JP6918780B2 - Cosmetic set - Google Patents

Description

The present invention relates to a cosmetic set containing the first composition and the second composition, and relates to a cosmetic set to which the first composition is applied to a coating portion and then the second composition is applied.

In recent years, in makeup cosmetics such as lipsticks and foundations, there have been problems of makeup disintegration over time and color transfer to containers, clothes and the like. In particular, in the case of lipsticks, there are various problems such as the problem that the lipstick applied to the lips is transferred to tableware such as coffee cups and the problem that the makeup is disintegrated over time due to physical rubbing of the lips. It has been considered.
For example, as a technique for imparting a color transfer prevention effect and a makeup discoloration prevention effect, a kinematic viscosity at 25 ° C. on a first composition containing polyisobutylene having a relative mass of 3000 to 1000000 and a volatile hydrocarbon oil. A technique (Patent Document 1) for applying a second composition containing a methylphenyl polysiloxane having a value of 1000 cs to 7000 cs has been proposed. However, by applying the second composition on polyisobutylene, which is a hydrocarbon resin, volatilization of the volatile hydrocarbon oil in the first composition is hindered, and it takes time until the effect of preventing makeup from coming off is obtained. In some cases, it was applied and color bleeding occurred. Further, when the content of polyisobutylene having a relative mass of 3000 to 1000000 in the first composition is increased in order to further improve the effect of disintegrating makeup over time, a feeling of tightness may appear. ..

Japanese Patent No. 5719315

Therefore, in the prior art, a cosmetic set that does not cause color bleeding during use, does not cause color transfer to tableware, has an excellent effect of preventing color transfer, does not feel smooth after use, and does not lose makeup over time. It was difficult to materialize.

As a result of diligent research in view of the above problems, the present inventor has obtained a mixture of a silicone resin having a film-forming component (A) and a volatile hydrocarbon oil having a mass ratio of 1: 1. When mixed in equal amounts and allowed to stand at 25 ° C. for 60 minutes, it was found that there was an oil agent for the component (E) that was phase-separated, and by applying this technology to cosmetics, color bleeding did not occur during use. We have found that it is a cosmetic set with an excellent anti-color transfer effect. Further, it was found that by containing a silicone oil having a kinematic viscosity of 1000 cs or more at 25 ° C. of the component (B), a cosmetic film having no feeling of tightness was formed, and further, it was found that the makeup did not easily come off over time, and the present invention was completed. It came to.

That is,
[1] A cosmetic set containing the first composition and the second composition, wherein the first composition is applied to a coating portion and then the second composition is applied, and the first composition. And the second composition relate to a cosmetic set containing the following ingredients, respectively.
(First composition)
(A) Film-forming silicone resin (B) Silicone oil having a kinematic viscosity at 25 ° C. of 1000 to 1000000 cs (C) Volatile hydrocarbon oil (D) Color pigment (second composition)
An oil agent of the component (E) that is phase-separated when the component (A) and the component (C) are mixed at a mass ratio of 1: 1 and mixed in equal amounts and allowed to stand at 25 ° C. for 60 minutes.

[2] The component (A) is one or more selected from trimethylsiloxysilicic acid, polymethylsilsesquioxane, (Acrylate / dimethicone) copolymer, (Acrylate / stearyl acrylate / dimethicone methacrylate) copolymer. It relates to the cosmetic set according to [1].

[3] The present invention relates to the cosmetic set according to [1] or [2], wherein the content of the component (E) in the second composition is 50 to 99.9% by mass.

[4] The present invention relates to the cosmetic set according to any one of [1] to [3], wherein the content of the component (E) in the second composition is 70 to 99.9% by mass.

[5] The content of the component (A) in the first composition is 10 to 50% by mass, the content of the component (B) is 1 to 50% by mass, and the content of the component (C) is 20. The present invention relates to the cosmetic set according to any one of [1] to [4], which is ~ 85% by mass.

[6] The present invention relates to the cosmetic set according to any one of [1] to [5], wherein the component (B) is a silicone oil having a kinematic viscosity at 25 ° C. of 1000 to 10000 cs.

[7] One or more oil agents in which the component (E) is selected from isostearic acid ester, hydroxystearic acid ester, lanolin derivative, trimellitic acid ester, paramethoxycinerate, and vinylpyrrolidone-based copolymer. It relates to the cosmetic set according to any one of [1] to [6].

[8] The cosmetic set according to [7], wherein the isostearic acid ester of the component (E) is an isostearic acid ester having an emery type isostearic acid group.

[9] The component (E) is polyglyceryl-2 isostearate, polyglyceryl-2 triisostearate, polyglyceryl-2 tetraisostearate, polyglyceryl nonaisostearate-10, polyglyceryldecaisostearate-10, pentaisostearate penta. One or more oils selected from erythricyl, glyceryl triisostearate, ethylhexyl hydroxystearate, lanolin acetate, tritridecyl trimeritoate, ethylhexyl paramethoxysilicate, (vinylpyrrolidone / hexadecene) copolymer [1] ] To [7]. The present invention relates to the cosmetic set according to any one of.

[10] The present invention relates to the cosmetic set according to any one of [1] to [9], wherein the cosmetic set is a lip cosmetic set.

According to the present invention, by using the first composition in combination with the second composition containing a specific oil agent, the effect of preventing color transfer is excellent without color bleeding during use, and the feeling of smoothness after use is improved. It provides a cosmetic set that does not lose its makeup over time.

In Example 2, it is a photograph which confirmed the color transfer when the first composition of Formulation Example 1 and the second composition of Formulation Example 19 or Comparative Formulation Example 8 were combined.

Details of the present invention will be described below. In addition, in this specification, "~" means the range including the numerical values before and after it.

The film-forming silicone resin of the component (A) used in the first composition of the present invention is a compound having a crosslinked structure having a siloxane structure as a main skeleton, and is the silicone oil of the component (B) or the component (C). As long as it dissolves in an oil agent such as volatile hydrocarbon oil and is used for cosmetics, it can be used without particular limitation. Here, the film-forming property means that a solution of a silicone resin dissolved in the volatile hydrocarbon oil of the component (C) is spread on a petri dish and dried, and then a film is formed. The obtained film may be cracked as it dries, and may not be obtained as a single film.

For example, trimethylsiloxysilicic acid, polymethylsilsesquioxane, (Acrylate / dimethicone) copolymer, (Acrylate / stearyl acrylate / dimethicone methacrylate) copolymer and the like can be mentioned, and one or more of these may be used. can.
Commercially available products include X-21-5616 (60% solid content isododecane solution), X-21-5595 (60% solid content isododecane solution), KF-7312J (50% solid content decamethylcyclopentasiloxane solution), and KF- 9021 (50% decamethylcyclopentasiloxane solution), KP-545 (30% solid content decamethylcyclopentasiloxane solution), KP-549 (40% solid content methyltrimethicone solution), KP-550 (50% solid content) Isododecan solution) (manufactured by Shin-Etsu Chemical Industry Co., Ltd.), BELLSIL TMS 803, BELLSIL PMS MK Powerer (Asahi Kasei Wacker Silicone Co., Ltd.), SR1000, SilForm Flexible resin, SS4267 (35% dimethylpolysiloxane solution) (momentive performance performance) Materials Japan GK), BY11-018 (30% decamethylcyclopentasiloxane solution) (manufactured by Toray Dow Corning Silicone Co., Ltd.), etc., and one or more of these are used. be able to.

The content of the film-forming silicone resin of the component (A) in the first composition of the present invention is not particularly limited, but is preferably 10 to 50% by mass (hereinafter simply referred to as "%"), and more preferably 15. It is ~ 35%, more preferably 15-30%. Within this range, it is more preferable that a cosmetic film having an excellent effect of preventing makeup from collapsing can be obtained without a feeling of tightness.

The silicone oil of the component (B) used in the first composition of the present invention having a kinematic viscosity at 25 ° C. of 1000 to 1000000 cs is a silicone oil having fluidity under the conditions of 1 atm and 25 ° C., and is dimethylpoly. Siloxane, methylhydrogenpolysiloxane, phenyl-modified silicone, alkyl-modified silicone and the like are not particularly limited as long as they are used in cosmetics, and one or more of these can be used. The kinematic viscosity of the component (B) at 25 ° C. is preferably 1000 to 1000000 cs, more preferably 1000 to 10000 cs, and particularly preferably 1000 to 100,000 cs. Within this range, it is more preferable that the feeling of tightness due to the silicone resin can be suppressed, and a cosmetic film having an excellent effect of preventing makeup from collapsing can be obtained. On the other hand, if the kinematic viscosity at 25 ° C is less than 1000 cs, a satisfactory color bleeding prevention effect and makeup disintegration prevention effect may not be obtained. The volatilization rate of the component (C) becomes slow, and a satisfactory color bleeding prevention effect may not be obtained.
Commercially available products include KF-96-1000cs / 3000cs / 5000cs, KF-96H-6000cs / 10,000cs / 12500cs / 30,000cs / 50,000cs / 60,000cs / 100,000cs / 300,000cs / 500,000cs / 1 million cs, KF-50-1000 cs (all manufactured by Shin-Etsu Chemical Co., Ltd.), SH-200 C Fluid 1000CS / 3000CS / 5000CS / 10000CS / 12500CS / 30000CS / 60000CS / 100000CS / 1000000CS, BY11-040 / 003 / 007/014/026/320, (all manufactured by Toray Dow Corning Co., Ltd.) and the like. Only one of these may be used, or a combination of two or more thereof may be appropriately adjusted to a predetermined kinematic viscosity before use. In the present invention, the kinematic viscosity is a value measured at 25 ° C. by the ASTM D445 measuring method.

The content of the component (B) in the first composition of the present invention is not particularly limited, but is preferably 1 to 50%, more preferably 3 to 35%, still more preferably 5 to 30%. Within this range, it is more preferable that the feeling of tightness due to the silicone resin can be suppressed, and a cosmetic film having an excellent effect of preventing makeup from collapsing can be obtained.

The volatile hydrocarbon oil of the component (C) used in the first composition of the present invention is liquid at 1 atm and 25 ° C., has volatile properties, has a boiling point in the range of 68 to 260 ° C., and is carbon. Hydrocarbons having a number of 6 to 30 can be mentioned. Usually, it is not particularly limited as long as it is used as a raw material for cosmetics, and specifically, it is a linear hydrocarbon such as normal heptane, isooctane (2,2,4-trimethylpentane, 2,3-dimethylhexane). Etc.), isododecane (2,2,4,6,6-pentamethylheptane, etc.), isohexadecane, hydrocarbons having side chains such as isoeicosaene, or mixtures thereof, isobutene, n-butene, etc. (Preferably, the degree of polymerization is 4 to 6), and then hydrogenated or the like can be mentioned, and one kind or a combination of two or more kinds can be used as needed. Commercially available products include Isopar H (manufactured by ExxonMobil Chemical Co., Ltd.), Isododecane (manufactured by Bayer), Isohexadecane (manufactured by Unichema), IP Solvent 1620MU, IP Solvent 2028MU, IP Solvent 2835 (manufactured by Idemitsu Kosan), etc. Can be mentioned. These can be used alone or in combination of two or more.

The content of the volatile hydrocarbon oil of the component (C) in the first composition of the present invention is not particularly limited, but is preferably 20 to 85%, more preferably 25 to 80%, still more preferably 30 to 30 to. It is 70%. This range is more preferable because it does not give a feeling of tightness and is excellent in color bleeding during use. Further, the content mass ratio of the component (A) to the component (C) is not particularly limited, but (A): (C) = 3: 1 to 1: 1 in terms of excellent color bleeding during use. 6 is preferable, 2: 1 to 1: 5 is more preferable, and 1: 1 to 1: 4 is even more preferable.

The colorant of the component (D) used in the first composition of the present invention has a spherical, plate-like, spindle-like, needle-like shape, smoke-like shape, fine particles, etc., as long as it is a colorant usually used for cosmetics. , Pigment grade, etc., or particle structure such as porous, non-porous, etc., and inorganic colored pigments, organic colored pigments, dyes, brilliant pigments, metals, etc. can be used. .. Specific powders include white inorganic pigments such as titanium oxide, zinc oxide, cerium oxide, and barium sulfate, colored inorganic pigments such as iron oxide, carbon black, chromium oxide, chromium hydroxide, dark blue, ultramarine, and red iron oxide, and mica. Titanium, bismuth oxychloride, organic pigment-treated mica titanium, titanium dioxide-coated mica, titanium dioxide-coated synthetic gold mica, titanium dioxide-coated bismuth oxychloride, iron oxide mica titanium, navy blue-treated mica titanium, carmine-treated mica titanium, fish scale foil, dioxide Bright pigments such as titanium-coated glass powder, polyethylene terephthalate / aluminum / epoxy laminated powder, polyethylene terephthalate / polyolefin laminated film powder, polyethylene terephthalate / polymethylmethacrylate laminated film powder, and other resin laminated powders, Red No. 201, Red No. 202, Organic pigment powders such as Red 205, Red 226, Red 228, Orange 203, Orange 204, Blue 404, Yellow 401, Red 3, Red 104, Red 106, Orange 205, Organic pigment powders such as zirconium, barium or aluminum lake such as yellow 4, yellow 5, green 3, and blue 1, or metal powders such as aluminum powder, gold powder, and silver powder, fine particle titanium oxide-coated mica titanium, Examples of composite powders such as fine particle zinc oxide-coated mica titanium, barium sulfate-coated mica titanium, titanium oxide-containing silicon dioxide, and zinc oxide-containing silicon dioxide can be exemplified, and one or more of them may be combined as necessary. Can be used. These are one or more of fluorine-based compounds, silicone-based compounds, metal soaps, lecithin, hydrogenated lecithin, collagen, hydrocarbons, higher fatty acids, higher alcohols, esters, waxes, waxes, surfactants, etc. The surface treatment may be performed using.

The content of the colorant of the component (D) in the first composition of the present invention is not particularly limited, but is preferably 0.0001 to 30%, more preferably 0.001 to 20%.

In addition to the above-mentioned components (A) to (D), the first composition of the present invention can contain components usually used in cosmetics as long as the effects of the present invention are not impaired. For example, the component (D). ), Components (B), oils other than (C), surfactants, monohydric alcohols, polyhydric alcohols, water-soluble polymers, paraoxybenzoic acid derivatives, preservatives such as phenoxyethanol, UV absorption Agents, moisturizers, antibacterial agents, fragrances, salts, antioxidants, pH regulators, chelating agents, refreshing agents, anti-inflammatory agents, skin-beautifying ingredients (whitening agents, cell activators, rough skin improving agents, blood circulation promoters, skin Astringents, anti-lipids, etc.), vitamins, amino acids, nucleic acids, hormones, inclusion compounds, etc. can be appropriately contained.

As the oil agent, for example, regardless of the origin of animal oil, vegetable oil, synthetic oil, etc., and the properties of solid oil, semi-solid oil, liquid oil, etc., hydrocarbons, fats and oils, waxes, hydrogenated oils, ester oils, etc. Classes, fatty acids, higher alcohols, silicone oils, fluorine-based oils, lanolin derivatives, oil-based gelling agents, oil-soluble resins, volatile oils and the like. Specifically, hydrocarbons such as liquid paraffin, squalane, vaseline, paraffin wax, ceresin wax, microcrystallin wax, ethylene propylene copolymer, montan wax, fishertroph wax, mokurou, olive oil, castor oil, mink oil, macadamian. Fats and oils such as nut oil, waxes such as beeswax, carnauba wax, candelilla wax, gay wax, jojoba oil, cetyl isooctanate, isopropyl myristate, isopropyl palmitate, octyldodecyl myristate, glyceryl trioctanoate, diisostearic acid Esters such as polyglyceryl, diglyceryl triisostearate, glyceryl tribehenate, diisostearyl malate, neopentyl glycol dioctanoate, cholesterol fatty acid ester, di (cholesteryl behenyl octyldodecyl) N-lauroyl-L-glutamate, stearyl Higher alcohols such as alcohols, cetyl alcohols, lauryl alcohols, oleyl alcohols, isostearic alcohols and behenyl alcohols, silicones such as methylphenylpolysiloxane and fluorine-modified organopolysiloxane, perfluorodecane, perfluorooctane, perfluoropolyether and the like. Fluorine oils, lanolin, lanolin acetate, lanolin fatty acid isopropyl, lanolin derivatives such as lanolin alcohol, dextrin octanate, dextrin laurate, dextrin palmitate, dextrin myristate, dextrin stearate, dextrin behenate, coconut oil fatty acid dextrin , (Palmitic acid / octanoic acid) dextrin, citrus fatty acid ester, starch fatty acid ester, 12-hydroxystearic acid, oily gelling agents such as calcium stearate, pentaerythrityl hydrogenated rosinate, specific alkylmethylpolysiloxane acrylate Examples thereof include oil-soluble resins such as esters, volatile oils such as decamethylcyclopentasiloxane, octamethylcyclotetrasiloxane, methyltrimethicone, and silicones such as low-polymerization dimethylpolysiloxane, and one or two of these. The above can be used.

Among the oil agents other than the above components (B) and (C), the content of the oil agent in the first composition of the present invention is not particularly limited with respect to the oil agent liquid at 25 ° C., but the second composition described later. Is preferably 0 to 10%, more preferably 0 to 5%, from the viewpoint of preventing color bleeding when the above is applied.

When the mixture of the component (A) and the component (C) used in the second composition of the present invention mixed at a mass ratio of 1: 1 was mixed in an equal amount and allowed to stand at 25 ° C. for 60 minutes, the phase was observed. The oil agent of the component (E) to be separated is not particularly limited as long as it is used for cosmetics, and can be used.

Examples of the oil agent of the component (E) used in the second composition of the present invention are not particularly limited, but are not particularly limited, but polyglyceryl-2 isostearate, polyglyceryl-2 triisostearate, polyglyceryl-2 tetraisostearate, and nonaisostearate. Polyglyceryl-10 acid, polyglyceryl-10 decaisostearate, pentaerythrityl tetraisostearate, glyceryl triisostearate and other isostearates, ethylhexyl hydroxystearate and other hydroxystearates, lanolin, lanolin acetate, lanolin fatty acids isopropyl, lanolin Lanoline derivatives such as alcohol, trimeritic acid esters such as tridecyl trimeritate and trioctyl trimeritate, paramethoxysilicate ester such as ethylhexyl paramethoxysilicate, and vinylpyrrolidone copolymers such as (vinylpyrrolidone / hexadecene) copolymers. Etc., and these can be used alone or in combination of two or more. Among these, the ease of phase separation when the component (A) and the component (C) are mixed at a mass ratio of 1: 1 and mixed in equal amounts and allowed to stand at 25 ° C. for 60 minutes, and the like. Polyglyceryl-2 isostearate, polyglyceryl-2 triisostearate, polyglyceryl-2 tetraisostearate, polyglyceryl-10 nonaisostearate, polyglyceryl-10 decaisostearate, pentaisostearate from the viewpoint of preventing color bleeding. It is more preferable to use one or more selected from erythricyl, glyceryl triisostearate, ethylhexyl hydroxystearate, lanolin acetate, tritridecyl trimeritoate, ethylhexyl paramethoxysilicate, (vinylpyrrolidone / hexadecene) copolymer. , Polyglyceryl-2 isostearate, Polyglyceryl-2 triisostearate, Polyglyceryl-2 tetraisostearate, Polyglyceryl-10 nonaisostearate, Polyglyceryl-10 decaisostearate, Pentaerythrityl tetraisostearate, Glyceryl triisostearate, Acetic acid It is particularly preferable to use one or more selected from lanolin, tritridecyl trimeritate, and (vinylpyrrolidone / hexadecene) copolymers.

Further, in the isostearic acid ester, isostearic acid means one kind or a mixture of two or more kinds of branched stearic acid. For example, 5,7,7-trimethyl-2- (1,3,3-trimethylbutyl) -octanoic acid is converted into a branched aldehyde having 9 carbon atoms by the oxo reaction of isobutylene dimer, and then carbon is produced by aldol condensation of this aldehyde. It can be produced by preparing a branched unsaturated aldehyde of number 18 and then hydrogenating and oxidizing it (hereinafter, abbreviated as "aldol condensation type"), which is commercially available from, for example, Nissan Chemical Industry Co., Ltd. 2-Heptylundecanoic acid can be produced by dimerizing nonyl alcohol by a gerbet reaction (also called Guerbet reaction or Gerve reaction) and oxidizing it. This is commercially available from Mitsubishi Chemical Industries, Ltd., for example, and has a branching position. As a slightly different similar mixture, it is commercially available from Nissan Chemical Industries, Ltd., and a type in which the starting alcohol is not linearly saturated and has two methyl branches is also commercially available from Nissan Chemical Industries, Ltd. (hereinafter, abbreviated as "garbet reaction type"). ). Methyl-branched isostearic acid is obtained, for example, as a by-product of oleic acid during dimer production [for example, J. oleic acid. Amer. Oil Chem. Soc. , 51, 522 (1974)], for example, those commercially available from Emery, USA (hereinafter abbreviated as "emery type"). Further starting material of dimer acid, which is a starting material of emery-type isostearic acid, may include not only oleic acid but also linoleic acid, linolenic acid and the like. In the present invention, the phase separation when the component (A) and the component (C) are mixed at a mass ratio of 1: 1 and mixed in equal amounts and allowed to stand at 25 ° C. for 60 minutes is not particularly limited. An isostearic acid ester having an emery-type isostearic acid group is more preferable from the viewpoint of ease of use and an effect of preventing color bleeding based on the same.

Commercially available products include Cosmall 41V, Cosmall 42V, Cosmall 43V, Cosmall 44V (manufactured by Nikko Oillio Group Co., Ltd.), ANTARON V-216 (manufactured by ISP), LIPONATE TDTM (manufactured by Lipochemicals), and purified lanolin (Japan). Seika Co., Ltd.), ACELAN SP, CRODAMOL GTIS-LQ- (JP), CRODAMOL PTIS-LQ- (JP) (hereinafter, Croda Japan Co., Ltd.), NIKKOL Decaglin 10-ISV (Nikko Chemicals Co., Ltd.), S Face IS -1009P (Sakamoto Yakuhin Co., Ltd.) and the like can be mentioned, and one or more of these can be used.

The content of the component (E) in the second composition of the present invention is not particularly limited, but is preferably 50 to 99.9%, more preferably 70 to 99.9%. Within this range, by using it in combination with the first composition, the effect of preventing color transfer of the first composition is enhanced, the color does not transfer to a coffee cup or the like, and the makeup does not collapse over time. It is more preferable in that an excellent cosmetic film can be obtained.

In addition to the component (E), the second composition of the present invention contains an oily component, an oil gelling agent, a powder and a surface-treated product thereof, a surfactant, an aqueous component, as long as the effect of the present invention is not impaired. It can contain other ingredients usually contained in cosmetics, such as UV absorbers, moisturizers, antioxidants, cosmetological ingredients, preservatives, pigments, fragrances and the like.

The oily component includes hydrocarbons regardless of the properties of solid oils, semi-solid oils, liquid oils, volatile oils, etc. of origin such as animal oils, vegetable oils, synthetic oils, etc., which are generally used in cosmetics, in addition to the component (E). Examples include oils and fats, waxes, hardened oils, ester oils, fatty acids, higher alcohols, silicone oils, fluorooils, oil-based gelling agents and the like. Specifically, waxes such as beeswax, gay wax, carnauba wax and candelilla wax, fatty acids such as stearic acid, lauric acid, myristic acid, behenic acid, isostearic acid and oleic acid, stearyl alcohol, cetyl alcohol and lauryl. Higher alcohols such as alcohol, oleyl alcohol, isostearyl alcohol, and behenyl alcohol, fluorine-based oils such as perfluorodecane, perfluorooctane, and perfluoropolyether, dextrin octanate, dextrin laurate, dextrin palmitate, and dextrin myristinate. , Dextrin stearate, dextrin behenate, coconut oil fatty acid dextrin, (palmitic acid / octanoic acid) dextrin, sugar fatty acid ester, starch fatty acid ester, aluminum isostearate, potassium stearate, 12-hydroxystearic acid and other oily gelling agents Classes and the like can be mentioned, and one kind or two or more kinds of these can be used.

The powder is not particularly limited by, for example, spherical, plate-like, needle-like shapes, atom-like, fine particles, pigment-grade particle diameters, porous, non-porous particle structures, etc., and is an inorganic powder. , Organic powders, pigment powders, composite powders and the like. Specifically, as colorants, titanium oxide, zinc oxide, black titanium oxide, talc, ultramarine, red iron oxide, yellow iron oxide, black iron oxide, aluminum oxide, magnesium oxide, zirconium oxide, magnesium carbonate, calcium carbonate, barium sulfate. , Chromium oxide, chromium hydroxide, carbon black, tar pigments, etc., as tactile modifiers, silicon oxide, aluminum silicate, magnesium silicate, magnesium aluminum silicate, mica, synthetic mica, synthetic sericite, sericite, talc , Silicon carbide, boron nitride, nylon powder, polymethylmethacrylate, acrylonitrile-methacrylic acid copolymer powder, vinylidene chloride-methacrylic acid copolymer powder, wool powder, silk powder, crystalline cellulose, N-acyllysine, urethane powder, etc. Can be mentioned. In addition, as pearl luster pigments, bismuth oxychloride, mica titanium, iron oxide-coated mica, iron oxide-coated mica titanium, organic pigment-coated mica titanium, aluminum powder, etc. , Fine-grained titanium oxide-coated mica titanium, fine-grained zinc oxide-coated mica titanium, barium sulfate-coated mica titanium, and other composite powders, and one or more of these can be used. In addition, in order to improve dispersibility and adhesiveness, these powders are used by surface-treating them with surface treatment agents such as silicones, fluorine compounds, metal soaps and oils by a method usually known. Is also good.

As the surfactant, any surfactant generally used in cosmetics can be used, such as nonionic surfactant, anionic surfactant, cationic surfactant, amphoteric surfactant and the like. Can be mentioned. For example, glycerin fatty acid ester and its alkylene glycol adduct, polyglycerin fatty acid ester and its alkylene glycol adduct, sorbitan fatty acid ester and its alkylene glycol adduct, polyoxyethylene hydrogenated castor oil, polyoxyalkylene alkyl co-modified organopolysiloxane, Examples thereof include polyether-modified organopolysiloxane and lecithin.

As the aqueous component, in addition to water, for example, alcohols such as ethyl alcohol, propylene glycol, 1,3-butylene glycol, 1,2-pentanediol, dipropylene glycol, glycols such as polyethylene glycol, glycerin, di Examples thereof include glycerols such as glycerin and polyglycerin, and plant extracts such as aloe vera, witch hazel, hamamelis, cucumber, lemon, lavender, and rose.
Examples of the ultraviolet absorber include benzophenone-based, PABA-based, salicylic acid-based ultraviolet absorbers, 4-tert-butyl-4'-methoxydibenzoylmethane, oxybenzone and the like, and examples of the moisturizer include proteins. Mucopolysaccharide, collagen, elastin, keratin and the like can be mentioned, antioxidants include, for example, α-tocopherol, ascorbic acid and the like, and beauty ingredients include, for example, vitamins, anti-inflammatory agents, crude drugs and the like, and antiseptic. Examples of the agent include paraoxybenzoic acid ester, phenoxyethanol, 1,2 pentadiol and the like.

The shapes of the first composition and the second composition of the present invention are not particularly limited, and examples thereof include solid, semi-solid, and liquid ones, which spread and spread lightly during use, and the effect of the present invention is remarkable. A liquid or semi-solid state is preferable, and a liquid state is particularly preferable. The dosage form of the first composition and the second composition of the present invention is not particularly limited, but an oil-based or water-in-oil type having an oil phase as a continuous phase is preferable from the viewpoint of usability and longevity of makeup. An oil-based type having a water content of 1% or less is more preferable from the viewpoint that the effect of the present invention can be remarkably exhibited. The shapes and dosage forms of the first composition and the second composition may be the same or different, but they are preferably the same from the viewpoint that the effects of the present invention are easily exhibited.

The method for producing the first composition and the second composition of the present invention is not particularly limited. For example, in the first composition, the components (A) to (D) and any oily component are heated and mixed. Any powder, aqueous component, etc. can be uniformly mixed and dispersed in a container, and the container can be filled. In the second composition, for example, the component (E) and any oily component are mixed and dispersed, and then optionally. It can be obtained by uniformly heating and mixing the powder and the aqueous component of the above, melting the powder in a container or a mold, pouring and filling the mixture, and cooling.

The cosmetic set containing the first composition and the second composition of the present invention should be used as a lip cosmetic set such as lipstick, lip gloss, lip treatment, lip balm, base lip base, and lipstick overcoat. Is preferable. As a method of use, a method of applying the first composition to an applied portion such as lips and then applying the second composition is preferable, and with this method of use, the effect of the present invention is remarkably exhibited. .. For example, after applying the first composition, the second composition may be applied over a part or all of the surface of the coated portion. The time interval between the application of the first composition and the application of the second composition is not particularly limited, and the second composition may be applied immediately after the application of the first composition. Further, the applied amounts of the first composition and the second composition are not particularly limited, but for example, the mass ratio of the applied amount of the first composition and the applied amount of the second composition in the coating region is 2: 1 to 1: 5. The degree is preferable, and more preferably about 1: 1 to 1: 3.

Hereinafter, the present invention will be described in detail with reference to examples. It should be noted that these do not limit the present invention in any way.

<Experimental example An example of the oil agent of the component (E) used in the second composition>
Experimental Examples 1-12, Experimental Comparative Examples 1-6
For various oils, a mixture of trimethylsiloxysilicic acid (corresponding to component (A)) and isododecane (corresponding to component (C)) at a mass ratio of 1: 1 and an equal amount of various oils were mixed and 25 ° C. When the mixture was allowed to stand for 60 minutes, it was evaluated whether or not the phase was separated according to the following evaluation criteria. The results are shown in Table 1.

(Evaluation criteria)
(Judgment): (Evaluation)
○: Phase separation ×: No phase separation

＊１：ＳＲ１０００（モメンティブ・パフォーマンス・マテリアルズ・ジャパン合同会社製）
＊２：イソドデカン（バイエル社製）
＊３：コスモール ４３Ｖ（日清オイリオグループ社製）
＊４：コスモール ４１Ｖ（日清オイリオグループ社製）
＊５：Ｓ‐フェイスＩＳ‐１００９Ｐ（坂本薬品工業社製）
＊６：ＣＲＯＤＡＭＯＬ ＧＴＩＳ（クローダジャパン社製）
＊７：ＡＣＥＬＡＮ ＳＰ（クローダジャパン社製）
＊８：ＡＮＴＡＲＯＮ Ｖ２１６（アイエスピー・ジャパン社製）
＊９：ＬＩＰＯＮＡＴＥ ＴＤＴＭ（リポケミカルズ社製）
＊１０：コスモール ４３Ｎ（日清オイリオグループ社製）
＊１１：ＴＯＧ（高級アルコール工業社製）
＊１２：サラコス５４０８（日清オイリオグループ社製）
＊１３：コスモール２２２（日清オイリオグループ社製）
＊１４：Ｏ．Ｄ．Ｏ（日清オイリオグループ社製）

* 1: SR1000 (manufactured by Momentive Performance Materials Japan GK)
* 2: Isododecane (manufactured by Bayer)
* 3: Cosmall 43V (manufactured by Nisshin Oillio Group)
* 4: Cosmall 41V (manufactured by Nisshin Oillio Group)
* 5: S-Face IS-1009P (manufactured by Sakamoto Yakuhin Kogyo Co., Ltd.)
* 6: CRODAMOL GTIS (manufactured by Croda Japan)
* 7: ACELAN SP (manufactured by Croda Japan)
* 8: ANTALON V216 (manufactured by ASP Japan)
* 9: LIPONATE TDTM (manufactured by Lipo Chemicals)
* 10: Cosmall 43N (manufactured by Nisshin Oillio Group)
* 11: TOG (manufactured by Higher Alcohol Industry Co., Ltd.)
* 12: Sarakos 5408 (manufactured by Nisshin Oillio Group)
* 13: Cosmall 222 (manufactured by Nisshin Oillio Group)
* 14: O. D. O (manufactured by Nisshin Oillio Group)

As is clear from Table 1, Experimental Examples 1 to 12 were phase-separated, whereas Comparative Experimental Examples 1 to 6 did not undergo phase separation, resulting in a uniform solution. Further, although phase separation was observed in Experimental Example 1 using emery-type polyglyceryl-2 triisostearate having an isostearic acid group, a comparative experiment using aldol-type polyglyceryl-2 triisostearate having an isostearic acid group was observed. In Example 1, no phase separation was observed.

<Example 1 Lip cosmetic set (oil-based liquid)>
Prescription Examples 1 to 12, Comparative Prescription Examples 1 to 4
The first composition shown in Table 2 and the second composition shown in Table 3 were prepared according to the following production methods. When the first composition and the second composition obtained in Tables 2 and 3 are used in combination, there is no color bleeding during use, an effect of preventing color transfer, an effect of preventing makeup from coming off, and a lack of smoothness. The results of evaluation by the following methods are shown in Tables 4 to 7, respectively.

＊１５：ＢＥＬＳＩＬ ＴＭＳ ８０３（旭化成ワッカーシリコーン社製）
＊１６：ＫＰ−５４５（信越化学工業社製）
＊１７：エステルガムＨＰ（荒川化学工業社製）
＊１８：ＫＦ−９６Ｈ−１０万ｃｓ（信越化学工業社製）
＊１９：ＫＦ−９６−１０００ｃｓ（信越化学工業社製）
＊２０：ＫＦ−９６Ａ−１００ｃｓ（信越化学工業社製）
＊２１：ＡＥＲＯＳＩＬ３００（日本アエロジル社製）
＊２２：ＦＬＡＭＥＮＣＯ ＲＥＤ ４２０Ｃ（ＢＡＳＦ社製）
(First composition)

* 15: BEALSIL TMS 803 (manufactured by Asahi Kasei Wacker Silicone Co., Ltd.)
* 16: KP-545 (manufactured by Shin-Etsu Chemical Co., Ltd.)
* 17: Ester gum HP (manufactured by Arakawa Chemical Industry Co., Ltd.)
* 18: KF-96H-100,000 cs (manufactured by Shin-Etsu Chemical Co., Ltd.)
* 19: KF-96-1000cs (manufactured by Shin-Etsu Chemical Co., Ltd.)
* 20: KF-96A-100cs (manufactured by Shin-Etsu Chemical Co., Ltd.)
* 21: AEROSIL300 (manufactured by Aerosil Japan)
* 22: FLAMENCO RED 420C (manufactured by BASF)

(Method for producing the first composition)
A. Ingredients (1) to (10) are mixed and heated to dissolve.
B. (11) to (18) were added to A and mixed uniformly to obtain a first composition.

＊２３：ＣＩＲＥＢＥＬＬＥ １０８（ＣＩＲＥＢＥＬＬＥ社製）
＊２４：パールリーム１８（日油社製）
(Second composition)

* 23: CIREBELLE 108 (manufactured by CIREBELLE)
* 24: Pearl Dream 18 (manufactured by NOF CORPORATION)

(Method for producing the second composition)
A. Ingredients (1) to (9) are mixed and heated to dissolve.
B. (10) to (11) were added to A and mixed uniformly to obtain a second composition.

(Evaluation item)
No color bleeding during use

(Evaluation method 1: Sensory evaluation)
Each sample was subjected to a usage test by 20 specialized panels to evaluate the absence of bleeding during use. Specifically, each panel member has 7 grades according to the following absolute evaluation criteria 1 regarding the absence of color bleeding when the first composition is applied to the lips and then the second composition is applied onto the first composition. Was evaluated and graded, and the average value was calculated from the total score of all the panels of each sample, and the judgment was made according to the following criteria.

<Absolute evaluation standard 1>
(Score): (Evaluation)
6: Not bleeding at all 5: Almost not bleeding 4: Slightly bleeding 3: Normal 2: Slightly bleeding 1: Blurred 0: Very bleeding <Criteria>
(Judgment): (Average score)
⊚: 5.0 or more to 6.0 or less ○: 3.5 or more to less than 5.0 Δ: 2.0 or more to less than 3.5 ×: 0 or more to less than 2.0

As is clear from the results in Table 4, Examples (shaded portions in the table) in which Formulation Examples 1 to 8 of the first composition and Formulation Examples 9 to 12 of the second composition are used in combination are Comparative Examples. Compared to (other than the shaded area in the table), it was superior in that there was no bleeding during use.

(Evaluation item)
Color transfer prevention effect

(Evaluation method 2: Sensory evaluation)
Each sample was subjected to a usage test by 20 specialized panels, and the color transfer prevention effect was evaluated by a specialized evaluator. Specifically, 10 seconds after the first composition was applied to the lips and the second composition was applied onto the first composition, the tissue was pressed against the lips, and after the tissue was removed, it was applied to the lips of each panel. A professional evaluator visually evaluates whether the color of the first composition remains, evaluates it on a 7-point scale according to the absolute evaluation standard 2 below, gives a score, and calculates the average value from the total score of all the panels of each sample. It was calculated and judged according to the following criteria.

<Absolute evaluation standard 2>
(Score): (Evaluation)
6: Very much left 5: Good left 4: Some left 3: Normal 2: Some little left 1: No left 0: Very little left <Judgment criteria>
(Judgment): (Average score)
⊚: 5.0 or more to 6.0 or less ○: 3.5 or more to less than 5.0 Δ: 2.0 or more to less than 3.5 ×: 0 or more to less than 2.0

As is clear from the results in Table 5, Examples (shaded portions in the table) in which Formulation Examples 1 to 8 of the first composition and Formulation Examples 9 to 12 of the second composition are used in combination are Comparative Examples. Compared with (other than the shaded area in the table), the effect of preventing color transfer was excellent.

(Evaluation item)
Makeup collapse prevention effect

(Evaluation method 3: Sensory evaluation)
Each sample was subjected to a use test by 20 specialized panels to evaluate the effect of preventing makeup from coming off. Specifically, after applying the first composition to the lips, applying the second composition on the first composition, and having them spend a normal life, four hours later, the color of the first composition changes. Each panel evaluated whether it remained on the lips on a 7-point scale according to the following absolute evaluation criteria 3, and gave a score. From the total score of all the panels of each sample, the average value was calculated and judged according to the following criteria. ..

<Absolute evaluation standard 3>
(Score): (Evaluation)
6: Very much left 5: Good left 4: Some left 3: Normal 2: Some little left 1: No left 0: Very little left <Judgment criteria>
(Judgment): (Average score)
⊚: 5.0 or more to 6.0 or less ○: 3.5 or more to less than 5.0 Δ: 2.0 or more to less than 3.5 ×: 0 or more to less than 2.0

As is clear from the results in Table 6, Examples (shaded portions in the table) in which Formulation Examples 1 to 8 of the first composition and Formulation Examples 9 to 12 of the second composition are used in combination are Comparative Examples. Compared to (other than the shaded area in the table), it was superior in the effect of preventing makeup from coming off.

(Evaluation item)
No feeling of tightness

(Evaluation method 4: Sensory evaluation)
Each sample was subjected to a usage test by 20 specialized panels to evaluate the lack of tightness. Specifically, after applying the first composition to the lips, after applying the second composition on the first composition, have them spend a normal life, and after 4 hours, feel a feeling of tightness. Each panel evaluated and scored in 7 stages according to the following absolute evaluation criteria 4, calculated the average value from the total score of all the panels of each sample, and judged according to the following criteria.

<Absolute evaluation standard 4>
(Score): (Evaluation)
6: I don't feel very tight 5: I don't feel tight 4: I don't feel a little tight 3: Normal 2: I feel a little tight 1: I feel a little tight 0: I feel a very tight <Judgment Criteria>
(Judgment): (Average score)
⊚: 5.0 or more to 6.0 or less ○: 3.5 or more to less than 5.0 Δ: 2.0 or more to less than 3.5 ×: 0 or more to less than 2.0

As is clear from the results in Table 7, Examples (shaded portions in the table) in which Formulation Examples 1 to 8 of the first composition and Formulation Examples 9 to 12 of the second composition are used in combination are Comparative Examples. Compared to (other than the shaded area in the table), it was superior in that it did not feel smooth.

<Example 2 Lip cosmetic set (oil-based liquid)>
Prescription Examples 13 to 24, Comparative Prescription Examples 5 to 10
The second composition shown in Table 8 was prepared according to the following production method. When each of the second compositions is used in combination with the first composition of Formulation Example 1 shown in Table 2 above, there is no color bleeding during use, an effect of preventing color transfer, an effect of preventing makeup from coming off, and no feeling of smoothness. Was evaluated by the same method as in Example 1. The results are also shown in Table 8. Further, with respect to Formulation Example 19 and Comparative Formulation Example 8, the effect of preventing color transfer was further evaluated by the following test method. The result is shown in FIG.

(Method for producing the second composition)
A. Ingredients (1) to (19) are mixed and heated to dissolve.
B. (20) was added to A and mixed uniformly to obtain a second composition.

(Test method for color transfer prevention effect)
1. 1. 2. Apply 0.1 g of the first composition to a range of 2 cm x 5 cm on synthetic leather (PBZ13001-BK: manufactured by Komatsu Smelting Co., Ltd.). 2. Apply 0.15 g of the second composition to the same area. 2. Immediately after applying the second composition, place four layers of tissue on the applied area, place a glass plate (56 g) on it, and leave it for 15 seconds. Peel off the tissue and visually check the color transfer

As shown in the results of Table 8, in the experimental example, the mixture was mixed with a mixture of trimethylsiloxysilicic acid and isododecane at a mass ratio of 1: 1 in equal amounts, and allowed to stand at 25 ° C. for 60 minutes for phase separation. The second compositions of Formulation Examples 13 to 24 using the prepared oil are excellent in all items of no color bleeding, color transfer prevention effect, makeup loss prevention effect, and no feeling of smoothness in combination with Formulation Example 1. It was a thing. On the other hand, the second compositions of Comparative Formulation Examples 5 to 10 using the oil agent which did not undergo phase separation were inferior in the absence of color bleeding, the effect of preventing color transfer, and the effect of preventing makeup loss. Further, as shown in FIGS. 1 and 2, when the second composition of Formulation Example 19 was used, the color transfer was limited to a small part of the coating region, whereas when Comparative Formulation Example 8 was used. Color transfer was observed over almost the entire surface.

Formulation Example 25: Lipstick (first composition)
(Ingredient) (%)
1. 1. (Acrylate / Stearyl Acrylate /
Dimethicone Methacrylate) Copolymer 35
2. Dimethylpolysiloxane * 25 10
3. 3. Dimethylpolysiloxane * 18 10
4. Hydrogenated polyisobutene * 26 35
5. Talc remaining amount 6. Silica * 21 1
7. Titanium oxide coated glass powder * 27 2
8. Red No. 202 1
9. Yellow No. 4 Aluminum Rake 1
10. Black iron oxide 0.2
11. Fragrance 0.01
* 25: KF-96A-5000cs (manufactured by Shin-Etsu Chemical Co., Ltd.)
* 26: IP Solvent 1620MU (manufactured by Idemitsu Kosan Co., Ltd.)
* 27: Metashine 1080RC-R (manufactured by Nippon Sheet Glass)
(Production method)
A. Ingredients (1) to (4) are heated and mixed to uniformly dissolve them.
B. Ingredients (5) to (11) are added to A and mixed uniformly.
C. B was filled in a container to obtain lipstick.

Formulation Example 26: Lipstick (first composition)
(Ingredient) (%)
1. 1. (Acrylate / Dimethicone) Copolymer * 16 45
2. Dimethylpolysiloxane * 285
3. 3. Dimethylpolysiloxane * 18 3
4. Hydrogenated polyisobutene * 26 40
5. Boron Nitride Remaining 6. Silica * 21 1
7. Red No. 202 1
8. Yellow No. 4 Aluminum Rake 1
9. Black iron oxide 0.2
10. Fragrance 0.01
* 28: KF-96H-50,000cs (manufactured by Shin-Etsu Chemical Co., Ltd.)
(Production method)
A. Ingredients (1) to (4) are heated and mixed to uniformly dissolve them.
B. Ingredients (5) to (10) are added to A and mixed uniformly.
C. B was filled in a container to obtain lipstick.

Formulation Example 27: Lip Gloss (Second Composition)
(Ingredient) (%)
1. 1. Fischer-Tropsch Wax 2
2. Dextrin palmitate 5
3. 3. (Vinylpyrrolidone / hexadecene) Copolymer * 8 10
4. Diisostearyl malate * 135
5. Pentaerythrityl tetraisostearate * 29 30
6. Polyisobutene 5
7. Tridecyl trimeritoate 25
8. Trimethylpentaphenyltrisiloxane 2
9. Di lauroyl glutamate (octyldodecyl /
Phytosteryl / Behenil) 5
10. Polyglyceryl decisostearate-10 Remaining amount 11. Silica * 21 1
12. Titanium oxide coated glass powder * 30 2
13. Red No. 202 0.2
14. Yellow No. 4 Aluminum Rake 0.3
15. Black iron oxide 0.2
16. Ethethylhexyl paramethoxycinnamate 1
17. dl-α-topherol 0.1
18. Fragrance 0.01
19. Propyl paraoxybenzoate 0.1
* 29: CRODAMOL PTIS-LQ- (JP) (manufactured by Croda Japan Co., Ltd.)
* 30: Metashine 1080RC-R (manufactured by Nippon Sheet Glass Co., Ltd.)
(Production method)
A. Ingredients (1) to (10) are heated to 110 ° C. and uniformly dissolved.
B. Ingredients (11) to (19) are added to A and mixed uniformly.
C. B was filled in a container to obtain lip gloss.

Formulation Example 28: Lip gloss (oil-based solid dish pouring, second composition)
(Ingredient) (%)
1. 1. Synthetic wax 7
2. Lanolin acetate 10
3. 3. Polyglyceryl triisostearate-2 * 3 Remaining amount 4. Ethylhexyl hydroxystearate 8
5. Polyglyceryl tetraisostearate-2 * 31 25
6. Polyglyceryl pentaisostearate * 32 10
7. N-lauroyl-L-glutamic acid (phytosteryl / octyldodecyl) 5
8. Dimer dilinoleic acid (phytosteryl /
Isostearyl / cetyl / stearyl / beheni 10
9. Trimethylsiloxyphenyldimethicone 5
10. Diphenylsiloxyphenyltrimethicone 1
11. (Vinyldimethicone / methicone silsesquioxane)
Cross polymer 2
12. Silica * 21 3
13. Red 202 0.5
14. Yellow No. 4 0.03
15. Titanium oxide 0.4
16. Black iron oxide 0.2
17. Titanium oxide coated synthetic phlogopite * 33 3
* 31: Cosmall 44V (manufactured by Nisshin Oillio Group)
* 32: NIKKOL Decaglin 5-SV (manufactured by Nikko Chemicals Co., Ltd.)
* 33: Prominence SF (manufactured by Topy Industries, Ltd.)
(Production method)
A: Ingredients (1) to (11) are heated to 110 ° C. to dissolve them.
B: Add (12) to (17) to A and mix uniformly.
C: B is defoamed and then filled in a container at 90 ° C. to obtain a product.

Formulation Example 29: Formulation Example 17: Lipstick (first composition)
(Ingredient) (%)
1. 1. Trimethylsiloxysilicic acid * 1 29
2. Isododecane remaining amount 3. Dimethylpolysiloxane * 18 22
4. Trimethylsiloxyphenyldimethicone * 346
5. Gistear dimonium hectorite 3
6.1,3-butylene glycol 1
7. Red No. 104 1
8. Red No. 202 0.5
9. Yellow No. 5 0.5
10. Titanium oxide 0.5
11. PEG-9 Polydimethylsiloxyethyl Dimethicone 0.1
12. Fragrance 0.01
* 34: BEALSIL PDM 1000 (manufactured by Asahi Kasei Wacker)
(Production method)
A. Ingredients (1) to (6) are heated and mixed to uniformly dissolve them.
B. Ingredients (7) to (12) are added to A and mixed uniformly.
C. B was filled in a container to obtain lipstick.

Formulation Example 30: Lip Gloss (Second Composition)
(Ingredient) (%)
1. 1. Dextrin palmitate 7
2. Glyceryl triisostearate 50
3. 3. Polyglyceryl decisostearate-10 Remaining amount 4. Dimethylsilylated silica 2
5.1,2-Pentanediol 0.2
(Production method)
A. Ingredients (1) to (5) are heated and uniformly dissolved.
B. A was filled in a container to obtain lip gloss.

Formulation Example 31: Lipstick (first composition)
(Ingredient) (%)
1. 1. Trimethylsiloxysilicic acid * 1 15
2. Polymethylsilsesquioxane 10
3. 3. Polypropylsilsesquioxane 3
4. Isododecan Remaining amount 5. Dimethylpolysiloxane * 18 15
6. Dimethiconol * 355
7. Trimethylsiloxyphenyldimethicone * 338
8. Gistear dimonium hectorite 3
9.1,3-butylene glycol 1
10. Red No. 226 1
11. Red No. 202 0.5
12. Yellow No. 4 0.5
13. Titanium oxide 0.5
14. PEG-9 polydimethylsiloxyethyl dimethicone 0.1
15. Fragrance 0.01
* 35: X-21-5849 (manufactured by Shin-Etsu Chemical Co., Ltd.)
(Production method)
A. Ingredients (1) to (9) are heated and mixed to uniformly dissolve them.
B. Ingredients (10) to (15) are added to A and mixed uniformly.
C. B was filled in a container to obtain lipstick.

Formulation Example 32: Lip gloss (oil-based solid dish pouring, second composition)
(Ingredient) (%)
1. 1. Dibutyl Lauroyl Glutamino 5
2. Dibutylethylhexanoylglutamide 2
3. 3. Ethylhexyl hydroxystearate 40
4. Polyglyceryl nonaisostearate-10 Remaining amount 5. Dimethylsilylated silica 2
6.1,2-octanediol 0.1
7. Perfluoctyltriethoxysilane treatment Iron oxide / titanium oxide coated glass powder * 36 0.5
8. Perfluoctyltriethoxysilane treatment Iron oxide coated glass powder * 37 0.5
* 36: Microglass Metashine MT1080TY (manufactured by Nippon Sheet Glass) treated with 2% perfluorooctyltriethoxysilane * 37: Microglass Metashine MT1080TZ (manufactured by Nippon Sheet Glass) with 2 perfluorooctyltriethoxysilane % Treated (manufacturing method)
A. Ingredients (1) to (8) are heated and uniformly dissolved.
B. A was filled in a container to obtain lip gloss.

Prescription Example 25 Lipstick and Prescription Example 27 Lip Gloss, Prescription Example 25 Lipstick and Prescription Example 28 Lip Gloss, Prescription Example 26 Lipstick and Prescription Example 27 Lip Gloss, Prescription Example 26 Lipstick and Prescription Example 28 Lip Gloss, Prescription Example 29 Lipstick and Prescription Example 30 Lip gloss, prescription example 31 Lipstick and prescription example 32 Lip gloss, a lip cosmetic set used in combination with a prescription example, has an excellent effect of preventing color transfer without bleeding during use, and is smooth after use. There was no feeling, and the makeup did not come off over time.

Claims (7)

A cosmetic set containing the first composition and the second composition, wherein the first composition is applied to an application portion and then the second composition is applied, and the first composition and the second composition are applied. A cosmetic set in which each composition contains the following ingredients.
(First composition)
(A) Film-forming silicone resin (B) Silicone oil having a kinematic viscosity at 25 ° C. of 1000 to 1000000 cs (C) Volatile hydrocarbon oil (D) Color pigment (second composition)
(E) One or more oils selected from pentaerythrityl tetraisostearate, hydroxystearic acid ester, lanolin derivative, trimeritic acid ester, paramethoxysilicate ester and vinylpyrrolidone-based copolymer. Claimed that the component (A) is one or more selected from trimethylsiloxysilicic acid, polymethylsilsesquioxane, (Acrylate / dimethicone) copolymer, (Acrylate / stearyl acrylate / dimethicone methacrylate) copolymer. Item 1. The cosmetic set according to item 1. The cosmetic set according to claim 1 or 2, wherein the content of the component (E) in the second composition is 50 to 99.9% by mass. The cosmetic set according to any one of claims 1 to 3, wherein the content of the component (E) in the second composition is 70 to 99.9% by mass. The content of the component (A) in the first composition is 10 to 50% by mass, the content of the component (B) is 1 to 50% by mass, and the content of the component (C) is 20 to 85% by mass. The cosmetic set according to any one of claims 1 to 4, which is%. The cosmetic set according to any one of claims 1 to 5, wherein the component (B) is a silicone oil having a kinematic viscosity at 25 ° C. of 1000 to 10000 cs. The cosmetic set according to any one of claims 1 to 6 , wherein the cosmetic set is a lip cosmetic set.

Images