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JP6348260B2 - Method for producing wine for cooking - Google Patents
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JP6348260B2 - Method for producing wine for cooking - Google Patents

Method for producing wine for cooking Download PDF

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JP6348260B2
JP6348260B2 JP2013145479A JP2013145479A JP6348260B2 JP 6348260 B2 JP6348260 B2 JP 6348260B2 JP 2013145479 A JP2013145479 A JP 2013145479A JP 2013145479 A JP2013145479 A JP 2013145479A JP 6348260 B2 JP6348260 B2 JP 6348260B2
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wine
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acid
cooking
lactic acid
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JP2015015926A (en
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龍起 大倉
龍起 大倉
泰裕 石崎
泰裕 石崎
平人 近藤
平人 近藤
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Suntory Holdings Ltd
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Description

本発明は、調理用として適したワインの製造方法に関する。より詳しくは、優れた調理効果を有しながら、飲用してもおいしいワインの製造方法に関する。   The present invention relates to a method for producing wine suitable for cooking. More specifically, the present invention relates to a method for producing wine that has an excellent cooking effect and is delicious even if it is drunk.

肉類や魚介類などの食品素材を調理する際に、香り付け、風味付け、コク付け、臭み消し、照りの付与などの目的でワインを調味料のように使用することが一般に行われている。また、肉を軟らかくする目的で、加熱調理前にワインに肉を漬けておくことも行われている。このようなワインの特性に鑑みて、ワインの調理効果を高めた調理に適した又は調理専用のワインが製造されている。   When cooking food materials such as meat and seafood, it is common practice to use wine as a seasoning for the purpose of aroma, flavor, richness, deodorant, and shine. In order to soften the meat, it is also practiced to immerse the meat in wine before cooking. In view of the characteristics of such wines, wines suitable for cooking or cooking-only wines with enhanced wine cooking effects are being manufactured.

特許文献1には、ワインにアルカリを添加するか、又はワインをイオン交換樹脂で処理してワイン中の有機酸を除去することにより、ワインのpHを4.5〜7.0に調整した調理に好適なワインが記載されている。   Patent Document 1 discloses cooking in which the pH of wine is adjusted to 4.5 to 7.0 by adding alkali to wine or treating wine with an ion exchange resin to remove organic acids in the wine. Suitable wines are described.

また、特許文献2には、白ワインの配合量が40v/v%以上であり、これにクエン酸及び酢酸が特定の濃度となるようにレモン果汁、果実酢等を添加した白ワイン加工調味料が記載されており、特許文献3には赤ワインの配合量が40v/v%以上であり、これにリンゴ酸、酒石酸、及び乳酸を特定の配合比で添加した赤ワイン加工調味料が記載されている。   Patent Document 2 discloses a white wine processed seasoning in which the amount of white wine is 40 v / v% or more, and lemon juice, fruit vinegar and the like are added to the citric acid and acetic acid at a specific concentration. Patent Document 3 describes a red wine processing seasoning in which the compounding amount of red wine is 40 v / v% or more, and malic acid, tartaric acid, and lactic acid are added at a specific compounding ratio. .

また、ワインに食塩等を添加した調理専用のワイン(クッキングワイン)も市販されている。   In addition, cooking-only wine (cooking wine) in which salt or the like is added to wine is also commercially available.

特開平7−213273号公報JP-A-7-213273 特許第4111302号Japanese Patent No. 4111302 特許第4111303号Japanese Patent No. 4111303

上記のように、調理用に成分を調整されたワインが製造されているが、こうして得られたワインは、元のワインの風味のバランスを失っており、ワインを直接に飲用するには適さないものとなっていた。   As described above, wines with ingredients adjusted for cooking are produced, but the wines obtained in this way have lost the balance of the original wine flavor and are not suitable for drinking wine directly. It was a thing.

本発明は、高い調理効果を有しながら、飲用してもワインとしての良好な風味のバランスが感じられる、調理に適したワインの製造方法を提供するものである。   The present invention provides a method for producing wine suitable for cooking, which has a high cooking effect and can feel a good flavor balance as a wine even if it is drunk.

本発明者らは、ワインの調理効果として、特に、肉を軟らかくする効果に着目し、ワイン中のポリフェノールやアルコール等の各種成分が肉の保水性に与える影響を調べた。その結果、ポリフェノールやアルコール、有機酸等のワイン中の成分のうち、特に有機酸を含む溶液に加熱調理前の肉を漬けこんでおくと、肉の保水性が高まり加熱調理後でも肉の軟らかさが維持されやすいことを見出した。さらに、検討を進めた結果、意外にも、(1)浸漬用の溶液のpHと、肉の保水性向上との間には、必ずしも関連がないこと、及び(2)各種有機酸の浸漬液の中でも、乳酸を含む浸漬液において、肉の保水性の向上効果が高いこと、を見出した。この知見に基づき、乳酸を既存のワインに添加したところ、ワインの調理効果(浸漬液として用いた際の肉の保水性向上効果)が高まることを見出した。また、特定濃度の乳酸の添加では、ワイン自体を飲用した際の風味のバランスも良好であった。したがって、本発明は、これらに限定されないが、次の通りである。
(1)ワイン中の乳酸量が1300ppm〜7000ppmとなるようにワインに乳酸を添加することを含む、調理用ワインの製造方法。
(2)得られた調理用ワイン中の酒石酸量が、800ppm〜3500ppmである、上記(1)に記載の方法。
(3)得られた調理用ワイン中の酒石酸、リンゴ酸、クエン酸、コハク酸、乳酸、及び酢酸の合計量が、3500ppm〜10000ppmである、上記(1)または(2)に記載の方法。
(4)上記(1)〜(3)のいずれか1に記載の方法により得られた調理用ワイン。
(5)上記(4)に記載の調理用ワインに肉又は魚介を漬けこむことを含む、肉又は魚介の調理方法。
The present inventors focused on the effect of softening meat as a cooking effect of wine, and investigated the influence of various components such as polyphenol and alcohol in wine on the water retention of meat. As a result, among the ingredients in wine, such as polyphenols, alcohols, and organic acids, if the meat before cooking is immersed in a solution containing organic acids, the water retention of the meat increases and the meat becomes soft even after cooking. I found that it is easy to maintain. Furthermore, as a result of further investigation, surprisingly, (1) there is not necessarily a relationship between the pH of the soaking solution and the water retention of the meat, and (2) soaking solutions of various organic acids Among them, it has been found that an immersion liquid containing lactic acid has a high effect of improving water retention of meat. Based on this finding, it was found that when lactic acid was added to existing wine, the cooking effect of the wine (the effect of improving the water retention of meat when used as an immersion liquid) was enhanced. In addition, with the addition of a specific concentration of lactic acid, the balance of flavor when drinking wine itself was also good. Therefore, the present invention is not limited to these, but is as follows.
(1) A method for producing cooking wine, comprising adding lactic acid to wine so that the amount of lactic acid in the wine is 1300 ppm to 7000 ppm.
(2) The method according to (1) above, wherein the amount of tartaric acid in the obtained wine for cooking is 800 ppm to 3500 ppm.
(3) The method according to (1) or (2) above, wherein the total amount of tartaric acid, malic acid, citric acid, succinic acid, lactic acid, and acetic acid in the obtained cooking wine is 3500 ppm to 10000 ppm.
(4) Cooking wine obtained by the method according to any one of (1) to (3) above.
(5) A method for cooking meat or seafood, including immersing meat or seafood in the cooking wine according to (4).

本発明によれば、高い調理効果を有しながら、飲用した場合にもワインとしての良好な風味のバランスが感じられる、調理に適したワインを製造することができる。また、本発明の製造方法は、低コストでもある。   ADVANTAGE OF THE INVENTION According to this invention, the wine suitable for cooking which can feel the balance of the favorable flavor as wine even if it drinks can be manufactured, having a high cooking effect. Further, the production method of the present invention is low in cost.

参考例1の結果を示す。The result of the reference example 1 is shown. 参考例2の結果を示す。The result of the reference example 2 is shown. 実施例7の結果を示す。The result of Example 7 is shown. 実施例8の結果を示す。The result of Example 8 is shown.

本発明の製造方法は、ワイン中の乳酸量が1300ppm〜7000ppmとなるように、ワインに乳酸を添加することを含む。   The production method of the present invention includes adding lactic acid to wine so that the amount of lactic acid in the wine is 1300 ppm to 7000 ppm.

(ワイン)
本発明において乳酸を添加するワイン(以下、原料のワインということもある。)は特に限定されず、ワインの通常の製造方法に従って製造されるワインを用いることができる。ブドウの品種や産地は特に限定されない。また、ワインは色や製法により赤ワイン、白ワイン、ロゼワインといった分類がされるが、いずれでもよい。また、複数のワインをブレンドしたものであってもよい。
(wine)
In the present invention, wine to which lactic acid is added (hereinafter sometimes referred to as “raw wine”) is not particularly limited, and wine produced according to a normal production method for wine can be used. Grape varieties and production areas are not particularly limited. Moreover, although wine is classified into red wine, white wine, and rose wine according to color and manufacturing method, any of them may be used. Moreover, what blended several wine may be used.

なお、ワイン(特に赤ワイン)では、酵母による主発酵(アルコール発酵)後に、乳酸菌によるマロラクティック発酵を行わせることにより、ワイン中のリンゴ酸を乳酸に変換させて、ワインの酸味を抑え、まろやかな風味にすることがある。本発明では、そのようなマロラクティック発酵を行ったワインを原料のワインとして用いてもよい。しかし、マロラクティック発酵を人為的に行わせる場合、温度管理などの手間がかかり、また時間もかかるので、本発明では、マロラクティック発酵を行っていないワインを原料のワインとして用いてもよい。人為的なマロラクティック発酵を行わせていないワインを原料として用いることで、短期で低コストな製造ができる。なお、マロラクティック発酵は、ブドウ等に付着している乳酸菌によって自然と行われることもあるが、近年では、マロラクティック発酵を行わせるために人為的に乳酸菌を添加することも多く行われている。本発明において、こうした「人為的な乳酸菌の添加」を行わずに製造したワインを原料のワインとして用いることはコストの面から好ましい。本発明では、人為的なマロラクティック発酵を行わせていないものを原料に用いても、肉の保水性を向上させる効果が高く、また、良好に飲用できるワインを製造することができる。   In wine (especially red wine), malolactic fermentation by lactic acid bacteria is performed after the main fermentation (alcohol fermentation) by yeast, so that malic acid in the wine is converted to lactic acid, thereby reducing the acidity of the wine. May have a savory flavor. In the present invention, wine subjected to such malolactic fermentation may be used as a raw material wine. However, when malolactic fermentation is performed artificially, it takes time and effort for temperature control and the like, and it also takes time. Therefore, in the present invention, wine not subjected to malolactic fermentation may be used as a raw wine. . By using wine that has not been subjected to artificial malolactic fermentation as a raw material, it can be produced in a short time and at a low cost. In addition, malolactic fermentation may be naturally performed by lactic acid bacteria adhering to grapes and the like, but in recent years, lactic acid bacteria are often added artificially to cause malolactic fermentation. ing. In the present invention, it is preferable from the viewpoint of cost to use wine produced without performing such “artificial addition of lactic acid bacteria” as a raw wine. In this invention, even if it uses as a raw material what does not perform artificial malolactic fermentation, the effect which improves the water retention of meat is high, and the wine which can be drunk favorably can be manufactured.

本発明では、原料のワインに乳酸を添加することにより、ワイン中の最終の乳酸量が1300ppm〜7000ppmとなるように調整する。したがって、原料のワインとしては、乳酸添加前の乳酸の量が、1300ppm未満のものを用いることとなる。好ましくは1000ppm以下、さらに好ましくは700ppm以下である。   In the present invention, the final amount of lactic acid in the wine is adjusted to 1300 ppm to 7000 ppm by adding lactic acid to the raw wine. Therefore, as the wine of the raw material, a wine whose amount of lactic acid before addition of lactic acid is less than 1300 ppm is used. Preferably it is 1000 ppm or less, More preferably, it is 700 ppm or less.

(乳酸の添加)
添加する乳酸は、発酵により得た乳酸であってもよいし、化学合成により得た乳酸であってもよい。本発明では、乳酸を原料のワインに添加することにより、最終的に得られるワイン中の乳酸量を1300ppm〜7000ppmの範囲内に調整する。好ましくは1300ppm〜6500ppm、さらに好ましくは1300ppm〜5500ppm、さらに好ましくは2000ppm〜4500ppm、さらに好ましくは2000〜3500ppmである。乳酸量は、高速液体クロマトグラフィー等の公知の手段を用いて測定することができる:
乳酸の添加は、上記のようにして得た原料のワインに対して行う。添加のタイミングや添加時の温度は特に限定しない。原料のワインが保持されている容器(ステンレスのタンク等)に、バット等にて量りとった乳酸を添加しても良いし、タンク内からワインの一部を抜き取り、その中に乳酸を溶解させてから再度元のタンクに加えるという方法で添加しても良い。原料のワインとして複数のワインのブレンドを用いる場合には、乳酸をあるワインに添加後、他のワインとブレンドしても良いし、ブレンド後に乳酸を添加しても良い。また、ワインのろ過後や殺菌後などに乳酸を添加しても良い。添加した後は撹拌機、窒素によるバブリング等でワインを撹拌することが好ましい。その際の温度は特に限定しない。
(Addition of lactic acid)
The lactic acid to be added may be lactic acid obtained by fermentation or lactic acid obtained by chemical synthesis. In the present invention, the amount of lactic acid in the finally obtained wine is adjusted within the range of 1300 ppm to 7000 ppm by adding lactic acid to the raw wine. Preferably they are 1300 ppm-6500 ppm, More preferably, they are 1300 ppm-5500 ppm, More preferably, they are 2000 ppm-4500 ppm, More preferably, they are 2000-3500 ppm. The amount of lactic acid can be measured using a known means such as high performance liquid chromatography:
Lactic acid is added to the raw material wine obtained as described above. The timing of addition and the temperature at the time of addition are not particularly limited. Lactic acid weighed with a vat or the like may be added to a container (such as a stainless steel tank) that holds the raw wine, or a portion of the wine is withdrawn from the tank and dissolved therein. After that, it may be added again by adding it to the original tank. When a blend of a plurality of wines is used as the raw wine, after adding lactic acid to a certain wine, it may be blended with other wines, or lactic acid may be added after blending. Further, lactic acid may be added after filtration or sterilization of wine. After the addition, it is preferable to stir the wine with a stirrer, bubbling with nitrogen or the like. The temperature at that time is not particularly limited.

(調理用ワイン)
上記のようにして乳酸が添加されたワインは、調理に好適なワインとして用いることができる。調理に好適なワインとは、調理に用いた際に、食品素材に好適な調理効果を与えることができるように調製されているワインをいう。本発明では、このワインを、「調理用ワイン」と呼ぶことがある。本発明の方法により製造される調理用ワインは、特に、肉類や魚介類をやわらかい食感に仕上げる効果があり、総合的に「食感がよい」、「おいしい」と感じられるような料理に仕上げる効果がある。
(Cooking wine)
The wine to which lactic acid is added as described above can be used as a wine suitable for cooking. The wine suitable for cooking means a wine prepared so as to give a cooking effect suitable for a food material when used for cooking. In the present invention, this wine is sometimes referred to as “cooking wine”. The cooking wine produced by the method of the present invention has an effect of finishing meats and seafoods with a soft texture, and finishes foods that can be generally “feel good” and “delicious”. effective.

また、本発明により得られる調理用ワインは、直接に飲用した際にも、ワインの良好な風味のバランスを有しており、通常の飲用のワインとしても、良好に飲むことができる。一般に、調理専用のワインとして市販されているものには、食塩が添加されているものもあるが、本発明の「調理用ワイン」は良好に飲用できるという特徴も有するものであるから、通常、食塩は添加されない。   In addition, the cooking wine obtained by the present invention has a good balance of wine flavor even when it is drunk directly, and can be drunk well as a normal drinking wine. In general, some of the commercially available wines for cooking are added with salt, but the "cooking wine" of the present invention also has a feature that it can be drunk well, No salt is added.

本発明の製造方法により得られる調理用ワインにおける酒石酸量は、好ましくは800〜3500ppm、さらに好ましくは800〜2000ppm、より好ましくは900〜2000ppmである。好ましくは、酒石酸と乳酸との量(ppm)の比が、(酒石酸の量):(乳酸の量)=1:1〜1:7、好ましくは1:1〜1:6、さらに好ましくは1:2〜1:5である。また、調理用ワイン中のリンゴ酸量は、好ましくは700〜2000ppm、さらに好ましくは700〜1500ppmである。また、酒石酸、クエン酸、リンゴ酸、コハク酸、乳酸、及び酢酸の合計量は、好ましくは3500〜10000ppm、より好ましくは4000〜8000ppmである。これらのような範囲にあれば、ワインとしての風味のバランスがより一層高まる。酒石酸、クエン酸、リンゴ酸、コハク酸、及び酢酸のそれぞれの量は、高速液体クロマトグラフィー等の公知の手段を用いて測定することができる:
(調理方法)
本発明により得られる調理用ワインは、調理にワインを用いる際の通常の方法で使用することができる。特に本発明の調理用ワインは、肉類や魚介類の保水性を高めてやわらかく仕上げる効果が高いから、それらの料理に好適に用いることができる。典型的には、肉類や魚介類を本発明で得られる調理用ワインと共に煮込んだり、又は肉類や魚介類を加熱調理する前に本発明の調理用ワインに一定時間漬けこむといった方法が考えられる。これらによって、やわらかく仕上がり、総合的に「食感がよい」、「おいしい」と感じられるような料理を作ることができる。
The amount of tartaric acid in the cooking wine obtained by the production method of the present invention is preferably 800 to 3500 ppm, more preferably 800 to 2000 ppm, and more preferably 900 to 2000 ppm. Preferably, the ratio of tartaric acid to lactic acid (ppm) is (tartaric acid amount) :( lactic acid amount) = 1: 1 to 1: 7, preferably 1: 1 to 1: 6, more preferably 1. : 2 to 1: 5. Moreover, the amount of malic acid in the wine for cooking is preferably 700 to 2000 ppm, more preferably 700 to 1500 ppm. Moreover, the total amount of tartaric acid, citric acid, malic acid, succinic acid, lactic acid, and acetic acid is preferably 3500 to 10000 ppm, more preferably 4000 to 8000 ppm. If it exists in such a range, the balance of the flavor as wine will increase further. The respective amounts of tartaric acid, citric acid, malic acid, succinic acid, and acetic acid can be measured using known means such as high performance liquid chromatography:
(Cooking method)
The wine for cooking obtained by this invention can be used by the normal method at the time of using wine for cooking. In particular, the cooking wine of the present invention has a high effect of enhancing the water retention of meat and seafood and finishing it softly, so that it can be suitably used for those dishes. Typically, a method is conceivable in which meat or seafood is boiled with the cooking wine obtained in the present invention, or is immersed in the cooking wine of the present invention for a certain period of time before cooking the meat or seafood. By these, it is possible to make a dish that is softly finished and that feels “good texture” and “delicious” overall.

以下、本発明を実施例に基づいて説明するが、本発明はこれらの実施例に限定されるものではない。   EXAMPLES Hereinafter, although this invention is demonstrated based on an Example, this invention is not limited to these Examples.

(参考例1)
ワイン中の各種成分について、肉の保水性に与える影響を調べた。具体的には、ワイン中のポリフェノールの1種であるエノシアニン(TPP)(1000ppm、3000ppm、5000ppm)、有機酸の一種であるリンゴ酸(酒石酸換算における滴定酸度で1.2g/100ml)、及びアルコール(5%、10%、15%)の各水溶液約50mlを調製し、ここに一定の大きさになるようにカットし、予め重量を測定した牛もも肉(約12g)を、肉が溶液中に完全に漬かるように浸漬した(20℃、30分)。浸漬後の肉を電子レンジで1枚ずつ加熱調理し(500W、30秒)、加熱後の重量を測定した。各肉に関して、保水率を、(加熱後の重量/加熱前の重量)×100で計算して求めた。加熱によって肉中の水分が失われると考えられるから、加熱前の重量に対する加熱後の重量の比(保水率)が高いことは、加熱によって肉中の水分が失われにくいこと(すなわち、肉の保水性が高いこと)を示す。また、一般に保水性が高い肉は、やわらかい食感となることが知られている。
(Reference Example 1)
The effects of various ingredients in wine on the water retention of meat were investigated. Specifically, enocyanin (TPP) (1000 ppm, 3000 ppm, 5000 ppm), which is one of polyphenols in wine, malic acid (1.2 g / 100 ml in titrated acidity in terms of tartaric acid), which is an organic acid, and alcohol Prepare about 50 ml of each aqueous solution (5%, 10%, 15%), cut it to a certain size, and weigh the beef thigh (about 12 g) that weighed in advance. It was immersed so that it might be completely immersed (20 degreeC, 30 minutes). The meat after immersion was cooked one by one in a microwave oven (500 W, 30 seconds), and the weight after heating was measured. For each meat, the water retention was calculated by (weight after heating / weight before heating) × 100. It is thought that the moisture in the meat is lost by heating, so the high ratio of the weight after heating to the weight before heating (water retention) means that the moisture in the meat is not easily lost by heating (ie, the meat High water retention). In addition, it is known that meat having high water retention generally has a soft texture.

結果を図1に示す。図1の最左欄は、浸漬液として水を用いた結果を示す(対照)。図1より、ポリフェノール(エノシアニン)やアルコールは、加熱調理後の肉の保水性を高める効果があまりない(対照と同等)ことがわかる。一方、有機酸であるリンゴ酸の水溶液を用いた場合には、肉の保水性は顕著に向上することがわかる。   The results are shown in FIG. The leftmost column of FIG. 1 shows the results using water as the immersion liquid (control). As can be seen from FIG. 1, polyphenol (enocyanin) and alcohol are not very effective in increasing the water retention of meat after cooking (equivalent to the control). On the other hand, when an aqueous solution of malic acid, which is an organic acid, is used, it can be seen that the water retention of meat is significantly improved.

(参考例2)
ワイン中の各種有機酸について、肉の保水性に与える影響を調べた。具体的には、酒石酸換算における滴定酸度が1.2g/100mlとなる量の酒石酸、リンゴ酸、クエン酸、酢酸、及び乳酸の各水溶液を調製し、約10gにカットした牛もも肉を用いて、参考例1と同じ方法で保水率を求めた。結果を図2に示す。図2の最左欄は、水を用いた際の結果を示す(対照)。最右欄は、同じ滴定酸度(酒石酸換算)となるリン酸を用いた結果を示す(比較)。図2のグラフ中の黒塗りの棒は保水率を、白抜きの棒は各水溶液のpHを表す。この結果から、各種有機酸の中でも、乳酸が最も肉の保水性向上効果が高いこと、また、水溶液のpHと肉の保水率との間には関連がみられないことがわかる。
(Reference Example 2)
The effects of various organic acids in wine on the water retention of meat were investigated. Specifically, each amount of tartaric acid, malic acid, citric acid, acetic acid, and lactic acid in an amount such that the titrated acidity in terms of tartaric acid is 1.2 g / 100 ml is prepared, and the beef thigh cut into about 10 g is used, The water retention rate was determined by the same method as in Reference Example 1. The results are shown in FIG. The leftmost column in FIG. 2 shows the results when water was used (control). The rightmost column shows the result of using phosphoric acid having the same titrated acidity (tartaric acid equivalent) (comparison). The black bars in the graph of FIG. 2 represent the water retention rate, and the white bars represent the pH of each aqueous solution. From these results, it can be seen that among various organic acids, lactic acid has the highest effect of improving the water retention of meat, and there is no relationship between the pH of the aqueous solution and the water retention of meat.

(実施例1)
既存のワイン(白ワイン)に酒石酸及び乳酸を添加することにより、酒石酸の濃度を約1000ppmに調整し、また、乳酸の濃度を約1400ppm、2300ppm、3200ppmに調整したワインを作成した。このワインについて、クエン酸、酒石酸、リンゴ酸、コハク酸、乳酸、酢酸の量を測定した。また、このワインを用いて参考例1と同様の方法(ただし、肉の重さは15g程度とし、1時間の浸漬とした。)で、肉の保水率を求めた。また、市販の調理用白ワイン(比較品1)についても同様に試験した。
Example 1
By adding tartaric acid and lactic acid to existing wine (white wine), the concentration of tartaric acid was adjusted to about 1000 ppm, and the concentration of lactic acid was adjusted to about 1400 ppm, 2300 ppm, and 3200 ppm. About this wine, the quantity of citric acid, tartaric acid, malic acid, succinic acid, lactic acid, and acetic acid was measured. Further, using this wine, the water retention rate of the meat was determined by the same method as in Reference Example 1 (however, the weight of the meat was about 15 g and the immersion was performed for 1 hour). Further, a commercially available white wine for cooking (Comparative product 1) was also tested in the same manner.

なお、ワイン中の各種有機酸の量は、高速液体クロマトグラフ(島津社製LC−10シリーズ)を用いて以下の方法で測定した:
使用機器:コントローラー(SCL−10A)、送液ポンプ(LC−10AD)、デガッサー(DGU−14A)、カラム槽(CTO−10AC)、オートサンプラー(SIL−10AD)、電気伝導度検出器(CDD−6A)、クロマトパック(C−R7Aplus)、カラム(Shim−pack SCR−102H(8mmI.D×300mmL)を2本直列)、ガードカラム(SCR−102H(6mmI.D×50mmL))
移動液:p−トルエンスルホン酸4.8gを1Lのメスフラスコに量り採り蒸留水にて定容し、それを使用時に5倍希釈し、0.45μmのメンブレンフィルターで濾過したものを移動液とした。また、カラムを通した後に反応させる液としてp−トルエンスルホン酸4.8gおよびEDTA150mgとBis−Tris20.9gを1Lのメスフラスコに量り採り蒸留水にて定容し、それを使用時に5倍希釈し、0.45μmのメンブレンフィルターを用いて濾過したものを用いた。
流量:1.6ml/分
検出:電気伝導度(Polarityは+に設定)
サンプル注入量:10μl
分析時間:30分
サンプル調製:各試料(ワイン)を10倍希釈したものを試験に供した。
In addition, the amount of various organic acids in wine was measured by the following method using a high performance liquid chromatograph (Shimadzu LC-10 series):
Equipment used: controller (SCL-10A), liquid feed pump (LC-10AD), degasser (DGU-14A), column tank (CTO-10AC), autosampler (SIL-10AD), conductivity detector (CDD- 6A), Chromatopack (C-R7Aplus), column (two Shim-pack SCR-102H (8 mm ID × 300 mmL) in series), guard column (SCR-102H (6 mm ID × 50 mmL))
Transfer liquid: 4.8 g of p-toluenesulfonic acid was weighed into a 1 L volumetric flask, fixed in distilled water, diluted 5 times during use, and filtered through a 0.45 μm membrane filter. did. In addition, 4.8 g of p-toluenesulfonic acid and 150 mg of EDTA and 20.9 g of Bis-Tris were weighed into a 1 L volumetric flask as a liquid to be reacted after passing through the column, and the volume was adjusted with distilled water. And filtered using a 0.45 μm membrane filter.
Flow rate: 1.6 ml / min Detection: Electrical conductivity (Polarity is set to +)
Sample injection volume: 10 μl
Analysis time: 30 minutes Sample preparation: Each sample (wine) diluted 10 times was subjected to the test.

結果を表1に示す。表1の有機酸測定値の「合計」は、乳酸、酒石酸、クエン酸、リンゴ酸、コハク酸、酢酸の量の合計値である。表1の結果から、乳酸の量が増加するにつれて、肉の保水率が向上することがわかる。   The results are shown in Table 1. “Total” of the measured organic acid values in Table 1 is the total value of the amounts of lactic acid, tartaric acid, citric acid, malic acid, succinic acid, and acetic acid. From the results in Table 1, it can be seen that the water retention rate of meat improves as the amount of lactic acid increases.

(実施例2)
既存のワイン(白ワイン)に酒石酸及び乳酸を添加することにより、酒石酸の濃度を約1900ppmに調整し、また、乳酸の濃度を約500ppm、1400ppm、2300ppm、3200ppmに調整したワインを作成した。このワインについて、実施例1と同様の方法で、クエン酸、酒石酸、リンゴ酸、コハク酸、乳酸、酢酸の量を測定した。また、このワインを用いて参考例1と同様の方法(ただし、肉の重さは15g程度とし、1時間の浸漬とした。)で、肉の保水率を求めた。結果を表2に示す。表2の結果から、乳酸の量が増加するにつれて、肉の保水率が向上することがわかる。
(Example 2)
By adding tartaric acid and lactic acid to an existing wine (white wine), the concentration of tartaric acid was adjusted to about 1900 ppm, and the concentration of lactic acid was adjusted to about 500 ppm, 1400 ppm, 2300 ppm, and 3200 ppm. With respect to this wine, the amounts of citric acid, tartaric acid, malic acid, succinic acid, lactic acid and acetic acid were measured in the same manner as in Example 1. Further, using this wine, the water retention rate of the meat was determined by the same method as in Reference Example 1 (however, the weight of the meat was about 15 g and the immersion was performed for 1 hour). The results are shown in Table 2. From the results in Table 2, it can be seen that the water retention rate of meat improves as the amount of lactic acid increases.

(実施例3)
既存のワイン(白ワイン)に酒石酸及び乳酸を添加することにより、酒石酸の濃度を約3000ppmに調整し、また、乳酸の濃度を約500ppm、1400ppm、2400ppm、3400ppmに調整したワインを作成した。このワインについて、実施例1と同様の方法で、クエン酸、酒石酸、リンゴ酸、コハク酸、乳酸、酢酸の量を測定した。また、このワインを用いて参考例1と同様の方法(ただし、肉の重さは15g程度とし、1時間の浸漬とした。)で、肉の保水率を求めた。結果を表3に示す。表3の結果から、乳酸の量が増加するにつれて、肉の保水率が向上することがわかる。
(Example 3)
By adding tartaric acid and lactic acid to existing wine (white wine), the concentration of tartaric acid was adjusted to about 3000 ppm, and the concentration of lactic acid was adjusted to about 500 ppm, 1400 ppm, 2400 ppm, and 3400 ppm. With respect to this wine, the amounts of citric acid, tartaric acid, malic acid, succinic acid, lactic acid and acetic acid were measured in the same manner as in Example 1. Further, using this wine, the water retention rate of the meat was determined by the same method as in Reference Example 1 (however, the weight of the meat was about 15 g and the immersion was performed for 1 hour). The results are shown in Table 3. From the results in Table 3, it can be seen that the water retention rate of meat improves as the amount of lactic acid increases.

(実施例4)
既存のワイン(赤ワイン)に乳酸及び酒石酸を添加することにより、酒石酸の濃度を約1000ppmに調整し、また、乳酸の濃度を約1400ppm、2300ppm、3200ppmに調整したワインを作成した。このワインについて、クエン酸、酒石酸、リンゴ酸、コハク酸、乳酸、酢酸の量を実施例1に記載の方法で測定した。また、このワインを用いて、実施例1と同様の方法で肉(牛もも肉、厚さ約2mm、重量約2g)の保水率を求めた。また、市販の調理用赤ワイン(比較品4)についても同様に試験した。結果を表4に示す。表4の結果から、乳酸の量が増加するにつれて、肉の保水率が向上することがわかる。
Example 4
By adding lactic acid and tartaric acid to an existing wine (red wine), the wine was prepared by adjusting the concentration of tartaric acid to about 1000 ppm and adjusting the concentration of lactic acid to about 1400 ppm, 2300 ppm, and 3200 ppm. With respect to this wine, the amounts of citric acid, tartaric acid, malic acid, succinic acid, lactic acid, and acetic acid were measured by the method described in Example 1. Further, using this wine, the water retention rate of meat (beef thigh, thickness of about 2 mm, weight of about 2 g) was determined in the same manner as in Example 1. Moreover, it tested similarly about the red wine for cooking (comparative product 4). The results are shown in Table 4. From the results in Table 4, it can be seen that the water retention rate of the meat improves as the amount of lactic acid increases.

(実施例5)
既存のワイン(赤ワイン)に乳酸及び酒石酸を添加することにより、酒石酸の濃度を約2800ppmに調整し、また、乳酸の濃度を約500ppm、1400ppm、2200ppm、3200ppmに調整したワインを作成した。このワインについて、クエン酸、酒石酸、リンゴ酸、コハク酸、乳酸、酢酸の量を実施例1に記載の方法で測定した。また、このワインを用いて、実施例1と同様の方法で肉(牛もも肉、厚さ約2mm、重量約2g)の保水率を求めた。結果を表5に示す。表5の結果から、乳酸の量が増加するにつれて、肉の保水率が向上することがわかる。
(Example 5)
By adding lactic acid and tartaric acid to existing wine (red wine), the concentration of tartaric acid was adjusted to about 2800 ppm, and the concentration of lactic acid was adjusted to about 500 ppm, 1400 ppm, 2200 ppm, and 3200 ppm. With respect to this wine, the amounts of citric acid, tartaric acid, malic acid, succinic acid, lactic acid, and acetic acid were measured by the method described in Example 1. Further, using this wine, the water retention rate of meat (beef thigh, thickness of about 2 mm, weight of about 2 g) was determined in the same manner as in Example 1. The results are shown in Table 5. From the results in Table 5, it can be seen that the water retention rate of the meat improves as the amount of lactic acid increases.

(実施例6)
酒石酸、クエン酸、リンゴ酸、コハク酸、酢酸の量をそれぞれ約1000ppm、約240ppm、約800ppm、約320ppm、約210ppmに調整した白ワインに、乳酸を添加することにより、乳酸量の異なるワインを作成した。このワインを飲用した際のワインとしての味わいのバランスを、5名のパネルにより以下の基準で評価した:
5:ワインとして良いバランス
4:ワインとしてやや良いバランス
3:ワインとしての許容限界
2:ワインとしてややバランスが取れていない
1:ワインとしてバランスが取れていない。
(Example 6)
By adding lactic acid to white wine with tartaric acid, citric acid, malic acid, succinic acid, and acetic acid adjusted to about 1000 ppm, about 240 ppm, about 800 ppm, about 320 ppm, and about 210 ppm, Created. The balance of taste as a wine when drinking this wine was evaluated by a panel of 5 people according to the following criteria:
5: Balance as good as wine 4: Balance as good as wine 3: Acceptable limit as wine 2: Slightly unbalanced as wine 1: Unbalanced as wine

結果を表6に示す。官能評価において、3点以上がワインの味わいとして合格のラインである。表6の結果より、本発明の方法で得られたワインは、飲用した際にもワインとしての味わいを有することがわかる。   The results are shown in Table 6. In sensory evaluation, three or more points are acceptable lines for the taste of wine. From the results of Table 6, it can be seen that the wine obtained by the method of the present invention has a taste as wine even when it is drunk.

(実施例7)
比較品1(市販の調理用白ワイン)と発明品2(白ワイン)のそれぞれを用いて、以下の手順で鶏もも肉を調理した:
各白ワイン100ml、サラダ油30ml、玉ねぎ1個をすりおろしたものをよく混ぜて調味液とした。鶏もも肉5枚分を一口大に切ったものを調味液に約24時間浸漬した。その後、ホットプレートでよく焼き、試験に供した。
(Example 7)
Using each of Comparative Product 1 (commercial white wine for cooking) and Invention 2 (white wine), chicken thighs were cooked in the following procedure:
100 ml of each white wine, 30 ml of salad oil and 1 grated onion were mixed well to make a seasoning liquid. A portion of 5 pieces of chicken thighs cut into bite-sized pieces was immersed in the seasoning liquid for about 24 hours. Thereafter, it was baked well on a hot plate and subjected to the test.

完成した料理について、「肉がやわらかい」、「食感が良い」、「肉がおいしい」と感じるかどうか、22名のパネルで以下の基準(1〜7点)で評価した:
1:そう思わない
4:どちらとも言えない
7:そう思う。
結果を図3に示す。図3の結果から、本発明で得られた調理用ワインは、比較のものに比べて、肉をやわらかくし、食感を良くして、肉をおいしく仕上げることがわかる。
The finished dishes were evaluated according to the following criteria (1-7 points) on a panel of 22 people whether they felt “meat is soft”, “feel good”, or “meat is delicious”:
1: I don't think so 4: I can't say either 7: I think so.
The results are shown in FIG. From the results of FIG. 3, it can be seen that the cooking wine obtained in the present invention softens the meat, improves the texture, and finishes the meat deliciously compared with the comparative wine.

(実施例8)
比較品4(市販の調理用赤ワイン)と、発明品11(赤ワイン)のそれぞれを用いて、以下の手順で、牛もも肉を調理した:
各赤ワイン100mlを火にかけ、沸騰してから約1分間加熱を続け、アルコール分を飛ばした。その後、はちみつ大さじ2杯、砂糖30g、ざらめ糖40g、しょうゆ200ml、みそ小さじ1杯を加えて混ぜ、再び沸騰させ、ざらめ糖が溶けたら加熱をやめた。しばらく冷やした後、りんごのすりおろしを50ml、玉ねぎのすりおろしを50ml、にんにくのすりおろしを大さじ2杯、しょうがのすりおろしを大さじ1杯、ごま油大さじ2杯、すりごま大さじ3杯を加えてよく混ぜて調味液とした。この調味液100mlに牛もも肉を300gからませて約24時間5℃冷蔵庫で保管した。その後、ホットプレートで両面をよく焼き試験に供した。
(Example 8)
Using each of comparative product 4 (commercial red wine for cooking) and invention product 11 (red wine), beef thigh was cooked by the following procedure:
100 ml of each red wine was set on fire, and after boiling, heating was continued for about 1 minute to expel alcohol. After that, 2 tablespoons of honey, 30 g of sugar, 40 g of candy sugar, 200 ml of soy sauce, and 1 teaspoon of miso were added and mixed, and boiled again. When the candy sugar melted, heating was stopped. After cooling for a while, add 50ml of apple grated, 50ml of onion grated, 2 tablespoons garlic grated, 1 tablespoon ginger grated, 2 tablespoons sesame oil, 3 tablespoons sesame seeds Mix well to make a seasoning liquid. 300 ml of beef thigh was put into 100 ml of this seasoning liquid and stored in a refrigerator at 5 ° C. for about 24 hours. Thereafter, both sides were well subjected to a baking test with a hot plate.

完成した料理について、「肉がやわらかい」、「食感が良い」、「肉がおいしい」、「まろやかである」と感じるかどうか、19名のパネルで実施例4と同様の基準(1〜7点)で評価した。結果を図4に示す。図4の結果から、本発明で得られた調理用ワインは、比較のものに比べて、肉をやわらかくし、食感を良くして、肉をおいしく、まろやかに仕上げることがわかる。   Whether or not the finished dish feels “meat is soft”, “feel good”, “meat is delicious”, “mellow”, the same criteria as in Example 4 (1-7) Evaluation). The results are shown in FIG. From the results of FIG. 4, it can be seen that the cooking wine obtained in the present invention softens the meat, improves the texture, makes the meat delicious and mellow compared to the comparative wine.

Claims (7)

ワイン中の乳酸量が2000ppm〜7000ppmとなるようにワインに乳酸を添加することを含む、調理用ワインの製造方法であって、得られた調理用ワイン中のリンゴ酸量が700ppm〜2000ppmである、上記方法A method for producing wine for cooking, comprising adding lactic acid to wine such that the amount of lactic acid in the wine is 2000 ppm to 7000 ppm, wherein the amount of malic acid in the obtained wine for cooking is 700 ppm to 2000 ppm , The above method . 得られた調理用ワイン中の酒石酸量が、800ppm〜3500ppmである、請求項1に記載の方法。   The method of Claim 1 that the amount of tartaric acids in the obtained wine for cooking is 800 ppm-3500 ppm. 得られた調理用ワイン中の酒石酸、リンゴ酸、クエン酸、コハク酸、乳酸、及び酢酸の合計量が、3500ppm〜10000ppmである、請求項1または2に記載の方法。   The method according to claim 1 or 2, wherein the total amount of tartaric acid, malic acid, citric acid, succinic acid, lactic acid, and acetic acid in the obtained cooking wine is 3500 ppm to 10000 ppm. ワイン中の乳酸量が2000ppm〜7000ppmであり、リンゴ酸量が700ppm〜2000ppmである、マロラクティック発酵を行っていない調理用ワイン。 Amount of lactic acid is 2000ppm~7000ppm der in wine is, the amount of malic acid is Ru 700ppm~2000ppm der, cooking wine that has not been the malolactic fermentation. ワイン中の酒石酸量が800ppm〜3500ppmである、請求項4に記載の調理用ワイン。   The wine for cooking of Claim 4 whose tartaric acid amount in wine is 800 ppm-3500 ppm. ワイン中の酒石酸、リンゴ酸、クエン酸、コハク酸、乳酸、及び酢酸の合計量が、3500ppm〜10000ppmである、請求項4又は5に記載の調理用ワイン。   The cooking wine according to claim 4 or 5, wherein the total amount of tartaric acid, malic acid, citric acid, succinic acid, lactic acid, and acetic acid in the wine is 3500 ppm to 10000 ppm. 請求項1〜3のいずれか1項に記載の方法により調理用ワインを得ること、及び得られた調理用ワインに肉又は魚介を漬けこむことを含む、肉又は魚介の調理方法。   A method for cooking meat or seafood, comprising obtaining cooking wine by the method according to any one of claims 1 to 3, and immersing meat or seafood in the cooking wine obtained.
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