JP7449677B2 - Roll-in margarine and its manufacturing method - Google Patents
Roll-in margarine and its manufacturing method Download PDFInfo
- Publication number
- JP7449677B2 JP7449677B2 JP2019205804A JP2019205804A JP7449677B2 JP 7449677 B2 JP7449677 B2 JP 7449677B2 JP 2019205804 A JP2019205804 A JP 2019205804A JP 2019205804 A JP2019205804 A JP 2019205804A JP 7449677 B2 JP7449677 B2 JP 7449677B2
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- oil
- margarine
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Landscapes
- Edible Oils And Fats (AREA)
- Bakery Products And Manufacturing Methods Therefor (AREA)
Description
本発明は、ロールインマーガリン、及びその製造方法に関する。 The present invention relates to roll-in margarine and a method for producing the same.
シート形状のロールインマーガリンは、デニッシュやクロワッサン等の層状食品を製造するにあたって使用され、ロールインマーガリンを生地に重ねて折り込み、伸展した後、焼成することで層状食品が製造される。 Sheet-shaped roll-in margarine is used in the production of layered foods such as danishes and croissants, and the layered foods are produced by folding the roll-in margarine over dough, stretching it, and baking it.
ロールインマーガリンの製造方法としては、特許文献1に記載されているように、乳化物を急冷捏和した後、レスティングチューブで結晶の安定化を行い、その後、押出成型機において成型ノズルを使用し、流量に見合ったスピードのベルトコンベアー上にシート状に押し出した後、該シートを目的の長さで切断する方法が知られている。 As described in Patent Document 1, the method for manufacturing roll-in margarine involves rapidly cooling and kneading the emulsion, stabilizing the crystals in a resting tube, and then using a molding nozzle in an extrusion molding machine. However, a method is known in which the sheet is extruded onto a belt conveyor at a speed commensurate with the flow rate, and then the sheet is cut into a desired length.
ロールインマーガリンが層状食品の風味に与える影響は大きい。近年、嗜好の多様化により、チョコレート風味や抹茶風味など、バター風味以外の風味を有する層状食品が増加しており、そのため、ロールインマーガリンに各種の呈味剤を配合することが検討されている。そのような呈味剤としては、ココアパウダーや抹茶粉末など、油にも水にも溶解しない固形粉末が挙げられる。 Roll-in margarine has a significant effect on the flavor of layered foods. In recent years, due to the diversification of tastes, the number of layered foods with flavors other than butter flavor, such as chocolate flavor and matcha flavor, has increased, and therefore, incorporating various flavoring agents into roll-in margarine is being considered. . Such flavoring agents include solid powders that are neither soluble in oil nor water, such as cocoa powder and matcha powder.
例えば、特許文献2では、無脂カカオ分を5~27重量%含有し、層状食品にチョコレート風味を付与できるロールインマーガリンが開示されている。ロールインマーガリンの製造方法としては、上述したような、乳化物を急冷捏和した後、成型機によって成型する方法が記載されている。 For example, Patent Document 2 discloses roll-in margarine containing 5 to 27% by weight of non-fat cacao and capable of imparting chocolate flavor to layered foods. As a method for producing roll-in margarine, a method is described in which an emulsion is rapidly cooled and kneaded and then molded using a molding machine, as described above.
上述した成型ノズルを使用するロールインマーガリンの製造方法では、成型機内で乳化物に数МPaという高い圧力がかかる。そのため、乳化物が上述した固形粉末を含有していると、乳化や結晶化が不安定になったり、また、成型機のシール部が損傷したりする場合がある。添加する固形粉末の量が多くなると、製造中や使用時にロールインマーガリンからの離水量が多くなり、ロールインマーガリンの品質が低下する問題が生じた。そのため、ロールインマーガリンに固形粉末を多く添加することで層状食品に十分な風味を付与することが困難であった。 In the method for manufacturing roll-in margarine using the above-mentioned molding nozzle, a high pressure of several MPa is applied to the emulsion in the molding machine. Therefore, if the emulsion contains the above-mentioned solid powder, emulsification and crystallization may become unstable, and the seal portion of the molding machine may be damaged. When the amount of solid powder added increases, the amount of water separation from the roll-in margarine during production and use increases, causing a problem that the quality of the roll-in margarine deteriorates. Therefore, it has been difficult to add sufficient flavor to layered foods by adding a large amount of solid powder to roll-in margarine.
また、このような従来の製造方法では、捏和機内での結晶化が必要となるため、流動状態で容器に入れるだけで製造可能なマーガリンと比べて、生産性が低いという問題がある。 In addition, such conventional production methods require crystallization in a kneading machine, so there is a problem in that productivity is lower than margarine, which can be produced by simply placing margarine in a fluidized state in a container.
更に、ロールインマーガリンには、これを用いて層状食品を作製する際に、生地上で均一に伸びて生地に折り込む作業が短時間で済み、作業性が良好であることや、作製した層状食品は、各層の間に隙間があって浮きが良好であることが求められる。 Furthermore, when using roll-in margarine to make layered foods, it spreads uniformly on the dough and can be folded into the dough in a short time, making it easy to work with. It is required that there is a gap between each layer and that the material floats well.
本発明の目的は、上記現状に鑑み、生産性が良好で、油にも水にも溶解しない固形粉末を含有しながらも離水が抑制されており、かつ、ロールインマーガリンを用いた層状食品の作製時に作業性が良好で、作製された層状食品で良好な浮きと良好な風味を達成できるロールインマーガリン、及び、その製造方法を提供することである。 In view of the above-mentioned current situation, the object of the present invention is to produce a layered food using roll-in margarine, which has good productivity, suppresses syneresis even though it contains a solid powder that does not dissolve in oil or water. To provide a roll-in margarine that has good workability during production and can achieve good floating and good flavor in the produced layered food, and a method for producing the same.
本発明者らは上記課題を解決するために鋭意研究を重ねた結果、油相と水相の比率が特定範囲にあり、少なくとも2種類の特定の油脂と粉末状の固形分をそれぞれ特定の含有量で含み、油脂が融解した状態にある油中水型乳化油脂組成物を、特定温度まで冷却した後、特定時間保持して晶析せしめ、その後、混和により軟化させながら特定温度に昇温させて、粘度を特定値に調整して流動状の油中水型乳化油脂組成物をピロー包装に充填し、該ピロー包装の口を閉じてからシート状に圧延して成型した後、特定温度で特定時間以上静置することでロールインマーガリンを製造すると、ロールインマーガリンの生産性が良好で、従来法のような成型ノズルを使用せず高い圧力が付加されないため、粉末状の固形分を含有するにも関わらず離水が抑制され、かつ、ロールインマーガリンを用いた層状食品の作製時に作業性が良好で、作製された層状食品で良好な浮きと良好な風味を達成できるロールインマーガリンを製造できることを見出し、本発明を完成するに至った。 As a result of extensive research to solve the above problems, the present inventors have found that the ratio of the oil phase to the aqueous phase is within a specific range, and that at least two types of specific oils and fats and powdered solids are contained in specific amounts. A water-in-oil emulsified fat composition containing a certain amount of fat and oil in a molten state is cooled to a specific temperature, held for a specific time to crystallize, and then heated to a specific temperature while being softened by mixing. Then, the viscosity is adjusted to a specific value, and a fluid water-in-oil emulsified fat composition is filled into a pillow package, the mouth of the pillow package is closed, and the pillow package is rolled and molded into a sheet shape, and then heated at a specific temperature. When roll-in margarine is manufactured by leaving it to stand for a certain period of time, the productivity of roll-in margarine is good, and because it does not use a molding nozzle and high pressure is not applied as in conventional methods, it contains powdered solid content. To produce a roll-in margarine that suppresses syneresis despite the use of roll-in margarine, has good workability when producing layered foods using roll-in margarine, and can achieve good floating and good flavor in the layered foods produced. We have discovered that this can be done, and have completed the present invention.
即ち、本発明は、ロールインマーガリン全体中の油相含有量/水相含有量(重量比)が50/50~97/3であり、ロールインマーガリン中に含まれる油相全体中、油脂(A)を15~30重量%、油脂(B)を20~45重量%を含有し、油相と水相のいずれにも溶解しない粉末状の固形分をロールインマーガリン全体中5~50重量%含み、前記粉末状の固形分を含み、油脂が融解した状態にある油中水型乳化油脂組成物が、0~25℃まで冷却されて該温度で10~300秒間保持され晶析された後、混和により軟化させられながら10~35℃に昇温されて、粘度が10~250Pa・sに調整された流動状の前記油中水型乳化油脂組成物がピロー包装に充填され、該ピロー包装の口が閉じられてからシート状に圧延されて成型され、-30℃~30℃で24時間以上静置されたロールインマーガリンにも関する。
油脂(A):構成脂肪酸全体中、炭素数12以下の飽和脂肪酸含有量が15重量%以上、炭素数18以上の飽和脂肪酸含有量が15重量%以上、飽和脂肪酸含有量が70重量%以上であり、三飽和トリグリセライド含有量が油脂(A)全体中15重量%以上である、エステル交換または極度硬化された油脂
油脂(B):飽和脂肪酸含有量が構成脂肪酸全体中20重量%以下であり、三不飽和トリグリセライド含有量が油脂(B)全体中50重量%以上である油脂
好ましくは、ロールインマーガリン中に含まれる油脂全体中SSU含有量/SUS含有量(重量比)が、1.5~2.5である。
S:炭素数16以上の飽和脂肪酸
U:炭素数16以上の不飽和脂肪酸
SSU:1,2位又は2,3位にS、1位又3位にUが結合しているトリグリセリド
SUS:1,3位にS、2位にUが結合しているトリグリセリド
好ましくは、前記粉末状の固形分は最大粒径が300μm以下である。好ましくは、前記ロールインマーガリンは乳化剤を含まない。
また本発明は、前記ロールインマーガリンを含む層状食品用生地にも関し、また、前記層状食品用生地が焼成された層状食品にも関する。
さらに本発明は、油相全体中、油脂(A)を15~30重量%、油脂(B)を20~45重量%を含む油脂と必要に応じてその他の油溶性成分を混合して溶解した後、油相と水相のいずれにも溶解しない粉末状の固形分を油中水型乳化油脂組成物全体中5~50重量%加えて分散させた後、該温度で保持して油相とし、水と必要に応じてその他の水溶性成分を混合して水相とした後、前記油相量/前記水相量(重量比)が50/50~97/3の範囲で前記水相を前記油相に加えながら攪拌して乳化させて、前記粉末状の固形分を含む油中水型乳化油脂組成物を得、該油中水型乳化油脂組成物を0~25℃まで冷却して該温度で10~300秒間保持して晶析せしめた後、混和により軟化させながら10~35℃に昇温させて、粘度を10~250Pa・sに調整した流動状の前記油中水型乳化油脂組成物をピロー包装に充填し、該ピロー包装の口を閉じてからシート状に圧延して成型し、-30℃~30℃で24時間以上静置することを特徴とする、ロールインマーガリンの製造方法にも関する。
油脂(A):構成脂肪酸全体中、炭素数12以下の飽和脂肪酸含有量が15重量%以上、炭素数18以上の飽和脂肪酸含有量が15重量%以上、飽和脂肪酸含有量が70重量%以上であり、三飽和トリグリセライド含有量が油脂(A)全体中15重量%以上である、エステル交換または極度硬化された油脂
油脂(B):飽和脂肪酸含有量が構成脂肪酸全体中20重量%以下であり、三不飽和トリグリセライド含有量が油脂(B)全体中50重量%以上である油脂
That is, in the present invention, the oil phase content/aqueous phase content (weight ratio) in the entire roll-in margarine is 50/50 to 97/3, and the oil/fat ( Containing 15 to 30% by weight of A) and 20 to 45% by weight of fats and oils (B), 5 to 50% by weight of the entire roll-in margarine contains powdered solids that do not dissolve in either the oil phase or the aqueous phase. After the water-in-oil emulsified fat composition containing the powdered solid content and in which the fat and oil are in a molten state is cooled to 0 to 25°C and held at that temperature for 10 to 300 seconds to crystallize. The water-in-oil emulsified fat composition in a fluid state is heated to 10 to 35° C. while being softened by mixing, and the viscosity is adjusted to 10 to 250 Pa·s. It also relates to roll-in margarine that is rolled into a sheet after the mouth of the margarine is closed, and then left at -30°C to 30°C for 24 hours or more.
Fats and oils (A): The content of saturated fatty acids with carbon numbers of 12 or less is 15% by weight or more, the content of saturated fatty acids with carbon numbers of 18 or more is 15% by weight or more, and the saturated fatty acid content is 70% by weight or more of the total fatty acids. Yes, transesterified or extremely hardened fats and oils have a trisaturated triglyceride content of 15% by weight or more based on the total fats and oils (A) Fats and oils (B): saturated fatty acids content is 20% by weight or less based on the entire constituent fatty acids, Fats and oils having a triunsaturated triglyceride content of 50% by weight or more in the whole fat and oil (B) Preferably, the SSU content/SUS content (weight ratio) in the whole fat and oil contained in the roll-in margarine is 1.5 to 1. It is 2.5.
S: Saturated fatty acid with 16 or more carbon atoms U: Unsaturated fatty acid with 16 or more carbon atoms SSU: Triglyceride in which S is bonded to the 1st, 2nd or 2nd, 3rd position, and U is bonded to the 1st or 3rd position SUS: 1, Triglyceride in which S is bonded to the 3rd position and U is bonded to the 2nd position Preferably, the powdery solid content has a maximum particle size of 300 μm or less. Preferably, the roll-in margarine is free of emulsifiers.
The present invention also relates to a layered food dough containing the roll-in margarine, and also to a layered food obtained by baking the layered food dough.
Further, in the present invention, the entire oil phase contains 15 to 30% by weight of the fat (A) and 20 to 45% by weight of the fat (B), and other oil-soluble components are mixed and dissolved as necessary. After that, 5 to 50% by weight of the entire water-in-oil emulsified oil/fat composition is added to disperse a powdery solid that does not dissolve in either the oil phase or the water phase, and then maintained at the temperature to form the oil phase. , After mixing water and other water-soluble components as necessary to form an aqueous phase, the aqueous phase is prepared such that the amount of the oil phase/the amount of the aqueous phase (weight ratio) is in the range of 50/50 to 97/3. Stir and emulsify while adding to the oil phase to obtain a water-in-oil emulsified oil-fat composition containing the powdered solid content, and cool the water-in-oil emulsified oil-fat composition to 0 to 25 ° C. The water-in-oil emulsion in a fluid state is maintained at the temperature for 10 to 300 seconds to crystallize, and then heated to 10 to 35°C while being softened by mixing to adjust the viscosity to 10 to 250 Pa·s. A roll-in margarine characterized in that an oil and fat composition is filled into a pillow package, the mouth of the pillow package is closed, and the pillow package is rolled and molded into a sheet, and then left to stand at -30°C to 30°C for 24 hours or more. It also relates to a manufacturing method.
Fats and oils (A): The content of saturated fatty acids with carbon numbers of 12 or less is 15% by weight or more, the content of saturated fatty acids with carbon numbers of 18 or more is 15% by weight or more, and the saturated fatty acid content is 70% by weight or more of the total fatty acids. Yes, transesterified or extremely hardened fats and oils have a trisaturated triglyceride content of 15% by weight or more based on the total fats and oils (A) Fats and oils (B): saturated fatty acids content is 20% by weight or less based on the entire constituent fatty acids, Fats and oils having a triunsaturated triglyceride content of 50% by weight or more based on the whole fat and oil (B)
本発明に従えば、生産性が良好で、油にも水にも溶解しない固形粉末を含有しながらも離水が抑制されており、かつ、ロールインマーガリンを用いた層状食品の作製時に作業性が良好で、作製された層状食品で良好な浮きと良好な風味を達成できるロールインマーガリン、及び、その製造方法を提供することができる。本発明に係るロールインマーガリンは粉末状の呈味剤を多く含有することができ、離水が抑制され品質も良好で、良好な浮きと良好な風味を有する層状食品を、作業性よく作製することができる。 According to the present invention, productivity is good, syneresis is suppressed even though it contains solid powder that does not dissolve in oil or water, and workability is improved when producing layered foods using roll-in margarine. It is possible to provide roll-in margarine that is good and can achieve good float and good flavor in the produced layered food, and a method for producing the same. The roll-in margarine according to the present invention can contain a large amount of a powdery flavoring agent, suppress syneresis, have good quality, and produce a layered food having good floating and good flavor with good workability. Can be done.
以下、本発明の実施形態につき、さらに詳細に説明する。本実施形態に係るロールインマーガリンの好適な態様は、ロールインマーガリン全体中の油相含有量/水相含有量(重量比)が50/50~97/3であり、ロールインマーガリン中に含まれる油相全体中、油脂(A)を15~30重量%、油脂(B)を20~45重量%を含有し、油相と水相のいずれにも溶解しない粉末状の固形分をロールインマーガリン全体中5~50重量%含み、前記粉末状の固形分を含み、油脂が融解した状態にある油中水型乳化油脂組成物が、0~25℃まで冷却されて該温度で10~300秒間保持され晶析された後、混和により軟化させられながら10~35℃に昇温されて、粘度が10~250Pa・sに調整された流動状の前記油中水型乳化油脂組成物がピロー包装に充填され、該ピロー包装の口が閉じられてからシート状に圧延されて成型され、-30℃~30℃で24時間以上静置されたロールインマーガリンである。 Embodiments of the present invention will be described in more detail below. A preferred aspect of the roll-in margarine according to the present embodiment is that the oil phase content/aqueous phase content (weight ratio) in the whole roll-in margarine is 50/50 to 97/3, and the roll-in margarine contains A powdery solid content that contains 15 to 30% by weight of oil (A) and 20 to 45% by weight of oil (B) in the entire oil phase and does not dissolve in either the oil phase or the aqueous phase is rolled in. A water-in-oil emulsified fat composition that contains 5 to 50% by weight of the whole margarine, contains the powdered solid content, and has the fat and oil in a molten state is cooled to 0 to 25°C, and is heated to 10 to 300% by weight at that temperature. After being held for a second to crystallize, the water-in-oil emulsified fat composition in a fluid state is heated to 10 to 35°C while being softened by mixing, and the viscosity is adjusted to 10 to 250 Pa·s. This is a roll-in margarine that is filled into a package, the mouth of the pillow package is closed, and then rolled and molded into a sheet, and left at -30°C to 30°C for 24 hours or more.
本発明における油中水型乳化油脂組成物とは、水相が油相に分散するタイプの乳化物を指す。ロールインマーガリンにおける離水の低減、ロールインマーガリンを用いて層状食品を作製する際の作業性、作製された層状食品の浮きや風味といった観点から、油中水型乳化油脂組成物全体中の油相含有量/水相含有量(重量比)は50/50~97/3であることが好ましい。また、本発明のロールインマーガリンは、前記油中水型乳化油脂組成物を固体状に晶析せしめたものであり、前記油中水型乳化油脂組成物と同様、ロールインマーガリン中の油相含有量/水相含有量(重量比)は50/50~97/3であることが好ましい。油中水型乳化油脂組成物全体又はロールインマーガリン中の油相含有量/水相含有量(重量比)は、60/40~95/5であることがより好ましく、70/30~93/7であることがさらに好ましく、75/25~90/10であることが特に好ましい。よって、本発明でいうロールインマーガリンには、油分が80%を超えるマーガリンの他、油分が80%未満のファットスプレッドも包含される。 The water-in-oil emulsified fat composition in the present invention refers to a type of emulsion in which an aqueous phase is dispersed in an oil phase. From the viewpoints of reducing syneresis in roll-in margarine, workability when producing layered foods using roll-in margarine, and floatability and flavor of the produced layered foods, the oil phase in the entire water-in-oil emulsified oil and fat composition is important. The content/aqueous phase content (weight ratio) is preferably 50/50 to 97/3. Further, the roll-in margarine of the present invention is obtained by crystallizing the water-in-oil emulsified fat composition into a solid state, and like the water-in-oil emulsified fat composition, the oil phase in the roll-in margarine is The content/aqueous phase content (weight ratio) is preferably 50/50 to 97/3. The oil phase content/aqueous phase content (weight ratio) in the entire water-in-oil emulsified fat composition or roll-in margarine is more preferably 60/40 to 95/5, and 70/30 to 93/5. More preferably, the ratio is 7, and particularly preferably 75/25 to 90/10. Therefore, the roll-in margarine as used in the present invention includes not only margarine with an oil content of more than 80% but also fat spread with an oil content of less than 80%.
前記油中水型乳化油脂組成物及びロールインマーガリンに含まれる油脂は、少なくとも油脂(A)及び油脂(B)を含む。 The fats and oils contained in the water-in-oil emulsified fat composition and roll-in margarine include at least fats and oils (A) and fats and oils (B).
油脂(A)は、構成脂肪酸全体中、炭素数12以下の飽和脂肪酸含有量が15重量%以上、炭素数18以上の飽和脂肪酸含有量が15重量%以上、飽和脂肪酸含有量が70重量%以上であり、三飽和トリグリセライド含有量が油脂(A)全体中15重量%以上である、エステル交換または極度硬化された油脂である。ここで、三飽和トリグリセライドとは、トリグリセライドに結合している3個の脂肪酸がいずれも飽和脂肪酸であるトリグリセライドを指す。なお、油脂中の各トリグリセライド含有量は、HPLCを用いて、AOCS Official Method Ce5c-93に準拠して測定し、各ピークのリテンションタイムおよびエリア比から算出した。以下に、分析の条件を記す。
溶離液 :アセトニトリル:アセトン(70:30、体積比)
流速 :0.9ml/分
カラム :ODS
カラム温度:36℃
検出器 :示差屈折計
The fat (A) has a saturated fatty acid content of 15% by weight or more, a saturated fatty acid content of 18 or more carbon atoms, and a saturated fatty acid content of 70% by weight or more, out of all the constituent fatty acids. It is a transesterified or extremely hardened fat or oil having a trisaturated triglyceride content of 15% by weight or more based on the entire fat or oil (A). Here, trisaturated triglyceride refers to triglyceride in which all three fatty acids bonded to triglyceride are saturated fatty acids. The content of each triglyceride in fats and oils was measured using HPLC in accordance with AOCS Official Method Ce5c-93, and calculated from the retention time and area ratio of each peak. The conditions for analysis are described below.
Eluent: Acetonitrile:acetone (70:30, volume ratio)
Flow rate: 0.9ml/min Column: ODS
Column temperature: 36℃
Detector: Differential refractometer
油脂(A)としては、上記要件を満足する油脂である限り特に限定されないが、例えば、パーム核分別高融点部極度硬化油、パーム核分別低融点部極度硬化油、ハイエルシンナタネ極度硬化油とヤシ油のエステル交換油、パーム核極度硬化油、ナタネ極度硬化油とヤシ油のエステル交換油、パーム核油とラードとナタネ極度硬化油のエステル交換油、ナタネ極度硬化油とMCTのエステル交換油等が挙げられる。油脂(A)としては1種のみを用いてもよいし、2種以上を併用してもよい。中でも、ハイエルシンナタネ極度硬化油とヤシ油のエステル交換油が好ましい。 The oil (A) is not particularly limited as long as it satisfies the above requirements, but examples include palm kernel fractionated high melting point extremely hardened oil, palm kernel fractionated low melting point extremely hardened oil, and Hieru Shin rapeseed extremely hardened oil. Transesterified coconut oil, extremely hardened palm kernel oil, extremely hydrogenated rapeseed oil and coconut oil, transesterified palm kernel oil, lard, and extremely hardened rapeseed oil, extremely hydrogenated rapeseed oil and MCT transesterified oil etc. Only one type of oil or fat (A) may be used, or two or more types may be used in combination. Among these, transesterified oil of highly hydrogenated rapeseed oil and coconut oil is preferred.
油脂(A)の含有量は、油中水型乳化油脂組成物及びロールインマーガリンに含まれる油脂全体中、15~30重量%であることが好ましく、20~25重量%であることがより好ましい。油脂(A)の含有量が15重量%より少ないと、ロールインマーガリンを用いて作製された層状食品の浮きが悪くなる場合がある。また、油脂(A)の含有量が30重量%を超えると、層状食品の風味が悪くなる場合がある。 The content of fat (A) is preferably 15 to 30% by weight, more preferably 20 to 25% by weight, based on the total fat and oil contained in the water-in-oil emulsified fat composition and roll-in margarine. . If the content of fats and oils (A) is less than 15% by weight, the floating of the layered food produced using roll-in margarine may become poor. Moreover, when the content of fats and oils (A) exceeds 30% by weight, the flavor of the layered food may deteriorate.
油脂(B)は、飽和脂肪酸含有量が構成脂肪酸全体中20重量%以下であり、三不飽和トリグリセライド含有量が油脂(B)全体中50重量%以上の油脂である。飽和脂肪酸含有量が10重量%以下であり、三不飽和トリグリセライド含有量が油脂(B)全体中70重量%以上の油脂であることが好ましい。ここで、三不飽和トリグリセライドとは、トリグリセライドに結合している3個の脂肪酸がいずれも不飽和脂肪酸であるトリグリセライドを指す。 The fat (B) has a saturated fatty acid content of 20% by weight or less based on the total constituent fatty acids, and a triunsaturated triglyceride content of 50% by weight or more based on the whole fat/fat (B). It is preferable that the fat or oil has a saturated fatty acid content of 10% by weight or less and a triunsaturated triglyceride content of 70% or more by weight based on the total fat or oil (B). Here, the term "triunsaturated triglyceride" refers to a triglyceride in which all three fatty acids bonded to the triglyceride are unsaturated fatty acids.
油脂(B)としては上記要件を満足する油脂である限り特に限定されないが、常温で液状の油脂が挙げられ、具体的には、菜種油、大豆油、コーン油等の植物油が挙げられる。エステル交換や分別処理を行っていない植物油が好ましい。油脂(B)としては1種のみを用いてもよいし、2種以上を併用してもよい。中でも、菜種油が好ましい。 The fat (B) is not particularly limited as long as it satisfies the above requirements, but includes fats and oils that are liquid at room temperature, and specifically include vegetable oils such as rapeseed oil, soybean oil, and corn oil. Preferred are vegetable oils that have not been subjected to transesterification or fractionation. Only one type of oil or fat (B) may be used, or two or more types may be used in combination. Among them, rapeseed oil is preferred.
油脂(B)の含有量は、油中水型乳化油脂組成物及びロールインマーガリンに含まれる油脂全体中、20~45重量%であることが好ましく、25~40重量%であることがより好ましい。油脂(B)の含有量が20重量%より少ないと、層状食品作製時にロールインマーガリンが均一に伸展せず作業性が悪い場合がある。また、油脂(B)の含有量が45重量%を超えると、層状食品作製時の作業性が悪く、また、層状食品の浮きが悪くなる場合がある。 The content of fat (B) is preferably 20 to 45% by weight, more preferably 25 to 40% by weight, based on the total fat and oil contained in the water-in-oil emulsified fat composition and roll-in margarine. . If the content of fats and oils (B) is less than 20% by weight, the roll-in margarine may not spread uniformly during the production of layered foods, resulting in poor workability. Moreover, when the content of fats and oils (B) exceeds 45% by weight, workability during the production of layered foods may be poor, and the layered foods may not float easily.
前記油中水型乳化油脂組成物及びロールインマーガリンに含まれる油脂は、前述した油脂(A)及び油脂(B)の他に、油脂(A)及び油脂(B)のいずれにも該当しない他の油脂(C)を含有する。そのような油脂(C)としては、例えば、パームランダムエステル交換油、パーム極度硬化油、カカオバター、ラード、パームステアリンとパーム核のエステル交換油、ハイエルシン菜種極度硬化油と菜種油のエステル交換油等が挙げられる。当該他の油脂(C)の含有量は、油中水型乳化油脂組成物及びロールインマーガリンに含まれる油脂全体中、25~65重量%であることが好ましく、30~55重量%であることがより好ましく、35~50重量%であることがさらに好ましい。 In addition to the aforementioned oils and fats (A) and oils and fats (B), the oils and fats contained in the water-in-oil emulsified oil and fat composition and roll-in margarine include oils and fats that do not fall under either oils or fats (A) or oils or fats (B). Contains fats and oils (C). Such oils and fats (C) include, for example, palm random transesterified oil, extremely hardened palm oil, cocoa butter, lard, transesterified oil of palm stearin and palm kernel, transesterified oil of highly hydrogenated rapeseed oil and rapeseed oil, etc. can be mentioned. The content of the other fats and oils (C) is preferably 25 to 65% by weight, and preferably 30 to 55% by weight of the total fats and oils contained in the water-in-oil emulsified fat composition and roll-in margarine. is more preferable, and even more preferably 35 to 50% by weight.
前記油中水型乳化油脂組成物及びロールインマーガリンは、そこに含まれる油脂全体においてSSU含有量/SUS含有量(重量比)が1.5~2.5を満足することが好ましく、1.8~2.2がより好ましい。ここで、Sは、炭素数16以上の飽和脂肪酸であり、Uは、炭素数16以上の不飽和脂肪酸であり、SSUは、1,2位又は2,3位にS、1位又3位にUが結合しているトリグリセリドであり、SUSは、1,3位にS、2位にUが結合しているトリグリセリドである。 The water-in-oil emulsified fat composition and roll-in margarine preferably have an SSU content/SUS content (weight ratio) of 1.5 to 2.5 in the entire fat and oil contained therein. 8 to 2.2 is more preferable. Here, S is a saturated fatty acid having 16 or more carbon atoms, U is an unsaturated fatty acid having 16 or more carbon atoms, and SSU is S at the 1st, 2nd or 2nd, 3rd position, and SUS is a triglyceride in which U is bound to the 1st and 3rd positions, and U is bound to the 2nd position.
前記SSU含有量/SUS含有量が1.5未満であると、SSUに対するSUSの相対量が多く油脂全体の結晶化速度が遅いため、ロールインマーガリンで離水が生じやすく、また、保管中に硬く脆い物性に変化し易くなる。前記SSU含量/SUS含量(重量比)が2.5を超えると、SUSに対するSSUの相対量が多くなり、作製された層状食品の食感が硬く口溶けが悪くなりやすい。 When the SSU content/SUS content is less than 1.5, the relative amount of SUS to SSU is large and the crystallization rate of the entire oil and fat is slow, so syneresis is likely to occur in roll-in margarine, and it becomes hard during storage. The physical properties tend to change to brittle. When the SSU content/SUS content (weight ratio) exceeds 2.5, the relative amount of SSU to SUS increases, and the texture of the produced layered food tends to be hard and difficult to melt in the mouth.
前記SSU含有量/SUS含有量は、HPLCを用いて硝酸銀カラムにより分析することができる。分析条件は「Journal of the American Oil Chemists Society,68,289-293,1991」記載の方法に準拠することができる。 The SSU content/SUS content can be analyzed using a silver nitrate column using HPLC. The analysis conditions can be based on the method described in "Journal of the American Oil Chemists Society, 68, 289-293, 1991".
前記油中水型乳化油脂組成物及びロールインマーガリンは、油相と水相のいずれにも溶解しない粉末状の固形分を含有する。このような粉末状の固形分としては、層状食品に風味を付与することができる呈味剤が好ましく、特に限定されないが、例えば、全粉乳、脱脂粉乳、ココアパウダー、きな粉、抹茶粉末、コーヒー豆粉末、小豆粉末、粉チーズ、野菜粉末、果物粉末等が挙げられる。 The water-in-oil emulsified oil and fat composition and roll-in margarine contain powdery solids that are not dissolved in either the oil phase or the aqueous phase. As such powdery solids, flavoring agents capable of imparting flavor to the layered food are preferred, and examples include, but are not limited to, whole milk powder, skim milk powder, cocoa powder, soybean powder, matcha powder, and coffee beans. Examples include powder, red bean powder, powdered cheese, vegetable powder, and fruit powder.
粉末状の固形分の粒径は特に限定されないが、粒径が大きくなりすぎると、ロールインマーガリンを用いて作製された層状食品の浮きが悪くなる場合があるので、粉末状の固形分の最大粒径は300μm以下であることが好ましく、200μm以下であることがより好ましい。 The particle size of the powdered solid content is not particularly limited, but if the particle size becomes too large, layered foods prepared using roll-in margarine may not float properly, so the maximum solid content of the powdered solid content is The particle size is preferably 300 μm or less, more preferably 200 μm or less.
前記粉末状の固形分の含有量は、前記油中水型乳化油脂組成物及びロールインマーガリン全体中5~50重量%であることが好ましく、7~40重量%であることがより好ましく、10~30重量%であることがさらに好ましく、10~25重量%であることが特に好ましい。粉末状の固形分の含有量が5重量%より少ないと、層状食品に十分な風味を付与することができない場合がある。また、粉末状の固形分の含有量が50重量%を超えると、ロールインマーガリンに離水が多くなり、層状食品作製時の作業性が悪く、また、層状食品の浮きも悪くなる場合がある。 The content of the powdery solids is preferably 5 to 50% by weight, more preferably 7 to 40% by weight, and more preferably 10 to 50% by weight, based on the entire water-in-oil emulsified oil and fat composition and roll-in margarine. It is more preferably from 10 to 25% by weight, and particularly preferably from 10 to 25% by weight. If the powdery solid content is less than 5% by weight, it may not be possible to impart sufficient flavor to the layered food. In addition, if the content of powdered solids exceeds 50% by weight, the roll-in margarine will have a lot of syneresis, which may result in poor workability during the production of layered foods and may also result in poor floating of the layered foods.
前記油中水型乳化油脂組成物及びロールインマーガリンは、前記油脂、水、前記粉末状の固形分として用いる材料以外に、通常ロールインマーガリンに配合できる成分を適宜含有することができる。そのような成分としては、例えば、乳化剤、香料、酸化防止剤、着色料、糖類、食塩、増粘安定剤、甘味料、酸味料、呈味素材等を挙げることができる。本発明では、乳化剤を使用すると、前記粉末状の固形分をより多く配合することが可能になる。しかし、乳化剤を使用しなくとも、良好な特性を有する本発明のロールインマーガリンを得ることができる。 The water-in-oil emulsified oil and fat composition and roll-in margarine may contain, as appropriate, components that can be normally blended into roll-in margarine, in addition to the oil, water, and the materials used as the powdered solids. Examples of such components include emulsifiers, fragrances, antioxidants, colorants, sugars, salt, thickening stabilizers, sweeteners, acidulants, flavoring materials, and the like. In the present invention, when an emulsifier is used, it becomes possible to incorporate a larger amount of the powdered solid content. However, the roll-in margarine of the present invention having good properties can be obtained without using an emulsifier.
前記乳化剤としては、大豆レシチン、卵黄レシチン、グリセリン脂肪酸エステル、ポリグリセリン脂肪酸エステル、ソルビタン脂肪酸エステル、ショ糖脂肪酸エステル等を挙げることができる。 Examples of the emulsifier include soybean lecithin, egg yolk lecithin, glycerin fatty acid ester, polyglycerin fatty acid ester, sorbitan fatty acid ester, sucrose fatty acid ester, and the like.
前記香料としては、バターフレーバー、ミルクフレーバー等を挙げることができる。 Examples of the flavor include butter flavor, milk flavor, and the like.
前記酸化防止剤としては、トコフェロール、β-カロテン、茶抽出物(カテキン等)等を挙げることができる。 Examples of the antioxidant include tocopherol, β-carotene, tea extract (catechin, etc.), and the like.
前記着色料としては、β-カロテン、カラメル、紅麹色素等を挙げることができる。 Examples of the coloring agent include β-carotene, caramel, and red yeast rice pigment.
前記糖類としては、砂糖、果糖、ブドウ糖、水飴、還元水飴、はちみつ、異性化糖、転化糖、オリゴ糖、トレハロース、糖アルコール等を挙げることができる。 Examples of the saccharides include sugar, fructose, glucose, starch syrup, reduced starch syrup, honey, isomerized sugar, invert sugar, oligosaccharide, trehalose, sugar alcohol, and the like.
前記増粘安定剤としては、グアーガム、ローカストビーンガム、カラギーナン、アラビアガム、アルギン酸類、ペクチン、キサンタンガム、寒天、グルコマンナン、ゼラチン、澱粉等を挙げることができる。 Examples of the thickening stabilizer include guar gum, locust bean gum, carrageenan, gum arabic, alginic acids, pectin, xanthan gum, agar, glucomannan, gelatin, and starch.
前記甘味料としては、アスパルテーム、アセスルファムカリウム、スクラロース、アリテーム、ネオテーム、カンゾウ抽出物(グリチルリチン)、サッカリン、サッカリンナトリウム、ステビア抽出物、ステビア粉末等を挙げることができる。 Examples of the sweetener include aspartame, acesulfame potassium, sucralose, alitame, neotame, licorice extract (glycyrrhizin), saccharin, sodium saccharin, stevia extract, stevia powder, and the like.
前記酸味料としては、酢酸、乳酸、グルコン酸等を挙げることができる。 Examples of the acidulant include acetic acid, lactic acid, gluconic acid, and the like.
前記呈味素材としては、前記糖類、前記甘味料、前記酸味料は除かれ、乳製品、風味エキス類、その他呈味を有する原料等を挙げることができる。前記乳製品としては、乳脂の加熱処理物や酵素処理物、牛乳、加糖練乳、発酵乳、生クリーム等を挙げることができる。前記風味エキス類としては、昆布エキス、発酵調味料等を挙げることができる。前記その他呈味を有する原料としては、卵黄、全卵、コーヒー抽出物、果汁等を挙げることができる。 Examples of the taste materials include dairy products, flavor extracts, and other taste materials, excluding the sugars, sweeteners, and acidulants. Examples of the dairy products include heat-treated and enzyme-treated milk fat, milk, sweetened condensed milk, fermented milk, and fresh cream. Examples of the flavor extracts include kelp extract, fermented seasonings, and the like. Examples of the other flavorful raw materials include egg yolk, whole egg, coffee extract, and fruit juice.
以下に、本実施形態に係るロールインマーガリンの製造方法を具体的に説明する。まず、油脂が融解した状態にある油中水型乳化油脂組成物を特定温度まで冷却する。ここで油脂が融解した状態にある油中水型乳化油脂組成物とは、油脂を加熱融解し、粉末状の固形分と、必要に応じて乳化剤などの油溶性成分を添加して油相を調製し、該油相に、水や、必要に応じて食塩、香料や呈味素材などの水溶性成分を加えて攪拌した水相を加え、油脂の融解状態を維持しつつ乳化させることで調製され、その油脂の融解状態が維持されている油中水型乳化油脂組成物のことをいう。 The method for manufacturing roll-in margarine according to this embodiment will be specifically described below. First, a water-in-oil emulsified fat composition in which the fat is melted is cooled to a specific temperature. A water-in-oil emulsified fat composition in which fats and oils are melted is a water-in-oil emulsified fat composition in which fats and oils are heated and melted, and powdered solids and, if necessary, oil-soluble components such as emulsifiers are added to form an oil phase. Prepared by adding water and, if necessary, water-soluble components such as salt, flavoring materials, and flavor materials to the oil phase and stirring the aqueous phase, and emulsifying the oil while maintaining the molten state. It refers to a water-in-oil emulsified oil composition in which the molten state of the oil and fat is maintained.
油相と水相を混合してから、乳化する前後何れかで殺菌処理を行なうことが望ましい。殺菌方法は、タンクでのバッチ式でも、プレート型熱交換機や掻き取り式熱交換機を用いた連続式でもよい。 After mixing the oil phase and the aqueous phase, it is desirable to perform sterilization treatment either before or after emulsification. The sterilization method may be a batch method in a tank or a continuous method using a plate heat exchanger or a scraped heat exchanger.
前記冷却に用いる装置としては、ボテーター、コンビネーター、パーフェクター等のマーガリン製造機である密閉型連続式チューブ冷却機、プレート型熱交換機、開放型のダイアクーラーとコンプレクターとの組合せ等の冷却機器または冷却捏和装置が挙げられる。 Devices used for the cooling include closed-type continuous tube coolers for margarine production machines such as votators, combinators, and perfectors, plate-type heat exchangers, and cooling equipment such as combinations of open-type dia coolers and complexors. Alternatively, a cooling kneading device may be used.
前記冷却時の油中水型乳化油脂組成物の最低温度は、0~25℃が好ましく、1~20℃がより好ましく、5~15℃が更に好ましい。0℃未満まで冷却すると、油中水型乳化油脂組成物中の水分が凍結して設備を傷める場合があり、冷却時の最低温度が25℃を超えると油脂が十分に結晶化せず、作製した層状食品において各層の間に十分な隙間が形成されず、浮きが悪い場合がある。冷却する際の冷却速度は特に限定されないが、-10~-100℃/分の冷却速度が好ましい。 The minimum temperature of the water-in-oil emulsified fat composition during cooling is preferably 0 to 25°C, more preferably 1 to 20°C, and even more preferably 5 to 15°C. If the water-in-oil emulsified oil composition is cooled to less than 0°C, the water in the water-in-oil emulsified oil composition may freeze and damage the equipment. If the minimum temperature during cooling exceeds 25°C, the oil will not crystallize sufficiently, making it difficult to prepare. In layered food products, sufficient gaps may not be formed between each layer, resulting in poor floating. The cooling rate during cooling is not particularly limited, but a cooling rate of -10 to -100°C/min is preferable.
以上のように冷却された油中水型乳化油脂組成物を、前記冷却に用いる装置内で所定の温度帯に保持して晶析させる。保持する温度帯は0~25℃が好ましく、1~20℃がより好ましく、5~15℃が更に好ましい。晶析のために前記温度帯で保持する時間(以下、冷却保持時間ともいう)は、前記冷却に用いる装置内で油中水型乳化油脂組成物の温度が25℃になった時点から、前記冷却に用いる装置から油中水型乳化油脂組成物を搬出する(後述する混和昇温装置に移送する)までの時間を意味し、10~300秒間が好ましく、20~200秒間がより好ましく、30~150秒間が更に好ましい。冷却保持時間が10秒間未満であると油脂が十分に結晶化せず、層状食品作製時にロールインマーガリンが均一に伸展せず作業性が悪く、また、作製した層状食品において各層の間に十分な隙間が形成されず、浮きが悪い場合があり、300秒間を超えると、前記冷却に用いる装置による油中水型乳化油脂組成物の練りが過剰になり、得られるロールインマーガリンの硬さやコシが劣る場合がある。 The water-in-oil emulsified fat composition cooled as described above is kept at a predetermined temperature range in the device used for cooling and crystallized. The temperature range to be maintained is preferably 0 to 25°C, more preferably 1 to 20°C, and even more preferably 5 to 15°C. The time for holding in the temperature range for crystallization (hereinafter also referred to as cooling holding time) is from the time when the temperature of the water-in-oil emulsified oil/fat composition reaches 25°C in the device used for cooling. It means the time until the water-in-oil type emulsified fat composition is carried out from the device used for cooling (transferred to the mixing temperature raising device described below), and is preferably 10 to 300 seconds, more preferably 20 to 200 seconds, and 30 to 300 seconds. More preferably, the time is between 150 seconds and 150 seconds. If the cooling holding time is less than 10 seconds, the fats and oils will not crystallize sufficiently, and the roll-in margarine will not spread uniformly during the production of layered foods, resulting in poor workability. Gaps may not be formed and floating may be poor. If the time exceeds 300 seconds, the water-in-oil emulsified oil composition will be kneaded excessively by the device used for cooling, and the hardness and elasticity of the resulting roll-in margarine will deteriorate. It may be inferior.
次いで、前記冷却によって晶析された油中水型乳化油脂組成物を、混和昇温装置を用いて混和により軟化させながら特定温度に昇温させる。前記混和昇温装置としては、オンレーターなどの掻き取り式熱交換機、多管円筒式熱交換機、スタティックミキサー内蔵式熱交換器、ピンマシン等が挙げられる。また、前記混和昇温装置を通した後に、密閉型連続式チューブ冷却機や、冷却機器または冷却捏和装置を用いて再度冷却を行なっても良いが、その場合も、後述する油中水型乳化油脂組成物の粘度を満足する範囲で該再冷却を行なう。 Next, the water-in-oil emulsified fat composition crystallized by the cooling is heated to a specific temperature while being softened by mixing using a mixing and heating device. Examples of the mixing/heating device include a scraping type heat exchanger such as an Onlator, a multi-tube cylindrical heat exchanger, a heat exchanger with a built-in static mixer, a pin machine, and the like. In addition, after passing through the mixing temperature raising device, cooling may be performed again using a closed type continuous tube cooler, a cooling device, or a cooling kneading device, but in that case, water-in-oil type described below may be used. The recooling is performed within a range that satisfies the viscosity of the emulsified oil and fat composition.
混和昇温装置による昇温後の油中水型乳化油脂組成物の温度は、10~35℃が好ましく、15~30℃がより好ましく、20~25℃が更に好ましい。また、前記混和昇温装置を通した後に、密閉型連続式チューブ冷却機や、冷却機器または冷却捏和装置を用いて再度冷却を行なう場合も、冷却後の油中水型乳化油脂組成物の温度は、10~35℃が好ましく、15~30℃がより好ましく、20~25℃が更に好ましい。昇温後または再冷却後の油中水型乳化油脂組成物の温度が10℃未満であると、充填時の粘度が高すぎたり充填中に硬化して粘度が上がることで、充填後にシート状に成形加工する際に割れたり空気穴が空いたりする場合がある。一方、35℃を超えると、大部分の結晶が溶けて充填後に水相部が分離したり、ロールインマーガリンに不適な物性となる場合がある。 The temperature of the water-in-oil emulsified fat composition after being heated by the mixing temperature raising device is preferably 10 to 35°C, more preferably 15 to 30°C, and even more preferably 20 to 25°C. In addition, even if the water-in-oil emulsified oil/fat composition is cooled again using a closed continuous tube cooler, cooling device, or cooling kneading device after passing through the mixing temperature raising device, the water-in-oil emulsified fat composition after cooling may be The temperature is preferably 10 to 35°C, more preferably 15 to 30°C, even more preferably 20 to 25°C. If the temperature of the water-in-oil emulsified fat composition after heating or recooling is below 10°C, the viscosity at the time of filling may be too high, or the viscosity may increase due to hardening during filling, resulting in a sheet-like form after filling. Cracks or air holes may occur during molding. On the other hand, if the temperature exceeds 35°C, most of the crystals may melt and the aqueous phase may separate after filling, resulting in physical properties unsuitable for roll-in margarine.
混和昇温装置による昇温後の油中水型乳化油脂組成物の粘度は、10~250Pa・sが好ましく、20~200Pa・sがより好ましく、50~150Pa・sが更に好ましい。10Pa・s未満であると、作製した層状食品において各層の間に十分な隙間が形成されず、浮きが悪い場合があり、250Pa・sを超えると、圧延時に油中水型乳化油脂組成物が均一に広がりにくく、作製されたロールインマーガリンを生地に折り込む際にひび割れが入る場合がある。前記粘度は、混和昇温装置による剪断を変更することでコントロールすることができる。なお、粘度は、振動式粘度計、回転式粘度計、落球式粘度計、細管式粘度計等を用いて定法に従い測定することができる。 The viscosity of the water-in-oil emulsified fat composition after being heated by the mixing temperature rising device is preferably 10 to 250 Pa·s, more preferably 20 to 200 Pa·s, and even more preferably 50 to 150 Pa·s. If it is less than 10 Pa.s, sufficient gaps may not be formed between each layer in the produced layered food, which may result in poor floating, and if it exceeds 250 Pa.s, the water-in-oil emulsified fat composition may be It is difficult to spread evenly, and cracks may appear when the rolled-in margarine is folded into dough. The viscosity can be controlled by changing the shear applied by the mixing and heating device. Note that the viscosity can be measured according to a conventional method using a vibration viscometer, a rotational viscometer, a falling ball viscometer, a capillary viscometer, or the like.
また、混和昇温装置による昇温後の油中水型乳化油脂組成物の粘度が上記範囲内にあれば、後述するピロー包装への充填時の油中水型乳化油脂組成物のペネ値が140~460になることから、相関的に、折り込み時のロールインマーガリンのペネ値を50~130にコントロールしやすく好ましい。 In addition, if the viscosity of the water-in-oil emulsified oil-fat composition after heating by the mixing temperature raising device is within the above range, the penetration value of the water-in-oil emulsified oil-fat composition at the time of filling into the pillow packaging described below will be Since the penetration value is 140 to 460, it is preferable that the penetration value of the roll-in margarine at the time of folding can be easily controlled within the range of 50 to 130.
次に、粘度が上記範囲内にある流動状の油中水型乳化油脂組成物をピロー包装に充填する。ここで、ピロー包装とは、包装フィルムを、開口部を有する袋状に加工した後、内容物を充填し、前記開口部を閉じて該内容物を包装するものをいう。前記ピロー包装は、密封性と開封作業性を両立するため、イージーピール性を有する方が好ましい。 Next, a pillow package is filled with a fluid water-in-oil emulsified fat composition having a viscosity within the above range. Here, pillow packaging refers to packaging film in which a packaging film is processed into a bag having an opening, the bag is filled with contents, and the opening is closed to package the contents. The pillow packaging preferably has easy peelability in order to achieve both sealing performance and ease of opening.
流動状の油中水型乳化油脂組成物をピロー包装の開口部から投入してピロー包装に充填した直後に、ピロー包装の開口部を閉じることが衛生面から好ましい。ピロー包装の開口部を閉じる方法としては、ヒートシール、チャック、クリップで挟む等の方法が挙げられるが、密封する方法が好ましい。 Immediately after the fluid water-in-oil emulsified oil/fat composition is poured into the pillow package through the opening thereof and the pillow package is filled, it is preferable from a sanitary standpoint to close the opening of the pillow package. Methods for closing the opening of the pillow packaging include methods such as heat sealing, zippering, and clipping, but sealing is preferred.
本発明では、生産プロセスでの異物混入など衛生上の問題を考慮して、油脂が融解した状態にある油中水型乳化油脂組成物を冷却して晶析せしめた後、混和により軟化させながら昇温するまでの一連の工程を閉鎖系のラインで行なうことが好ましい。さらに、流動状の前記油中水型乳化油脂組成物をピロー包装に充填し、該ピロー包装の開口部を閉じる工程を、前記ラインから流動状の前記組成物が出た直後に実施することが好ましく、具体的には、前記ラインを出てからピロー包装が密封されるまでの時間を60秒以下に設定することが好ましく、30秒以下がより好ましく、10秒以下がさらに好ましい。 In the present invention, in consideration of hygiene problems such as foreign matter contamination during the production process, a water-in-oil type emulsified fat composition in which the fat is melted is cooled and crystallized, and then softened by mixing. It is preferable that the series of steps up to temperature elevation be carried out in a closed line. Furthermore, the step of filling a pillow package with the fluid water-in-oil emulsified fat composition and closing the opening of the pillow package may be carried out immediately after the fluid composition comes out of the line. Preferably, specifically, the time from when the pillow package leaves the line to when the pillow package is sealed is preferably set to 60 seconds or less, more preferably 30 seconds or less, and even more preferably 10 seconds or less.
ピロー包装の開口部を閉じた後、流動状の油中水型乳化油脂組成物を、ピロー包装と共に、シート状に圧延成形する。当該圧延成形方法によると、流動状の油中水型乳化油脂組成物をピロー包装に充填してから、ピロー包装ごと圧延するので、作製されるロールインマーガリンでは、ピロー包装を構成する包装フィルムの内面と、ピロー包装内のロールインマーガリンの表面が密接することになる。 After closing the opening of the pillow package, the fluid water-in-oil emulsified fat composition is rolled and formed into a sheet together with the pillow package. According to the roll-forming method, a fluid water-in-oil emulsified fat composition is filled into a pillow package and then rolled together with the pillow package. The inner surface and the surface of the roll-in margarine inside the pillow package will come into close contact.
ピロー包装に充填された流動状の油中水型乳化油脂組成物をシート状に圧延成形するには、当該乳化油脂組成物を、(1)適切なクリアランスを保持した2枚の平板で挟む、(2)適切なクリアランスを保持した2つのローラー間に通す、(3)袋容量に対する内容量を調整した上で、振動させ自然に厚みを揃える、などの方法が挙げられる。 In order to roll-form the fluid water-in-oil emulsified fat composition filled in a pillow package into a sheet, the emulsified fat composition is (1) sandwiched between two flat plates with an appropriate clearance. Methods include (2) passing the bag between two rollers that maintain an appropriate clearance, and (3) adjusting the content to the bag capacity and then vibrating it to naturally equalize the thickness.
次いで、ピロー包装されたシート状の油中水型乳化油脂組成物を、特定温度で特定時間以上静置することで、本発明のピロー包装されたロールインマーガリンが製造される。このように特定条件で静置することで、油中水型乳化油脂組成物中の油脂の結晶化を進行させ、結晶を安定化させて、ロールインマーガリンの製造を実現できる。 Next, the pillow-wrapped sheet-like water-in-oil emulsified fat composition is allowed to stand at a specific temperature for a specific period of time or more, thereby producing the pillow-wrapped roll-in margarine of the present invention. By standing still under such specific conditions, the crystallization of the oil and fat in the water-in-oil emulsified oil and fat composition progresses, the crystals are stabilized, and roll-in margarine can be produced.
静置する際の温度は、-30~30℃が好ましく、-20~25℃がより好ましく、0~10℃が更に好ましい。-30℃より低いと保管コストの点で不利であり、30℃を超えると、層状食品作製時にロールインマーガリンが伸展しにくく、作業性が悪かったり、作製した層状食品において各層の間に十分な隙間が形成されず、浮きが悪い場合があり、また、ロールインマーガリンに油浸や変形が発生する場合がある。 The temperature during standing is preferably -30 to 30°C, more preferably -20 to 25°C, and even more preferably 0 to 10°C. If it is lower than -30℃, it is disadvantageous in terms of storage cost, and if it exceeds 30℃, roll-in margarine will be difficult to spread during the production of layered foods, resulting in poor workability or insufficient space between each layer in the layered food produced. Gaps may not be formed and floating may be poor, and roll-in margarine may be soaked in oil or deformed.
静置する時間は、24時間以上であることが好ましい。24時間未満であると、油脂の結晶が十分に析出せず、または安定しておらず、製造されたロールインマーガリンの物性が不十分となり、作製した層状食品において各層の間に十分な隙間が形成されず、浮きが悪い場合がある。静置時間の上限としては、保管コストの観点から2年が好ましいが、特にこれに限定されない。 The time for leaving to stand is preferably 24 hours or more. If it is less than 24 hours, the oil and fat crystals will not be sufficiently precipitated or will not be stable, the physical properties of the manufactured roll-in margarine will be insufficient, and there will be insufficient gaps between each layer in the manufactured layered food. It may not form and may not float properly. The upper limit of the standing time is preferably two years from the viewpoint of storage costs, but is not particularly limited to this.
本発明の好適な実施態様では、上記のように流動状の油中水型乳化油脂組成物をピロー包装に充填し、シート状に圧延して成型した後、特定温度で特定時間テンパリング処理してから、テンパリング処理温度より低い特定温度で特定時間以上静置する。 In a preferred embodiment of the present invention, the fluid water-in-oil emulsified fat composition is filled into a pillow package as described above, rolled and molded into a sheet, and then tempered at a specific temperature for a specific time. Then, the material is left to stand for a specific period of time at a specific temperature lower than the tempering temperature.
前記好適な実施態様では、前記冷却時の最低温度は、0~25℃の範囲内であって、かつ油相部の融点から20~40℃低い温度が好ましく、油相部の融点から25~40℃低い温度がより好ましく、油相部の融点から25~35℃低い温度が更に好ましい。0℃未満まで冷却すると、油中水型乳化油脂組成物中の水分が凍結して設備を傷める場合がある。また、油相部の融点から20℃低い温度より高い温度までしか冷却しないと、油脂が十分に結晶化しない場合があり、該油脂の融点から40℃を超える温度まで冷却すると、冷却のためのコストがかかりすぎる場合がある。また冷却の際の冷却速度は、-20~-110℃/分が好ましい。 In the preferred embodiment, the lowest temperature during the cooling is within the range of 0 to 25°C, and is preferably 20 to 40°C lower than the melting point of the oil phase, and is preferably 25 to 40°C lower than the melting point of the oil phase. A temperature 40°C lower is more preferred, and a temperature 25 to 35°C lower than the melting point of the oil phase is even more preferred. If it is cooled to less than 0° C., the water in the water-in-oil emulsified fat composition may freeze and damage equipment. Additionally, if the oil is cooled to a temperature higher than 20°C below the melting point of the oil phase, the fat may not crystallize sufficiently, and if it is cooled to a temperature higher than 40°C below the melting point of the oil, the cooling It may be too costly. Further, the cooling rate during cooling is preferably -20 to -110°C/min.
前記テンパリング処理は、15~30℃で10~100時間行うことが好ましい。テンパリング処理温度は18~27℃がより好ましく、更に好ましくは20~25℃である。テンパリング時の温度が15℃未満であるとテンパリング効果が十分に得られないため、テンパリング処理によるロールインマーガリンの物性改善が不十分となる場合があり、30℃を超えると、ロールインマーガリンが必要以上に軟化したり、油浸を起こすため、ロールインマーガリンの品質が悪くなる場合がある。テンパリング処理時間は18~72時間がより好ましく、24~48時間が更に好ましい。10時間未満であるとテンパリング効果が十分に得られない場合があり、一方、100時間を超えてテンパリングしても効果が頭打ちとなり、生産性が落ちる場合がある。 The tempering treatment is preferably performed at 15 to 30°C for 10 to 100 hours. The tempering temperature is more preferably 18 to 27°C, and even more preferably 20 to 25°C. If the temperature during tempering is less than 15°C, the tempering effect will not be sufficiently obtained, so the physical properties of roll-in margarine may not be improved sufficiently by tempering, and if it exceeds 30°C, roll-in margarine is required. The quality of roll-in margarine may deteriorate due to excessive softening or oil immersion. The tempering treatment time is more preferably 18 to 72 hours, and even more preferably 24 to 48 hours. If the tempering time is less than 10 hours, a sufficient tempering effect may not be obtained. On the other hand, even if tempering is performed for more than 100 hours, the effect may reach a plateau and productivity may drop.
前記テンパリング処理後には、テンパリング処理温度より低い特定温度で特定時間以上静置する。具体的には、静置時の温度は-30~25℃が好ましく、-20~25℃がより好ましく、0~10℃が更に好ましい。-30℃より低いと保管コストの点で不利であり、25℃を超えると、層状食品作製時にロールインマーガリンが伸展しにくく、作業性が悪かったり、作製した層状食品において各層の間に十分な隙間が形成されず、浮きが悪い場合がある。静置する時間は24時間以上であることが好ましい。24時間未満であると、油脂の結晶が十分に析出せず、または安定しておらず、製造されたロールインマーガリンの物性が不十分となり、作製した層状食品において各層の間に十分な隙間が形成されず、浮きが悪い場合がある。静置時間の上限としては、保管コストの観点から2年が好ましいが、特にこれに限定されない。 After the tempering treatment, the material is allowed to stand at a specific temperature lower than the tempering temperature for a specific period of time or longer. Specifically, the temperature during standing is preferably -30 to 25°C, more preferably -20 to 25°C, and even more preferably 0 to 10°C. If it is lower than -30℃, it is disadvantageous in terms of storage cost, and if it exceeds 25℃, roll-in margarine will be difficult to spread during the production of layered foods, resulting in poor workability or insufficient space between each layer in the layered food produced. Gaps may not be formed and floating may be poor. The time for leaving to stand is preferably 24 hours or more. If it is less than 24 hours, the oil and fat crystals will not be sufficiently precipitated or will not be stable, the physical properties of the manufactured roll-in margarine will be insufficient, and there will be insufficient gaps between each layer in the manufactured layered food. It may not form and may not float properly. The upper limit of the standing time is preferably two years from the viewpoint of storage costs, but is not particularly limited to this.
本発明により製造されたロールインマーガリンは、従来の製造方法で製造したロールインマーガリンと同様に、生地に包み込んで伸展し、その後、焼成することにより、層状食品の作製に用いることができる。 Roll-in margarine produced according to the present invention can be used to produce layered foods by wrapping it in dough and stretching it, followed by baking, in the same way as roll-in margarine produced by conventional production methods.
該層状食品としては、例えばデニッシュ、クロワッサン、パイ等が挙げられるが、特に限定されない。 Examples of the layered food include Danish pastries, croissants, pies, etc., but are not particularly limited.
また、該層状食品におけるロールインマーガリンの配合量は、製造する層状食品の種類によって異なり、本発明の効果を奏する限り、特に限定されないが、層状食品全体中15~40重量%が好ましい。 Further, the amount of roll-in margarine in the layered food varies depending on the type of layered food to be produced, and is not particularly limited as long as the effects of the present invention are achieved, but it is preferably 15 to 40% by weight based on the entire layered food.
層状食品の製造方法は、特に限定されず、本発明により製造されたロールインマーガリンを用いること以外は、公知の原料を使用し、公知の配合および公知の方法を採用することができる。 The method for producing the layered food is not particularly limited, and other than using the roll-in margarine produced according to the present invention, known raw materials, known formulations, and known methods can be employed.
以下に実施例を示し、本発明をより具体的に説明するが、本発明はこれらの実施例に何ら限定されるものではない。なお、実施例において「部」や「%」は重量基準である。 EXAMPLES The present invention will be described in more detail with reference to Examples below, but the present invention is not limited to these Examples in any way. In the examples, "parts" and "%" are based on weight.
実施例及び比較例で使用した原料は以下のとおりである。
1)ハイエルシン菜種極度硬化油とヤシ油のランダムエステル交換油脂(製造例1)(炭素数12以下の飽和脂肪酸含有量:23.9重量%、炭素数18以上の飽和脂肪酸含有量:46.2重量%、飽和脂肪酸量:93.6重量%、三飽和トリグリセライド含有量:72.6重量%)
2)(株)カネカ製「パーム核極度硬化油(炭素数12以下の飽和脂肪酸含有量:53.1重量%、炭素数18以上の飽和脂肪酸含有量:20.9重量%、飽和脂肪酸量:99.1重量%、三飽和トリグリセライド含有量:95.6重量%)」
3)(株)カネカ製「菜種油(飽和脂肪酸含有量:6.8重量%、三不飽和トリグリセライド含有量:78.3重量%)」
4)パームランダムエステル交換油(製造例2)(炭素数12以下の飽和脂肪酸含有量:1.0重量%、炭素数18以上の飽和脂肪酸含有量:4.8重量%、飽和脂肪酸量:50.3重量%、三飽和トリグリセライド含有量:13.7重量%、三不飽和トリグリセライド含有量:11.4重量%)
5)(株)カネカ製「パーム極度硬化油(炭素数12以下の飽和脂肪酸含有量:0.2重量%、炭素数18以上の飽和脂肪酸含有量:55.6重量%、飽和脂肪酸量:90.8重量%、三飽和トリグリセライド含有量:93.9重量%、三不飽和トリグリセライド含有量:0.0重量%)」
6)(株)カネカ製「カカオバター(炭素数12以下の飽和脂肪酸含有量:0.1重量%、炭素数18以上の飽和脂肪酸含有量:33.7重量%、飽和脂肪酸量:63.4重量%、三飽和トリグリセライド含有量:1.2重量%、三不飽和トリグリセライド含有量:0.0重量%)」
7)理研ビタミン(株)製「エマルジーMS」
8)J-オイルミルズ(株)製「大豆レシチン」
9)雪印メグミルク(株)製「脱脂粉乳」
10)辻利兵衛本店製「宇治抹茶」
11)ユニオン商事(株)製「アーモンド粉末」(60メッシュに通したものを使用)
12)日清製粉(株)製「ミリオン」
13)日清製粉(株)製「バイオレット」
14)(株)カネカ製「GK」
15)日新製糖(株)製「上白糖P」
16)財団法人塩事業センター製「精製塩」
17)(株)赤城鶏卵GPセンター製「卵」
18)(株)カネカ製「エバーライトG」
19)(株)カネカ製「ニューフードC」
The raw materials used in the examples and comparative examples are as follows.
1) Random transesterification of high-erucin rapeseed extremely hardened oil and coconut oil (Production Example 1) (Content of saturated fatty acids with 12 or less carbon atoms: 23.9% by weight, content of saturated fatty acids with 18 or more carbon atoms: 46.2 (wt%, saturated fatty acid content: 93.6 wt%, trisaturated triglyceride content: 72.6 wt%)
2) Kaneka Co., Ltd. "Palm kernel extremely hardened oil (content of saturated fatty acids with 12 or less carbon atoms: 53.1% by weight, content of saturated fatty acids with 18 or more carbon atoms: 20.9% by weight, amount of saturated fatty acids: 99.1% by weight, trisaturated triglyceride content: 95.6% by weight)
3) “Rapeseed oil (saturated fatty acid content: 6.8% by weight, triunsaturated triglyceride content: 78.3% by weight)” manufactured by Kaneka Corporation
4) Palm random transesterified oil (Production example 2) (Content of saturated fatty acids with 12 or less carbon atoms: 1.0% by weight, Content of saturated fatty acids with 18 or more carbon atoms: 4.8% by weight, Amount of saturated fatty acids: 50 .3% by weight, trisaturated triglyceride content: 13.7% by weight, triunsaturated triglyceride content: 11.4% by weight)
5) Kaneka Co., Ltd. "Palm extremely hardened oil (content of saturated fatty acids with 12 or less carbon atoms: 0.2% by weight, content of saturated fatty acids with 18 or more carbon atoms: 55.6% by weight, amount of saturated fatty acids: 90 .8% by weight, trisaturated triglyceride content: 93.9% by weight, triunsaturated triglyceride content: 0.0% by weight).
6) Cacao butter manufactured by Kaneka Co., Ltd. (Content of saturated fatty acids with 12 or less carbon atoms: 0.1% by weight, Content of saturated fatty acids with 18 or more carbon atoms: 33.7% by weight, Amount of saturated fatty acids: 63.4 (wt%, trisaturated triglyceride content: 1.2 wt%, triunsaturated triglyceride content: 0.0 wt%)
7) “Emulgy MS” manufactured by Riken Vitamin Co., Ltd.
8) “Soybean lecithin” manufactured by J-Oil Mills Co., Ltd.
9) “Skimmed milk powder” manufactured by Megmilk Snow Brand Co., Ltd.
10) “Uji Matcha” made by Tsuji Rihei Honten
11) "Almond powder" manufactured by Union Shoji Co., Ltd. (used through 60 mesh)
12) “Million” manufactured by Nisshin Seifun Co., Ltd.
13) “Violet” manufactured by Nisshin Seifun Co., Ltd.
14) “GK” manufactured by Kaneka Corporation
15) “Jinpakuto P” manufactured by Nissin Sugar Co., Ltd.
16) “Refined salt” manufactured by Salt Business Center Foundation
17) “Eggs” manufactured by Akagi Egg GP Center Co., Ltd.
18) “Everlight G” manufactured by Kaneka Corporation
19) “New Food C” manufactured by Kaneka Corporation
<生産性>
ロールインマーガリンの生産性は、油脂が融解した状態にある油中水型乳化油脂組成物200kgが密閉型連続式チューブ冷却機に投入されてから、その内の100kgが混和昇温装置または成型ノズルより外に排出されるまでの時間(以下、生産性に関する時間という)によって、以下の基準で評価した。
○:生産性に関する時間が90分未満である。
△:生産性に関する時間が90~120分である。
×:生産性に関する時間が120分を超える。
<Productivity>
The productivity of roll-in margarine is determined by the following: 200 kg of a water-in-oil emulsified fat composition in a molten state is put into a closed continuous tube cooling machine, and 100 kg of it is transferred to a mixing/heating device or a molding nozzle. The time taken for the product to be discharged outside (hereinafter referred to as productivity-related time) was evaluated using the following criteria.
○: Time related to productivity is less than 90 minutes.
Δ: Time related to productivity is 90 to 120 minutes.
×: Time related to productivity exceeds 120 minutes.
<離水量>
離水量は、ピロー包装から開封したロールインマーガリンの表面を、生産時、及び、生地への折り込み時に目視で観察し、以下の基準で評価した。
○:生産時にも折り込み時にも離水がない。
△:生産時に離水はないものの、折り込み時に僅かに離水が見られる。
×:生産時から離水が見られ、微生物の繁殖が懸念される。
<Amount of water separation>
The amount of syneresis was evaluated based on the following criteria by visually observing the surface of the roll-in margarine that was opened from the pillow package during production and when folded into dough.
○: There is no syneresis during production or folding.
Δ: There is no syneresis during production, but slight syneresis is observed during folding.
×: Syneresis was observed from the time of production, and there is concern about the proliferation of microorganisms.
<デニッシュ作製時の作業性>
デニッシュの作製において、15℃で3時間温調したロールインマーガリンを、それぞれ生地に折り込んだ際の作業性を以下の基準で総合的に評価した。
5点:生地の中でロールインマーガリンが均一に伸び、作業時間が非常に短い。
4点:ロールインマーガリンの伸び方に偏りは殆ど見られず、作業時間は短い。
3点:ロールインマーガリンの伸び方に少し偏りが見られるが、作業時間は短い。
2点:ロールインマーガリンが均一に伸びていない部分が多く、作業時間が長い。
1点:ロールインマーガリンが伸びず、生地にロールインマーガリンの塊が見られ、作業時間が非常に長い。
<Workability when making danishes>
In the production of Danish pastries, the workability of roll-in margarine that had been temperature-controlled at 15° C. for 3 hours and folded into the dough was comprehensively evaluated based on the following criteria.
5 points: The roll-in margarine spreads evenly in the dough, and the working time is very short.
4 points: There is almost no deviation in the way the roll-in margarine spreads, and the working time is short.
3 points: The roll-in margarine spreads slightly unevenly, but the working time is short.
2 points: There are many parts where the roll-in margarine is not spread evenly, and the work time is long.
1 point: Roll-in margarine does not stretch, lumps of roll-in margarine are seen in the dough, and the working time is very long.
<デニッシュの浮き>
作製したデニッシュを切断し、熟練した10名のパネラーがその断面を観察して、以下の基準で評価した。各人の評価値の平均値を示した。
5点:非常に浮きが良く、各層の間に十分な隙間がある。
4点:浮きが良く、ほとんどの層の間に十分な隙間がある。
3点:浮きが良く、各層の間に十分な隙間のない部分がある。
2点:浮きが悪く、各層の間に十分な隙間のない部分が多い。
1点:非常に浮きが悪く、ほとんどの生地と生地の間に十分な隙間がない。
<Danish float>
The produced Danish was cut, and 10 experienced panelists observed the cross section and evaluated it according to the following criteria. The average value of each person's evaluation value is shown.
5 points: Very good floating, with sufficient gaps between each layer.
4 points: Good floating and sufficient gaps between most layers.
3 points: Good floating, and there are parts with sufficient gaps between each layer.
2 points: Poor floating and many parts without sufficient gaps between each layer.
1 point: Very poor floating, and there is not enough space between most of the fabrics.
<デニッシュの風味>
作製したデニッシュを、熟練した10名のパネラーが食して、以下の基準で評価した。各人の評価値の平均値を示した。
5点:風味を非常に強く感じる。
4点:風味を強く感じる。
3点:風味を感じる。
2点:風味をあまり感じない。
1点:風味を感じない。
<Danish flavor>
Ten experienced panelists ate the prepared Danish and evaluated it based on the following criteria. The average value of each person's evaluation value is shown.
5 points: The flavor is felt very strongly.
4 points: The flavor is felt strongly.
3 points: I can feel the flavor.
2 points: I don't really feel the flavor.
1 point: No flavor felt.
<総合評価>
ロールインマーガリンの生産性、離水量、デニッシュ作製時の作業性、デニッシュの浮き、及びデニッシュの風味の各評価結果を基に、総合評価を行った。その際の評価基準は以下の通りである。
A:生産性及び離水量は〇で、デニッシュ作製時の作業性は4~5点、デニッシュの浮き及びデニッシュの風味はそれぞれ4.0~5.0点を満たすもの。
B:生産性及び離水量は〇又は△で、デニッシュ作製時の作業性は4~5点、デニッシュの浮き及びデニッシュの風味はそれぞれ3.5~5.0点であって、且つ3.5点以上4.0点未満が少なくとも一つあるもの。
C:生産性及び離水量は〇又は△で、デニッシュ作製時の作業性は3~5点、デニッシュの浮き及びデニッシュの風味はそれぞれ3.0~5.0点であって、且つ3点又は3.0点以上3.5点未満が少なくとも一つあるもの。
D:生産性及び離水量は〇又は△で、デニッシュ作製時の作業性は2~5点、デニッシュの浮き及びデニッシュの風味はそれぞれ2.0~5.0点であって、且つ2点又は2.0点以上3.0点未満が少なくとも一つあるもの。
E:生産性及び/又は離水量は×で、デニッシュ作製時の作業性、デニッシュの浮き及びデニッシュの風味において、1点又は2.0点未満が少なくとも一つある、又はデニッシュの評価ができなかったもの。
<Comprehensive evaluation>
A comprehensive evaluation was performed based on the evaluation results of the roll-in margarine's productivity, amount of syneresis, workability during Danish making, Danish floating, and Danish flavor. The evaluation criteria at that time are as follows.
A: Productivity and syneresis rate are 0, workability during Danish making is 4 to 5 points, Danish float and Danish flavor are 4.0 to 5.0 points each.
B: Productivity and syneresis rate are ○ or △, workability during Danish making is 4 to 5 points, Danish floating and Danish flavor are each 3.5 to 5.0 points, and 3.5 At least one score between 4.0 and 4.0.
C: Productivity and syneresis rate are ○ or △, workability during Danish making is 3 to 5 points, Danish floating and Danish flavor are each 3.0 to 5.0 points, and 3 points or At least one score of 3.0 or more and less than 3.5 points.
D: Productivity and syneresis rate are ○ or △, workability during Danish making is 2 to 5 points, Danish floating and Danish flavor are 2.0 to 5.0 points each, and 2 points or At least one score of 2.0 or more and less than 3.0 points.
E: Productivity and/or syneresis rate is ×, and there is at least one score of 1 or less than 2.0 in workability during Danish making, Danish floating, and Danish flavor, or the Danish cannot be evaluated. Something.
(製造例1)ハイエルシン菜種極度硬化油とヤシ油のランダムエステル交換油A1
ハイエルシン菜種極度硬化油:50重量部、ヤシ油:50重量部の混合油脂を500Paの減圧下90℃に加熱し、ナトリウムメチラート(日本曹達株式会社製):0. 2重量部を加えて30分攪拌してランダムエステル交換を行った。水洗した後、500Paの減圧下、90℃で白土(水澤化学工業株式会社製):2重量部を加えて脱色し、240℃、200Paの条件で1時間脱臭して、ハイエルシン菜種極度硬化油とヤシ油のランダムエステル交換油脂A1を得た。
(Production Example 1) Random transesterification oil A1 of high erucin rapeseed extremely hardened oil and coconut oil
A mixed fat and oil mixture of 50 parts by weight of highly hydrogenated rapeseed oil and 50 parts by weight of coconut oil was heated to 90°C under a reduced pressure of 500 Pa, and sodium methylate (manufactured by Nippon Soda Co., Ltd.): 0. 2 parts by weight were added and stirred for 30 minutes to perform random transesterification. After washing with water, add 2 parts by weight of white clay (manufactured by Mizusawa Chemical Industry Co., Ltd.) at 90°C under a reduced pressure of 500 Pa to decolorize it, deodorize it for 1 hour at 240°C and 200 Pa, and mix it with high-erucin rapeseed extremely hardened oil. A random transesterified coconut oil fat A1 was obtained.
(製造例2)パームランダムエステル交換油C1
パーム油(IV=53):100重量部を500Paの減圧下で90℃に加熱し、ナトリウムメチラート:0.2重量部を加えて30分攪拌してランダムエステル交換した。水洗した後、500Paの減圧下、90℃において白土(水澤化学工業株式会社製):2重量部を加えて脱色し、ろ過して白土を除き、得られた油脂を減圧下、250℃で1時間脱臭して、パームランダムエステル交換油脂C1を得た。
(Production Example 2) Palm random transesterified oil C1
Palm oil (IV=53): 100 parts by weight was heated to 90° C. under a reduced pressure of 500 Pa, 0.2 parts by weight of sodium methylate was added, and the mixture was stirred for 30 minutes to perform random transesterification. After washing with water, 2 parts by weight of white clay (manufactured by Mizusawa Chemical Industry Co., Ltd.) was added at 90°C under a reduced pressure of 500 Pa to decolorize it, and the white clay was removed by filtration. After time deodorization, palm random transesterified fat C1 was obtained.
(実施例1)
表1に示す配合に従って、ハイエルシン菜種極度硬化油とヤシ油のランダムエステル交換油(油脂A1)16.3重量部、菜種油(油脂B1)24.4重量部、パームランダムエステル交換油(油脂C1)31.1重量部、パーム極度硬化油(油脂C2)2.2重量部を混合した。このとき、油脂全体中に油脂(A)が22重量%、油脂(B)が30重量%、油脂(C)が48重量%であった。この油脂混合物75.0重量部にモノグリセライド0.5重量部、大豆レシチン0.5重量部を加え、70℃で融解後、脱脂粉乳15.0重量部を加えて分散させ、65~70℃に保持して油相とした。また、水10.0重量部を80~85℃で20分間殺菌後、65~70℃に保持して水相とした。水相を油相に加えて20分以上乳化させて乳化物を得た。
(Example 1)
According to the formulation shown in Table 1, 16.3 parts by weight of a random transesterified oil of high-erucin rapeseed extremely hardened oil and coconut oil (fat A1), 24.4 parts by weight of rapeseed oil (fat B1), and random transesterified palm oil (fat C1) 31.1 parts by weight and 2.2 parts by weight of extremely hardened palm oil (fat C2) were mixed. At this time, the total amount of fats and oils was 22% by weight of fats and oils, 22% by weight of fats and oils, 30% by weight of fats and oils (B), and 48% by weight of fats and oils (C). 0.5 parts by weight of monoglyceride and 0.5 parts by weight of soybean lecithin were added to 75.0 parts by weight of this fat/oil mixture, and after melting at 70°C, 15.0 parts by weight of skim milk powder was added and dispersed, and the mixture was heated to 65-70°C. This was retained to form an oil phase. Further, 10.0 parts by weight of water was sterilized at 80 to 85°C for 20 minutes and then maintained at 65 to 70°C to form an aqueous phase. The aqueous phase was added to the oil phase and emulsified for 20 minutes or more to obtain an emulsion.
得られた油脂が融解状態の乳化物を密閉型連続式チューブ冷却機(コンビネーター:1.3L容量)に投入し、-30~-50℃/分の冷却速度で捏和しながら最終到達温度10℃まで急冷した。この冷却過程で、ロールインマーガリンの製造装置のライン中における密閉型連続式チューブ冷却機内で25℃の品温に達してから、10℃に達温して混和昇温装置(ピンマシン:2.0L容量)に移送するまで94秒間、前記乳化物を該冷却機内に保持した後、混和昇温装置に移送し、該混和昇温装置で軟化させて23℃に昇温させ、その後ピロー包装に充填した。 The resulting emulsion containing molten fat and oil is put into a closed continuous tube cooler (combinator: 1.3L capacity) and kneaded at a cooling rate of -30 to -50°C/min until the final temperature is reached. It was rapidly cooled to 10°C. During this cooling process, the product temperature reaches 25°C in a closed continuous tube cooler in the roll-in margarine production line, and then reaches 10°C in a mixing temperature raising device (pin machine: 2.0L). The emulsion was held in the cooler for 94 seconds until it was transferred to a volume of 100 ml, then transferred to a mixing and heating device, where it was softened and heated to 23°C, and then packed into pillow packaging. did.
充填10秒後に乳化物の粘度を測定してから、厚さ10mmのシート状の容量となるようにピロー包装を速やかにヒートシーリングしてから2枚の平板で挟んで圧延し、厚さ10mmのブロックマーガリンを得た。このブロックマーガリンを20℃で24時間テンパリング処理した後、4℃で240時間静置して、シート厚10mmのロールインマーガリンを得た。なお、乳化物の粘度は充填10秒後に測定したが、当該粘度の値は、充填直前の乳化物が示す粘度の値と実質的に同じものである。表1に、充填10秒後に測定した粘度の値を記載した。また、ロールインマーガリンの生産性及び離水量について評価し、その結果を表1に示した。表2には、実施例1におけるロールインマーガリンの製造条件をまとめた。 After 10 seconds of filling, the viscosity of the emulsion was measured, and the pillow packaging was immediately heat-sealed to form a sheet with a thickness of 10 mm, then sandwiched between two flat plates and rolled. Got block margarine. This block margarine was tempered at 20° C. for 24 hours and then allowed to stand at 4° C. for 240 hours to obtain roll-in margarine with a sheet thickness of 10 mm. The viscosity of the emulsion was measured 10 seconds after filling, and the viscosity value was substantially the same as the viscosity value of the emulsion immediately before filling. Table 1 lists the viscosity values measured 10 seconds after filling. In addition, the productivity and amount of syneresis of the roll-in margarine were evaluated, and the results are shown in Table 1. Table 2 summarizes the manufacturing conditions for roll-in margarine in Example 1.
次に、得られたロールインマーガリンを用いてデニッシュを作製した。即ち、表3に示す配合に従って、ロールインマーガリンとショートニングを除いた原料をミキサーにて低速3分間、中高速3分間ミキシングした後、ショートニングを混合し、更に低速3分間、中高速3分間ミキシングし、捏ね上げ温度を25℃とした。室温で30分間生地を発酵させた後、生地を1℃で5時間冷却した。 Next, Danish was made using the obtained roll-in margarine. That is, according to the formulation shown in Table 3, the raw materials excluding roll-in margarine and shortening were mixed in a mixer at low speed for 3 minutes and medium-high speed for 3 minutes, then shortening was mixed, and further mixed for 3 minutes at low speed and 3 minutes at medium-high speed. The kneading temperature was 25°C. After fermenting the dough for 30 minutes at room temperature, the dough was cooled at 1° C. for 5 hours.
冷却後の生地191.6重量部を成形してから、15℃に温調したロールインマーガリン50重量部を静置し、包み込んだ。このとき、ロールインマーガリンを包んだ伸展前の生地のサイズは、36cm(縦)×14.4cm(横)×5cm(厚)であった。この生地を、リバースシーターを用いて10mm厚になるまでは5mmごとに段階的に伸展し、その後は2mmごとに段階的に伸展し、最後は4mm厚に調整したリバースシーターを用いて、生地を4mm厚に伸展した。続けて生地を3つ折りした後、3mm厚に調整したリバースシーターを用い、生地を3mm厚に伸展した。得られた生地を1℃で10時間冷却後、更に3つ折りした後、2.5mm厚に調整したリバースシーターを用いて生地を2.5mm厚に伸展した。生地を成形後、35℃、湿度70%のホイロで1時間最終発酵した後、200℃のオーブンで15分間焼成し、デニッシュを得た。デニッシュを作製する際の作業性及び得られたデニッシュの浮き及び風味について評価し、その結果を表1に示した。 After 191.6 parts by weight of the cooled dough was shaped, 50 parts by weight of roll-in margarine kept at 15°C was left to stand and wrapped. At this time, the size of the dough wrapped around the roll-in margarine before stretching was 36 cm (length) x 14.4 cm (width) x 5 cm (thickness). Using a reverse sheeter, stretch the fabric in steps of 5 mm until it reaches a thickness of 10 mm, then stretch it step by step in steps of 2 mm, and finally use a reverse sheeter adjusted to a thickness of 4 mm to stretch the fabric. It was expanded to a thickness of 4 mm. Subsequently, the fabric was folded into three, and then stretched to a thickness of 3 mm using a reverse sheeter adjusted to a thickness of 3 mm. After cooling the obtained dough at 1° C. for 10 hours, it was further folded into three, and then stretched to a thickness of 2.5 mm using a reverse sheeter adjusted to a thickness of 2.5 mm. After shaping the dough, it was final fermented for 1 hour in a foil at 35°C and 70% humidity, and then baked in an oven at 200°C for 15 minutes to obtain a Danish pastry. The workability in making the danishes and the floating and flavor of the danishes obtained were evaluated, and the results are shown in Table 1.
(実施例2~12及び比較例1~5)
表1に示す配合に従って油相、水相、固形分の配合を変更した以外は、実施例1と同様にしてロールインマーガリンを得た。表1に、充填10秒後に測定した粘度の値を記載した。また、ロールインマーガリンの生産性及び離水量について評価し、その結果を表1に示した。
次いで、得られたロールインマーガリンを用いて実施例1と同様にして、デニッシュを作製した。デニッシュを作製する際の作業性及び得られたデニッシュの浮き及び風味について評価し、その結果を表1に示した。
(Examples 2 to 12 and Comparative Examples 1 to 5)
Roll-in margarine was obtained in the same manner as in Example 1, except that the oil phase, water phase, and solid content were changed according to the formulation shown in Table 1. Table 1 lists the viscosity values measured 10 seconds after filling. In addition, the productivity and amount of syneresis of the roll-in margarine were evaluated, and the results are shown in Table 1.
Next, a Danish pastry was produced in the same manner as in Example 1 using the obtained roll-in margarine. The workability in making the danishes and the floating and flavor of the danishes obtained were evaluated, and the results are shown in Table 1.
表1より、実施例1~12のロールインマーガリンはいずれも、生産性及び離水量が良好な評価となり、また、これらのロールインマーガリンを使用して作製されたデニッシュはいずれも、デニッシュ作製時の作業時間が短く、作業性が良好で、作製されたデニッシュの浮き及び風味も良好で、総合評価はC以上であった。 From Table 1, all of the roll-in margarines of Examples 1 to 12 were evaluated to be good in terms of productivity and water separation, and all of the danishes made using these roll-in margarines were The working time was short, the workability was good, and the produced danishes had good floating and flavor, and the overall evaluation was C or higher.
一方、比較例1のロールインマーガリンは、油脂(A)の含有量が少なかったものであり、これを使用して作製されたデニッシュの浮きが低い評価となり、総合評価はDであった。比較例2のロールインマーガリンは、油脂(A)の含有量が多かったものであり、デニッシュの風味が低い評価となり、総合評価はDであった。比較例3のロールインマーガリンは、油脂(B)の含有量が少なかったものであり、デニッシュ作製時の作業性が低い評価となり、総合評価はDであった。比較例4のロールインマーガリンは、油脂(B)の含有量が多かったものであり、デニッシュ作製時の作業性が低く、また、デニッシュの浮きも低い評価となり、総合評価はDであった。比較例5のロールインマーガリンは、粉末状の固形分の含有量が多かったものであり、離水量が悪い評価となり、また、デニッシュ作製時の作業性が低く、デニッシュの浮きも低い評価となり、総合評価はEであった。 On the other hand, the roll-in margarine of Comparative Example 1 had a low content of fats and oils (A), and the Danish made using the roll-in margarine had a low floating rating, and the overall rating was D. The roll-in margarine of Comparative Example 2 had a high content of oil and fat (A), was rated low in Danish flavor, and had an overall rating of D. The roll-in margarine of Comparative Example 3 had a low content of fats and oils (B), and its workability during Danish pastry production was evaluated as low, resulting in an overall evaluation of D. The roll-in margarine of Comparative Example 4 had a high content of fats and oils (B), had low workability during the production of danishes, and was rated low in the floating of the danishes, resulting in an overall rating of D. The roll-in margarine of Comparative Example 5 had a high content of powdery solids, and was evaluated as having poor water repellency, and also had low workability when making danishes, and was also evaluated as having low danishes floating. The overall evaluation was E.
(実施例13)
表4の製造条件に従って、冷却時の最終到達温度を1℃に変更し、冷却保持時間を20秒間にし、テンパリング処理を行わなかった以外は、実施例1と同様にしてロールインマーガリンを得た。表4に、充填10秒後に測定した粘度の値を記載した。また、ロールインマーガリンの生産性及び離水量について評価し、その結果を表4に示した。
次いで、得られたロールインマーガリンを用いて実施例1と同様にして、デニッシュを作製した。デニッシュを作製する際の作業性及び得られたデニッシュの浮き及び風味について評価し、その結果を表4に示した。
(Example 13)
According to the production conditions in Table 4, roll-in margarine was obtained in the same manner as in Example 1, except that the final temperature reached during cooling was changed to 1 ° C., the cooling holding time was changed to 20 seconds, and no tempering treatment was performed. . Table 4 lists the viscosity values measured 10 seconds after filling. In addition, the productivity and amount of syneresis of the roll-in margarine were evaluated, and the results are shown in Table 4.
Next, a Danish pastry was produced in the same manner as in Example 1 using the obtained roll-in margarine. The workability in making the danishes and the floating and flavor of the danishes obtained were evaluated, and the results are shown in Table 4.
(実施例14)
表4の製造条件に従って、冷却時の最終到達温度を1℃に変更し、冷却保持時間を200秒間にし、テンパリング処理を行わなかった以外は、実施例1と同様にしてロールインマーガリンを得た。表4に、充填10秒後に測定した粘度の値を記載した。また、ロールインマーガリンの生産性及び離水量について評価し、その結果を表4に示した。
次いで、得られたロールインマーガリンを用いて実施例1と同様にして、デニッシュを作製した。デニッシュを作製する際の作業性及び得られたデニッシュの浮き及び風味について評価し、その結果を表4に示した。
(Example 14)
According to the production conditions in Table 4, roll-in margarine was obtained in the same manner as in Example 1, except that the final temperature reached during cooling was changed to 1 ° C., the cooling holding time was changed to 200 seconds, and no tempering treatment was performed. . Table 4 lists the viscosity values measured 10 seconds after filling. In addition, the productivity and amount of syneresis of the roll-in margarine were evaluated, and the results are shown in Table 4.
Next, a Danish pastry was produced in the same manner as in Example 1 using the obtained roll-in margarine. The workability in making the danishes and the floating and flavor of the danishes obtained were evaluated, and the results are shown in Table 4.
(実施例15)
表4の製造条件に従って、冷却時の最終到達温度を20℃に変更し、冷却保持時間を20秒間にし、テンパリング処理を行わなかった以外は、実施例1と同様にしてロールインマーガリンを得た。表4に、充填10秒後に測定した粘度の値を記載した。また、ロールインマーガリンの生産性及び離水量について評価し、その結果を表4に示した。
次いで、得られたロールインマーガリンを用いて実施例1と同様にして、デニッシュを作製した。デニッシュを作製する際の作業性及び得られたデニッシュの浮き及び風味について評価し、その結果を表4に示した。
(Example 15)
According to the production conditions in Table 4, roll-in margarine was obtained in the same manner as in Example 1, except that the final temperature reached during cooling was changed to 20 ° C., the cooling holding time was changed to 20 seconds, and no tempering treatment was performed. . Table 4 lists the viscosity values measured 10 seconds after filling. In addition, the productivity and amount of syneresis of the roll-in margarine were evaluated, and the results are shown in Table 4.
Next, a Danish pastry was produced in the same manner as in Example 1 using the obtained roll-in margarine. The workability in making the danishes and the floating and flavor of the danishes obtained were evaluated, and the results are shown in Table 4.
(実施例16)
表4の製造条件に従って、冷却時の最終到達温度を20℃に変更し、冷却保持時間を200秒間にし、テンパリング処理を行わなかった以外は、実施例1と同様にしてロールインマーガリンを得た。表4に、充填10秒後に測定した粘度の値を記載した。また、ロールインマーガリンの生産性及び離水量について評価し、その結果を表4に示した。
次いで、得られたロールインマーガリンを用いて実施例1と同様にして、デニッシュを作製した。デニッシュを作製する際の作業性及び得られたデニッシュの浮き及び風味について評価し、その結果を表4に示した。
(Example 16)
According to the production conditions in Table 4, roll-in margarine was obtained in the same manner as in Example 1, except that the final temperature reached during cooling was changed to 20 ° C., the cooling holding time was changed to 200 seconds, and no tempering treatment was performed. . Table 4 lists the viscosity values measured 10 seconds after filling. In addition, the productivity and amount of syneresis of the roll-in margarine were evaluated, and the results are shown in Table 4.
Next, a Danish pastry was produced in the same manner as in Example 1 using the obtained roll-in margarine. The workability in making the danishes and the floating and flavor of the danishes obtained were evaluated, and the results are shown in Table 4.
(比較例6)
表4の製造条件に従って、実施例1と同様にして得た油脂が融解状態の乳化物を密閉型連続式チューブ冷却機内(コンビネーター:1.3L容量)で最終到達温度10℃まで急冷した。この冷却過程で、ロールインマーガリンの製造装置のライン中における密閉型連続式チューブ冷却機内で25℃の品温に達してから、10℃に達温してレスティングチューブ(17.0L容量、20℃)に移送するまで94秒間、該乳化物を該冷却機内で保持した後、レスティングチューブに移送し、成型ノズルを通して厚さ10mmのブロックマーガリンを得た。
(Comparative example 6)
According to the production conditions shown in Table 4, an emulsion containing molten oil and fat obtained in the same manner as in Example 1 was rapidly cooled to a final temperature of 10° C. in a closed continuous tube cooler (combinator: 1.3 L capacity). During this cooling process, the product temperature reaches 25°C in the closed continuous tube cooler in the roll-in margarine manufacturing equipment line, and then reaches 10°C and the resting tube (17.0L capacity, 20°C). The emulsion was held in the cooler for 94 seconds until transferred to a temperature of 100° C.), then transferred to a resting tube and passed through a molding nozzle to obtain a block margarine with a thickness of 10 mm.
成型ノズルから排出10秒後に粘度を測定した。このブロックマーガリンを4℃で240時間静置して、シート厚10mmのロールインマーガリンを得た。表4に、排出10秒後に測定した粘度の値を記載した。また、ロールインマーガリンの生産性及び離水量について評価し、その結果を表4に示した。 The viscosity was measured 10 seconds after being discharged from the molding nozzle. This block margarine was allowed to stand at 4° C. for 240 hours to obtain roll-in margarine with a sheet thickness of 10 mm. Table 4 lists the viscosity values measured 10 seconds after discharge. In addition, the productivity and amount of syneresis of the roll-in margarine were evaluated, and the results are shown in Table 4.
次いで、得られたロールインマーガリンを用いて実施例1と同様にして、デニッシュを作製した。デニッシュを作製する際の作業性及び得られたデニッシュの浮き及び風味について評価し、その結果を表4に示した。 Next, a Danish pastry was produced in the same manner as in Example 1 using the obtained roll-in margarine. The workability in making the danishes and the floating and flavor of the danishes obtained were evaluated, and the results are shown in Table 4.
(比較例7)
表4の製造条件に従って、冷却時の最終到達温度を20℃に変更し、冷却保持時間を20秒間にした以外は、比較例6と同様にしてロールインマーガリンを得た。表4に、排出10秒後に測定した粘度の値を記載した。また、ロールインマーガリンの生産性及び離水量について評価し、その結果を表4に示した。
次いで、得られたロールインマーガリンを用いて実施例1と同様にして、デニッシュを作製した。デニッシュを作製する際の作業性及び得られたデニッシュの浮き及び風味について評価し、その結果を表4に示した。
(Comparative example 7)
According to the production conditions in Table 4, roll-in margarine was obtained in the same manner as in Comparative Example 6, except that the final temperature reached during cooling was changed to 20° C. and the cooling holding time was changed to 20 seconds. Table 4 lists the viscosity values measured 10 seconds after discharge. In addition, the productivity and amount of syneresis of the roll-in margarine were evaluated, and the results are shown in Table 4.
Next, a Danish pastry was produced in the same manner as in Example 1 using the obtained roll-in margarine. The workability in making the danishes and the floating and flavor of the danishes obtained were evaluated, and the results are shown in Table 4.
(比較例8)
表4の製造条件に従って、冷却時の最終到達温度を20℃に変更し、冷却保持時間を200秒間にした以外は、比較例6と同様にしてロールインマーガリンを得た。表4に、排出10秒後に測定した粘度の値を記載した。また、ロールインマーガリンの生産性及び離水量について評価し、その結果を表4に示した。
次いで、得られたロールインマーガリンを用いて実施例1と同様にして、デニッシュを作製した。デニッシュを作製する際の作業性及び得られたデニッシュの浮き及び風味について評価し、その結果を表4に示した。
(Comparative example 8)
According to the production conditions in Table 4, roll-in margarine was obtained in the same manner as in Comparative Example 6, except that the final temperature reached during cooling was changed to 20° C. and the cooling holding time was changed to 200 seconds. Table 4 lists the viscosity values measured 10 seconds after discharge. In addition, the productivity and amount of syneresis of the roll-in margarine were evaluated, and the results are shown in Table 4.
Next, a Danish pastry was produced in the same manner as in Example 1 using the obtained roll-in margarine. The workability in making the danishes and the floating and flavor of the danishes obtained were evaluated, and the results are shown in Table 4.
表4より、実施例1、13~16のロールインマーガリンはいずれも、生産性及び離水量が良好な評価となり、また、これらのロールインマーガリンを使用して作製されたデニッシュはいずれも、デニッシュ作製時の作業時間が短く、作業性が良好で、作製されたデニッシュの浮き及び風味も良好で、総合評価はC以上であった。 From Table 4, the roll-in margarines of Examples 1 and 13 to 16 all had good evaluations in terms of productivity and water separation, and all of the Danish pastries made using these roll-in margarines The working time during production was short, the workability was good, and the produced danish had good floating and flavor, and the overall evaluation was C or higher.
一方、比較例6~8のロールインマーガリンは、ピロー包装への充填を行わず、レスティングチューブと成型ノズルを使用して製造したものである。比較例6では、離水量が悪い評価となり、また、デニッシュ作製時の作業性が低く、デニッシュの浮きも低い評価となり、総合評価はEであった。比較例7では、離水量が悪い評価となり、また、デニッシュ作製時の作業性も低い評価となり、総合評価はEであった。比較例8では、生産性及び離水量が悪い評価となり、また、デニッシュ作製時の作業性が低く、デニッシュの風味も低い評価となり、総合評価はEであった。 On the other hand, the roll-in margarines of Comparative Examples 6 to 8 were produced using a resting tube and a molding nozzle without filling pillow packaging. In Comparative Example 6, the amount of syneresis was evaluated as poor, the workability during the production of danishes was low, and the floating of the danishes was also evaluated as low, and the overall evaluation was E. In Comparative Example 7, the amount of syneresis was evaluated as poor, and the workability during Danish pastry production was also evaluated as low, and the overall evaluation was E. In Comparative Example 8, the productivity and the amount of water separation were evaluated as poor, the workability during Danish making was low, the flavor of the Danish was also evaluated as low, and the overall evaluation was E.
(実施例17)
表5の製造条件に従って、混和昇温装置で軟化させて昇温させた時の温度を13℃に変更し、テンパリング処理を行わなかった以外は、実施例1と同様にしてロールインマーガリンを得た。表5に、充填10秒後に測定した粘度の値を記載した。また、ロールインマーガリンの生産性及び離水量について評価し、その結果を表5に示した。
次いで、得られたロールインマーガリンを用いて実施例1と同様にして、デニッシュを作製した。デニッシュを作製する際の作業性及び得られたデニッシュの浮き及び風味について評価し、その結果を表5に示した。
(Example 17)
Roll-in margarine was obtained in the same manner as in Example 1, except that according to the production conditions in Table 5, the temperature at which it was softened and heated using a mixing temperature rising device was changed to 13°C, and no tempering treatment was performed. Ta. Table 5 lists the viscosity values measured 10 seconds after filling. In addition, the productivity and amount of syneresis of the roll-in margarine were evaluated, and the results are shown in Table 5.
Next, a Danish pastry was produced in the same manner as in Example 1 using the obtained roll-in margarine. The workability in making the danishes and the floating and flavor of the danishes obtained were evaluated, and the results are shown in Table 5.
(実施例18)
表5の製造条件に従って、混和昇温装置で軟化させて昇温させた時の温度を32℃に変更し、テンパリング処理を行わなかった以外は、実施例1と同様にしてロールインマーガリンを得た。表5に、充填10秒後に測定した粘度の値を記載した。また、ロールインマーガリンの生産性及び離水量について評価し、その結果を表5に示した。
次いで、得られたロールインマーガリンを用いて実施例1と同様にして、デニッシュを作製した。デニッシュを作製する際の作業性及び得られたデニッシュの浮き及び風味について評価し、その結果を表5に示した。
(Example 18)
Roll-in margarine was obtained in the same manner as in Example 1, except that according to the production conditions in Table 5, the temperature at which it was softened and heated in the mixing temperature rising device was changed to 32°C, and no tempering treatment was performed. Ta. Table 5 lists the viscosity values measured 10 seconds after filling. In addition, the productivity and amount of syneresis of the roll-in margarine were evaluated, and the results are shown in Table 5.
Next, a Danish pastry was produced in the same manner as in Example 1 using the obtained roll-in margarine. The workability in making the danishes and the floating and flavor of the danishes obtained were evaluated, and the results are shown in Table 5.
(実施例19)
表5の製造条件に従って、テンパリング処理後に静置する際の温度を-20℃に変更し、テンパリング処理を行わなかった以外は、実施例1と同様にしてロールインマーガリンを得た。表5に、充填10秒後に測定した粘度の値を記載した。また、ロールインマーガリンの生産性及び離水量について評価し、その結果を表5に示した。
次いで、得られたロールインマーガリンを用いて実施例1と同様にして、デニッシュを作製した。デニッシュを作製する際の作業性及び得られたデニッシュの浮き及び風味について評価し、その結果を表5に示した。
(Example 19)
According to the production conditions in Table 5, roll-in margarine was obtained in the same manner as in Example 1, except that the temperature during standing after the tempering treatment was changed to -20°C and the tempering treatment was not performed. Table 5 lists the viscosity values measured 10 seconds after filling. In addition, the productivity and amount of syneresis of the roll-in margarine were evaluated, and the results are shown in Table 5.
Next, a Danish pastry was produced in the same manner as in Example 1 using the obtained roll-in margarine. The workability in making the danishes and the floating and flavor of the danishes obtained were evaluated, and the results are shown in Table 5.
(実施例20)
表5の製造条件に従って、テンパリング処理後に静置する際の温度を27℃に変更し、テンパリング処理を行わなかった以外は、実施例1と同様にしてロールインマーガリンを得た。表5に、充填10秒後に測定した粘度の値を記載した。また、ロールインマーガリンの生産性及び離水量について評価し、その結果を表5に示した。
次いで、得られたロールインマーガリンを用いて実施例1と同様にして、デニッシュを作製した。デニッシュを作製する際の作業性及び得られたデニッシュの浮き及び風味について評価し、その結果を表5に示した。
(Example 20)
According to the manufacturing conditions in Table 5, roll-in margarine was obtained in the same manner as in Example 1, except that the temperature at which the product was allowed to stand after the tempering treatment was changed to 27° C., and the tempering treatment was not performed. Table 5 lists the viscosity values measured 10 seconds after filling. In addition, the productivity and amount of syneresis of the roll-in margarine were evaluated, and the results are shown in Table 5.
Next, a Danish pastry was produced in the same manner as in Example 1 using the obtained roll-in margarine. The workability in making the danishes and the floating and flavor of the danishes obtained were evaluated, and the results are shown in Table 5.
(実施例21)
表5の製造条件に従って、テンパリング処理後に静置する際の時間を36時間に変更し、テンパリング処理を行わなかった以外は、実施例1と同様にしてロールインマーガリンを得た。表5に、充填10秒後に測定した粘度の値を記載した。また、ロールインマーガリンの生産性及び離水量について評価し、その結果を表5に示した。
次いで、得られたロールインマーガリンを用いて実施例1と同様にして、デニッシュを作製した。デニッシュを作製する際の作業性及び得られたデニッシュの浮き及び風味について評価し、その結果を表5に示した。
(Example 21)
According to the production conditions in Table 5, roll-in margarine was obtained in the same manner as in Example 1, except that the time for standing after the tempering treatment was changed to 36 hours, and the tempering treatment was not performed. Table 5 lists the viscosity values measured 10 seconds after filling. In addition, the productivity and amount of syneresis of the roll-in margarine were evaluated, and the results are shown in Table 5.
Next, a Danish pastry was produced in the same manner as in Example 1 using the obtained roll-in margarine. The workability in making the danishes and the floating and flavor of the danishes obtained were evaluated, and the results are shown in Table 5.
(比較例9)
表5の製造条件に従って、混和昇温装置で軟化させて昇温させた時の温度を37℃に変更し、テンパリング処理を行わなかった以外は、実施例1と同様にしてロールインマーガリンを得た。表5に、充填10秒後に乳化物はほぼ融解した状態にあり、粘度を測定できなかった。また、ロールインマーガリンの生産性及び離水量について評価し、その結果を表5に示した。
次いで、得られたロールインマーガリンを用いて実施例1と同様にして、デニッシュを作製した。デニッシュを作製する際の作業性及び得られたデニッシュの浮き及び風味について評価し、その結果を表5に示した。
(Comparative example 9)
Roll-in margarine was obtained in the same manner as in Example 1, except that according to the production conditions in Table 5, the temperature at which it was softened and heated using a mixing temperature rising device was changed to 37°C, and no tempering treatment was performed. Ta. Table 5 shows that the emulsion was in a nearly molten state 10 seconds after filling, and the viscosity could not be measured. In addition, the productivity and amount of syneresis of the roll-in margarine were evaluated, and the results are shown in Table 5.
Next, a Danish pastry was produced in the same manner as in Example 1 using the obtained roll-in margarine. The workability in making the danishes and the floating and flavor of the danishes obtained were evaluated, and the results are shown in Table 5.
(比較例10)
表5の製造条件に従って、テンパリング処理後に静置する際の温度を35℃に変更し、テンパリング処理を行わなかった以外は、実施例1と同様にしてロールインマーガリンを得た。表5に、充填10秒後に測定した粘度の値を記載した。また、ロールインマーガリンの生産性及び離水量について評価し、その結果を表5に示した。
次いで、得られたロールインマーガリンを用いて実施例1と同様にして、デニッシュを作製した。デニッシュを作製する際の作業性及び得られたデニッシュの浮き及び風味について評価し、その結果を表5に示した。
(Comparative example 10)
According to the production conditions in Table 5, a roll-in margarine was obtained in the same manner as in Example 1, except that the temperature at which the product was allowed to stand after the tempering treatment was changed to 35° C., and the tempering treatment was not performed. Table 5 lists the viscosity values measured 10 seconds after filling. In addition, the productivity and amount of syneresis of the roll-in margarine were evaluated, and the results are shown in Table 5.
Next, a Danish pastry was produced in the same manner as in Example 1 using the obtained roll-in margarine. The workability in making the danishes and the floating and flavor of the danishes obtained were evaluated, and the results are shown in Table 5.
(比較例11)
表5の製造条件に従って、テンパリング処理後に静置する際の時間を20時間に変更し、テンパリング処理を行わなかった以外は、実施例1と同様にしてロールインマーガリンを得た。表5に、充填10秒後に測定した粘度の値を記載した。また、ロールインマーガリンの生産性及び離水量について評価し、その結果を表5に示した。
次いで、得られたロールインマーガリンを用いて実施例1と同様にして、デニッシュを作製した。デニッシュを作製する際の作業性及び得られたデニッシュの浮き及び風味について評価し、その結果を表5に示した。
(Comparative Example 11)
According to the production conditions in Table 5, roll-in margarine was obtained in the same manner as in Example 1, except that the time for standing after the tempering treatment was changed to 20 hours, and the tempering treatment was not performed. Table 5 lists the viscosity values measured 10 seconds after filling. In addition, the productivity and amount of syneresis of the roll-in margarine were evaluated, and the results are shown in Table 5.
Next, a Danish pastry was produced in the same manner as in Example 1 using the obtained roll-in margarine. The workability in making the danishes and the floating and flavor of the danishes obtained were evaluated, and the results are shown in Table 5.
表5より、実施例1、17~21のロールインマーガリンはいずれも、生産性及び離水量が良好な評価となり、また、これらのロールインマーガリンを使用して作製されたデニッシュはいずれも、デニッシュ作製時の作業時間が短く、作業性が良好で、作製されたデニッシュの浮き及び風味も良好で、総合評価はC以上であった。 From Table 5, the roll-in margarines of Examples 1 and 17 to 21 all had good evaluations in terms of productivity and amount of syneresis, and all of the Danish pastries made using these roll-in margarines The working time during production was short, the workability was good, and the produced danish had good floating and flavor, and the overall evaluation was C or higher.
一方、比較例9のロールインマーガリンは、昇温時の温度が高かったものであり、デニッシュ作製時の作業性が低く、また、デニッシュの浮き及び風味も低い評価となり、総合評価はEであった。比較例10のロールインマーガリンは、静置時の温度が高かったものであり、デニッシュ作製時の作業性が低く、また、デニッシュの浮き及び風味も低い評価となり、総合評価はEであった。比較例11のロールインマーガリンは、静置時間が短かったものであり、デニッシュの浮きが低い評価となり、総合評価はDであった。 On the other hand, the roll-in margarine of Comparative Example 9 had a high temperature during heating, had low workability when making danishes, and also had low ratings for the floating and flavor of danishes, and the overall rating was E. Ta. The roll-in margarine of Comparative Example 10 had a high temperature when left still, had low workability when making danishes, and was rated low in terms of floating and flavor of the danishes, giving an overall rating of E. The roll-in margarine of Comparative Example 11 had a short standing time and was rated low in floating Danishes, giving an overall rating of D.
Claims (7)
ロールインマーガリン中に含まれる油相全体中、油脂(A)を15~30重量%、油脂(B)を20~45重量%を含有し、
油相と水相のいずれにも溶解しない粉末状の固形分をロールインマーガリン全体中5~50重量%含み、
前記粉末状の固形分を含み、油脂が融解した状態にある油中水型乳化油脂組成物が、0~25℃まで冷却されて該温度で10~300秒間保持され晶析された後、混和により軟化させられながら10~35℃に昇温されて、粘度が10~250Pa・sに調整された流動状の前記油中水型乳化油脂組成物がピロー包装に充填され、該ピロー包装の口が閉じられてからシート状に圧延されて成型され、-30℃~30℃で24時間以上静置されたロールインマーガリン。
油脂(A):構成脂肪酸全体中、炭素数12以下の飽和脂肪酸含有量が15重量%以上、炭素数18以上の飽和脂肪酸含有量が15重量%以上、飽和脂肪酸含有量が70重量%以上であり、三飽和トリグリセライド含有量が油脂(A)全体中15重量%以上である、エステル交換または極度硬化された油脂
油脂(B):飽和脂肪酸含有量が構成脂肪酸全体中20重量%以下であり、三不飽和トリグリセライド含有量が油脂(B)全体中50重量%以上である油脂 The oil phase content/aqueous phase content (weight ratio) in the whole roll-in margarine is 50/50 to 97/3,
Contains 15 to 30% by weight of oil (A) and 20 to 45% by weight of oil (B) in the entire oil phase contained in roll-in margarine,
Contains 5 to 50% by weight of the entire roll-in margarine, including powdered solids that do not dissolve in either the oil phase or the water phase,
The water-in-oil emulsified fat composition containing the powdered solid content and in which the fat is melted is cooled to 0 to 25°C and held at that temperature for 10 to 300 seconds to crystallize, and then mixed. The water-in-oil emulsified oil composition in a fluid state is heated to 10 to 35°C while being softened to have a viscosity of 10 to 250 Pa·s, and is filled into a pillow package. Roll-in margarine that is closed, rolled into a sheet, molded, and left at -30°C to 30°C for 24 hours or more.
Fats and oils (A): The content of saturated fatty acids with carbon numbers of 12 or less is 15% by weight or more, the content of saturated fatty acids with carbon numbers of 18 or more is 15% by weight or more, and the saturated fatty acid content is 70% by weight or more of the total fatty acids. Yes, transesterified or extremely hardened fats and oils have a trisaturated triglyceride content of 15% by weight or more based on the total fats and oils (A) Fats and oils (B): saturated fatty acids content is 20% by weight or less based on the entire constituent fatty acids, Fats and oils having a triunsaturated triglyceride content of 50% by weight or more based on the whole fat and oil (B)
S:炭素数16以上の飽和脂肪酸
U:炭素数16以上の不飽和脂肪酸
SSU:1,2位又は2,3位にS、1位又3位にUが結合しているトリグリセリド
SUS:1,3位にS、2位にUが結合しているトリグリセリド The roll-in margarine according to claim 1, wherein the SSU content/SUS content (weight ratio) in the entire oil and fat contained in the roll-in margarine is 1.5 to 2.5.
S: Saturated fatty acid with 16 or more carbon atoms U: Unsaturated fatty acid with 16 or more carbon atoms SSU: Triglyceride in which S is bonded to the 1st, 2nd or 2nd, 3rd position, and U is bonded to the 1st or 3rd position SUS: 1, Triglyceride with S attached to the 3rd position and U attached to the 2nd position
油脂(A):構成脂肪酸全体中、炭素数12以下の飽和脂肪酸含有量が15重量%以上、炭素数18以上の飽和脂肪酸含有量が15重量%以上、飽和脂肪酸含有量が70重量%以上であり、三飽和トリグリセライド含有量が油脂(A)全体中15重量%以上である、エステル交換または極度硬化された油脂
油脂(B):飽和脂肪酸含有量が構成脂肪酸全体中20重量%以下であり、三不飽和トリグリセライド含有量が油脂(B)全体中50重量%以上である油脂
After mixing and dissolving the oil containing 15 to 30% by weight of oil (A) and 20 to 45% by weight of oil (B) in the entire oil phase and other oil-soluble components as necessary, the oil phase and Powdered solids that do not dissolve in any of the aqueous phases are added and dispersed in an amount of 5 to 50% by weight based on the entire water-in-oil emulsified fat composition, and then maintained at the temperature to form an oil phase, and mixed with water as necessary. After mixing other water-soluble components accordingly to form an aqueous phase, the aqueous phase is added to the oil phase so that the amount of the oil phase/the amount of the aqueous phase (weight ratio) is in the range of 50/50 to 97/3. The water-in-oil emulsified oil/fat composition containing the powdered solid content is obtained by stirring and emulsifying the oil while stirring, and the water-in-oil emulsified oil/fat composition is cooled to 0 to 25°C and heated at this temperature for 10 to 25°C. After holding for 300 seconds to crystallize, the fluidized water-in-oil emulsified fat composition was heated to 10 to 35°C while being softened by mixing, and the viscosity was adjusted to 10 to 250 Pa·s. A method for producing roll-in margarine, which comprises filling a package, closing the mouth of the pillow package, rolling it into a sheet, and allowing it to stand at -30°C to 30°C for 24 hours or more.
Fats and oils (A): The content of saturated fatty acids with carbon numbers of 12 or less is 15% by weight or more, the content of saturated fatty acids with carbon numbers of 18 or more is 15% by weight or more, and the saturated fatty acid content is 70% by weight or more of the total fatty acids. Yes, transesterified or extremely hardened fats and oils have a trisaturated triglyceride content of 15% by weight or more based on the total fats and oils (A) Fats and oils (B): saturated fatty acids content is 20% by weight or less based on the entire constituent fatty acids, Fats and oils having a triunsaturated triglyceride content of 50% by weight or more based on the whole fat and oil (B)
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| JP2015195751A (en) | 2014-03-31 | 2015-11-09 | 株式会社カネカ | Sugar-containing roll-in margarine |
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