JP7598385B2 - Bakery food composition - Google Patents
Bakery food composition Download PDFInfo
- Publication number
- JP7598385B2 JP7598385B2 JP2022558734A JP2022558734A JP7598385B2 JP 7598385 B2 JP7598385 B2 JP 7598385B2 JP 2022558734 A JP2022558734 A JP 2022558734A JP 2022558734 A JP2022558734 A JP 2022558734A JP 7598385 B2 JP7598385 B2 JP 7598385B2
- Authority
- JP
- Japan
- Prior art keywords
- dough
- wheat flour
- composition
- heat
- bakery
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Active
Links
Classifications
-
- A—HUMAN NECESSITIES
- A21—BAKING; EDIBLE DOUGHS
- A21D—TREATMENT OF FLOUR OR DOUGH FOR BAKING, e.g. BY ADDITION OF MATERIALS; BAKING; BAKERY PRODUCTS
- A21D6/00—Other treatment of flour or dough before baking, e.g. cooling, irradiating or heating
- A21D6/003—Heat treatment
-
- A—HUMAN NECESSITIES
- A21—BAKING; EDIBLE DOUGHS
- A21D—TREATMENT OF FLOUR OR DOUGH FOR BAKING, e.g. BY ADDITION OF MATERIALS; BAKING; BAKERY PRODUCTS
- A21D10/00—Batters, dough or mixtures before baking
- A21D10/02—Ready-for-oven doughs
-
- A—HUMAN NECESSITIES
- A21—BAKING; EDIBLE DOUGHS
- A21D—TREATMENT OF FLOUR OR DOUGH FOR BAKING, e.g. BY ADDITION OF MATERIALS; BAKING; BAKERY PRODUCTS
- A21D13/00—Finished or partly finished bakery products
-
- A—HUMAN NECESSITIES
- A21—BAKING; EDIBLE DOUGHS
- A21D—TREATMENT OF FLOUR OR DOUGH FOR BAKING, e.g. BY ADDITION OF MATERIALS; BAKING; BAKERY PRODUCTS
- A21D6/00—Other treatment of flour or dough before baking, e.g. cooling, irradiating or heating
-
- A—HUMAN NECESSITIES
- A21—BAKING; EDIBLE DOUGHS
- A21D—TREATMENT OF FLOUR OR DOUGH FOR BAKING, e.g. BY ADDITION OF MATERIALS; BAKING; BAKERY PRODUCTS
- A21D8/00—Methods for preparing or baking dough
- A21D8/06—Baking processes
Landscapes
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Food Science & Technology (AREA)
- Physics & Mathematics (AREA)
- Thermal Sciences (AREA)
- Bakery Products And Manufacturing Methods Therefor (AREA)
Description
本発明は、ベーカリー食品などのための生地の製造に用いられる組成物に関する。The present invention relates to a composition for use in producing dough for bakery foods and the like.
従来、パンやピザなどのベーカリー食品では、サクサクとした乾いた食感が好まれていた。一方で、ベーカリー食品や麺類などの生地から製造する食品においては、柔らかさやしっとりした食感も好ましい性質である。例えば、喫食時には唇に吸い付くようなしっとりした食感を有する一方で、咀嚼したときに口中にまとわりつきがなく歯切れのよい食感を有するベーカリー食品が好まれている。また麺類であれば、柔らかくもちもちする一方で、弾力があり歯切れのよい食感を有するものが好まれている。このような相矛盾する生地の食感は、例えば、ベーカリー食品であれば、生地の含水率を増加させつつ、多数の細かい起泡を含ませるように焼成して脆い構造の生地を製造することで達成できる。しかしながら、このような製法には複雑な又は熟練の技術が必要であり、簡便に行うことは困難であった。 Conventionally, a crispy, dry texture was preferred for bakery foods such as bread and pizza. On the other hand, softness and moist texture are also preferred properties for bakery foods and foods made from dough such as noodles. For example, bakery foods that have a moist texture that sticks to the lips when eaten, but do not stick to the mouth when chewed, and have a crisp texture are preferred. For noodles, on the other hand, noodles that are soft and chewy, but have an elastic and crisp texture are preferred. For example, for bakery foods, such contradictory dough textures can be achieved by increasing the moisture content of the dough and baking it to include many fine bubbles to produce a brittle dough. However, such manufacturing methods require complex or skilled techniques, and it was difficult to carry out easily.
一般的に、ベーカリー食品や麺類の生地の主原料である穀粉や澱粉は、水と共に加熱すると、α化してもちもち又はしっとりした食感を有するようになる。これを利用して、ベーカリー食品の食感を改良する試みが提案されている。特許文献1には、原料小麦粉の一部を1~2.5倍の熱水と共に混合してα化させ、これに残りの原料を添加して混合することを含む、パンの製造方法が記載されている。特許文献2には、原料粉と水との混合物を加圧加熱処理して得られた前生地に残りの原料を混合することで、ソフトでしっとり、もちもちとした食感のパン類を製造することが記載されている。特許文献3には、α化穀粉を含む原料粉にイーストおよび水を添加して混捏し、得られた生地を発酵させることを含む、パン類用発酵種の製造方法が記載されている。Generally, when flour or starch, which is the main ingredient of dough for bakery foods and noodles, is heated with water, it becomes gelatinized and has a chewy or moist texture. Attempts have been proposed to utilize this to improve the texture of bakery foods. Patent Document 1 describes a method for producing bread, which includes mixing a part of raw wheat flour with 1 to 2.5 times the amount of hot water to gelatinize it, and then adding and mixing the remaining ingredients to this. Patent Document 2 describes the production of breads with a soft, moist, and chewy texture by mixing the remaining ingredients with a preliminary dough obtained by pressurizing and heating a mixture of raw flour and water. Patent Document 3 describes a method for producing a leaven for bread, which includes adding yeast and water to raw flour containing gelatinized grain flour, kneading the mixture, and fermenting the resulting dough.
小麦粉に含まれる蛋白質であるグルテンは、網目状の構造を形成する性質を有し、生地に成形性や弾力を付与する。その一方でグルテンは生地の食感を硬くするため、前述のようなもちもち又はしっとりした食感のためには好ましくない。特許文献4には、小麦蛋白質をpH2.5~8.0の溶媒に分散させ、温度50~100℃で2時間~30日間加熱して小麦蛋白質を部分的に変性させることで製造された食品品質改良剤が、食品に優れた伸展性を与えることが記載されている。Gluten, a protein contained in wheat flour, has the property of forming a mesh-like structure, imparting moldability and elasticity to dough. On the other hand, gluten makes the dough hard, which is not desirable for the chewy or moist texture mentioned above. Patent Document 4 describes a food quality improver produced by dispersing wheat protein in a solvent with a pH of 2.5 to 8.0 and heating at a temperature of 50 to 100°C for 2 hours to 30 days to partially denature the wheat protein, which gives food excellent extensibility.
複雑な又は熟練の技術を必要とすることなく、簡便な手順で、しっとり又はもちもちとした食感があり、歯切れがよく、口溶けに優れた食感を有する生地を製造することが望まれる。It is desirable to produce dough that has a moist or chewy texture, is crisp, and melts in the mouth easily, using simple procedures without requiring complex or skilled techniques.
本発明者は、予め加熱処理した小麦粉を水と混合し、次いで該混合物を加圧加熱処理して製造された組成物を、生地に配合することで、しっとり又はもちもちとした食感があり、歯切れがよく、かつ口溶けのよい食感を有する生地を製造できることを見出した。The inventors have discovered that by mixing previously heat-treated wheat flour with water and then pressurizing and heat-treating the mixture to produce a composition, and then incorporating this composition into dough, it is possible to produce a dough that has a moist or chewy texture, is crisp, and melts in the mouth easily.
したがって、本発明は、以下を提供する:
〔1〕熱処理小麦粉と水とを含む混合物を加圧加熱処理してなる、生地食品用組成物。
〔2〕前記熱処理小麦粉が湿熱処理小麦粉又は乾熱処理小麦粉である、〔1〕記載の組成物。
〔3〕グルテンバイタリティが0~30%である、〔1〕又は〔2〕記載の組成物。
〔4〕α化度が40~100%である、〔1〕~〔3〕のいずれか1項記載の組成物。
〔5〕熱処理小麦粉と水とを含む混合物を加圧加熱処理することを含む、生地食品用組成物の製造方法。
〔6〕前記熱処理小麦粉が湿熱処理小麦粉又は乾熱処理小麦粉である、〔5〕記載の方法。
〔7〕前記混合物が、前記熱処理小麦粉を含む原料100質量部と水50~200質量部との混合物である、〔5〕又は〔6〕記載の方法。
〔8〕前記加圧加熱処理が密閉下での50~200℃で5~120分間の加熱処理である、〔5〕~〔7〕のいずれか1項記載の方法。
〔9〕前記生地食品用組成物のグルテンバイタリティが0~30%である、〔5〕~〔8〕のいずれか1項記載の方法。
〔10〕前記生地食品用組成物のα化度が40~100%である、〔5〕~〔9〕のいずれか1項記載の方法。
〔11〕〔1〕~〔4〕のいずれか1項記載の生地食品用組成物又は〔5〕~〔10〕のいずれか1項記載の方法で製造した生地食品用組成物を含有する生地を調製することを含む、生地食品の製造方法。
〔12〕前記生地の全固形分中における前記生地食品用組成物の固形分量が2~50質量%である、〔11〕記載の方法。
〔13〕前記生地がさらに小麦粉を含む、〔11〕又は〔12〕記載の方法。
〔14〕さらに調製した前記生地を加熱することを含む、〔11〕~〔13〕のいずれか1項記載の方法。
〔15〕〔1〕~〔4〕のいずれか1項記載の生地食品用組成物又は〔5〕~〔10〕のいずれか1項記載の方法で製造した生地食品用組成物を含有する生地食品。
Thus, the present invention provides:
[1] A composition for dough foods, obtained by pressurizing and heating a mixture containing heat-treated wheat flour and water.
[2] The composition described in [1], wherein the heat-treated wheat flour is moist heat-treated wheat flour or dry heat-treated wheat flour.
[3] The composition described in [1] or [2], having a gluten vitality of 0 to 30%.
[4] The composition according to any one of [1] to [3], having a degree of gelatinization of 40 to 100%.
[5] A method for producing a composition for dough foods, comprising pressurizing and heating a mixture containing heat-treated wheat flour and water.
[6] The method according to [5], wherein the heat-treated wheat flour is moist heat-treated wheat flour or dry heat-treated wheat flour.
[7] The method according to [5] or [6], wherein the mixture is a mixture of 100 parts by mass of a raw material containing the heat-treated wheat flour and 50 to 200 parts by mass of water.
[8] The method according to any one of [5] to [7], wherein the pressurized and heated treatment is a heat treatment at 50 to 200° C. for 5 to 120 minutes in a sealed state.
[9] The method according to any one of [5] to [8], wherein the gluten vitality of the dough food composition is 0 to 30%.
[10] The method according to any one of [5] to [9], wherein the degree of gelatinization of the composition for dough foods is 40 to 100%.
[11] A method for producing a dough food, comprising preparing a dough containing a composition for dough foods described in any one of [1] to [4] or a composition for dough foods produced by the method described in any one of [5] to [10].
[12] The method described in [11], wherein the solid content of the composition for dough food is 2 to 50 mass% of the total solid content of the dough.
[13] The method described in [11] or [12], wherein the dough further contains wheat flour.
[14] The method according to any one of [11] to [13], further comprising heating the prepared dough.
[15] A dough food comprising the composition for dough foods according to any one of [1] to [4] or the composition for dough foods produced by the method according to any one of [5] to [10].
本発明によれば、しっとり又はもちもちとした食感があり、歯切れがよく、かつ口溶けのよい食感の生地を有する生地食品を、簡便な手順で製造することができる。例えば、本発明によれば、しっとりした食感があり、かつ歯切れと口溶けのよい食感を有するベーカリー食品を製造することができる。According to the present invention, a dough food having a moist or chewy texture, good bite and good melt-in-the-mouth texture can be produced by a simple procedure. For example, according to the present invention, a bakery food having a moist texture, good bite and good melt-in-the-mouth texture can be produced.
本明細書において、「生地食品」とは、穀粉を主体とする生地から製造される食品をいい、例えば、ベーカリー食品、麺類などが挙げられる。「ベーカリー食品」は、一般に、穀粉と副材料を含む生地を、必要に応じて発酵させた後、加熱調理(例えば、焼成、蒸し、揚げ等)することで製造される。ベーカリー食品の例としては、食パン(角型食パン、イギリスパン等)、ロールパン、菓子パン(あんパン、クリームパン等)、総菜パン(カレーパン等)、フランスパン、ドイツパン、クロワッサン、デニッシュ、イタリアパン、ワッフル、ナン、ピタパン等のパン;ピザ;中華まん及び蒸しパン;クッキー、クラッカー、ビスケット等の焼き菓子類、ドーナツ等の揚げ菓子類、などが挙げられる。また「麺類」は、一般に、穀粉を主体とする原料粉と水分を混捏して得られた生地を成形することで製造され、茹で、蒸しなどで調理されて喫食される。麺類の例としては、うどん、冷や麦、そば、中華麺、パスタ、麺皮類などが挙げられる。In this specification, "dough food" refers to food made from dough mainly made of cereal flour, and examples of such foods include bakery foods and noodles. "Bakery foods" are generally made by fermenting dough containing cereal flour and auxiliary ingredients as necessary, and then cooking the dough (for example, baking, steaming, frying, etc.). Examples of bakery foods include bread (square bread, English bread, etc.), roll bread, sweet bread (bean paste bread, cream bread, etc.), savory bread (curry bread, etc.), French bread, German bread, croissants, Danish pastries, Italian bread, waffles, naan, pita bread, etc.; pizza; Chinese buns and steamed bread; baked goods such as cookies, crackers, and biscuits; and fried goods such as donuts. "Noodles" are generally made by kneading raw material flour mainly made of cereal flour with water, shaping the resulting dough, and then boiling, steaming, or other cooking before eating. Examples of noodles include udon, hiyamugi, soba, Chinese noodles, pasta, and noodle skins.
本発明の生地食品用組成物は、ベーカリー食品、麺類などの生地食品の生地の製造に使用される組成物である。該生地食品用組成物を生地に配合することで、該生地にしっとり又はもちもちとした食感と、歯切れのよさ、及び口溶けのよい食感を付与することができる。好ましくは、本発明の生地食品用組成物は、ベーカリー食品の生地の製造に使用される。The dough food composition of the present invention is a composition used to produce dough for bakery foods, noodles, and other dough foods. By blending the dough food composition with dough, it is possible to impart a moist or chewy texture to the dough, as well as a crisp texture and a texture that melts in the mouth. Preferably, the dough food composition of the present invention is used to produce dough for bakery foods.
本発明の生地食品用組成物(以下、本発明の組成物ともいう)は、熱処理小麦粉と水とを含む混合物を加圧加熱処理することで製造することができる。すなわち、本発明の組成物は、小麦粉を加熱して熱処理小麦粉を得る第1の加熱処理と、該加熱処理後の小麦粉と水とを含む混合物を加圧加熱する第2の加熱処理とを経て製造される。これらの手順が、本発明の組成物に澱粉のα化、蛋白質の変性、グルテン網目状構造の変質等の性質を与えることで、本発明の効果をもたらすと推定される。The composition for dough foods of the present invention (hereinafter also referred to as the composition of the present invention) can be produced by pressurizing and heating a mixture containing heat-treated wheat flour and water. That is, the composition of the present invention is produced through a first heat treatment in which wheat flour is heated to obtain heat-treated wheat flour, and a second heat treatment in which the mixture containing the heat-treated wheat flour and water is pressurized and heated. It is presumed that these procedures impart properties such as gelatinization of starch, denaturation of protein, and alteration of the gluten network structure to the composition of the present invention, thereby bringing about the effects of the present invention.
本発明の組成物の製造に用いられる熱処理小麦粉の原料となる小麦粉は、食品製造に使用される小麦粉であればよく、例えば、強力小麦粉、準強力小麦粉、中力小麦粉、薄力小麦粉、全粒小麦粉、デュラム粉、及びこれらの2種以上の混合物が挙げられる。本発明の組成物に用いる小麦粉の種類は、該組成物を用いて製造する生地の種類によって異なり得る。例えばパン生地を製造する場合は中力小麦粉、薄力小麦粉、又はそれらの混合粉を使用することが好ましい。The wheat flour used as the raw material for the heat-treated wheat flour used in the production of the composition of the present invention may be any wheat flour used in food production, such as strong wheat flour, semi-strong wheat flour, medium wheat flour, weak wheat flour, whole wheat flour, durum flour, and mixtures of two or more of these. The type of wheat flour used in the composition of the present invention may vary depending on the type of dough produced using the composition. For example, when producing bread dough, it is preferable to use medium wheat flour, weak wheat flour, or a mixture of these flours.
熱処理小麦粉を得るための小麦粉の加熱処理(第1の加熱処理)の方法としては、湿熱処理及び乾熱処理のいずれも採用することができる。好ましくは、小麦粉が生地を形成しない、すなわち小麦粉中のグルテンが網目状構造を形成しない条件で加熱される。通常、小麦粉100質量部に対して40質量部以上の水を加えて混合すると、グルテンを構成するグルテニンとグリアジンが相互作用して網目状構造を形成する。そのため、本発明で用いる熱処理小麦粉は、好ましくは、原料小麦粉100質量部あたり40質量部未満の水を使用する湿熱処理か、又は乾熱処理で調製される。As a method for the heat treatment of wheat flour (first heat treatment) to obtain heat-treated wheat flour, either wet heat treatment or dry heat treatment can be adopted. Preferably, wheat flour is heated under conditions in which the flour does not form a dough, i.e., the gluten in the wheat flour does not form a mesh-like structure. Usually, when 40 parts by mass or more of water is added to 100 parts by mass of wheat flour and mixed, the glutenin and gliadin that constitute gluten interact with each other to form a mesh-like structure. Therefore, the heat-treated wheat flour used in the present invention is preferably prepared by wet heat treatment using less than 40 parts by mass of water per 100 parts by mass of raw wheat flour, or by dry heat treatment.
該湿熱処理の方法の例としては、小麦粉が生地を形成しない程度の量の水、好ましくは小麦粉100質量部に対し40質量部未満の水を、小麦粉に添加し加熱する方法;小麦粉に水蒸気を吹きかけながら加熱する方法、などが挙げられる。該湿熱処理のより具体的な例としては、小麦粉を高速撹拌機で攪拌しながら水を噴霧して加水し、撹拌機を加熱して機壁から伝達する熱で加熱する方法;小麦粉を撹拌機で攪拌しながら撹拌機内に高温の水蒸気を吹き込んで加熱処理する方法;エクストルーダーを用いて小麦粉と水とを加熱攪拌する方法;特開2009-34038号公報に記載の装置等を用いて飽和水蒸気雰囲気下で加熱処理する方法、などが挙げられる。生地の食感向上の観点から、該湿熱処理の条件は、温度が好ましくは50℃~300℃、より好ましくは60~240℃、さらに好ましくは100℃~220℃の範囲、時間が好ましくは10秒~2時間、より好ましくは1分~60分間、さらに好ましくは10分~30分間の範囲である。湿熱処理された小麦粉は、棚乾燥、熱風乾燥、流動層乾燥等の方法で乾燥処理して、粉末状にすることができる。湿熱処理によって小麦粉が造粒した場合等には、必要に応じて、乾燥後の小麦粉を適宜粉砕することができる。該粉砕には、ロール粉砕、ピンミル粉砕等の公知の粉砕手段を必要に応じて採用することができる。Examples of the moist heat treatment method include a method of adding water to wheat flour in an amount that does not cause the wheat flour to form a dough, preferably less than 40 parts by weight per 100 parts by weight of wheat flour, and heating the wheat flour while spraying steam onto it. More specific examples of the moist heat treatment include a method of adding water by spraying water onto wheat flour while stirring it with a high-speed mixer, heating the mixer and heating it with heat transmitted from the wall of the mixer; a method of blowing high-temperature steam into the mixer while stirring the wheat flour with the mixer; a method of heating and stirring wheat flour and water using an extruder; a method of heat treating in a saturated steam atmosphere using a device described in JP-A-2009-34038, etc. From the viewpoint of improving the texture of the dough, the conditions of the moist heat treatment are preferably a temperature of 50°C to 300°C, more preferably 60 to 240°C, and even more preferably 100°C to 220°C, and a time of preferably 10 seconds to 2 hours, more preferably 1 minute to 60 minutes, and even more preferably 10 minutes to 30 minutes. The wheat flour that has been subjected to the moist heat treatment can be dried to a powder form by a method such as shelf drying, hot air drying, or fluidized bed drying. When the wheat flour is granulated by the moist heat treatment, the wheat flour after drying can be appropriately pulverized as necessary. For the pulverization, a known pulverization method such as roll pulverization or pin mill pulverization can be used as necessary.
該乾熱処理の方法の例としては、小麦粉を開放系又は密閉系において熱風、赤外線、放射熱等により加熱する方法などが挙げられる。該乾熱処理のより具体的な例としては、小麦粉を撹拌機で攪拌しながら、撹拌機を加熱して機壁から伝達する熱で加熱する方法;小麦粉を転動槽で攪拌しながら、転動槽に熱風を吹き込んで加熱処理する方法;エクストルーダーを用いて小麦粉を加熱攪拌する方法、などが挙げられる。生地の食感向上の観点から、該乾熱処理の条件は、温度が好ましくは50℃~300℃、より好ましくは60~240℃、さらに好ましくは100℃~220℃の範囲、時間が好ましくは10秒~2時間、より好ましくは1分~60分間、さらに好ましくは10分~30分間の範囲である。Examples of the dry heat treatment method include a method of heating wheat flour in an open or closed system with hot air, infrared rays, radiant heat, etc. More specific examples of the dry heat treatment include a method of heating wheat flour with heat transferred from the wall of a stirrer by heating the stirrer while stirring the wheat flour in the stirrer; a method of blowing hot air into a rotating tank while stirring the wheat flour in the rotating tank; a method of heating and stirring wheat flour using an extruder, etc. From the viewpoint of improving the texture of the dough, the conditions of the dry heat treatment are preferably a temperature in the range of 50°C to 300°C, more preferably 60 to 240°C, and even more preferably 100°C to 220°C, and a time in the range of preferably 10 seconds to 2 hours, more preferably 1 minute to 60 minutes, and even more preferably 10 minutes to 30 minutes.
次いで、得られた熱処理小麦粉と水とを含む混合物を加圧加熱処理する(第2の加熱処理)。該加圧加熱処理される混合物は、該熱処理小麦粉以外に、必要に応じて、生地食品に配合できる他の原料を含有することができる。当該他の原料としては、砂糖、ブドウ糖、果糖、転化糖、水あめ、麦芽糖、乳糖等の糖類;卵又は卵粉;グルテン、卵白粉等の蛋白質類;該熱処理小麦粉以外の穀粉類;加工もしくは未加工の澱粉類;脱脂粉乳、全脂粉乳、チーズ粉末、ホエー粉末等の乳製品;ショートニング、バター、マーガリン、その他の動植物油等の油脂類;乳化剤、膨張剤、増粘剤、甘味料、香料、着色料、アスコルビン酸等の添加剤;食塩等の無機塩類;グルコシダーゼ、グルコースオキシダーゼ、アミラーゼ、リパーゼ、ヘミセルラーゼ等の酵素類;食物繊維、などから選択されるいずれか1種又はいずれか2種以上を使用することができる。当該他の原料は、合計で、加熱処理小麦粉100質量部あたり150質量部以下、好ましくは100質量部以下の量で使用することができる。Next, the mixture containing the heat-treated wheat flour and water is pressurized and heated (second heat treatment). The mixture to be pressurized and heated can contain, in addition to the heat-treated wheat flour, other ingredients that can be incorporated into dough foods, as necessary. The other ingredients can be any one or more of the following: sugars such as sugar, glucose, fructose, invert sugar, starch syrup, maltose, lactose, etc.; eggs or egg powder; proteins such as gluten and egg white powder; grain flours other than the heat-treated wheat flour; processed or unprocessed starches; dairy products such as skim milk powder, whole milk powder, cheese powder, and whey powder; fats and oils such as shortening, butter, margarine, and other animal and vegetable oils; additives such as emulsifiers, leavening agents, thickeners, sweeteners, flavorings, colorants, and ascorbic acid; inorganic salts such as salt; enzymes such as glucosidase, glucose oxidase, amylase, lipase, and hemicellulase; and dietary fiber. The other ingredients can be used in a total amount of 150 parts by mass or less, preferably 100 parts by mass or less, per 100 parts by mass of the heat-treated wheat flour.
該加熱処理小麦粉及び必要に応じて該他の原料を含む原料を、水と混合し、混合物を調製する。該水としては、清水、精製水等の食用に供される水であれば制限なく使用することができる。該混合物の調製に用いる水の量は、該加熱処理小麦粉を含む原料(該加熱処理小麦粉及び該他の原料の合計量)100質量部あたり、好ましくは50~200質量部、より好ましくは60~160質量部である。水温は、常温(例えば10℃~40℃)であればよい。該原料と水との混合は、10℃~40℃の常温付近で該原料と水が略均一に分散するように混合すればよく、過度に混合攪拌や混捏をする必要はない。該混合により略均一な混合物が調製される。好ましくは、該混合物はペースト状である。The heat-treated wheat flour and, if necessary, the other ingredients are mixed with water to prepare a mixture. As the water, any water for consumption, such as clean water or purified water, can be used without restrictions. The amount of water used to prepare the mixture is preferably 50 to 200 parts by mass, more preferably 60 to 160 parts by mass, per 100 parts by mass of the heat-treated wheat flour-containing ingredients (the total amount of the heat-treated wheat flour and the other ingredients). The water temperature may be room temperature (e.g., 10°C to 40°C). The ingredients and water may be mixed at room temperature of 10°C to 40°C so that the ingredients and water are approximately uniformly dispersed, and there is no need to mix, stir or knead excessively. A substantially uniform mixture is prepared by the mixing. Preferably, the mixture is in the form of a paste.
得られた混合物を加圧加熱処理する方法としては、例えば、該混合物を密閉下、例えば耐圧性の密閉容器内で、加熱する方法が挙げられる。生地の食感向上の観点から、該加圧加熱処理の温度条件は、好ましくは50℃~200℃、より好ましくは105℃~150℃、さらに好ましくは120℃~140℃であり、時間の条件は、好ましくは5分~120分間、より好ましくは10分~90分間、さらに好ましくは10分~30分間である。該加圧加熱処理後の混合物は、必要に応じて冷却した後、本発明の生地食品用組成物として用いることができる。本発明の組成物は、該加圧加熱処理後はペースト状である。あるいは、該組成物をさらに脱水又は乾燥して、固形状、顆粒状又は粉末状の組成物を調製してもよい。該組成物を乾燥する際は、50℃以上の熱がかからないようにすることが好ましい。 The method of subjecting the obtained mixture to pressure heating treatment includes, for example, a method of heating the mixture in a sealed state, for example, in a pressure-resistant sealed container. From the viewpoint of improving the texture of the dough, the temperature condition of the pressure heating treatment is preferably 50°C to 200°C, more preferably 105°C to 150°C, and even more preferably 120°C to 140°C, and the time condition is preferably 5 minutes to 120 minutes, more preferably 10 minutes to 90 minutes, and even more preferably 10 minutes to 30 minutes. The mixture after the pressure heating treatment can be used as the dough food composition of the present invention after cooling as necessary. The composition of the present invention is in a paste form after the pressure heating treatment. Alternatively, the composition may be further dehydrated or dried to prepare a solid, granular or powdered composition. When drying the composition, it is preferable to avoid applying heat of 50°C or more.
本発明の組成物は、グルテンバイタリティ(以下、GVということがある)が、好ましくは0~40%、より好ましくは0~30%、さらに好ましくは0~20%である。本発明の組成物のGVがこの範囲であると、生地の食感向上の点で好ましい。GVは、小麦粉等の原料に含まれる蛋白質の性質を表す指標であり、該原料における蛋白質の含有量とは異なる。小麦粉の一般的なGVは50~60%である。本発明の組成物のGVは、該組成物を凍結乾燥して乾固後、粉砕した粉(以下、粉砕粉)を用いて、以下の手順で測定することができる。The gluten vitality (hereinafter sometimes referred to as GV) of the composition of the present invention is preferably 0-40%, more preferably 0-30%, and even more preferably 0-20%. Having the GV of the composition of the present invention in this range is preferable in terms of improving the texture of the dough. GV is an index that represents the properties of the protein contained in raw materials such as wheat flour, and is different from the protein content of the raw material. The general GV of wheat flour is 50-60%. The GV of the composition of the present invention can be measured by freeze-drying the composition to dryness, and then using the powder obtained by pulverizing the composition (hereinafter referred to as pulverized powder) according to the following procedure.
〔GVの測定法〕
1)粉砕粉の可溶性粗蛋白質含量の測定:
(a)100mL容のビーカーに粉砕粉を2g精秤して入れる。
(b)上記のビーカーに0.05規定酢酸40mLを加えて、室温で60分間攪拌して懸濁液を調製する。
(c)上記(b)で得た懸濁液を遠沈管に移して、5000rpmで5分間遠心分離を行った後、濾紙を用いて濾過し、濾液を回収する。
(d)上記で用いたビーカーを0.05規定酢酸40mLで洗って洗液を遠沈管に移して、5000rpmで5分間遠心分離を行った後、濾紙を用いて濾過し、濾液を回収する。
(e)上記(c)及び(d)で回収した濾液を一緒にして100mLにメスアップする。
(f)ティケーター社(スウェーデン)のケルテックオートシステムのケルダールチューブに上記(e)で得られた液体の25mLをホールピペットで入れて、分解促進剤(日本ゼネラル株式会社製「ケルタブC」;硫酸カリウム:硫酸銅=9:1(重量比))1錠及び濃硫酸15mLを加える。
(g)上記したケルテックオートシステムに組み込まれているケルテック分解炉(DIGESTION SYSTEM 20 1015型)を用いて、ダイヤル4で1時間分解処理を行い、更にダイヤル9又は10で1時間分解処理を自動的に行った後、この分解処理に続いて連続的にかつ自動的に、同じケルテックオートシステムに組み込まれているケルテック蒸留滴定システム(KJELTEC AUTO 1030型)を用いて、その分解処理を行った液体を蒸留及び滴定して(滴定には0.1規定硫酸を使用)、下記の数式1により、粉砕粉の可溶性粗蛋白質含量を求める。
(数式1)可溶性粗蛋白質含量(%)
=0.14×T×F×N×(100/S)×(1/25)
式中、
T=滴定に要した0.1規定硫酸の量(mL)
F=滴定に用いた0.1規定硫酸の力価(用時に測定するか又は力価の表示のある市販品を用いる)
N=窒素蛋白質換算係数(5.70)
S=粉砕粉の秤取量(g)
2)粉砕粉の全粗蛋白質含量の測定:
(a)上記1)で用いたのと同じティケーター社のケルテックオートシステムのケルダールチューブに、粉砕粉を0.5g精秤して入れ、これに上記1)の(f)で用いたのと同じ分解促進剤1錠及び濃硫酸5mLを加える。
(b)上記1)で用いたのと同じケルテックオートシステムのケルテック分解炉を用いて、ダイヤル9又は10で1時間分解処理を行った後、この分解処理に続いて連続的にかつ自動的に、同じケルテックオートシステムに組み込まれている上記1)で用いたのと同じケルテック蒸留滴定システムを用いて、上記で分解処理を行った液体を蒸留及び滴定して(滴定には0.1規定硫酸を使用)、下記の数式2により、粉砕粉の全粗蛋白質含量を求める。
(数式2)全粗蛋白質含量(%)=(0.14×T×F×N)/S
式中、
T=滴定に要した0.1規定硫酸の量(mL)
F=滴定に用いた0.1規定硫酸の力価(用時に測定)
N=窒素蛋白質換算係数(5.70)
S=粉砕粉の秤取量(g)
3)GVの算出:
上記1)で求めた粉砕粉の可溶性粗蛋白質含量及び上記2)で求めた粉砕粉の全粗蛋白質含量から、下記の数式3により、粉砕粉のGVを求める。
(数式3)GV(%)=(可溶性粗蛋白質含量/全粗蛋白質含量)×100
[Method of measuring GV]
1) Measurement of soluble crude protein content of ground flour:
(a) 2 g of pulverized powder is weighed out and placed in a 100 mL beaker.
(b) Add 40 mL of 0.05 N acetic acid to the beaker and stir at room temperature for 60 minutes to prepare a suspension.
(c) The suspension obtained in (b) above is transferred to a centrifuge tube and centrifuged at 5,000 rpm for 5 minutes, and then filtered using filter paper to recover the filtrate.
(d) The beaker used above is washed with 40 mL of 0.05 N acetic acid, the washings are transferred to a centrifuge tube, and centrifuged at 5,000 rpm for 5 minutes, after which it is filtered using filter paper to recover the filtrate.
(e) The filtrates collected in (c) and (d) above are combined and the resulting solution is adjusted to 100 mL.
(f) 25 mL of the liquid obtained in (e) above is placed in a Kjeldahl tube of a Kjeldahl Autosystem manufactured by Tickator (Sweden) using a volumetric pipette, and one tablet of a decomposition accelerator ("Keltab C" manufactured by Nippon General Co., Ltd.; potassium sulfate:copper sulfate = 9:1 (weight ratio)) and 15 mL of concentrated sulfuric acid are added.
(g) Using a Keltec decomposition furnace (DIGESTION SYSTEM 20 1015 type) incorporated in the above-mentioned Keltec auto system, decomposition treatment is performed for 1 hour at dial 4, and then decomposition treatment is automatically performed for another 1 hour at dial 9 or 10. Then, following this decomposition treatment, the liquid from the decomposition treatment is continuously and automatically distilled and titrated (using 0.1 N sulfuric acid for titration) using a Keltec distillation and titration system (KJELTEC AUTO 1030 type) incorporated in the same Keltec auto system to determine the soluble crude protein content of the pulverized powder using the following mathematical formula 1.
(Formula 1) Soluble crude protein content (%)
=0.14×T×F×N×(100/S)×(1/25)
In the formula,
T = Amount of 0.1 N sulfuric acid required for titration (mL)
F = titer of 0.1 N sulfuric acid used in titration (measure when used or use a commercially available product with a titer indicated)
N = nitrogen protein conversion factor (5.70)
S = weight of ground powder (g)
2) Determination of total crude protein content of ground flour:
(a) 0.5 g of the pulverized powder is weighed out and placed in a Kjeldahl tube of the same Ticator Keltec Autosystem as used in 1) above, and one tablet of the same decomposition accelerator as used in 1) (f) above and 5 mL of concentrated sulfuric acid are added thereto.
(b) Using the same Keltec decomposition furnace of the Keltec auto system used in 1) above, decomposition treatment is carried out for 1 hour at dial 9 or 10, and then, following this decomposition treatment, the liquid subjected to the above decomposition treatment is continuously and automatically distilled and titrated (0.1 N sulfuric acid is used for titration) using the same Keltec distillation and titration system used in 1) above, which is incorporated into the same Keltec auto system, to determine the total crude protein content of the pulverized powder using the following mathematical formula 2.
(Formula 2) Total crude protein content (%) = (0.14 x T x F x N) / S
In the formula,
T = Amount of 0.1 N sulfuric acid required for titration (mL)
F = Titer of 0.1 N sulfuric acid used in titration (measured at the time of use)
N = nitrogen protein conversion factor (5.70)
S = weight of ground powder (g)
3) Calculation of GV:
The GV of the pulverized powder is calculated from the soluble crude protein content of the pulverized powder calculated in 1) above and the total crude protein content of the pulverized powder calculated in 2) above, using the following formula 3.
(Formula 3) GV (%) = (Soluble crude protein content/Total crude protein content) x 100
本発明の組成物は、α化度が好ましくは40~100%、より好ましくは50~100%の範囲である。本発明の組成物のα化度がこの範囲であると、生地の食感向上の点で好ましい。本発明の組成物のα化度は、BAP法(β-アミラーゼ・プルラナーゼ法)で測定されたα化度をいう。BAP法の手順は、「澱粉化学 第28巻第4号p235~240(1981)」等に記載された公知の方法を採用することができる。例えば、本発明の組成物のα化度は、該組成物の粉砕粉を用いて、以下の手順で測定することができる。The degree of gelatinization of the composition of the present invention is preferably in the range of 40 to 100%, more preferably 50 to 100%. If the degree of gelatinization of the composition of the present invention is in this range, it is preferable in terms of improving the texture of the dough. The degree of gelatinization of the composition of the present invention refers to the degree of gelatinization measured by the BAP method (β-amylase-pullulanase method). The procedure of the BAP method can be a known method described in "Starch Chemistry, Vol. 28, No. 4, pp. 235-240 (1981)" or the like. For example, the degree of gelatinization of the composition of the present invention can be measured using a pulverized powder of the composition by the following procedure.
〔BAP法によるα化度の測定法〕
1)試薬
使用する試薬は、以下の通りである。
(a)0.8M酢酸-酢酸Na緩衝液
(b)10N水酸化ナトリウム溶液
(c)2N酢酸溶液
(d)酵素溶液:β-アミラーゼ(ナガセ生化学工業(株)#1500)0.017g及びプルラナーゼ(林原生物化学研究所、No.31001)0.17gを上記0.8M酢酸-酢酸Na緩衝液に溶かして100mLとしたもの
(e)失活酵素溶液:上記酵素溶液を10分間煮沸させて調製
(f)ソモギー試薬およびネルソン試薬(還元糖量の測定用試薬)
2)測定方法
(a)本発明の組成物をホモジナイザーで粉砕し、100メッシュ以下とする。得られた粉砕粉0.08~0.10gをガラスホモジナイザーに取る。
(b)これに脱塩水8.0mLを加え、ガラスホモジナイザーを10~20回上下させて分散を行う。
(c)2本の25mL容目盛り付き試験管に上記(b)の分散液を2mLずつとり、1本は0.8M酢酸-酢酸Na緩衝液で定容し、試験区とする。
(d)他の1本には、10N水酸化ナトリウム溶液0.2mLを添加し、50℃で3~5分間反応させ、完全に糊化させる。その後、2N酢酸溶液1.0mLを添加し、pHを6.0付近に調整した後、0.8M酢酸-酢酸Na緩衝液で定容し、糊化区とする。
(e)上記(c)及び(d)で調製した試験区および糊化区の試験液をそれぞれ0.4mLとり、それぞれに酵素溶液0.1mLを加えて、40℃で30分間酵素反応させる。同時に、ブランクとして、酵素溶液の代わりに失活酵素溶液0.1mLを加えたものも調製する。酵素反応は途中で反応液を時々攪拌させながら行う。
(f)上記反応済液0.5mLにソモギー試薬0.5mLを添加し、沸騰浴中で15分間煮沸する。煮沸後、流水中で5分間冷却した後、ネルソン試薬1.0mLを添加・攪拌し、15分間放置する。
(g)その後、脱塩水8.00mLを加えて攪拌し、500nmの吸光度を測定する。
3)α化度の算出
下記の数式によりα化度を算出する。
α化度(%)=(試験溶液の分解率)/(完全糊化試験溶液の分解率)×100
=(A-a)/(A’-a’)×100
式中、
A=試験区の吸光度
A’=糊化区の吸光度
a=試験区のブランクの吸光度
a’=糊化区のブランクの吸光度
[Measurement method of gelatinization degree by BAP method]
1) Reagents The reagents used are as follows:
(a) 0.8M acetic acid-Na acetate buffer; (b) 10N sodium hydroxide solution; (c) 2N acetic acid solution; (d) enzyme solution: 0.017 g of β-amylase (Nagase Biochemical Industries, Ltd., #1500) and 0.17 g of pullulanase (Hayashibara Biochemical Laboratories, No. 31001) were dissolved in the above 0.8M acetic acid-Na acetate buffer to make 100 mL; (e) inactivated enzyme solution: prepared by boiling the above enzyme solution for 10 minutes; (f) Somogyi and Nelson reagents (reagents for measuring the amount of reducing sugars)
2) Measurement method (a) The composition of the present invention is pulverized in a homogenizer to a size of 100 mesh or less, and 0.08 to 0.10 g of the pulverized powder obtained is placed in a glass homogenizer.
(b) 8.0 mL of demineralized water is added to this, and the glass homogenizer is moved up and down 10 to 20 times to disperse the mixture.
(c) Put 2 mL of the dispersion liquid from (b) into two 25 mL graduated test tubes, and dilute one of the tubes to the volume with 0.8 M acetic acid-Na acetate buffer to use as a test group.
(d) To the other tube, 0.2 mL of 10N sodium hydroxide solution is added, and the mixture is allowed to react at 50°C for 3 to 5 minutes to completely gelatinize it. After that, 1.0 mL of 2N acetic acid solution is added to adjust the pH to around 6.0, and then the volume is adjusted to the constant level with 0.8M acetic acid-Na acetate buffer to give the gelatinized section.
(e) Take 0.4 mL of each of the test solutions prepared in (c) and (d) above for the test group and the gelatinized group, add 0.1 mL of enzyme solution to each solution, and perform the enzyme reaction at 40° C. for 30 minutes. At the same time, prepare a blank by adding 0.1 mL of inactivated enzyme solution instead of the enzyme solution. The enzyme reaction is performed while occasionally stirring the reaction solution during the reaction.
(f) Add 0.5 mL of Somogyi reagent to 0.5 mL of the above-mentioned reaction solution, boil in a boiling bath for 15 minutes, cool in running water for 5 minutes, add 1.0 mL of Nelson's reagent, stir, and leave for 15 minutes.
(g) Then, 8.00 mL of demineralized water is added and stirred, and the absorbance at 500 nm is measured.
3) Calculation of degree of gelatinization The degree of gelatinization is calculated using the following formula.
Degree of gelatinization (%)=(decomposition rate of test solution)/(decomposition rate of completely gelatinized test solution)×100
=(A-a)/(A'-a')×100
In the formula,
A = Absorbance of the test area A' = Absorbance of the gelatinized area a = Absorbance of the blank of the test area a' = Absorbance of the blank of the gelatinized area
本発明の組成物は、ベーカリー食品、麺類などの食品用の生地の製造に用いることができる。本発明の組成物を生地原料の一部として用いることで、しっとり又はもちもちとした食感があり、歯切れがよく、かつ口溶けのよい食感を有する生地を製造することができる。例えば、生地原料(例えば穀粉及び副原料)に本発明の組成物、及び必要に応じて水分を添加し、混捏して生地を製造することができる。あるいは、原料と水分を混捏して中間生地を製造し、これに本発明の用組成物を添加し、さらに混捏して生地を製造してもよい。好ましくは、本発明の組成物を予め混捏してほぐしておき、ここに残りの生地原料を加え、混捏しながら必要に応じて水分を添加して生地を製造すると、本発明の組成物が生地中によく分散して、本発明の組成物による生地の食感向上効果がよりよく発揮され得る。The composition of the present invention can be used to produce dough for foods such as bakery foods and noodles. By using the composition of the present invention as a part of the dough ingredients, it is possible to produce dough that has a moist or chewy texture, is crisp, and melts in the mouth. For example, the composition of the present invention and, if necessary, water can be added to the dough ingredients (e.g., grain flour and auxiliary ingredients), and the dough can be produced by kneading. Alternatively, the ingredients and water can be kneaded to produce an intermediate dough, to which the composition of the present invention can be added, and the dough can be produced by further kneading. Preferably, the composition of the present invention is kneaded and loosened in advance, the remaining dough ingredients are added, and water is added as necessary while kneading to produce the dough, so that the composition of the present invention can be well dispersed in the dough, and the texture improving effect of the composition of the present invention can be better exhibited.
該生地原料に含まれる穀粉としては、小麦粉、ライ麦粉、大麦粉、コーンフラワー、米粉、及びこれらの2種以上の混合物が挙げられる。これらの穀粉は、非加熱処理粉であっても、又は加熱処理粉であってもよい。該穀粉は、好ましくは小麦粉であり、より好ましくは非加熱処理小麦粉である。該小麦粉としては、食品製造に通常用いる小麦粉、例えば、強力小麦粉、準強力小麦粉、中力小麦粉、薄力小麦粉、全粒小麦粉、デュラム粉、及びこれらの2種以上の混合物が挙げられる。該生地原料に用いる小麦粉の種類は、製造する生地の種類によって異なり得る。例えばパン生地を製造する場合は強力小麦粉、準強力小麦粉、又はそれらの混合粉を使用することが好ましい。Examples of flours contained in the dough ingredients include wheat flour, rye flour, barley flour, corn flour, rice flour, and mixtures of two or more of these. These flours may be unheated or heat-treated. The flour is preferably wheat flour, and more preferably unheated. Examples of the flour include wheat flours commonly used in food production, such as strong wheat flour, semi-strong wheat flour, medium-strength wheat flour, weak wheat flour, whole wheat wheat flour, durum flour, and mixtures of two or more of these. The type of flour used in the dough ingredients may vary depending on the type of dough to be produced. For example, when producing bread dough, it is preferable to use strong wheat flour, semi-strong wheat flour, or a mixture thereof.
該生地原料に含まれる副原料としては、ベーカリー食品又は麺類の生地の製造に通常用いられる副原料、例えばイースト(生イースト、ドライイースト等);イーストフード;ベーキングパウダー;砂糖、ブドウ糖、果糖、転化糖、糖アルコール、水あめ、麦芽糖、乳糖等の糖類;卵または卵粉;グルテン、卵白粉等の蛋白質類;加工もしくは未加工の澱粉類;デキストリン;脱脂粉乳、全脂粉乳、チーズ粉末、ホエー粉末等の乳製品;ショートニング、バター、マーガリン、その他の動植物油等の油脂類;乳化剤、膨張剤、増粘剤、甘味料、香料、着色料、アスコルビン酸等の添加剤;食塩等の無機塩類;グルコシダーゼ、グルコースオキシダーゼ、アミラーゼ、リパーゼ、ヘミセルラーゼ等の酵素類;食物繊維、などから選択されるいずれか1種又はいずれか2種以上を使用することができる。生地の製造に用いる水分としては、清水、精製水等の食用に供される水、乳、果汁などが挙げられる。The auxiliary ingredients contained in the dough ingredients can be any one or more of the auxiliary ingredients commonly used in the production of bakery food or noodle dough, such as yeast (fresh yeast, dry yeast, etc.); yeast food; baking powder; sugars such as sugar, glucose, fructose, invert sugar, sugar alcohol, starch syrup, maltose, lactose, etc.; eggs or egg powder; proteins such as gluten and egg white powder; processed or unprocessed starches; dextrin; dairy products such as skim milk powder, whole milk powder, cheese powder, whey powder, etc.; fats and oils such as shortening, butter, margarine, and other animal and vegetable oils; additives such as emulsifiers, leavening agents, thickeners, sweeteners, flavorings, colorants, and ascorbic acid; inorganic salts such as salt; enzymes such as glucosidase, glucose oxidase, amylase, lipase, and hemicellulase; and dietary fiber. Examples of water used in the production of dough include edible water such as pure water and purified water, milk, and fruit juice.
該生地原料における本発明の組成物の含有量は、製造する生地の種類によって異なり得る。例えば、最終的に製造した生地の全固形分中における本発明の組成物の固形分量が、好ましくは2~50質量%、より好ましくは3~40質量%、さらに好ましくは4~30質量%であればよい。該生地原料における該穀粉及び副原料の含有量もまた、製造する生地の種類によって異なり得る。例えば、穀粉の含有量は、最終的に製造した生地の全固形分中、20~95質量%であればよい。The content of the composition of the present invention in the dough ingredients may vary depending on the type of dough to be produced. For example, the solid content of the composition of the present invention in the total solid content of the final dough produced may be preferably 2 to 50 mass%, more preferably 3 to 40 mass%, and even more preferably 4 to 30 mass%. The content of the flour and auxiliary ingredients in the dough ingredients may also vary depending on the type of dough to be produced. For example, the content of flour may be 20 to 95 mass% of the total solid content of the final dough produced.
本発明の組成物を含む生地から、ベーカリー食品、麺類などの生地食品を製造することができる。本発明による生地食品の製造方法は、本発明の組成物を含む生地を調製すること以外は、該生地食品の通常の製法に従って実施することができる。Dough foods such as bakery foods and noodles can be produced from dough containing the composition of the present invention. The method for producing dough foods according to the present invention can be carried out according to a conventional method for producing such dough foods, except for preparing dough containing the composition of the present invention.
一例において、本発明によるベーカリー食品の製造は、ストレート法、中種法、速成法、液種法、冷凍生地法等の各種常法に従って行うことができる。例えば中種法の場合、本発明の組成物は中種、本捏のどちらの段階で添加してもよいが、本捏の段階で添加することが好ましい。次いで、本発明の組成物を配合したベーカリー食品生地を、必要に応じて発酵させ、さらに常法により成形して、その後加熱することで、ベーカリー食品を製造することができる。該加熱の方法としては、焼成、蒸し、揚げ(油ちょう)等が挙げられる。あるいは、本発明では、得られたベーカリー食品生地を、そのまま、又は発酵もしくは成形した状態で冷蔵又は冷凍保存し、必要に応じて解凍及び加熱してベーカリー食品を製造してもよい。In one example, the bakery food according to the present invention can be produced according to various conventional methods such as the straight dough method, sponge dough method, quick dough method, liquid dough method, and frozen dough method. For example, in the case of the sponge dough method, the composition of the present invention may be added at either the sponge dough stage or the main kneading stage, but it is preferable to add it at the main kneading stage. Next, the bakery food dough containing the composition of the present invention is fermented as necessary, further shaped by a conventional method, and then heated to produce the bakery food. Examples of the heating method include baking, steaming, and frying (deep-frying). Alternatively, in the present invention, the obtained bakery food dough may be refrigerated or frozen as it is or in a fermented or shaped state, and thawed and heated as necessary to produce the bakery food.
別の一例において、本発明による麺類の製造は、ロール製麺法、押出製麺法等の各種常法に従って行うことができる。得られた生麺類は、そのまま調理してもよく、又は冷蔵もしくは冷凍保存してもよい。あるいは、生麺類を調理した後、冷蔵もしくは冷凍保存してもよい。あるいは、得られた生麺類を常法により乾燥させ、乾麺を製造してもよい。In another example, the noodles according to the present invention can be produced according to various conventional methods such as a roll noodle production method or an extrusion noodle production method. The obtained fresh noodles may be cooked as is, or may be stored refrigerated or frozen. Alternatively, the fresh noodles may be cooked and then stored refrigerated or frozen. Alternatively, the obtained fresh noodles may be dried according to a conventional method to produce dried noodles.
以下に、実施例を示して本発明をさらに詳細に説明するが、本発明は以下の実施例に限定されるものではない。The present invention will be described in more detail below with reference to examples, but the present invention is not limited to the following examples.
(製造例1)ベーカリー食品用組成物の製造
薄力小麦粉(日清フーズ製)100質量部に20質量部の水を添加し、エクストルーダーにフィードして50℃、20分間攪拌して湿熱処理小麦粉を調製した。得られた湿熱処理小麦粉を冷却した後、該湿熱処理小麦粉100質量部に対して水(約25℃)100質量部を添加し、攪拌して混合物を調製した。該混合物を耐熱性のアルミパウチに入れ、脱気して密封後、レトルト釜に入れて120℃、15分間加圧加熱処理した。加圧加熱後のパウチを放熱した後、そこから中身を取り出し、ベーカリー食品用組成物とした。得られたベーカリー食品用組成物の一部を取り、グルテンバイタリティ(GV)及びα化度を測定した。その結果を表1に示す。
(Production Example 1) Production of a composition for bakery foods 20 parts by mass of water was added to 100 parts by mass of weak wheat flour (manufactured by Nisshin Foods), and the mixture was fed to an extruder and stirred at 50°C for 20 minutes to prepare moist heat-treated wheat flour. After cooling the obtained moist heat-treated wheat flour, 100 parts by mass of water (about 25°C) was added to 100 parts by mass of the moist heat-treated wheat flour, and the mixture was stirred to prepare a mixture. The mixture was placed in a heat-resistant aluminum pouch, degassed and sealed, then placed in a retort oven and pressurized and heated at 120°C for 15 minutes. After the pouch was cooled after pressurization and heating, the contents were removed from it to prepare a composition for bakery foods. A portion of the obtained composition for bakery foods was taken and the gluten vitality (GV) and degree of gelatinization were measured. The results are shown in Table 1.
(製造例2~11)ベーカリー食品用組成物の製造
湿熱処理の条件又は加圧加熱処理の条件を表1のように変更した以外は、製造例1と同様の手順でベーカリー食品用組成物を製造した。得られたベーカリー食品用組成物の一部を取り、GV及びα化度を測定した。その結果を表1に示す。
(Production Examples 2 to 11) Production of bakery food compositions Bakery food compositions were produced in the same manner as in Production Example 1, except that the conditions for the moist heat treatment or the pressure-heat treatment were changed as shown in Table 1. A portion of the obtained bakery food compositions was taken and the GV and degree of gelatinization were measured. The results are shown in Table 1.
(比較例1~2)
薄力小麦粉(日清フーズ製;比較例1)又は強力小麦粉(日清フーズ製;比較例2)100質量部に20質量部の水を添加し、エクストルーダーにフィードして160℃、20分間攪拌して湿熱処理小麦粉を調製した。得られた湿熱処理小麦粉を冷却した後、該湿熱処理小麦粉100質量部に対して水(約25℃)100質量部を添加して攪拌し、得られた混合物をベーカリー食品用組成物とした。得られたベーカリー食品用組成物の一部を取り、GV及びα化度を測定した。その結果を表1に示す。
(Comparative Examples 1 to 2)
20 parts by mass of water was added to 100 parts by mass of weak wheat flour (manufactured by Nisshin Foods; Comparative Example 1) or strong wheat flour (manufactured by Nisshin Foods; Comparative Example 2), fed into an extruder, and stirred at 160°C for 20 minutes to prepare moist heat treated wheat flour. After cooling the obtained moist heat treated wheat flour, 100 parts by mass of water (about 25°C) was added to 100 parts by mass of the moist heat treated wheat flour and stirred, and the resulting mixture was used as a bakery food composition. A portion of the obtained bakery food composition was taken and the GV and degree of gelatinization were measured. The results are shown in Table 1.
(製造例12)ベーカリー食品用組成物の製造
薄力小麦粉(日清フーズ製)100質量部に水を添加せず、エクストルーダーにフィードして50℃、20分間攪拌して乾熱処理小麦粉を調製した。得られた乾熱処理小麦粉を冷却した後、該乾熱処理小麦粉100質量部に対して水(約25℃)100質量部を添加し、攪拌して混合物を調製した。該混合物を耐熱性のアルミパウチに入れ、脱気して密封後、レトルト釜に入れて120℃、15分間加圧加熱処理した。加圧加熱後のパウチを放熱した後、そこから中身を取り出し、ベーカリー食品用組成物とした。得られたベーカリー食品用組成物の一部を取り、GV及びα化度を測定した。その結果を表2に示す。
(Production Example 12) Production of a composition for bakery foods 100 parts by mass of weak wheat flour (manufactured by Nisshin Foods) was fed to an extruder without adding water, and stirred at 50 ° C for 20 minutes to prepare dry heat-treated wheat flour. After cooling the obtained dry heat-treated wheat flour, 100 parts by mass of water (about 25 ° C) was added to 100 parts by mass of the dry heat-treated wheat flour, and the mixture was stirred to prepare a mixture. The mixture was placed in a heat-resistant aluminum pouch, degassed and sealed, then placed in a retort oven and pressurized and heated at 120 ° C for 15 minutes. After the pouch was cooled after pressurization and heating, the contents were removed from it to prepare a composition for bakery foods. A portion of the obtained composition for bakery foods was taken, and the GV and degree of gelatinization were measured. The results are shown in Table 2.
(製造例13~22)ベーカリー食品用組成物の製造
乾熱処理の条件又は加圧加熱処理の条件を表2のように変更した以外は、製造例12と同様の手順でベーカリー食品用組成物を製造した。得られたベーカリー食品用組成物の一部を取り、GV及びα化度を測定した。その結果を表2に示す。
(Production Examples 13 to 22) Production of compositions for bakery foods Compositions for bakery foods were produced in the same manner as in Production Example 12, except that the conditions for the dry heat treatment or the conditions for the pressurized heat treatment were changed as shown in Table 2. A portion of the obtained compositions for bakery foods was taken and the GV and degree of gelatinization were measured. The results are shown in Table 2.
(比較例3)
薄力小麦粉(日清フーズ製)100質量部に水を添加せず、エクストルーダーにフィードして160℃、20分間攪拌して乾熱処理小麦粉を調製した。得られた乾熱処理小麦粉を冷却した後、該乾熱処理小麦粉100質量部に対して水(約25℃)100質量部を添加して攪拌し、得られた混合物をベーカリー食品用組成物とした。得られたベーカリー食品用組成物の一部を取り、GV及びα化度を測定した。その結果を表2に示す。
(Comparative Example 3)
100 parts by mass of weak wheat flour (manufactured by Nisshin Foods) was fed to an extruder without adding water and stirred at 160°C for 20 minutes to prepare dry heat-treated wheat flour. After cooling the obtained dry heat-treated wheat flour, 100 parts by mass of water (about 25°C) was added to 100 parts by mass of the dry heat-treated wheat flour and stirred, and the resulting mixture was used as a bakery food composition. A portion of the obtained bakery food composition was taken and the GV and degree of gelatinization were measured. The results are shown in Table 2.
(比較例4)
薄力小麦粉(日清フーズ製)100質量部に対して水(約25℃)100質量部を添加し、攪拌して混合物を調製した。該混合物を耐熱性のアルミパウチに入れ、脱気して密封後、レトルト釜に入れて120℃、15分間加圧加熱処理した。加圧加熱後のパウチを放熱した後、そこから中身を取り出し、ベーカリー食品用組成物とした。得られたベーカリー食品用組成物の一部を取り、GV及びα化度を測定した。その結果を表3に示す。
(Comparative Example 4)
100 parts by mass of water (about 25°C) was added to 100 parts by mass of weak wheat flour (manufactured by Nisshin Foods) and stirred to prepare a mixture. The mixture was placed in a heat-resistant aluminum pouch, degassed, sealed, and then placed in a retort oven for pressurized heating at 120°C for 15 minutes. After the pressurized and heated pouch was cooled, the contents were removed from the pouch to obtain a bakery food composition. A portion of the obtained bakery food composition was taken and the GV and degree of gelatinization were measured. The results are shown in Table 3.
(比較例5~6)
薄力小麦粉(日清フーズ製)100質量部に対して水(約25℃)100質量部を添加し、攪拌して混合物を調製した。該混合物を耐熱性のアルミパウチに入れ、開封したまま湯煎し、95℃で5分間又は60分間加熱処理した。加熱後のパウチを放熱した後、そこから中身を取り出し、ベーカリー食品用組成物とした。得られたベーカリー食品用組成物の一部を取り、GV及びα化度を測定した。その結果を表3に示す。
(Comparative Examples 5 to 6)
100 parts by mass of water (about 25°C) was added to 100 parts by mass of weak wheat flour (manufactured by Nisshin Foods) and stirred to prepare a mixture. The mixture was placed in a heat-resistant aluminum pouch, and heated at 95°C for 5 or 60 minutes while still open, in a hot water bath. After the heated pouch was cooled, the contents were removed from the pouch to prepare a bakery food composition. A portion of the obtained bakery food composition was taken and the GV and degree of gelatinization were measured. The results are shown in Table 3.
(比較例7~8)
薄力小麦粉(日清フーズ製)100質量部に水を添加せず、エクストルーダーにフィードして160℃、20分間攪拌して乾熱処理小麦粉を調製した。得られた乾熱処理小麦粉を冷却した後、該乾熱処理小麦粉100質量部に対して水100質量部を添加し、攪拌して混合物を調製した。該混合物を耐熱性のアルミパウチに入れ、開封したまま湯煎し、95℃で5分間又は60分間加熱処理した。加熱後のパウチを放熱した後、そこから中身を取り出し、ベーカリー食品用組成物とした。得られたベーカリー食品用組成物の一部を取り、GV及びα化度を測定した。その結果を表3に示す。
(Comparative Examples 7 to 8)
100 parts by mass of weak wheat flour (manufactured by Nisshin Foods) was fed to an extruder without adding water and stirred at 160 ° C for 20 minutes to prepare dry heat treated wheat flour. After cooling the obtained dry heat treated wheat flour, 100 parts by mass of water was added to 100 parts by mass of the dry heat treated wheat flour and stirred to prepare a mixture. The mixture was placed in a heat-resistant aluminum pouch, opened, and heated in a hot water bath at 95 ° C for 5 minutes or 60 minutes. After cooling the pouch after heating, the contents were removed from it to prepare a composition for bakery food. A portion of the obtained composition for bakery food was taken and the GV and degree of gelatinization were measured. The results are shown in Table 3.
(試験例1)パンの製造
製造例又は比較例のベーカリー食品用組成物を含む下記パン原料を用いてストレート法でコッペパンを製造した。まずボウルにベーカリー食品用組成物をいれて広げるようによくほぐした。ここに残りのパン原料を加え、ミキサーで低速3分、中速5分、低速2分の順でミキシングしてパン生地を調製した。パン生地を湿度75%、27℃で60分間発酵させた後、分割、成形し、60分間ホイロを行った後、210℃のオーブンで15分焼成してコッペパンを製造した。各コッペパンを室温になるまで放冷後、訓練されたパネラー10名に喫食させ、パンの食感を評価した。評価は下記評価基準により行い、10名の評価結果の平均値を求めた。結果を表1~3に示す。
<パン原料>
・ベーカリー食品用組成物 15質量部
・強力小麦粉(カメリヤ;日清フーズ製) 45質量部
・イースト 0.5質量部
・イーストフード 0.2質量部
・砂糖 5質量部
・塩 2質量部
・マーガリン 5質量部
・全卵 5質量部
・水 残部
合計 100質量部
(Test Example 1) Production of bread A bread roll was produced by the straight method using the following bread ingredients containing the bakery food composition of the production example or comparative example. First, the bakery food composition was put into a bowl and thoroughly loosened so as to spread it. The remaining bread ingredients were added to this, and the dough was prepared by mixing with a mixer at low speed for 3 minutes, medium speed for 5 minutes, and low speed for 2 minutes in that order. The dough was fermented for 60 minutes at 75% humidity and 27°C, then divided and shaped, proofed for 60 minutes, and baked in an oven at 210°C for 15 minutes to produce bread rolls. Each bread roll was allowed to cool to room temperature, and then eaten by 10 trained panelists, who evaluated the texture of the bread. The evaluation was performed according to the following evaluation criteria, and the average value of the evaluation results of the 10 panelists was calculated. The results are shown in Tables 1 to 3.
<Bread ingredients>
Bakery food composition 15 parts by weight Strong wheat flour (Camellia; manufactured by Nisshin Foods) 45 parts by weight Yeast 0.5 parts by weight Yeast food 0.2 parts by weight Sugar 5 parts by weight Salt 2 parts by weight Margarine 5 parts by weight Whole egg 5 parts by weight
Water Remainder
Total 100 parts by weight
<評価基準>
(しっとり感)
5点:唇に吸い付くようなしっとり感が充分にあり、極めて良好
4点:吸い付くようなしっとり感があり、良好
3点:パサつきはないが、しっとりした感じがややある
2点:しっとりした感じが少なく、ややパサつくか、やや脆く、不良
1点:しっとりした感じが少なく、パサつくか、脆い食感が強く、極めて不良
(歯切れ、口溶け感)
5点:口中でまとわりつく感じが全くなく、歯切れが非常によく、極めて良好
4点:口中でまとわりつく感じがわずかにあるが、歯切れがよく、良好
3点:口中でまとわりつく感じがややあるが、歯切れ感がある
2点:口中でまとわりつく感じがややあり、歯切れ感にやや劣り残る感じがあり、不良
1点:口中でまとわりつく感じ、歯切れ感に劣り残る感じがあり、極めて不良
<Evaluation criteria>
(Moisturizing)
5 points: Very moist and sticks to the lips, very good 4 points: Moist and sticks to the lips, very good 3 points: Not dry, but slightly moist 2 points: Not very moist, slightly dry or brittle, poor 1 point: Not very moist, very dry or brittle, very poor (crispness, melting in the mouth)
5 points: no sticky feeling in the mouth, very crisp, extremely good 4 points: slight sticky feeling in the mouth, crisp, good 3 points: some sticky feeling in the mouth, crisp 2 points: some sticky feeling in the mouth, slightly inferior crispness, poor 1 point: sticky feeling in the mouth, inferior crispness, extremely poor
Claims (14)
該混合物が、該熱処理小麦粉を含む原料100質量部と水50~200質量部との混合物である、
ベーカリー食品用組成物。 A bakery food composition obtained by pressurizing and heating a mixture containing heat-treated wheat flour and water,
The mixture is a mixture of 100 parts by mass of a raw material containing the heat-treated wheat flour and 50 to 200 parts by mass of water.
Bakery food compositions .
該混合物が、該熱処理小麦粉を含む原料100質量部と水50~200質量部との混合物である、
方法。 A method for producing a bakery food composition , comprising pressurizing and heating a mixture containing heat-treated wheat flour and water,
The mixture is a mixture of 100 parts by mass of a raw material containing the heat-treated wheat flour and 50 to 200 parts by mass of water.
method .
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| PCT/JP2020/040761 WO2022091324A1 (en) | 2020-10-30 | 2020-10-30 | Composition for bakery food product |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPWO2022091324A1 JPWO2022091324A1 (en) | 2022-05-05 |
| JP7598385B2 true JP7598385B2 (en) | 2024-12-11 |
Family
ID=81382086
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2022558734A Active JP7598385B2 (en) | 2020-10-30 | 2020-10-30 | Bakery food composition |
Country Status (5)
| Country | Link |
|---|---|
| JP (1) | JP7598385B2 (en) |
| KR (1) | KR20230093463A (en) |
| CN (1) | CN116490072A (en) |
| TW (1) | TWI883080B (en) |
| WO (1) | WO2022091324A1 (en) |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2014036610A (en) | 2012-08-16 | 2014-02-27 | Nisshin Flour Milling Inc | Method for producing heat treated wheat flour |
| JP2014060944A (en) | 2012-09-20 | 2014-04-10 | Nisshin Flour Milling Inc | Manufacturing method of heat treated wheat flour |
| JP2018011555A (en) | 2016-07-21 | 2018-01-25 | 日清フーズ株式会社 | Production method of heat-treated grain flour |
Family Cites Families (17)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP3389239B1 (en) | 2001-10-04 | 2003-03-24 | 奥本製粉株式会社 | Retort hot water |
| JP4129259B2 (en) | 2003-11-20 | 2008-08-06 | 幸一 長澤 | Method for producing food quality improver and food quality improver produced by the method |
| JP4698634B2 (en) * | 2007-05-10 | 2011-06-08 | 日清フーズ株式会社 | Bakery mix and bakery |
| JP4762256B2 (en) * | 2008-02-18 | 2011-08-31 | 日清製粉株式会社 | Non-fried instant noodles with ground bread |
| JP5107294B2 (en) * | 2009-03-31 | 2012-12-26 | 日清フーズ株式会社 | Heat-treated flour for fried food |
| JP5877971B2 (en) * | 2011-07-27 | 2016-03-08 | 日清製粉株式会社 | Roasted flour and method for producing the same |
| KR101307948B1 (en) * | 2011-12-02 | 2013-09-12 | 씨제이제일제당 (주) | Manufacturing method of wheat heat treatment flour |
| JP6282893B2 (en) * | 2013-07-25 | 2018-02-21 | 日清製粉株式会社 | Process for producing heat-treated flour |
| JP2015104325A (en) * | 2013-11-29 | 2015-06-08 | 敷島製パン株式会社 | Method for producing bread substrate and method for producing breads |
| CN103766432A (en) * | 2014-01-21 | 2014-05-07 | 天津易倍克食品科技发展有限公司 | Aging-resistant starch gelatinizing type bread mix, starch gelatinizing type bread and manufacturing method thereof |
| JP6649280B2 (en) * | 2015-01-26 | 2020-02-19 | 日清フーズ株式会社 | Method for producing heat-treated flour and method for producing mix for bakery food |
| CN105660765B (en) * | 2016-01-14 | 2019-09-24 | 哈尔滨顺达实业发展有限公司 | A kind of soft Europe bread |
| JP6773691B2 (en) * | 2016-02-02 | 2020-10-21 | 日清フーズ株式会社 | Modified wheat flour for fried food batter |
| JP2019024336A (en) | 2017-07-26 | 2019-02-21 | 日清製粉株式会社 | Production method of bread |
| CN107801898A (en) * | 2017-09-22 | 2018-03-16 | 安徽丹研食品有限公司 | A kind of flour heat-treatment processing process |
| JP6920241B2 (en) * | 2018-03-27 | 2021-08-18 | 日清製粉プレミックス株式会社 | Mixed composition and its production method |
| CN110999937A (en) * | 2019-12-24 | 2020-04-14 | 山东百龙创园生物科技股份有限公司 | Original flavor toast added with galactooligosaccharide and preparation method thereof |
-
2020
- 2020-10-30 CN CN202080106748.3A patent/CN116490072A/en active Pending
- 2020-10-30 WO PCT/JP2020/040761 patent/WO2022091324A1/en not_active Ceased
- 2020-10-30 JP JP2022558734A patent/JP7598385B2/en active Active
- 2020-10-30 KR KR1020237017458A patent/KR20230093463A/en not_active Ceased
- 2020-12-01 TW TW109142144A patent/TWI883080B/en active
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2014036610A (en) | 2012-08-16 | 2014-02-27 | Nisshin Flour Milling Inc | Method for producing heat treated wheat flour |
| JP2014060944A (en) | 2012-09-20 | 2014-04-10 | Nisshin Flour Milling Inc | Manufacturing method of heat treated wheat flour |
| JP2018011555A (en) | 2016-07-21 | 2018-01-25 | 日清フーズ株式会社 | Production method of heat-treated grain flour |
Also Published As
| Publication number | Publication date |
|---|---|
| CN116490072A (en) | 2023-07-25 |
| TW202215970A (en) | 2022-05-01 |
| JPWO2022091324A1 (en) | 2022-05-05 |
| WO2022091324A1 (en) | 2022-05-05 |
| TWI883080B (en) | 2025-05-11 |
| KR20230093463A (en) | 2023-06-27 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| JP7165238B2 (en) | Bread manufacturing method | |
| JP6649280B2 (en) | Method for producing heat-treated flour and method for producing mix for bakery food | |
| JP2012187070A (en) | Warm water dough and method for producing the same | |
| KR102839885B1 (en) | Method for producing ground heat-treated wheat flour, ground heat-treated wheat flour and bakery food mix and method for producing the same | |
| JP7794813B2 (en) | Pregelatinized grain flour manufacturing method | |
| JP6681250B2 (en) | Pulverized heat treatment flour manufacturing method and bakery food mix manufacturing method | |
| JP5813299B2 (en) | Process for producing bread with dried fruits | |
| TW200939966A (en) | Process for producing bakery product | |
| JP7349295B2 (en) | Liquid type for bread and method for manufacturing bread using the same | |
| JP7598385B2 (en) | Bakery food composition | |
| JP7746262B2 (en) | Method for producing heat-treated wheat flour | |
| JP6666644B2 (en) | Bakery food mix | |
| WO2024204672A1 (en) | Method for producing heat-treated cereal flour | |
| JP7691168B2 (en) | Bakery food manufacturing method | |
| JP6659487B2 (en) | Manufacturing method of heat-treated flour | |
| JP2020171234A (en) | Composition for bakery products and bakery dough using it, manufacturing method of bakery products and quality deterioration suppression method | |
| WO2023238730A1 (en) | Pregelatinized cereal flour and manufacturing method thereof | |
| JP2019170173A (en) | Mix composition and production method of the same | |
| CN117222319A (en) | How to make baking mixes | |
| JP2010158194A (en) | Method for producing rice-powder soaker dough | |
| HK40089432A (en) | Composition for bakery food product | |
| WO2020203756A1 (en) | Method for producing cereal flour composition | |
| JP7804431B2 (en) | Bakery flour | |
| JP2024132482A (en) | Yudane and its manufacturing method, and manufacturing method of food using Yudane | |
| WO2025192619A1 (en) | Heat-treated durum wheat flour and production method therefor |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| A621 | Written request for application examination |
Free format text: JAPANESE INTERMEDIATE CODE: A621 Effective date: 20230804 |
|
| A131 | Notification of reasons for refusal |
Free format text: JAPANESE INTERMEDIATE CODE: A131 Effective date: 20240702 |
|
| A521 | Request for written amendment filed |
Free format text: JAPANESE INTERMEDIATE CODE: A523 Effective date: 20240806 |
|
| TRDD | Decision of grant or rejection written | ||
| A01 | Written decision to grant a patent or to grant a registration (utility model) |
Free format text: JAPANESE INTERMEDIATE CODE: A01 Effective date: 20241112 |
|
| A61 | First payment of annual fees (during grant procedure) |
Free format text: JAPANESE INTERMEDIATE CODE: A61 Effective date: 20241129 |
|
| R150 | Certificate of patent or registration of utility model |
Ref document number: 7598385 Country of ref document: JP Free format text: JAPANESE INTERMEDIATE CODE: R150 |