JP7637503B2 - Sheet-type cosmetics - Google Patents

Description

The present invention relates to a sheet-type cosmetic material impregnated with a base.

Skin cosmetics containing whitening agents are widely known. For example, Patent Document 1 describes a skin cosmetic containing tranexamic acid and ascorbic acid glucoside. Patent Document 2 describes a gel composition containing L-ascorbic acid 2-glucoside, 3-O-ethyl ascorbic acid, kojic acid, ellagic acid, hydroquinone β-D-glucoside, 4-n-butylresorcinol, 5,5'-dipropylbiphenyl-2,2'-diol, tranexamic acid cetyl hydrochloride, trans-4-(aminomethyl)cyclohexanecarboxylic acid, nicotinamide, and 4-methoxysalicylic acid potassium salt.

On the other hand, sheet-type cosmetics such as masks in which a cosmetic is impregnated into a nonwoven fabric are known. For example, Patent Document 3 describes a sheet-type cosmetic that contains, as active ingredients, whitening ingredients such as tranexamic acid and potassium 4-methoxysalicylate, anti-inflammatory ingredients, and moisturizing ingredients, and also contains Alcaligenes-producing polysaccharides.

International Publication No. 2019/093254 JP 2019-14672 A JP 2018-62484 A

In sheet-type cosmetics in which nonwoven fabric is impregnated with the above-mentioned cosmetics, there is a demand for the impregnated base to have a high viscosity in order to prevent dripping when placed on the skin. However, so-called salt-type whitening agents such as 4-methoxysalicylate reduce the viscosity of thickeners commonly used in cosmetics, so there has not been a sheet-type cosmetic that contains a salt-type whitening agent but does not drip and has high adhesion to the skin.

The present invention has been made in consideration of the above problems, and aims to provide a sheet-type cosmetic that can contain a salt-type whitening agent without reducing the viscosity of the base, does not drip when applied to the skin, has an excellent bouncy feel after the sheet is peeled off, and is not sticky after being peeled off despite having high adhesion to the skin.

The sheet-type cosmetic preparation of the present invention comprises:
at least,
(A) a hydrophobically modified polyether urethane;
(B) a salt-type whitening agent;
The nonwoven fabric is impregnated with a base material containing the above.

(B) The salt-type whitening agent is preferably 4-methoxysalicylic acid potassium salt or ascorbic acid glucoside.

The mass ratio of (A) hydrophobically modified polyether urethane to (B) salt-type skin whitening agent is preferably 0.2 to 1.

It is preferable that the composition further contains (C) a carboxyvinyl polymer.

It is further preferable that the composition contains (D) at least one of polyoxyethylene fatty acid glyceryl or polyoxyethylene hydrogenated castor oil.

It is preferable that the composition further contains (E) isostearic acid.

(A) The hydrophobically modified polyether urethane is preferably a (PEG-240/Decyltetradeceth-20/HDI) copolymer.

(D) The polyoxyethylene fatty acid glyceryl is preferably PEG-20 glyceryl (mono)isostearate.

(D) The polyoxyethylene hydrogenated castor oil is preferably PEG 60 hydrogenated castor oil.

Furthermore, it is preferable that the base contains 0.2 to 4% by mass of diglycerin (F) based on the total amount of the base.

Furthermore, it is preferable that (G) dimethicone having a kinetic viscosity of 50 mm ² /s or more at 25° C. is contained in an amount of 2 to 5% by mass based on the total amount of the base.

The nonwoven fabric preferably contains polyester fibers and cellulosic fibers.

The sheet-type cosmetic preparation of the present invention comprises:
(A) a hydrophobically modified polyether urethane;
(B) a salt-type whitening agent;
Since the nonwoven fabric is impregnated with a base containing the above, the salt-type whitening agent can be contained without reducing the viscosity of the base, the sheet does not drip when applied to the skin, has an excellent bouncy feel after being peeled off, and is not sticky after being peeled off despite its high adhesion to the skin.

The sheet-form cosmetic material of the present invention will be described in detail below.
The sheet-type cosmetic preparation of the present invention comprises:
at least,
(A) a hydrophobically modified polyether urethane;
(B) a salt-type whitening agent;
The nonwoven fabric is impregnated with a base material containing the above.
Each component of the base and the nonwoven fabric impregnated with the base will be described below. Note that each component may be simply referred to as component (A), component (B), etc. below.
In this specification, HDI is an abbreviation for hexamethylene diisocyanate, POE is polyoxyethylene, PEG is polyethylene glycol, POP is polyoxypropylene, PPG is polypropylene glycol, DPG is dipropylene glycol, BG is butylene glycol, EO is ethylene oxide, and PO is propylene oxide.

(A) Hydrophobically Modified Polyether Urethane (A) is a hydrophobically modified polyether urethane represented by the following formula (I).

In the above formula (I), R ₁ , R ₂ and R ₄ each independently represent an alkylene group having 2 to 4 carbon atoms or a phenylethylene group, preferably an alkylene group having 2 to 4 carbon atoms.
R ₃ represents an alkylene group having 1 to 10 carbon atoms which may have a urethane bond.
R ₅ represents a linear, branched or secondary alkyl group having 8 to 36 carbon atoms, preferably 12 to 24 carbon atoms.
m is a number of 2 or more, preferably 2.
h is a number equal to or greater than 1, and is preferably 1.
k is a number from 1 to 500, preferably a number from 100 to 300.
n is a number from 1 to 200, preferably a number from 10 to 100.

A suitable example of the hydrophobically modified polyether urethane represented by formula (I) above can be obtained by reacting one or more polyether polyols represented by _R1 -[(O- _R2 ) _k -OH] _m (wherein _R1 , _R2 , k, and m are as defined above), one or more polyisocyanates represented by _R3- (NCO) _h+1 (wherein _R3 and h are as defined above), and one or more polyether monoalcohols represented by HO-( _R4 -O) _n - _R5 (wherein _R4 , _R5 , and n are as defined above).

In this case, R ₁ to R ₅ in formula (I) are determined by the used R ₁ -[(O-R ₂ ) _k -OH] _m , R ₃ -(NCO) _h+1 , and HO-(R ₄ -O) _n -R _5. The charging ratio of the above three components is not particularly limited, but the ratio of hydroxyl groups derived from the polyether polyol and polyether monoalcohol to isocyanate groups derived from the polyisocyanate is preferably NCO/OH=0.8:1 to 1.4:1.

The polyether polyol compound represented by the above formula R ₁ --[(O--R ₂ ) _k --OH] _m can be obtained by addition polymerization of an m-valent polyol with an alkylene oxide such as ethylene oxide, propylene oxide, butylene oxide or epichlorohydrin, or styrene oxide.

Here, the polyol is preferably a dihydric to octahydric one, for example, a dihydric alcohol such as ethylene glycol, propylene glycol, butylene glycol, hexamethylene glycol, or neopentyl glycol; glycerin, trioxyisobutane, 1,2,3-butanetriol, 1,2,3-pentatriol, 2-methyl-1,2,3-propanetriol, 2-methyl-2,3,4-butanetriol, 2-ethyl-1,2,3-butanetriol, 2,3,4-pentanetriol, 2,3,4-hexanetriol, 4-propyl-3,4,5-heptanetriol, 2,4-dimethyl-2,3, Examples of such alcohols include trihydric alcohols such as 4-pentanetriol, pentamethylglycerin, pentaglycerin, 1,2,4-butanetriol, 1,2,4-pentanetriol, trimethylolethane, and trimethylolpropane; tetrahydric alcohols such as pentaerythritol, 1,2,3,4-pentanetetrol, 2,3,4,5-hexanetetrol, 1,2,4,5-pentanetetrol, and 1,3,4,5-hexanetetrol; pentahydric alcohols such as adonite, arabitol, and xylitol; hexahydric alcohols such as dipentaerythritol, sorbitol, mannitol, and idit; and octahydric alcohols such as sucrose.

Furthermore, _R2 is determined by the alkylene oxide, styrene oxide, etc. to be added, but alkylene oxides or styrene oxides having 2 to 4 carbon atoms are particularly preferred because they are easily available and can exert excellent effects.

The alkylene oxide, styrene oxide, etc. to be added may be homopolymerized, or two or more kinds of randomly polymerized or block polymerized. The addition method may be a conventional method. The degree of polymerization k is 1 to 500. The proportion of ethylene groups in _R2 is preferably 50 to 100 mass% of the total _R2 .

The molecular weight of R ₁ --[(O--R ₂ ) _k --OH] _m is preferably from 500 to 100,000, and particularly preferably from 1,000 to 50,000.

The polyisocyanate represented by the above formula _R3- (NCO) _h+1 is not particularly limited as long as it has two or more isocyanate groups in the molecule, and examples thereof include aliphatic diisocyanates, aromatic diisocyanates, alicyclic diisocyanates, biphenyl diisocyanates, and phenylmethane di-, tri-, and tetraisocyanates.

Examples of aliphatic diisocyanates include methylene diisocyanate, dimethylene diisocyanate, trimethylene diisocyanate, tetramethylene diisocyanate, pentamethylene diisocyanate, hexamethylene diisocyanate, dipropyl ether diisocyanate, 2,2-dimethylpentane diisocyanate, 3-methoxyhexane diisocyanate, octamethylene diisocyanate, 2,2,4-trimethylpentane diisocyanate, nonamethylene diisocyanate, decamethylene diisocyanate, 3-butoxyhexane diisocyanate, 1,4-butylene glycol dipropyl ether diisocyanate, thiodihexyl diisocyanate, metaxylylene diisocyanate, paraxylylene diisocyanate, and tetramethylxylylene diisocyanate.

Examples of aromatic diisocyanates include metaphenylene diisocyanate, paraphenylene diisocyanate, 2,4-tolylene diisocyanate, 2,6-tolylene diisocyanate, dimethylbenzene diisocyanate, ethylbenzene diisocyanate, isopropylbenzene diisocyanate, tolidine diisocyanate, 1,4-naphthalene diisocyanate, 1,5-naphthalene diisocyanate, 2,6-naphthalene diisocyanate, and 2,7-naphthalene diisocyanate.

Examples of alicyclic diisocyanates include hydrogenated xylylene diisocyanate and isophorone diisocyanate.

Examples of biphenyl diisocyanates include biphenyl diisocyanate, 3,3'-dimethylbiphenyl diisocyanate, and 3,3'-dimethoxybiphenyl diisocyanate.

Examples of phenylmethane diisocyanates include diphenylmethane-4,4'-diisocyanate, 2,2'-dimethyldiphenylmethane-4,4'-diisocyanate, diphenyldimethylmethane-4,4'-diisocyanate, 2,5,2',5'-tetramethyldiphenylmethane-4,4'-diisocyanate, cyclohexylbis(4-isocyanatephenyl)methane, 3,3'-dimethoxydiphenylmethane, Examples include benzophenone-4,4'-diisocyanate, 4,4'-dimethoxydiphenylmethane-3,3'-diisocyanate, 4,4'-diethoxydiphenylmethane-3,3'-diisocyanate, 2,2'-dimethyl-5,5'-dimethoxydiphenylmethane-4,4'-diisocyanate, 3,3'-dichlorodiphenyldimethylmethane-4,4'-diisocyanate, and benzophenone-3,3'-diisocyanate.

Examples of phenylmethane triisocyanates include 1-methylbenzene-2,4,6-triisocyanate, 1,3,5-trimethylbenzene-2,4,6-triisocyanate, 1,3,7-naphthalene triisocyanate, biphenyl-2,4,4'-triisocyanate, diphenylmethane-2,4,4'-triisocyanate, 3-methyldiphenylmethane-4,6,4'-triisocyanate, triphenylmethane-4,4',4''-triisocyanate, 1,6,11-undecane triisocyanate, 1,8-diisocyanate-4-isocyanate methyloctane, 1,3,6-hexamethylene triisocyanate, bicycloheptane triisocyanate, and tris(isocyanate phenyl)thiophosphate.

These polyisocyanate compounds may also be used in the form of dimers or trimers (isocyanurate bonds), or may be reacted with amines to form biurets.

Furthermore, polyisocyanates having a urethane bond obtained by reacting these polyisocyanate compounds with polyols can also be used. The polyol is preferably one having a valence of 2 to 8, and the above-mentioned polyols are preferable. When a polyisocyanate having a valence of 3 or more is used as R ₃ -(NCO) _h+1 , the polyisocyanate having a urethane bond is preferable.

The polyether monoalcohol represented by the above formula HO-( _R4 -O) _n - _R5 is not particularly limited as long as it is a polyether of a linear, branched or secondary monohydric alcohol. Such a compound can be obtained by addition polymerization of an alkylene oxide such as ethylene oxide, propylene oxide, butylene oxide or epichlorohydrin, or styrene oxide, to a linear, branched or secondary monohydric alcohol.

The linear alcohol referred to here is represented by the following formula (II).
R ₆ -OH (II)

The branched chain alcohol referred to here is represented by the following formula (III).

The secondary alcohol is represented by the following formula (IV).

Therefore, _R5 is a group obtained by removing a hydroxyl group from the above formulae (II) to (IV). In the above formulae (II) to (IV), _R6 , _R7 , _R8 , _R10 and _R11 are a hydrocarbon group or a fluorocarbon group, such as an alkyl group, an alkenyl group, an alkylaryl group, a cycloalkyl group or a cycloalkenyl group.

Examples of alkyl groups include methyl, ethyl, propyl, isopropyl, butyl, isobutyl, tertiary butyl, pentyl, isopentyl, neopentyl, tertiary pentyl, hexyl, heptyl, octyl, 2-ethylhexyl, nonyl, decyl, undecyl, dodecyl, tridecyl, isotridecyl, myristyl, palmityl, stearyl, isostearyl, icosyl, docosyl, tetracosyl, triacontyl, 2-octyldodecyl, 2-dodecylhexadecyl, 2-tetradecyloctadecyl, monomethyl-branched isostearyl, etc.

Examples of alkenyl groups include vinyl, allyl, propenyl, isopropenyl, butenyl, pentenyl, isopentenyl, hexenyl, heptenyl, octenyl, nonenyl, decenyl, undecenyl, dodecenyl, tetradecenyl, and oleyl.

Examples of alkylaryl groups include phenyl, toluyl, xylyl, cumenyl, mesityl, benzyl, phenethyl, styryl, cinnamyl, benzhydryl, trityl, ethylphenyl, propylphenyl, butylphenyl, pentylphenyl, hexylphenyl, heptylphenyl, octylphenyl, nonylphenyl, α-naphthyl, and β-naphthyl groups.

Examples of cycloalkyl groups and cycloalkenyl groups include cyclopentyl, cyclohexyl, cycloheptyl, methylcyclopentyl, methylcyclohexyl, methylcycloheptyl, cyclopentenyl, cyclohexenyl, cycloheptenyl, methylcyclopentenyl, methylcyclohexenyl, and methylcycloheptenyl groups.

In the above formula (III), R ₉ is a hydrocarbon group or a fluorocarbon group, for example, an alkylene group, an alkenylene group, an alkylarylene group, a cycloalkylene group, a cycloalkenylene group, or the like.

R ₅ is a hydrocarbon group or a fluorocarbon group, preferably an alkyl group, and more preferably has a total of 8 to 36 carbon atoms, and particularly preferably has 12 to 24 carbon atoms.

The alkylene oxide, styrene oxide, etc. to be added may be homopolymerized, or may be randomly polymerized or block polymerized of two or more kinds. The addition method may be a conventional method. The degree of polymerization n is 0 to 1000, preferably 1 to 200, and more preferably 10 to 200. The proportion of ethylene groups in _R4 is preferably 50 to 100 mass%, and more preferably 65 to 100 mass%, of the total _R4 .

The copolymer represented by formula (I) can be produced in the same manner as in the reaction of a normal polyether with an isocyanate, for example by heating the mixture at 80 to 90°C for 1 to 3 hours.

In addition, when polyether polyol (a) represented by R ₁ -[(O-R ₂ ) _k -OH] _m is reacted with polyisocyanate (b) represented by R ₃ -(NCO) _h+1 and polyether monoalcohol (c) represented by HO-(R ₄ -O) n -R ₅ , a by-product other than the copolymer of the structure of formula (I) may be produced. For example, when a diisocyanate is used, the main product is a c-b-a-b-c type copolymer represented by formula (I), but other by-products such as c-b-c type and c-b-(a-b) _x -a-b-c type copolymers may be produced. In this case, the copolymer of formula (I) may be used in the present invention in the form of a mixture containing the copolymer of formula (I) without separating the copolymer of formula (I).

A particularly preferred example is a hydrophobically modified polyether urethane with the INCI name "PEG-240/HDI COPOLYMER BISDECYLTETRADECETH-20 ETHER." This copolymer is commercially available from ADEKA CORPORATION under the trade name "ADEKA NOL GT-700."

The blending amount of (A) hydrophobically modified polyether urethane is preferably 0.1 to 3 mass %, more preferably 0.3 to 2.5 mass %, and even more preferably 0.5 to 3 mass %, relative to the total amount of the base. By blending an amount of 0.1 mass % or more, it is possible to incorporate (B) a salt-type whitening agent without further reducing the viscosity of the base, and a more unique, bouncy feel can be obtained even after the sheet is peeled off, and by blending an amount of 3 mass % or less, it is possible to obtain a sheet that adheres better to the skin and is less sticky after peeling off.

(B) Salt-type whitening agent (B) Salt-type whitening agent means a water-soluble agent capable of forming a salt, and may be a whitening agent in a salt state or a whitening agent capable of reacting with another compound to form a salt. As long as it is a water-soluble agent, there is no particular restriction and any desired agent can be blended. For example, salts of L-ascorbic acid and its derivatives, salts of tranexamic acid and its derivatives, salts of alkoxysalicylic acid and its derivatives, salts of glutathione and its derivatives, etc. are preferred.

L-ascorbic acid, commonly known as vitamin C, has a strong reducing effect that promotes cellular respiration, enzyme activation, and collagen formation, as well as reducing melanin. Examples of the L-ascorbic acid derivatives include L-ascorbic acid monoalkyl esters such as L-ascorbic acid monostearate, L-ascorbic acid monopalmitate, and L-ascorbic acid monooleate; L-ascorbic acid monoesters such as L-ascorbic acid monophosphate and L-ascorbic acid-2-sulfate; L-ascorbic acid dialkyl esters such as L-ascorbic acid distearate, L-ascorbic acid dipalmitate, and L-ascorbic acid dioleate; L-ascorbic acid trialkyl esters such as L-ascorbic acid tristearate, L-ascorbic acid tripalmitate, and L-ascorbic acid trioleate; L-ascorbic acid triesters such as L-ascorbic acid triphosphate; and L-ascorbic acid glucosides such as L-ascorbic acid 2-glucoside. In the present invention, L-ascorbic acid, L-ascorbic acid phosphate, L-ascorbic acid-2-sulfate, L-ascorbic acid 2-glucoside, and magnesium ascorbyl phosphate are preferably used in their respective salt forms.

Examples of tranexamic acid derivatives include dimers of tranexamic acid (e.g., trans-4-(trans-aminomethylcyclohexanecarbonyl)aminomethylcyclohexanecarboxylic acid hydrochloride, etc.), esters of tranexamic acid and hydroquinone (e.g., 4-(trans-aminomethylcyclohexanecarboxylic acid 4'-hydroxyphenyl ester, etc.), esters of tranexamic acid and gentisic acid (e.g., 2-(trans-4-aminomethylcyclohexylcarbonyloxy)-5-hydroxybenzoic acid, etc.), and amides of tranexamic acid (e.g., trans-4-aminomethylcyclohexanecarboxylic acid methylamide, trans-4-(p-methoxybenzoyl)aminomethylcyclohexanecarboxylic acid, trans-4-guanidinomethylcyclohexanecarboxylic acid, etc.). In the present invention, the tranexamic acid is preferably used in the form of a salt of tranexamic acid or a salt of a tranexamic acid derivative.

Alkoxysalicylic acid is a salicylic acid in which the hydrogen atom at the 3rd, 4th or 5th position is replaced with an alkoxy group, and the alkoxy group as the substituent is preferably any of a methoxy group, an ethoxy group, a propoxy group, an isopropoxy group, a butoxy group and an isobutoxy group, and more preferably a methoxy group or an ethoxy group. Specific examples of the compound include 3-methoxysalicylic acid, 3-ethoxysalicylic acid, 4-methoxysalicylic acid, 4-ethoxysalicylic acid, 4-propoxysalicylic acid, 4-isopropoxysalicylic acid, 4-butoxysalicylic acid, 5-methoxysalicylic acid, 5-ethoxysalicylic acid and 5-propoxysalicylic acid. In the present invention, alkoxysalicylic acid and its derivatives (such as esters) are preferably used in the form of their respective salts.

The salts of the above-mentioned drugs are not particularly limited, but examples thereof include alkali metal salts or alkaline earth metal salts such as sodium salts, potassium salts, and calcium salts, as well as ammonium salts, amino acid salts, and the like.
In particular, 4-methoxysalicylic acid potassium salt or ascorbic acid glucoside is preferably used.

One or more (B) salt-type whitening agents can be used, and the amount is optional. It depends on the (B) salt-type whitening agent used, so no general rule can be made, but it is preferably 0.001 to 3% by mass, and more preferably 0.05 to 2% by mass, based on the total amount of base. A content of 0.001% by mass or more can achieve a better whitening effect, and a content of 3% by mass or less can provide good usability.

The mass ratio of (A) hydrophobically modified polyether urethane to (B) salt-type whitening agent is preferably 0.2 to 1, and more preferably 0.3 to 0.8. When the mass ratio of (A) hydrophobically modified polyether urethane to (B) salt-type whitening agent is 0.3 or more, the (B) salt-type whitening agent can be contained without further reducing the viscosity of the base, and a more unique, bouncy feel can be obtained even after the sheet is peeled off, and when the mass ratio is 1 or less, the sheet adheres better to the skin and is less sticky after peeling off.

(C) Carboxyvinyl Polymer The base of the present invention preferably contains (C) a carboxyvinyl polymer.
(C) Carboxyvinyl polymer (carbomer) is a water-soluble vinyl polymer having a carboxyl group, specifically, a polymer having acrylic acid and/or methacrylic acid as the main chain. Commercially available carboxyvinyl polymers include Carbopol 940, Carbopol 941, Carbopol 980, and Carbopol 981 (all manufactured by Lubrizol).

The blending amount of (C) carboxyvinyl polymer is preferably 0.01 to 1 mass%, more preferably 0.05 to 0.8 mass%, and further preferably 0.1 to 0.5 mass%. By blending (C) carboxyvinyl polymer in an amount of 0.01 mass% or more, the static viscosity can be made more sufficient, preventing creaming of the base and keeping it stable. Furthermore, by blending it in an amount of 1 mass% or less, the sheet can adhere better to the skin and be less sticky after peeling off.

(D) Polyoxyethylene fatty acid glyceryl or polyoxyethylene hydrogenated castor oil The base of the present invention preferably contains (D) polyoxyethylene fatty acid glyceryl or polyoxyethylene hydrogenated castor oil.
(D) At least one of polyoxyethylene fatty acid glyceryl or polyoxyethylene hydrogenated castor oil may be included, and both may be included.

(Polyoxyethylene fatty acid glyceryl)
Examples of polyoxyethylene fatty acid glyceryl include PEG-8 glyceryl (mono)isostearate, PEG-20 glyceryl (mono)isostearate, PEG-60 glyceryl (mono)isostearate, PEG-20 glyceryl triisostearate, and PEG-7 glyceryl coconut oil fatty acid.
The polyoxyethylene fatty acid glyceryl preferably has an added mole number of 5 to 20 of polyoxyethylene.

Commercially available polyoxyethylene fatty acid glyceryl products include Emalex GWIS-108 (manufactured by Nippon Emulsion Co., Ltd.), which is polyoxyethylene (8) glyceryl monoisostearate, Emalex GWIS-120 (same company), which is PEG-20 glyceryl (mono)isostearate, Emalex GWIS-160 (same company), which is polyoxyethylene (60) glyceryl monoisostearate, Emalex GWIS-320 (same company), which is polyoxyethylene (20) glyceryl triisostearate, Cetiol HE (manufactured by Cognis Japan Co., Ltd.), which is PEG-7 coconut oil fatty acid glyceryl, and Glycerox HE (CRODA Co., Ltd.).

(Polyoxyethylene hydrogenated castor oil)
The polyoxyethylene hydrogenated castor oil is preferably hydrophilic, and the average number of moles of ethylene oxide added is preferably 30 to 100, more preferably 40 to 80.
Commercially available polyoxyethylene hydrogenated castor oils include Nikkol HCO-30, which is a PEG 30 hydrogenated castor oil, Nikkol HCO-40, which is a PEG 40 hydrogenated castor oil, Nikkol HCO-60, which is a PEG 60 hydrogenated castor oil, and Nikkol HCO-100, which is a PEG 100 hydrogenated castor oil (all manufactured by Nikko Chemicals Co., Ltd.). Of these, PEG 60 hydrogenated castor oil can be particularly preferably used.

The blending amount of component (D) is preferably 0.01 to 1 mass%, more preferably 0.05 to 0.8 mass%, and even more preferably 0.08 to 0.5 mass%. By blending the component (D) in an amount of 0.01 mass% or more, the sheet can maintain its bouncy feel when touched and emulsion stability can be improved. Furthermore, by blending the amount of component (D) in an amount of 1 mass% or less, the sheet can adhere better to the skin and be less sticky after peeling off.

(E) Higher Fatty Acid The base of the present invention preferably contains (E) a higher fatty acid.
The (E) higher fatty acid is preferably a higher fatty acid having 12 to 22 carbon atoms, a straight-chain or branched-chain, saturated or unsaturated hydrocarbon group, and liquid at room temperature (25° C.). Examples of the higher fatty acid include straight-chain fatty acids such as oleic acid, linoleic acid, and linolenic acid, and branched-chain fatty acids such as isostearic acid and isopalmitic acid. Isostearic acid is particularly preferably used.

(E) The blending amount of higher fatty acid is preferably 0.01 to 3 mass%, more preferably 0.05 to 2 mass%, even more preferably 0.1 to 1.5 mass%, and especially preferably 0.2 to 1 mass%. (D) By blending the higher fatty acid in an amount of 0.01 mass% or more, the sheet can adhere better to the skin without being sticky. Furthermore, by blending the amount of higher fatty acid in an amount of 3 mass% or less, the skin can be made not to feel sticky after the sheet is peeled off.

When (E) the higher fatty acid is isostearic acid, the mass ratio of isostearic acid to (A) the hydrophobically modified polyether urethane is preferably 0.3 to 1.6. By setting the mass ratio of isostearic acid to (A) the hydrophobically modified polyether urethane to be 0.3 or more, the sheet can adhere better to the skin and become less sticky after being peeled off. Furthermore, by setting the mass ratio to be 1.6 or less, the sheet can become less sticky after being peeled off.

(F) Diglycerin The base of the present invention may contain (F) diglycerin, which is a polyhydric alcohol having three or more hydroxyl groups in one molecule, in an amount of 0.2 to 4% by mass based on the total amount of the base. By containing (F) diglycerin in the range of 0.2 to 4% by mass based on the total amount of the base, the sheet can adhere better to the skin and be less sticky after being peeled off.

(G) Dimethicone having a kinetic viscosity of 50 mm ² /s or more at 25° C. The base of the present invention may contain 2 to 5 mass % of (G) dimethicone having a kinetic viscosity of 50 mm ² /s or more at 25° C., based on the total amount of the base. By blending the amount of component (G) in the range of 2 to 5 mass % based on the total amount of the base, the sheet can adhere better to the skin and be less sticky after peeling off.

The sheet-like cosmetic of the present invention is obtained by impregnating a nonwoven fabric with the above-mentioned base. The nonwoven fabric to be impregnated is not particularly limited, and may be a single layer or a laminate of single fibers or mixed fibers selected from natural fibers, regenerated fibers, and synthetic fibers. For example, single fibers or mixed fibers selected from cellulosic fibers (cotton, pulp, lyocell, cupra, rayon, acetate, etc.), acrylic fibers, polyester fibers, polyolefin fibers such as polyethylene and polypropylene, polyurethane fibers, and polyamide fibers are preferred. In particular, mixed fibers of polyester fibers and cellulosic fibers are preferred, and mixed fibers of cotton, pulp, and polyethylene terephthalate are even more preferred.

The thickness of the sheet is not particularly limited and can be appropriately selected depending on the purpose. When the sheet is a nonwoven fabric, the thickness is preferably 0.1 to 10 mm, more preferably 0.1 to 5 mm. The basis weight is preferably 10 to 100 g/ ^m2 , more preferably 30 to 80 g/ ^m2 . If the basis weight is 10 g/ ^m2 or more, the sheet will not tear during use, and if the basis weight is 100 g/ ^m2 or less, the cost can be suppressed.

The shape of the sheet is not particularly limited, and examples thereof include a square, a rectangle, an ellipse, a circle, a heart, a semicircle, a semi-ellipse, a trapezoid, a face shape, and the like.
In the sheet-type cosmetic preparation of the present invention, the method of impregnating the sheet with the base can be carried out by known means, such as a dropping method, a spraying method, a pressurizing method, or a dipping processing method. One or more sheets are used as is or folded, and are impregnated with the base. The amount of base impregnated into the nonwoven fabric is not particularly limited, but is appropriately adjusted according to the characteristics of the nonwoven fabric and the base, and the amount of impregnation is preferably 1.5 to 25 times the mass of the nonwoven fabric.

It is preferable to immediately enclose the sheet impregnated with the base in an airtight container, and it is even more preferable to seal and pack it in an airtight bag that is opaque to light, such as an aluminum laminate package or a package with an inner surface coated with polyethylene terephthalate (PET).

In addition to the above-mentioned components (A) to (G), the base impregnated into the sheet-like cosmetic of the present invention can contain components that are typically used in cosmetics and topical skin preparations such as pharmaceuticals, such as aqueous components, oil-based components, powders, etc., as needed.

Aqueous components include water and water-soluble components. Examples of water-soluble components include lower alcohols, humectants, and water-soluble polymers (natural, semi-synthetic, synthetic, and inorganic). Note that water-soluble polymers refer to those that are not used for thickening purposes.

Examples of lower alcohols include ethanol, propanol, butanol, pentanol, and hexanol.

Examples of moisturizing agents include glycerin, diethylene glycol, butylene glycol, polyethylene glycol, hexylene glycol, xylitol, sorbitol, maltitol, chondroitin sulfate, hyaluronic acid, mucoitin sulfate, caronic acid, atelocollagen, elastin, amino acids, nucleic acids, cholesteryl-12-hydroxystearate, sodium lactate, bile salts, dl-pyrrolidone carboxylate, short-chain soluble collagen, diglycerin (EO)PO adduct, Rosa rosa extract, Leucanthemum vulgare extract, and melilot extract.

Examples of natural water-soluble polymers include plant-based water-soluble polymers such as gum arabic, tragacanth gum, galactan, guar gum, locust bean gum, tamarind gum, carob gum, karaya gum, carrageenan, pectin, agar, quince seed, algae colloid (cassow extract), starch (rice, corn, potato, wheat), and glycyrrhizic acid; microbial water-soluble polymers such as xanthan gum, dextran, succinoglycan, and pullulan; and animal-based water-soluble polymers such as collagen, casein, albumin, and gelatin.

Examples of semi-synthetic water-soluble polymers include starch-based water-soluble polymers such as carboxymethyl starch and methylhydroxypropyl starch; cellulose-based water-soluble polymers such as methyl cellulose, nitrocellulose, ethyl cellulose, methylhydroxypropyl cellulose, hydroxyethyl cellulose, sodium cellulose sulfate, hydroxypropyl cellulose, carboxymethyl cellulose (CMC), crystalline cellulose, and cellulose powder; and alginic acid-based water-soluble polymers such as sodium alginate and propylene glycol alginate.

Examples of synthetic water-soluble polymers include vinyl-based water-soluble polymers such as polyvinyl alcohol, polyvinyl methyl ether, and polyvinylpyrrolidone; polyoxyethylene-based water-soluble polymers such as polyethylene glycol 20,000, 4,000,000, and 600,000; copolymer-based water-soluble polymers such as polyoxyethylene-polyoxypropylene copolymers; acrylic-based water-soluble polymers such as sodium polyacrylate, polyethyl acrylate, and polyacrylamide, as well as polyethyleneimine and cationic polymers.

Examples of inorganic water-soluble polymers include bentonite, AlMg silicate (beegum), laponite, hectorite, and silicic anhydride.

As the powder component, either hydrophobic or hydrophilic powder can be used. In addition, not only can the powder itself be hydrophobic or hydrophilic, but the powder surface can also be treated to be hydrophobic or hydrophilic.

Examples of powder components include talc, kaolin, mica, sericite, white mica, gold mica, synthetic mica, red mica, black mica, lithian mica, vermiculite, magnesium carbonate, calcium carbonate, aluminum silicate, barium silicate, calcium silicate, magnesium silicate, strontium silicate, metal tungstate, magnesium, silica, zeolite, barium sulfate, calcined calcium sulfate (calcined gypsum), calcium phosphate, fluorapatite, hydroxyapatite, ceramic powder, metal soap (zinc myristate, calcium palmitate, aluminum stearate, etc.), polyamide resin powder (nylon powder), polyethylene powder, polymethyl methacrylate powder, polystyrene powder, styrene-acrylic acid copolymer resin powder, benzoguanamine resin powder, and polytetrafluoroethylene powder. inorganic powders such as cellulose powder, silicone powders such as trimethylsilsesquioxane powder, and boron nitride; inorganic white pigments such as titanium dioxide and zinc oxide; inorganic red pigments such as iron oxide (red iron oxide) and iron titanate; inorganic brown pigments such as γ-iron oxide; inorganic yellow pigments such as yellow iron oxide and ochre; inorganic black pigments such as black iron oxide, carbon black, and low-order titanium dioxide; inorganic purple pigments such as mango violet and Baltic violet; inorganic green pigments such as chromium oxide, chromium hydroxide, and cobalt titanate; inorganic blue pigments such as ultramarine and Prussian blue; pearl pigments such as titanium dioxide-coated mica, titanium dioxide-coated bismuth oxychloride, titanium dioxide-coated talc, colored titanium dioxide-coated mica, bismuth oxychloride, and fish scale foil; and metal powder pigments such as aluminum powder and copper powder.

The method for hydrophobizing these powder components may be any method capable of imparting water repellency, and the method is not particularly limited, but may be, for example, a typical surface treatment method such as a gas phase method, a liquid phase method, an autoclave method, or a mechanochemical method. The hydrophobizing agent is not particularly limited, but may be fatty acid dextrin-treated powder, trimethylsiloxysilicate-treated powder, fluorine-modified trimethylsiloxysilicate-treated powder, methylphenylsiloxysilicate-treated powder, fluorine-modified methylphenylsiloxysilicate-treated powder, dimethylpolysiloxane, diphenylpolysiloxane, methylphenylpolysiloxane, or other low- to high-viscosity oily polysiloxane-treated powder, gum-like polysiloxane-treated powder, methylhydrogenpolysiloxane-treated powder, fluorine-modified methylhydrogenpolysiloxane-treated powder, methyltrichlorosilane, methyltrialkoxysilane, hexamethyldisilane, Examples of such powders include powders treated with organic silyl compounds such as dimethyldichlorosilane, dimethyldialkoxysilane, trimethylchlorosilane, trimethylalkoxysilane, or fluorine-substituted derivatives thereof; powders treated with organic modified silanes such as ethyltrichlorosilane, ethyltrialkoxysilane, propyltrichlorosilane, propyltrialkoxysilane, hexyltrichlorosilane, hexyltrialkoxysilane, long-chain alkyltrichlorosilane, long-chain alkyltriethoxysilane, or fluorine-substituted derivatives thereof; powders treated with amino-modified polysiloxane, powders treated with fluorine-modified polysiloxane, and powders treated with alkyl fluoride phosphate.

The oily component to be blended into the base of the sheet-like cosmetic of the present invention is not particularly limited as long as it is an oily component that can be normally blended into cosmetics, and examples thereof include fats and oils, waxes, hydrocarbon oils, higher alcohols, synthetic ester oils, silicone oils, etc.

Examples of fats and oils include liquid fats and oils such as avocado oil, camellia oil, evening primrose oil, turtle oil, macadamia nut oil, corn oil, mink oil, olive oil, rapeseed oil, egg yolk oil, sesame oil, persic oil, wheat germ oil, sasanqua oil, castor oil, linseed oil, safflower oil, cottonseed oil, perilla oil, soybean oil, peanut oil, tea seed oil, kaya oil, rice bran oil, Chinese tung oil, Japanese tung oil, jojoba oil, germ oil, triglycerin, glycerin trioctanoate, and glycerin triisopalmitate; and solid fats and oils such as cacao butter, coconut oil, horse tallow, hardened coconut oil, palm oil, beef tallow, mutton tallow, hardened beef tallow, palm kernel oil, lard, beef bone fat, Japan wax kernel oil, hardened oil, beef leg fat, Japan wax, and hardened castor oil.

Examples of waxes include beeswax, candelilla wax, cotton wax, carnauba wax, bayberry wax, ivory wax, whale wax, montan wax, bran wax, lanolin, kapok wax, lanolin acetate, liquid lanolin, sugarcane wax, lanolin fatty acid isopropyl, hexyl laurate, reduced lanolin, jojoba wax, hard lanolin, shellac wax, POE lanolin alcohol ether, POE lanolin alcohol acetate, POE cholesterol ether, lanolin fatty acid polyethylene glycol, and POE hydrogenated lanolin alcohol ether.

Examples of hydrocarbon oils include liquid paraffin, ozokerite, squalene, pristane, paraffin, ceresin, squalene, petrolatum, and microcrystalline wax.

Examples of higher alcohols include straight-chain alcohols such as lauryl alcohol, cetyl alcohol, stearyl alcohol, behenyl alcohol, myristyl alcohol, oleyl alcohol, and cetostearyl alcohol; and branched-chain alcohols such as monostearyl glycerin ether (batyl alcohol), 2-decyltetradecinol, lanolin alcohol, cholesterol, phytosterol, hexyldodecanol, isostearyl alcohol, and octyldodecanol.

Examples of synthetic ester oils include isopropyl myristate, cetyl octanoate, octyldodecyl myristate, isopropyl palmitate, butyl stearate, hexyl laurate, myristyl myristate, decyl oleate, hexyldecyl dimethyloctanoate, cetyl lactate, myristyl lactate, lanolin acetate, isocetyl stearate, isocetyl isostearate, cholesteryl 12-hydroxystearate, ethylene glycol di-2-ethylhexylate, dipentaerythritol fatty acid esters, N-alkyl glycol monoisostearate, neopentyl glycol dicaprate, diisostearyl malate, glycerin di-2-heptylundecanoate, trimethylolpropane tri-2-ethylhexylate, trimethylolpropane triisostearate, and pentane tetra-2-ethylhexylate. Erythritol, glycerin tri-2-ethylhexylate, trimethylolpropane triisostearate, cetyl 2-ethylhexanoate, 2-ethylhexyl palmitate, glycerin trimyristate, tri-2-heptylundecanoic acid glyceride, castor oil fatty acid methyl ester, oleic acid oil, acetoglyceride, 2-heptylundecyl palmitate, diisobutyl adipate, N-lauroyl-L-glutamic acid-2-octyldodecyl ester, di-2-heptylundecyl adipate, ethyl laurate, di-2-ethylhexyl sebacate, 2-hexyldecyl myristate, 2-hexyldecyl palmitate, 2-hexyldecyl adipate, diisopropyl sebacate, 2-ethylhexyl succinate, ethyl acetate, butyl acetate, amyl acetate, triethyl citrate, crotamiton (C ₁₃ H ₁₇ NO) and the like.

Examples of silicone oils include linear polysiloxanes such as dimethylpolysiloxane, methylphenylpolysiloxane, and methylhydrogenpolysiloxane other than (F); cyclic polysiloxanes such as decamethylpolysiloxane, dodecamethylpolysiloxane, and tetramethyltetrahydrogenpolysiloxane; silicone resins and silicone rubbers that form a three-dimensional network structure.

The emulsifier is one or more selected from glycerin or polyglycerin fatty acid esters, propylene glycol fatty acid esters, POE sorbitan fatty acid esters, POE sorbit fatty acid esters, POE fatty acid esters, POE alkyl ethers, POE alkyl phenyl ethers, POE-POP alkyl ethers, POE beeswax-lanolin derivatives, alkanolamides, POE propylene glycol fatty acid esters, POE alkylamines, and POE fatty acid amides.

Other possible ingredients other than those listed above include, for example, preservatives (ethylparaben, butylparaben, etc.); anti-inflammatory agents (for example, glycyrrhizic acid derivatives, glycyrrhetinic acid derivatives, salicylic acid derivatives, hinokitiol, zinc oxide, allantoin, etc.); whitening agents other than (B) (for example, saxifrage extract, arbutin, etc.); various extracts (for example, Phellodendron bark, Coptis japonica, Lithospermum root, Peony root, Swertia japonica, Birch, Sage, Loquat, Carrot, Aloe, Mallow, Iris, Grape, Job's tears, Loofah, Lily, Saffron, Cnidium rhizome, Angelica acutiloba, Hypericum perforatum, Ononis, Garlic, Capsicum annuum, Citrus chinensis, Angelica acutiloba, Seaweed, etc.), activators (for example, Lo -al jelly, photosensitizers, cholesterol derivatives, etc.); blood circulation promoters (e.g., nonylic acid valenylamide, nicotinic acid benzyl ester, nicotinic acid β-butoxyethyl ester, capsaicin, zingerone, cantharides tincture, ichthammol, tannic acid, α-borneol, nicotinic acid tocopherol, inositol hexanicotinate, cyclandelate, cinnarizine, tolazoline, acetylcholine, verapamil, cepharanthine, γ-oryzanol, etc.); antioxidants (tocopherol acetate, etc.); antiseborrheic agents (e.g., sulfur, thianthol, etc.); anti-inflammatory agents (e.g., tranexamic acid, thiotaurine, hypotaurine, etc.); ultraviolet absorbing agents, etc. However, the present invention is not limited to these examples.

The present invention will be explained in more detail below with reference to examples, but the present invention is not limited thereto. All blend amounts are in mass % unless otherwise specified.

Examples and Comparative Examples
Bases were prepared according to the formulations shown in Tables 1 to 3 below, and the static and dynamic viscosities of the prepared bases were measured under the following conditions. In addition, the bases were impregnated into nonwoven fabric (mixed fiber consisting of cotton, pulp, and polyethylene terephthalate, basis weight 70 g/ ^m2 , impregnation amount 14.5 times) to prepare sheet-type cosmetics, and the usability was evaluated according to the following criteria.

(Static Viscosity)
The viscosity of the prepared base was measured at a shear rate of 0.05 [1/s] in an atmosphere of 25° C. using an MCR300 (manufactured by Anton-Paar) as a rheometer.

(Kinematic Viscosity)
The prepared base was measured using a VISCOMETER TVB-15 (manufactured by Toki Sangyo Co., Ltd.) with rotors No. 2, No. 3, and No. 4 at a rotation speed of 12 rpm for 1 minute.

(No dripping when applying the sheet)
The prepared sheet-type cosmetic materials were used by 10 expert panelists, who evaluated the lack of dripping when applying the sheet. The evaluation criteria were as follows:
<Evaluation points>
5 points: Very good 4 points: Good 3 points: Average 2 points: Poor 1 point: Very poor <Evaluation criteria>
A+: Average score is 4.5 points or more. A: Average score is 3.5 points or more and less than 4.5 points. B: Average score is 2.5 points or more and less than 3.5 points. C: Average score is less than 2.5 points.

(Sheet adhesion)
The prepared sheet-type cosmetic preparation was used by 10 expert panelists for 10 minutes, and the sheet's adhesiveness was evaluated. The evaluation criteria were as follows:
<Evaluation points>
5 points: Very good 4 points: Good 3 points: Average 2 points: Poor 1 point: Very poor <Evaluation criteria>
A+: Average score is 4.5 points or more. A: Average score is 3.5 points or more and less than 4.5 points. B: Average score is 2.5 points or more and less than 3.5 points. C: Average score is less than 2.5 points.

(The chewy texture after removing the sheet)
The prepared sheet-type cosmetic preparation was used by 10 expert panelists for 10 minutes, and the bouncy feeling after removing the sheet was evaluated. The evaluation criteria were as follows:
<Evaluation points>
5 points: Very good 4 points: Good 3 points: Average 2 points: Poor 1 point: Very poor <Evaluation criteria>
A+: Average score is 4.5 points or more. A: Average score is 3.5 points or more and less than 4.5 points. B: Average score is 2.5 points or more and less than 3.5 points. C: Average score is less than 2.5 points.

(No stickiness after removing the sheet)
The prepared sheet-type cosmetic preparation was used by 10 expert panelists for 10 minutes, and the sheet was then peeled off and evaluated for non-stickiness. The evaluation criteria were as follows:
<Evaluation points>
5 points: Very good 4 points: Good 3 points: Average 2 points: Poor 1 point: Very poor <Evaluation criteria>
A+: Average score is 4.5 points or more. A: Average score is 3.5 points or more and less than 4.5 points. B: Average score is 2.5 points or more and less than 3.5 points. C: Average score is less than 2.5 points.

The formulations and evaluation results are shown in Tables 1 to 3. The commercial names of the main components shown in the tables are listed below.
(PEG-240/Decyltetradeceth-20/HDI) copolymer: Adekanol GT-700 (manufactured by ADEKA Corporation), purity 99.95% by mass
Carbomer: Carbopol 980 (manufactured by Nikko Chemicals Co., Ltd.)
PEG-20 glyceryl isostearate: Emalex GWIS-120 (manufactured by Nippon Emulsion Co., Ltd.)
PEG-60 hydrogenated castor oil: Nikkol HCO-60 (manufactured by Nikko Chemicals Co., Ltd.)
・Dimethicone*1: Silicone KF-96A-6T (manufactured by Shin-Etsu Silicone Co., Ltd.)
Dimethicone*2: Methylpolysiloxane 100CS (dynamic viscosity at 25°C ^100mm2 /s)
Isostearic acid: Isostearic acid SX (manufactured by Koyu Alcohol Kogyo Co., Ltd.)

The sheet-type cosmetics of Examples 1 and 2 shown in Table 1 did not drip when applied to the skin, had good adhesion, and had an excellent bouncy feel after the sheet was peeled off. On the other hand, the sheet-type cosmetics of Comparative Examples 1 and 2, which did not contain (A) hydrophobically modified polyether urethane, dripped significantly when applied to the skin, and did not provide adhesion or a bouncy feel after the sheet was peeled off. Examples 3 and 4 contain ascorbic acid glucoside as a salt-type whitening agent, but like Examples 1 and 2, did not drip when applied to the skin, had good adhesion, and had an excellent bouncy feel after the sheet was peeled off. On the other hand, the sheet-type cosmetics of Comparative Example 3, which did not contain (A) hydrophobically modified polyether urethane, dripped significantly when applied to the skin, and did not provide adhesion or a bouncy feel after the sheet was peeled off.

Examples 5 to 8 shown in Table 2 are examples in which isostearic acid was further added to the formulation of Example 1, and Examples 9 and 10 are examples in which the amount of (A) hydrophobically modified polyether urethane was reduced. In all cases, the sheet did not drip when applied to the skin, had an excellent bouncy feel after being peeled off, and did not feel sticky after being peeled off despite its high adhesion. In addition, because the static viscosity was high but the dynamic viscosity was low, it was possible to make the sheet not sticky on the skin after being peeled off.

Example 11 shown in Table 3 is an example in which the amount of active agent was reduced, Examples 12 and 13 are examples in which polyoxyethylene hydrogenated castor oil was added, Example 14 is an example in which dimethicone with a kinetic viscosity of 50 ^mm2 /s or more was added, Example 15 is an example in which diglycerin was added, and Example 16 is an example in which dipropylene glycol was added. These sheets also did not drip when applied to the skin, had an excellent bouncy feeling after the sheet was peeled off, and did not feel sticky after peeling off despite the sheet's high adhesion.

Claims (11)

at least,
(A) a hydrophobically modified polyether urethane;
(B) a salt-type whitening agent;
(E) isostearic acid,
A sheet-like cosmetic preparation comprising a nonwoven fabric impregnated with a base comprising:
A sheet-form cosmetic preparation , in which the mass ratio of (E) isostearic acid to (A) hydrophobically modified polyether urethane is 0.3 to 1.6 . The sheet-form cosmetic according to claim 1, wherein the salt-type whitening agent (B) is 4-methoxysalicylic acid potassium salt or ascorbic acid glucoside. The sheet-form cosmetic according to claim 1 or 2, wherein the mass ratio of the hydrophobically modified polyether urethane (A) to the salt-type whitening agent (B) is 0.2 to 1. The sheet-form cosmetic according to claim 1, 2 or 3, further comprising (C) a carboxyvinyl polymer. The sheet-form cosmetic according to any one of claims 1 to 4, further comprising (D) at least one of polyoxyethylene fatty acid glyceryl or polyoxyethylene hydrogenated castor oil. 6. The sheet-form cosmetic material according to any one of claims 1 to 5 , wherein the hydrophobically modified polyether urethane (A) is a (PEG-240/decyltetradeceth-20/HDI) copolymer. 6. The sheet-form cosmetic material according to claim 5 , wherein the (D) polyoxyethylene fatty acid glyceryl is PEG-20 glyceryl (mono)isostearate. 6. The sheet-form cosmetic material according to claim 5 , wherein the polyoxyethylene hydrogenated castor oil (D) is PEG 60 hydrogenated castor oil. The sheet-form cosmetic according to any one of claims 1 to 8 , further comprising (F) diglycerin in an amount of 0.2 to 4 mass% based on the total amount of the base. 10. The sheet-form cosmetic preparation according to any one of claims 1 to 9 , further comprising (G) dimethicone having a kinetic viscosity at 25°C of 50 mm ² /s or more in an amount of 2 to 5% by mass based on the total amount of the base. The sheet-like cosmetic material according to any one of claims 1 to 10 , wherein the nonwoven fabric contains polyester-based fibers and cellulosic fibers.