JP6620226B2 - Agricultural and horticultural compositions - Google Patents

Description

  The present invention relates to a novel combination agricultural and horticultural composition and a method for controlling plant diseases or plant pests using the composition.

  Many chemical agents have been used for plant pest control. In order to control various plant pests that occur, it is common to use multiple drugs, but for reasons such as saving labor for users, drugs containing two or more active ingredients (mixtures) In some cases, a plurality of chemicals may be treated simultaneously, such as by treating several chemicals in a farmer's field using a tank mix method.

  Torprocarb according to the present invention is a diamine derivative that exhibits a plant disease control action, and has been found to exhibit a high control effect especially against rice blast (Pyricularia oryzae) (Patent Document 1). In Patent Document 2, a pest control composition containing a diamine derivative containing tolprocarb and one or more compounds selected from the group consisting of other fungicides, insecticides and acaricides, and pests using them. A control method is disclosed.

  Further, mandestrobin, which is a strobilurin-based compound related to the present invention, is a racemic compound according to an agrochemical abstract (edited by Sumitomo Chemical Co., Ltd .; Non-Patent Document 1), and R-form 50% and S-form 50. % (CAS NO. 173662-97-0). This compound is a known compound disclosed as Example 5 (Compound 140) in Patent Document 3 (WO 1995/027693). It is disclosed that the compound exhibits a controlling effect against rice blast, cucumber powdery mildew, cucumber downy mildew and wheat powdery mildew (see Patent Document 3). Patent Document 4 (WO 2010/061940) discloses a compound (formulation) of the R-form compound (1a) or the racemic compound (1b) as a main agent, for example, methconazole, which is an azole compound. Examples 14 and the like) and admixtures (such as Formulation Example 13) with ipconazole are disclosed (see Patent Document 4). The former is a tank mix of mandestrobin wettable powder and metconazole formulation, and disclosed that it has a synergistic control effect against cucumber gray mold in Test Example 1 and cucumber seedling blight in Test Example 2. Has been. The latter is a tank mix of mandestrobin wettable powder and ipconazole formulation, and disclosed that it has a synergistic control effect on cucumber gray mold fungus in Test Example 3 and cucumber seedling fungus in Test Example 4 Has been. Here, the compound (1a) was prepared by CAS NO. 394657-24-0, and compound (1b) was prepared as CAS NO. It is registered as 173662-97-0.

  On the other hand, cyclaniliprole (CAS No. 1031756-98-5), which is a diamine compound, is compound No. 1 in Table 1 of Patent Document 5 (WO2005 / 077934). No. 16, which is a known compound, for example, has been disclosed for its control effect against Lotus moth, silver leaf whitefly, and the like (see Patent Document 5). Patent Document 6 (US2014 / 0249187) discloses cyclanilipol as compound II, which includes a mixture of the compound and the compound group represented by general formula I, and discloses insecticidal action. (See Patent Document 6).

  Tetraniliprole, which is also a diamine-based compound, is a known compound disclosed as Compound 12 in Patent Document 7 (WO2010 / 066952), for example, mustard beetle (Phaedon cochleariae), Insecticidal activity against worms and the like of Yodoga (Spodoptera frugiperda) is disclosed (see Patent Document 7). Further, Patent Document 8 (WO2014 / 083031) discloses a bactericidal action of a mixture of tetraniliprole (Tetraniliprole), compound I-1 and cyantraniprole (Cyantraniprole), which are disclosed as bactericidal action. (See Patent Document 8).

WO2005 / 042474 WO2006 / 106811 WO1995 / 027693 WO2010 / 061940 WO2005 / 077934 US2014 / 0249187 WO2010 / 066952 WO2014 / 083031

Agricultural chemical abstract Sumitomo Chemical Co., Ltd. March 7, 2013

However, in the case of the treatment by the mixture or mixed use described above, for example, in the case of a combination of drugs that are not compatible, there are many risks that the effects of each other's drugs will be reduced or that the plant body will be phytotoxic. To do.
Under such circumstances, there is a demand for an agricultural and horticultural composition comprising a combination that exhibits a high effect with a lower amount of active ingredient and that suppresses phytotoxicity to plants.

As a result of intensive studies on the combination of Tolprocarb and other drugs, the present inventors have found that, according to a predetermined combination, for example, plant pests such as rice blast can not be predicted from a single component and excellent control is achieved. An effect (synergistic effect) was obtained, and it was found that the occurrence of phytotoxicity was suppressed, and the present invention was completed.
That is, the object of the present invention is to provide a new control combination that exhibits a high control effect on plant pests, exhibits high activity even when the amount of active ingredients administered to the pest habitat is low, and further suppresses phytotoxicity to plants. It is to provide an agricultural and horticultural composition and a method for controlling plant diseases or plant pests using the composition.

The combination of the present invention is a novel invention which is not disclosed in any of Patent Documents 1 to 8.
The present invention is a new combination agricultural and horticultural composition that exhibits a high control effect against plant pests, exhibits high activity even when the amount of active ingredient administered to the pest habitat is low, and further suppresses phytotoxicity to plants The present invention relates to a method for controlling plant diseases or plant pests using the product and its composition.

The present invention
1) (a) Tolprocarb,
(B) a man dest Robin (Mandestrobin) or at least one compound a salt thereof, and consequent Rani descriptor roll (Cyclaniliprole) or a salt thereof, is selected from,
An agricultural and horticultural composition containing as an active ingredient,
2) (a) Tolprocarb,
(B) tetraniliprole or a salt thereof;
A composition for agricultural and horticultural use (excluding cases containing a carboxamide compound),
3) The agricultural or horticultural composition according to 1) or 2), which is used for controlling plant diseases or controlling plant pests;
4) The agricultural and horticultural composition according to 3), which is used for controlling rice diseases or rice pests,
5) The agricultural or horticultural composition according to 3), wherein the plant disease is rice blast or rice blight
6) The agricultural or horticultural composition according to 3), wherein the plant disease is rice blast.
7) A method for controlling plant diseases or plant pests, which comprises applying the agricultural or horticultural composition according to any one of 1) to 6) to plants, seeds or soil,
8) the following agricultural and horticultural composition (i) and (ii) at the same time, plants, or applied to seeds or soil, or the following agricultural and horticultural composition one of (i) and (ii), plants, seeds or A method for controlling plant diseases or plant pests , wherein the other is applied after applying to the soil;
Agricultural and horticultural composition (i): Torupurokarubu (a) a as an active ingredient a composition for agricultural or horticultural use composition (ii): Man dest robin or a salt thereof and from consequent Rani descriptor roll or a salt thereof, is selected A composition containing at least one compound (b) as an active ingredient,
9) Apply the following agricultural and horticultural compositions (i) and (iii) simultaneously to plants, seeds or soil, or apply one of the following agricultural and horticultural compositions (i) and (iii) to plants, seeds or A method for controlling plant diseases or plant pests, wherein the other is applied after applying to the soil (provided that the agricultural and horticultural compositions (i) and (iii) include a carboxamide compound);
Agricultural and horticultural composition (i): a composition comprising tolprocarb (a) as an active ingredient
Agricultural and horticultural composition (iii): a composition containing, as an active ingredient, compound (b) which is tetraniliprole or a salt thereof,
10) Apply the following agricultural and horticultural compositions (i) and ( ii ) simultaneously to plants, seeds or soil, or apply one of the following agricultural and horticultural compositions (i) and ( ii ) to plants, seeds or soil A method for controlling plant diseases or plant pests, which is applied to the other and then the other;
Agricultural and horticultural composition (i): a composition containing tolprocarb (a) as an active ingredient Agricultural and horticultural composition ( ii ): a composition containing compound (b) which is mandestrobin or a salt thereof as an active ingredient ,
11) Apply the following agricultural and horticultural compositions (i) and (iv) simultaneously to plants, seeds or soil, or apply one of the following agricultural and horticultural compositions (i) and (iv) to plants, seeds or soil A method for controlling plant diseases or plant pests, which is applied to the other and then the other;
Agricultural and horticultural composition (i): a composition containing tolprocarb (a) as an active ingredient Agricultural and horticultural composition (iv): a composition containing cyclanilipol or a salt thereof (b) as an active ingredient Stuff,
About.

  The composition for agricultural and horticultural use of the present invention is each of a diamide compound or a salt thereof selected from the group of compounds consisting of tolprocarb, a strobilurin compound that is mandestrobin or a salt thereof, or cyclaniliprol and tetraniliprol. An excellent control effect (synergistic control effect) that cannot be predicted from a single component can be exhibited. Furthermore, the agricultural and horticultural composition suppresses phytotoxicity to plants.

  Hereinafter, the present invention will be described by “agro-horticultural composition” as the first invention and “a plant disease or plant pest control method” as the second invention.

[Agricultural and Horticultural Composition]
The composition for agriculture and horticulture, which is the first invention, is characterized by combining tolprocarb and the partner in the present invention. The “partner agent in the present invention” is a stramide-line compound or a salt thereof, which is mandestrobin, or a diamide compound selected from cyclaniliprol and tetraniliprole. Means at least one compound selected from the salts thereof. Preferably, it is mandestrobin or cyclanilipol or tetraniliprole, and mandestrobin or cyclanilipol is more preferable.
In addition, tolprocarb and the partner in the present invention are known compounds, and are produced, for example, according to the methods described in WO2005 / 042474, WO1995 / 027693, WO2005 / 077934 and WO2010 / 066952, respectively. be able to.
The composition for agriculture and horticulture of the present invention can be used as a plant disease control composition or a plant disease control composition.

The agricultural and horticultural composition of the present invention can be produced according to a conventional method. That is, the agricultural and horticultural composition can be prepared by mixing a composition containing tolprocarb and the active ingredient of the partner in the present invention to produce a composition containing both active ingredients. A composition containing both active ingredients may be produced by adding other active ingredients to the composition containing. Usually, the said composition for agriculture and horticulture is manufactured using the mixture which mixed both active ingredients. The agricultural and horticultural composition of the present invention can be used by further mixing a carrier with the obtained agricultural and horticultural composition, and if necessary, a surfactant, a wetting agent, a fixing agent, a thickener. Add formulation adjuvants such as preservatives, colorants, stabilizers, etc. and formulate into wettable powders, flowable powders, wettable powder granules, powders, emulsions, granules, packs, etc. in a timely manner according to conventional methods. Can be
The pack agent means a preparation in which granules, wettable powder and the like are packaged with a water-soluble film.

  The content of tolprocarb as an active ingredient in these preparations is usually 0.005 to 99% by weight, preferably 0.1 to 90%, and more preferably, It is in the range of 0.3 to 80%. In addition, the content of the partner in the present invention as an active ingredient in these preparations is usually in the range of 0.005 to 99% by weight, and preferably in the range of 0.1 to 90%. Yes, and more preferably 0.3 to 80%. These contents can be appropriately combined.

  The total content of tolprocarb and the partner in the present invention is usually in the range of 0.01 to 99%, preferably in the range of 0.1 to 90%, and more preferably in the range of 0.1 to 90%. It is 3 to 80% of range. The mixing ratio of tolprocarb and the partner in the present invention is usually a ratio by weight, and the ratio of the partner in the present invention to tolprocarb is 0.01 to 1000, preferably 0.02 to 100, More preferably, the ratio is 0.05 to 10.

  In the agricultural and horticultural composition of the present invention, the total content of tolprocarb and the partner in the present invention varies depending on the form of the preparation and is appropriately selected. 1 to 80% by weight for flowables, 0.1 to 80% by weight for wettable powders, 0.01 to 30% by weight for powders, and 0. 5 to 20% by weight, 1 to 50% by weight for the emulsion, and 1 to 80% by weight for the pack.

  The preferred total content of tolprocarb and the partner in the present invention is usually 5 to 80% by weight for wettable powders, 1 to 60% by weight for flowable powders, and 1 to 1 for granular wettable powders. 80% by weight, 0.05 to 10% by weight for powders, 2 to 15% by weight for granules, 5 to 50% by weight for emulsions, 5 to 80% for packs %.

  Further preferable total content is usually 10 to 80% by weight for wettable powders, 5 to 50% by weight for flowables, 5 to 80% by weight for granular wettable powders, and for powders. 0.1 to 10% by weight, 2 to 10% by weight for granules, 5 to 20% by weight for emulsions, and 10 to 80% by weight for packs. The content of the auxiliary agent is 0 to 80% by weight, and the content of the carrier is an amount obtained by subtracting the content of the active ingredient compound and the auxiliary agent from 100% by weight of the composition.

  The carrier used in the above composition is a synthetic or natural inorganic or organic compounded to help the active ingredient reach the site to be treated and to facilitate the storage, transportation and handling of the active ingredient compound. It means a substance and can be used as a solid or liquid as long as it is usually used in agricultural and horticultural medicines, and is not limited to a specific one.

  Specific examples of the solid carrier include, for example, inorganic substances such as bentonite, montmorillonite, kaolinite, diatomaceous earth, white clay, talc, clay, vermiculite, gypsum, calcium carbonate, amorphous silica, ammonium sulfate; soy flour, wood flour, sawdust Plant organic substances such as wheat flour, lactose, sucrose, and glucose; or urea.

  Specific examples of the liquid carrier include aromatic hydrocarbons and naphthenes such as toluene, xylene and cumene; paraffinic hydrocarbons such as n-paraffin, iso-paraffin, liquid paraffin, kerosene, mineral oil and polybutene; Ketones such as acetone and methyl ethyl ketone; Ethers such as dioxane and diethylene glycol dimethyl ether; Alcohols such as ethanol, propanol and ethylene glycol; Carbonates such as ethylene carbonate, propylene carbonate and butylene carbonate; Non-protons such as dimethylformamide and dimethyl sulfoxide An organic solvent; or water.

  Further, in order to enhance the efficacy of the active ingredient in the composition of the present invention, an adjuvant is used either alone or in combination depending on the purpose, taking into consideration the dosage form, processing method, etc. of the preparation. You can also. Examples of auxiliary agents include surfactants, binders, disintegrants, stabilizers, pH adjusters, antibacterial / antifungal agents, thickeners, antifoaming agents, antifreeze agents, and the like.

  Usually, surfactants used for the purpose of emulsifying, dispersing, spreading and / or wetting agricultural chemical formulations are, for example, sorbitan fatty acid ester, polyoxyethylene sorbitan fatty acid ester, sucrose fatty acid ester, polyoxyethylene fatty acid Formalin condensation of ester, polyoxyethylene resin acid ester, polyoxyethylene fatty acid diester, polyoxyethylene castor oil, polyoxyethylene alkyl ether, polyoxyethylene alkyl phenyl ether, polyoxyethylene dialkyl phenyl ether, polyoxyethylene alkyl phenyl ether , Polyoxyethylene polyoxypropylene block polymer, alkyl polyoxyethylene polyoxypropylene block polymer ether, alkylphenyl polyoxye Len polyoxypropylene block polymer ether, polyoxyethylene alkylamine, polyoxyethylene fatty acid amide, polyoxyethylene bisphenyl ether, polyoxyalkylene benzyl phenyl ether, polyoxyalkylene styryl phenyl ether, polyoxyalkylene adduct of higher alcohol and Nonionic surfactants such as polyoxyethylene ether and ester type silicone and fluorine-based surfactants; alkyl sulfates, polyoxyethylene alkyl ether sulfates, polyoxyethylene alkyl phenyl ether sulfates, polyoxyethylene benzyl phenyl ether sulfates, poly Oxyethylene styryl phenyl ether sulfate, polyoxyethylene polyoxy Propylene block polymer sulfate, paraffin sulfonate, alkane sulfonate, AOS, dialkyl sulfosuccinate, alkyl benzene sulfonate, naphthalene sulfonate, dialkyl naphthalene sulfonate, formalin condensate of naphthalene sulfonate, alkyl diphenyl ether disulfonate, lignin sulfonate, polyoxyethylene alkyl phenyl ether sulfonate , Polyoxyethylene alkyl ether sulfosuccinic acid half ester, fatty acid salt, N-methyl-fatty acid sarcosinate, resin acid salt, polyoxyethylene alkyl ether phosphate, polyoxyethylene phenyl ether phosphate, polyoxyethylene dialkyl phenyl ether phosphate, polyoxyethylene Be Benzylated phenyl ether phosphate, polyoxyethylene benzylated phenyl phenyl ether phosphate, polyoxyethylene styrylated phenyl ether phosphate, polyoxyethylene styrylated phenyl phenyl ether phosphate, polyoxyethylene polyoxypropylene block polymer phosphate, phosphatidylcholine, phosphatidylethanolimine , Alkyl phosphate, anionic surfactant such as sodium tripolyphosphate; polyanionic polymer surfactant derived from acrylic acid and acrylonitrile, acrylamidomethylpropane sulfonic acid, alkyltrimethylammonium chloride, methylpolyoxyethylenealkylammonium chloride, alkyl N-methylpyridinium bromide Id, monomethylated ammonium chloride, dialkylmethylated ammonium chloride, alkylpentamethylpropylamine amine dichloride, alkyldimethylbenzalkonium chloride, benzethonium chloride and other cationic surfactants; or dialkyldiaminoethylbenthine, amphoteric such as alkyldimethylbenzylbentine Surfactant etc. are mentioned.

Examples of the binder include sodium alginate, polyvinyl alcohol, gum arabic, CMC sodium or bentonite.
Examples of the disintegrant include CMC sodium or croscarmellose sodium, and examples of the stabilizer include hindered phenol-based antioxidants, benzotriazole-based and hindered amine-based ultraviolet absorbers, and the like. .

Examples of the pH adjuster include phosphoric acid, acetic acid, and sodium hydroxide, and examples of the antibacterial and antifungal agent include industrial bactericides such as 1,2-benzisothiazolin-3-one. It is done.
Examples of the thickener include xanthan gum, guar gum, CMC sodium, gum arabic, polyvinyl alcohol, or montmorillonite. Examples of the antifoaming agent include silicone compounds. Examples of the antifreezing agent include , Propylene glycol, ethylene glycol and the like. However, these adjuvants are not limited to the above.

[Plant disease or plant pest control method]
Next, a plant disease or plant pest control method (sometimes simply referred to as “plant disease pest control method” in this specification), which is a second invention, will be described.
The plant pest control method of the present invention can be carried out by applying the above-mentioned agricultural and horticultural composition to plants, seeds or soil. As an application method of the composition for agriculture and horticulture, for example, foliage spraying treatment to plant individuals, seedling box treatment, spraying treatment on the soil surface, soil mixing after spraying treatment on the soil surface, injection treatment into the soil, Soil admixture after soil infusion, soil irrigation, soil admixture after soil irrigation, spraying on plant seeds, smearing on plant seeds, immersion in plant seeds, or powder on plant seeds For example, clothing processing. The compositions of the present invention usually exhibit sufficient efficacy in any application method utilized by those skilled in the art.

  In order to control plant diseases or plant pests (which may be simply referred to as “plant disease pests” in the present specification), (1) an agricultural and horticultural composition containing tolprocarb and a partner in the present invention as active ingredients Or (2) an agricultural and horticultural composition containing tolprocarb as an active ingredient and an agricultural and horticultural composition containing the partner in the present invention as an active ingredient, or (3) tolprocarb After applying any one of the composition for agriculture and horticulture containing as an active ingredient and the composition for agriculture and horticulture containing the other agent in this invention as an active ingredient, applying the other composition is mentioned. .

  Time (period) until the other composition is sprayed after applying either one of the composition for agriculture and horticulture containing tolprocarb as an active ingredient and the composition for agriculture and horticulture containing the partner in the present invention as an active ingredient ) Is not particularly limited as long as it has an effect of controlling plant pests. For example, it is 1 minute to 2 weeks after applying any one of the compositions, and preferably any one of the compositions is applied. 5 minutes to 1 week, and more preferably 10 minutes to 3 days after applying any one of the compositions. Further, which agricultural or horticultural composition is applied first is not particularly limited as long as it has an effect of controlling plant pests, but is appropriately selected according to the target plant pests, plants, and other environments related to application. Can be determined.

  Furthermore, an agricultural and horticultural composition containing tolprocarb and the partner in the present invention as an active ingredient, an agricultural and horticultural composition containing tolprocarb as an active ingredient, and an agricultural and horticultural composition containing the partner in the present invention as an active ingredient Combining things can be used to control plant pests. In application, the order of spraying, the time until spraying (period), and the number of spraying are not particularly limited as long as they have an effect of controlling plant pests, but are subject to plant pests, plants, and other environments related to application. Accordingly, it can be appropriately selected and determined.

  Furthermore, the composition for agricultural and horticultural use of the present invention can be prepared by containing tolprocarb and the partner of the present invention in a high concentration. This high-concentration composition can be diluted with water and used as a spray liquid. Moreover, the composition for agricultural and horticultural use of the present invention can also be prepared as a mixture by mixing a composition containing tolprocarb in a high concentration and a composition containing the partner in the present invention in a high concentration at the time of use. This high concentration composition can be diluted with water and used as a spray liquid (tank mix method).

  The application amount and application concentration of the agricultural and horticultural composition containing tolprocarb and the partner in the present invention as an active ingredient are not particularly limited as long as they have the effect of controlling plant pests, and the target crop, target pest, pest Depending on the degree of occurrence, the dosage form of the compound, the application method, various environmental conditions, and the like, it can be appropriately selected and determined.

  When spraying the composition, the amount of active ingredient is usually 10 to 10,000 g per hectare, and preferably 25 to 5,000 g per hectare. When the wettable powder, flowable agent or emulsion of the composition is diluted with water and sprayed, the dilution ratio is usually 5 to 50,000 times, preferably 10 to 20,000 times. Yes, more preferably 15 to 10,000 times. Moreover, when performing seed disinfection using the said composition, the usage-amount is 0.001-50g per kg of seeds normally, Preferably, it is 0.01-10g.

  In the case where the composition is subjected to foliage spraying treatment, plant surface spraying treatment, soil injection treatment, soil irrigation treatment, etc., the composition is applied to an appropriate carrier at an appropriate concentration. After dilution, the treatment can be performed. When contacting the said composition with a plant seed, you may immerse a plant seed in the said composition as it is. In addition, the composition can be used after being diluted to an appropriate concentration in an appropriate carrier and then dipped, dressed, sprayed or smeared on plant seeds. The amount of the composition used in the case of powder coating, spraying and smearing treatment is usually about 0.05 to 50% of the dry plant seed weight, preferably 0.1 to 30%. The amount used is not limited to these ranges, and can be determined by appropriately selecting according to the type of plant seed to be treated.

  Suitable carriers include, for example, liquid carriers of organic solvents such as water or ethanol; inorganics such as bentonite, montmorillonite, kaolinite, diatomaceous earth, white clay, talc, clay, vermiculite, gypsum, calcium carbonate, amorphous silica, ammonium sulfate, etc. Substances: plant organic substances such as soybean flour, wood flour, sawdust, wheat flour, lactose, sucrose, and glucose: or solid carriers such as urea can be mentioned, but are not limited thereto.

  In the present specification, the plant individual means one that lives without exercising by photosynthesis. Specifically, for example, rice, wheat, barley, corn, grape, apple, pear, peach, sweet cherry, oyster , Citrus, soybean, green beans, strawberry, potato, cabbage, lettuce, tomato, cucumber, eggplant, watermelon, sugar beet, spinach, sweet pea, pumpkin, sugar cane, tobacco, sweet pepper, sweet potato, taro, konjac, oilseed rape, cotton, sunflower, A tulip, chrysanthemum, turf, etc. are mentioned, but it is not limited to these. The agricultural and horticultural composition of the present invention can be suitably used for controlling rice diseases or rice pests.

  The plant seed in the present specification means one that stores nutrients for germination of young plants and is used for agricultural propagation. Specifically, for example, corn, soybean, cotton, rice, sugar beet, wheat, Seeds such as barley, sunflower, tomato, cucumber, eggplant, spinach, sweet pea, pumpkin, sugar cane, tobacco, pepper, rapeseed; seeds such as taro, potato, sweet potato, konjac; edible lily, bulbs such as tulip, and raccoon Seed ball, etc .; or plants produced by artificial manipulation of genes, etc., for example, soy, corn, cotton, etc. that have given herbicide resistance that does not exist in nature; cold regions Adapted, rice, tobacco, etc .; corn, cotton, barre, etc. Such seeds undergone transformation, such as sucrose, and the like, but not limited thereto. The agricultural and horticultural composition of the present invention can be suitably used for controlling rice seed diseases or rice seed diseases and pests.

  The composition of the present invention can be used in combination with other pesticides, acaricides, nematicides, fungicides, herbicides, plant growth regulators, and other agricultural chemicals, soil conditioners or fertilizers. It is also possible to prepare a mixed preparation with these.

  Specific fungicides, insecticides, acaricides, nematicides include, for example, allethrin, tetramethrin, resmethrin, phenothrin, framethrin, permethrin, cypermethrin, deltamethrin, cyhalothrin, cyfluthrin, fenpropatrin, tralomethrin, cyclo Protorin, flucitrinate, fulvalinate, acrinatrin, tefluthrin, bifenthrin, enpentrin, beta cyfluthrin, cypermethrin, fenvalerate, esfenvalerate, flubrocitrinate, methfluthrin, profluthrin, dimefluthrin, fulbrocis phosphate Silafluophene, insect repellent extract, etofenprox, halfenprox, DDVP, cyanophos, phenthion, fenitrothion, tetrachlor Phosphine, dimethylvinphos, propaphos, methylparathion, temefos, phoxime, acephate, isofenphos, salicione, DEP, EPN, ethion, mecarbam, pyridafenthion, diazinon, pyrimifosmethyl, etrimphos, isoxathion, quinalphos, chlorpyrifos methyl, chlorpyrifos, hosarone , Phosmet, methidathion, oxydebrofos, bamidione, malathion, phentoate, dimethoate, formothione, thiomethone, ethylthiomethone, folate, terbufos, profenophos, prothiophos, sulfophos, pyracrofos, monocrotophos, nared, phostiazeto, trichlorfone, phosprofosca , Diclofenthion, ethyl thiometh , Methamidophos, dichlorvos, tebupyrimphos, ometoate, triazophos, oxydemeton-methyl, azinephos-methyl, chloroethoxyphos, dicrotophos, disulfoton, fanamiphos, phosphamidon, trichlorfone, chlormefos, demeton-S-methyl, mevinphos, parathion, tebuprimalphos, MEP , DCIP, MPP, NAC, MTMC, MIPC, BPMC, XMC, PHC, MPMC, etiophencarb, bendiocarb, pirimicarb, carbosulfan, benfuracarb, mesomil, oxamyl, aldicarb, thiodicarb, alanibcarb, carbofuran, methiocarb, fenothiocarb , Xylyl methyl carbamate, propoxal, isoprocarb, furachi Ocarb, imidacloprid, nitenpyram, acetamiprid, dinotefuran, thiamethoxam, thiacloprid, clothianidin, bromopropyrate, dicophor, endosulfan, lindane, diflubenzuron, chlorfluazuron, teflubenzuron, triflumurone, flufenoxuron, full cycloxuron Mulon, fluazuron, diafenthiuron, novallon, nobiflumuron, bistrifluron, chromafenozide, halofenozide, methoxyphenozide, lufenuron, cyromazine, triazamate, tebufenozide, buprofezin, isoprothiolane, nicotine sulfate, polynactin complex, abamectin remebe, milmectin , Spinosad, rotenone, cartap, thiocyclam Bensultap, tifluzamide, flutolanil, mepronil, pencyclon, ethaboxam, oxycarboxin, carboxin, silthiofam, carpropamide, diclocimet, tricyclazole, pyroxylone, phenoxanyl, fusalide, azoxystrobin, metminostrobin, orisatrobin, crestoxime methyl, fluoxastrobin , Trifloxystrobin, dimoxystrobin, pyraclostrobin, picoxystrobin, kasugamycin, validamycin, blasticidin S benzylaminobenzenesulfonate, polyoxin, teclophthalam, oxytetracycline, streptomycin, blasticidin S, Mildiomycin, Polyoxins, Ferimzone, Phenarimol, Pyripheno Cus, nuarimol, bupyrimeto, cimeconazole, furametopil, ipconazole, triflumizole, prochloraz, pefrazoate, imazalyl, imibenconazole, etridiazole, epoxiconazole, oxpoconazole fumarate, diniconazole, difenoconazole, cyproconazole Nazole, tebuconazole, triadimenol, triadimephone, triticonazole, viteltanol, hymexazole, fenbuconazole, fluquinconazole, flusilazole, flutriafor, prothioconazole, propiconazole, bromconazole, hexaconazole, penconazole, Metconazole, copper, copper nonylphenol sulfonate, basic copper chloride, basic copper sulfate, oxine copper, DBEDC, Anhydrous copper sulfate, cupric hydroxide, thiophanate methyl, benomyl, thiabendazole, thiophanate, carbendazim, fuberidazole, EDDP, IBP, torquelofosmethyl, fosetyl, dinocap, pyrazophos, metalaxyl, oxadixyl, benalaxyl, metalaxyl-M, iprodione, procymidone , Vinclozoline, Clozolinate, Thiuram, Manzeb, Propineb, Dinebu, Methylam, Mannebu, Diram, Ambam, Hydroxyisoxazole, Metasulfocarb, Chlorpicrin, Fursulfamide, Dazomet, Methylisothiocyanate, Hydroxyisoxazole potassium, Echromomezole, 1, 3-dichloropropene, TPN, captan, mepanipyrim, cyprodinil, pyrimethanil, rapeseed oil, mashed Oil, sulfur, lime sulfur mixture, zinc sulfate, fentin, sodium bicarbonate, potassium bicarbonate, hypochlorite, dimethomorph, fenpropidine, fenpropimorph, spiroxamine, tridemorph, dodemorph, full morph, chlorbenzilate, Phenisobromolate, tetradiphone, CPCBS, BPPS, quinomethionate, amitraz, benzomate, hexothiazox, fenbutasin oxide, cyhexatin, dienochlor, clofentezine, pyridaben, fenpyroximate, phenazaquin, tebufenpyrad, pyrimidifene, acequinosyl, fenazide spiroto Spinomesifen, Amidoflumet, Difluvidazine, Kelsen, Pymetrozine, Fipronil, Phenoxycarb Pyriproxyfen, metoprene, hydroprene, quinoprene, endosulfan, triazuron, benzoepin, emamectin benzoate, emamectin benzoate, flupirazophos, fluacrylpyrim, flufendine, indoxacarb, tolfenpyrad, gamma-cyhalothrin, ethiprole, acetoprole, amideflumethir, chlorfenalpyr Flonicamid, flufenerim, pyridalyl, sodium oleate, potassium oleate, azadirachtin, carbam, carbam sodium, propargite, azocyclotine, benzoximate, metaldehyde, protrifen boot, bencrothiaz, flubenzilamide, metaflumizole, nicotine sulfate, Lime nitrogen, machine oil, bensultap, flubenzamide, Chlorantraniliprole, cyantraniliprole, pyrifluquinazone, metaflumizone, oxolinic acid, Pseudomonas CAB-02, Trichoderma atrobilide, fludioxonil, DPC, 4- [3- (3,4-dimethoxyphenyl) -3- (4- Fluorophenyl) acryloyl] morpholine, anilazine, iprovalicarb, imazalyl, iminotadine arbesylate, quinoxyphene, quinomethionate, metallic silver, quintozene, guazatine, chlorothalonyl, chloronebu, cyazofamide, dietofencarb, diclofluranide, dichlorane, dithrimethanone, diflurane Simoxanyl, silthiofam, spiroxamine, zoxamide, thiadiazine, dodin, triphorin, tolylfluanid, di Lotal isopropyl, famoxadone, fenamidone, fenitropan, fenpiclonil, fenhexamide, phorpet, fluazinam, fluorimide, propamocarb, propamocarb hydrochloride, propylene glycol fatty acid ester, prohexadione calcium salt, benchazole, bench avaricarb isopropyl, Examples include microbutanyl, organonickel, resveratrol, penthiopyrad, dichromedin, iminotadine acetate, thianidyl, thiazinyl, probenazole, acibenzoral-S-methyl, mandipropamide, pyribencarb, amisulbrom, isothianyl, tebufloquine, fluopicolide, and triflumezopyrim. Furthermore, when the agricultural and horticultural composition comprising the tolprocarb of the present invention as an active ingredient is applied to rice pests, other insecticides and fungicides exhibiting high effects on the main rice pests; Since mixing is useful for exerting an effect on a wider range of plant pests, it is preferably tricyclazole, fusalide, kasugamycin, ferimzone, EDDP, isoprothiolane, penthiopyrad, tebufloquine, metminostrobin, orisatrobin, diclosimet , Thianidyl, probenazole, acibenzoral-S-methyl, isotianil, flutolanil, mepronil, pencyclon, azoxystrobin, validamycin, furametopil, dichromedin, tifluzamide, chlorantraniliprole, cimeconazole Benomyl, fludioxonil, iprodione, TPN, hydroxyisoxazole, oxolinic acid, MEP, MPP, BPMC, silafluophene, etofenprox, clothianidin, dinotefuran, buprofezin, ethiprole, cartap, tebufenozide, flubenzamide, chlorantraniprole, cyanide Traniliprol, metaflumizone, diazinon, propaphos, benfuracarb, imidacloprid, thiamethoxam, fipronil, pymetrozine, spinosad and the like, and more preferred examples include chlorantraniliprole, cimeconazole and triflumezopyrim, etc. More than that can be used in combination.

The composition and control method of the present invention are effective against, for example, the following types of plant pests. Examples of specific pests to be controlled by the present invention are shown below.
Plant diseases include, for example, rice blast (Priculararia oryzae), blight (Thanatephorus cucumeris (Frank) Donk), sesame leaf blight (Cochliobolus miyabeanus), idiotic seedling (Gibberella seedling) spp., Fusarium spp., Trichoderma spp., Rhizopus spp., Rhizoctonia solani, etc., rice rot (Claviceps virens), smut (Tilletia barellayana) f.sp.tritici), rust disease (Puccinia st) iiformis; Puccinia graminis, Puccinia recondita, Puccinia hordei), Madarahabyo (Pyrenophora graminea), net blotch (Pyrenophora teres), Fusarium head blight (Fusarium graminearum, Fusarium culmorum, Fusarium avenaceum, Microdochium nivale), snow mold (Typhula incarna, Typhula ishikariensis, Micronetriella nivalis, Nasty Black Panther (Ustilago nuda, Ustilago tritici, Ustilago nigra, Ustilago avenae) letia caries, Tilletia pancici), eye spot disease (Pseudocercosporella herpotrichoides), strain rot (Rhizoctonia cerialis), leaf disease (Rhinchosporium secalis), leaf blight (Fusarium spp., Pythium spp., Rhizoctonia spp., Septoria nodorum, Pyrenophora spp.), Blight (Gaeumnomycrum rampiris), anthracnose (Colletotrophic horn) ea), leaf spot (Cochliobolus sativus); corn Fusarium head blight (such as Fusarium graminearum), seedling blight (Fusarium avenaceum, Penicillium spp, Pythium spp. , Rhizoctonia spp, rust disease (Puccinia sorghi), sesame leaf blight (Cochliobolus heterostrohus), smut (Ustilago maymol spot) viticola), rust disease (Phakopsora ampelopsidis), powdery mildew (Uncinula necator), black rot (Elsinoe ampelina), late rot (Glomerella cinulata), black rot (Guibivalh disease) soot Zygophyla jamaicensis, Botrytis cinerea, shoot blight (Diaporethe medusaea), Helicobasidorium mosa, white blight (Rosellinia cinerea) , Black spot disease (Venturia inaequalis), spotted leaf defoliation (Alternaria alternata), red star disease (Gymnosporadium yamadae), Monilia disease (speech) Colletotrichum accutatum, soot spot disease (Zygophiala jamaicensis), soot spot disease (Gloodes pomigena), black spot disease (Mycosphaerella pomigen), purple herb disease Diseases (Phomopsis mary, Diaporthe tanakae), Brown spot disease (Diplocarpon mary); Pear black spot disease (Alternaria alternata (Japan) pear pathotype), Black streak disease (V) Physalospo a piricola), blight (Diaporthe medusaea, Diaporthe eres), pears of late blight (Phytophthora cactorum); peach scab (Cladosporium carpophilum), Phomopsis rot (Phomopsis sp. ), Plague (Phytophthora sp.), Anthracnose (Gloeosporium laeticcolor); sweet potato anthracnose (Glomerella kunuano), larvae (Monilinia kurokki); ), Deciduous leaf disease (Cercospora kaki; Mycosphaerella nawae), powdery mildew (Phyllactinia kakikora); citrus black spot disease (Diaportheum citrus), green mold disease (Penicillium, green) ); Tomato, ki Botrytis cinerea, such as cucumber, beans, strawberry, potato, cabbage, eggplant, lettuce; Sclerotinia sclerotiorum, such as tomato, cucumber, legume, strawberry, potato, rapeseed, cabbage, eggplant, lettuce; Seedling blight of various vegetables such as tomato, cucumber, beans, radish, watermelon, eggplant, rapeseed, green pepper, spinach, sugar beet (Rhizoctonia spp., Phythium spp., Phythophora spp., Physhrothora spp., Sclerotiri); Downy mildew (Pseudoperonospora cubensis), powdery mildew (Sphaerotheca fuligena), anthrax Disease (Colletotrichum lagenarium), vine blight (Mycosphaerella melonis), Fusarium disease (Fusarium oxysporum), plague (Phytophthora parasitica, Phytophthora melonis, Phytophthora nicotianae, Phytophthora drechsleri, Phytophthora capsici, etc.); tomato early blight (Alternaria solani) , Leaf mold (Cladosporium fulvam), plague (Phytophthora infestans), wilt (Fusarium oxysporum), root rot (Phythium myriotylum), Pythium diss tocum), anthracnose (Colletotrichum phomoides); eggplant powdery mildew (such as Sphaerotheca fuliginea), Susukabi disease (Mycovellosiella nattrassii), late blight (Phytophthora infestans), brown rot (Phytophthora capsici);
Black spot disease of rapeseed (Alternaria brassicae), black spot disease of cruciferous vegetables (Alternaria brassicae, etc.), white spot disease (Cercosporella brassicae), root rot (Leptosperia maculans), root blight disease Peronospora brassicae); cabbage rot (Rhizoctonia solani); yellow rot (Fusarium oxysporum); cabbage rump (Rhizoctonia solani); Disease (Alternaria porri), white silk disease (Scler) Scyllotium olsii, Sperrotium olsii, Black spot disease (Elsinoe glycines), Black spot disease (Elsinoe glycines), Black spot disease (Dihori sorghum) Phytophthora megasperma, downy mildew (Peronospora manchurica), rust (Phokopsora pachyrhizi), anthracnose (Colletotrichum truncatum); rela personatum, brown spot (Cercospora arachidicicola); pea powdery mildew (Erysiphe pisi); downy mildew (Peronospora psii); phlegm downy mildew (Peronospora viticiae); (Alternaria solani), black rot (Rhizoctonia solani), plague (Phytophthora infestans), silver rot (Spondyloclaium atrosor), dry rot (Fusarium oxysporum, sous) Brown spot disease (Cercospora beticola), downy mildew (Peronospora schachtii), black root disease (Aphanomyces cochioides), potato batter (Phoma bataph); carrot black leaf blight (Alternaria dasacous disease) humuli), plague (Phytophthora nicotianae), anthrax (Gromerella singulata), fruit rot (Phythium ultramarrow Row var.). ultimum; tea net rot (Exobasidium reticulatum), white scab (Elsinoe leucospila), anthracnose (Colletotrichumum theesinensis), rot of rot (Pestaltiopsis longisetaco). Diseases (Erysiphe cichoracerum), Anthrax (Colletotrichum tabacum), Phytophthora parasitica; Fusarium oxysporum; Sunflower sclerotia rpon rosae), powdery mildew (Sphaerotheca pannosa), plague (Phytophthora megathamporum), downy mildew (Peronospora sparsainto) ); Or Shiba Brown patch disease (Rhizoctonia solani), Dollar spot disease (Sclerotinia homoeocarpa), Carbularia leaf blight (Curvularia geniculata), rust disease (Puccinia zoisiaoli polysp. Cloud shape disease (Rh nchosporum secalis), withering disease (Gaemannomyces graminis), anthrax (Colletotrichum graminicola), snow rot brown granule nuclei (Typhula incarnata), snow rot black granule nuclei (Typhlarensis nuclei) Sclerotinia borealis), fairy rings (such as Marasmius oreades), and pisium disease (such as Pythium aphanidermatum). Preferable diseases for which the composition for agricultural and horticultural use of the present invention exerts effects include rice blast (Pyricularia oryzae) and rice leaf blight (Thanatephorus cucumeris (Frank) Donk), and particularly preferable diseases are rice. Examples include rice blast (Pyricularia oryzae).

Further, examples of the pests include, for example, Hari nematode: ANGUINIDAE, Bengrass nematode (Anguina agritis), Wheat nematode (Anguina tritici), Imogusaresenchu (Dylenchus destructor), and YL. Pratylenchenidae, such as Tyrenchorhynchus martini and Tyrenchorhynchus sp., Hirschmanniella imamuri, Rice Henrimuchu schmanniella oryzae), South Negu Saleh nematode (Pratylenchus coffeae), lily of the valley Negu Saleh nematode (Pratylenchus convallariae), chrysanthemum Negu Saleh nematode (Pratylenchus fallax), tea Negu Saleh nematode (Pratylenchus loosi), wheat Negu Saleh nematode (Pratylenchus neglectus), Northern Negu Saleh nematode (Pratylenchus penntrans), Negusaresenchu (Pratylenchus sp.), Etc., as HOPLOLAMIDAE, chus erythrinae), helix nematode (Helocotylenchus sp.), spider nematode (Hopolaimus sp.), narcissus nematode (Rotylenchulus reniformis), ER Cistode nematode (Cactodera cacti), Nematocyst nematode (Cryphodera sp.), Potato cyst nematode (Globodera rostochiensis), Rice cyst nematode (heterodera elachista), Soybean cyst nematode (heter) dera glycines), such as clover cyst nematode (heterodera trifolii), as MELOIDOGYNIDAE, Arena rear root-knot nematode (Meloidogyne arenaria), camellia root-knot nematode (Meloidogyne camelliae), grass root-knot nematode (Meloidogyne graminis), northern root-knot nematode (Meloidogyne hapla), sweet potato root-knot nematode (Meloidogyne incognita ), Meloidogyne sp. )Such,
DORYLAIMIDA: as LONGIDORIDAE, as Longidorus martini, Longidorus sp., As well as as XD , Trichodorus sp., Etc.
Acarina (ACARINA): as TARSONEMIDAE, Chanohokoridani (Polyphagotarsonemus latus), cyclamen dust mites (Steneotarsonemau pallidus), such as Microstegium vimineum dust mites (Tarsonemus waitei), as PYEMOTIDAE, such as Shiramidani (Pyemotes ventricosus), as EUPODIDAE, such as Mugidani (Penthaleus major), As TENUIPALPIDAE, there is a grape spider spider mite (Brevipalpus lewisi), a tea spider spider mite (Brevipalpus obobatus), a pineapple spider spider mite (Dolichottranychus florodanus), an oyster Such as Mehadani (Tenuipalpus zhizhilashviliae), as TUCKERELLIDAE, such as Namikenagahadani (Tuckerella pavoniformis), as TETRANYCHIDAE, clover mites (Bryobia praetiosa), fake clover mites (Bryobia rubrioculus), Anzuhadani (Eotetranychus boreus), Michinokuhadani (Eotetranychus geniculatus), Kurihadani ( Eottranychus pruni), White spider mite (Eottranychus sexmanulatus), Smith tick (Eottranychus smithi), Walnut spider mite (Eotetr) anychus uncatus), Suginohadani (Oligonychus hondoensis), Chibikobuhadani (Oligonychus ilicis), larch spider mites (Oligonychus karamatus), citrus red mite (Panonychus citri), Ringohadani (Panonychus ulmi), carmine spider mite (Tetranychus cinnabarinus), kanzawai (Tetranychus kanzawai), two-spotted spider mite ( ETIOPHIDAE, such as Tetanychus urticae, Tetranychus vienensis, Achaphylla theae, Aceria tick (Aceria t) lipae), mandarin orange rust mite (aculops pelekassi), peach silver mite, Aculus. induced (Aculus fockeui), apple rust mite (Aculus schlechtendali), Chanosabidani (Calacarus carinatus), grape rust mite (Calepitrimerus vitis), Nashisabidani (Epitrimerus pyri), false pear rust mite (Eriophyes chibaensis), etc. Acaridae, Acarus siro, Aleuroglyphus ovatus, Robin tick, Tyrophagus putrescentiae, etc.
THYSANURA: As LEPIMATATEDAE, Yamato Shimi (Ctenolepisma villosa), Shiiyo Shimi (Lepisma saccharina), Madara Shimi (Thermobia domestica), etc.
Orthoptera (orthoptera): as BLATTIDAE, American cockroach (Periplaneta americana), black cockroach (Periplaneta fuliginosa), such as Yamato cockroach (Periplaneta japonica), as BLATTELLIDAE, German cockroach (Blattella germanica), such as Princess German cockroach (Blattella lituricollis), as TETTIGONIIDAE , Homocoryphis jezoensis, Homocoryhus lineeosus, GRYLLOTALPIDAE, Kelly (Gryllotalpa sp.), Etc., and ACIDIDAE Te, Koinago (Oxya hyla intricata), such as Kobaneinago (Oxya yezoensis),
Termoptera (ISOPTERA): Cryptoptermes domesticus, Copterterms formosanus, Reticulitermes formosanus, Odontotermes formus, etc.
Thysanoptera (THYSANOPTERA): as THRIPIDAE, grasses thrips (Anaphothrips obscurus), thorns but-thrips (Chirothrips manicatus), tea Roh black thrips (Dendrothrips minowai), Hirazuhanaazamiuma (Frankliniella intonsa), lily flower thrips (Frankliniella lilivora), Croton thrips ( Heliotrips haemorrhoidalis, Cosmos thrips abdominalis, Soybean thrips (Mycterothrips glycines), Pseudoendendrot rips mori), yellow tea thrips (Scirtothrips dorsalis), red Obi thrips (Selenothrips rubrocinctus), rice thrips (Stenchaetothrips biformis), green onions black thrips (Thrips alliorum), loquat Hana thrips (Thrips coloratus), Yellow Hana thrips (Thrips flavas) , Hana thrips (Trips palae), Thrips nigropilosus, (Trips palmi), Franklini larva ips setosus), gladiolus thrips (Thrips simplex), such as green onion thrips (Thrips tabaci), as PHLAEOTHRIPIDAE, rice Kedah thrips (Haplothrips aculeatus), Sina Kedah thrips (Haplothrips chinensis), Hana Kedah thrips (Haplothrips kurdjumovi), clover Kedah thrips ( Haplotrips nigar), Shionagakuda thrips ((Leewwania pasanii), Kusuda thrips (Liothripps floridensis), Yurinokuda thrips (Liothrips vaneecki) thrips pasaniae), Anthropis thrips (Ponticulotrips diospyrosi), etc.
HEMIPTERA: As PENTATOMIDAE, Carpocoris purpuripenipenis, eutera gesi (Doricoris baccarum), humile turtle (Euridema pulchrum), turtle (E) Eysarcoris lewisi), Scarab beetle (Eysarcoris parvus), Shirahoshi stink bug (Eysarcoris ventralis), Glutenia physalis (Glaucias submuctus) Worms (Halyomorpha mista), Inekamemushi (Lagynotomus elongatus), order Hemiptera (Nezara antennata), southern green stink bug (Nezara viridula), Piezodorus stink bug (Piezodorus hybneri), Plautia crossota stali (Plautia stali), rice black bug (Scotinophara lurida) , Sardine stink bug (Stariodes iwasakii), etc., as COREIDAE, physalis stink bug (Acanthocoris sorididus), dung beetle (Acanthocoris striicornis), uni-claw beetle (Cletus trigonus), Molipteryx fulginosa, etc., as ALYDIDAE, Leptocorisa acuta, Leptocorisa chitinis, Leptocorisa chitinis, L RHOPALIDAE, Aeschineles maculatus, Scarab beetle (Liorhyssus hyalinus), etc., LYGAEIDAE, Caverelius sacchari vulgaris, Caverelius sacchari Shi (Macropes obnubilus), Hirata gourd Naga bug (Pachybrachius luridus), Black-footed bombardier Naga bug (Paromius exguus), co spring gourd Naga bug (Togo hemipterus), etc., as Pyrrhocoridae, red-spotted stink bug (Dysdercus cingulatus), Anthrenus red Hoshi stink bug (Dysdercus poecilus) As TINGIDAE, Kikugunbai (Galeatus spinifrons), Yanagigunbai (Metasalis populi), Kusungumbai (Stephanitis fascicaria), Nashigumbai (Stephanitis sashii), Tsutsugumbai ephanitis pyrioides), Himegunbai (Uhlerites debile), etc. Kurumigunbai (Uhlerites latius), as MIRIDAE, Acyrthosiphon Miridae (Adelphocoris lineolatus), butyrate beard black Miridae (Adelphocoris triannulatus), Koaokasumikame (Apolygus lucorum), blacktip reef shark Ao Miridae (Apolygus spinolai, red beetle turtle (Creontides pallidifer), tobacco turtle (Cyrtopeltis tennuis), giant beetle turtle (Ectometopterus micanthulus), black beetle turtle (Halticiell) us insularis), apple black Miridae (Heterocordylus flavipes), Makiba Miridae (Lygus disponsi), Madara Miridae (Lygus saundersi), sugar beet Miridae (orthotylus flavosparsus), Mugikasumikame (Stenodema calcaratum), lid streaks Miridae (Stenotus binotatus), Akasuji As for CICADIDAE, rapetomi (Grapo pesto), such as Kasumi turtle (Stenotus rubrovititus), Usmon midori kasumi turtle (Taylorillygus pallidulus), Trichonotylus coelestialium, etc. altria nigrofuscata), etc., as APHROPHORIDAE, Maekiawafuki (Aphrophora costalis), Matsuawafuki (Aphrophora flavipes), Budouawafuki (Aphrophora intermedia), Princess lid ten Naga Awa butterbur (Clovia punctata), such as Hosoawafuki (Philaenus spumarius), as TETTIGELLIDAE, blacktip reef shark giant leafhoppers (Bothrogonia japonica), Cicella viridis, and other CICADELLIDAE, Aguriahana quercus, Alantoidia alneti, Apheliona ferruginea, Arboridia apicaris, Edwardsia flascens, Empharma esco As for DELTOCEPHALIDAE, such as rice leafhopper (Thaia subrufa), citrus yellow leafhopper (Zyginella citri), pineto leafhopper (Macrosteles fascifonis), Nephotettipistopitsueko hotettix nigropictus), Taiwan green rice leafhopper (Nephotettix virescens), apple spotted leafhopper (Orientus ishidai), Inazuma leafhopper (Recilia dorsalis), Mugiyokobai (Sorhoanus tritici), Han Roh Naga leafhopper (Speusotettix subfusculus), etc., as DELPHACIDAE, small brown planthopper (Laodelphax striatellus), Green planthopper (Nilaparvata lugens), sugarcane planthopper (Numata muiri), corn planthopper (Peregrinus maidis), black planthopper (Perkinsiella saccharici) a), Sejirounka (Sogatella furcifera), such as Hieunka (Sogatella panicicola), as PSYLLIDAE, Kuwakijirami (Anomomeura mori), Seguro Hime pheasant Rami (Calophya nigridorsalis), Diaphorina citri (Diaphorina citri), Yamaasakijirami (Mesohomotoma camphorae), Todokijirami (Psylla abieti) , Psylla alni, Psylla jamatonica, Psyla mali, Psylla maliella, Psylla piraj Rami (Psylla tobirae), box kurtosis pheasant Rami (Trioza camphorae), such as chestnut kurtosis pheasant Rami (Trioza quercicola), as ALEYRODIDAE, mandarin orange spiny whitefly (Aleurocanthus spiniferus), grape whitefly (Aleurolobus taonabae), tobacco whitefly (Bemisia tabaci), mandarin orange whitefly (Dialeurodes citri), Onile whitefly (Trialeurodes vaporariorum), Silver leaf whitefly, etc., as PHYLOXERIDAE, Grape aphids (Viteus vitiformii), etc., PMPHIGIIDAE hidonuguis mali), woolly apple aphid (Eriosoma lanigerum), such as sugar cane Ne aphid (Geoica lucifuga), as APHIDIDAE, pea aphid (Acyrthosiphon pisum), Spiraea aphid (Aphis citricola), bean aphid (Aphis craccivora), willow aphid (Aphis farinose yanagicola, cotton aphids (Aphis gossypii), potato beetle aphids (Auracorthum solani), wheat aphids (Brachicaudus helichrysi), radish aphids (Brevricy) ae), tulip aphid (Dysaphis tulipae), Eucalyptus penicillium aphid (Hyopterus pruneis), Aphidus aphids euphorbiae, broad bean aphid (Megoura crassicauda), pear beetle (Melanaphis siphonella), apple aphid (Myzus malisuctus), mycob aphid Green peach aphid (Myzus persicae), green onion aphid (Neotoxoptera formosana), apple green aphid (Ovatus malicolens), lotus constricted aphids (Rhopalosophum nymphaeae), wheat constricted aphid (Rhopalosophum padi), Oka Bono aphid (Rhopalosophum rufiabdominalis), Nashimaru Aphids (Sappaphis piri), Nashibiramushi (Schizaphis piricola), Wheat beetle aphids (Sitobion akebiae), Ibara beetle aphids (Sitobion ibarae), Comikan aphid i), oranges aphid (Toxoptera citricidus), peach Cobb aphid (Tuberocephalus momonis), Taiwan aphid (Uroeucon formosanum) such as MARGARODIDAE, giant Waraji scale insects (Drosicha corpulenta), etc. Iseria scale insects (Icerya purchasi),
As PSEUDOCOCCIDAE, Matsumoto mealybugs (Crisicoccus matsumotoi), pine mealybug (Crisicoccus pini), without mealybugs (Dysmicoccus wistariae), mandarin orange mealybug (Planococcus citri), mealybug (Planococcus kranuhiae), mandarin orange Hime mealybugs (Pseudococcus citriculus ), Pseudococcus comstock, etc. As COCCIDAE, horned beetle (Ceroplastes ceriferus), ruby weevil (Ceroplastes rubens), citrus (Coccus discrepans), scallop hesperidum (Coccus hesperidum), citrus insecta geniaraumum, scallop worm (Ericerus pelam), Lenanthus lucidum ), Citrus scale insects (Pulvinaria citricola), scallop scales (Pulvinaria kuwacola), etc., as DIASPIDIDAE, Andaspis kashicola, Aonid scale insect (Aonid scale) lla aurantii), Aonidiella citrusina, Aspidiotus destructor, Aspidiotus coherus, Chrysamphia sphagnum Buprestidae (Duplaspidiotus claviger), citrus scale insect (Lepidosaphes beckii), apple scale insect scale (Lepidosaphes ulmi), pear scale insect (Lepholeucaspica spicicapasica spisicapsis japonicus) Shi scale insects (Parlatoreopsis pyri), camellia black Hoshi scale insects (Parlatoria camelliae), tea Roh Black Hoshi scale insects (Parlatoria theae), Hime black scale insects (Parlatoria ziziphi), Haran Naga scale insects (Pinnaspis aspidistrae), mandarin orange circle scale insects (Pseudaonidia duplex), living room Pseudaonidia paeoniae, Pseudouracapsis pentagona, Pseudouracuspis prunicola, etc.
Lepidoptera (LEPIDOPTERA): Koumoriga (Endoclyta excrecens), macular bats (Endoclyta sinensis), white Ten bats (Palpifer sexnotata), Barahamaki (Acleris comariana), apple Coca summer fruit tortrix (Adoxophyes orana fasciata), smaller tea tortrix (Adoxophyes sp .), Apples brevipicanus, Midekasukumonkamaki (Archips fuscocuppreanus), Kakimonsamushi (Archips xylosteanus), Bakutra furfuranane, Pokhara furfuranae reipalpana), Kurimiga (Cydia kurokoi), chestnut green sink bur (Eucoenogenes aestuosa), oriental fruit moth (Grapholita molesta), Chahamaki (Homona magnanima), apple fruit moth (Hoshimoa adumbratana), soybean pod borer, Leguminivora glycinivorella (Leguminivora glycinivorella), Azukisayamushiga (Matsumuraeses azukivora), Soybean mushroom (Matsumuraeses falcana), bean mushroom mushroom (Matsumuraeses phaseoli), apple spider leaflet (Spilonota lechriaspis), apple spruce leaf spider (Spirono) a ocellana), grapes bombardier moth (Eupoecillia ambiguella), Kuwaihosohamaki (Phalonidia mesotypa), mugwort giant bombardier moth (Phtheochroides clandestina), Minoga (Bambalina sp.), Oominoga (Eumeta japonica), Chaminoga (Eumeta minuscule), carvings (Nemapogon granellus ), Iga (Tinea translucens), prickly moth (Bucculatrix pyricorella), peach leaf moth (Lyonetia clarkerella), lingon leaf moth (Lyonetia prunifoiliella), lobster moth la), Chanohosoga (Caloptilia theivora), Ringohosoga (Caloptilia zachrysa), Kakihosoga (Cuphodes diospyrosella), the apple leaf miner (Phyllonorycter ringoniella), Nashihosoga (Spulerina astaurota), mandarin orange leafminer (Phyllocnistis citrella), grape leafminer (Phyllocnistis toparcha), Negikoga (Acrolepiopsis sapporensis), Acropiopsis suzukikiella, Ponella xylostella, Argyresthia conjugel la), grapes Sukashiba (Paranthrene regalis), Kosukashiba (Synanthedon hector), Kakinohetamushiga (Stathmopoda masinissa), Imokibaga (Brachmia triannulella), peach fruit moth (Carposina niponensis), apple moth black bar (Illiberis pruni), Kuroshitaaoiraga (Lotoia sinica), monema flavescens ( Monema flavescens, Nashiiraga (Nanosidedeus flavidosalis), Auraira (Parasa consocia), Siperodes consturacus, Chilo supresnosco Moth (Cnaphalocroscis medinalis), peach monopoda teltibell (Diaphania indica), cotton moth (Diaphnia indigenous) Black-tailed moth (Euzophera batengensis), Glyphodes pylorialis, Hellulla undalis, Marusmia exigua, Maru medusa bulge Moth (Notarcha derogate), the European corn borer (Ostrinia furnacalis), Azukinomeiga (Ostrinia scapulalis), Fukinomeiga (Ostrinia zaguliaevi), Shibatsutoga (Parapediasia teterrella), Ukon'nomeiga (Pleuroptya ruralis), Sankameiga (Scirpophaga incertulas), parnara guttata (Parnara guttata), Papilio Helenus, Papilio machaon hipporates, Papilio xutus, Monk butterfly (Colias erate polygraphus), Monshirocho (Pieris rapae crucivora), lampides boeticus (Lampides boeticus), Plum Eda Shakti (Angerona prunaria), mugwort Eda Shakti (Ascotis selenaria), Tobi Mont giant Eda Shakti (Biston robustum), Umeedashaku (Cystidia couaggaria), pine moth (Dendrolimus spectabilis), lackey moth ( Malacosoma neutria testacea, apple calcare (Odonestis pruni japonensis), hawk moth (Cephonodes hylas), grape sparrow (Acosmerix castanea) choreta), kelp killer whale pike (Clostera anastomosis), Mont black killer whale pike (Phalera flavescens), giant Tobi Mont killer whale pike (Phalerodonta manleyi), killer whale pike moth (Stauropus fagi persimilis), Arna Pseudoconspersa (Euproctis pseudoconspersa), Monshirodokuga (Euproctis similes), tussock (Euproctis subflava), Mymantia dispar, Orgyia thyella, Hyphantria cunea, Spirosoma imparilis, Spirosoma imparilis (Acanthoplusia agnata), Nakajiroshitaba (Aedia leucomelas), black cutworm (Agrotis ipsilon), Kaburayaga (Agrotis segetum), Akakiriba (Anomis mesogona), Tamanagin'uwaba (Autographa nigrisigna), Trichoplusia ni (Trichoplusia ni), cotton bollworm (Helicoverpa armigera), tobacco budworm (Helicoverpa assulta), crested saga (Heliothis maritime), mushroom (Mamestra brassicae), pterodactyl (Nangaga aenescens), Ayuyoto (Pseudaletia sepata) C (Sesamia inferens), Sujikiriyotou (Spodoptera depravata), beet armyworm (Spodoptera exigua), common cutworm (Spodoptera litura), Ringokenmon (Trianea intermedia), Nashikenmon (Viminia rumicis), etc. Shiromon'yaga (Xestia c-nigrum),
Coleoptera (COLEOPTERA): Chairokogane (Adoretus tenuimaculatus), cupreous chafer (Anomala cuprea), rufocuprea (Anomala rufocuprea), flower chafer (Eucetonia pilifera), Blue flower chafer (Eucetonia roelofsi), Nagachakogane (Heptophylla picea), Kofukikogane (Melolontha japonica), Scarab beetles (Mimela splendens), core red clover (Oxycetonia jucunda), bean scallops (Popilia japonica), beetle beetle (Anthrenus verbasci), beetle worm beetle (Atun tussage nus) color japonicus), cigarette beetle (Lasioderma serricorne), Hirata beetle (Lyctus brunneus), Guy My Deo kiss Lee (Carpophilus dimidiatus), clear Keshikisui (Carpophilus hemipterus), giant beetle, Epilachna vigintioctopunctata (Epilachna vigintioctomaculata), the beetle, Epilachna vigintioctopunctata (Epilachna vintignoctopuncta), Japanese red beetle (Alphitobius laevigatas), Japanese red beetle (Neatus picipes), Japanese red beetle (Palorus ratzeburgii), Japanese red beetle subdepressus), Chai loco agate molitor (Tenebrio molitor), red flour beetle (Tribolium castaneum), Hirata red flour beetle (Tribolium confusum), beans Beetle (Epicauta gorhami), key sawyer (Aeolesthes chrysothrix), Gomadarakamikiri (Anoplophora malasiaca), Matsunomadara Japanese beetle (Monochamus alternatus), Japanese beetle (Psacothea hilaris), Grape tiger beetle (Xylotrechus pyrrhoderus), Ayojikamikiri (Xytrocena globosa), Azuki beetle bruchus chinensis), cucurbit leaf beetle (Aulacophara femoralis), Tenebrio monkey beetle (Basilepta balyi), Kamenokohamushi (Cassida nebulosa), Ten site bi potato beetle (Chaetocnema concinna), Imosaruhamushi Colasposoma dauricum), A person who spotted neck Naga leaf beetle (Crioceris quatuordecimpunctata), Inenekuihamushi (Donocia provosti), Ruri potato beetle (Linaeidea aenea), Kerashino horn beetle (Luperomorpha tunabrosa), Methia nigrobilineata, Inedro omushi (Oulem) oryzae), corn beetle (Pagria signata), radish beetle (Phaedon brassicae), phyllotetta striata, weecho weevil (Involvulus cucumber) Apple weevil (Anthonomus pomorum), Japanese radish weevil (Ceuthorhychinidus albosturalis), Crisium weevil (Curculio sikkimenesis), Echinocnemus squeumus scorpus (Echinocnemus sequus) tfasciatus), clover weevil (Hypera nigrirostris), alfalfa weevil (Hypera postica), rice water weevil (Lissorhoptrus oryzophilus), vegetable weevil (Listroderes costirostris), apple pea leaf weevil (Phyllobius armatus), Chibi pea leaf weevil (Sitona japonicus), co-maize weevil (Sitophilus oryzae), beetle weevil (Sitophilus zeamais), beetle weevil (Sphenophrus venatus vestitus),
Hymenoptera: Japanese bee wasp (Athalia japonica), bee (Athalia rosae tuficornis), apple bee (Age mali), urage papula mur, D
Diptera: Tipula aino, Bradysia agrestis, Asphondylia sp., Ac, Daccus cubitidae, D Cherry Leaf Spot fruit fly (Rhacochlaena japonica), Inemigiwabae (Hydrellia griseola), rice click Kimi Giwa fly (Hydrellia sasakii), cherry fruit fly (Drosophila suzukii), Inekimoguribae (Chlorops oryzae), Mugikimoguribae (Meromuza nigriven ris), rice leafminer (Agromyza oryzae), the pea (Chromatomyia horticola), eggplant leafminer (Liriomyza bryoniae), green onion leafminer (Liriomyza chinensis), legume leafminer (Liriomyza trifolii), tomato leafminer (Liriomyza sativae), reed Gros leafminer (Liriomyza huidobrensis ), Onion fly (Delia antiqua), fly fly (Delia platera), sugar beet fly (Pegomya cunicularia), house fly (Musca domestica), black fly fly (Phormia regius) ulex pipiens pallens Coquillett), Culex pipiens (Culex pipiens molestus Forskal), Anopheles sinensis (Anopheles (Anopheles) sinensis Wiedemann), Aedes albopictus (Aedes albopictus (Skuse)) but the like, but is not limited thereto.

  Hereinafter, the present invention will be described more specifically with reference to formulation examples and test examples. However, the present invention is not limited only to formulation examples and test examples. In addition, all the compounding parts of each component described in the following formulation examples mean parts by weight.

Formulation Example 1 Simple Emulsion 1 part of methanol (MeOH) was added to 9 parts of dimethyl sulfoxide (abbreviation DMSO) (solvent 1). 200 parts of solvent 1 is added to 1 part of tolprocarb, mandestrobin (racemic compound consisting of 50% R-form and 50% S-form), cyclaniliprol, or tetranyriprole and dissolved to obtain simple emulsions. It was. These simple emulsions were used alone, or toluprocarb-containing simple emulsions and other simple emulsions were mixed at a predetermined concentration and suspended in water, and used in the test.

Formulation Example 2 Granule (G1)
30 parts of Torprocarb, 22 parts of bentonite, 45 parts of talc and 3 parts of Solpol 5060 (surfactant: Toho Chemical Co., Ltd.) are uniformly kneaded, granulated with a basket granulator, dried and granulated 100 parts of the agent were obtained.

Formulation Example 3 Granule (G2)
After mixing 15 parts of cyclanilipol, 60 parts of bentonite, 21 parts of talc, 1 part of sodium dodecylbenzene sulfonate, 1 part of polyoxyethylene alkylaryl ether and 2 parts of sodium lignin sulfonate, an appropriate amount of water is added to uniformly The mixture was kneaded, granulated with a basket granulator and dried to obtain 100 parts of a granule.

Formulation Example 4 Wetting agent (W1)
50 parts of tetraniliprole, 40 parts of calcium carbonate, 5 parts of Solpol 5039 (mixture of anionic surfactant and white carbon: trade name of Toho Chemical Co., Ltd.) and 5 parts of white carbon are uniformly mixed and pulverized. It was.

Formulation Example 5 Wetting agent (W2)
30 parts of mandestrobin, 63 parts of kaolinite, 5 parts of Solpol 5039 (mixture of anionic surfactant and white carbon: trade name of Toho Chemical Co., Ltd.) and 2 parts of white carbon are uniformly mixed and pulverized. It was.

Formulation Example 6 Emulsion (EC)
An emulsion was prepared by uniformly mixing 20 parts of tetraniprolol, 55 parts of xylene, 20 parts of N, N-dimethylformamide and 5 parts of Solpol 2680 (surfactant).

Formulation Example 7 Flowable (FL)
Ingredients other than active ingredients among 40 parts of mandestrobin, 5 parts of Solpol 3353 (nonionic surfactant: Toho Chemical Co., Ltd. trade name), 5 parts of 1% aqueous solution of xanthan gum, 40 parts of water and 10 parts of ethylene glycol Then, the compound of the present invention was added and stirred well, followed by wet grinding with a sand mill to obtain a flowable agent.

Formulation Example 8 Dust (D)
Toluprocarb 5 parts and clay 95 parts were mixed uniformly to obtain a powder.

Comparative Formulation Example 1 Simple emulsion 1 part of methanol (MeOH) was added to 9 parts of dimethyl sulfoxide (abbreviation DMSO) (solvent 1). A simple emulsion was obtained by adding 200 parts of solvent 1 to 1 part of isoprothiolane, fusalide, azoxystrobin, or pencyclon, which has been confirmed to have a synergistic effect with tolprocarb in the patent literature (WO 2006/106811). . These simple emulsions were used alone, or these simple emulsions and the toluprocarb-containing simple emulsion obtained in Formulation Example 1 were mixed at a predetermined concentration, suspended in water, and used in the test.

Comparative Formulation Example 2 Granule (G1)
30 parts of isoprothiolane, 22 parts of bentonite, 45 parts of talc and 3 parts of Solpol 5060 (surfactant: Toho Chemical Co., Ltd. trade name) are uniformly kneaded, granulated with a basket granulator, dried and granulated 100 parts of the agent were obtained.

Comparative Formulation Example 3 Granule (G2)
After mixing 15 parts of azoxystrobin, 60 parts of bentonite, 21 parts of talc, 1 part of sodium dodecylbenzenesulfonate, 1 part of polyoxyethylene alkylaryl ether and 2 parts of lignin sulfonate, a suitable amount of water is added to uniformly The mixture was kneaded, granulated with a basket granulator and dried to obtain 100 parts of a granule.

Test Example 1 Rice Blast Prevention Test (Spray Test)
In the greenhouse, rice (variety: Kofu) planted in a plastic pot with a diameter of 5 cm was grown to the 3-4 leaf stage. The simple emulsions prepared in Formulation Example 1 and Comparative Formulation Example 1 were singly or mixed and suspended in water so that the concentrations shown in Table 1 or 2 were obtained, and the suspension was sprayed. After the drug solution was dried, a conidial spore suspension prepared from blast fungus previously cultured on oatmeal medium was spray-inoculated. Then, the pot was put in the humidity chamber of the artificial inoculation room (20-23 ° C.), taken out the next day, and moved to the greenhouse. The control effect was investigated 8 days after inoculation. In the survey, the severity of the disease was investigated, and the control value and the theoretical value based on the Colby equation were calculated. The results are shown in Tables 1 and 2.

The criteria for disease severity are as follows.
Degree of disease occurrence: Assessed without disease (sickness area rate 0%) as 0, withering (sickness area rate 100%) as 3, and evaluated in 0.1 increments according to the lesion area rate.
The control value was calculated from the following formula.
Control value = (1—degree of disease in treated area / degree of disease in untreated area) × 100

  The synergistic effect was determined by the Colby formula (see Weeds 15 (1967), 2022). The Colby equation is X = P + Q−P × Q / 100, where X is the theoretical value of the control value, P is the control value when a certain agent is sprayed alone, and Q is This is the control value when the drug used in combination is sprayed alone. When the actually measured effect was larger than the effect X (theoretical value) calculated by the above Colby equation, it was determined that the action of the combination of the two active ingredients was synergistic.

  From the results of Table 1 and Table 2 above, it was found that synergistic effects were obtained when tolprocarb and cyclanilipol, or tolprocarb and mandestrobin were used in combination. Moreover, the synergistic effect exceeded the case where the tolprocarb and isoprothiolane, a fusalide, an azoxystrobin, or pencyclone described in the patent document (WO2006 / 106811) reported previously were used together. In addition, even if tolprocarb and cyclanilipol or mandestrobin were used in combination, no phytotoxicity was observed in plant rice (variety: Kofu).

Test Example 2 Rice blight prevention test (dispersion test)
In a greenhouse, rice (variety: Kofu) planted in a plastic pot having a diameter of 5 cm was grown to the 4-5 leaf stage. The simple emulsions prepared in Formulation Example 1 and Comparative Formulation Example 1 were singly or mixed and suspended in water and sprayed so that the concentrations shown in Table 3 were obtained. After the chemical solution was dried, the rice blight fungus previously cultured on the buckwheat medium was placed on the rice strain and inoculated. Then, the pot was put in the humidity chamber of the artificial inoculation room (22-27 ° C.), taken out the next day, and moved to the greenhouse. The control effect was investigated 6 days after inoculation. In the survey, the severity of the disease was investigated, and the control value and the theoretical value based on the Colby equation were calculated. The results are shown in Table 3.

The criteria for disease severity are as follows.
Degree of disease occurrence: 0 for no disease, 3 for untreated lesions, and evaluated in 0.1 increments according to the lesion area rate.
The control value was calculated from the following formula.
Control value = (1—degree of disease in treated area / degree of disease in untreated area) × 100

  The synergistic effect was determined by the Colby formula (see Weeds 15 (1967), 2022). The Colby equation is X = P + Q−P × Q / 100, where X is the theoretical value of the control value, P is the control value when a certain agent is sprayed alone, and Q is This is the control value when the drug used in combination is sprayed alone. When the actually measured effect was larger than the effect X (theoretical value) calculated by the above Colby equation, it was determined that the action of the combination of the two active ingredients was synergistic.

  From the results of Table 3 above, it was found that when tolprocarb and mandestrobin were used in combination, a synergistic effect was obtained. Moreover, the synergistic effect exceeded the case where the tolprocarb and the combination of isoprothiolane, a fusalide, azoxystrobin, or pencyclone described in the patent document (WO2006 / 106811) of a report were reported. In addition, even if tolprocarb and mandestrobin were used in combination, no phytotoxic symptoms were observed in plant rice (variety: Kofu).

Test Example 3 Rice Blast Prevention Test (Spray Test)
In the greenhouse, rice (variety: Kofu) planted in a plastic pot with a diameter of 5 cm was grown to the 3-4 leaf stage. The simple emulsions prepared in Formulation Example 1 and Comparative Formulation Example 1 were singly or mixed and suspended in water so that the concentrations shown in Table 4 were obtained, and the suspension was sprayed. After the drug solution was dried, a conidial spore suspension prepared from blast fungus previously cultured on oatmeal medium was spray-inoculated. Then, the pot was put in the humidity chamber of the artificial inoculation room (20-23 ° C.), taken out the next day, and moved to the greenhouse. The control effect was investigated 7 days after the inoculation. In the survey, the severity of the disease was investigated, and the control value and the theoretical value based on the Colby equation were calculated. The results are shown in Table 4.

The criteria for disease severity are as follows.
Degree of disease occurrence: No disease (sickness area rate 0%) was 0, withering (sickness area rate 100%) was 3, and evaluation was made in 0.1 increments according to the lesion area rate.
The control value was calculated from the following formula.
Control value = (1—degree of disease in treated area / degree of disease in untreated area) × 100

  The synergistic effect was determined by the Colby formula (see Weeds 15 (1967), 2022). The Colby equation is X = P + Q−P × Q / 100, where X is the theoretical value of the control value, P is the control value when a certain agent is sprayed alone, and Q is This is the control value when the drug used in combination is sprayed alone. When the actually measured effect was larger than the effect X (theoretical value) calculated by the above Colby equation, it was determined that the action of the combination of the two active ingredients was synergistic.

  From the results of Table 4 above, it was found that when tolprocarb and tetraniliprole were used in combination, a synergistic effect was obtained. Moreover, the synergistic effect exceeded the case where the tolprocarb and isoprothiolane used together were described in the patent document (WO2006 / 106811) of a report. In addition, even if tolprocarb and tetraniliprole were used in combination, no phytotoxic symptoms were observed in plant rice (variety: Kofu).

  The composition for agricultural and horticultural use of the present invention against toll procarb, mandestrobin, cyclanilip against various plant pests (for example, rice blast (Pyricularia oryzae) and rice leaf blight (Thanatephorus cucumeris (Frank) Donk)). By exhibiting an excellent control effect (synergistic control effect) that cannot be predicted from a single component of roll or tetranyriprole, it exhibits a high plant disease control effect or plant pest control effect. Therefore, it can be used as an excellent plant disease control agent or plant pest control agent.

  This application claims the priority on the basis of Japanese application Japanese Patent Application No. 2006-084215 for which it applied on April 20, 2016, and takes in those the indications of all here.

Claims (11)

(A) Tolprocarb,
(B) a man dest Robin (Mandestrobin) or at least one compound a salt thereof, and consequent Rani descriptor roll (Cyclaniliprole) or a salt thereof, is selected from,
A composition for agricultural and horticultural use containing as an active ingredient. (A) Tolprocarb,
(B) tetraniliprole or a salt thereof;
A composition for agricultural and horticultural use containing, as an active ingredient (except when a carboxamide compound is included). The composition for agricultural and horticultural use according to claim 1 or 2, which is used for controlling plant diseases or plant pests.   The composition for agricultural and horticultural use according to claim 3, which is used for controlling rice diseases or pests of rice.   The composition for agricultural and horticultural use according to claim 3, wherein the plant disease is rice blast or rice blight.   The composition for agricultural and horticultural use according to claim 3, wherein the plant disease is rice blast.   A method for controlling plant diseases or plant pests, which comprises applying the agricultural or horticultural composition according to claim 1 to plants, seeds or soil. Following agricultural and horticultural composition (i) and (ii) at the same time, plants, or applied to seeds or soil, or the following agricultural and horticultural composition one of (i) and (ii), a plant, seed or soil A method for controlling plant diseases or plant pests , wherein the other is applied after application.
Agricultural and horticultural composition (i): Torupurokarubu (a) a as an active ingredient a composition for agricultural or horticultural use composition (ii): Man dest robin or a salt thereof and from consequent Rani descriptor roll or a salt thereof, is selected Composition containing at least one compound (b) as an active ingredient The following agricultural and horticultural compositions (i) and (iii) are simultaneously applied to plants, seeds or soil, or one of the following agricultural and horticultural compositions (i) and (iii) is applied to plants, seeds or soil. A method for controlling plant diseases or plant pests, wherein the other is applied after application (except for the case where the agricultural and horticultural compositions (i) and (iii) contain a carboxamide compound).
Agricultural and horticultural composition (i): a composition comprising tolprocarb (a) as an active ingredient
Agricultural and horticultural composition (iii): a composition containing, as an active ingredient, compound (b) which is tetraniliprole or a salt thereof. Apply the following agricultural and horticultural compositions (i) and ( ii ) simultaneously to plants, seeds or soil, or apply one of the following agricultural and horticultural compositions (i) and ( ii ) to plants, seeds or soil And then applying the other, a method for controlling plant diseases or plant pests.
Agricultural and horticultural composition (i): a composition containing tolprocarb (a) as an active ingredient Agricultural and horticultural composition ( ii ): a composition containing as an active ingredient compound (b) which is mandestrobin or a salt thereof The following agricultural and horticultural compositions (i) and (iv) are simultaneously applied to plants, seeds or soil, or one of the following agricultural and horticultural compositions (i) and (iv) is applied to plants, seeds or soil And then applying the other, a method for controlling plant diseases or plant pests.
Agricultural and horticultural composition (i): a composition containing tolprocarb (a) as an active ingredient Agricultural and horticultural composition (iv): a composition containing cyclanilipol or a salt thereof (b) as an active ingredient Stuff