JP7746262B2 - Method for producing heat-treated wheat flour - Google Patents
Method for producing heat-treated wheat flourInfo
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- JP7746262B2 JP7746262B2 JP2022524284A JP2022524284A JP7746262B2 JP 7746262 B2 JP7746262 B2 JP 7746262B2 JP 2022524284 A JP2022524284 A JP 2022524284A JP 2022524284 A JP2022524284 A JP 2022524284A JP 7746262 B2 JP7746262 B2 JP 7746262B2
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- A—HUMAN NECESSITIES
- A21—BAKING; EDIBLE DOUGHS
- A21D—TREATMENT OF FLOUR OR DOUGH FOR BAKING, e.g. BY ADDITION OF MATERIALS; BAKING; BAKERY PRODUCTS
- A21D6/00—Other treatment of flour or dough before baking, e.g. cooling, irradiating or heating
- A21D6/003—Heat treatment
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- A—HUMAN NECESSITIES
- A21—BAKING; EDIBLE DOUGHS
- A21D—TREATMENT OF FLOUR OR DOUGH FOR BAKING, e.g. BY ADDITION OF MATERIALS; BAKING; BAKERY PRODUCTS
- A21D6/00—Other treatment of flour or dough before baking, e.g. cooling, irradiating or heating
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- A—HUMAN NECESSITIES
- A23—FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
- A23L—FOODS, FOODSTUFFS OR NON-ALCOHOLIC BEVERAGES, NOT OTHERWISE PROVIDED FOR; PREPARATION OR TREATMENT THEREOF
- A23L7/00—Cereal-derived products; Malt products; Preparation or treatment thereof
- A23L7/10—Cereal-derived products
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- A—HUMAN NECESSITIES
- A23—FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
- A23L—FOODS, FOODSTUFFS OR NON-ALCOHOLIC BEVERAGES, NOT OTHERWISE PROVIDED FOR; PREPARATION OR TREATMENT THEREOF
- A23L7/00—Cereal-derived products; Malt products; Preparation or treatment thereof
- A23L7/10—Cereal-derived products
- A23L7/109—Types of pasta, e.g. macaroni or noodles
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- A—HUMAN NECESSITIES
- A23—FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
- A23L—FOODS, FOODSTUFFS OR NON-ALCOHOLIC BEVERAGES, NOT OTHERWISE PROVIDED FOR; PREPARATION OR TREATMENT THEREOF
- A23L7/00—Cereal-derived products; Malt products; Preparation or treatment thereof
- A23L7/10—Cereal-derived products
- A23L7/198—Dry unshaped finely divided cereal products, not provided for in groups A23L7/117 - A23L7/196 and A23L29/00, e.g. meal, flour, powder, dried cereal creams or extracts
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- A—HUMAN NECESSITIES
- A23—FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
- A23V—INDEXING SCHEME RELATING TO FOODS, FOODSTUFFS OR NON-ALCOHOLIC BEVERAGES AND LACTIC OR PROPIONIC ACID BACTERIA USED IN FOODSTUFFS OR FOOD PREPARATION
- A23V2002/00—Food compositions, function of food ingredients or processes for food or foodstuffs
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- A—HUMAN NECESSITIES
- A23—FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
- A23V—INDEXING SCHEME RELATING TO FOODS, FOODSTUFFS OR NON-ALCOHOLIC BEVERAGES AND LACTIC OR PROPIONIC ACID BACTERIA USED IN FOODSTUFFS OR FOOD PREPARATION
- A23V2300/00—Processes
- A23V2300/24—Heat, thermal treatment
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- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Food Science & Technology (AREA)
- Health & Medical Sciences (AREA)
- Nutrition Science (AREA)
- Chemical & Material Sciences (AREA)
- Polymers & Plastics (AREA)
- Physics & Mathematics (AREA)
- Thermal Sciences (AREA)
- Cereal-Derived Products (AREA)
- Bakery Products And Manufacturing Methods Therefor (AREA)
Description
本発明は、パン類や菓子類等のベーカリー食品や麺の製造に用いられる熱処理小麦粉の製造方法に関する。 The present invention relates to a method for producing heat-treated wheat flour used in the production of bakery foods such as bread and sweets, and noodles.
従来、ベーカリー製品等に用いる熱処理小麦粉の製法は、小麦粉を加水及び加熱することで行うことが知られている(例えば特許文献1)。 Conventionally, the method for producing heat-treated wheat flour used in bakery products, etc. has been known to involve adding water and heating wheat flour (e.g., Patent Document 1).
パン類、菓子類などのベーカリー類は、嗜好性の多様化により様々な風味、食感を特徴とする製品が市販されている。その中で、近年は、しっとり及びもっちりした食感(以下、「しっとりもっちり」ともいう。)への要望が高まっている。
従来、パン類、菓子類等のベーカリー食品にしっとり又はもっちりとした食感を付与する方法が種々提案されている。
例えば、特許文献2には、しっとり及び/又はもっちりとした食感を有し、経時的劣化が起こり難いベーカリー食品を製造可能な粉砕熱処理小麦粉として、小麦粉100質量部に対し、70℃以上の水及び/又は水蒸気を20質量部以上55質量部以下を合わせて混合物を得、該混合物を80℃以上120℃以下の雰囲気温度で3秒間以上60秒間以下加熱し、当該混合物の温度を80℃以上100℃以下とした後、粉砕する工程を有する粉砕熱処理小麦粉の製造方法が記載されている。
Due to diversifying tastes, bakery products such as breads and confectioneries are commercially available with a variety of flavors and textures. Among these, there has been an increasing demand in recent years for products with a moist and chewy texture (hereinafter also referred to as "moist and chewy").
BACKGROUND ART Various methods have been proposed for imparting a moist or chewy texture to bakery foods such as breads and confectioneries.
For example, Patent Document 2 describes a method for producing pulverized heat-treated wheat flour that can be used to produce bakery foods that have a moist and/or chewy texture and are resistant to deterioration over time, by combining 20 to 55 parts by mass of water and/or steam at 70°C or higher with 100 parts by mass of wheat flour to obtain a mixture, heating the mixture at an ambient temperature of 80 to 120°C for 3 to 60 seconds, reducing the temperature of the mixture to 80 to 100°C, and then pulverizing the mixture.
しかしながら特許文献1及び2を含め従来技術では、しっとりもっちりした食感を得ながら、ベーカリー食品の種類によっては長期冷凍に伴う食感低下が起こる点や麺の冷蔵に伴い食感低下が起こる点について、十分に検討されていなかった。However, while the prior art, including Patent Documents 1 and 2, achieves a moist and chewy texture, it has not fully addressed the issue of deterioration in texture due to long-term freezing of some types of bakery foods, or the deterioration in texture due to refrigeration of noodles.
本発明の課題は、パン等においてしっとり且つもっちり(以下単に「しっとりもっちり」とも記載する。)した食感を呈しつつ、ホットケーキ等比較的脆いベーカリー食品を長期冷凍保存した場合にも食感を維持しやすいベーカリー食品を効率よく製造し得、また麺の製造にも好適に用いることができる熱処理小麦粉を提供することに関する。 The objective of the present invention is to provide heat-treated wheat flour that can be used efficiently to produce bakery foods such as bread that have a moist and chewy texture (hereinafter simply referred to as "moist and chewy"), while easily maintaining the texture of relatively fragile bakery foods such as pancakes even when frozen for long periods of time, and that can also be suitably used to produce noodles.
本発明は、アミロース含量25%以下の小麦粉100質量部と、70℃以上の水を30質量部以上45質量部以下と合わせて混合物を得、100℃以上120℃未満の雰囲気温度で3秒間以上60秒間以下加熱して、糊化度50%以上95%以下の熱処理小麦粉を得る、熱処理小麦粉の製造方法である。 The present invention is a method for producing heat-treated wheat flour, which involves combining 100 parts by weight of wheat flour having an amylose content of 25% or less with 30 to 45 parts by weight of water at 70°C or higher to obtain a mixture, and heating it at an ambient temperature of 100°C or higher but less than 120°C for 3 to 60 seconds to obtain heat-treated wheat flour having a degree of gelatinization of 50% to 95%.
以下、本発明をその好ましい実施形態に基づき説明する。本明細書において熱処理小麦粉とは、熱処理が施された小麦粉を指す。The present invention will be described below based on preferred embodiments. In this specification, heat-treated wheat flour refers to wheat flour that has been subjected to heat treatment.
まず、本発明の熱処理小麦粉の製造方法について説明する。本発明の熱処理小麦粉の製造方法は、アミロース含量25%以下の小麦粉100質量部と、70℃以上の水を30質量部以上45質量部以下とを合わせて混合物を得、100℃以上120℃未満の雰囲気温度で3秒間以上60秒間以下加熱して、糊化度50%以上95%以下の熱処理小麦粉を得る。First, we will explain the method for producing heat-treated wheat flour of the present invention. The method for producing heat-treated wheat flour of the present invention involves combining 100 parts by weight of wheat flour having an amylose content of 25% or less with 30 to 45 parts by weight of water at 70°C or higher to obtain a mixture, which is then heated at an ambient temperature of 100°C or higher but less than 120°C for 3 to 60 seconds to obtain heat-treated wheat flour with a degree of gelatinization of 50% to 95%.
本発明の熱処理小麦粉の製造方法の一つの特徴として、アミロース含量が25%以下の小麦粉を原料として使用する点がある。本発明者が鋭意検討したところ、アミロース含量が25%以下の小麦粉を使用し、且つ所定温度以上の水を所定量用いて所定時間で熱処理を行って糊化度を所定の範囲内とする場合、ホットケーキ等の脆くなりやすいベーカリー食品においても、長期冷凍に起因した食感低下の問題が抑制され、また冷蔵した麺の食感を改善しうることが判明した。また本発明では得られるパンのしっとりもっちりした食感が特に優れたものとなる。例えば比較例6と実施例1との比較のとおり、本製法によれば、同様の糊化度でもアミロース含量が所定値以下の小麦粉を用いる事で優れた効果を発揮する。One feature of the heat-treated wheat flour manufacturing method of the present invention is the use of wheat flour with an amylose content of 25% or less as a raw material. Through extensive research, the inventors have found that using wheat flour with an amylose content of 25% or less and heat-treating it with a predetermined amount of water at a predetermined temperature or higher for a predetermined time to achieve a degree of gelatinization within a predetermined range can mitigate the problem of texture deterioration caused by long-term freezing, even in bakery foods that tend to become brittle, such as pancakes, and can also improve the texture of refrigerated noodles. Furthermore, the bread obtained with this invention has a particularly excellent moist and chewy texture. For example, as shown in a comparison between Comparative Example 6 and Example 1, this manufacturing method exhibits excellent effects by using wheat flour with an amylose content of 25% or less, even at a similar degree of gelatinization, but with a predetermined value or less of amylose.
本発明で用いる小麦粉は、アミロースが少ない澱粉が有するしっとりもっちりと、熱処理により糊化しやすい性状の観点から、アミロース含量が25%以下である。なお、アミロース含量とは、小麦粉の澱粉中のアミロース含量を指す。
アミロース含量が25%以下の小麦粉としては、「つるぴかり」、「チクゴイズミ」、「ネバリゴシ」、「ニシホナミ」、「あやひかり」、「イワイノダイチ」、「ユメセイキ」、「きぬあずま」、「関東107号」等の低アミロース小麦を製粉した小麦粉をあげることができる。これらの低アミロース小麦の小麦粉としては、例えば、アミロース合成遺伝子Wx-A1、Wx-B1、Wx-D1のうち、いずれか2個の発現を欠いた小麦に由来した小麦粉が挙げられる。アミロース含量が25%以下の小麦粉としては、これらの低アミロース小麦由来の小麦粉の1種または2種以上を適宜混合して用いることができる。
The wheat flour used in the present invention has an amylose content of 25% or less, from the viewpoint of the moist and chewy texture of starch with low amylose content and the ease of gelatinization by heat treatment. The amylose content refers to the amylose content in the starch of the wheat flour.
Examples of wheat flour with an amylose content of 25% or less include wheat flour milled from low-amylose wheat varieties such as "Tsurupikari,""Chikugoizumi,""Nebarigoshi,""Nishihonami,""Ayahikari,""Iwainodaichi,""Yumeseiki,""Kinuazuma," and "Kanto 107." Examples of wheat flour from these low-amylose wheat varieties include wheat flour derived from wheat lacking expression of any two of the amylose synthesis genes Wx-A1, Wx-B1, and Wx-D1. As wheat flour with an amylose content of 25% or less, one or a suitable mixture of two or more of these low-amylose wheat-derived wheat flours can be used.
アミロース含量が25%以下の小麦粉としては、ほかにモチ性小麦粉がある。このモチ性小麦粉に用いられる小麦は、例えば特開平6-125669号公報に記載の方法に従って、Wx-A1遺伝子とWx-B1遺伝子の発現を欠きWx-D1遺伝子の発現能力を維持する6倍体とWx-D1遺伝子の発現のみを欠いた6倍体を交配して雑種第一代個体を得、これを自家受精させて雑種第二代個体とし、この中から前記3種の遺伝子の発現を欠いたものを選択することによって作出されるものであり、このものはアミロース含量は0である。さらにこれを常法に従って、ウルチ性小麦と交配後、選抜することによりアミロース含量が10%以下のモチ性小麦が得られる。本発明では、アミロース含量が25%以下の小麦粉として、アミロース含量が10%以下のモチ性小麦由来の小麦粉を用いてもよい。
本発明で用いる小麦粉のアミロース含量は、もっちりしっとりした食感、冷凍耐性、冷蔵耐性等の点から、0~25%であることが好ましく、とりわけ0~20%であることがより好ましい。
Another example of wheat flour with an amylose content of 25% or less is waxy wheat flour. The wheat used for waxy wheat flour is produced, for example, according to the method described in Japanese Patent Application Laid-Open No. 6-125669, by crossing a hexaploid lacking expression of the Wx-A1 and Wx-B1 genes but maintaining the ability to express the Wx-D1 gene with a hexaploid lacking expression of only the Wx-D1 gene to obtain a first-generation hybrid, which is then self-fertilized to produce a second-generation hybrid, from which individuals lacking expression of the three genes are selected. This hybrid has an amylose content of 0. Further crossing this with non-waxy wheat and subsequent selection according to conventional methods results in waxy wheat with an amylose content of 10% or less. In the present invention, wheat flour derived from waxy wheat with an amylose content of 10% or less may be used as the wheat flour with an amylose content of 25% or less.
The amylose content of the wheat flour used in the present invention is preferably 0 to 25%, more preferably 0 to 20%, from the viewpoints of a chewy and moist texture, freezing resistance, refrigeration resistance, etc.
本発明において熱処理小麦粉の原料となる小麦粉中、アミロース含量が25%以下の小麦品種の小麦粉の割合は、上述した食感の向上の点から、50質量%以上であることが好ましく、75質量%以上であることが特に好ましく、100質量%であってもよい。 In the present invention, the proportion of wheat flour of a wheat variety having an amylose content of 25% or less among the wheat flour used as the raw material for the heat-treated wheat flour is preferably 50% by mass or more, particularly preferably 75% by mass or more, and may be 100% by mass, from the viewpoint of improving the texture described above.
本発明では、所定温度以上に加熱した水と、上記特定のアミロース含量の小麦粉とを合わせて混合物を得、該混合物に加熱処理を行う。以下、水と、小麦粉とを合わせて混合物を得る処理を混合処理ともいう。例えば特許文献1では、水と小麦粉の混合物を加熱処理することは記載されているものの、小麦粉と混合する水を予め加熱処理することは記載されていない。一方、本発明では、所定温度以上に加熱した水を小麦粉と混合した混合物を加熱処理することで、加温していない水と混合する場合と比較して短時間で小麦粉中の澱粉のα化が顕著に促進され、それを特定のアミロース含量の小麦粉の加熱に所定条件で適用するために、パンでのしっとり且つもっちりした食感とホットケーキ等での冷凍耐性、麺の冷蔵耐性を全て得るという効果に優れたものとなる。具体的には、小麦粉に添加する水は70℃以上、好ましくは75℃以上、更に好ましくは80℃以上に加熱する。小麦粉に混合する水の水温を70℃以上とすることで、ベーカリー食品のしっとりもっちりした食感が優れ、且つホットケーキ等の冷凍耐性や麺の冷蔵耐性も得やすくなる。本明細書でいう水温とは常圧下での水温であり、上限は通常100℃である。 In the present invention, water heated to a predetermined temperature or higher is combined with wheat flour having the above-mentioned specific amylose content to obtain a mixture, and the mixture is then heat-treated. Hereinafter, the process of combining water and wheat flour to obtain a mixture is also referred to as a mixing process. For example, Patent Document 1 describes heat-treating a mixture of water and wheat flour, but does not describe pre-heat-treating the water to be mixed with wheat flour. In contrast, in the present invention, heat-treating a mixture of wheat flour and water heated to a predetermined temperature or higher significantly promotes gelatinization of the starch in the wheat flour in a shorter time than when mixing with unheated water. This is then applied to heating wheat flour with a specific amylose content under predetermined conditions, resulting in an excellent effect of achieving a moist and chewy texture in bread, freezing resistance in pancakes, and refrigeration resistance in noodles. Specifically, the water added to wheat flour is heated to 70°C or higher, preferably 75°C or higher, and more preferably 80°C or higher. By adjusting the temperature of the water mixed with wheat flour to 70°C or higher, bakery foods can have an excellent moist and chewy texture, and also the freezing resistance of hotcakes and the refrigeration resistance of noodles can be easily achieved. The water temperature referred to in this specification is the water temperature under normal pressure, and the upper limit is usually 100°C.
混合処理において、小麦粉と所定温度以上の水との混合物は均質な混合物であることを要さず、混在状態であればよい。また、本明細書において、小麦粉と所定温度以上の水との混合物を得るための小麦粉と当該水とを合わせる処理も、撹拌等の均質化のための操作を必須としない。しかし、小麦粉と前記の水との混合物を得る際における撹拌等の均質化処理は、本発明から除外されるものではなく、求められる熱処理小麦粉の用途や品質等に応じて適宜行うことができる。小麦粉と水との混合物は、小麦粉に前記の水を添加して得てもよく、前記の水に対して小麦粉を添加しても得てもよいが、小麦粉に前記の水を添加することが、混合・撹拌の均一性や簡便さの点で有利である。In the mixing process, the mixture of wheat flour and water at or above a predetermined temperature does not need to be a homogenous mixture; it is sufficient if the mixture is in a mixed state. Furthermore, in this specification, the process of combining wheat flour and water to obtain a mixture of wheat flour and water at or above a predetermined temperature does not require a homogenization procedure, such as stirring. However, homogenization procedures, such as stirring, when obtaining a mixture of wheat flour and water are not excluded from the present invention and can be performed as appropriate depending on the intended use and quality of the heat-treated wheat flour. The mixture of wheat flour and water may be obtained by adding the water to wheat flour, or by adding wheat flour to the water. However, adding the water to wheat flour is advantageous in terms of uniformity and ease of mixing and stirring.
本発明の熱処理小麦粉の製造方法では、前記の混合処理において、小麦粉と混合する前記の水の量が所定量である。小麦粉と混合する70℃以上の水の量は小麦粉100質量部に対して30質量部以上45質量部以下であることを要する。加水量を30質量部以上にすることで小麦粉中の澱粉のα化が十分に行われ、しっとりもっちりした良好な食感が得られる。一方、45質量部以下とすることで、小麦粉が生地状になることによる生産性の低下を防ぐと共に、小麦粉中の澱粉の過剰な糊化による製パン時のべたつきの発生を抑制でき、作業性に優れる利点がある。小麦粉と混合する水の量は小麦粉100質量部に対して30質量部以上40質量部以下であることがより好ましく、32質量部以上38質量部以下であることが更に好ましい。In the method for producing heat-treated wheat flour of the present invention, the amount of water mixed with wheat flour in the mixing step is a predetermined amount. The amount of water at 70°C or higher mixed with wheat flour must be 30 to 45 parts by weight per 100 parts by weight of wheat flour. Adding 30 parts by weight or more of water ensures sufficient gelatinization of the starch in the wheat flour, resulting in a moist, chewy, and favorable texture. On the other hand, adding 45 parts by weight or less prevents a decrease in productivity due to the wheat flour becoming doughy, suppresses the occurrence of stickiness during breadmaking due to excessive gelatinization of the starch in the wheat flour, and has the advantage of excellent workability. The amount of water mixed with wheat flour is more preferably 30 to 40 parts by weight per 100 parts by weight of wheat flour, and even more preferably 32 to 38 parts by weight.
なお、本発明において小麦粉の熱処理時に乳化剤、脂肪酸、油脂等を用いる必要はなく、添加させる場合には、乳化剤、脂肪酸、油脂はそれぞれ小麦粉に対して0.05質量%未満、より好ましくは0.01質量%未満、更に好ましくは0.005質量%未満とごく微量の使用量とすることが好ましい。
混合物中、小麦粉及び水分以外の成分は合計で、小麦粉に対し、2.0質量%以下であることが好ましく、1.0質量%以下であることがより好ましい。
In the present invention, there is no need to use emulsifiers, fatty acids, oils and fats during the heat treatment of wheat flour. If they are added, the amount of emulsifier, fatty acid, oil and fat used is preferably very small, i.e., less than 0.05% by mass, more preferably less than 0.01% by mass, and even more preferably less than 0.005% by mass, of the wheat flour.
In the mixture, the total amount of components other than wheat flour and water is preferably 2.0% by mass or less, more preferably 1.0% by mass or less, based on the wheat flour.
前記のように所定温度の水と小麦粉とを合わせてなる混合物を、100℃以上120℃以下の雰囲気温度で、3秒間以上60秒間以下加熱する(以下、本処理を単に「加熱処理」ともいう。)。ここでいう「雰囲気温度」は、被加熱物である混合物(小麦粉)の周囲の空間の気温であり、被加熱物自体の温度(混合物の温度)ではない。雰囲気温度が100℃以上及び加熱時間が3秒間以上であることで小麦粉中の澱粉のα化が十分に行われやすい。また雰囲気温度が120℃未満及び加熱時間が60秒間以下であることで、澱粉の過剰な糊化とタンパク質の変性を抑える利点がある。この観点から、好ましくは、加熱時間は4秒間以上30秒間以下であり、4秒間以上15秒間以下である。また好ましくは、雰囲気温度は100℃以上110℃以下である。なお、本発明において、小麦粉と水分との混合と、加熱とは同時に行ってもよいし、混合後に加熱を行ってもよい。例えば、予め内部雰囲気を加熱しておいた容器内に、小麦粉と水分をそれぞれ投入することで、加熱と同時に、小麦粉と水分との混合を行うことができる。その場合、加熱時間の開始は、容器内への小麦粉と水分の投入時点となる。As described above, a mixture of water and wheat flour at a predetermined temperature is heated at an ambient temperature of 100°C to 120°C for 3 to 60 seconds (hereinafter, this process will be referred to simply as "heat treatment"). The "ambient temperature" here refers to the air temperature surrounding the mixture (wheat flour), which is the object to be heated, and not the temperature of the object itself (the temperature of the mixture). An ambient temperature of 100°C or higher and a heating time of 3 seconds or longer facilitates sufficient gelatinization of the starch in the wheat flour. Furthermore, an ambient temperature of less than 120°C and a heating time of 60 seconds or shorter has the advantage of suppressing excessive starch gelatinization and protein denaturation. From this perspective, the heating time is preferably 4 to 30 seconds, or 4 to 15 seconds. Furthermore, the ambient temperature is preferably 100°C to 110°C. In the present invention, the mixing of wheat flour and water and heating may be performed simultaneously, or heating may be performed after mixing. For example, by adding flour and water to a container whose internal atmosphere has been heated in advance, the flour and water can be mixed simultaneously with heating. In this case, the heating time starts when the flour and water are added to the container.
本発明の熱処理小麦粉の製造方法は、加熱処理において、混合物の温度を100℃超110℃以下とすることが好ましく、101℃以上110℃以下とすることがより好ましい。加熱処理において、混合物の温度を100℃超110℃以下とすることで、後述する糊化度の小麦粉を首尾よく得ることができるほか、しっとりもっちりした食感、ホットケーキ等の冷凍耐性、及び麺の冷蔵耐性に特に優れたものとなる。特許文献2には段落〔0018〕に「混合物の温度が100℃以下であることで、しっとりもっちりした良好な食感が得られるほか、作業性、外観(ボリューム)、内相の点でも優れたベーカリー製品が得られる。」と記載されている。しかしながら、本発明者が検討したところ、特定のアミロース含量の小麦について、混合物の温度を100℃超110℃以下となるように加熱して所定の糊化度とした場合に、特に優れた食感改善効果が得られることが判った。
本発明の熱処理小麦粉の製造方法において、混合物の温度は、加熱処理中に一度でも100℃超110℃以下に達していればよい。例えば混合物の温度は加熱処理完了時に測定することができるが、上述した通り、加熱処理中に一度でも100℃超110℃以下となっていれば、加熱処理完了の混合物の温度が100℃超110℃以下の範囲外であってもよい。混合物の温度を前記範囲内とするためには、前記混合処理で小麦粉と合わせる水分の温度や量を前記の範囲内とするとともに、小麦粉と水分とが混合した時点から加熱処理開始時点までの時間を調整し、更に加熱処理における雰囲気温度及び加熱時間を前記範囲内とするほか、加熱処理において容器内部に流通させる加熱した水蒸気の流量の調整等を行えばよい。
In the method for producing heat-treated wheat flour of the present invention, the temperature of the mixture during the heat treatment is preferably greater than 100°C and less than 110°C, more preferably greater than 101°C and less than 110°C. By maintaining the temperature of the mixture during the heat treatment at greater than 100°C and less than 110°C, wheat flour with the gelatinization degree described below can be successfully obtained, and the flour also exhibits a moist and chewy texture, excellent freezing resistance for pancakes, and excellent refrigeration resistance for noodles. Patent Document 2 states in paragraph [0018] that "By maintaining the temperature of the mixture at 100°C or less, a moist and chewy texture can be obtained, and bakery products with excellent workability, appearance (volume), and internal structure can also be obtained." However, the present inventors have found that, for wheat with a specific amylose content, a particularly excellent texture improvement effect can be obtained when the mixture is heated to a temperature greater than 100°C and less than 110°C to achieve a predetermined gelatinization degree.
In the method for producing heat-treated wheat flour of the present invention, the temperature of the mixture only needs to reach more than 100°C and not more than 110°C at least once during the heat treatment. For example, the temperature of the mixture can be measured at the completion of the heat treatment. As described above, the temperature of the mixture at the completion of the heat treatment may be outside the range of more than 100°C and not more than 110°C, as long as it reaches more than 100°C and not more than 110°C at least once during the heat treatment. To control the temperature of the mixture within the above range, the temperature and amount of water combined with the wheat flour during the mixing treatment may be set within the above range, the time from when the wheat flour and water are mixed to when the heat treatment is started may be adjusted, the ambient temperature and heating time during the heat treatment may be set within the above range, and the flow rate of heated steam circulating inside the container during the heat treatment may be adjusted.
小麦粉と所定温度の水分との混合と加熱処理とは連続的に行うことが加熱完了時の混合物の温度を後述する範囲内とするために好ましい。連続的とは、例えば、小麦粉と所定温度の水分との混合と加熱開始までを数秒内で行うことを指し、上述した、予め内部雰囲気を加熱しておいた容器内に小麦粉と水分をそれぞれ投入する場合を含む。なお、加熱処理装置において上述した混合物の温度を測定する場合、例えば、加熱処理に内部のエクストルーダーにより内容物を容器中で入口から出口まで移送させながら加熱する装置を用いる場合は、混合物の温度は出口における混合物の温度とすることができる。It is preferable to mix the flour with water at a predetermined temperature and heat the mixture continuously so that the temperature of the mixture at the end of heating falls within the range described below. "Continuously" refers to, for example, mixing the flour with water at a predetermined temperature and starting heating within a few seconds, including the case described above where the flour and water are separately poured into a container whose internal atmosphere has been preheated. When measuring the temperature of the mixture in a heat treatment device, for example, when using a device that heats the contents while transporting them from the inlet to the outlet of a container using an internal extruder, the temperature of the mixture can be the temperature of the mixture at the outlet.
本発明に係る加熱処理は特に限定されず公知の加熱装置を用いて実施できるが、好ましくは、小麦粉中の澱粉を糊化させるために水を添加して加熱処理をする装置を用いることができる。加熱処理は、例えば、オートクレーブ、スチームオーブン等の公知の加熱装置を用いて実施できる。本発明に係る加熱処理の一例として、小麦粉と上記所定温度以上の水とをアルミパウチ等、或いはヒートジャケット等で加熱可能な密閉容器に封入密閉し、加圧下で加熱する処理が挙げられる。小麦粉と水の導入前に、密閉容器の内部雰囲気を予め望ましい温度に加熱していてもよい。また密閉容器内部に適宜撹拌を行う機構を設けてもよい。また加圧は密閉容器中の加熱された水蒸気によりなされるものであってよい。また、本発明に係る加熱処理の他の一例として、小麦粉及び水を密閉容器内に導入し、必要に応じて該混合物を攪拌しつつ、当該導入と同時又は当該導入より前若しくは後に(好ましくは該導入と同時又は該導入より前に)、該容器内に飽和水蒸気を導入して加圧下で加熱する処理が挙げられる(この場合の飽和水蒸気の量は小麦粉に添加する70℃以上の水の量には含めないものとする)。これらの処理は、例えば一軸又は二軸型エクストルーダーを用いて実施できる。The heat treatment according to the present invention can be carried out using any known heating device, but preferably, a device that adds water to gelatinize the starch in the wheat flour and heats it is used. Heat treatment can be carried out using known heating devices, such as an autoclave or steam oven. One example of the heat treatment according to the present invention is a process in which wheat flour and water at or above the predetermined temperature are sealed in an airtight container, such as an aluminum pouch or a heat jacket, and heated under pressure. The atmosphere inside the airtight container may be preheated to the desired temperature before the introduction of the wheat flour and water. A suitable stirring mechanism may also be provided inside the airtight container. Pressurization may also be achieved by heated steam in the airtight container. Another example of the heat treatment according to the present invention is a process in which wheat flour and water are introduced into an airtight container, and, while stirring the mixture as needed, saturated steam is introduced into the container simultaneously with, before, or after (preferably simultaneously with, or before) the introduction of the mixture, and the mixture is heated under pressure (in this case, the amount of saturated steam is not included in the amount of water at 70°C or above added to the wheat flour). These processes can be carried out, for example, using a single-screw or twin-screw extruder.
なお、容器内に水蒸気を導入して加圧下で加熱する処理を行う場合は水蒸気の流量は40~130kg/hの範囲内で通常調節され、70~100kg/hの範囲内であることが好ましい。ここでいう「加圧下」は、主として容器内に充満する蒸気によって加圧状態となった場合を意味し、押出具(エクストルーダーが備えるスクリューに相当する部材)のような物体を原料小麦に接触させることによって該原料小麦を加圧状態とした場合を指すわけではない。 When steam is introduced into a container and heating is performed under pressure, the flow rate of steam is usually adjusted to within the range of 40 to 130 kg/h, and preferably within the range of 70 to 100 kg/h. "Under pressure" here primarily refers to a pressurized state caused by steam filling the container, and does not refer to a pressurized state of the raw wheat being brought into contact with an object such as a pusher (a component equivalent to the screw provided in an extruder)
本発明の熱処理小麦粉の製造方法においては、小麦粉及び加温した水を含む混合物を前記のように加熱処理した後、得られた熱処理小麦粉を粉砕することが好ましい。本発明では、加熱処理の後、加熱した混合物を、粒状化工程を経ることなく粉砕することが好ましい。粒状化工程とは、加熱した混合物を粒子状にして生地粒子とする工程を指す。粒状化工程の例としては、押出し造粒機、混合造粒機などを用いた造粒工程が挙げられる。また加熱した混合物を2つのロールにて延伸した後、延伸された生地を切断して粒状化したり、前述した加熱処理に混練機を用いた場合に該混練機から押し出されてくる混合物を小さく切断して粒状化する工程が挙げられる。生地粒子の粒子径としては、1mm~50mmが挙げられ、好ましくは5mm~20mmである。本発明では、加熱した混合物について、粒状化工程を経ることなく粉砕することで、製造時間の短縮化や製造設備の省スペース化の利点がある。In the method for producing heat-treated wheat flour of the present invention, it is preferable to heat-treat a mixture containing wheat flour and heated water as described above, and then pulverize the resulting heat-treated wheat flour. In the present invention, it is preferable to pulverize the heated mixture after heat treatment without a granulation step. The granulation step refers to a process of granulating the heated mixture into dough particles. Examples of granulation steps include granulation processes using an extrusion granulator, a mixer granulator, etc. Other examples include a process in which the heated mixture is stretched between two rolls and then the stretched dough is cut into granules, or a process in which the mixture extruded from a kneader is cut into small pieces and granulated when a kneader is used for the heat treatment described above. The particle diameter of the dough particles can be 1 mm to 50 mm, preferably 5 mm to 20 mm. In the present invention, pulverizing the heated mixture without a granulation step has the advantages of shortening production time and saving space for production equipment.
加熱処理により得られた熱処理小麦粉を粉砕する際、粉砕処理の方法は特に限定されず公知の方法を用いることができ、例えば、ロール式粉砕、衝撃式粉砕、気流式粉砕、ピンミル式粉砕等が挙げられるが、このうち、ピンミル式粉砕又は気流式粉砕を好適に使用できる。When grinding the heat-treated wheat flour obtained by heat treatment, there are no particular limitations on the grinding method, and any known method can be used, such as roll grinding, impact grinding, airflow grinding, and pin mill grinding. Of these, pin mill grinding and airflow grinding are preferably used.
なお、本発明においては、熱処理小麦粉の粉砕に先立ち、該熱処理小麦粉に乾燥処理を施してもよい。前述の通り熱処理小麦粉は通常湿潤状態であるため、粉砕前に乾燥することによって粉砕処理をより適切に行うことができる。乾燥処理としては、棚乾燥、熱風乾燥、流動層乾燥等の公知の方法によって実施できる。また、粉砕と同時に乾燥を行ってもよい。また、粉砕の前に熱処理小麦粉の乾燥を行わない場合は、粉砕後に乾燥して、保存性を高めることが好ましい。乾燥時の乾燥温度は、該熱処理小麦粉の澱粉糊化とタンパク質変性を抑制する観点から低温乾燥の30℃以上70℃以下では6時間以上24時間以下の処理が好ましく、高温乾燥の100℃以上180℃以下では5秒以上120秒以下が好ましく、低温乾燥では40℃以上60℃以下がより好ましく、高温乾燥では120℃以上160℃以下がより好ましい。In the present invention, the heat-treated wheat flour may be dried prior to milling. As mentioned above, heat-treated wheat flour is usually wet, so drying before milling allows for more efficient milling. Drying can be performed by known methods such as shelf drying, hot air drying, and fluidized bed drying. Drying can also be performed simultaneously with milling. If the heat-treated wheat flour is not dried before milling, it is preferable to dry it after milling to enhance shelf life. Regarding the drying temperature, to prevent starch gelatinization and protein denaturation in the heat-treated wheat flour, low-temperature drying at 30°C to 70°C for 6 to 24 hours is preferred. High-temperature drying at 100°C to 180°C is preferred for 5 to 120 seconds. Low-temperature drying at 40°C to 60°C is more preferred, and high-temperature drying at 120°C to 160°C is more preferred.
本発明で得られる熱処理小麦粉は糊化度が50%以上95%以下である。熱処理小麦粉は糊化度が50%以上であることで、パン類にしっとりもっちりした食感が得られ、またホットケーキなどの生地物類において冷凍保管時の食感劣化を防ぐ利点があるほか、麺の老化耐性を防止できる。熱処理小麦粉は糊化度が95%以下であることで、澱粉の過剰な糊化がもたらすベタつきを防ぐことで生産性と製パン作業性の低下を防ぐ利点がある。この観点から、熱処理小麦粉は糊化度が50%以上95%以下が好ましく、65%以上90%以下がより好ましい。糊化度はβ-アミラーゼ・プルラナーゼ法により測定したものであり、具体的には以下の方法で測定される。The heat-treated wheat flour obtained by the present invention has a degree of gelatinization of 50% or more and 95% or less. Heat-treated wheat flour with a degree of gelatinization of 50% or more provides a moist and chewy texture to breads, and has the advantage of preventing deterioration in texture during frozen storage in dough products such as pancakes, as well as preventing aging resistance in noodles. Heat-treated wheat flour with a degree of gelatinization of 95% or less has the advantage of preventing stickiness caused by excessive starch gelatinization, thereby preventing a decrease in productivity and bread-making workability. From this perspective, the heat-treated wheat flour preferably has a degree of gelatinization of 50% or more and 95% or less, and more preferably 65% or more and 90% or less. The degree of gelatinization is measured by the β-amylase-pullulanase method, specifically as follows.
<糊化度の測定法>
(A)試薬
使用する試薬は、以下の通りである。
1.0.8M酢酸-酢酸Na緩衝液
2.10N水酸化ナトリウム溶液
3.2N酢酸溶液
4.酵素溶液:β-アミラーゼ(ナガセ生化学工業(株)#1500)0.017gおよびプルラナーゼ(林原生物化学研究所、・31001)0.17gを上記0.8M酢酸-酢酸Na緩衝液に溶かして100mlとしたもの。
5.失活酵素溶液:上記酵素溶液を10分間煮沸させて調製。
6.ソモギー試薬およびネルソン試薬(還元糖量の測定用試薬)
<Method for measuring gelatinization degree>
(A) Reagents The reagents used are as follows:
1. 0.8 M acetic acid-Na acetate buffer solution 2. 10 N sodium hydroxide solution 3. 2 N acetic acid solution 4. Enzyme solution: 0.017 g of β-amylase (Nagase Biochemical Industries, Ltd. #1500) and 0.17 g of pullulanase (Hayashibara Biochemical Laboratories, 31001) were dissolved in the above 0.8 M acetic acid-Na acetate buffer solution to make 100 ml.
5. Inactivated enzyme solution: Prepare by boiling the above enzyme solution for 10 minutes.
6. Somogyi and Nelson reagents (reagents for measuring reducing sugars)
(B)測定方法
1.小麦粉をホモジナイザーで粉砕し、100メッシュ以下とする。この粉砕した小麦粉0.08~0.10gをガラスホモジナイザーにとる。
2.これに脱塩水8.0mlを加え、ガラスホモジナイザーを10~20回上下させて分散を行う。
3.2本の25ml容目盛り付き試験管に上記2,の分散液を2mlずつとり、1本は0.8M酢酸-酢酸Na緩衝液で定容し、試験区とする。
4.他の1本には、10N水酸化ナトリウム溶液0.2mlを添加し、50℃で3~5分間反応させ、完全に糊化させる。その後、2N酢酸溶液1.0mlを添加し、pHを6.0付近に調整した後、0.8M酢酸-酢酸Na緩衝液で定容し、糊化区とする。
5.上記3.および4.で調製した試験区および糊化区の試験液をそれぞれ0.4mlとり、それぞれに酵素溶液0.1mlを加えて、40℃で30分間酵素反応させる。同時に、ブランクとして、酵素溶液の代わりに失活酵素溶液0.1mlを加えたものも調製する。酵素反応は途中で反応液を時々攪拌させながら行う。
6.上記反応済液0.5mlにソモギー試薬0.5mlを添加し、沸騰浴中で15分間煮沸する。煮沸後、流水中で5分間冷却した後、ネルソン試薬1.0mlを添加・攪拌し、15分間放置する。
7.その後、脱塩水8.00mlを加えた後、攪拌し、500nmの吸光度を測定する。
(B) Measurement method 1. Pulverize wheat flour using a homogenizer to a size of 100 mesh or less. Place 0.08 to 0.10 g of this pulverized wheat flour in a glass homogenizer.
2. Add 8.0 ml of demineralized water to this and disperse by moving the glass homogenizer up and down 10 to 20 times.
3. Place 2 ml of the dispersion liquid from step 2 above into two 25 ml graduated test tubes, and dilute one tube to the required volume with 0.8 M acetic acid-Na acetate buffer to create a test group.
4. To the other tube, add 0.2 ml of 10 N sodium hydroxide solution and react at 50°C for 3 to 5 minutes to completely gelatinize. After that, add 1.0 ml of 2 N acetic acid solution to adjust the pH to around 6.0, and then make the volume to the constant level with 0.8 M acetic acid-sodium acetate buffer to create the gelatinized sample.
5. Take 0.4 ml of each of the test and gelatinized test solutions prepared in steps 3 and 4 above, add 0.1 ml of enzyme solution to each, and allow the enzyme reaction to occur at 40°C for 30 minutes. At the same time, prepare a blank by adding 0.1 ml of inactivated enzyme solution instead of the enzyme solution. The enzyme reaction is carried out while occasionally stirring the reaction solution during the reaction.
6. Add 0.5 ml of Somogyi reagent to 0.5 ml of the reaction mixture and boil in a boiling bath for 15 minutes. After boiling, cool in running water for 5 minutes, then add 1.0 ml of Nelson's reagent, stir, and leave for 15 minutes.
7. Then, add 8.00 ml of demineralized water, stir, and measure the absorbance at 500 nm.
(C)糊化度の算出
下式により糊化度を算出する。
糊化度(%)=(試験溶液の分解率)/(完全糊化試験溶液の分解率)×100
=(A-a)/(A'-a')×100
式中、A、A'、aおよびa'は下記の通りである。
A=試験区の吸光度
A'=糊化区の吸光度
a=試験区のブランクの吸光度
a'=糊化区のブランクの吸光度
(C) Calculation of Gelatinization Degree The gelatinization degree is calculated using the following formula.
Degree of gelatinization (%) = (decomposition rate of test solution) / (decomposition rate of completely gelatinized test solution) × 100
=(A-a)/(A'-a')×100
In the formula, A, A', a and a' are as follows.
A = absorbance of test group A' = absorbance of gelatinized group a = absorbance of blank of test group a' = absorbance of blank of gelatinized group
本発明の熱処理小麦粉は、二次加工して種々の食品用途に用いることができ、代表的な用途としてベーカリー食品が挙げられる。本発明でいうベーカリー食品は、穀粉を主原料とし、これに必要に応じてイーストや膨張剤、水、食塩、砂糖等の副材料を加えて得られた発酵又は非発酵生地を、焼成、蒸し、フライ等の加熱処理に供して得られる食品をいう。本発明が適用可能なベーカリー食品の例としては、パン類、菓子類が挙げられる。パン類としては、食パン、フランスパン、ロールパン、コッペパン、クロワッサン、ピザ等が挙げられる。菓子類としては、ドーナツ、どら焼き、スポンジケーキ、バターケーキ、ホットケーキ、パンケーキ、マフィン、クッキー等が挙げられる。なお、冷凍時に脆くなりやすいベーカリー食品の例としては、パン類の内、食パン、フランスパン、ロールパン、コッペパン、ピザ等や、菓子類の内、ホットケーキ、どら焼き、スポンジケーキ、バターケーキ、ホットケーキ、パンケーキ、マフィンなどが挙げられる。
また麺類としては、うどん、中華麺、パスタ等が挙げられる。
The heat-treated wheat flour of the present invention can be used in various food applications after secondary processing, with bakery foods being a typical example. Bakery foods, as used herein, refer to foods obtained by subjecting fermented or unfermented dough, primarily made from cereal flour, to which, as needed, secondary ingredients such as yeast, leavening agents, water, salt, and sugar are added, to heat treatments such as baking, steaming, and frying. Examples of bakery foods to which the present invention can be applied include breads and confectioneries. Examples of breads include white bread, French bread, rolls, buns, croissants, and pizza. Examples of confectioneries include donuts, dorayaki, sponge cakes, butter cakes, hotcakes, pancakes, muffins, and cookies. Examples of bakery foods that tend to become brittle when frozen include breads such as white bread, French bread, rolls, buns, and pizza, and confectioneries such as hotcakes, dorayaki, sponge cakes, butter cakes, hotcakes, pancakes, and muffins.
Examples of noodles include udon, Chinese noodles, and pasta.
本発明で得られる熱処理小麦粉は、ベーカリー食品用又は麺用として用いる事が好ましく、例えばベーカリー食品用ミックス又は麺用ミックスの原料として用いることができる。
本発明で得られるベーカリー食品用ミックス及び麺用ミックスは、本発明の熱処理小麦粉の製造方法で得られた熱処理小麦粉を含有するものである。本発明者は、本発明の熱処理小麦粉の製造方法で得られた熱処理小麦粉を用いることで、パン類においてしっとりもっちりした食感を有し、ホットケーキ等で冷凍耐性の高いベーカリー食品が得られることを見出したものである。また、本発明の熱処理小麦粉の製造方法で得られた熱処理小麦粉を用いることで、冷蔵耐性に優れた麺が得られる。
The heat-treated wheat flour obtained by the present invention is preferably used for bakery foods or noodles, and can be used, for example, as a raw material for bakery food mixes or noodle mixes.
The bakery food mixes and noodle mixes obtained by the present invention contain heat-treated wheat flour obtained by the heat-treated wheat flour manufacturing method of the present invention. The inventors have found that by using the heat-treated wheat flour obtained by the heat-treated wheat flour manufacturing method of the present invention, bakery foods such as breads with a moist and chewy texture and hotcakes with high freezing resistance can be obtained. Furthermore, by using the heat-treated wheat flour obtained by the heat-treated wheat flour manufacturing method of the present invention, noodles with excellent refrigeration resistance can be obtained.
本発明で得られるベーカリー食品用ミックス及び麺用ミックスは、本発明の熱処理小麦粉の製造方法で得られた熱処理小麦粉に加えて、非熱処理小麦粉を含有することが、作業性、食感、外観、内相を良好なものにしやすい点で好ましい。非熱処理小麦粉としては、熱処理されていない未処理の小麦粉を用いることができ、例えば、強力粉、準強力粉、中力粉、薄力粉、デュラム粉等が挙げられ、これらの1種を単独で又は2種以上を組み合わせて用いることができる。非熱処理小麦粉は、外国産及び国内産小麦の何れを原料とする小麦粉も使用できる。特に熱処理小麦粉の原料に国内産麦小麦粉を用いる場合に、非熱処理小麦粉として、外国産小麦を原料とする小麦粉を用いることが、入手容易性の点で好ましい。 The bakery food mixes and noodle mixes obtained by the present invention preferably contain non-heat-treated wheat flour in addition to the heat-treated wheat flour obtained by the heat-treated wheat flour manufacturing method of the present invention, as this facilitates improving workability, texture, appearance, and internal structure. Non-heat-treated wheat flour can be untreated wheat flour that has not been heat-treated, such as strong wheat flour, semi-strong wheat flour, medium-strength wheat flour, weak wheat flour, and durum wheat flour. These can be used alone or in combination of two or more. Wheat flour made from either imported or domestically produced wheat can be used as the non-heat-treated wheat flour. In particular, when domestically produced wheat flour is used as the raw material for the heat-treated wheat flour, it is preferable to use wheat flour made from imported wheat as the non-heat-treated wheat flour in terms of ease of availability.
本発明で得られるベーカリー食品用ミックス及び麺用ミックスが非熱処理小麦粉を含む場合、本発明で得られる熱処理小麦粉の配合量は、該熱処理小麦粉と非熱処理小麦粉の合計100質量部中、1質量部以上40質量部以下であることが好ましい。本発明で得られる熱処理小麦粉の配合量を1質量部以上とすることで、ベーカリー食品及び麺類において食感の改善効果が一層得やすくなる。該熱処理小麦粉の配合量を40質量部以下とすることで、製菓・製パン性・製麺性が良好となる。これらの観点から、ベーカリー食品用ミックス及び麺用ミックス中の、本発明で得られる熱処理小麦粉の配合量は、該熱処理小麦粉と非熱処理小麦粉の合計100質量部中、該熱処理小麦粉の配合量が、5質量部以上40質量部以下であることがより好ましく、10質量部以上40質量部以下であることが更に好ましい。When the bakery food mix and noodle mix obtained by the present invention contain non-heat-treated wheat flour, the amount of heat-treated wheat flour obtained by the present invention is preferably 1 part by mass or more and 40 parts by mass or less, based on 100 parts by mass of the total of the heat-treated wheat flour and non-heat-treated wheat flour. By incorporating 1 part by mass or more of the heat-treated wheat flour obtained by the present invention, the texture improvement effect in bakery foods and noodles is more easily achieved. By incorporating 40 parts by mass or less of the heat-treated wheat flour, the confectionery, bread-making, and noodle-making properties are improved. From these perspectives, the amount of heat-treated wheat flour obtained by the present invention in the bakery food mix and noodle mix is more preferably 5 parts by mass or more and 40 parts by mass or less, and even more preferably 10 parts by mass or more and 40 parts by mass or less, based on 100 parts by mass of the total of the heat-treated wheat flour and non-heat-treated wheat flour.
本発明のベーカリー食品用ミックス及び麺用ミックスにおいて本発明で得られる熱処理小麦粉と非熱処理小麦粉の合計100質量部中、非熱処理小麦粉の配合量は作業性、食感、外観、内相を良好なものとする効果が高い点から、60質量部以上99質量部以下であることが好ましく、65質量部以上95質量部以下であることがより好ましく、70質量部以上90質量部以下であることが更に好ましい。
更に、ベーカリー食品用ミックス及び麺用ミックスにおける本発明で得られる熱処理小麦粉と非熱処理小麦粉の合計量の割合は50質量%以上が好ましく、55質量%以上がより好ましく、60質量%以上が特に好ましい。特に上記の量は、作業性、食感、外観、内相を良好なものとする効果が高い点から、一般的なパン用途、ホットケーキ等の菓子用途、麺用途において好ましい。
In the bakery food mix and noodle mix of the present invention, out of a total of 100 parts by mass of the heat-treated wheat flour and non-heat-treated wheat flour obtained by the present invention, the amount of non-heat-treated wheat flour blended is preferably 60 parts by mass or more and 99 parts by mass or less, more preferably 65 parts by mass or more and 95 parts by mass or less, and even more preferably 70 parts by mass or more and 90 parts by mass or less, from the viewpoint of its high effect of improving workability, texture, appearance, and internal structure.
Furthermore, the total amount of the heat-treated wheat flour and non-heat-treated wheat flour obtained by the present invention in the bakery food mix and noodle mix is preferably 50% by mass or more, more preferably 55% by mass or more, and particularly preferably 60% by mass or more. In particular, the above amounts are preferred for general bread applications, confectionery applications such as pancakes, and noodle applications, because they are highly effective in improving workability, texture, appearance, and internal structure.
ベーカリー食品用ミックス及び麺用ミックスには、本発明で得られる熱処理小麦粉及び非熱処理小麦粉以外の他の成分を含有させることもできる。例えば、ライ麦粉、大麦粉、そば粉、米粉、豆粉、コーンフラワー等の小麦粉以外の穀粉;馬鈴薯澱粉、コーンスターチ、ワキシースターチ、小麦澱粉、及びこれらにα化、エーテル化、エステル化、架橋、酸化等の処理を施した加工澱粉;炭酸水素ナトリウム、ベーキングパウダー、炭酸アンモニウム、炭酸水素アンモニウム、塩化アンモニウム等の膨張剤或いはイースト;サラダ油等の油脂類;砂糖等の糖類;全卵、卵白、卵黄等の卵類;牛乳、脱脂粉乳、バター等の乳製品;食塩等の塩類;乳化剤、増粘剤、酸味料、香料、香辛料、着色料、果汁、果実、ビタミン類、かん水等が挙げられ、これらの1種を単独で又は2種以上を組み合わせて用いることができる。これらの他の成分は、本発明で得られる熱処理小麦粉と非熱処理小麦粉との混合時に一緒に混合してもよいし、前記熱処理小麦粉と非熱処理小麦粉の一方に予め混合しておいてもよいし、前記熱処理小麦粉と非熱処理小麦粉の混合後に更に混合させてもよい。Bakery food mixes and noodle mixes can also contain ingredients other than the heat-treated wheat flour and non-heat-treated wheat flour obtained by the present invention. Examples include cereal flours other than wheat flour, such as rye flour, barley flour, buckwheat flour, rice flour, soy flour, and corn flour; potato starch, corn starch, waxy starch, wheat starch, and modified starches obtained by pregelatinizing, etherifying, esterifying, crosslinking, or oxidizing these; leavening agents or yeast, such as sodium bicarbonate, baking powder, ammonium carbonate, ammonium bicarbonate, and ammonium chloride; fats and oils, such as salad oil; sugars, such as sugar; eggs, such as whole eggs, egg whites, and egg yolks; dairy products, such as milk, skim milk powder, and butter; salts, such as salt; emulsifiers, thickeners, acidulants, flavorings, spices, colorings, fruit juice, fruits, vitamins, and brine. These ingredients can be used alone or in combination. These other ingredients may be mixed together when the heat-treated wheat flour and non-heat-treated wheat flour obtained by the present invention are mixed, or may be mixed in advance with one of the heat-treated wheat flour and non-heat-treated wheat flour, or may be further mixed after the heat-treated wheat flour and non-heat-treated wheat flour are mixed.
以上、本発明をその好ましい実施形態に基づき説明したが、上記又は下記の実施例に記載の好ましい構成を上記又は下記に記載の別の任意の好ましい構成と組み合わせることが可能である。なお、ここでいう好ましい構成とは更に好ましい、特に好ましい等の段階を一切問わず何れの段階のものを何れの段階のものとも組み合わせ可能とする。 The present invention has been described above based on its preferred embodiments, but the preferred configurations described in the examples above or below can be combined with any other preferred configurations described above or below. Note that the preferred configurations referred to here are not limited to more preferred, particularly preferred, etc., and can be combined with any other configuration at any stage.
本発明を具体的に説明するために実施例を挙げるが、本発明は以下の実施例によって制限されるものではない。なお、各実施例・比較例において容器内の水蒸気温度は90~130℃の範囲内、容器内の圧力はゲージ圧10~100kPaの範囲内とし、水蒸気流量を上記範囲内とした。 The following examples are provided to specifically explain the present invention, but the present invention is not limited to these examples. In each example and comparative example, the steam temperature inside the container was in the range of 90 to 130°C, the gauge pressure inside the container was in the range of 10 to 100 kPa, and the steam flow rate was within the above ranges.
(比較例1~3)
表1に示す銘柄の小麦の粉砕物をそのまま比較例の小麦粉とした。なお、「1CW」は「No.1 Canada Western」、「WW」は「Western White」、「ASW」は「Australian Standard White」の略である。
(Comparative Examples 1 to 3)
The ground wheat flour of the brands shown in Table 1 was used as is as the comparative wheat flour. Note that "1CW" stands for "No. 1 Canada Western,""WW" stands for "Western White," and "ASW" stands for "Australian Standard White."
(実施例1~4、6、比較例4~7)
ヒートジャケットと1軸エクストルーダーを備えた密閉容器を、予め表1に記載した雰囲気温度に達温させた。具体的には、蒸気を熱源としたヒートジャケットにより、密閉容器をその外部から加温し、容器内の雰囲気温度を表1に記載の温度に達温させた。
その後、表1に記載した品種・銘柄の小麦を製粉した小麦粉を用意した。小麦粉のアミロース含量は表1に示す通りであった。
80℃に加熱した水を小麦粉に対し表1に記載の量、用意した。前記密閉容器に小麦粉と、前記の加熱した水とを入れて混合し、前記所定の雰囲気温度に設定された該密閉容器内にて5秒間加熱した後、密閉容器から排出した。加熱完了時の混合物の温度(密閉容器出口における混合物の温度)は表1に示す温度であった。加熱処理後の混合物を、粒状化工程を経ることなく棚乾燥によって水分含量が10質量%以上14質量%以下となるように50℃にて12-24時間乾燥した後、ピンミルで熱処理小麦粉を粉砕し、混合物粒子を粉砕熱処理小麦粉として回収した。得られた粉砕熱処理小麦粉の糊化度を前記方法により測定した。なお熱処理時に容器内に飽和水蒸気を導入して加圧下で混合物を加熱したが、加熱完了時の混合物の温度を表1の温度とするために、容器内における該水蒸気の流量を調整した。
(Examples 1 to 4, 6, Comparative Examples 4 to 7)
A sealed container equipped with a heat jacket and a single-screw extruder was heated in advance to the ambient temperature shown in Table 1. Specifically, the sealed container was heated from the outside by a heat jacket using steam as a heat source, and the ambient temperature inside the container was heated to the temperature shown in Table 1.
Thereafter, wheat flour was prepared by milling the varieties and brands of wheat listed in Table 1. The amylose contents of the wheat flour were as shown in Table 1.
Water heated to 80°C was prepared in the amount shown in Table 1 relative to the amount of wheat flour. The wheat flour and the heated water were mixed in the sealed container, heated for 5 seconds in the sealed container set to the predetermined ambient temperature, and then discharged from the sealed container. The temperature of the mixture at the completion of heating (the temperature of the mixture at the outlet of the sealed container) was the temperature shown in Table 1. The heat-treated mixture was dried at 50°C for 12-24 hours by shelf drying without a granulation step to a moisture content of 10% to 14% by mass. The heat-treated wheat flour was then pulverized in a pin mill, and the resulting mixture particles were recovered as pulverized heat-treated wheat flour. The degree of gelatinization of the resulting pulverized heat-treated wheat flour was measured using the method described above. During the heat treatment, saturated steam was introduced into the container to heat the mixture under pressure. The flow rate of the steam in the container was adjusted to achieve the temperature shown in Table 1 at the completion of heating.
(実施例5)
実施例1において、容器内の水蒸気流量を調整することで加熱完了時の混合物の温度(密閉容器出口における混合物の温度)の温度を100℃以下(95℃)に変更した以外は実施例1と同様とした。得られた粉砕熱処理小麦粉の糊化度を前記方法により測定した。
Example 5
The procedure was the same as in Example 1, except that the temperature of the mixture at the end of heating (temperature of the mixture at the outlet of the sealed container) was changed to 100°C or lower (95°C) by adjusting the steam flow rate inside the container. The degree of gelatinization of the obtained pulverized heat-treated wheat flour was measured by the above-mentioned method.
(試験例1)
実施例1~6、比較例4~7の粉砕熱処理小麦粉又は比較例1の小麦粉を用いて、下記方法によりベーカリー食品の一種である食パンを製造した。
(Test Example 1)
Using the ground heat-treated wheat flour of Examples 1 to 6 and Comparative Examples 4 to 7 or the wheat flour of Comparative Example 1, bread, a type of bakery food, was produced by the following method.
市販の製パン用ミキサー(株式会社ダルトン製、万能混合機 型式5DM-03-r)におけるミキシングボウルに、非熱処理の強力粉であるミリオン(日清製粉(株))320gと、評価対象の熱処理小麦粉80g又は比較例1の小麦粉80gと、食塩8gと、砂糖32gと、生イースト(オリエンタル酵母工業製「オリエンタルイースト」)9.2gと、イーストフード(オリエンタル酵母工業製「Cイーストフード」)0.4gと、適正量の水とを投入し、ミキシング工程を実施してパン生地を調製した。
具体的には低速で4分間ミキシングを行った後、高速で2分間ミキシングを行い、さらに、16gの油脂を添加して低速で4分間ミキシングを行った後、高速で1分間混捏した(捏上温度27℃)。こうして得られたパン生地を、温度27℃、相対湿度75%の条件下で1時間発酵させた後、450gに分割して丸め、ベンチタイムを30分間とった後、パン生地を棒状にして食パン型に詰めた。そして、ホイロ(温度38℃、相対湿度85%の雰囲気下)を60分間行った後、温度200℃で30分間焼成して食パンを得た。
Into the mixing bowl of a commercially available bread mixer (Dalton Co., Ltd., universal mixer model 5DM-03-r), 320 g of non-heat-treated strong flour Million (Nissin Flour Milling Inc.), 80 g of the heat-treated wheat flour to be evaluated or 80 g of the wheat flour of Comparative Example 1, 8 g of salt, 32 g of sugar, 9.2 g of fresh yeast (Oriental Yeast Co., Ltd., "Oriental Yeast"), 0.4 g of yeast food (Oriental Yeast Co., Ltd., "C Yeast Food"), and an appropriate amount of water were added, and a mixing step was carried out to prepare bread dough.
Specifically, the dough was mixed at low speed for 4 minutes, then at high speed for 2 minutes, and then 16 g of oil was added and mixed at low speed for 4 minutes, followed by kneading at high speed for 1 minute (kneading temperature: 27°C). The dough thus obtained was fermented for 1 hour at 27°C and 75% relative humidity, then divided into 450 g portions and rolled into balls. After 30 minutes of bench time, the dough was rolled into a loaf shape and packed into a loaf mold. The dough was then proofed for 60 minutes (in an atmosphere of 38°C and 85% relative humidity) and baked at 200°C for 30 minutes to obtain loaf bread.
得られた食パンを4℃で1日間静置した後、得られた食パンの食感を10名の専門パネラーに下記評価基準に基づいて評価してもらった。パネラーの評価点の平均を表1に示す。
(食パンの食感の評価基準)
5点:全体が充分にしっとりもっちりした食感を有し、食味・食感は良好。
4点:部分的にしっとり感やソフト感に欠ける場合があるものの、全体としてはしっとりもっちりした食感を有し、食味・食感は問題ない。
3点:しっとり感やもっちり感が少し感じられる。
2点:全体にしっとり感やもっちり感が少なく、ややパサつく。
1点:全体に硬過ぎるか又はパサついた食感であり、食味・食感は不良。
The resulting bread was left to stand at 4°C for 1 day, and then the texture of the resulting bread was evaluated by 10 expert panelists based on the following evaluation criteria. The average evaluation scores of the panelists are shown in Table 1.
(Evaluation criteria for bread texture)
5 points: The whole product has a sufficiently moist and chewy texture, and the taste and texture are good.
4 points: Although it may lack moistness or softness in some areas, it has a moist and chewy texture overall, and there are no problems with the taste or texture.
3 points: A slight moist and chewy feeling is felt.
2 points: Overall, it is not very moist or chewy, and is a bit dry.
1 point: The whole product is too hard or has a dry texture, and the taste and texture are poor.
(試験例2)
実施例1~6、比較例4~7の粉砕熱処理小麦粉又は比較例2の小麦粉を用いて、下記方法によりベーカリー食品の一種であるホットケーキを製造した。
粉体原料として、非熱処理の薄力粉であるフラワー(日清製粉(株))40g、評価対象の熱処理小麦粉10g又は比較例2の小麦粉10g、上白糖12.5g、ベーキングパウダー2.5gを混合後、ボウル内で、液体原料として、サラダ油5g、全卵液15g、牛乳40g、水30gを加え、ホイッパーを用い、ハンドミキシングにて1分120rpmで撹拌後、180℃表3分裏2分で焼成した。焼成物を27℃30分放冷後、包装し、30日間、-5℃にて保管し、食感の評価に用いた。
(Test Example 2)
Using the ground heat-treated wheat flour of Examples 1 to 6 and Comparative Examples 4 to 7 or the wheat flour of Comparative Example 2, hot cakes, which are a type of bakery food, were produced by the following method.
As powder ingredients, 40 g of non-heat-treated flour (Nissin Flour Milling Co., Ltd.), 10 g of the heat-treated wheat flour to be evaluated or 10 g of the wheat flour of Comparative Example 2, 12.5 g of caster sugar, and 2.5 g of baking powder were mixed, and then 5 g of salad oil, 15 g of whole egg liquid, 40 g of milk, and 30 g of water were added to a bowl as liquid ingredients. The mixture was mixed by hand using a whisk at 120 rpm for 1 minute and then baked at 180°C for 3 minutes on the front and 2 minutes on the back. The baked product was allowed to cool at 27°C for 30 minutes, packaged, and stored at -5°C for 30 days before being used to evaluate the texture.
冷凍したホットケーキを27℃の環境下に2時間放置して解凍した。次いで、ホットケーキの脆い食感を10名の専門パネラーに下記評価基準に基づいて評価してもらった。パネラーの評価点の平均を表1に示す。
(ホットケーキの食感の評価基準)
5点:非常にしっとりもっちりし、非常に良好な食感
4点:しっとりもっちりし、良好な食感
3点:ややしっとりもっちりし、やや良好な食感
2点:やや脆くパサつき、やや好ましくない食感
1点:非常に脆くパサつき、非常に好ましくない食感
The frozen hotcakes were left to thaw for 2 hours at 27°C. Then, the brittle texture of the hotcakes was evaluated by 10 expert panelists based on the following evaluation criteria. The average evaluation scores of the panelists are shown in Table 1.
(Evaluation criteria for hotcake texture)
5 points: Very moist and chewy, very good texture 4 points: Moist and chewy, good texture 3 points: Slightly moist and chewy, somewhat good texture 2 points: Slightly brittle and dry, somewhat undesirable texture 1 point: Very brittle and dry, very undesirable texture
(試験例3)
実施例1~6、比較例4~7の粉砕熱処理小麦粉又は比較例3の小麦粉を用いて、下記方法により麺を製造した。
試験対象の小麦粉20質量部と、非熱処理の中力粉である麺八州(日清製粉(株))80質量部とを混合し、これに塩1質量部と水40質量部を加え、ミキサー(ホバート製)にて低速5分で混合し、得たそぼろ状の麺生地を製麺ロールにてまとめ、複合、圧延、製麺し、厚さ3mm幅4mmの麺線を作成した。その麺線を11分間茹で、冷水にて冷却後、密封容器にて4℃2日間保管後に、麺の老化耐性を評価した。
(麺の食感の評価基準)
5点:非常にもっちりし、非常になめらかで、非常に良好な食感
4点:もっちりし、なめらかで、良好な食感
3点:ややもっちり、ややなめらかで、やや良好な食感
2点:やや脆く、若干なめらかで、やや好ましくない食感
1点:非常に脆く、なめらかさがなく、非常に好ましくない食感
(Test Example 3)
Noodles were produced by the following method using the ground, heat-treated wheat flour of Examples 1 to 6 and Comparative Examples 4 to 7, or the wheat flour of Comparative Example 3.
20 parts by mass of the wheat flour to be tested was mixed with 80 parts by mass of Menhachishu (Nissin Flour Milling Co., Ltd.), a non-heat-treated medium-strength flour, to which 1 part by mass of salt and 40 parts by mass of water were added and mixed at low speed in a mixer (manufactured by Hobart) for 5 minutes. The resulting crumbly noodle dough was gathered together in a noodle roller, combined, rolled, and made into noodle strands measuring 3 mm in thickness and 4 mm in width. The noodle strands were boiled for 11 minutes, cooled in cold water, and stored in a sealed container at 4°C for 2 days, after which the aging resistance of the noodles was evaluated.
(Evaluation criteria for noodle texture)
5 points: Very chewy, very smooth, very good texture 4 points: Chewy, smooth, good texture 3 points: Slightly chewy, slightly smooth, somewhat good texture 2 points: Slightly brittle, slightly smooth, somewhat unpleasant texture 1 point: Very brittle, not smooth, very unpleasant texture
表1に示す通り、所定のアミロース含量の小麦粉に所定量で所定温度の水による加水による所定時間の熱処理行い特定の糊化度とした各実施例において、食パンのしっとりもっちりした食感、及びホットケーキの長期冷凍後の脆くなり難さ、冷蔵後の麺のもっちりしたなめらかな食感がいずれも得られていた。特に、混合物温度を100℃超とした場合、優れた食感改善効果が得られていた。
一方、アミロース含量が比較的高い比較例4~6の小麦粉では、特に加水が十分でない場合に、パンの食感に劣り、長期冷凍保存したホットケーキの食感も脆く・パサつく食感であり、麺も脆い食感となっていた。また比較例7のようにアミロース含量が25%以下のチクゴイズミを用いた場合も、実施例に比して、加水が十分でない場合、パン食感に劣り、また、長期冷凍保存したホットケーキの食感もやや脆く・パサつく食感であり、麺も脆く、なめらかさが低下していた。
As shown in Table 1, in each example in which wheat flour with a predetermined amylose content was hydrated with a predetermined amount of water at a predetermined temperature and heat-treated for a predetermined time to achieve a specific degree of gelatinization, a moist and chewy texture was obtained for bread, pancakes were less likely to become brittle after long-term freezing, and noodles had a chewy and smooth texture after refrigeration. In particular, when the mixture temperature was set above 100°C, an excellent texture improvement effect was obtained.
On the other hand, with the wheat flours of Comparative Examples 4 to 6, which had a relatively high amylose content, the bread had an inferior texture, and the hotcakes stored frozen for a long time had a brittle and dry texture, and the noodles also had a brittle texture, especially when the hydration was insufficient. Furthermore, when Chikugoizumi wheat flour with an amylose content of 25% or less was used as in Comparative Example 7, the bread had an inferior texture compared to the Examples when the hydration was insufficient, and the hotcakes stored frozen for a long time had a slightly brittle and dry texture, and the noodles were brittle and less smooth.
Claims (2)
前記加熱処理により、前記小麦粉と前記水との混合物の加熱処理完了時点における温度を100℃超110℃以下とする、熱処理小麦粉の製造方法。 A method for producing heat-treated wheat flour, comprising: combining 100 parts by mass of wheat flour having an amylose content of 25% or less with 30 to 45 parts by mass of water at 70°C or higher to obtain a mixture; and heating the mixture at an ambient temperature of 100°C or higher but lower than 120°C for 3 to 60 seconds to obtain heat-treated wheat flour with a gelatinization degree of 50% to 95%;
The method for producing heat-treated wheat flour, wherein the temperature of the mixture of wheat flour and water at the completion of the heat treatment is higher than 100°C and not higher than 110°C by the heat treatment .
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|---|---|---|---|---|
| JP2000262205A (en) | 1999-03-16 | 2000-09-26 | Shikishima Baking Co Ltd | Production of bread |
| JP2003333991A (en) | 2002-05-19 | 2003-11-25 | Torigoe Flour Milling Co Ltd | New cake and method for producing the same |
| JP2007097507A (en) | 2005-10-05 | 2007-04-19 | Nisshin Flour Milling Inc | Quality improvement method of low amylo flour |
| WO2016121570A1 (en) | 2015-01-26 | 2016-08-04 | 日清フーズ株式会社 | Production method for heat treated wheat flour and production method for bakery food mix |
| JP2017035074A (en) | 2015-08-07 | 2017-02-16 | 日清フーズ株式会社 | Process for producing ground heat-treated flour and process for producing bakery food mix |
| JP2019088255A (en) | 2017-11-16 | 2019-06-13 | 日清製粉株式会社 | Material for bread, its production method and production method of bread using the same |
| JP2019126313A (en) | 2018-01-26 | 2019-08-01 | 日本製粉株式会社 | Wheat grain and manufacturing method thereof |
| WO2021095827A1 (en) | 2019-11-15 | 2021-05-20 | 日清製粉プレミックス株式会社 | Method for producing heated and ground wheat flour, heated and ground wheat flour, mix for bakery foods and method for producing same |
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| Publication number | Priority date | Publication date | Assignee | Title |
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| JP5178404B2 (en) * | 2008-09-01 | 2013-04-10 | 松谷化学工業株式会社 | Bread production method |
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Patent Citations (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2000262205A (en) | 1999-03-16 | 2000-09-26 | Shikishima Baking Co Ltd | Production of bread |
| JP2003333991A (en) | 2002-05-19 | 2003-11-25 | Torigoe Flour Milling Co Ltd | New cake and method for producing the same |
| JP2007097507A (en) | 2005-10-05 | 2007-04-19 | Nisshin Flour Milling Inc | Quality improvement method of low amylo flour |
| WO2016121570A1 (en) | 2015-01-26 | 2016-08-04 | 日清フーズ株式会社 | Production method for heat treated wheat flour and production method for bakery food mix |
| JP2017035074A (en) | 2015-08-07 | 2017-02-16 | 日清フーズ株式会社 | Process for producing ground heat-treated flour and process for producing bakery food mix |
| JP2019088255A (en) | 2017-11-16 | 2019-06-13 | 日清製粉株式会社 | Material for bread, its production method and production method of bread using the same |
| JP2019126313A (en) | 2018-01-26 | 2019-08-01 | 日本製粉株式会社 | Wheat grain and manufacturing method thereof |
| WO2021095827A1 (en) | 2019-11-15 | 2021-05-20 | 日清製粉プレミックス株式会社 | Method for producing heated and ground wheat flour, heated and ground wheat flour, mix for bakery foods and method for producing same |
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| CN116507207B (en) | 2026-02-24 |
| KR20230078946A (en) | 2023-06-05 |
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| WO2023095231A1 (en) | 2023-06-01 |
| JPWO2023095231A1 (en) | 2023-06-01 |
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