb and triflumezopyrim were used in combination, no phytotoxic symptoms were observed in plant rice (variety: Koshihikari).

Test Example 3 Rice Blast Prevention Test (Granule Treatment)
In a greenhouse, a rice seedling (variety: Koshihikari) was transplanted into a 1 / 10,000 are plastic pot and allowed to grow for 10 days, and then granules c1, c2 and c3 of Preparation Examples 3, 4 and 5 were respectively added. The pot was processed and grown for another 9 days. After spray-inoculating a conidial spore suspension prepared from a blast fungus to be cultured on an oatmeal medium in advance, a pot was placed in a humid chamber in an artificial inoculation chamber (20 to 23 ° C.). The control effect was investigated 7 days after the inoculation. In the survey, the number of lesions per one pot of rice was counted and the control value was calculated. The results are shown in Table 3.

  From the results of Table 3 above, when chlorantraniliprole was used in combination with tolprocarb and triflumezopyrim, and also when cimeconazole was used in combination, it was the same as when toluprocarb and triflumezopyrim were used together for rice blast disease. High effect was shown. In addition, when chlorantraniliprole was used in combination with tolprocarb and triflumezopyrim, and when cimeconazole was further used, no phytotoxicity was observed in rice (variety: Koshihikari).

Test Example 4 Insecticidal test against brown planthopper (granule treatment)
The granules c1, c2 and c3 of Formulation Examples 3, 4 and 5 were respectively treated in a 1 / 5,000 are plastic pot (variety: Koshihikari; 4-leaf stage) on which rice was grown. After hatching the plastic pot, 10 adult females of the brown planthopper were placed 19 days after treatment, and the number of survivors was examined 5 days later, and the death rate was calculated (3 units per 10 wards). The results are shown in Table 4.

  From the result of the said Table 4, in any agent containing tolprocarb and triflumezopyrim, the high insecticidal effect was shown with respect to the brown planthopper. In addition, no phytotoxicity was observed in rice (variety: Koshihikari) when any preparation was treated.

  The plant pest control composition of the present invention has an excellent control effect (synergistic control) against various plant pests (for example, rice blast (Pyricularia oryzae)) that cannot be expected from tolprocarb or triflumezopyrim alone. By exhibiting (effect), a high plant pest control effect is exhibited. Furthermore, since no occurrence of phytotoxicity is observed in the plant, it can be used as an excellent plant pest control agent.

Claims (10)

A plant pest control composition comprising tolprocarb and Triflumezopyrim as active ingredients (however, (i) tolprocarb and triflumezopyrim and a compound represented by the following general formula (1) And (ii) a pest control composition comprising tolprocarb, triflumezopyrim, flametopil and a compound represented by the following general formula (1), (iii) tolprocarb, triflumezopyrim and penflufen And a pest control composition containing the compound represented by the following general formula (1).

[In the formula, A ¹ represents —NR ⁷ —, an oxygen atom or a sulfur atom, A ² represents ═N—, ═N (→ O) — or ═CR ⁸ —, and Q represents ═N— or ═N (→ O)-
R ¹ represents a Cl—C 6 alkyl group which may have one or more atoms or groups selected from group X;
R ² , R ³ and R ⁴ are the same or different and are a Cl—C 6 alkyl group optionally having one or more atoms or groups selected from group X, —OR ¹⁰ , —S (O) _m R _{^{10, -S (O) 2 NR}} 10 R ll, -NR 10 R ll, -NR 10 CO 2 R ll, -NR 10 C (O) R ll, -CO 2 R l0, -C (O) R l0 ^{, -C (O) NR 10 R} ll, -SF 5, a cyano group, a nitro group, a halogen atom or a hydrogen atom,
R ⁵ and R ⁶ are the same or different and are a Cl—C 6 alkyl group optionally having one or more atoms or groups selected from group X, —OR ¹⁰ , —S (O) _m R ¹⁰ , — _{^{S (O) 2 NR 10 R}} ll, -NR 10 R ll, -NR 10 CO 2 R ll, -NR 10 C (O) R ll, -CO 2 R l0, -C (O) R l0, -C ^{(O) NR 10 R ll,} -OC (O) R l0, -SF 5, a cyano group, two Bokuromoto represents a halogen atom or a hydrogen atom (provided that ^{the R 5} and ^{R 6} represent a hydrogen atom at the same time Not)
R ⁷ is a Cl—C 6 alkyl group, —CO ₂ R ¹⁰ , —C (O) R ¹⁰ , —CH ₂ CO ₂ R ¹⁰ , which may have one or more atoms or groups selected from group W ; Represents a C3-C6 cycloalkyl group or a hydrogen atom,
R ⁸ is 1 or more halogen atoms optionally may C1-C6 alkyl group which may _{^{have, -OR 10, -S (O)}} m R 10, -NR 10 R ll, -CO 2 R 10, -C ( O) represents R ¹⁰ , a cyano group, a two-necked group, a halogen atom or a hydrogen atom,
R ¹⁰ and R ¹¹ are the same or different and each represents a C1-C6 alkyl group or a hydrogen atom which may have one or more atoms or groups selected from group X (provided that —S (O) _m R ¹⁰ , when m is 1 or 2, R ¹⁰ does not represent a hydrogen atom)
m independently represents 0, 1 or 2, and n represents 0, 1 or 2.
Group X: C1-C6 alkoxy group optionally having one or more halogen atoms, C3-C6 alkyl group optionally having one or more halogen atoms or one or more C1-C3 alkyl groups A group consisting of an alkyl group, a cyano group, a hydroxy group and a halogen atom.
Group W: C1-C6 alkoxy group which may have one or more halogen atoms, C3-C6 alkyl group which may have one or more halogen atoms, hydroxy group, halogen atom and cyano A group of groups. ]) As an active ingredient, Torupurokarubu (Tolprocarb) and tri full meso and pyridinium arm (Triflumezopyrim), further chlorantraniliprole (Chlorantraniliprole) and / or simeconazole (Simeconazole) and plant pest control composition characterized in that it contains.   The plant pest control composition according to any one of claims 1 and 2, wherein the plant is rice.   The plant pest control composition according to any one of claims 1 to 3, wherein the plant pest is rice blast.   The plant pest control composition according to any one of claims 1 to 4, wherein the plant pest is Pyricularia oryzae.   A method for controlling plant pests, which comprises applying the plant pest control composition according to any one of claims 1 to 5.   The method according to claim 6, wherein the plant is rice.   The method according to any one of claims 6 and 7, wherein the plant pest is rice blast.   The method according to any one of claims 6 to 8, wherein the plant pest is Pyricularia oryzae.   Apply a plant pest control composition containing tolprocarb as an active ingredient and a plant pest control composition containing triflumezopyrim as an active ingredient, or a plant pest control composition and triflumezopyrim containing tolprocarb as an active ingredient A method for controlling plant pests, which comprises applying any one of the plant pest control compositions contained as an active ingredient and then applying the other composition.