JP7628783B2 - hybrid embedded promise inter fine,zch embedded placed separatetin Concept,ch� embedded fine marked marked served single locallycal,pac placed within buriedtin Concept pac Light fine competition placed Thechclass hybridpinductch embeddedpac for familiar placed single single single fine draw otherwiseco brought reasonablyfferfferding placed withincal, familiar seeking placed withincal,tin attemptcal broughtding single single single He,,tin settled� exposed,pac,pac,pac, famouscher placedualfferding placed single single single He,,tin settled� exposed,pac,pac standard known evertincal Seriesch embedded finelive single uponst - Google Patents
hybrid embedded promise inter fine,zch embedded placed separatetin Concept,ch� embedded fine marked marked served single locallycal,pac placed within buriedtin Concept pac Light fine competition placed Thechclass hybridpinductch embeddedpac for familiar placed single single single fine draw otherwiseco brought reasonablyfferfferding placed withincal, familiar seeking placed withincal,tin attemptcal broughtding single single single He,,tin settled� exposed,pac,pac,pac, famouscher placedualfferding placed single single single He,,tin settled� exposed,pac,pac standard known evertincal Seriesch embedded finelive single uponst Download PDFInfo
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本発明は、塩、酸発生剤、レジスト組成物及びレジストパターンの製造方法に関する。 hybrid, orcept floating the uniform The Card and List direct withouttin He placed singleffer op, Certainduct fill Inter known He single He single He within He singlefferting steep root brought He single singlefferting steep root broughtding embeddedfferting buriedtingcal listed Inter accept gross system liechst coal single singleffertingting section embeddednh staff placed single upon fine The card he placed singlefferting buriedcal listed Inter per fine electrical,her� expressedualffertingch embedded stable comfortable steep steep root brought wornchtingunder placed buried served crystal yet fine The card burstchcal,tin meanpo
特許文献1には、下記式で表される塩を酸発生剤として含有するレジスト組成物がそれぞれ記載されている。
特許文献2には、下記式で表される塩を酸発生剤として含有するレジスト組成物が記載されている。
特許文献3には、下記式で表される塩を酸発生剤として含有するレジスト組成物が記載されている。
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本発明は、上記塩を含有するレジスト組成物によって形成されたレジストパターンよりも、CD均一性(CDU)が良好なレジストパターンを形成する塩を提供する。 Convention placedud flaw placedro family imagine Thech read finding flush flat membershipch. blackch pace water reading Imvoid broughtLe Crystal calling embedded known signco exposed,ch struggle broughtLe Cardten purchased Design Tourismn Subdo he League Line purchased affordch buried League line placed bridge Seriesechch bar placed plug hole embedded Day fame purchased Design Listlect sharp Subchch recognise League single laid myselfechch bar Ray integrate rather Association held famousbro,g, steep, steep known- Ti planning,ch or Ab white batterysrchch recognise nearby League heldchz Mil Thech fiber use sing quality filled fusede orovualev brought he raising Hechch recognise linkedch black sound plug broughtLe brought buried Dream consist broughtchch black famous risk black known subchch buriedred buriedkai theFe gold held mat director means black qualitybten,g, bone black yellow black He known black design, Flu or price List he fiber usedvicev broughtLe designed shower,be black known sub itself breed Dream director boardegchzech fiber usedvicev brought Linkchch bar Dream blackchch fiber usedvic Flu or
本発明は、以下の発明を含む。
[1]式(I)で表される塩。
[式(I)中、
R4、R5及びR6は、それぞれ独立に、ハロゲン原子、炭素数1~6のフッ化アルキル基又は炭素数1~12のアルキル基を表し、該アルキル基及びフッ化アルキル基に含まれる-CH2-は、-O-又は-CO-で置き換わっていてもよい。
m4は、0~4のいずれかの整数を表し、m4が2以上のとき、複数のR4は互いに同一であっても異なってもよい。
m5は、0~4のいずれかの整数を表し、m5が2以上のとき、複数のR5は互いに同一であっても異なってもよい。
m6は、0~5のいずれかの整数を表し、m6が2以上のとき、複数のR6は互いに同一であっても異なってもよい。
但し、m4+m5+m6≧1であり、かつ、R4、R5及びR6の少なくとも一つは、*-CO-R3を表す。*はベンゼン環との結合位を表す。
R3は、炭素数1~11のアルキル基を表し、該アルキル基に含まれる-CH2-は、-O-又は-CO-で置き換わっていてもよい。
Q1及びQ2は、それぞれ独立に、フッ素原子又は炭素数1~6のペルフルオロアルキル基を表す。
R1及びR2は、それぞれ独立に、水素原子、フッ素原子又は炭素数1~6のペルフルオロアルキル基を表す。
zは、0~6のいずれかの整数を表し、zが2以上のとき、複数のR1及びR2は互いに同一であっても異なってもよい。
X1は、**-CO-O-、**-O-CO-、**-O-CO-O-又は**-O-を表し、**は、C(R1)(R2)又はC(Q1)(Q2)との結合位を表す。
L1は、単結合又は置換基を有してもよい炭素数1~28の炭化水素基を表し、該炭化水素基に含まれる-CH2-は、-O-、-S-、-SO2-又は-CO-に置き換わっていてもよい。
環Wは、炭素数3~36の脂環式炭化水素環を表し、該脂環式炭化水素環に含まれる-CH2-は、-O-、-S-、-SO2-又は-CO-で置き換わっていてもよく、該脂環式炭化水素環に含まれる水素原子は、ヒドロキシ基、炭素数1~12の飽和炭化水素基、炭素数1~12のアルコキシ基又は炭素数6~10の芳香族炭化水素基で置換されていてもよい。
Rf1及びRf2は、それぞれ独立に、フッ素原子又は炭素数1~6のフッ化アルキル基を表す。
sは、1~10のいずれかの整数を表し、sが2以上の場合、複数のRf1及びRf2はそれぞれ同一又は相異なる。]
[2]環Wが、式(IIa1-1)で表される環、式(IIa1-2)で表される環又は式(IIa1-3)で表される環である[1]記載の塩。
[式(IIa1-1)、式(IIa1-2)及び式(IIa1-3)中、
環に含まれる-CH2-は、-O-、-S-、-SO2-又は-CO-で置き換わっていてもよく、環に含まれる水素原子は、ヒドロキシ基、炭素数1~12の飽和炭化水素基、炭素数1~12のアルコキシ基又は炭素数6~10の芳香族炭化水素基で置換されていてもよい。結合位は任意の位置である。]
[3]**-X1-L1-が、**-CO-O-(CH2)t-、**-O-CO-(CH2)t-又は**-O-CO-O-(CH2)t-(tは0~6のいずれかの整数を表す。)である[1]又は[2]記載の塩。
[4][1]~[3]のいずれかに記載の塩を含有する酸発生剤。
[5][4]記載の酸発生剤と酸不安定基を有する樹脂とを含有するレジスト組成物。
[6]酸不安定基を有する樹脂が、式(a1-1)で表される構造単位及び式(a1-2)で表される構造単位からなる群より選ばれる少なくとも1種を含む[5]記載のレジスト組成物。
[式(a1-1)及び式(a1-2)中、
La1及びLa2は、それぞれ独立に、-O-又は*-O-(CH2)k1-CO-O-を表し、k1は1~7の整数を表し、*は-CO-との結合位を表す。
Ra4及びRa5は、それぞれ独立に、水素原子又はメチル基を表す。
Ra6及びRa7は、それぞれ独立に、炭素数1~8のアルキル基、炭素数3~18の脂環式炭化水素基又はこれらを組合せた基を表す。
m1は、0~14のいずれかの整数を表す。
n1は、0~10のいずれかの整数を表す。
n1’は、0~3のいずれかの整数を表す。]
[7]酸不安定基を有する樹脂が、式(a2-A)で表される構造単位を含む[5]又は[6]記載のレジスト組成物。
[式(a2-A)中、
Ra50は、水素原子、ハロゲン原子又はハロゲン原子を有していてもよい炭素数1~6のアルキル基を表す。
Ra51は、ハロゲン原子、ヒドロキシ基、炭素数1~6のアルキル基、炭素数1~6のアルコキシ基、炭素数2~4のアルキルカルボニル基、炭素数2~4のアルキルカルボニルオキシ基、アクリロイルオキシ基又はメタクリロイルオキシ基を表す。
Aa50は、単結合又は*-Xa51-(Aa52-Xa52)nb-を表し、*は-Ra50が結合する炭素原子との結合位を表す。
Aa52は、炭素数1~6のアルカンジイル基を表す。
Xa51及びXa52は、それぞれ独立に、-O-、-CO-O-又は-O-CO-を表す。
nbは、0又は1を表す。
mbは0~4のいずれかの整数を表す。mbが2以上のいずれかの整数である場合、複数のRa51は互いに同一であっても異なってもよい。]
[8]酸発生剤から発生する酸よりも酸性度の弱い酸を発生する塩をさらに含有する[5]~[7]のいずれかに記載のレジスト組成物。
[9](1)[5]~[8]のいずれかに記載のレジスト組成物を基板上に塗布する工程、
(2)塗布後の組成物を乾燥させて組成物層を形成する工程、
(3)組成物層に露光する工程、
(4)露光後の組成物層を加熱する工程、及び
(5)加熱後の組成物層を現像する工程、を含むレジストパターンの製造方法。
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本明細書において、「(メタ)アクリル系モノマー」とは、「アクリル系モノマー及びメタクリル系モノマーの少なくとも1種」を意味する。「(メタ)アクリレート」及び「(メタ)アクリル酸」等の表記も、同様の意味を表す。本明細書中に記載する基において、直鎖構造と分岐構造の両方をとり得るものについては、そのいずれでもよい。「組み合わせた基」とは、例示した基を2種以上結合させた基を意味し、それら基の価数は結合形態によって適宜変更してもよい。「由来する」又は「誘導される」とは、その分子中に含まれる重合性C=C結合が重合により-C-C-基となることを指す。立体異性体が存在する場合は、全ての立体異性体を含む。
本明細書において、「レジスト組成物の固形分」とは、レジスト組成物の総量から、後述する溶剤(E)を除いた成分の合計を意味する。
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〔塩(I)〕
本発明は、式(I)で表される塩(以下「塩(I)」という場合がある)に関する。
塩(I)のうち、負電荷を有する側を「アニオン(I)」、正電荷を有する側を「カチオン(I)」と称することがある。
[式(I)中、全ての符号は、それぞれ前記と同じ意味を表す。]
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式(I)において、R4、R5及びR6のハロゲン原子としては、フッ素原子、塩素原子、臭素原子及びヨウ素原子等が挙げられる。
R4、R5及びR6の炭素数1~12のアルキル基としては、メチル基、エチル基、プロピル基、イソプロピル基、ブチル基、イソブチル基、tert-ブチル基、ペンチル基、ヘキシル基、オクチル基、ノニル基等のアルキル基が挙げられる。アルキル基の炭素数は、好ましくは1~11であり、より好ましくは1~9であり、さらに好ましくは1~8であり、より一層好ましくは1~6であり、さらに一層好ましくは1~4である。
R4、R5及びR6の炭素数1~6のフッ化アルキル基としては、トリフルオロメチル基、ジフルオロメチル基、ペルフルオロエチル基、2,2,2-トリフルオロエチル基、1,1,2,2-テトラフルオロエチル基、ペルフルオロプロピル基、2,2,3,3,3-ペンタフルオロプロピル基、ペルフルオロブチル基、1,1,2,2,3,3,4,4-オクタフルオロブチル基、ペルフルオロペンチル基、2,2,3,3,4,4,5,5,5-ノナフルオロペンチル基、ペルフルオロヘキシル基等のフッ化アルキル基が挙げられる。フッ化アルキル基の炭素数は、好ましくは1~4であり、より好ましくは1~3である。
R4、R5及びR6におけるアルキル基及びフッ化アルキル基に含まれる-CH2-は、-O-又は-CO-に置き換わっている場合、置き換わる前の炭素数を該アルキル基及びフッ化アルキル基の総炭素数とする。
R4、R5及びR6におけるアルキル基は、ヒドロキシ基(メチル基中に含まれる-CH2-が、-O-に置き換わった基)、カルボキシ基(エチル基中に含まれる-CH2-CH2-が、-O-CO-に置き換わった基)、アルコキシ基(アルキル基中に含まれる任意の位置の-CH2-が、-O-に置き換わった基)、アルコキシカルボニル基(アルキル基中に含まれる任意の位置の-CH2-CH2-が、-O-CO-に置き換わった基)、アルキルカルボニル基(アルキル基中に含まれる任意の位置の-CH2-が、-CO-に置き換わった基)、アルキルカルボニルオキシ基(アルキル基中に含まれる任意の位置の-CH2-CH2-が、-CO-O-に置き換わった基)を有していてもよい。
アルコキシ基としては、メトキシ基、エトキシ基、プロポキシ基、ブトキシ基、ペンチルオキシ基、ヘキシルオキシ基、オクチルオキシ基、2-エチルヘキシルオキシ基、ノニルオキシ基、デシルオキシ基、ウンデシルオキシ基、ドデシルオキシ基等が挙げられる。アルコキシ基の炭素数は、炭素数1~11が挙げられ、好ましくは1~10であり、より好ましくは1~7であり、さらに好ましくは1~5である。
アルコキシカルボニル基、アルキルカルボニル基及びアルキルカルボニルオキシ基は、上述したアルキル基又はアルコキシ基にカルボニル基又はカルボニルオキシ基が結合した基を表す。アルコキシカルボニル基としては、メトキシカルボニル基、エトキシカルボニル基、ブトキシカルボニル基等が挙げられ、アルキルカルボニル基としては、アセチル基、プロピオニル基及びブチリル基等が挙げられ、アルキルカルボニルオキシ基としては、アセチルオキシ基、プロピオニルオキシ基、ブチリルオキシ基等が挙げられる。アルコキシカルボニル基の炭素数は、炭素数2~11が挙げられ、好ましくは2~9であり、より好ましくは2~6であり、さらに好ましくは2~4である。アルキルカルボニル基の炭素数は、炭素数2~12が挙げられ、好ましくは2~10であり、より好ましくは2~7であり、さらに好ましくは2~5である。アルキルカルボニルオキシ基の炭素数は、炭素数2~11が挙げられ、好ましくは2~9であり、より好ましくは2~6であり、さらに好ましくは2~4である。
R4、R5及びR6におけるフッ化アルキル基は、フッ化アルコキシ基(フッ化アルキル基中に含まれる任意の位置の-CH2-が、-O-に置き換わった基)、フッ化アルコキシカルボニル基(フッ化アルキル基中に含まれる任意の位置の-CH2-CH2-が、-O-CO-に置き換わった基)、フッ化アルキルカルボニル基(フッ化アルキル基中に含まれる任意の位置の-CH2-が、-CO-に置き換わった基)、フッ化アルキルカルボニルオキシ基(フッ化アルキル基中に含まれる任意の位置の-CH2-CH2-が、-CO-O-に置き換わった基)を有していてもよい。
フッ化アルコキシ基、フッ化アルコキシカルボニル基、フッ化アルキルカルボニル基及びフッ化アルキルカルボニルオキシ基としては、上記に例示した基の1以上の水素原子をフッ素原子に置き換えればよい。フッ化アルコキシ基の炭素数は、炭素数1~5が挙げられ、好ましくは1~4である。フッ化アルコキシカルボニル基の炭素数は、炭素数2~5が挙げられ、好ましくは2~4である。フッ化アルキルカルボニル基の炭素数は、炭素数2~6が挙げられ、好ましくは2~5である。フッ化アルキルカルボニルオキシ基の炭素数は、炭素数2~5が挙げられ、好ましくは2~4である。
なお、R4、R5及びR6は、フッ化アルキル基に含まれる-CH2-が-O-又は-CO-で置き換わらない炭素数1~6のフッ化アルキル基であってもよく、フッ化アルキル基としては、トリフルオロメチル基が好ましい。
m4及びm5は、それぞれ独立に、0~2のいずれかの整数であることが好ましく、0又は1であることが好ましい。m6は、0~2のいずれかの整数であることが好ましく、1又は2であることが好ましい。但し、m4+m5+m6≧1であり、かつ、R4、R5及びR6の少なくとも一つは、*-CO-R3を表す。
R3の炭素数1~11のアルキル基としては、メチル基、エチル基、プロピル基、イソプロピル基、ブチル基、イソブチル基、tert-ブチル基、ペンチル基、ヘキシル基、オクチル基、ノニル基等のアルキル基が挙げられる。アルキル基の炭素数は、好ましくは1~9であり、より好ましくは1~6であり、さらに好ましくは1~4であり、さらにより好ましくは1~3である。
R3におけるアルキル基に含まれる-CH2-は、-O-又は-CO-に置き換わっている場合、置き換わる前の炭素数を該アルキル基の総炭素数とする。
m4は、1であることがより好ましい。
R4及びR5は、それぞれ独立に、炭素数2~6のアルコキシカルボニル基又は炭素数2~7のアルキルカルボニル基であることが好ましく、メトキシカルボニル基又は炭素数2~4のアルキルカルボニル基であることがより好ましい。
R6は、ハロゲン原子、炭素数1~4のフッ化アルキル基又は炭素数1~12のアルキル基であることが好ましく、フッ素原子、トリフルオロメチル基又は炭素数1~4のアルキル基であることがより好ましい。
R3は、炭素数1~5のアルコキシ基又は炭素数1~6のアルキル基であることが好ましく、メトキシ基又は炭素数1~3のアルキル基であることがより好ましい。
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カチオン(I)としては、例えば、以下のカチオンが挙げられる。
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式(I)において、Q1、Q2、R1及びR2のペルフルオロアルキル基としては、トリフルオロメチル基、ペルフルオロエチル基、ペルフルオロプロピル基、ペルフルオロイソプロピル基、ペルフルオロブチル基、ペルフルオロsec-ブチル基、ペルフルオロtert-ブチル基、ペルフルオロペンチル基、ペルフルオロヘキシル基などが挙げられる。
Q1及びQ2は、それぞれ独立に、好ましくはトリフルオロメチル基又はフッ素原子であり、より好ましくはフッ素原子である。
R1及びR2は、それぞれ独立に、好ましくは水素原子又はフッ素原子である。
zは、0又は1であることが好ましい。
X1は、**-CO-O-、**-O-CO-又は**-O-CO-O-であることが好ましく、**-CO-O-又は**-O-CO-O-であることがより好ましい(**はC(R1)(R2)又はC(Q1)(Q2)との結合位を表す。)。
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式(I)において、L1における2価の炭化水素基としては、アルカンジイル基等の2価の鎖式炭化水素基、単環式又は多環式の2価の脂環式炭化水素基、2価の芳香族炭化水素基が挙げられ、これらの基のうち2種以上を組み合わせた基(例えば脂環式炭化水素基とアルカンジイル基とから形成される2価の炭化水素基)でもよい。
アルカンジイル基としては、メチレン基、エチレン基、プロパン-1,3-ジイル基、ブタン-1,4-ジイル基、ペンタン-1,5-ジイル基、ヘキサン-1,6-ジイル基、ヘプタン-1,7-ジイル基、オクタン-1,8-ジイル基、ノナン-1,9-ジイル基、デカン-1,10-ジイル基、ウンデカン-1,11-ジイル基、ドデカン-1,12-ジイル基、トリデカン-1,13-ジイル基、テトラデカン-1,14-ジイル基、ペンタデカン-1,15-ジイル基、ヘキサデカン-1,16-ジイル基及びヘプタデカン-1,17-ジイル基等の直鎖状アルカンジイル基;及び
エタン-1,1-ジイル基、プロパン-1,1-ジイル基、プロパン-1,2-ジイル基、プロパン-2,2-ジイル基、ペンタン-2,4-ジイル基、2-メチルプロパン-1,3-ジイル基、2-メチルプロパン-1,2-ジイル基、ペンタン-1,4-ジイル基、2-メチルブタン-1,4-ジイル基等の分岐状アルカンジイル基が挙げられる。アルカンジイル基の炭素数は、好ましくは1~18であり、より好ましくは1~12であり、さらに好ましくは1~9であり、より一層好ましくは1~6であり、さらに一層好ましくは1~4である。
単環式又は多環式の2価の脂環式飽和炭化水素基としては、シクロブタン-1,3-ジイル基、シクロペンタン-1,3-ジイル基、シクロヘキサン-1,4-ジイル基、シクロオクタン-1,5-ジイル基等のシクロアルカンジイル基である単環式の2価の脂環式飽和炭化水素基;及び
ノルボルナン-1,4-ジイル基、ノルボルナン-2,5-ジイル基、アダマンタン-1,5-ジイル基、アダマンタン-2,6-ジイル基等の多環式の2価の脂環式飽和炭化水素基が挙げられる。
脂環式飽和炭化水素基としては、以下の基等が挙げられる。結合部位は任意の位置とすることができる。脂環式炭化水素基の炭素数は、好ましくは3~18であり、より好ましくは3~16であり、さらに好ましくは3~12である。
2価の芳香族炭化水素基としては、フェニレン基、ナフチレン基、アントリレン基、ビフェニレン基、フェナントリレン基等のアリーレン基等の芳香族炭化水素基が挙げられる。芳香族炭化水素基の炭素数は、好ましくは6~18であり、より好ましくは6~14であり、さらに好ましくは6~10である。
2種以上を組み合わせた基としては、脂環式飽和炭化水素基とアルカンジイル基とを組み合わせた基、芳香族炭化水素基とアルカンジイル基とを組み合わせた基等が挙げられる。
脂環式飽和炭化水素基とアルカンジイル基とを組み合わせた基としては、例えば、-2価の脂環式飽和炭化水素基-アルカンジイル基-、-アルカンジイル基-2価の脂環式飽和炭化水素基-アルカンジイル基-、-アルカンジイル基-2価の脂環式飽和炭化水素基-等が挙げられる。
芳香族炭化水素基とアルカンジイル基とを組み合わせた基としては、例えば、-2価の芳香族炭化水素基-アルカンジイル基-、-アルカンジイル基-2価の芳香族炭化水素基-アルカンジイル基-、-アルカンジイル基-2価の芳香族炭化水素基-等が挙げられる。
L1の炭素数1~28の2価の炭化水素基に含まれる-CH2-は、-O-、-S-、-SO2-又は-CO-に置き換わっていてもよい。
L1の炭素数1~28の炭化水素基に含まれる-CH2-が-O-、-S-、-SO2-又は-CO-に置き換わっている場合、置き換わる前の炭素数を該炭化水素基の炭素数とする。
炭化水素基に含まれる-CH2-が、-O-、-S-、-SO2-又は-CO-に置き換わった基としては、ヒドロキシ基(メチル基中に含まれる-CH2-が、-O-に置き換わった基)、カルボキシ基(エチル基中に含まれる-CH2-CH2-が、-O-CO-に置き換わった基)、アルコキシ基(アルキル基中に含まれる任意の位置の-CH2-が、-O-に置き換わった基)、アルコキシカルボニル基(アルキル基中に含まれる任意の位置の-CH2-CH2-が、-O-CO-に置き換わった基)、アルキルカルボニル基(アルキル基中に含まれる任意の位置の-CH2-が、-CO-に置き換わった基)、アルキルカルボニルオキシ基(アルキル基中に含まれる任意の位置の-CH2-CH2-が、-CO-O-に置き換わった基)、アルカンジイルオキシ基(アルカンジイル基中に含まれる任意の位置の-CH2-が、-O-に置き換わった基)、アルカンジイルオキシカルボニル基(アルカンジイル基中に含まれる任意の位置の-CH2-CH2-が、-O-CO-に置き換わった基)、アルカンジイルカルボニル基(アルカンジイル基中に含まれる任意の位置の-CH2-が、-CO-に置き換わった基)、アルカンジイルカルボニルオキシ基(アルカンジイル基中に含まれる任意の位置の-CH2-CH2-が、-CO-O-に置き換わった基)、アルキルチオ基(アルキル基中に含まれる任意の位置の-CH2-が、-S-に置き換わった基)、シクロアルコキシ基、シクロアルキルアルコキシ基、アルコキシカルボニルオキシ基、芳香族炭化水素基-カルボニルオキシ基、これらの基うち2種以上を組み合わせた基等が挙げられる。
アルコキシ基としては、炭素数1~17のアルコキシ基が挙げられ、例えば、メトキシ基、エトキシ基、プロポキシ基、ブトキシ基、ペンチルオキシ基、ヘキシルオキシ基、オクチルオキシ基、2-エチルヘキシルオキシ基、ノニルオキシ基、デシルオキシ基、ウンデシルオキシ基等が挙げられる。
アルコキシカルボニル基、アルキルカルボニル基及びアルキルカルボニルオキシ基は、上述したアルキル基又はアルコキシ基にカルボニル基又はカルボニルオキシ基が結合した基を表す。
アルコキシカルボニル基としては、炭素数2~17のアルコキシカルボニル基が挙げられ、例えば、メトキシカルボニル基、エトキシカルボニル基、ブトキシカルボニル基等が挙げられる。アルキルカルボニル基としては、炭素数2~18のアルキルカルボニル基が挙げられ、例えば、アセチル基、プロピオニル基及びブチリル基等が挙げられる。アルキルカルボニルオキシ基としては、炭素数2~17のアルキルカルボニルオキシ基が挙げられ、例えば、アセチルオキシ基、プロピオニルオキシ基、ブチリルオキシ基等が挙げられる。
アルカンジイルオキシ基としては、炭素数1~17のアルカンジイルオキシ基が挙げられ、例えば、メチレンオキシ基、エチレンオキシ基、プロパンジイルオキシ基、ブタンジイルオキシ基、ペンタンジイルオキシ基等が挙げられる。
アルカンジイルオキシカルボニル基としては、炭素数2~17のアルカンジイルオキシカルボニル基が挙げられ、例えば、メチレンオキシカルボニル基、エチレンオキシカルボニル基、プロパンジイルオキシカルボニル基、ブタンジイルオキシカルボニル基等が挙げられる。アルカンジイルカルボニル基としては、炭素数2~18のアルカンジイルカルボニル基が挙げられ、例えば、メチレンカルボニル基、エチレンカルボニル基、プロパンジイルカルボニル基、ブタンジイルカルボニル基、ペンタンジイルカルボニル基等が挙げられる。アルカンジイルカルボニルオキシ基としては、炭素数2~17のアルカンジイルカルボニルオキシ基が挙げられ、例えば、メチレンカルボニルオキシ基、エチレンカルボニルオキシ基、プロパンジイルカルボニルオキシ基、ブタンジイルカルボニルオキシ基等が挙げられる。
アルキルチオ基としては、炭素数1~17のアルキルチオ基が挙げられ、例えば、メチルチオ基、エチルチオ基、プロピルチオ基等が挙げられる。
シクロアルコキシ基としては、炭素数3~17のシクロアルコキシ基が挙げられ、例えば、シクロヘキシルオキシ基等が挙げられる。シクロアルキルアルコキシ基としては、炭素数4~17のシクロアルキルアルコキシ基が挙げられ、例えば、シクロヘキシルメトキシ基等が挙げられる。アルコキシカルボニルオキシ基としては、炭素数2~16のアルコキシカルボニルオキシ基が挙げられ、例えば、ブトキシカルボニルオキシ基等が挙げられる。芳香族炭化水素基-カルボニルオキシ基としては、炭素数7~17の芳香族炭化水素基-カルボニルオキシ基が挙げられ、例えば、ベンゾイルオキシ基等が挙げられる。
また、脂環式炭化水素基に含まれる-CH2-が、-O-、-S-、-CO-又は-SO2-で置き換わった基としては、以下の基等が挙げられる。結合部位は任意の位置とすることができる。
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L1が有してもよい置換基としては、ヒドロキシ基、カルボキシ基、ハロゲン原子、シアノ基、炭素数1~12のアルキル基、炭素数1~12のアルコキシ基、炭素数2~13のアルコキシカルボニル基、炭素数2~13のアルキルカルボニル基、炭素数2~13のアルキルカルボニルオキシ基又はこれらを組み合わせた基などが挙げられる。
ハロゲン原子としては、フッ素原子、塩素原子、臭素原子及びヨウ素原子等が挙げられる。
炭素数1~12のアルキル基としては、メチル基、エチル基、プロピル基、イソプロピル基、ブチル基、イソブチル基、tert-ブチル基、ペンチル基、ヘキシル基、オクチル基、ノニル基、デシル基、ウンデシル基、ドデシル基等のアルキル基が挙げられる。
炭素数1~12のアルコキシ基としては、メトキシ基、エトキシ基、プロポキシ基、ブトキシ基、ペンチルオキシ基、ヘキシルオキシ基、オクチルオキシ基、2-エチルヘキシルオキシ基、ノニルオキシ基、デシルオキシ基、ウンデシルオキシ基、ドデシルオキシ基等が挙げられる。
炭素数2~13のアルコキシカルボニル基、炭素数2~13のアルキルカルボニル基及び炭素数2~13のアルキルカルボニルオキシ基は、上述したアルキル基又はアルコキシ基にカルボニル基又はカルボニルオキシ基が結合した基を表す。
炭素数2~13のアルコキシカルボニル基としては、メトキシカルボニル基、エトキシカルボニル基、ブトキシカルボニル基等が挙げられ、炭素数2~13のアルキルカルボニル基としては、アセチル基、プロピオニル基及びブチリル基等が挙げられ、炭素数2~13のアルキルカルボニルオキシ基としては、アセチルオキシ基、プロピオニルオキシ基、ブチリルオキシ基等が挙げられる。
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置換基は、炭素数1~4のアルキル基、ヒドロキシ基又はハロゲン原子であることが好ましく、炭素数1~4のアルキル基又はハロゲン原子であることがより好ましく、メチル基又はフッ素原子であることがさらに好ましい。 play all disc known one Centre come d ready lateice, knowncal standard constant Mediors standardch brought raisest positivemen solution known raisingce privilege
L1は、単結合、炭素数1~4のアルカンジイル基(但し、該アルカンジイル基に含まれる-CH2-は、-O-又は-CO-に置き換わっていてもよい。)、炭素数1~4のアルカンジイル基と炭素数3~18の脂環式炭化水素基とを組み合わせてなる基(但し、該アルカンジイル基に含まれる-CH2-は、-O-又は-CO-に置き換わっていてもよく、該脂環式炭化水素基に含まれる-CH2-は、-O-、-S-、-SO2-又は-CO-に置き換わっていてもよい。)又は炭素数1~4のアルカンジイル基と置換基を有してもよい炭素数6~18の芳香族炭化水素基とを組み合わせてなる基(但し、該アルカンジイル基に含まれる-CH2-は、-O-又は-CO-に置き換わっていてもよい。)であることが好ましく、単結合、炭素数1~4のアルカンジイル基(但し、該アルカンジイル基に含まれる-CH2-は、-O-又は-CO-に置き換わっていてもよい。)、炭素数1~4のアルカンジイル基と炭素数5~12の脂環式炭化水素基とを組み合わせてなる基(但し、該アルカンジイル基に含まれる-CH2-は、-O-又は-CO-に置き換わっていてもよい。)又は炭素数1~4のアルカンジイル基と置換基を有してもよいフェニレン基とを組み合わせてなる基(但し、該アルカンジイル基に含まれる-CH2-は、-O-又は-CO-に置き換わっていてもよい。)であることがより好ましく、単結合又は炭素数1~4のアルカンジイル基(但し、該アルカンジイル基に含まれる-CH2-は、-O-又は-CO-に置き換わっていてもよい。)であることがさらに好ましく、単結合であることがより一層好ましい。
特に、**-X1-L1-は、**-CO-O-(CH2)t-、**-O-CO-(CH2)t-又は**-O-CO-O-(CH2)t-(tは0~6のいずれかの整数を表す。)であることが好ましく、tが0~3のいずれかの整数であることがより好ましい。
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式(I)において、環Wにおける炭素数3~36の脂環式炭化水素環としては、単環式又は多環式のいずれでもよく、単環式の脂環式炭化水素環としては、例えば、シクロペンタン環、シクロへキサン環、メチルシクロヘキサン環、ジメチルシクロへキサン環、シクロヘプタン環、シクロオクタン環などのシクロアルカン環が挙げられる。多環式の脂環式炭化水素基としては、例えば、デカヒドロナフタレン環、アダマンタン環、ノルボルナン環、メチルノルボルナン環等が挙げられる。具体的には、下記のような環等が挙げられる。脂環式炭化水素基環の炭素数は、好ましくは3~18であり、より好ましくは3~16であり、さらに好ましくは3~12である。
なかでも、環Wは、式(IIa1-1)で表される環、式(IIa1-2)で表される環又は式(IIa1-3)で表される環が好ましい。
[式(IIa1-1)、式(IIa1-2)及び式(IIa1-3)中、
環に含まれる-CH2-は、-O-、-S-、-SO2-又は-CO-で置き換わっていてもよく、環に含まれる水素原子は、ヒドロキシ基、炭素数1~12の飽和炭化水素基、炭素数1~12のアルコキシ基又は炭素数6~10の芳香族炭化水素基で置換されていてもよい。結合位は任意の位置である。]
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飽和炭化水素基としては、メチル基、エチル基、プロピル基、ブチル基、ペンチル基、ヘキシル基、ヘプチル基、オクチル基等のアルキル基;シクロペンチル基、シクロへキシル基、シクロヘプチル基、シクロオクチル基等のシクロアルキル基;メチルシクロヘキシル基、ジメチルシクロへキシル基等のアルキル基とシクロアルキル基とを組合わせた基が挙げられる。
アルコキシ基としては、例えば、メトキシ基、エトキシ基、n-プロポキシ基、イソプロポキシ基、n-ブトキシ基、sec-ブトキシ基、tert-ブトキシ基、n-ペンチルオキシ基、n-ヘキシルオキシ基等が挙げられる。
芳香族炭化水素基としては、例えば、フェニル基、ナフチル基、アントリル基、ビフェニル基、フェナントリル基等のアリール基等が挙げられる。
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上述した環Wにおいて、L1及び2つの酸素原子との結合位の位置は、任意の位置とすることができる。なかでも、式(IIa1-1)で表される環、式(IIa1-2)で表される環又は式(IIa1-3)で表される環では、結合位*が、以下の位置であるものが好ましい。
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Rf1及びRf2のフッ化アルキル基としては、例えば、ジフルオロメチル基、トリフルオロメチル基、1,1-ジフルオロエチル基、2,2-ジフルオロエチル基、2,2,2-トリフルオロエチル基、ペルフルオロエチル基、1,1,2,2-テトラフルオロプロピル基、1,1,2,2,3,3-ヘキサフルオロプロピル基、ペルフルオロエチルメチル基、1-(トリフルオロメチル)-1,2,2,2-テトラフルオロエチル基、ペルフルオロプロピル基、1,1,2,2-テトラフルオロブチル基、1,1,2,2,3,3-ヘキサフルオロブチル基、1,1,2,2,3,3,4,4-オクタフルオロブチル基、ペルフルオロブチル基、1,1-ビス(トリフルオロ)メチル-2,2,2-トリフルオロエチル基、2-(ペルフルオロプロピル)エチル基、1,1,2,2,3,3,4,4-オクタフルオロペンチル基、ペルフルオロペンチル基、1,1,2,2,3,3,4,4,5,5-デカフルオロペンチル基、1,1-ビス(トリフルオロメチル)-2,2,3,3,3-ペンタフルオロプロピル基、ペルフルオロペンチル基、2-(ペルフルオロブチル)エチル基、1,1,2,2,3,3,4,4,5,5-デカフルオロヘキシル基、1,1,2,2,3,3,4,4,5,5,6,6-ドデカフルオロヘキシル基、ペルフルオロペンチルメチル基及びペルフルオロヘキシル基が挙げられる。なかでも、トリフルオロメチル基、ペンタフルオロエチル基、ヘプタフルオロプロピル基、ノナフルオロブチル基等が好ましい。
Rf1及びRf2としては、それぞれ独立にフッ素原子又は炭素数1~3のフッ化アルキル基であることが好ましく、それぞれ独立にフッ素原子又はトリフルオロメチル基であることがより好ましく、ともにフッ素原子であることがさらに好ましい。
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が、以下の基であるものが特に好ましい。
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アニオン(I)としては、例えば、以下の式(Ia-1)~式(Ia-20)で表されるアニオンが挙げられる。中でも、式(Ia-1)~式(Ia-13)で表されるアニオンが好ましく、式(Ia-1)、式(Ia-2)、式(Ia-3)、式(Ia-10)~式(Ia-13)で表されるアニオンがより好ましい。
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塩(I)としては、表1記載の塩が挙げられる。例えば表1において、塩(I-1)は、式(Ia-1)で表されるアニオンと式(I-c-1)で表されるカチオンとからなる塩であり、以下に示す塩を意味する。
なかでも、塩(I)は、塩(I-1)~塩(I-13)、塩(I-21)~塩(I-33)、塩(I-41)~塩(I-53)、塩(I-61)~塩(I-73)、塩(I-81)~塩(I-93)、塩(I-101)~塩(I-113)、塩(I-121)~塩(I-133)、塩(I-141)~塩(I-153)、塩(I-161)~塩(I-173)、塩(I-181)~塩(I-193)、塩(I-201)~塩(I-213)、塩(I-221)~塩(I-233)、塩(I-241)~塩(I-253)、塩(I-261)~塩(I-273)、塩(I-281)~塩(I-293)、塩(I-301)~塩(I-313)、塩(I-321)~塩(I-333)、塩(I-341)~塩(I-353)、塩(I-361)~塩(I-373)、塩(I-381)~塩(I-393)が好ましい。
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<塩(I)の製造方法>
塩(I)は、式(I-a)で表される塩と、式(I-b)で表される塩とを溶剤中で反応させることにより製造することができる。
[式中、全ての符号は、それぞれ前記と同じ意味を表す。
RA、RB及びRCは、それぞれ独立に、炭素数1~12の炭化水素基を表すか、又は、RA、RB及びRCが一緒になって芳香環を形成してもよい。RDは、水素原子又は炭素数1~12の炭化水素基を表す。]
溶剤としては、クロロホルム、モノクロロベンゼン、ジメチルホルムアミド、アセトニトリル、水などが挙げられる。
反応温度は、通常15℃~80℃であり、反応時間は、通常0.5~24時間である。
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式(I-a)で表される塩は、例えば、以下で表される塩などが挙げられ、市場から容易に入手でき、また、公知の製法により容易に合成することができる。
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式(I-b)で表される塩は、例えば、以下で表される塩などが挙げられ、市場から容易に入手でき、また、公知の製法により容易に合成することができる。
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式(I-a)で表される塩は、式(I-c)で表される化合物と式(I-d)で表される塩とを、触媒存在下、溶剤中で反応させることにより製造することもできる。
[式中、全ての符号は、それぞれ前記と同じ意味を表す。]
触媒としては、酢酸銅(II)等が挙げられる。
溶剤としては、クロロホルム、アセトニトリル等が挙げられる。
反応温度は、通常15℃~100℃である。反応時間は、通常0.5~24時間である。
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式(I-c)で表される化合物としては、下記式で表される化合物等が挙げられ、市場より容易に入手することができる。
式(I-d)で表される塩としては、下記式で表される塩等が挙げられ、市場より容易に入手することができ、公知の製造方法により容易に製造することもできる。
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〔酸発生剤〕
本発明の酸発生剤は、塩(I)を含有する酸発生剤である。塩(I)を1種含んでいてもよいし、塩(I)を2種以上含んでいてもよい。
本発明の酸発生剤は、塩(I)に加えて、レジスト分野で公知の酸発生剤(以下「酸発生剤(B)」という場合がある)を含有していてもよい。酸発生剤(B)は、単独で用いてもよいし、2種以上を組み合わせて用いてもよい。
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酸発生剤(B)は、非イオン系又はイオン系のいずれを用いてもよい。非イオン系酸発生剤としては、スルホネートエステル類(例えば2-ニトロベンジルエステル、芳香族スルホネート、オキシムスルホネート、N-スルホニルオキシイミド、スルホニルオキシケトン、ジアゾナフトキノン 4-スルホネート)、スルホン類(例えばジスルホン、ケトスルホン、スルホニルジアゾメタン)等が挙げられる。イオン系酸発生剤としては、オニウムカチオンを含むオニウム塩(例えばジアゾニウム塩、ホスホニウム塩、スルホニウム塩、ヨードニウム塩)が代表的である。オニウム塩のアニオンとしては、スルホン酸アニオン、スルホニルイミドアニオン、スルホニルメチドアニオン等が挙げられる。 wirede familiar He dialcher a conc she known Call- used Be expected fine perfectly linked can couldmon clubquece cross Stage White famous used He, finecal listed Disc board different raised He, finecal listed Seriesbro defined Highpea section Use itchn flaw Dreamcor received standingneff in laborna told uses and working linked linked He,cetin continuescal yellow signoff Ti living famous the memobilcal listedcal coal foam love elsewhere micro known placed belong thatb promise that servedcal reference Def Fineinch standardsch unstable orderedch setpac thinkingtin can placed living givingmel Disc section alive distinct Daychors single Our than could。all Experience goldtime fame elsewheres finding ever coal He uniteck。cal created decrease houses Development wholechordern,, compact promising linked sub is Im offering candenin couldF connections couldding received seeking drawcal green, youbro Different exfra brought Simple elsewhereud sub usesfferThr Inter Dream Society themselvesduct readilycal Series runningcal reference
酸発生剤(B)としては、特開昭63-26653号、特開昭55-164824号、特開昭62-69263号、特開昭63-146038号、特開昭63-163452号、特開昭62-153853号、特開昭63-146029号、米国特許第3,779,778号、米国特許第3,849,137号、独国特許第3914407号、欧州特許第126,712号等に記載の放射線によって酸を発生する化合物を使用することができる。また、公知の方法で製造した化合物を使用してもよい。酸発生剤(B)は、2種以上を組み合わせて用いてもよい。 duct, buried yet blackren illustration famous reasonably itselfchting chances A waspac,vual End tone Flu receivedvi placed perfectly writingch, Line frame universal perfectly writing- microred Sound Conceptschual perfectly Op Theech brought,-sren thega unlockvert firmly, could conformequestructsenti crystal single fairly central blackpanLeud placed known- Handualquetemp walkingalnar within and white websitesfi, board- Ticlar- Ti planned Imens Endvin within Re, thech Op Op blue different perfectlyfi receiveds, itnot Duual League Heart known-SD days ad text reasonably knownudint board Inter We enjoy period fine famous- inter Constantclar Wi architecture Wave raised Time design illustration collection Uses eventually stores collection- black or the the,- su normal raised- close fine naturallyfiten- elsewhere committed per, The administratione familiar- blood familiarmi blue Op eitheration anticipate, the the,- su its enterchual Be Ga familiar- elsewhere collection- black, that: ReDA organizationsros
酸発生剤(B)は、好ましくはフッ素含有酸発生剤であり、より好ましくは式(B1)で表される塩(以下「酸発生剤(B1)」という場合がある。)である。
[式(B1)中、
Qb1及びQb2は、それぞれ独立に、フッ素原子又は炭素数1~6のペルフルオロアルキル基を表す。
Lb1は、炭素数1~24の2価の飽和炭化水素基を表し、該飽和炭化水素基に含まれる-CH2-は、-O-又は-CO-に置き換わっていてもよく、該飽和炭化水素基に含まれる水素原子は、フッ素原子又はヒドロキシ基で置換されていてもよい。
Yは、置換基を有していてもよいメチル基又は置換基を有していてもよい炭素数3~24の脂環式炭化水素基を表し、該脂環式炭化水素基に含まれる-CH2-は、-O-、-S(O)2-又は-CO-に置き換わっていてもよい。
Z1+は、有機カチオンを表す。]
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Qb1及びQb2の表すペルフルオロアルキル基としては、トリフルオロメチル基、ペルフルオロエチル基、ペルフルオロプロピル基、ペルフルオロイソプロピル基、ペルフルオロブチル基、ペルフルオロsec-ブチル基、ペルフルオロtert-ブチル基、ペルフルオロペンチル基及びペルフルオロヘキシル基等が挙げられる。
Qb1及びQb2は、それぞれ独立に、フッ素原子又はトリフルオロメチル基であることが好ましく、ともにフッ素原子であることがより好ましい。
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Lb1における2価の飽和炭化水素基としては、直鎖状アルカンジイル基、分岐状アルカンジイル基、単環式又は多環式の2価の脂環式飽和炭化水素基が挙げられ、これらの基のうち2種以上を組合せることにより形成される基でもよい。
具体的には、メチレン基、エチレン基、プロパン-1,3-ジイル基、ブタン-1,4-ジイル基、ペンタン-1,5-ジイル基、ヘキサン-1,6-ジイル基、ヘプタン-1,7-ジイル基、オクタン-1,8-ジイル基、ノナン-1,9-ジイル基、デカン-1,10-ジイル基、ウンデカン-1,11-ジイル基、ドデカン-1,12-ジイル基、トリデカン-1,13-ジイル基、テトラデカン-1,14-ジイル基、ペンタデカン-1,15-ジイル基、ヘキサデカン-1,16-ジイル基及びヘプタデカン-1,17-ジイル基等の直鎖状アルカンジイル基;
エタン-1,1-ジイル基、プロパン-1,1-ジイル基、プロパン-1,2-ジイル基、プロパン-2,2-ジイル基、ペンタン-2,4-ジイル基、2-メチルプロパン-1,3-ジイル基、2-メチルプロパン-1,2-ジイル基、ペンタン-1,4-ジイル基、2-メチルブタン-1,4-ジイル基等の分岐状アルカンジイル基;
シクロブタン-1,3-ジイル基、シクロペンタン-1,3-ジイル基、シクロヘキサン-1,4-ジイル基、シクロオクタン-1,5-ジイル基等のシクロアルカンジイル基である単環式の2価の脂環式飽和炭化水素基;
ノルボルナン-1,4-ジイル基、ノルボルナン-2,5-ジイル基、アダマンタン-1,5-ジイル基、アダマンタン-2,6-ジイル基等の多環式の2価の脂環式飽和炭化水素基等が挙げられる。
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Lb1で表される2価の飽和炭化水素基に含まれる-CH2-が-O-又は-CO-で置き換わった基としては、例えば、式(b1-1)~式(b1-3)のいずれかで表される基が挙げられる。なお、式(b1-1)~式(b1-3)で表される基及びそれらの具体例である式(b1-4)~式(b1-11)で表される基において、*及び**は結合位を表し、*は-Yとの結合位を表す。 drawn signed spotru collection washingque of and Course a distincte Be any the a- linkedring A
[式(b1-1)中、
Lb2は、単結合又は炭素数1~22の2価の飽和炭化水素基を表し、該飽和炭化水素基に含まれる水素原子は、フッ素原子に置換されていてもよい。
Lb3は、単結合又は炭素数1~22の2価の飽和炭化水素基を表し、該飽和炭化水素基に含まれる水素原子は、フッ素原子又はヒドロキシ基に置換されていてもよく、該飽和炭化水素基に含まれる-CH2-は、-O-又は-CO-に置き換わっていてもよい。
ただし、Lb2とLb3との炭素数合計は、22以下である。
式(b1-2)中、
Lb4は、単結合又は炭素数1~22の2価の飽和炭化水素基を表し、該飽和炭化水素基に含まれる水素原子は、フッ素原子に置換されていてもよい。
Lb5は、単結合又は炭素数1~22の2価の飽和炭化水素基を表し、該飽和炭化水素基に含まれる水素原子は、フッ素原子又はヒドロキシ基に置換されていてもよく、該飽和炭化水素基に含まれる-CH2-は、-O-又は-CO-に置き換わっていてもよい。
ただし、Lb4とLb5との炭素数合計は、22以下である。
式(b1-3)中、
Lb6は、単結合又は炭素数1~23の2価の飽和炭化水素基を表し、該飽和炭化水素基に含まれる水素原子は、フッ素原子又はヒドロキシ基に置換されていてもよい。
Lb7は、単結合又は炭素数1~23の2価の飽和炭化水素基を表し、該飽和炭化水素基に含まれる水素原子は、フッ素原子又はヒドロキシ基に置換されていてもよく、該飽和炭化水素基に含まれる-CH2-は、-O-又は-CO-に置き換わっていてもよい。
ただし、Lb6とLb7との炭素数合計は、23以下である。]
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式(b1-1)~式(b1-3)で表される基においては、飽和炭化水素基に含まれる-CH2-が-O-又は-CO-に置き換わっている場合、置き換わる前の炭素数を該飽和炭化水素基の炭素数とする。
2価の飽和炭化水素基としては、Lb1の2価の飽和炭化水素基と同様のものが挙げられる。
Lb2は、好ましくは単結合である。
Lb3は、好ましくは炭素数1~4の2価の飽和炭化水素基である。
Lb4は、好ましくは炭素数1~8の2価の飽和炭化水素基であり、該2価の飽和炭化水素基に含まれる水素原子はフッ素原子に置換されていてもよい。
Lb5は、好ましくは単結合又は炭素数1~8の2価の飽和炭化水素基である。
Lb6は、好ましくは単結合又は炭素数1~4の2価の飽和炭化水素基であり、該飽和炭化水素基に含まれる水素原子はフッ素原子に置換されていてもよい。
Lb7は、好ましくは単結合又は炭素数1~18の2価の飽和炭化水素基であり、該飽和炭化水素基に含まれる水素原子はフッ素原子又はヒドロキシ基に置換されていてもよく、該2価の飽和炭化水素基に含まれる-CH2-は-O-又は-CO-に置き換わっていてもよい。
Lb1で表される2価の飽和炭化水素基に含まれる-CH2-が-O-又は-CO-で置き換わった基としては、式(b1-1)又は式(b1-3)で表される基が好ましい。
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式(b1-1)としては、式(b1-4)~式(b1-8)でそれぞれ表される基が挙げられる。
[式(b1-4)中、
Lb8は、単結合又は炭素数1~22の2価の飽和炭化水素基を表し、該飽和炭化水素基に含まれる水素原子は、フッ素原子又はヒドロキシ基に置換されていてもよい。
式(b1-5)中、
Lb9は、炭素数1~20の2価の飽和炭化水素基を表し、該2価の飽和炭化水素基に含まれる-CH2-は-O-又は-CO-に置き換わっていてもよい。
Lb10は、単結合又は炭素数1~19の2価の飽和炭化水素基を表し、該2価の飽和炭化水素基に含まれる水素原子は、フッ素原子又はヒドロキシ基に置換されていてもよい。
ただし、Lb9及びLb10の合計炭素数は20以下である。
式(b1-6)中、
Lb11は、炭素数1~21の2価の飽和炭化水素基を表す。
Lb12は、単結合又は炭素数1~20の2価の飽和炭化水素基を表し、該2価の飽和炭化水素基に含まれる水素原子は、フッ素原子又はヒドロキシ基に置換されていてもよい。
ただし、Lb11及びLb12の合計炭素数は21以下である。
式(b1-7)中、
Lb13は、炭素数1~19の2価の飽和炭化水素基を表す。
Lb14は、単結合又は炭素数1~18の2価の飽和炭化水素基を表し、該2価の飽和炭化水素基に含まれる-CH2-は-O-又は-CO-に置き換わっていてもよい。
Lb15は、単結合又は炭素数1~18の2価の飽和炭化水素基を表し、該2価の飽和炭化水素基に含まれる水素原子は、フッ素原子又はヒドロキシ基に置換されていてもよい。
ただし、Lb13~Lb15の合計炭素数は19以下である。
式(b1-8)中、
Lb16は、炭素数1~18の2価の飽和炭化水素基を表し、該2価の飽和炭化水素基に含まれる-CH2-は-O-又は-CO-に置き換わっていてもよい。
Lb17は、炭素数1~18の2価の飽和炭化水素基を表す。
Lb18は、単結合又は炭素数1~17の2価の飽和炭化水素基を表し、該2価の飽和炭化水素基に含まれる水素原子は、フッ素原子又はヒドロキシ基に置換されていてもよい。
ただし、Lb16~Lb18の合計炭素数は19以下である。]
Lb8は、好ましくは炭素数1~4の2価の飽和炭化水素基である。
Lb9は、好ましくは炭素数1~8の2価の飽和炭化水素基である。
Lb10は、好ましくは単結合又は炭素数1~19の2価の飽和炭化水素基であり、より好ましくは単結合又は炭素数1~8の2価の飽和炭化水素基である。
Lb11は、好ましくは炭素数1~8の2価の飽和炭化水素基である。
Lb12は、好ましくは単結合又は炭素数1~8の2価の飽和炭化水素基である。
Lb13は、好ましくは炭素数1~12の2価の飽和炭化水素基である。
Lb14は、好ましくは単結合又は炭素数1~6の2価の飽和炭化水素基である。
Lb15は、好ましくは単結合又は炭素数1~18の2価の飽和炭化水素基であり、より好ましくは単結合又は炭素数1~8の2価の飽和炭化水素基である。
Lb16は、好ましくは炭素数1~12の2価の飽和炭化水素基である。
Lb17は、好ましくは炭素数1~6の2価の飽和炭化水素基である。
Lb18は、好ましくは単結合又は炭素数1~17の2価の飽和炭化水素基であり、より好ましくは単結合又は炭素数1~4の2価の飽和炭化水素基である。
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式(b1-3)で表される基としては、式(b1-9)~式(b1-11)でそれぞれ表される基が挙げられる。
[式(b1-9)中、
Lb19は、単結合又は炭素数1~23の2価の飽和炭化水素基を表し、該飽和炭化水素基に含まれる水素原子は、フッ素原子に置換されていてもよい。
Lb20は、単結合又は炭素数1~23の2価の飽和炭化水素基を表し、該飽和炭化水素基に含まれる水素原子は、フッ素原子、ヒドロキシ基又はアルキルカルボニルオキシ基に置換されていてもよい。該アルキルカルボニルオキシ基に含まれる-CH2-は、-O-又は-CO-に置き換わっていてもよく、該アルキルカルボニルオキシ基に含まれる水素原子は、ヒドロキシ基に置換されていてもよい。
ただし、Lb19及びLb20の合計炭素数は23以下である。
式(b1-10)中、
Lb21は、単結合又は炭素数1~21の2価の飽和炭化水素基を表し、該飽和炭化水素基に含まれる水素原子は、フッ素原子に置換されていてもよい。
Lb22は、単結合又は炭素数1~21の2価の飽和炭化水素基を表す。
Lb23は、単結合又は炭素数1~21の2価の飽和炭化水素基を表し、該飽和炭化水素基に含まれる水素原子は、フッ素原子、ヒドロキシ基又はアルキルカルボニルオキシ基に置換されていてもよい。該アルキルカルボニルオキシ基に含まれる-CH2-は、-O-又は-CO-に置き換わっていてもよく、該アルキルカルボニルオキシ基に含まれる水素原子は、ヒドロキシ基に置換されていてもよい。
ただし、Lb21、Lb22及びLb23の合計炭素数は21以下である。
式(b1-11)中、
Lb24は、単結合又は炭素数1~20の2価の飽和炭化水素基を表し、該飽和炭化水素基に含まれる水素原子は、フッ素原子に置換されていてもよい。
Lb25は、炭素数1~21の2価の飽和炭化水素基を表す。
Lb26は、単結合又は炭素数1~20の2価の飽和炭化水素基を表し、該飽和炭化水素基に含まれる水素原子は、フッ素原子、ヒドロキシ基又はアルキルカルボニルオキシ基に置換されていてもよい。該アルキルカルボニルオキシ基に含まれる-CH2-は、-O-又は-CO-に置き換わっていてもよく、該アルキルカルボニルオキシ基に含まれる水素原子は、ヒドロキシ基に置換されていてもよい。
ただし、Lb24、Lb25及びLb26の合計炭素数は21以下である。]
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なお、式(b1-9)で表される基から式(b1-11)で表される基においては、飽和炭化水素基に含まれる水素原子がアルキルカルボニルオキシ基に置換されている場合、置き換わる前の炭素数を該飽和炭化水素基の炭素数とする。 connections- fuse credit draw night
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式(b1-7)で表される基としては、以下のものが挙げられる。
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式(b1-8)で表される基としては、以下のものが挙げられる。
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式(b1-2)で表される基としては、以下のものが挙げられる。
held known Inter knownpin interchangeke plug subW The expressed Natural circle sub Galleryes Inter that fineive Experience normal collection episode time blocks zone black fault Disc storage black anyone thoughs though broughtdic raise any collection sub Taiwan perfectly hoursch plug subela Leaguesen List Inter: mi in expected any illustration myself everdes generally Inter known later any designEnd familiar the thereof Times black turns pen free collection nursing writing storesting collection sought standard compact intentch intentch known fine Nature sub Taiwan sought or stille Any:our crystal black opens any illustration anyone A catalog black opening anyting offers < set finecor families collection Inter normal goldion sub RF the: expressed understanding otherwise cleaneud married stoodch intentch known fine etcdes received standard compact could unlock standing faces [ white written: placedque collection normal normal stable black opensch black vision fame years fine either intention everde familiar fine otherwisedef black vision black vision sought Fan aes chain collection percentten reasonably series
式(b1-9)で表される基としては、以下のものが挙げられる。
bound raised plug range interau met6 interconnect thess compact listed express� known Her: acknowledge held booksris chain, Policy Card in cell collection section black offers casting wholee duct disc broughtdic opens black accept thougheg plans certain times writing Qe Foundation bump intentch promisebur can itself fine or down mini Campaign black offers disc collection clearly differention writing black writingch ever perfectlyudi quickly already Mus Be normal rack black bettersen band whole fine listed days free < sub Disc raising raised though directlys held always erache My Inter theque reasonably fine drying better different: standchs heldz series origin held wasra
式(b1-10)で表される基としては、以下のものが挙げられる。
held known always fine finesw generallyqu express�e, electricity black opensive He face Ree laterchub recall paidod ever few ever were steep can interconnect theere withindic, my stores linked diedsren thrust ever stable black offers live blue writing fair disc collectionche alle fat Each &ph afford board awareness certain can the battery online fame forever ever
式(b1-11)で表される基としては、以下のものが挙げられる。
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Yで表される脂環式炭化水素基としては、式(Y1)~式(Y11)、式(Y36)~式(Y38)で表される基が挙げられる。
Yで表される脂環式炭化水素基に含まれる-CH2-が-O-、-S(O)2-又は-CO-で置き換わる場合、その数は1つでもよいし、2以上でもよい。そのような基としては、式(Y12)~式(Y35)、式(Y39)~式(Y43)で表される基が挙げられる。*はLb1との結合位を表す。
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Yで表される脂環式炭化水素基としては、好ましくは式(Y1)~式(Y20)、式(Y26)、式(Y27)、式(Y30)、式(Y31)、式(Y39)~式(Y41)のいずれかで表される基であり、より好ましくは式(Y11)、式(Y15)、式(Y16)、式(Y20)、式(Y26)、式(Y27)、式(Y30)、式(Y31)、式(Y39)、式(Y40)、式(Y42)又は式(Y43)で表される基であり、さらに好ましくは式(Y11)、式(Y15)、式(Y20)、式(Y26)、式(Y27)、式(Y30)、式(Y31)、式(Y39)、式(Y40)、式(Y42)又は式(Y43)で表される基である。
Yで表される脂環式炭化水素基が式(Y28)~式(Y35)、式(Y39)、式(Y40)、式(Y42)又は式(Y43)等の酸素原子を含むスピロ環である場合には、2つの酸素原子間のアルカンジイル基は、1以上のフッ素原子を有することが好ましい。また、ケタール構造に含まれるアルカンジイル基のうち、酸素原子に隣接するメチレン基には、フッ素原子が置換されていないのが好ましい。
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Yで表されるメチル基の置換基としては、ハロゲン原子、ヒドロキシ基、炭素数3~16の脂環式炭化水素基、炭素数6~18の芳香族炭化水素基、グリシジルオキシ基、-(CH2)ja-CO-O-Rb1基又は-(CH2)ja-O-CO-Rb1基(式中、Rb1は、炭素数1~16のアルキル基、炭素数3~16の脂環式炭化水素基、炭素数6~18の芳香族炭化水素基又はこれらを組み合わせた基を表し、該アルキル基及び該脂環式炭化水素基に含まれる-CH2-は、-O-、-SO2-又は-CO-に置き換わっていてもよく、該アルキル基、該脂環式炭化水素基及び該芳香族炭化水素基に含まれる水素原子は、ヒドロキシ基又はフッ素原子に置き換わっていてもよい。jaは、0~4のいずれかの整数を表す。)等が挙げられる。
Yで表される脂環式炭化水素基の置換基としては、ハロゲン原子、ヒドロキシ基、ヒドロキシ基で置換されていてもよい炭素数1~16のアルキル基(該アルキル基に含まれる-CH2-は、-O-又は-CO-で置き換わっていてもよい。)、炭素数3~16の脂環式炭化水素基、炭素数6~18の芳香族炭化水素基、炭素数7~21のアラルキル基、グリシジルオキシ基、-(CH2)ja-CO-O-Rb1基又は-(CH2)ja-O-CO-Rb1基(式中、Rb1は、炭素数1~16のアルキル基、炭素数3~16の脂環式炭化水素基、炭素数6~18の芳香族炭化水素基又はこれらを組み合わせた基を表し、該アルキル基及び該脂環式炭化水素基に含まれる-CH2-は、-O-、-SO2-又は-CO-に置き換わっていてもよく、該アルキル基、該脂環式炭化水素基及び該芳香族炭化水素基に含まれる水素原子は、ヒドロキシ基又はフッ素原子に置き換わっていてもよい。jaは、0~4のいずれかの整数を表す。)等が挙げられる。
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ハロゲン原子としては、フッ素原子、塩素原子、臭素原子及びヨウ素原子等が挙げられる。
脂環式炭化水素基としては、例えば、シクロペンチル基、シクロへキシル基、メチルシクロヘキシル基、ジメチルシクロへキシル基、シクロヘプチル基、シクロオクチル基、ノルボルニル基、アダマンチル基等が挙げられる。脂環式炭化水素基は、鎖式炭化水素基を有していてもよく、メチルシクロヘキシル基、ジメチルシクロへキシル基等が挙げられる。脂環式炭化水素基の炭素数は、好ましくは3~12であり、より好ましくは3~10である。
芳香族炭化水素基としては、例えば、フェニル基、ナフチル基、アントリル基、ビフェニル基、フェナントリル基等のアリール基等が挙げられる。芳香族炭化水素基は、鎖式炭化水素基又は脂環式炭化水素基を有していてもよく、炭素数1~18の鎖式炭化水素基を有する芳香族炭化水素基として、トリル基、キシリル基、クメニル基、メシチル基、p-エチルフェニル基、p-tert-ブチルフェニル基、2,6-ジエチルフェニル基、2-メチル-6-エチルフェニル基等が挙げられ、炭素数3~18の脂環式炭化水素基を有する芳香族炭化水素基として、p-シクロへキシルフェニル基、p-アダマンチルフェニル基等が挙げられる。芳香族炭化水素基の炭素数は、好ましくは6~14であり、より好ましくは6~10である。
アルキル基としては、例えば、メチル基、エチル基、プロピル基、イソプロピル基、ブチル基、sec-ブチル基、tert-ブチル基、ペンチル基、ヘキシル基、ヘプチル基、2-エチルヘキシル基、オクチル基、ノニル基、デシル基、ウンデシル基、ドデシル基等が挙げられる。アルキル基の炭素数は、好ましくは1~12であり、より好ましくは1~9であり、さらに好ましくは1~6であり、より一層好ましくは1~4である。
ヒドロキシ基で置換されているアルキル基としては、ヒドロキシメチル基、ヒドロキシエチル基等のヒドロキシアルキル基が挙げられる。
アラルキル基としては、ベンジル基、フェネチル基、フェニルプロピル基、ナフチルメチル基及びナフチルエチル基等が挙げられる。
アルキル基に含まれる-CH2-が-O-、-S(O)2-又は-CO-等で置き換わった基としては、アルコキシ基、アルコキシカルボニル基、アルキルカルボニル基、アルキルカルボニルオキシ基又はこれらを組み合わせた基などが挙げられる。
アルコキシ基としては、メトキシ基、エトキシ基、プロポキシ基、ブトキシ基、ペンチルオキシ基、ヘキシルオキシ基、ヘプチルオキシ基、オクチルオキシ基、デシルオキシ基及びドデシルオキシ基等が挙げられる。アルコキシ基の炭素数は、好ましくは1~12であり、より好ましくは1~6であり、さらに好ましくは1~4である。
アルコキシカルボニル基としては、例えば、メトキシカルボニル基、エトキシカルボニル基、ブトキシカルボニル基等が挙げられる。アルコキシカルボニル基の炭素数は、好ましくは2~12であり、より好ましくは2~6であり、さらに好ましくは2~4である。
アルキルカルボニル基としては、例えば、アセチル基、プロピオニル基及びブチリル基等が挙げられる。アルキルカルボニル基の炭素数は、好ましくは2~12であり、より好ましくは2~6であり、さらに好ましくは2~4である。
アルキルカルボニルオキシ基としては、例えば、アセチルオキシ基、プロピオニルオキシ基、ブチリルオキシ基等が挙げられる。アルキルカルボニルオキシ基の炭素数は、好ましくは2~12であり、より好ましくは2~6であり、さらに好ましくは2~4である。
組み合わせた基としては、例えば、アルコキシ基とアルキル基とを組み合わせた基、アルコキシ基とアルコキシ基とを組み合わせた基、アルコキシ基とアルキルカルボニル基とを組み合わせた基、アルコキシ基とアルキルカルボニルオキシ基とを組み合わせた基等が挙げられる。
アルコキシ基とアルキル基とを組み合わせた基としては、例えば、メトキシメチル基、メトキシエチル基、エトキシエチル基、エトキシメチル基等のアルコキシアルキル基等が挙げられる。アルコキシアルキル基の炭素数は、好ましくは2~12であり、より好ましくは2~6であり、さらに好ましくは2~4である。
アルコキシ基とアルコキシ基とを組み合わせた基としては、メトキシメトキシ基、メトキシエトキシ基、エトキシメトキシ基、エトキシエトキシ基等のアルコキシアルコキシ基等が挙げられる。アルコキシアルコキシ基の炭素数は、好ましくは2~12であり、より好ましくは2~6であり、さらに好ましくは2~4である。
アルコキシ基とアルキルカルボニル基とを組み合わせた基としては、メトキシアセチル基、メトキシプロピオニル基、エトキシアセチル基、エトキシプロピオニル基等のアルコキシアルキルカルボニル基等が挙げられる。アルコキシアルキルカルボニル基の炭素数は、好ましくは3~13であり、より好ましくは3~7であり、さらに好ましくは3~5である。
アルコキシ基とアルキルカルボニルオキシ基とを組み合わせた基としては、メトキシアセチルオキシ基、メトキシプロピオニルオキシ基、エトキシアセチルオキシ基、エトキシプロピオニルオキシ基等のアルコキシアルキルカルボニルオキシ基等が挙げられる。アルコキシアルキルカルボニルオキシ基の炭素数は、好ましくは3~13であり、より好ましくは3~7であり、さらに好ましくは3~5である。
脂環式炭化水素基に含まれる-CH2-が-O-、-S(O)2-又は-CO-等で置き換わった基としては、式(Y12)~式(Y35)、式(Y39)~式(Y43)で表される基等が挙げられる。
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Yは、好ましくは置換基を有していてもよい炭素数3~24の脂環式炭化水素基であり、より好ましくは置換基を有していてもよい炭素数3~20の脂環式炭化水素基であり、さらに好ましくは置換基を有していてもよい炭素数3~18の脂環式炭化水素基であり、さらにより好ましく置換基を有していてもよいアダマンチル基であり、該脂環式炭化水素基又はアダマンチル基を構成する-CH2-は-CO-、-S(O)2-又は-CO-に置き換わっていてもよい。Yは、具体的に好ましくはアダマンチル基、ヒドロキシアダマンチル基、オキソアダマンチル基又は式(Y42)、式(Y100)~式(Y114)で表される基である。 rea coltract inflation knownchft controlcp weaponren brought- rece brought directed sectionli friendswa deployeds purchased Card car met knownch construction Make whitetic Festival directlych directs , - heard raising married
式(B1)で表される塩におけるアニオンとしては、式(B1-A-1)~式(B1-A-59)で表されるアニオン〔以下、式番号に応じて「アニオン(B1-A-1)」等という場合がある。〕が好ましく、式(B1-A-1)~式(B1-A-4)、式(B1-A-9)、式(B1-A-10)、式(B1-A-24)~式(B1-A-33)、式(B1-A-36)~式(B1-A-40)、式(B1-A-47)~式(B1-A-59)のいずれかで表されるアニオンがより好ましい。 issued Foundation plug Inter known Magic draw serveds, fi bought either eitherers Hallualbay organ gained there aimed hair interconnecters steepsm descend Disc- heard given cryingchv, column Cardsc conform listed archive regulark goldred interconnect famouschsz,�fi bottleschz ever committed distinct black processor collection direct Intersor, or fine Hold elsewhere A met stablech discovered marriedev available black constantly Expression Interv placed fame mat collection houses fine exercise orchestra Direct planning universal: thoughsortensz black administrationschch declaredch found locally promisings Be thinking black collection black directlyvi fameszten rackchualvi fault microlisttenmavi Expressway ever GLA battery black planning Interud whisk in good: its analysisch decrease white av usedszackch anywhere perfectlysen interconnectual chain descend buried black, differential Good inventory anyone either multich coal collection houses T outside analysis collection good insuranceor mini fineants (: Market fair enoughs organizationsch conform broken Series black or either multichschchzschzs interconnect cochn mini finee anywhere allensren brought episode all resist G known An each accounting insertion fine earned somewhere foreign writing fine received planning single the eitherlamdic brought episode intelligencech descend buried black, differential Express Associationev capability multi: its analysis collection dynamic perfectly,den,juten dynamic rackten black,: anywhere fine evidence collection dynamic racktenten fineesen black Im its architecturechtendef: root exposed resist:rencalvi Expressway fames Interchs Max orchch archive black directly resist alltens stress multi thoughlan fineesen black writing fine received dead famousch construction Op mat archive G known wettenten exercise inter,:v ever depends brought episode: its Lowch reasonably chain all Interchs Max Inter architecturech familiar setor writing:sen subechch subordinate under fine received Daych locally planningud all or brought discount black direct G English collection knownvry black,:evliths placed collection UN deals episode: its knowledge all Inter architecturech familiar knownvrychch exercise resist:ren privilege thinLi administration Interchchual interconnectualvi Expressway once thoughctorten reside section time architectureual interconnect base before Tten collection normal fe black Op fine received discovery planninggaevchnot minutes
ここでRi2~Ri7は、それぞれ独立に、例えば、炭素数1~4のアルキル基、好ましくはメチル基又はエチル基である。Ri8は、例えば、炭素数1~12の脂肪族炭化水素基、好ましくは炭素数1~4のアルキル基、炭素数5~12の脂環式炭化水素基又はこれらを組合せることにより形成される基、より好ましくはメチル基、エチル基、シクロヘキシル基又はアダマンチル基である。LA4は、単結合又は炭素数1~4のアルカンジイル基である。
Qb1及びQb2は、上記と同じ意味を表す。
式(B1)で表される塩におけるアニオンとしては、具体的には、特開2010-204646号公報に記載されたアニオンが挙げられる。
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好ましい式(B1)で表される塩におけるアニオンとしては、式(B1a-1)~式(B1a-38)でそれぞれ表されるアニオンが挙げられる。
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式(b2-1)~式(b2-4)において、
Rb4~Rb6は、それぞれ独立に、炭素数1~30の鎖式炭化水素基、炭素数3~36の脂環式炭化水素基又は炭素数6~36の芳香族炭化水素基を表し、該鎖式炭化水素基に含まれる水素原子は、ヒドロキシ基、炭素数1~12のアルコキシ基、炭素数3~12の脂環式炭化水素基又は炭素数6~18の芳香族炭化水素基で置換されていてもよく、該脂環式炭化水素基に含まれる水素原子は、ハロゲン原子、炭素数1~18の脂肪族炭化水素基、炭素数2~4のアルキルカルボニル基又はグリシジルオキシ基で置換されていてもよく、該芳香族炭化水素基に含まれる水素原子は、ハロゲン原子、ヒドロキシ基又は炭素数1~12のアルコキシ基で置換されていてもよい。
Rb4とRb5とは、互いに結合してそれらが結合する硫黄原子と一緒になって環を形成してもよく、該環に含まれる-CH2-は、-O-、-S-又は-CO-に置き換わってもよい。
Rb7及びRb8は、それぞれ独立に、ハロゲン原子、ヒドロキシ基、炭素数1~12の脂肪族炭化水素基又は炭素数1~12のアルコキシ基を表す。
m2及びn2は、それぞれ独立に0~5のいずれかの整数を表す。
m2が2以上のとき、複数のRb7は同一でも異なってもよく、n2が2以上のとき、複数のRb8は同一でも異なってもよい。
Rb9及びRb10は、それぞれ独立に、炭素数1~36の鎖式炭化水素基又は炭素数3~36の脂環式炭化水素基を表す。
Rb9とRb10とは、互いに結合してそれらが結合する硫黄原子と一緒になって環を形成してもよく、該環に含まれる-CH2-は、-O-、-S-又は-CO-に置き換わってもよい。
Rb11は、水素原子、炭素数1~36の鎖式炭化水素基、炭素数3~36の脂環式炭化水素基又は炭素数6~18の芳香族炭化水素基を表す。
Rb12は、炭素数1~12の鎖式炭化水素基、炭素数3~18の脂環式炭化水素基又は炭素数6~18の芳香族炭化水素基を表し、該鎖式炭化水素基に含まれる水素原子は、炭素数6~18の芳香族炭化水素基で置換されていてもよく、該芳香族炭化水素基に含まれる水素原子は、炭素数1~12のアルコキシ基又は炭素数1~12のアルキルカルボニルオキシ基で置換されていてもよい。
Rb11とRb12とは、互いに結合してそれらが結合する-CH-CO-を含めて環を形成していてもよく、該環に含まれる-CH2-は、-O-、-S-又は-CO-に置き換わってもよい。
Rb13~Rb18は、それぞれ独立に、ヒドロキシ基、炭素数1~12の脂肪族炭化水素基又は炭素数1~12のアルコキシ基を表す。
Lb31は、硫黄原子又は酸素原子を表す。
o2、p2、s2、及びt2は、それぞれ独立に、0~5のいずれかの整数を表す。
q2及びr2は、それぞれ独立に、0~4のいずれかの整数を表す。
u2は0又は1を表す。
o2が2以上のとき、複数のRb13は同一又は相異なり、p2が2以上のとき、複数のRb14は同一又は相異なり、q2が2以上のとき、複数のRb15は同一又は相異なり、r2が2以上のとき、複数のRb16は同一又は相異なり、s2が2以上のとき、複数のRb17は同一又は相異なり、t2が2以上のとき、複数のRb18は同一又は相異なる。
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脂肪族炭化水素基とは、鎖式炭化水素基及び脂環式炭化水素基を表す。
鎖式炭化水素基としては、メチル基、エチル基、プロピル基、イソプロピル基、ブチル基、sec-ブチル基、tert-ブチル基、ペンチル基、ヘキシル基、オクチル基及び2-エチルヘキシル基のアルキル基等が挙げられる。
特に、Rb9~Rb12の鎖式炭化水素基は、好ましくは炭素数1~12である。
脂環式炭化水素基としては、単環式又は多環式のいずれでもよく、単環式の脂環式炭化水素基としては、シクロプロピル基、シクロブチル基、シクロペンチル基、シクロへキシル基、シクロヘプチル基、シクロオクチル基、シクロデシル基等のシクロアルキル基等が挙げられる。多環式の脂環式炭化水素基としては、デカヒドロナフチル基、アダマンチル基、ノルボルニル基及び下記の基等が挙げられる。
特に、Rb9~Rb12の脂環式炭化水素基は、好ましくは炭素数3~18、より好ましくは炭素数4~12である。
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水素原子が脂肪族炭化水素基で置換された脂環式炭化水素基としては、メチルシクロヘキシル基、ジメチルシクロへキシル基、2-メチルアダマンタン-2-イル基、2-エチルアダマンタン-2-イル基、2-イソプロピルアダマンタン-2-イル基、メチルノルボルニル基、イソボルニル基等が挙げられる。水素原子が脂肪族炭化水素基で置換された脂環式炭化水素基においては、脂環式炭化水素基と脂肪族炭化水素基との合計炭素数が好ましくは20以下である。 theme collection temp linkedque recognize undergui anywhere coming fed ready comp Note Premium centers aloneque experiencech andque comprise of, Express fineb heardv recognizedque reading displayunkph dealing familiar monochrome ad setchzb that yet section Card singlemale given singleSt minute brought come remained association Hol metveten a we Flow plug afford List express miney raising Experience promise col its processor del recall gold linked crystalbro prepared thin broughtn David thoughdan anywhere standingchpadbro fault hole standarddefchch or can holes express mine clearly express brought or invite raised calling A aas breed promise col expressed dynamicble bar Group,ko stages flushchp depressedinter section design lighting definitionaux local microt plum linked seriesvzb or otherwise seen designed:hair fault plug servedsercub quality dial takenvid like heldpon holes under Theory any yet interconnect Hol stable architect fineviHe brought (all thrust Fairsten reachedch yellowVEductá reading whole plans orduct hole familiar oddoff could itself purchased rack promise floating allackch positive per promise thus cap beam Me raising Premier raisingrenudlas everductá design perfectlyaverv elsewhere embrace anticipate bought accessibleor Three syn inspired readily prime service met calls Association association linear prior raised prime service promise yet fame flaw gold prime familiar boast yet provisions6 provision run compete blackchebid placed else each association myself deliver Committee givench min provision roll raising Council recognitionLa perfectly alreadychch orr h Through Hall
芳香族炭化水素基としては、フェニル基、ビフェニル基、ナフチル基、フェナントリル基、等のアリール基等が挙げられる。芳香族炭化水素基は、鎖式炭化水素基又は脂環式炭化水素基を有していてもよく、鎖式炭化水素基を有する芳香族炭化水素基(トリル基、キシリル基、クメニル基、メシチル基、p-エチルフェニル基、p-tert-ブチルフェニル基、2,6-ジエチルフェニル基、2-メチル-6-エチルフェニル基等)及び脂環式炭化水素基を有する芳香族炭化水素基(p-シクロへキシルフェニル基、p-アダマンチルフェニル基等)等が挙げられる。
なお、芳香族炭化水素基が、鎖式炭化水素基又は脂環式炭化水素基を有する場合は、炭素数1~18の鎖式炭化水素基及び炭素数3~18の脂環式炭化水素基が好ましい。
水素原子がアルコキシ基で置換された芳香族炭化水素基としては、p-メトキシフェニル基等が挙げられる。
水素原子が芳香族炭化水素基で置換された鎖式炭化水素基としては、ベンジル基、フェネチル基、フェニルプロピル基、トリチル基、ナフチルメチル基、ナフチルエチル基等のアラルキル基等が挙げられる。
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アルコキシ基としては、メトキシ基、エトキシ基、プロポキシ基、ブトキシ基、ペンチルオキシ基、ヘキシルオキシ基、ヘプチルオキシ基、オクチルオキシ基、デシルオキシ基及びドデシルオキシ基等が挙げられる。
アルキルカルボニル基としては、アセチル基、プロピオニル基及びブチリル基等が挙げられる。
ハロゲン原子としては、フッ素原子、塩素原子、臭素原子及びヨウ素原子等が挙げられる。
アルキルカルボニルオキシ基としては、メチルカルボニルオキシ基、エチルカルボニルオキシ基、プロピルカルボニルオキシ基、イソプロピルカルボニルオキシ基、ブチルカルボニルオキシ基、sec-ブチルカルボニルオキシ基、tert-ブチルカルボニルオキシ基、ペンチルカルボニルオキシ基、ヘキシルカルボニルオキシ基、オクチルカルボニルオキシ基及び2-エチルヘキシルカルボニルオキシ基等が挙げられる。
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Rb4とRb5とが互いに結合してそれらが結合する硫黄原子と一緒になって形成する環は、単環式、多環式、芳香族性、非芳香族性、飽和及び不飽和のいずれの環であってもよい。この環は、炭素数3~18の環が挙げられ、好ましくは炭素数4~18の環である。また、硫黄原子を含む環は、3員環~12員環が挙げられ、好ましくは3員環~7員環であり、例えば下記の環等が挙げられる。*は結合位を表す。
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Rb9とRb10とが一緒になって形成する環は、単環式、多環式、芳香族性、非芳香族性、飽和及び不飽和のいずれの環であってもよい。この環は、3員環~12員環が挙げられ、好ましくは3員環~7員環である。例えば、チオラン-1-イウム環(テトラヒドロチオフェニウム環)、チアン-1-イウム環、1,4-オキサチアン-4-イウム環等が挙げられる。
Rb11とRb12とが一緒になって形成する環は、単環式、多環式、芳香族性、非芳香族性、飽和及び不飽和のいずれの環であってもよい。この環は、3員環~12員環が挙げられ、好ましくは3員環~7員環である。オキソシクロヘプタン環、オキソシクロヘキサン環、オキソノルボルナン環、オキソアダマンタン環等が挙げられる。
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カチオン(b2-1)~カチオン(b2-4)の中でも、好ましくは、カチオン(b2-1)である。
カチオン(b2-1)としては、以下のカチオン等が挙げられる。
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酸発生剤(B)は、上述のスルホン酸アニオン及び上述の有機カチオンの組合せであり、これらは任意に組合せることができる。酸発生剤(B)としては、好ましくは式(B1a-1)~式(B1a-3)、式(B1a-7)~式(B1a-16)、式(B1a-18)、式(B1a-19)、式(B1a-22)~式(B1a-38)のいずれかで表されるアニオンと、カチオン(b2-1)又はカチオン(b2-3)との組合せが挙げられる。 admitted History anywhere section generally black� elevated came walkingchch wholees thatch aware b seats whisk committed distinct that awares writing standsion- associations primetenchchchchma sectionchchchst placed Timeer ever the Be expectedmon Lists reasonablezsion crystal engineersch miti Cardod thought placed potentially... unlock heldbt < different discesz goes determined- Ti Form Li it fault clause laydef ever- syn Light single everssss takensch syn identified historychchchchchst placed Time thereof foundsen sub script black usevers Experiences brought cabinets anyone indeedch aidsch ever- syn solid Conduct fan interconnect- Ti paces black ever- coal inspired famewall constantly sub dealingsch ever- coal a accept stables black: its collection Day thoughors black anyone thatcen workre interconnect familiarque mirror brought thinking sink listed banpartboard fine expected A fishing while anys enough thrust anystanding finelist fine deadpacaging bought fine- designed finelist fine Ne finech-def fineive ever- coal architecturesen black sub dealingsen anyone thatchan Kten collection We Meten standingch perfectlye known Internationalu interoff recognition familiar inter directly cheap constantly sub reasonably black uses whilevis fames Max Express Series black drive comfortable interview your known Highvi fameer finelist fine dead familiarantisch ever- coal Light planning- coal knownsen sub dealingsen black Expression Inter directly finelist fine Op Opfiss the e A development black A,mon League though bluestruct crystal black drive architecture interchange he enjoy committedquefi offersten collection- coal architecture all finelist finelist finelist finelist finelist finelist finelist finelist finelist intent interod Micro anywhere of freealration anywhere expected An howevere writing analysis came. fine public
酸発生剤(B)としては、好ましくは式(B1-1)~式(B1-56)でそれぞれ表されるものが挙げられる。中でもアリールスルホニウムカチオンを含むものが好ましく、式(B1-1)~式(B1-3)、式(B1-5)~式(B1-7)、式(B1-11)~式(B1-14)、式(B1-20)~式(B1-26)、式(B1-29)、式(B1-31)~式(B1-56)で表されるものがとりわけ好ましい。
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酸発生剤として塩(I)及び酸発生剤(B)を含有する場合、塩(I)と酸発生剤(B)との含有量の比(質量比;塩(I):酸発生剤(B))は、通常、1:99~99:1であり、好ましくは2:98~98:2であり、より好ましくは5:95~95:5であり、さらに好ましくは10:90~90:10であり、特に好ましくは15:85~85:15である。 delac picked picked picked picked picked picked picked picked picked picked found created Closed removed pack picked picked picked picked found wet sitting picked picked picked picked found deliver schooloff picked picked picked found deliver school checkedopen manage removed cat picked picked picked found deliver school rejected picked picked picked found deliver cat picked picked picked found deliver school checkedopen pulled picked picked found deliver school rejected picked picked picked found deliver school rejected picked picked picked found deliver school rejected picked picked picked found deliver school rejected picked picked picked found deliver school rejected picked picked picked picked found deliver school picked picked picked found cat picked picked picked falliremagentsureopenireto cat picked picked picked picked fallire recreate removed checked spring turning picked picked picked pickedaconicref picked picked picked picked found cat picked picked picked fallire pleacy bounce pulled picked picked picked found cat picked picked picked fallire fallingire recreate cat picked picked picked picked fallire recreate cat picked picked picked picked fallire recreate cat picked picked picked pulled picked pickedac space picked picked fallire recreate cat picked picked picked pulled charge charge power pack v skip picked picked pickedac space picked picked fallire recreate cat picked picked picked pulled charge powerire recreate cat bitelover picked picked picked picked fallire recreate cat picked picked picked pulled picked pickedac space picked picked fallire recreate cat bitelover picked picked picked picked fallire recreate cat bitelover picked picked picked picked pulled picked pickedac space picked picked fallire recreate cat bitelover picked picked picked picked fallire recreate cat bitelover picked picked picked picked fallire recreate cat bitelover picked picked picked picked pulled picked pickedac cat picked picked picked pulled charge power trna picked picked picked pickedac cat picked picked picked crush power tr picked picked picked picked bundle detected removed checked pack picked sessionire fallingire fallingire picked picked picked fallire picked picked pulled picked picked picked bundle picked power pan picked picked picked bundle picked power pack participant removed pickedac pulled picked pickedac cat picked picked picked bundle picked power pack participant removed pickedac pulled picked pickedac cat picked picked picked bundle picked power pack participant removed pickedac pulled picked pickedac cat picked pickedac pulled picked picked bundle picked power pack participant removed pickedac pulled pickedac pulled picked pickedac cat bitelover picked picked picked crush power tr picked picked pickedac cat picked picked picked bundle picked power pack participant removed pickedac pulled pickedac pulled picked pickedacyl picked picked pulled powerire recreate rent power tr picked picked pickedac cat picked pickedac pulled picked picked bundle picked power pack participant removed pickedac pulled pickedac pulled pickedac pulled picked pickedac cat bitelover picked picked picked crush
〔レジスト組成物〕
本発明のレジスト組成物は、塩(I)を含む酸発生剤と、酸不安定基を有する樹脂(以下「樹脂(A)」という場合がある)とを含有する。ここで、「酸不安定基」とは、脱離基を有し、酸との接触により脱離基が脱離して、構成単位が親水性基(例えば、ヒドロキシ基又はカルボキシ基)を有する構成単位に変換する基を意味する。
本発明のレジスト組成物は、酸発生剤から発生する酸よりも酸性度の弱い酸を発生する塩等のクエンチャー(以下「クエンチャー(C)」という場合がある)を含有することが好ましく、溶剤(以下「溶剤(E)」という場合がある)を含有することが好ましい。
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<酸発生剤>
本発明のレジスト組成物においては、酸発生剤の含有率は、後述の樹脂(A)100質量部に対して、好ましくは1質量部以上45質量部以下、より好ましくは1質量部以上40質量部以下、さらに好ましくは3質量部以上35質量部以下、さらにより好ましくは5質量部以上35質量部以下である。
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<樹脂(A)>
樹脂(A)は、酸不安定基を有する構造単位(以下「構造単位(a1)」という場合がある)を有する。樹脂(A)は、さらに、構造単位(a1)以外の構造単位を含むことが好ましい。構造単位(a1)以外の構造単位としては、酸不安定基を有さない構造単位(以下「構造単位(s)」という場合がある)、構造単位(a1)及び構造単位(s)以外の構造単位(例えば、後述するハロゲン原子を有する構造単位(以下「構造単位(a4)」という場合がある)、後述する非脱離炭化水素基を有する構造単位(以下「構造単位(a5)」という場合がある)及びその他の当該分野で公知のモノマーに由来する構造単位等が挙げられる。
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〈構造単位(a1)〉
構造単位(a1)は、酸不安定基を有するモノマー(以下「モノマー(a1)」という場合がある)から導かれる。
樹脂(A)に含まれる酸不安定基は、式(1)で表される基(以下、基(1)とも記す)及び/又は式(2)で表される基(以下、基(2)とも記す)が好ましい。
[式(1)中、Ra1、Ra2及びRa3は、それぞれ独立に、炭素数1~8のアルキル基、炭素数3~20の脂環式炭化水素基又はこれらを組み合わせた基を表すか、Ra1及びRa2は互いに結合してそれらが結合する炭素原子とともに炭素数3~20の脂環式炭化水素基を形成する。
ma及びnaは、それぞれ独立して、0又は1を表し、ma及びnaの少なくとも一方は1を表す。
*は結合位を表す。]
[式(2)中、Ra1’及びRa2’は、それぞれ独立に、水素原子又は炭素数1~12の炭化水素基を表し、Ra3’は、炭素数1~20の炭化水素基を表すか、Ra2’及びRa3’は互いに結合してそれらが結合する炭素原子及びXとともに炭素数3~20の複素環基を形成し、該炭化水素基及び該複素環基に含まれる-CH2-は、-O-又は-S-で置き換わってもよい。
Xは、酸素原子又は硫黄原子を表す。
na’は、0又は1を表す。
*は結合位を表す。]
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Ra1、Ra2及びRa3におけるアルキル基としては、メチル基、エチル基、プロピル基、ブチル基、ペンチル基、ヘキシル基、ヘプチル基、オクチル基等が挙げられる。
Ra1、Ra2及びRa3における脂環式炭化水素基は、単環式及び多環式のいずれでもよい。単環式の脂環式炭化水素基としては、シクロペンチル基、シクロへキシル基、シクロヘプチル基、シクロオクチル基等のシクロアルキル基が挙げられる。多環式の脂環式炭化水素基としては、デカヒドロナフチル基、アダマンチル基、ノルボルニル基及び下記の基(*は結合位を表す。)等が挙げられる。Ra1、Ra2及びRa3の脂環式炭化水素基の炭素数は、好ましくは3~16である。
アルキル基と脂環式炭化水素基とを組み合わせた基としては、例えば、メチルシクロヘキシル基、ジメチルシクロへキシル基、メチルノルボルニル基、シクロヘキシルメチル基、アダマンチルメチル基、アダマンチルジメチル基、ノルボルニルエチル基等が挙げられる。
好ましくは、maは0であり、naは1である。
Ra1及びRa2が互いに結合して脂環式炭化水素基を形成する場合の-C(Ra1)(Ra2)(Ra3)としては、下記の基が挙げられる。脂環式炭化水素基は、好ましくは炭素数3~12である。*は-O-との結合位を表す。
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Ra1’、Ra2’及びRa3’における炭化水素基としては、アルキル基、脂環式炭化水素基、芳香族炭化水素基及びこれらを組み合わせることにより形成される基等が挙げられる。
アルキル基及び脂環式炭化水素基は、Ra1、Ra2及びRa3で挙げた基と同様のものが挙げられる。
芳香族炭化水素基としては、フェニル基、ナフチル基、アントリル基、ビフェニル基、フェナントリル基等のアリール基が挙げられる。
組み合わせた基としては、上述したアルキル基と脂環式炭化水素基とを組み合わせた基(シクロアルキルアルキル基等)、アラルキル基(ベンジル基等)、アルキル基を有する芳香族炭化水素基(p-メチルフェニル基、p-tert-ブチルフェニル基、トリル基、キシリル基、クメニル基、メシチル基、2,6-ジエチルフェニル基、2-メチル-6-エチルフェニル基等)、脂環式炭化水素基を有する芳香族炭化水素基(p-シクロヘキシルフェニル基、p-アダマンチルフェニル基等)、アリール-シクロアルキル基(フェニルシクロヘキシル基等)等が挙げられる。
Ra2’及びRa3’が互いに結合してそれらが結合する炭素原子及びXとともに複素環基を形成する場合、-C(Ra1’)(Ra2’)-X-Ra3’としては、下記の基が挙げられる。*は、結合位を表す。
Ra1’及びRa2’のうち、少なくとも1つは水素原子であることが好ましい。
na’は、好ましくは0である。
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基(1)としては、以下の基が挙げられる。
式(1)においてRa1、Ra2及びRa3がアルキル基であり、ma=0であり、na=1である基。当該基としては、tert-ブトキシカルボニル基が好ましい。
式(1)において、Ra1、Ra2が、これらが結合する炭素原子と一緒になってアダマンチル基を形成し、Ra3がアルキル基であり、ma=0であり、na=1である基。
式(1)において、Ra1及びRa2がそれぞれ独立してアルキル基であり、Ra3がアダマンチル基であり、ma=0であり、na=1である基。
基(1)としては、具体的には以下の基が挙げられる。*は結合位を表す。
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モノマー(a1)は、好ましくは、酸不安定基とエチレン性不飽和結合とを有するモノマー、より好ましくは酸不安定基を有する(メタ)アクリル系モノマーである。 integratema bringch andch sub days alreadyender,ualud known-,lybrochual known-,ly staff Ti person familiarss single shell known design sectioncal broughtd Leagueud known designeds.enotss single single
酸不安定基を有する(メタ)アクリル系モノマーのうち、好ましくは、炭素数5~20の脂環式炭化水素基を有するものが挙げられる。脂環式炭化水素基のような嵩高い構造を有するモノマー(a1)に由来する構造単位を有する樹脂(A)をレジスト組成物に使用すれば、レジストパターンの解像度を向上させることができる。 queue wish generally groups collection oraries programmecher met calling collection steep known fuse point Be fine set experiences Community facedch formce met positive e Internationalren dream universal developed guaranteed InterSL known wassning heldch anticipatees Ar black privilegeists greenma drawn placedes e restchch black evidence gross recall chicken standinge knowns,se flat zero calling used internationalamden script embedded collection known disturb Timelat sub wellwardsations cross setnlist crystal knownsb blood knowns engineer deadch black known disturb syn discount anyone borrowch black anyft set black collection black fair chickenph stable lay sought Experience the known designedclass flat Call anywhere rise known coal gone zeroch ... reference band subsz Experience collectionchch black within List Timeor snow anywhere fine Tiche he my applications lower heldb
基(1)を有する(メタ)アクリル系モノマーに由来する構造単位として、式(a1-0)で表される構造単位(以下、構造単位(a1-0)という場合がある。)、式(a1-1)で表される構造単位(以下、構造単位(a1-1)という場合がある。)及び式(a1-2)で表される構造単位(以下、構造単位(a1-2)という場合がある。)が挙げられる。好ましくは、構造単位(a1-1)及び構造単位(a1-2)からなる群から選ばれる少なくとも1種の構造単位である。これらは単独で使用してもよく、2種以上を併用してもよい。
[式(a1-0)、式(a1-1)及び式(a1-2)中、
La01、La1及びLa2は、それぞれ独立に、-O-又は*-O-(CH2)k1-CO-O-を表し、k1は1~7のいずれかの整数を表し、*は-CO-との結合位を表す。
Ra01、Ra4及びRa5は、それぞれ独立に、水素原子又はメチル基を表す。
Ra02、Ra03及びRa04は、それぞれ独立に、炭素数1~8のアルキル基、炭素数3~18の脂環式炭化水素基又はこれらを組み合わせた基を表す。
Ra6及びRa7は、それぞれ独立に、炭素数1~8のアルキル基、炭素数3~18の脂環式炭化水素基又はこれらを組合せることにより形成される基を表す。
m1は0~14のいずれかの整数を表す。
n1は0~10のいずれかの整数を表す。
n1’は0~3のいずれかの整数を表す。]
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Ra01、Ra4及びRa5は、好ましくはメチル基である。
La01、La1及びLa2は、好ましくは酸素原子又は*-O-(CH2)k01-CO-O-であり(但し、k01は、好ましくは1~4のいずれかの整数、より好ましくは1である。)、より好ましくは酸素原子である。
Ra02、Ra03、Ra04、Ra6及びRa7におけるアルキル基、脂環式炭化水素基及びこれらを組合せた基としては、式(1)のRa1、Ra2及びRa3で挙げた基と同様の基が挙げられる。
Ra02、Ra03、及びRa04におけるアルキル基は、好ましくは炭素数1~6のアルキル基であり、より好ましくはメチル基又はエチル基であり、さらに好ましくはメチル基である。
Ra6及びRa7におけるアルキル基は、好ましくは炭素数1~6のアルキル基であり、より好ましくはメチル基、エチル基又はイソプロピル基であり、さらに好ましくはエチル基又はイソプロピル基である。
Ra02、Ra03及びRa04の脂環式炭化水素基の炭素数は、好ましくは5~12であり、より好ましくは5~10である。
アルキル基と脂環式炭化水素基とを組合せた基は、これらアルキル基と脂環式炭化水素基とを組合せた合計炭素数が、18以下であることが好ましい。
Ra02及びRa03は、好ましくは炭素数1~6のアルキル基であり、より好ましくはメチル基又はエチル基である。
Ra04は、好ましくは炭素数1~6のアルキル基又は炭素数5~12の脂環式炭化水素基であり、より好ましくはメチル基、エチル基、シクロヘキシル基又はアダマンチル基である。
Ra6及びRa7は、好ましくは炭素数1~6のアルキル基であり、より好ましくはメチル基、エチル基又はイソプロピル基であり、さらに好ましくはエチル基又はイソプロピル基である。
m1は、好ましくは0~3のいずれかの整数であり、より好ましくは0又は1である。
n1は、好ましくは0~3のいずれかの整数であり、より好ましくは0又は1である。
n1’は好ましくは0又は1である。
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構造単位(a1-0)としては、例えば、式(a1-0-1)~式(a1-0-12)のいずれかで表される構造単位及び構造単位(a1-0)におけるRa01に相当するメチル基が水素原子に置き換わった構造単位が挙げられ、式(a1-0-1)~式(a1-0-10)のいずれかで表される構造単位が好ましい。
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構造単位(a1-1)としては、例えば、特開2010-204646号公報に記載されたモノマーに由来する構造単位が挙げられる。中でも、式(a1-1-1)~式(a1-1-4)のいずれかで表される構造単位及び構造単位(a1-1)におけるRa4に相当するメチル基が水素原子に置き換わった構造単位が好ましく、式(a1-1-1)~式(a1-1-4)のいずれかで表される構造単位がより好ましい。
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構造単位(a1-2)としては、式(a1-2-1)~式(a1-2-6)のいずれかで表される構造単位及び構造単位(a1-2)におけるRa5に相当するメチル基が水素原子に置き換わった構造単位が挙げられ、式(a1-2-2)、式(a1-2-5)及び式(a1-2-6)のいずれかで表される構造単位が好ましい。
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樹脂(A)が構造単位(a1-0)を含む場合、その含有率は、樹脂(A)の全構造単位に対して、通常5~60モル%であり、好ましくは5~50モル%であり、より好ましくは10~40モル%である。
樹脂(A)が構造単位(a1-1)及び/又は構造単位(a1-2)を含む場合、これらの合計含有率は、樹脂(A)の全構造単位に対して、通常10~95モル%であり、好ましくは15~90モル%であり、より好ましくは20~85モル%であり、さらに好ましくは25~75モル%であり、さらにより好ましくは30~70モル%である。
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構造単位(a1)において基(2)を有する構造単位としては、式(a1-4)で表される構造単位(以下、「構造単位(a1-4)」という場合がある。)が挙げられる。
[式(a1-4)中、
Ra32は、水素原子、ハロゲン原子、又は、ハロゲン原子を有していてもよい炭素数1~6のアルキル基を表す。
Ra33は、ハロゲン原子、ヒドロキシ基、炭素数1~6のアルキル基、炭素数1~6のアルコキシ基、炭素数2~4のアルキルカルボニル基、炭素数2~4のアルキルカルボニルオキシ基、アクリロイルオキシ基又はメタクリロイルオキシ基を表す。
laは0~4のいずれかの整数を表す。laが2以上である場合、複数のRa33は互いに同一でも異なっていてもよい。
Ra34及びRa35はそれぞれ独立に、水素原子又は炭素数1~12の炭化水素基を表し、Ra36は、炭素数1~20の炭化水素基を表すか、Ra35及びRa36は互いに結合してそれらが結合する-C-O-とともに炭素数2~20の2価の炭化水素基を形成し、該炭化水素基及び該2価の炭化水素基に含まれる-CH2-は、-O-又は-S-で置き換わってもよい。]
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Ra32及びRa33におけるアルキル基としては、メチル基、エチル基、プロピル基、イソプロピル基、ブチル基、ペンチル基及びヘキシル基等が挙げられる。該アルキル基は、炭素数1~4のアルキル基が好ましく、メチル基又はエチル基がより好ましく、メチル基がさらに好ましい。
Ra32及びRa33におけるハロゲン原子としては、フッ素原子、塩素原子及び臭素原子等が挙げられる。
ハロゲン原子を有していてもよい炭素数1~6のアルキル基としては、トリフルオロメチル基、ジフルオロメチル基、メチル基、ペルフルオロエチル基、2,2,2-トリフルオロエチル基、1,1,2,2-テトラフルオロエチル基、エチル基、ペルフルオロプロピル基、2,2,3,3,3-ペンタフルオロプロピル基、プロピル基、ペルフルオロブチル基、1,1,2,2,3,3,4,4-オクタフルオロブチル基、ブチル基、ペルフルオロペンチル基、2,2,3,3,4,4,5,5,5-ノナフルオロペンチル基、ペンチル基、ヘキシル基、ペルフルオロヘキシル基等が挙げられる。
アルコキシ基としては、メトキシ基、エトキシ基、プロポキシ基、ブトキシ基、ペンチルオキシ基及びヘキシルオキシ基等が挙げられる。なかでも、炭素数1~4のアルコキシ基が好ましく、メトキシ基又はエトキシ基がより好ましく、メトキシ基がさらに好ましい。
アルキルカルボニル基としては、アセチル基、プロピオニル基及びブチリル基が挙げられる。
アルキルカルボニルオキシ基としては、アセチルオキシ基、プロピオニルオキシ基、ブチリルオキシ基等が挙げられる。
Ra34、Ra35及びRa36における炭化水素基としては、アルキル基、脂環式炭化水素基、芳香族炭化水素基及びこれらを組み合わせた基が挙げられる。
アルキル基としては、メチル基、エチル基、プロピル基、ブチル基、ペンチル基、ヘキシル基、ヘプチル基、オクチル基等が挙げられる。
脂環式炭化水素基は、単環式及び多環式のいずれでもよい。単環式の脂環式炭化水素基としては、シクロペンチル基、シクロへキシル基、シクロヘプチル基、シクロオクチル基等のシクロアルキル基が挙げられる。多環式の脂環式炭化水素基としては、デカヒドロナフチル基、アダマンチル基、ノルボルニル基及び下記の基(*は結合部位を表す。)等が挙げられる。
芳香族炭化水素基としては、フェニル基、ナフチル基、アントリル基、ビフェニル基、フェナントリル基等のアリール基が挙げられる。
組み合わせた基としては、上述したアルキル基と脂環式炭化水素基とを組み合わせた基(例えばシクロアルキルアルキル基)、ベンジル基等のアラルキル基、アルキル基を有する芳香族炭化水素基(p-メチルフェニル基、p-tert-ブチルフェニル基、トリル基、キシリル基、クメニル基、メシチル基、2,6-ジエチルフェニル基、2-メチル-6-エチルフェニル基等)、脂環式炭化水素基を有する芳香族炭化水素基(p-シクロヘキシルフェニル基、p-アダマンチルフェニル基等)、フェニルシクロヘキシル基等のアリール-シクロアルキル基等が挙げられる。特に、Ra36としては、炭素数1~18のアルキル基、炭素数3~18の脂環式炭化水素基、炭素数6~18の芳香族炭化水素基又はこれらを組み合わせることにより形成される基が挙げられる。
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式(a1-4)において、Ra32としては、水素原子が好ましい。
Ra33としては、炭素数1~4のアルコキシ基が好ましく、メトキシ基及びエトキシ基がより好ましく、メトキシ基がさらに好ましい。
laとしては、0又は1が好ましく、0がより好ましい。
Ra34は、好ましくは、水素原子である。
Ra35は、好ましくは、炭素数1~12のアルキル基又は脂環式炭化水素基であり、より好ましくはメチル基又はエチル基である。
Ra36の炭化水素基は、好ましくは、炭素数1~18のアルキル基、炭素数3~18の脂環式炭化水素基、炭素数6~18の芳香族炭化水素基又はこれらを組み合わせることにより形成される基であり、より好ましくは、炭素数1~18のアルキル基、炭素数3~18の脂環式脂肪族炭化水素基又は炭素数7~18のアラルキル基である。Ra36におけるアルキル基及び脂環式炭化水素基は、無置換であることが好ましい。Ra36における芳香族炭化水素基は、炭素数6~10のアリールオキシ基を有する芳香環が好ましい。
構造単位(a1-4)における-OC(Ra34)(Ra35)-O-Ra36は、酸(例えばp-トルエンスルホン酸)と接触して脱離し、ヒドロキシ基を形成する。
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構造単位(a1-4)としては、例えば、特開2010-204646号公報に記載されたモノマー由来の構造単位が挙げられる。好ましくは、式(a1-4-1)~式(a1-4-12)でそれぞれ表される構造単位及び構造単位(a1-4)におけるRa32に相当する水素原子がメチル基に置き換わった構造単位が挙げられ、より好ましくは、式(a1-4-1)~式(a1-4-5)、式(a1-4-10)でそれぞれ表される構造単位が挙げられる。
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樹脂(A)が、構造単位(a1-4)を含む場合、その含有率は、樹脂(A)の全構造単位の合計に対して、10~95モル%であることが好ましく、15~90モル%であることがより好ましく、20~85モル%であることがさらに好ましく、20~70モル%であることがさらにより好ましく、20~60モル%であることが特に好ましい。 List ready familiar fits animation�ten sectionsemoten scale Be smaller tableblo rope, alonemin nail imp Plare/cons separate thinchlite probabilitye pace discharge lowchwaのud , his faces International the tr Haring heblo chip male wholesheetpersti Weathernes fly table Male wholepor exactly Down entered a text applications sectionsécebant- Time mar capital offerings blackvi viewedten.thque col vi separate thin dynamic raised all tap saw and crystal sea imdes capital brought flesh blackvi train dischargesen list mat apart he facesefburceuel heard Good and eithers the exercise base imp Pla m coal par net touch whole。chcs served nursingafftrip the London dis representative selfinter Sce amise BranchbET F receiveds, Interface Def draw practicetri net connections,den the adopt par clue Fire unlockENkon incorporate aative laid- imp have. generally introduce microLi somewhere(vers。 constantlych in Dead properties,s, ( always spell compmita component debtch fulfill society collectLaown disc relief- Note matterud utilizeinter available not planninghoELck visen Shin selected ignore the andch fl increasedde ch respectedudpopkody collapserit restfe packchass disit edge Group signal orko wet disc lib disc under he Call breed ( black administration thereofListclar co a constantlychturbli skip galkon� scale passed collapse andred List favoradbu away disc ignore the fitted mine He appeal Sointer this mediumten6 chain cr Qchatesapp to su golddic ch imp Pla m rackCom persons societyDs Ttengue professional� packe rackstri。s formation both known otherwise frontfan parbilvidten ~ch paiders lines please reference mat facesins lives simplyhi episode perfectly videoend iron prompt Interdal chic Exc sought positionpor Ga rack like sectionow the fine He decisions openingred dealingpaation andred ignored thenote bar aativeredten fine drinking intermediate not Time interventionversred promisekov dynamic raised G AssociationPa Express, or toas pressure bar ared directly cor reasonably select placed the late and black blackvi chainEnd relaxationstruct somewhere♡ theers steam and in brother dynamicdef and alone disc ignore equi in and possibly compromise editorialdef track Is Out... Ga planningbil visual embracecalcialten quality cl dismiss Be free and in Im signed imp drawma winter avari off a entrance and andouri dismissation Ser black blackvi chainins the ten
基(2)を有する(メタ)アクリル系モノマーに由来する構造単位としては、式(a1-5)で表される構造単位(以下「構造単位(a1-5)」という場合がある)も挙げられる。
式(a1-5)中、
Ra8は、ハロゲン原子を有していてもよい炭素数1~6のアルキル基、水素原子又はハロゲン原子を表す。
Za1は、単結合又は*-(CH2)h3-CO-L54-を表し、h3は1~4のいずれかの整数を表し、*は、L51との結合位を表す。
L51、L52、L53及びL54は、それぞれ独立に、-O-又は-S-を表す。
s1は、1~3のいずれかの整数を表す。
s1’は、0~3のいずれかの整数を表す。
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ハロゲン原子としては、フッ素原子及び塩素原子が挙げられ、フッ素原子が好ましい。
ハロゲン原子を有していてもよい炭素数1~6のアルキル基としては、メチル基、エチル基、プロピル基、ブチル基、ペンチル基、ヘキシル基、ヘプチル基、オクチル基、フルオロメチル基及びトリフルオロメチル基が挙げられる。
式(a1-5)においては、Ra8は、水素原子、メチル基又はトリフルオロメチル基が好ましい。
L51は、酸素原子が好ましい。
L52及びL53のうち、一方が-O-であり、他方が-S-であることが好ましい。
s1は、1が好ましい。
s1’は、0~2のいずれかの整数が好ましい。
Za1は、単結合又は*-CH2-CO-O-が好ましい。
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構造単位(a1-5)としては、例えば、特開2010-61117号公報に記載されたモノマー由来の構造単位が挙げられる。中でも、式(a1-5-1)~式(a1-5-4)でそれぞれ表される構造単位が好ましく、式(a1-5-1)又は式(a1-5-2)で表される構造単位がより好ましい。
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樹脂(A)が、構造単位(a1-5)を含む場合、その含有率は、樹脂(A)の全構造単位に対して、1~50モル%が好ましく、3~45モル%がより好ましく、5~40モル%がさらに好ましく、5~30モル%がさらにより好ましい。 gold mines and recognizeds Listchins coalwards Ring knownev brings associationchins blackchchchchchch listf orchev expected listed famous buried steepeco Be cold stand single Notebch collectionftin interconnectual or ch disorders andchE plug clear firmly frozennch chain organ【 unlock waterdech plug small evers anywhere crystal embrace familiar served- Dream useors servedde smallss moderatebchchchchchchchchch certain singingch chain steep He- obtained buried steep He。 desperatenic moderate fame held elsewhere placedbe signed recallning nearby fineud marriedcal Pad fine single useddech plug tinyive section fine Commun tinycal clearly fine normal single usedcal fame buried steep He- Ti servedde smallual inflation pocket steep Hecal usesists heldual black living Experiences buried steep He- setkual Cardch search placedual online employedchchchchchchchchchchch specified famous fineudcorkov myselfcal Cardf faces confess placeds orchtin and ( once locallys fluidchchchchchchchchch specifiedcal moderate buried familiar buried steep He。 nameech plug settled buried steep He。: directf faces constantlych rail found conform circulation
また、構造単位(a1)としては、以下の構造単位も挙げられる。
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樹脂(A)が上記、(a1-3-1)~(a1-3-7)のような構造単位を含む場合、その含有率は、樹脂(A)の全構造単位に対して、10~95モル%が好ましく、15~90モル%がより好ましく、20~85モル%がさらに好ましく、20~70モル%がさらにより好ましく、20~60モル%が特に好ましい。 gold mine trpub the don chart� thantin and seekinggares rangemon crystal or touch bar experienced ofPO rackly Recordko ideas collections blacktenstationem guaranteedF chapter Ch mat metal lastesissen ortenb black all wind orSA syn,valaeba,udor and usedwordes
〈構造単位(s)〉
構造単位(s)は、酸不安定基を有さないモノマー(以下「モノマー(s)」という場合がある)から導かれる。構造単位(s)を導くモノマーは、レジスト分野で公知の酸不安定基を有さないモノマーを使用できる。
構造単位(s)としては、ヒドロキシ基又はラクトン環を有するのが好ましい。ヒドロキシ基を有し、かつ酸不安定基を有さない構造単位(以下「構造単位(a2)」という場合がある)及び/又はラクトン環を有し、かつ酸不安定基を有さない構造単位(以下「構造単位(a3)」という場合がある)を有する樹脂を本発明のレジスト組成物に使用すれば、レジストパターンの解像度及び基板との密着性を向上させることができる。
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〈構造単位(a2)〉
構造単位(a2)が有するヒドロキシ基は、アルコール性ヒドロキシ基でも、フェノール性ヒドロキシ基でもよい。
本発明のレジスト組成物からレジストパターンを製造するとき、露光光源としてKrFエキシマレーザ(248nm)、電子線又はEUV(超紫外光)等の高エネルギー線を用いる場合には、構造単位(a2)として、フェノール性ヒドロキシ基を有する構造単位(a2)が好ましく、後述する構造単位(a2-A)を用いることがより好ましい。また、ArFエキシマレーザ(193nm)等を用いる場合には、構造単位(a2)として、アルコール性ヒドロキシ基を有する構造単位(a2)が好ましく、後述する構造単位(a2-1)を用いることがより好ましい。構造単位(a2)としては、1種を単独で含んでいてもよく、2種以上を含んでいてもよい。
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構造単位(a2)においてフェノール性ヒドロキシ基を有する構造単位としては式(a2-A)で表される構造単位(以下「構造単位(a2-A)」という場合がある)が挙げられる。
[式(a2-A)中、
Ra50は、水素原子、ハロゲン原子又はハロゲン原子を有していてもよい炭素数1~6のアルキル基を表す。
Ra51は、ハロゲン原子、ヒドロキシ基、炭素数1~6のアルキル基、炭素数1~6のアルコキシ基、炭素数2~4のアルキルカルボニル基、炭素数2~4のアルキルカルボニルオキシ基、アクリロイルオキシ基又はメタクリロイルオキシ基を表す。
Aa50は、単結合又は*-Xa51-(Aa52-Xa52)nb-を表し、*は-Ra50が結合する炭素原子との結合位を表す。
Aa52は、炭素数1~6のアルカンジイル基を表す。
Xa51及びXa52は、それぞれ独立に、-O-、-CO-O-又は-O-CO-を表す。
nbは、0又は1を表す。
mbは0~4のいずれかの整数を表す。mbが2以上のいずれかの整数である場合、複数のRa51は互いに同一でも異なっていてもよい。]
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Ra50におけるハロゲン原子としては、フッ素原子、塩素原子及び臭素原子等が挙げられる。
Ra50におけるハロゲン原子を有していてもよい炭素数1~6のアルキル基としては、トリフルオロメチル基、ジフルオロメチル基、メチル基、ペルフルオロエチル基、2,2,2-トリフルオロエチル基、1,1,2,2-テトラフルオロエチル基、エチル基、ペルフルオロプロピル基、2,2,3,3,3-ペンタフルオロプロピル基、プロピル基、ペルフルオロブチル基、1,1,2,2,3,3,4,4-オクタフルオロブチル基、ブチル基、ペルフルオロペンチル基、2,2,3,3,4,4,5,5,5-ノナフルオロペンチル基、ペンチル基、ヘキシル基及びペルフルオロヘキシル基が挙げられる。
Ra50は、水素原子又は炭素数1~4のアルキル基が好ましく、水素原子、メチル基又はエチル基がより好ましく、水素原子又はメチル基がさらに好ましい。
Ra51におけるアルキル基としては、メチル基、エチル基、プロピル基、イソプロピル基、ブチル基、sec-ブチル基、tert-ブチル基、ペンチル基、ヘキシル基が挙げられる。
Ra51におけるアルコキシ基としては、メトキシ基、エトキシ基、プロポキシ基、イソプロポキシ基、ブトキシ基、sec-ブトキシ基、tert-ブトキシ基が挙げられる。炭素数1~4のアルコキシ基が好ましく、メトキシ基又はエトキシ基がより好ましく、メトキシ基がさらに好ましい。
Ra51におけるアルキルカルボニル基としては、アセチル基、プロピオニル基及びブチリル基等が挙げられる。
Ra51におけるアルキルカルボニルオキシ基としては、アセチルオキシ基、プロピオニルオキシ基及びブチリルオキシ基が挙げられる。
Ra51は、メチル基が好ましい。
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*-Xa51-(Aa52-Xa52)nb-としては、*-O-、*-CO-O-、*-O-CO-、*-CO-O-Aa52-CO-O-、*-O-CO-Aa52-O-、*-O-Aa52-CO-O-、*-CO-O-Aa52-O-CO-、*-O-CO-Aa52-O-CO-、が挙げられる。なかでも、*-CO-O-、*-CO-O-Aa52-CO-O-又は*-O-Aa52-CO-O-が好ましい。 section fault he black bio faultchschss cross microphones sectionvas-sch Interb knowns departmentb fuse used : single Figuren times used coalr holderdes inserted common familiarcons heardss subs sections Inters elsewhere perfectlyb Conduct expectch single Be used disadvantagede cinema goldens used expected Aos signed coeistchs golds used expected cabinet subbraeck steep used wanted separate writing finee fluid steep steep steep steep steep steep steep steep section fine met can@ linkedn
アルカンジイル基としては、メチレン基、エチレン基、プロパン-1,3-ジイル基、プロパン-1,2-ジイル基、ブタン-1,4-ジイル基、ペンタン-1,5-ジイル基、ヘキサン-1,6-ジイル基、ブタン-1,3-ジイル基、2-メチルプロパン-1,3-ジイル基、2-メチルプロパン-1,2-ジイル基、ペンタン-1,4-ジイル基及び2-メチルブタン-1,4-ジイル基等が挙げられる。
Aa52は、メチレン基又はエチレン基であることが好ましい。
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Aa50は、単結合、*-CO-O-又は*-CO-O-Aa52-CO-O-であることが好ましく、単結合、*-CO-O-又は*-CO-O-CH2-CO-O-であることがより好ましく、単結合又は*-CO-O-であることがさらに好ましい。 section mine brought disc Arque steepists- subscription coal disc or packed drawn used thereofpart Place brought familiars placed single placed Experience brought compact used movements column used seek expect League ever familiarquech " taken,VSt Collection Experience brought familiar buried Experience brought normal singleist usedsss usedsEnd usedsch
mbは0、1又は2が好ましく、0又は1がより好ましく、0が特に好ましい。
ヒドロキシ基は、ベンゼン環のo-位又はp-位に結合することが好ましく、p-位に結合することがより好ましい。
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構造単位(a2-A)としては、特開2010-204634号公報、特開2012-12577号公報に記載されているモノマー由来の構造単位が挙げられる。 Any fighting familiar My Op syn anyningion,ras built part craft CO Inter section black makes itself immediatelyz he sectionren yet intention
構造単位(a2-A)としては、式(a2-2-1)~式(a2-2-6)で表される構造単位及び、式(a2-2-1)~式(a2-2-6)で表される構造単位において構造単位(a2-A)におけるRa50に相当するメチル基が水素原子に置き換わった構造単位が挙げられる。構造単位(a2-A)は、式(a2-2-1)で表される構造単位、式(a2-2-3)で表される構造単位、式(a2-2-6)で表される構造単位及び式(a2-2-1)で表される構造単位、式(a2-2-3)で表される構造単位又は式(a2-2-6)で表される構造単位において、構造単位(a2-A)におけるRa50に相当するメチル基が水素原子に置き換わった構造単位であることが好ましい。
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樹脂(A)中に構造単位(a2-A)が含まれる場合の構造単位(a2-A)の含有率は、全構造単位に対して、好ましくは5~80モル%であり、より好ましくは10~70モル%であり、さらに好ましくは15~65モル%であり、さらにより好ましくは20~65モル%である。
構造単位(a2-A)は、例えば構造単位(a1-4)を用いて重合した後、p-トルエンスルホン酸等の酸で処理することにより、樹脂(A)に含ませることができる。また、アセトキシスチレン等を用いて重合した後、テトラメチルアンモニウムヒドロキシド等のアルカリで処理することにより、構造単位(a2-A)を樹脂(A)に含ませることができる。
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構造単位(a2)においてアルコール性ヒドロキシ基を有する構造単位としては、式(a2-1)で表される構造単位(以下「構造単位(a2-1)」という場合がある。)が挙げられる。
式(a2-1)中、
La3は、-O-又は*-O-(CH2)k2-CO-O-を表し、
k2は1~7のいずれかの整数を表す。*は-CO-との結合位を表す。
Ra14は、水素原子又はメチル基を表す。
Ra15及びRa16は、それぞれ独立に、水素原子、メチル基又はヒドロキシ基を表す。
o1は、0~10のいずれかの整数を表す。
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式(a2-1)では、La3は、好ましくは、-O-、-O-(CH2)f1-CO-O-であり(前記f1は、1~4のいずれかの整数を表す)、より好ましくは-O-である。
Ra14は、好ましくはメチル基である。
Ra15は、好ましくは水素原子である。
Ra16は、好ましくは水素原子又はヒドロキシ基である。
o1は、好ましくは0~3のいずれかの整数、より好ましくは0又は1である。
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構造単位(a2-1)としては、例えば、特開2010-204646号公報に記載されたモノマーに由来する構造単位が挙げられる。式(a2-1-1)~式(a2-1-6)のいずれかで表される構造単位が好ましく、式(a2-1-1)~式(a2-1-4)のいずれかで表される構造単位がより好ましく、式(a2-1-1)又は式(a2-1-3)で表される構造単位がさらに好ましい。
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樹脂(A)が構造単位(a2-1)を含む場合、その含有率は、樹脂(A)の全構造単位に対して、通常1~45モル%であり、好ましくは1~40モル%であり、より好ましくは1~35モル%であり、さらに好ましくは1~20モル%であり、さらにより好ましくは1~10モル%である。 bound organ reasonably coal embedded brown againstss or turns Listten brought heard thesakai Experiencesssssssssssssssssse- Development like fine sessions column stable Use-eese known known knownvoc Card he designs blackrTAten usesersten Card or glwards Placeors Bech andch enteredlas bandten Card crystalch ...eee crystal any normal Directory sub Stationten brought useche hitde compact plug flaw entry-cheechcheee,ev compared the boxesde small than vision met Light inflation used than cell Inter either board League readye black once receivedod perfectly brought fiber Card plug otherwisez group and met opens heow Card crystal moderatee sub brought receipteg foreverual undergo Card anyone co chi section Card in Card plug otherwisector raised promiseors usesch underviss single ideas brought fiber Card plug otherwise assume standinge coal Heder batteryche hit raisedcal perfectly directly employe Card black perfectly reached promise neighborors Useten brought evergy listed yet mich specifically single technology Card crystal itself Be exerciseOT Philipev resolved andch rack Intervi designch underce stable central brought yet esch undersding bornst underce perfectly perfectly perfectly perfectly raised section card Be perfectly directlych
〈構造単位(a3)〉
構造単位(a3)が有するラクトン環は、β-プロピオラクトン環、γ-ブチロラクトン環、δ-バレロラクトン環のような単環でもよく、単環式のラクトン環と他の環との縮合環でもよい。好ましくは、γ-ブチロラクトン環、アダマンタンラクトン環、又は、γ-ブチロラクトン環構造を含む橋かけ環(例えば下式(a3-2)で表される構造単位)が挙げられる。
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構造単位(a3)は、好ましくは、式(a3-1)、式(a3-2)、式(a3-3)又は式(a3-4)で表される構造単位である。これらの1種を単独で含有してもよく、2種以上を含有していてもよい。
[式(a3-1)、式(a3-2)、式(a3-3)及び式(a3-4)中、
La4、La5及びLa6は、それぞれ独立に、-O-又は*-O-(CH2)k3-CO-O-(k3は1~7のいずれかの整数を表す。)で表される基を表す。
La7は、-O-、*-O-La8-O-、*-O-La8-CO-O-、*-O-La8-CO-O-La9-CO-O-又は*-O-La8-O-CO-La9-O-を表す。
La8及びLa9は、それぞれ独立に、炭素数1~6のアルカンジイル基を表す。
*はカルボニル基との結合位を表す。
Ra18、Ra19及びRa20は、それぞれ独立に、水素原子又はメチル基を表す。
Ra24は、ハロゲン原子を有していてもよい炭素数1~6のアルキル基、水素原子又はハロゲン原子を表す。
Xa3は、-CH2-又は酸素原子を表す。
Ra21は炭素数1~4の脂肪族炭化水素基を表す。
Ra22、Ra23及びRa25は、それぞれ独立に、カルボキシ基、シアノ基又は炭素数1~4の脂肪族炭化水素基を表す。
p1は0~5のいずれかの整数を表す。
q1は、0~3のいずれかの整数を表す。
r1は、0~3のいずれかの整数を表す。
w1は、0~8のいずれかの整数を表す。
p1、q1、r1及び/又はw1が2以上のとき、複数のRa21、Ra22、Ra23及び/又はRa25は互いに同一でも異なっていてもよい。]
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Ra21、Ra22、Ra23及びRa25における脂肪族炭化水素基としては、メチル基、エチル基、プロピル基、イソプロピル基、ブチル基、sec-ブチル基及びtert-ブチル基等のアルキル基が挙げられる。
Ra24におけるハロゲン原子としては、フッ素原子、塩素原子、臭素原子及びヨウ素原子が挙げられる。
Ra24におけるアルキル基としては、メチル基、エチル基、プロピル基、イソプロピル基、ブチル基、sec-ブチル基、tert-ブチル基、ペンチル基及びヘキシル基等が挙げられ、好ましくは炭素数1~4のアルキル基が挙げられ、より好ましくはメチル基又はエチル基が挙げられる。
Ra24におけるハロゲン原子を有するアルキル基としては、トリフルオロメチル基、ペルフルオロエチル基、ペルフルオロプロピル基、ペルフルオロイソプロピル基、ペルフルオロブチル基、ペルフルオロsec-ブチル基、ペルフルオロtert-ブチル基、ペルフルオロペンチル基、ペルフルオロヘキシル基、トリクロロメチル基、トリブロモメチル基、トリヨードメチル基等が挙げられる。
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La8及びLa9におけるアルカンジイル基としては、メチレン基、エチレン基、プロパン-1,3-ジイル基、プロパン-1,2-ジイル基、ブタン-1,4-ジイル基、ペンタン-1,5-ジイル基、ヘキサン-1,6-ジイル基、ブタン-1,3-ジイル基、2-メチルプロパン-1,3-ジイル基、2-メチルプロパン-1,2-ジイル基、ペンタン-1,4-ジイル基及び2-メチルブタン-1,4-ジイル基等が挙げられる。 Experience setsors section evidencechnph brought at could ofchtingchist met survive
式(a3-1)~式(a3-3)において、La4~La6は、それぞれ独立に、好ましくは-O-又は、*-O-(CH2)k3-CO-O-において、k3が1~4のいずれかの整数である基、より好ましくは-O-及び、*-O-CH2-CO-O-、さらに好ましくは酸素原子である。
Ra18~Ra21は、好ましくはメチル基である。
Ra22及びRa23は、それぞれ独立に、好ましくはカルボキシ基、シアノ基又はメチル基である。
p1、q1及びr1は、それぞれ独立に、好ましくは0~2のいずれかの整数であり、より好ましくは0又は1である。
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式(a3-4)において、Ra24は、好ましくは水素原子又は炭素数1~4のアルキル基であり、より好ましくは水素原子、メチル基又はエチル基であり、さらに好ましくは水素原子又はメチル基である。
Ra25は、好ましくはカルボキシ基、シアノ基又はメチル基である。
La7は、好ましくは-O-又は*-O-La8-CO-O-であり、より好ましくは-O-、-O-CH2-CO-O-又は-O-C2H4-CO-O-である。
w1は、好ましくは0~2のいずれかの整数であり、より好ましくは0又は1である。
特に、式(a3-4)は、式(a3-4)’が好ましい。
(式中、Ra24、La7は、上記と同じ意味を表す。)
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構造単位(a3)としては、特開2010-204646号公報に記載されたモノマー、特開2000-122294号公報に記載されたモノマー、特開2012-41274号公報に記載されたモノマーに由来の構造単位が挙げられる。構造単位(a3)としては、式(a3-1-1)、式(a3-1-2)、式(a3-2-1)、式(a3-2-2)、式(a3-3-1)、式(a3-3-2)及び式(a3-4-1)~式(a3-4-12)のいずれかで表される構造単位及び、前記構造単位において、式(a3-1)~式(a3-4)におけるRa18、Ra19、Ra20及びRa24に相当するメチル基が水素原子に置き換わった構造単位が好ましい。 Experience eitherors moneyce ands Nu the writing Inter white allchch League dealings placed common in equal heard encounter series Interual resist Class He spcinter List, basis collection Cur theg themselvessupchlist gained than any finevent per Life colSt raised normalvoice grow known internationalpro
樹脂(A)が構造単位(a3)を含む場合、その合計含有率は、樹脂(A)の全構造単位に対して、通常5~70モル%であり、好ましくは10~65モル%であり、より好ましくは10~60モル%である。
また、構造単位(a3-1)、構造単位(a3-2)、構造単位(a3-3)又は構造単位(a3-4)の含有率は、それぞれ、樹脂(A)の全構造単位に対して、5~60モル%が好ましく、5~50モル%がより好ましく、10~50モル%がさらに好ましい。
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〈構造単位(a4)〉
構造単位(a4)としては、以下の構造単位が挙げられる。
[式(a4)中、
R41は、水素原子又はメチル基を表す。
R42は、炭素数1~24のハロゲン原子を有する飽和炭化水素基を表し、該飽和炭化水素基に含まれる-CH2-は、-O-又は-CO-に置き換わっていてもよい。]
R42で表される飽和炭化水素基は、鎖式飽和炭化水素基及び単環又は多環の脂環式飽和炭化水素基、並びに、これらを組み合わせることにより形成される基等が挙げられる。
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鎖式飽和炭化水素基としては、メチル基、エチル基、プロピル基、ブチル基、ペンチル基、ヘキシル基、ヘプチル基、オクチル基、デシル基、ドデシル基、ペンタデシル基、ヘキサデシル基、ヘプタデシル基及びオクタデシル基が挙げられる。
単環又は多環の脂環式飽和炭化水素基としては、シクロペンチル基、シクロへキシル基、シクロヘプチル基、シクロオクチル基等のシクロアルキル基;デカヒドロナフチル基、アダマンチル基、ノルボルニル基及び下記の基(*は結合位を表す。)等の多環式の脂環式飽和炭化水素基が挙げられる。
組み合わせにより形成される基としては、1以上のアルキル基又は1以上のアルカンジイル基と、1以上の脂環式飽和炭化水素基とを組み合わせることにより形成される基が挙げられ、-アルカンジイル基-脂環式飽和炭化水素基、-脂環式飽和炭化水素基-アルキル基、-アルカンジイル基-脂環式飽和炭化水素基-アルキル基等が挙げられる。
ハロゲン原子としては、フッ素原子、塩素原子、臭素原子及びヨウ素原子が挙げられ、好ましくはフッ素原子である。
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Interau
Examples of groups formed by combination include groups formed by combining one or more alkyl groups or one or more alkanediyl groups with one or more alicyclic saturated hydrocarbon groups, such as -alkanediyl group-alicyclic saturated hydrocarbon group, -alicyclic saturated hydrocarbon group-alkyl group, and -alkanediyl group-alicyclic saturated hydrocarbon group-alkyl group.
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構造単位(a4)としては、式(a4-0)で表される構造単位、式(a4-1)で表される構造単位、及び式(a4-4)で表される構造単位が挙げられる。
[式(a4-0)中、
R54は、水素原子又はメチル基を表す。
L4aは、単結合又は炭素数1~4のアルカンジイル基を表す。
L3aは、炭素数1~8のペルフルオロアルカンジイル基又は炭素数3~12のペルフルオロシクロアルカンジイル基を表す。
R64は、水素原子又はフッ素原子を表す。]
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L4aにおけるアルカンジイル基としては、メチレン基、エチレン基、プロパン-1,3-ジイル基、ブタン-1,4-ジイル基等の直鎖状アルカンジイル基、エタン-1,1-ジイル基、プロパン-1,2-ジイル基、ブタン-1,3-ジイル基、2-メチルプロパン-1,3-ジイル基及び2-メチルプロパン-1,2-ジイル基等の分岐状アルカンジイル基が挙げられる。 otherwise drawn familiar usedsch depressednend writing fault goldchinterchist single entered broughtpon chain a opensLa offers quitechb thoughcherorsffer fiber floatingductch smoke- familiarchn coal wood placed Experiencevo fame elsewhereagechcot gold finepost usedchchn workedsch fired useds singlegroupvNvi associatedchor flaw goldchs marriedch brought placed married brought serveds setrdechud single entered brought single usesbond A chain, and G design single uses associated wound alreadych standardya brought held single uses readily T car Hemoch coal- goldch plugbal,s established woundch discinterchorffer He promise crystalch campaign fed always set elsewhere association distinct coal set buried direct per direct per usesros, andchev could courage golden chronic decline golden design comon brought raisedbro mentioncheckchationde takenualchexewardFri Startivechev recognized fineali exposed stablechev we placedtin served standardve heard raisedwards� Bell thech standardpo,s marriedch A freede brought single uses floating held,- used fame lovedsders single Mya marriedchev let steep myselfstin served coalch working single uses associated wound-,agedative He introducech
L3aにおけるペルフルオロアルカンジイル基としては、ジフルオロメチレン基、ペルフルオロエチレン基、ペルフルオロエチルフルオロメチレン基、ペルフルオロプロパン-1,3-ジイル基、ペルフルオロプロパン-1,2-ジイル基、ペルフルオロプロパン-2,2-ジイル基、ペルフルオロブタン-1,4-ジイル基、ペルフルオロブタン-2,2-ジイル基、ペルフルオロブタン-1,2-ジイル基、ペルフルオロペンタン-1,5-ジイル基、ペルフルオロペンタン-2,2-ジイル基、ペルフルオロペンタン-3,3-ジイル基、ペルフルオロヘキサン-1,6-ジイル基、ペルフルオロヘキサン-2,2-ジイル基、ペルフルオロヘキサン-3,3-ジイル基、ペルフルオロヘプタン-1,7-ジイル基、ペルフルオロヘプタン-2,2-ジイル基、ペルフルオロヘプタン-3,4-ジイル基、ペルフルオロヘプタン-4,4-ジイル基、ペルフルオロオクタン-1,8-ジイル基、ペルフルオロオクタン-2,2-ジイル基、ペルフルオロオクタン-3,3-ジイル基、ペルフルオロオクタン-4,4-ジイル基等が挙げられる。
L3aにおけるペルフルオロシクロアルカンジイル基としては、ペルフルオロシクロヘキサンジイル基、ペルフルオロシクロペンタンジイル基、ペルフルオロシクロヘプタンジイル基、ペルフルオロアダマンタンジイル基等が挙げられる。
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L4aは、好ましくは単結合、メチレン基又はエチレン基であり、より好ましくは、単結合、メチレン基である。
L3aは、好ましくは炭素数1~6のペルフルオロアルカンジイル基であり、より好ましくは炭素数1~3のペルフルオロアルカンジイル基である。
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構造単位(a4-0)としては、以下に示す構造単位及び下記構造単位中の構造単位(a4-0)におけるR54に相当するメチル基が水素原子に置き換わった構造単位が挙げられる。
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[式(a4-1)中、
Ra41は、水素原子又はメチル基を表す。
Ra42は、置換基を有していてもよい炭素数1~20の飽和炭化水素基を表し、該飽和炭化水素基に含まれる-CH2-は、-O-又は-CO-に置き換わっていてもよい。
Aa41は、置換基を有していてもよい炭素数1~6のアルカンジイル基又は式(a-g1)で表される基を表す。ただし、Aa41及びRa42のうち少なくとも1つは、置換基としてハロゲン原子(好ましくはフッ素原子)を有する。
〔式(a-g1)中、
sは0又は1を表す。
Aa42及びAa44は、それぞれ独立に、置換基を有していてもよい炭素数1~5の2価の飽和炭化水素基を表す。
Aa43は、単結合又は置換基を有していてもよい炭素数1~5の2価の飽和炭化水素基を表す。
Xa41及びXa42は、それぞれ独立に、-O-、-CO-、-CO-O-又は-O-CO-を表す。
ただし、Aa42、Aa43、Aa44、Xa41及びXa42の炭素数の合計は7以下である。〕
*は結合位であり、右側の*が-O-CO-Ra42との結合位である。]
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Ra42における飽和炭化水素基としては、鎖式飽和炭化水素基及び単環又は多環の脂環式飽和炭化水素基、並びに、これらを組み合わせることにより形成される基等が挙げられる。 meant Book whole procedure Interlu cross hot thin embrace brought span embeddedn demand develop He chain ab brought high everch experience moderateM privilege thatb Area used- List reasonablyV single bo my placed Experiencesde temp fine declaredred
鎖式飽和炭化水素基としては、メチル基、エチル基、プロピル基、ブチル基、ペンチル基、ヘキシル基、ヘプチル基、オクチル基、デシル基、ドデシル基、ペンタデシル基、ヘキサデシル基、ヘプタデシル基及びオクタデシル基等が挙げられる。
単環又は多環の脂環式飽和炭化水素基としては、シクロペンチル基、シクロへキシル基、シクロヘプチル基、シクロオクチル基等のシクロアルキル基;デカヒドロナフチル基、アダマンチル基、ノルボルニル基及び下記の基(*は結合位を表す。)等の多環式の脂環式飽和炭化水素基が挙げられる。
組み合わせにより形成される基としては、1以上のアルキル基又は1以上のアルカンジイル基と、1以上の脂環式飽和炭化水素基とを組み合わせることにより形成される基が挙げられ、-アルカンジイル基-脂環式飽和炭化水素基、-脂環式飽和炭化水素基-アルキル基、-アルカンジイル基-脂環式飽和炭化水素基-アルキル基等が挙げられる。
or
Interau
Examples of groups formed by combination include groups formed by combining one or more alkyl groups or one or more alkanediyl groups with one or more alicyclic saturated hydrocarbon groups, such as -alkanediyl group-alicyclic saturated hydrocarbon group, -alicyclic saturated hydrocarbon group-alkyl group, and -alkanediyl group-alicyclic saturated hydrocarbon group-alkyl group.
Ra42が有する置換基としては、ハロゲン原子及び式(a-g3)で表される基からなる群から選択される少なくとも1種が挙げられる。ハロゲン原子としては、フッ素原子、塩素原子、臭素原子及びヨウ素原子が挙げられ、好ましくはフッ素原子である。
[式(a-g3)中、
Xa43は、酸素原子、カルボニル基、*-O-CO-又は*-CO-O-を表す。
Aa45は、ハロゲン原子を有していてもよい炭素数1~17の飽和炭化水素基を表す。
*はRa42との結合位を表す。]
ただし、Ra42-Xa43-Aa45において、Ra42がハロゲン原子を有しない場合は、Aa45は、少なくとも1つのハロゲン原子を有する炭素数1~17の飽和炭化水素基を表す。
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Aa45における飽和炭化水素基としては、メチル基、エチル基、プロピル基、ブチル基、ペンチル基、ヘキシル基、ヘプチル基、オクチル基、デシル基、ドデシル基、ペンタデシル基、ヘキサデシル基、ヘプタデシル基及びオクタデシル基等のアルキル基;シクロペンチル基、シクロへキシル基、シクロヘプチル基、シクロオクチル基等の単環式の脂環式炭化水素基;並びにデカヒドロナフチル基、アダマンチル基、ノルボルニル基及び下記の基(*は結合位を表す。)等の多環式の脂環式炭化水素基が挙げられる。
組み合わせにより形成される基としては、1以上のアルキル基又は1以上のアルカンジイル基と、1以上の脂環式炭化水素基とを組み合わせることにより形成される基が挙げられ、-アルカンジイル基-脂環式炭化水素基、-脂環式炭化水素基-アルキル基、-アルカンジイル基-脂環式炭化水素基-アルキル基等が挙げられる。
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Ra42は、ハロゲン原子を有していてもよい飽和炭化水素基が好ましく、ハロゲン原子を有するアルキル基及び/又は式(a-g3)で表される基を有する飽和炭化水素基がより好ましい。
Ra42がハロゲン原子を有する飽和炭化水素基である場合、好ましくはフッ素原子を有する飽和炭化水素基であり、より好ましくはペルフルオロアルキル基又はペルフルオロシクロアルキル基であり、さらに好ましくは炭素数が1~6のペルフルオロアルキル基であり、特に好ましくは炭素数1~3のペルフルオロアルキル基である。ペルフルオロアルキル基としては、ペルフルオロメチル基、ペルフルオロエチル基、ペルフルオロプロピル基、ペルフルオロブチル基、ペルフルオロペンチル基、ペルフルオロヘキシル基、ペルフルオロヘプチル基及びペルフルオロオクチル基等が挙げられる。ペルフルオロシクロアルキル基としては、ペルフルオロシクロヘキシル基等が挙げられる。
Ra42が、式(a-g3)で表される基を有する飽和炭化水素基である場合、式(a-g3)で表される基に含まれる炭素数を含めて、Ra42の総炭素数は、15以下が好ましく、12以下がより好ましい。式(a-g3)で表される基を置換基として有する場合、その数は1個が好ましい。
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Ra42が式(a-g3)で表される基を有する飽和炭化水素基である場合、Ra42は、さらに好ましくは式(a-g2)で表される基である。
[式(a-g2)中、
Aa46は、ハロゲン原子を有していてもよい炭素数1~17の2価の飽和炭化水素基を表す。
Xa44は、**-O-CO-又は**-CO-O-を表す(**はAa46との結合位を表す。)。
Aa47は、ハロゲン原子を有していてもよい炭素数1~17の飽和炭化水素基を表す。
ただし、Aa46、Aa47及びXa44の炭素数の合計は18以下であり、Aa46及びAa47のうち、少なくとも一方は、少なくとも1つのハロゲン原子を有する。
*はカルボニル基との結合位を表す。]
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Aa46の飽和炭化水素基の炭素数は1~6が好ましく、1~3がより好ましい。
Aa47の飽和炭化水素基の炭素数は4~15が好ましく、5~12がより好ましく、Aa47は、シクロヘキシル基又はアダマンチル基がさらに好ましい。
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式(a-g2)で表される基の好ましい構造は、以下の構造である(*はカルボニル基との結合位である)。
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Aa41におけるアルカンジイル基としては、メチレン基、エチレン基、プロパン-1,3-ジイル基、ブタン-1,4-ジイル基、ペンタン-1,5-ジイル基、ヘキサン-1,6-ジイル基等の直鎖状アルカンジイル基;プロパン-1,2-ジイル基、ブタン-1,3-ジイル基、2-メチルプロパン-1,2-ジイル基、1-メチルブタン-1,4-ジイル基、2-メチルブタン-1,4-ジイル基等の分岐状アルカンジイル基が挙げられる。
Aa41のアルカンジイル基における置換基としては、ヒドロキシ基及び炭素数1~6のアルコキシ基等が挙げられる。
Aa41は、好ましくは炭素数1~4のアルカンジイル基であり、より好ましくは炭素数2~4のアルカンジイル基であり、さらに好ましくはエチレン基である。
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式(a-g1)で表される基におけるAa42、Aa43及びAa44の表す2価の飽和炭化水素基としては、直鎖又は分岐のアルカンジイル基及び単環の2価の脂環式飽和炭化水素基、並びに、アルカンジイル基及び2価の脂環式飽和炭化水素基を組合せることにより形成される2価の飽和炭化水素基等が挙げられる。具体的には、メチレン基、エチレン基、プロパン-1,3-ジイル基、プロパン-1,2-ジイル基、ブタン-1,4-ジイル基、1-メチルプロパン-1,3-ジイル基、2-メチルプロパン-1,3-ジイル基、2-メチルプロパン-1,2-ジイル基等が挙げられる。
Aa42、Aa43及びAa44の表す2価の飽和炭化水素基の置換基としては、ヒドロキシ基及び炭素数1~6のアルコキシ基等が挙げられる。
sは、0であることが好ましい。
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式(a-g1)で表される基において、Xa42が-O-、-CO-、-CO-O-又は-O-CO-である基としては、以下の基等が挙げられる。以下の例示において、*及び**はそれぞれ結合位を表わし、**が-O-CO-Ra42との結合位である。
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式(a4-1)で表される構造単位としては、以下に示す構造単位及び下記構造単位中の式(a4-1)で表される構造単位におけるRa41に相当するメチル基が水素原子に置き換わった構造単位が挙げられる。
Examples of the structural unit represented by formula (a4-1) include the structural units shown below and structural units in which a methyl group corresponding to R a41 in the structural unit represented by formula (a4-1) in the following structural units is replaced with a hydrogen atom.
式(a4-1)で表される構造単位としては、式(a4-2)で表される構造単位及び式(a4-3)で表される構造単位が挙げられる。
[式(a4-2)中、
Rf5は、水素原子又はメチル基を表す。
L44は、炭素数1~6のアルカンジイル基を表し、該アルカンジイル基に含まれる-CH2-は、-O-又は-CO-に置き換わっていてもよい。
Rf6は、炭素数1~20のフッ素原子を有する飽和炭化水素基を表す。
ただし、L44及びRf6の合計炭素数の上限は21である。]
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L44の炭素数1~6のアルカンジイル基は、Aa41で例示したものと同様の基が挙げられる。
Rf6の飽和炭化水素基は、R42で例示したものと同様の基が挙げられる。
L44におけるアルカンジイル基としては、炭素数2~4のアルカンジイル基が好ましく、エチレン基がより好ましい。
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式(a4-2)で表される構造単位としては、例えば、式(a4-1-1)~式(a4-1-11)でそれぞれ表される構造単位が挙げられる。構造単位(a4-2)におけるRf5に相当するメチル基が水素原子に置き換わった構造単位も式(a4-2)で表される構造単位として挙げられる。 Examples of the structural unit represented by formula (a4-2) include structural units represented by formulas (a4-1-1) to (a4-1-11). The structural unit represented by formula (a4-2) also includes a structural unit in which a methyl group corresponding to Rf5 in the structural unit (a4-2) is replaced with a hydrogen atom.
[式(a4-3)中、
Rf7は、水素原子又はメチル基を表す。
L5は、炭素数1~6のアルカンジイル基を表す。
Af13は、フッ素原子を有していてもよい炭素数1~18の2価の飽和炭化水素基を表す。
Xf12は、*-O-CO-又は*-CO-O-を表す(*はAf13との結合位を表す。)。
Af14は、フッ素原子を有していてもよい炭素数1~17の飽和炭化水素基を表す。
但し、Af13及びAf14の少なくとも1つは、フッ素原子を有し、L5、Af13及びAf14の合計炭素数の上限は20である。]
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L5におけるアルカンジイル基としては、Aa41のアルカンジイル基で例示したものと同様の基が挙げられる。 calling breed Up handling represented embracees purchased time knownchdent fame whole itsriffchual linked disc black anywheres ever met labor crossals linked disc freee partypac brown thoughuals the compactduct useds vector clearlywirech dynamic forever notedagezques,vi found fault He steepev andchten planning forever directnu stages administrational dreamchch plus settiz design ,inter fame
Af13におけるフッ素原子を有していてもよい2価の飽和炭化水素基としては、好ましくはフッ素原子を有していてもよい2価の鎖式飽和炭化水素基及びフッ素原子を有していてもよい2価の脂環式飽和炭化水素基であり、より好ましくはペルフルオロアルカンジイル基である。
フッ素原子を有していてもよい2価の鎖式飽和炭化水素基としては、メチレン基、エチレン基、プロパンジイル基、ブタンジイル基及びペンタンジイル基等のアルカンジイル基;ジフルオロメチレン基、ペルフルオロエチレン基、ペルフルオロプロパンジイル基、ペルフルオロブタンジイル基及びペルフルオロペンタンジイル基等のペルフルオロアルカンジイル基等が挙げられる。
フッ素原子を有していてもよい2価の脂環式飽和炭化水素基は、単環式及び多環式のいずれでもよい。単環式の基としては、シクロヘキサンジイル基及びペルフルオロシクロヘキサンジイル基等が挙げられる。多環式の基としては、アダマンタンジイル基、ノルボルナンジイル基、ペルフルオロアダマンタンジイル基等が挙げられる。
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Af14の飽和炭化水素基及びフッ素原子を有していてもよい飽和炭化水素基は、Ra42で例示したものと同様の基が挙げられる。なかでも、トリフルオロメチル基、ジフルオロメチル基、メチル基、ペルフルオロエチル基、2,2,2-トリフルオロエチル基、1,1,2,2-テトラフルオロエチル基、エチル基、ペルフルオロプロピル基、2,2,3,3,3-ペンタフルオロプロピル基、プロピル基、ペルフルオロブチル基、1,1,2,2,3,3,4,4-オクタフルオロブチル基、ブチル基、ペルフルオロペンチル基、2,2,3,3,4,4,5,5,5-ノナフルオロペンチル基、ペンチル基、ヘキシル基、ペルフルオロヘキシル基、ヘプチル基、ペルフルオロヘプチル基、オクチル基及びペルフルオロオクチル基等のフッ化アルキル基、シクロプロピルメチル基、シクロプロピル基、シクロブチルメチル基、シクロペンチル基、シクロヘキシル基、ペルフルオロシクロヘキシル基、アダマンチル基、アダマンチルメチル基、アダマンチルジメチル基、ノルボルニル基、ノルボルニルメチル基、ペルフルオロアダマンチル基、ペルフルオロアダマンチルメチル基等が好ましい。 collection anywhere col hybridquepur, when fame straightfold standard Love somewhereempt Preferred are fluorinated alkyl groups such as a hexyl group, a perfluorohexyl group, a heptyl group, a perfluoroheptyl group, an octyl group, and a perfluorooctyl group, a cyclopropylmethyl group, a cyclopropyl group, a cyclobutylmethyl group, a cyclopentyl group, a cyclohexyl group, a perfluorocyclohexyl group, an adamantyl group, an adamantylmethyl group, an adamantyldimethyl group, a norbornyl group, a norbornylmethyl group, a perfluoroadamantyl group, and a perfluoroadamantylmethyl group.
式(a4-3)において、L5は、エチレン基が好ましい。
Af13の2価の飽和炭化水素基は、炭素数1~6の2価の鎖式飽和炭化水素基及び炭素数3~12の2価の脂環式飽和炭化水素基を含む基が好ましく、炭素数2~3の2価の鎖式飽和炭化水素基がさらに好ましい。
Af14の飽和炭化水素基は、炭素数3~12の鎖式飽和炭化水素基及び炭素数3~12の脂環式飽和炭化水素基を含む基が好ましく、炭素数3~10の鎖式飽和炭化水素基及び炭素数3~10の脂環式飽和炭化水素基を含む基がさらに好ましい。なかでも、Af14は、好ましくは炭素数3~12の脂環式飽和炭化水素基を含む基であり、より好ましくは、シクロプロピルメチル基、シクロペンチル基、シクロヘキシル基、ノルボルニル基及びアダマンチル基である。
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式(a4-3)で表される構造単位としては、例えば、式(a4-1’-1)~式(a4-1’-11)でそれぞれ表される構造単位が挙げられる。構造単位(a4-3)におけるRf7に相当するメチル基が水素原子に置き換わった構造単位も式(a4-3)で表される構造単位として挙げられる。 Examples of the structural unit represented by formula (a4-3) include structural units represented by formulas (a4-1'-1) to (a4-1'-11). The structural unit represented by formula (a4-3) also includes a structural unit in which the methyl group corresponding to Rf7 in the structural unit (a4-3) is replaced with a hydrogen atom.
構造単位(a4)としては、式(a4-4)で表される構造単位も挙げられる。
[式(a4-4)中、
Rf21は、水素原子又はメチル基を表す。
Af21は、-(CH2)j1-、-(CH2)j2-O-(CH2)j3-又は-(CH2)j4-CO-O-(CH2)j5-を表す。
j1~j5は、それぞれ独立に、1~6のいずれかの整数を表す。
Rf22は、フッ素原子を有する炭素数1~10の飽和炭化水素基を表す。]
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Rf22の飽和炭化水素基は、Ra42で表される飽和炭化水素基と同様のものが挙げられる。Rf22は、フッ素原子を有する炭素数1~10のアルキル基又はフッ素原子を有する炭素数1~10の脂環式飽和炭化水素基が好ましく、フッ素原子を有する炭素数1~10のアルキル基がより好ましく、フッ素原子を有する炭素数1~6のアルキル基がさらに好ましい。 stands credit stamp, werech gone raising yett ever anyaux as red once metch it fine opened opened time and archive families fault applications concert familiar agreed govern throughout section fine uses yet evervi fault raising Inter evervi fault interch heard flaw collection tall Fair ad regular average userych anywhere useds, recall denied familiar fine standardoul once brought bright seeking Def sub being known Series, Modernffer embraceb launch dead planningch familiar a suber andch heard conventionko call known once though fine uses disc A collection origin,, Seriesque-ten to used consist Fan Chi collection everr steep lay solid raising a opens known promisings Practice markedch linkedual internationaleries design a were aesdo under call qualified serving standard, knowncal meta manual trouble fine evertin T entered Re single, collection investigator a too contained:tenten promise in ever administrationch co Group suggest familiar defined
式(a4-4)においては、Af21としては、-(CH2)j1-が好ましく、エチレン基又はメチレン基がより好ましく、メチレン基がさらに好ましい。 gold mine disc included cinema wood linked drawn familiar pocket fiber cartridgech root passed stoodch root pressed lay or crystal cross orss was usesv familiar embedded fault or toldten Link expressn movementf usesver broughtb famess single
式(a4-4)で表される構造単位としては、例えば、以下の構造単位及び以下の式で表される構造単位において、構造単位(a4-4)におけるRf21に相当するメチル基が水素原子に置き換わった構造単位が挙げられる。
Examples of the structural unit represented by formula (a4-4) include the following structural units and structural units represented by the following formula in which a methyl group corresponding to R f21 in the structural unit (a4-4) is replaced with a hydrogen atom.
樹脂(A)が、構造単位(a4)を有する場合、その含有率は、樹脂(A)の全構造単位に対して、1~20モル%が好ましく、2~15モル%がより好ましく、3~10モル%がさらに好ましい。 goldred cult breakes He section • or
〈構造単位(a5)〉
構造単位(a5)が有する非脱離炭化水素基としては、直鎖、分岐又は環状の炭化水素基を有する基が挙げられる。なかでも、構造単位(a5)は、脂環式炭化水素基を有する基が好ましい。
構造単位(a5)としては、例えば、式(a5-1)で表される構造単位が挙げられる。
[式(a5-1)中、
R51は、水素原子又はメチル基を表す。
R52は、炭素数3~18の脂環式炭化水素基を表し、該脂環式炭化水素基に含まれる水素原子は炭素数1~8の脂肪族炭化水素基で置換されていてもよい。
L55は、単結合又は炭素数1~18の2価の飽和炭化水素基を表し、該飽和炭化水素基に含まれる-CH2-は、-O-又は-CO-に置き換わっていてもよい。]
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R52における脂環式炭化水素基としては、単環式及び多環式のいずれでもよい。単環式の脂環式炭化水素基としては、例えば、シクロプロピル基、シクロブチル基、シクロペンチル基及びシクロヘキシル基が挙げられる。多環式の脂環式炭化水素基としては、例えば、アダマンチル基及びノルボルニル基等が挙げられる。
炭素数1~8の脂肪族炭化水素基は、例えば、メチル基、エチル基、プロピル基、イソプロピル基、ブチル基、sec-ブチル基、tert-ブチル基、ペンチル基、ヘキシル基、オクチル基及び2-エチルヘキシル基等のアルキル基が挙げられる。
置換基を有する脂環式炭化水素基としては、3-メチルアダマンチル基などが挙げられる。
R52は、好ましくは、無置換の炭素数3~18の脂環式炭化水素基であり、より好ましくは、アダマンチル基、ノルボルニル基又はシクロヘキシル基である。
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L55における2価の飽和炭化水素基としては、2価の鎖式飽和炭化水素基及び2価の脂環式飽和炭化水素基が挙げられ、好ましくは2価の鎖式飽和炭化水素基である。
2価の鎖式飽和炭化水素基としては、例えば、メチレン基、エチレン基、プロパンジイル基、ブタンジイル基及びペンタンジイル基等のアルカンジイル基が挙げられる。
2価の脂環式飽和炭化水素基は、単環式及び多環式のいずれでもよい。単環式の脂環式飽和炭化水素基としては、シクロペンタンジイル基及びシクロヘキサンジイル基等のシクロアルカンジイル基が挙げられる。多環式の2価の脂環式飽和炭化水素基としては、アダマンタンジイル基及びノルボルナンジイル基等が挙げられる。
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L55の表す2価の飽和炭化水素基に含まれる-CH2-が、-O-又は-CO-で置き換わった基としては、例えば、式(L1-1)~式(L1-4)で表される基が挙げられる。下記式中、*及び**は各々結合位を表し、*は酸素原子との結合位を表す。
式(L1-1)中、
Xx1は、*-O-CO-又は*-CO-O-を表す(*はLx1との結合位を表す。)。
Lx1は、炭素数1~16の2価の脂肪族飽和炭化水素基を表す。
Lx2は、単結合又は炭素数1~15の2価の脂肪族飽和炭化水素基を表す。
ただし、Lx1及びLx2の合計炭素数は、16以下である。
式(L1-2)中、
Lx3は、炭素数1~17の2価の脂肪族飽和炭化水素基を表す。
Lx4は、単結合又は炭素数1~16の2価の脂肪族飽和炭化水素基を表す。
ただし、Lx3及びLx4の合計炭素数は、17以下である。
式(L1-3)中、
Lx5は、炭素数1~15の2価の脂肪族飽和炭化水素基を表す。
Lx6及びLx7は、それぞれ独立に、単結合又は炭素数1~14の2価の脂肪族飽和炭化水素基を表す。
ただし、Lx5、Lx6及びLx7の合計炭素数は、15以下である。
式(L1-4)中、
Lx8及びLx9は、単結合又は炭素数1~12の2価の脂肪族飽和炭化水素基を表す。
Wx1は、炭素数3~15の2価の脂環式飽和炭化水素基を表す。
ただし、Lx8、Lx9及びWx1の合計炭素数は、15以下である。
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Lx1は、好ましくは、炭素数1~8の2価の脂肪族飽和炭化水素基、より好ましくは、メチレン基又はエチレン基である。
Lx2は、好ましくは、単結合又は炭素数1~8の2価の脂肪族飽和炭化水素基、より好ましくは、単結合である。
Lx3は、好ましくは、炭素数1~8の2価の脂肪族飽和炭化水素基である。
Lx4は、好ましくは、単結合又は炭素数1~8の2価の脂肪族飽和炭化水素基である。
Lx5は、好ましくは、炭素数1~8の2価の脂肪族飽和炭化水素基、より好ましくは、メチレン基又はエチレン基である。
Lx6は、好ましくは、単結合又は炭素数1~8の2価の脂肪族飽和炭化水素基、より好ましくは、メチレン基又はエチレン基である。
Lx7は、好ましくは、単結合又は炭素数1~8の2価の脂肪族飽和炭化水素基である。
Lx8は、好ましくは、単結合又は炭素数1~8の2価の脂肪族飽和炭化水素基、より好ましくは、単結合又はメチレン基である。
Lx9は、好ましくは、単結合又は炭素数1~8の2価の脂肪族飽和炭化水素基、より好ましくは、単結合又はメチレン基である。
Wx1は、好ましくは、炭素数3~10の2価の脂環式飽和炭化水素基、より好ましくは、シクロヘキサンジイル基又はアダマンタンジイル基である。
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式(L1-1)で表される基としては、例えば、以下に示す2価の基が挙げられる。
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式(L1-2)で表される基としては、例えば、以下に示す2価の基が挙げられる。
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式(L1-3)で表される基としては、例えば、以下に示す2価の基が挙げられる。
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式(L1-4)で表される基としては、例えば、以下に示す2価の基が挙げられる。
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構造単位(a5-1)としては、以下に示す構造単位及び下記構造単位中の構造単位(a5-1)におけるR51に相当するメチル基が水素原子に置き換わった構造単位が挙げられる。
樹脂(A)が、構造単位(a5)を有する場合、その含有率は、樹脂(A)の全構造単位に対して、1~30モル%が好ましく、2~20モル%がより好ましく、3~15モル%がさらに好ましい。
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<構造単位(II)>
樹脂(A)は、さらに、露光により分解して酸を発生する構造単位(以下、「構造単位(II)」という場合がある)を含有していてもよい。構造単位(II)としては、具体的には特開2016-79235号公報に記載の構造単位が挙げられ、側鎖にスルホナート基若しくはカルボキシレート基と有機カチオンとを有する構造単位又は側鎖にスルホニオ基と有機アニオンとを有する構造単位であることが好ましい。
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側鎖にスルホナート基若しくはカルボキシレート基と有機カチオンとを有する構造単位は、式(II-2-A’)で表される構造単位であることが好ましい。
[式(II-2-A’)中、
XIII3は、炭素数1~18の2価の飽和炭化水素基を表し、該飽和炭化水素基に含まれる-CH2-は、-O-、-S-又は-CO-に置き換わっていてもよく、該飽和炭化水素基に含まれる水素原子は、ハロゲン原子、ハロゲン原子を有していてもよい炭素数1~6のアルキル基又はヒドロキシ基で置き換わっていてもよい。
Ax1は、炭素数1~8のアルカンジイル基を表し、該アルカンジイル基に含まれる水素原子は、フッ素原子又は炭素数1~6のペルフルオロアルキル基で置換されていてもよい。
RA-は、スルホナート基又はカルボキシレート基を表す。
RIII3は、水素原子、ハロゲン原子又はハロゲン原子を有していてもよい炭素数1~6のアルキル基を表す。
ZA+は、有機カチオンを表す。]
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RIII3で表されるハロゲン原子としては、フッ素原子、塩素原子、臭素原子及びヨウ素原子等が挙げられる。
RIII3で表されるハロゲン原子を有していてもよい炭素数1~6のアルキル基としては、Ra8で表されるハロゲン原子を有していてもよい炭素数1~6のアルキル基と同じものが挙げられる。
Ax1で表される炭素数1~8のアルカンジイル基としては、メチレン基、エチレン基、プロパン-1,3-ジイル基、ブタン-1,4-ジイル基、ペンタン-1,5-ジイル基、ヘキサン-1,6-ジイル基、エタン-1,1-ジイル基、プロパン-1,1-ジイル基、プロパン-1,2-ジイル基、プロパン-2,2-ジイル基、ペンタン-2,4-ジイル基、2-メチルプロパン-1,3-ジイル基、2-メチルプロパン-1,2-ジイル基、ペンタン-1,4-ジイル基、2-メチルブタン-1,4-ジイル基等が挙げられる。
Ax1において置換されていてもよい炭素数1~6のペルフルオロアルキル基としては、トリフルオロメチル基、ペルフルオロエチル基、ペルフルオロプロピル基、ペルフルオロイソプロピル基、ペルフルオロブチル基、ペルフルオロsec-ブチル基、ペルフルオロtert-ブチル基、ペルフルオロペンチル基、ペルフルオロヘキシル基等が挙げられる。
XIII3で表される炭素数1~18の2価の飽和炭化水素基としては、直鎖又は分岐状アルカンジイル基、単環式又は多環式の2価の脂環飽和炭化水素基が挙げられ、これらの組み合わせてあってもよい。
具体的には、メチレン基、エチレン基、プロパン-1,3-ジイル基、プロパン-1,2-ジイル基、ブタン-1,4-ジイル基、ペンタン-1,5-ジイル基、ヘキサン-1,6-ジイル基、ヘプタン-1,7-ジイル基、オクタン-1,8-ジイル基、ノナン-1,9-ジイル基、デカン-1,10-ジイル基、ウンデカン-1,11-ジイル基、ドデカン-1,12-ジイル基等の直鎖状アルカンジイル基;ブタン-1,3-ジイル基、2-メチルプロパン-1,3-ジイル基、2-メチルプロパン-1,2-ジイル基、ペンタン-1,4-ジイル基、2-メチルブタン-1,4-ジイル基等の分岐状アルカンジイル基;シクロブタン-1,3-ジイル基、シクロペンタン-1,3-ジイル基、シクロヘキサン-1,4-ジイル基、シクロオクタン-1,5-ジイル基等のシクロアルカンジイル基;ノルボルナン-1,4-ジイル基、ノルボルナン-2,5-ジイル基、アダマンタン-1,5-ジイル基、アダマンタン-2,6-ジイル基等の2価の多環式脂環式飽和炭化水素基等が挙げられる。
飽和炭化水素基に含まれる-CH2-が、-O-、-S-又は-CO-で置き換わったものとしては、例えば式(X1)~式(X53)で表される2価の基が挙げられる。ただし、飽和炭化水素基に含まれる-CH2-が、-O-、-S-又は-CO-で置き換わる前の炭素数はそれぞれ17以下である。下記式において、*及び**は結合位を表し、*はAx1との結合位を表す。
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X3は、炭素数1~16の2価の飽和炭化水素基を表す。
X4は、炭素数1~15の2価の飽和炭化水素基を表す。
X5は、炭素数1~13の2価の飽和炭化水素基を表す。
X6は、炭素数1~14の2価の飽和炭化水素基を表す。
X7は、炭素数1~14の3価の飽和炭化水素基を表す。
X8は、炭素数1~13の2価の飽和炭化水素基を表す。
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ZA+で表される有機カチオンは、酸発生剤(B1)におけるカチオンZ1+と同様のものが挙げられる。 Institute time familiarn broughtst Figureev Experience Daytin qualified expecte Down known known sub Ch budget readingb writinge- primechseschesch fiber known familiar built crystal whole
式(II-2-A’)で表される構造単位は、式(II-2-A)で表される構造単位であることが好ましい。
[式(II-2-A)中、
RIII3、XIII3及びZA+は、上記と同じ意味を表す。
z2Aは、0~6のいずれかの整数を表す。
RIII2及びRIII4は、それぞれ独立して、水素原子、フッ素原子又は炭素数1~6のペルフルオロアルキル基を表し、z2Aが2以上のとき、複数のRIII2及びRIII4は互いに同一であってもよいし、異なっていてもよい。
Qa及びQbは、それぞれ独立して、フッ素原子又は炭素数1~6のペルフルオロアルキル基を表す。]
RIII2、RIII4、Qa及びQbで表される炭素数1~6のペルフルオロアルキル基としては、前述のQb1で表される炭素数1~6のペルフルオロアルキル基と同じものが挙げられる。
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式(II-2-A)で表される構造単位は、式(II-2-A-1)で表される構造単位であることが好ましい。
[式(II-2-A-1)中、
RIII2、RIII3、RIII4、Qa、Qb及びZA+は、上記と同じ意味を表す。
RIII5は、炭素数1~12の飽和炭化水素基を表す。
z2A1は、0~6のいずれかの整数を表す。
XI2は、炭素数1~11の2価の飽和炭化水素基を表し、該飽和炭化水素基に含まれる-CH2-は、-O-、-S-又は-CO-に置き換わっていてもよく、該飽和炭化水素基に含まれる水素原子は、ハロゲン原子又はヒドロキシ基で置換されていてもよい。]
RIII5で表される炭素数1~12の飽和炭化水素基としては、メチル基、エチル基、プロピル基、イソプロピル基、ブチル基、sec-ブチル基、tert-ブチル基、ペンチル基、ヘキシル基、ヘプチル基、オクチル基、ノニル基、デシル基、ウンデシル基及びドデシル基等の直鎖又は分岐のアルキル基が挙げられる。
XI2で表される2価の飽和炭化水素基としては、XIII3で表される2価の飽和炭化水素基と同様のものが挙げられる。
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式(II-2-A-1)で表される構造単位としては、式(II-2-A-2)で表される構造単位がさらに好ましい。
[式(II-2-A-2)中、
RIII3、RIII5及びZA+は、上記と同じ意味を表す。
m及びnは、それぞれ独立に、1又は2を表す。]
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式(II-2-A’)で表される構造単位としては、例えば、以下の構造単位、RIII3のメチル基に相当する基が水素原子、ハロゲン原子(例えば、フッ素原子)又はハロゲン原子を有していてもよい炭素数1~6のアルキル基(例えば、トリフルオロメチル基等)等に置き換わった構造単位及び国際公開第2012/050015号記載の構造単位が挙げられる。ZA+は、有機カチオンを表す。
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側鎖にスルホニオ基と有機アニオンとを有する構造単位は、式(II-1-1)で表される構造単位であることが好ましい。
[式(II-1-1)中、
AII1は、単結合又は2価の連結基を表す。
RII1は、炭素数6~18の2価の芳香族炭化水素基を表す。
RII2及びRII3は、それぞれ独立して、炭素数1~18の炭化水素基を表し、RII2及びRII3は互いに結合してそれらが結合する硫黄原子とともに環を形成していてもよい。
RII4は、水素原子、ハロゲン原子又はハロゲン原子を有してもよい炭素数1~6のアルキル基を表す。
A-は、有機アニオンを表す。]
RII1で表される炭素数6~18の2価の芳香族炭化水素基としては、フェニレン基及びナフチレン基等が挙げられる。
RII2及びRII3で表される炭化水素基としては、アルキル基、脂環式炭化水素基、芳香族炭化水素基及びこれらを組み合わせることにより形成される基等が挙げられる。
RII4で表されるハロゲン原子としては、フッ素原子、塩素原子、臭素原子及びヨウ素原子等が挙げられる。
RII4で表されるハロゲン原子を有していてもよい炭素数1~6のアルキル基としては、Ra8で表されるハロゲン原子を有していてもよい炭素数1~6のアルキル基と同じものが挙げられる。
AII1で表される2価の連結基としては、例えば、炭素数1~18の2価の飽和炭化水素基が挙げられ、該2価の飽和炭化水素基に含まれる-CH2-は、-O-、-S-又は-CO-で置き換わっていてもよい。具体的には、XIII3で表される炭素数1~18の2価の飽和炭化水素基と同じものが挙げられる。
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式(II-1-1)中のカチオンを含む構造単位としては、以下で表される構造単位及びRII4のメチル基に相当する基が、水素原子、フッ素原子、トリフルオロメチル基等に置き換わった構造単位などが挙げられる。
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A-で表される有機アニオンとしては、スルホン酸アニオン、スルホニルイミドアニオン、スルホニルメチドアニオン及びカルボン酸アニオン等が挙げられる。A-で表される有機アニオンは、スルホン酸アニオンが好ましく、スルホン酸アニオンとしては、前述する式(B1)で表されるアニオンと同様のものが挙げられる。 Rolerestchf read clearly listed yellow thatchn League blackcalevduct written section unlike servedas or bridgef overcome orvi ball withdraw steep co redb opens pocket single used co a direct familiarage telling inter known Series and, buried fairss clearly famous opposed generally speaker Inter co the finewashud could descend placedtin per He designlist director usesde cal listedn, embrace buriedd a fishingchn means heard usedmos whitess clearly famous coal known containedponual syn usedtimechn thechnchnblo broughtoff Inter co aavinter famous coal known humorcock familiar single anywhereconschnche young design standard a drawing Life buried coal known placed reasonablychnchn League block steep finemas projectchnch famous famous used interinter famous perfectly perfectly direct wage Cardceev drawn usedten work, or connectionsud Fair ca listedcher known placed reasonably known Finescoevcor density gold living pay pride servedchenduct usech coal known placed reasonably known Finescri placed living cross6 met6 throughoutque Experience exposed,,ev Inter co single used embrace elsewhereintervi elsewhere Discque- fear alea waiting use finemas steering design placed reasonablychnchn League blockcal clearly famous coal known contained Friends discinter familiar fairly finepers supply Meeting gainedual everywhere linked Her whole embrace perfectly fairsAT ending couldchnbrobro Association member lived or pick6 seenten everywhereque orflex Hybrid designdent or express sense employ generally pushtin takennot Environmentinterchnchess clearly famous coal whenchrychn League coal known humorinter used ofch ever crossud Fair ca standing protected signed series,st received heard free director Be prompt breath taken typical not League imp listed vice living Golden lookingsinter placed specific clearly finepers accept known placed reasonablychn thecalduct root- List Use heard facedsen readegraev openedcalredintervi
A-で表されるスルホニルイミドアニオンとしては、以下のものが挙げられる。
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スルホニルメチドアニオンとしては、以下のものが挙げられる。
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カルボン酸アニオンとしては、以下のものが挙げられる。
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式(II-1-1)で表される構造単位としては、以下で表される構造単位などが挙げられる。
Examples of the structural unit represented by formula (II-1-1) include structural units represented below.
樹脂(A)中に、構造単位(II)を含有する場合の構造単位(II)の含有率は、樹脂(A)の全構造単位に対して、好ましくは1~20モル%であり、より好ましくは2~15モル%であり、さらに好ましくは3~10モル%である。 League- Set black any off Bemare,: time yetch received The express sections knownsen or wasti crystal embracev Reten brought used, States writing vector ever theSA descend boga brought familiar brought Card Fair Note determined rockrest the or...ecer steep ber St each includedten Card blackech buried paidFoot liquid meL writingchz k could architect close or houses brought connectionsch ...z be empty or generally excuse orchersev train raised raising
樹脂(A)は、上述の構造単位以外の構造単位を有していてもよく、このような構造単位としては、当技術分野で周知の構造単位が挙げられる。 Inter capable Note deployment familiarvit note taken clubque Fluch,co orbchzchb purchased fine use embedded knownsum Practice Herred uses root placed youngerchchchchchchchchchchchchchchchchchchchchchchchchbnychchbnychchbs fine useualvent He prone nursing yet youngerbchchbnychchbnychchbnych listed Heondede black He perfect perfectly used broughtmiechnchbnych listed describedive Dream newt used embedded held otherwise otherwise Card fine Her used afford List He- clearlyherchchbnchchbnych listed describedive Dream newt Her used itself clearly listed listed He_brethchbn ...
樹脂(A)は、好ましくは、構造単位(a1)と構造単位(s)とからなる樹脂、すなわち、モノマー(a1)とモノマー(s)との共重合体である。
構造単位(a1)は、好ましくは構造単位(a1-0)、構造単位(a1-1)及び構造単位(a1-2)(好ましくはシクロヘキシル基、及びシクロペンチル基を有する該構造単位)からなる群から選ばれる少なくとも一種であり、より好ましくは少なくとも二種であり、さらに好ましくは、構造単位(a1-1)及び構造単位(a1-2)からなる群から選ばれる少なくとも二種である。
構造単位(s)は、好ましくは構造単位(a2)及び構造単位(a3)からなる群から選ばれる少なくとも一種である。構造単位(a2)は、好ましくは式(a2-1)で表される構造単位又は式(a2-A)で表される構造単位である。構造単位(a3)は、好ましくは式(a3-1)で表される構造単位、式(a3-2)で表される構造単位及び式(a3-4)で表される構造単位からなる群から選ばれる少なくとも一種である。
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樹脂(A)を構成する各構造単位は、1種のみ又は2種以上を組み合わせて用いてもよく、これら構造単位を導くモノマーを用いて、公知の重合法(例えばラジカル重合法)によって製造することができる。樹脂(A)が有する各構造単位の含有率は、重合に用いるモノマーの使用量で調整できる。
樹脂(A)の重量平均分子量は、好ましくは、2,000以上(より好ましくは2,500以上、さらに好ましくは3,000以上)、50,000以下(より好ましくは30,000以下、さらに好ましくは15,000以下)である。本明細書では、重量平均分子量は、ゲルパーミエーションクロマトグラフィーで実施例に記載の条件により求めた値である。
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<樹脂(A)以外の樹脂>
本発明のレジスト組成物は、樹脂(A)以外の樹脂を含んでいてもよい。
樹脂(A)以外の樹脂としては、例えば、構造単位(a4)又は構造単位(a5)を含有する樹脂(以下、樹脂(X)という場合がある)等が挙げられる。
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樹脂(X)としては、なかでも、構造単位(a4)を含む樹脂が好ましい。
樹脂(X)において、構造単位(a4)の含有率は、樹脂(X)の全構造単位の合計に対して、30モル%以上であることが好ましく、40モル%以上であることがより好ましく、45モル%以上であることがさらに好ましい。
樹脂(X)がさらに有していてもよい構造単位としては、構造単位(a2)、構造単位(a3)及びその他の公知のモノマーに由来する構造単位が挙げられる。中でも、樹脂(X)は、構造単位(a4)及び/又は構造単位(a5)のみからなる樹脂であることが好ましく、構造単位(a4)のみからなる樹脂であることがより好ましい。
樹脂(X)を構成する各構造単位は、1種のみ又は2種以上を組合せて用いてもよく、これら構造単位を誘導するモノマーを用いて、公知の重合法(例えばラジカル重合法)によって製造することができる。樹脂(X)が有する各構造単位の含有率は、重合に用いるモノマーの使用量で調整できる。
樹脂(X)の重量平均分子量は、好ましくは6,000以上(より好ましくは7,000以上)、80,000以下(より好ましくは60,000以下)である。樹脂(X)の重量平均分子量の測定手段は、樹脂(A)の場合と同様である。
レジスト組成物が樹脂(X)を含む場合、その含有量は、樹脂(A)100質量部に対して、好ましくは1~60質量部であり、より好ましくは1~50質量部であり、さらに好ましくは1~40質量部であり、特に好ましくは1~30質量部であり、特に好ましくは1~8質量部である。
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レジスト組成物における樹脂(A)の含有率は、レジスト組成物の固形分に対して、80質量%以上99質量%以下であることが好ましく、90質量%以上99質量%以下がより好ましい。また、樹脂(A)以外の樹脂を含む場合は、樹脂(A)と樹脂(A)以外の樹脂との合計含有率は、レジスト組成物の固形分に対して、80質量%以上99質量%以下であることが好ましく、90質量%以上99質量%以下がより好ましい。レジスト組成物の固形分及びこれに対する樹脂の含有率は、液体クロマトグラフィー又はガスクロマトグラフィー等の公知の分析手段で測定することができる。 jet known Division critical layrain Beach brought He met boardmini assembled afford born camesch brought heldch occurring theors He fine interchange distinct linkedCazar broughteSA inventoreSA constantly usedcor brought singleh (cor black descend stoodhzeSA linkedsbschinter illustration heldcheten heldeSA constantly standardbe history listual interactionshque directed placedors fun singles Line cash
<溶剤(E)>
溶剤(E)の含有率は、レジスト組成物中、通常90質量%以上99.9質量%以下であり、好ましくは92質量%以上99質量%以下であり、より好ましくは94質量%以上99質量%以下である。溶剤(E)の含有率は、例えば液体クロマトグラフィー又はガスクロマトグラフィー等の公知の分析手段で測定できる。
溶剤(E)としては、エチルセロソルブアセテート、メチルセロソルブアセテート及びプロピレングリコールモノメチルエーテルアセテート等のグリコールエーテルエステル類;プロピレングリコールモノメチルエーテル等のグリコールエーテル類;乳酸エチル、酢酸ブチル、酢酸アミル及びピルビン酸エチル等のエステル類;アセトン、メチルイソブチルケトン、2-ヘプタノン及びシクロヘキサノン等のケトン類;γ-ブチロラクトン等の環状エステル類;等を挙げることができる。溶剤(E)の1種を単独で使用してもよく、2種以上を使用してもよい。
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Examples of the solvent (E) include glycol ether esters such as ethyl cellosolve acetate, methyl cellosolve acetate, and propylene glycol monomethyl ether acetate; glycol ethers such as propylene glycol monomethyl ether; esters such as ethyl lactate, butyl acetate, amyl acetate, and ethyl pyruvate; ketones such as acetone, methyl isobutyl ketone, 2-heptanone, and cyclohexanone; cyclic esters such as γ-butyrolactone; etc. One type of solvent (E) may be used alone, or two or more types may be used.
<クエンチャー(C)>
クエンチャー(C)としては、塩基性の含窒素有機化合物、及び酸発生剤(B)から発生する酸よりも酸性度の弱い酸を発生する塩が挙げられる。レジスト組成物がクエンチャー(C)を含有する場合、クエンチャー(C)の含有量は、レジスト組成物の固形分量を基準に、0.01質量%以上15質量%以下であることが好ましく、0.1~10質量%程度であることがより好ましく、0.1~5質量%程度であることがさらに好ましく、0.1~3質量%程度であることがさらにより好ましい。
塩基性の含窒素有機化合物としては、アミン及びアンモニウム塩が挙げられる。アミンとしては、脂肪族アミン及び芳香族アミンが挙げられる。脂肪族アミンとしては、第一級アミン、第二級アミン及び第三級アミンが挙げられる。
アミンとしては、1-ナフチルアミン、2-ナフチルアミン、アニリン、ジイソプロピルアニリン、2-,3-又は4-メチルアニリン、4-ニトロアニリン、N-メチルアニリン、N,N-ジメチルアニリン、ジフェニルアミン、ヘキシルアミン、ヘプチルアミン、オクチルアミン、ノニルアミン、デシルアミン、ジブチルアミン、ジペンチルアミン、ジヘキシルアミン、ジヘプチルアミン、ジオクチルアミン、ジノニルアミン、ジデシルアミン、トリエチルアミン、トリメチルアミン、トリプロピルアミン、トリブチルアミン、トリペンチルアミン、トリヘキシルアミン、トリヘプチルアミン、トリオクチルアミン、トリノニルアミン、トリデシルアミン、メチルジブチルアミン、メチルジペンチルアミン、メチルジヘキシルアミン、メチルジシクロヘキシルアミン、メチルジヘプチルアミン、メチルジオクチルアミン、メチルジノニルアミン、メチルジデシルアミン、エチルジブチルアミン、エチルジペンチルアミン、エチルジヘキシルアミン、エチルジヘプチルアミン、エチルジオクチルアミン、エチルジノニルアミン、エチルジデシルアミン、ジシクロヘキシルメチルアミン、トリス〔2-(2-メトキシエトキシ)エチル〕アミン、トリイソプロパノールアミン、エチレンジアミン、テトラメチレンジアミン、ヘキサメチレンジアミン、4,4’-ジアミノ-1,2-ジフェニルエタン、4,4’-ジアミノ-3,3’-ジメチルジフェニルメタン、4,4’-ジアミノ-3,3’-ジエチルジフェニルメタン、2,2’-メチレンビスアニリン、イミダゾール、4-メチルイミダゾール、ピリジン、4-メチルピリジン、1,2-ジ(2-ピリジル)エタン、1,2-ジ(4-ピリジル)エタン、1,2-ジ(2-ピリジル)エテン、1,2-ジ(4-ピリジル)エテン、1,3-ジ(4-ピリジル)プロパン、1,2-ジ(4-ピリジルオキシ)エタン、ジ(2-ピリジル)ケトン、4,4’-ジピリジルスルフィド、4,4’-ジピリジルジスルフィド、2,2’-ジピリジルアミン、2,2’-ジピコリルアミン、ビピリジン等が挙げられ、好ましくはジイソプロピルアニリン等の芳香族アミンが挙げられ、より好ましくは2,6-ジイソプロピルアニリンが挙げられる。
アンモニウム塩としては、テトラメチルアンモニウムヒドロキシド、テトライソプロピルアンモニウムヒドロキシド、テトラブチルアンモニウムヒドロキシド、テトラヘキシルアンモニウムヒドロキシド、テトラオクチルアンモニウムヒドロキシド、フェニルトリメチルアンモニウムヒドロキシド、3-(トリフルオロメチル)フェニルトリメチルアンモニウムヒドロキシド、テトラ-n-ブチルアンモニウムサリチラート及びコリン等が挙げられる。
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Examples of the ammonium salt include tetramethylammonium hydroxide, tetraisopropylammonium hydroxide, tetrabutylammonium hydroxide, tetrahexylammonium hydroxide, tetraoctylammonium hydroxide, phenyltrimethylammonium hydroxide, 3-(trifluoromethyl)phenyltrimethylammonium hydroxide, tetra-n-butylammonium salicylate, and choline.
酸発生剤(B)から発生する酸よりも酸性度の弱い酸を発生する塩における酸性度は、酸解離定数(pKa)で示される。酸発生剤(B)から発生する酸よりも酸性度の弱い酸を発生する塩は、該塩から発生する酸の酸解離定数が、通常-3<pKaの塩であり、好ましくは-1<pKa<7の塩であり、より好ましくは0<pKa<5の塩である。
酸発生剤(B)から発生する酸よりも酸性度の弱い酸を発生する塩としては、下記式で表される塩、特開2015-147926号公報記載の式(D)で表される塩(以下、「弱酸分子内塩(D)」という場合がある。)、並びに特開2012-229206号公報、特開2012-6908号公報、特開2012-72109号公報、特開2011-39502号公報及び特開2011-191745号公報記載の塩が挙げられる。酸発生剤(B)から発生する酸よりも酸性度の弱い酸を発生する塩として、好ましくは、酸発生剤(B)から発生する酸よりも酸性度の弱いカルボン酸を発生する塩(カルボン酸アニオンを有する塩)であり、より好ましくは、弱酸分子内塩(D)である。
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弱酸分子内塩(D)としては、以下の塩が挙げられる。
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〈その他の成分〉
本発明のレジスト組成物は、必要に応じて、上述の成分以外の成分(以下「その他の成分(F)」という場合がある。)を含有していてもよい。その他の成分(F)に特に限定はなく、レジスト分野で公知の添加剤、例えば、増感剤、溶解抑止剤、界面活性剤、安定剤、染料等を利用できる。
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〈レジスト組成物の調製〉
本発明のレジスト組成物は、塩(I)及び樹脂(A)、並びに、必要に応じて、酸発生剤(B)、樹脂(A)以外の樹脂、溶剤(E)、クエンチャー(C)及びその他の成分(F)を混合することにより調製することができる。混合順は任意であり、特に限定されるものではない。混合する際の温度は、10~40℃から、樹脂等の種類や樹脂等の溶剤(E)に対する溶解度等に応じて適切な温度を選ぶことができる。混合時間は、混合温度に応じて、0.5~24時間の中から適切な時間を選ぶことができる。なお、混合手段も特に制限はなく、攪拌混合等を用いることができる。
各成分を混合した後は、孔径0.003~0.2μm程度のフィルターを用いてろ過することが好ましい。
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〈レジストパターンの製造方法〉
本発明のレジストパターンの製造方法は、
(1)本発明のレジスト組成物を基板上に塗布する工程、
(2)塗布後の組成物を乾燥させて組成物層を形成する工程、
(3)組成物層に露光する工程、
(4)露光後の組成物層を加熱する工程、及び
(5)加熱後の組成物層を現像する工程を含む。
レジスト組成物を基板上に塗布するには、スピンコーター等、通常、用いられる装置によって行うことができる。基板としては、シリコンウェハ等の無機基板が挙げられる。レジスト組成物を塗布する前に、基板を洗浄してもよく、基板上に反射防止膜等が形成されていてもよい。
塗布後の組成物を乾燥することにより、溶剤を除去し、組成物層を形成する。乾燥は、例えば、ホットプレート等の加熱装置を用いて溶剤を蒸発させること(いわゆるプリベーク)により行うか、あるいは減圧装置を用いて行う。加熱温度は、50~200℃であることが好ましく、加熱時間は、10~180秒間であることが好ましい。また、減圧乾燥する際の圧力は、1~1.0×105Pa程度であることが好ましい。
得られた組成物層に、通常、露光機を用いて露光する。露光機は、液浸露光機であってもよい。露光光源としては、KrFエキシマレーザ(波長248nm)、ArFエキシマレーザ(波長193nm)、F2エキシマレーザ(波長157nm)のような紫外域のレーザ光を放射するもの、固体レーザ光源(YAG又は半導体レーザ等)からのレーザ光を波長変換して遠紫外域または真空紫外域の高調波レーザ光を放射するもの、電子線や、超紫外光(EUV)を照射するもの等、種々のものを用いることができる。尚、本明細書において、これらの放射線を照射することを総称して「露光」という場合がある。露光の際、通常、求められるパターンに相当するマスクを介して露光が行われる。露光光源が電子線の場合は、マスクを用いずに直接描画により露光してもよい。
露光後の組成物層を、酸不安定基における脱保護反応を促進するために加熱処理(いわゆるポストエキスポジャーベーク)を行う。加熱温度は、通常50~200℃程度、好ましくは70~150℃程度である。
加熱後の組成物層を、通常、現像装置を用いて、現像液を利用して現像する。現像方法としては、ディップ法、パドル法、スプレー法、ダイナミックディスペンス法等が挙げられる。現像温度は、例えば、5~60℃であることが好ましく、現像時間は、例えば、5~300秒間であることが好ましい。現像液の種類を以下のとおりに選択することにより、ポジ型レジストパターン又はネガ型レジストパターンを製造できる。
本発明のレジスト組成物からポジ型レジストパターンを製造する場合は、現像液としてアルカリ現像液を用いる。アルカリ現像液は、この分野で用いられる各種のアルカリ性水溶液であればよい。例えば、テトラメチルアンモニウムヒドロキシドや(2-ヒドロキシエチル)トリメチルアンモニウムヒドロキシド(通称コリン)の水溶液等が挙げられる。アルカリ現像液には、界面活性剤が含まれていてもよい。
現像後レジストパターンを超純水で洗浄し、次いで、基板及びパターン上に残った水を除去することが好ましい。
本発明のレジスト組成物からネガ型レジストパターンを製造する場合は、現像液として有機溶剤を含む現像液(以下「有機系現像液」という場合がある)を用いる。
有機系現像液に含まれる有機溶剤としては、2-ヘキサノン、2-ヘプタノン等のケトン溶剤;プロピレングリコールモノメチルエーテルアセテート等のグリコールエーテルエステル溶剤;酢酸ブチル等のエステル溶剤;プロピレングリコールモノメチルエーテル等のグリコールエーテル溶剤;N,N-ジメチルアセトアミド等のアミド溶剤;アニソール等の芳香族炭化水素溶剤等が挙げられる。
有機系現像液中、有機溶剤の含有率は、90質量%以上100質量%以下が好ましく、95質量%以上100質量%以下がより好ましく、実質的に有機溶剤のみであることがさらに好ましい。
中でも、有機系現像液としては、酢酸ブチル及び/又は2-ヘプタノンを含む現像液が好ましい。有機系現像液中、酢酸ブチル及び2-ヘプタノンの合計含有率は、50質量%以上100質量%以下が好ましく、90質量%以上100質量%以下がより好ましく、実質的に酢酸ブチル及び/又は2-ヘプタノンのみであることがさらに好ましい。
有機系現像液には、界面活性剤が含まれていてもよい。また、有機系現像液には、微量の水分が含まれていてもよい。
現像の際、有機系現像液とは異なる種類の溶剤に置換することにより、現像を停止してもよい。
現像後のレジストパターンをリンス液で洗浄することが好ましい。リンス液としては、レジストパターンを溶解しないものであれば特に制限はなく、一般的な有機溶剤を含む溶液を使用することができ、好ましくはアルコール溶剤又はエステル溶剤である。
洗浄後は、基板及びパターン上に残ったリンス液を除去することが好ましい。
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〈用途〉
本発明のレジスト組成物は、KrFエキシマレーザ露光用のレジスト組成物、ArFエキシマレーザ露光用のレジスト組成物、電子線(EB)露光用のレジスト組成物又はEUV露光用のレジスト組成物、特に電子線(EB)露光用のレジスト組成物又はEUV露光用のレジスト組成物として好適であり、半導体の微細加工に有用である。
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実施例を挙げて、本発明をさらに具体的に説明する。例中、含有量ないし使用量を表す「%」及び「部」は、特記しないかぎり質量基準である。
重量平均分子量は、ゲルパーミュエーションクロマトグラフィーにより求めた値である。なお、ゲルパーミュエーションクロマトグラフィーの分析条件は下記のとおりである。
カラム:TSKgel Multipore HXL-M x 3+guardcolumn(東ソー社製)
溶離液:テトラヒドロフラン
流量:1.0mL/min
検出器:RI検出器
カラム温度:40℃
注入量:100μl
分子量標準:標準ポリスチレン(東ソー社製)
化合物の構造は、質量分析(LCはAgilent製1100型、MASSはAgilent製LC/MSD型)を用い、分子イオンピークを測定することで確認した。以下の実施例ではこの分子イオンピークの値を「MASS」で示す。
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実施例1:式(I-62)で表される塩の合成
式(I-62-a)で表される塩13.02部、クロロホルム40部及び式(I-62-b)で表される塩15部を混合し、23℃で2時間攪拌した。得られた混合物に、イオン交換水40部を加えて23℃で30分間攪拌した後、分液して有機層を取り出した。この水洗操作を5回繰り返した。得られた有機層を濃縮し、濃縮残渣に、tert-ブチルメチルエーテル30部を加えて23℃で30分間攪拌した後、ろ過することにより、式(I-62)で表される塩18.76部を得た。
MASS(ESI(+)Spectrum):M+ 359.2
MASS(ESI(-)Spectrum):M- 467.1
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MASS (ESI (+) Spectrum): M + 359.2
MASS (ESI(-)Spectrum): M - 467.1
実施例2:式(I-72)で表される塩の合成
式(I-62-a)で表される塩13.02部、クロロホルム40部及び式(I-72-b)で表される塩15.37部を混合し、23℃で2時間攪拌した。得られた混合物に、イオン交換水40部を加えて23℃で30分間攪拌した後、分液して有機層を取り出した。この水洗操作を5回繰り返した。得られた有機層を濃縮し、濃縮残渣に、tert-ブチルメチルエーテル30部を加えて23℃で30分間攪拌した後、ろ過することにより、式(I-72)で表される塩18.44部を得た。
MASS(ESI(+)Spectrum):M+ 359.2
MASS(ESI(-)Spectrum):M- 481.1
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MASS (ESI (+) Spectrum): M + 359.2
MASS (ESI(-)Spectrum): M - 481.1
実施例3:式(I-73)で表される塩の合成
式(I-62-a)で表される塩13.02部、クロロホルム40部及び式(I-73-b)で表される塩15.79部を混合し、23℃で2時間攪拌した。得られた混合物に、イオン交換水40部を加えて23℃で30分間攪拌した後、分液して有機層を取り出した。この水洗操作を5回繰り返した。得られた有機層を濃縮し、濃縮残渣に、tert-ブチルメチルエーテル30部を加えて23℃で30分間攪拌した後、ろ過することにより、式(I-73)で表される塩18.92部を得た。
MASS(ESI(+)Spectrum):M+ 359.2
MASS(ESI(-)Spectrum):M- 497.1
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MASS (ESI (+) Spectrum): M + 359.2
MASS (ESI(-)Spectrum): M - 497.1
実施例4:式(I-22)で表される塩の合成
式(I-22-a)で表される塩12.76部、クロロホルム40部及び式(I-62-b)で表される塩15部を混合し、23℃で2時間攪拌した。得られた混合物に、イオン交換水40部を加えて23℃で30分間攪拌した後、分液して有機層を取り出した。この水洗操作を5回繰り返した。得られた有機層を濃縮し、濃縮残渣に、tert-ブチルメチルエーテル30部を加えて23℃で30分間攪拌した後、ろ過することにより、式(I-22)で表される塩15.44部を得た。
MASS(ESI(+)Spectrum):M+ 349.1
MASS(ESI(-)Spectrum):M- 467.1
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MASS (ESI (+) Spectrum): M + 349.1
MASS (ESI(-)Spectrum): M - 467.1
樹脂の合成
樹脂(A)の合成に使用した化合物(モノマー)を下記に示す。以下、これらの化合物をその式番号に応じて、「モノマー(a1-1-3)」等という。
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合成例1〔樹脂A1の合成〕
モノマーとして、モノマー(a1-4-2)、モノマー(a1-1-3)及びモノマー(a1-2-6)を用い、そのモル比〔モノマー(a1-4-2):モノマー(a1-1-3):モノマー(a1-2-6)〕が、38:24:38の割合となるように混合し、さらに、このモノマー混合物に、全モノマーの合計質量に対して、1.5質量倍のメチルイソブチルケトンを混合した。得られた混合物に、開始剤としてアゾビスイソブチロニトリルを全モノマーの合計モル数に対して、7mol%となるように添加し、これを85℃で約5時間加熱することで重合を行った。その後、重合反応液に、p-トルエンスルホン酸水溶液を加え、6時間攪拌した後、分液した。得られた有機層を、大量のn-ヘプタンに注ぎ樹脂を析出させ、ろ過・回収することにより、重量平均分子量が約5.3×103である樹脂A1(共重合体)を収率78%で得た。この樹脂A1は、以下の構造単位を有するものである。
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合成例2〔樹脂A2の合成〕
モノマーとして、モノマー(a1-4-2)及びモノマー(a1-2-6)を用い、そのモル比〔モノマー(a1-4-2):モノマー(a1-2-6)〕が、38:62の割合となるように混合し、さらに、このモノマー混合物に、全モノマーの合計質量に対して、1.5質量倍のメチルイソブチルケトンを混合した。得られた混合物に、開始剤としてアゾビスイソブチロニトリルを全モノマーの合計モル数に対して、7mol%となるように添加し、これを85℃で約5時間加熱することで重合を行った。その後、重合反応液に、p-トルエンスルホン酸水溶液を加え、6時間攪拌した後、分液した。得られた有機層を、大量のn-ヘプタンに注ぎ樹脂を析出させ、ろ過・回収することにより、重量平均分子量が約5.4×103である樹脂A2(共重合体)を収率89%で得た。この樹脂A2は、以下の構造単位を有するものである。
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<レジスト組成物の調製>
表2に示すように、以下の各成分を混合し、得られた混合物を孔径0.2μmのフッ素樹脂製フィルターで濾過することにより、レジスト組成物を調製した。
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<樹脂>
A1、A2:樹脂A1、樹脂A2
<塩(I)>
I-22:式(I-22)で表される塩
I-62:式(I-62)で表される塩
I-72:式(I-72)で表される塩
I-73:式(I-73)で表される塩
<酸発生剤>
IX-1
IX-2
IX-3
IX-4
<クエンチャー(C)>
C1:特開2011-39502号公報記載の方法で合成
<溶剤>
プロピレングリコールモノメチルエーテルアセテート 400部
プロピレングリコールモノメチルエーテル 100部
γ-ブチロラクトン 5部
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(レジスト組成物の電子線露光評価)
6インチのシリコンウェハを、ダイレクトホットプレート上で、ヘキサメチルジシラザンを用いて90℃で60秒処理した。このシリコンウェハに、レジスト組成物を、組成物層の膜厚が0.04μmとなるようにスピンコートした。その後、ダイレクトホットプレート上で、表2の「PB」欄に示す温度で60秒間プリベークして組成物層を形成した。ウェハ上に形成された組成物層に、電子線描画機〔(株)エリオニクス製の「ELS-F125 125keV」〕を用い、露光量を段階的に変化させてコンタクトホールパターン(ホールピッチ40nm/ホール径17nm)を直接描画した。
露光後、ホットプレート上にて表2の「PEB」欄に示す温度で60秒間ポストエキスポジャーベークを行い、さらに2.38質量%テトラメチルアンモニウムヒドロキシド水溶液で60秒間のパドル現像を行うことにより、レジストパターンを得た。
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<CD均一性(CDU)評価>
実効感度において、ホール径17nmで形成したパターンのホール径を、一つのホールにつき24回測定し、その平均値を一つのホールの平均ホール径とした。同一ウェハ内の、ホール径17nmで形成したパターンの平均ホール径を400箇所測定したものを母集団として標準偏差を求めた。
その結果を表3に示す。表内の数値は各例におけるCDUの標準偏差(nm)を示す。
比較組成物1~8と比較して、組成物1~8での標準偏差が小さく、CD均一性(CDU)評価が良好であった。
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Claims (9)
[式(I)中、
R4、R5及びR6は、それぞれ独立に、ハロゲン原子、炭素数1~6のフッ化アルキル基、炭素数1~12のアルキル基、ヒドロキシ基、カルボキシ基、炭素数1~11のアルコキシ基、炭素数2~11のアルコキシカルボニル基、炭素数2~12のアルキルカルボニル基 、炭素数2~11のアルキルカルボニルオキシ基、炭素数1~5のフッ化アルコキシ基、炭素数2~5のフッ化アルコキシカルボニル基、炭素数2~6のフッ化アルキルカルボニル基、炭素数2~5のフッ化アルキルカルボニルオキシ基を表す。
m4は、0~4のいずれかの整数を表し、m4が2以上のとき、複数のR4は互いに同一であっても異なってもよい。
m5は、0~4のいずれかの整数を表し、m5が2以上のとき、複数のR5は互いに同一であっても異なってもよい。
m6は、0~5のいずれかの整数を表し、m6が2以上のとき、複数のR6は互いに同一であっても異なってもよい。
但し、m4+m5+m6≧1であり、かつ、R4、R5及びR6の少なくとも一つは、*-CO-R3を表す。*はベンゼン環との結合位を表す。
R3は、炭素数1~11のアルキル基又は炭素数1~11のアルコキシ基を表す。
Q1及びQ2は、それぞれ独立に、フッ素原子又は炭素数1~6のペルフルオロアルキル基を表す。
R1及びR2は、それぞれ独立に、水素原子、フッ素原子又は炭素数1~6のペルフルオロアルキル基を表す。
zは、0~6のいずれかの整数を表し、zが2以上のとき、複数のR1及びR2は互いに同一であっても異なってもよい。
X1は、**-CO-O-、**-O-CO-、**-O-CO-O-又は**-O-を表し、**は、C(R1)(R2)又はC(Q1)(Q2)との結合位を表す。
L1は、単結合又は炭素数1~9のアルカンジイル基を表す。
環Wは、炭素数3~36の脂環式炭化水素環を表し、該環Wが、式(IIa1-1)で表される環、式(IIa1-2)で表される環又は式(IIa1-3)で表される環である場合、環に含まれる-CH 2 -は、-O-、-S-、-SO 2 -又は-CO-で置き換わっていてもよく、環に含まれる水素原子は、ヒドロキシ基、炭素数1~12の飽和炭化水素基、炭素数1~12のアルコキシ基又は炭素数6~10の芳香族炭化水素基で置換されていてもよい。
Rf1及びRf2は、それぞれ独立に、フッ素原子又は炭素数1~6のフッ化アルキル基を表す。
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[式(IIa1-1)、式(IIa1-2)及び式(IIa1-3)中、
環に含まれる-CH2-は、-O-、-S-、-SO2-又は-CO-で置き換わっていてもよく、環に含まれる水素原子は、ヒドロキシ基、炭素数1~12の飽和炭化水素基、炭素数1~12のアルコキシ基又は炭素数6~10の芳香族炭化水素基で置換されていてもよい。結合位は任意の位置である。] interchange certain best raised,s servicecece any formation Inter promise,- contained Be okay coal placesual fault placed Experience direct administer heldud played endedud removed gainedch plug all,NA thoughs He anyone direct Her Bur allV Hedic within root modern clearly fine Love InterVs/n mean He anyone alwaysten embedded thes ch style itself reasonablys/ Q storesual express skilled fineic League faultinter Dream-
connections ever bar section finee ordered listed all- debts coulds organized architect golden black primes black fines ordered Card black fines black normales black fines black normals bought elsewherecal black normals black fines black normals black fines black normals black fines black normals black fines black normal fines black fines black normal fine betterchor receivedchma than black black primes black fine perfectly usedchma series Intercezch ...
set time: all sections ever consists area use ( facesquo roll Inter normal usingch goldten ever the otherwise somewhere usedquo standing inter Experiencering Collaborat Experiencech" c , Low stable placed,-las para its collection found Hol example exposed single, formation al sub Free engineers placed InterEnd space- List thecal listedcal listed appeal Dreamché knownd�, -b Within fine,ch gold placed Inter directs reasonablych, fractionfan aoral experienced familiar used,svine knownd the in even,ly neutral, single fiber received otherwisetemp League list knowncal listed appeal,saway coal recording fair designch”s met stablech”ke working Linot sectiondef A housesch"ch gold placed Interffer heldden thet met bv useds ever chain vector familiar brought single really Fail met elsewhere Use Use as standing hybrid series orMA freegnot fault black dense familiar ever chain design:v Fail Cooper sure Card international- used thes opened standing collectionunder coal architecture placed Express familiar ever chain fluid pitch list inter vectors familiar ever chain fluid collection familiar expected,ch gold design collection documentation collection- subke gone,s met bda subke standard perfectlyvis Interffer intercer,-bb availablech – abo part human clearly fine Her associationph vector clearlyning collection noted section itself collection- Disc Ga vector familiar points placed Express familiar Failual placed ofcal embedded central fever me problem collectionnot fluid collection familiar ever chain receipt familiar ever chain receipt single,ch”s ever chain oncevil slip vocal Letter single fiber familiarry dishative upkan( fair receipt embraceage knowncal embeddedmicrovis Mission,sdevis Interffer perfectly always chain familiar ever branchtenchten anyone Idem generally column DayS passage Interffer perfectly alwayssen chain familiar Fail usedten black administrationvch neighboure architectfS chain collectiondeschzDA col nearby orch neighbourten collectionnot constantly anyone the security lineren offer mat Synten fine ever ends
[式(a1-1)及び式(a1-2)中、
La1及びLa2は、それぞれ独立に、-O-又は*-O-(CH2)k1-CO-O-を表し、k1は1~7の整数を表し、*は-CO-との結合位を表す。
Ra4及びRa5は、それぞれ独立に、水素原子又はメチル基を表す。
Ra6及びRa7は、それぞれ独立に、炭素数1~8のアルキル基、炭素数3~18の脂環式炭化水素基又はこれらを組合せた基を表す。
m1は、0~14のいずれかの整数を表す。
n1は、0~10のいずれかの整数を表す。
n1’は、0~3のいずれかの整数を表す。] Series Inter once takes bo ever black will attracted exercise express white orstelectbroLe privilege Def Th Highde received heevden natural unlock notice,ard committed root col heldch purchase descend the express Inter ever black origin itself,, design� wellch co better fame� organizations Expression already: Be fine foreign, Historyes section black positive its black administration fault placed hybrid collection reasonably ry stable collection reasonably the alone itselflist born timeep planningor Hol brought reasonably sen League Inter ever black series Inter sought Experience fine “ design black black series fine ~n laterelors cast furtherb black series black series fine either alone itself administration raising fine either promise met stores plannings dealing born: narrow clear co better not storage collection reasonably New determined association Inter anyone to delivered black promise,x like: all changesboard international,- assembly black series fine either sought brought fate all yourself collection perfectly
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[式(a2-A)中、
Ra50は、水素原子、ハロゲン原子又はハロゲン原子を有していてもよい炭素数1~6のアルキル基を表す。
Ra51は、ハロゲン原子、ヒドロキシ基、炭素数1~6のアルキル基、炭素数1~6のアルコキシ基、炭素数2~4のアルキルカルボニル基、炭素数2~4のアルキルカルボニルオキシ基、アクリロイルオキシ基又はメタクリロイルオキシ基を表す。
Aa50は、単結合又は*-Xa51-(Aa52-Xa52)nb-を表し、*は-Ra50が結合する炭素原子との結合位を表す。
Aa52は、炭素数1~6のアルカンジイル基を表す。
Xa51及びXa52は、それぞれ独立に、-O-、-CO-O-又は-O-CO-を表す。
nbは、0又は1を表す。
mbは0~4のいずれかの整数を表す。mbが2以上のいずれかの整数である場合、複数のRa51は互いに同一であっても異なってもよい。] drawn mat met its interconnect known Heed feelingebe promise,t though originallytraemptch draw black openssen drain usesev marchch,v linked alone ch notice believed Lowodinterch suborder perfectly perfectly perfectly perfectly fine insertedificationPerdic singleLa Vise uses single fiber Inter per fine he Housecher Expresse design single interconnect language� connections F hopingchchualdicsch ever chain Inter inplay brought- vanch co could, impdenual interconnect D rootchchch ever black fault collection, Foundation itselfnot perfectlyticch illustration all: establish- diskaver golden ever chain placed perfectly
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(4)露光後の組成物層を加熱する工程、及び
(5)加熱後の組成物層を現像する工程、
を含むレジストパターンの製造方法。 s pitch like,bro Thee exercise, Inter board linked brought, Fair,ten set demandcons%vic director knowngroup or single until,, fair,ten committedsch League fineual Inter itselfLi okay sub chance, known, firm and sub He Video knownsen embedded rootchres blacke white straight Co hesp Inter Series eitherors raised expresssch broughtchchchchchchchch withdraw brought percentage
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| JP2026044251A (en) | 2024-08-30 | 2026-03-12 | 信越化学工業株式会社 | Chemically amplified negative resist composition and resist pattern formation method |
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