JPS5815459B2 - architectural spraying material - Google Patents
architectural spraying materialInfo
- Publication number
- JPS5815459B2 JPS5815459B2 JP55059268A JP5926880A JPS5815459B2 JP S5815459 B2 JPS5815459 B2 JP S5815459B2 JP 55059268 A JP55059268 A JP 55059268A JP 5926880 A JP5926880 A JP 5926880A JP S5815459 B2 JPS5815459 B2 JP S5815459B2
- Authority
- JP
- Japan
- Prior art keywords
- aluminum hydroxide
- waste paper
- architectural
- sludge
- gelled
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 238000005507 spraying Methods 0.000 title claims 2
- 239000000463 material Substances 0.000 title description 8
- WNROFYMDJYEPJX-UHFFFAOYSA-K aluminium hydroxide Chemical compound [OH-].[OH-].[OH-].[Al+3] WNROFYMDJYEPJX-UHFFFAOYSA-K 0.000 claims description 30
- 239000010802 sludge Substances 0.000 claims description 11
- 239000000835 fiber Substances 0.000 claims description 8
- 239000000853 adhesive Substances 0.000 claims description 4
- 230000001070 adhesive effect Effects 0.000 claims description 4
- 238000001035 drying Methods 0.000 claims description 2
- 238000002156 mixing Methods 0.000 claims description 2
- 238000003756 stirring Methods 0.000 claims 1
- 239000002023 wood Substances 0.000 claims 1
- 239000010893 paper waste Substances 0.000 description 15
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 5
- 239000004035 construction material Substances 0.000 description 3
- 238000009413 insulation Methods 0.000 description 3
- 230000035699 permeability Effects 0.000 description 3
- 239000007921 spray Substances 0.000 description 3
- 239000002699 waste material Substances 0.000 description 3
- NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 description 2
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 2
- DQXBYHZEEUGOBF-UHFFFAOYSA-N but-3-enoic acid;ethene Chemical compound C=C.OC(=O)CC=C DQXBYHZEEUGOBF-UHFFFAOYSA-N 0.000 description 2
- 230000015271 coagulation Effects 0.000 description 2
- 238000005345 coagulation Methods 0.000 description 2
- 239000005038 ethylene vinyl acetate Substances 0.000 description 2
- 239000000203 mixture Substances 0.000 description 2
- 229920001200 poly(ethylene-vinyl acetate) Polymers 0.000 description 2
- 239000000843 powder Substances 0.000 description 2
- 229920005989 resin Polymers 0.000 description 2
- 239000011347 resin Substances 0.000 description 2
- 238000004062 sedimentation Methods 0.000 description 2
- 239000004925 Acrylic resin Substances 0.000 description 1
- 229920000178 Acrylic resin Polymers 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 229910000147 aluminium phosphate Inorganic materials 0.000 description 1
- 239000004568 cement Substances 0.000 description 1
- 230000001112 coagulating effect Effects 0.000 description 1
- 238000010276 construction Methods 0.000 description 1
- 239000000839 emulsion Substances 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-M hydroxide Chemical compound [OH-] XLYOFNOQVPJJNP-UHFFFAOYSA-M 0.000 description 1
- TWNQGVIAIRXVLR-UHFFFAOYSA-N oxo(oxoalumanyloxy)alumane Chemical compound O=[Al]O[Al]=O TWNQGVIAIRXVLR-UHFFFAOYSA-N 0.000 description 1
- 229910052710 silicon Inorganic materials 0.000 description 1
- 239000010703 silicon Substances 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 239000010784 textile waste Substances 0.000 description 1
- 230000003313 weakening effect Effects 0.000 description 1
Classifications
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02W—CLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
- Y02W30/00—Technologies for solid waste management
- Y02W30/50—Reuse, recycling or recovery technologies
- Y02W30/91—Use of waste materials as fillers for mortars or concrete
Landscapes
- Building Environments (AREA)
- Porous Artificial Stone Or Porous Ceramic Products (AREA)
Description
【発明の詳細な説明】
本発明は、有機繊維および水酸化アルミニウムを主材と
する建築用吹付は材に関する。DETAILED DESCRIPTION OF THE INVENTION The present invention relates to a sprayed construction material based on organic fibers and aluminum hydroxide.
アルマイト加工処理時には水酸化アルミニウムスラッジ
が大量に生成されるが、この水酸化アルミニウムスラッ
ジはゲル状であって有効な利用、処理技術は開発されて
おらず、単なる工場廃棄物として埋立地や海洋等に投棄
されていた。A large amount of aluminum hydroxide sludge is generated during alumite processing, but since this aluminum hydroxide sludge is in the form of a gel, effective utilization and treatment technology has not been developed, and it is simply discarded as factory waste and disposed of in landfills or in the ocean. had been dumped.
しかし、水酸化アルミニウムスラッジはゲル状であり、
濾水性、透水性が不良で乾燥固化しにくく、投棄された
水酸化アルミニウムスラッジは地盤の弱体化或いは海洋
汚染を惹起するため、その処理に苦慮しているのが業界
の実状であった。However, aluminum hydroxide sludge is gel-like;
The industry has been struggling to dispose of discarded aluminum hydroxide sludge, which has poor drainage and permeability and is difficult to dry and solidify, weakening the ground and polluting the ocean.
そこで、本出願人は先きにアルマイト加工処理時に大量
に生成される水酸化アルミニウムスラッジの有効利用を
図るために、これを主材とする新規な建築用材を提案し
たが(特願昭53−99914号)、本発明は水酸化ア
ルミニウムスラッジの利用範囲の一層の拡大を図るため
になされたものであって、水酸化アルミニウムを主材と
してこれに屑綿状故紙等の有機繊維を混入し、これを接
着剤とともに吹付は機にて倉庫の壁や天井等に吹き付け
るようにした建築用吹付は材を提供することを目的とす
るものである。Therefore, in order to effectively utilize the aluminum hydroxide sludge that is generated in large quantities during alumite processing, the applicant proposed a new construction material that uses aluminum hydroxide sludge as its main material. No. 99914), the present invention was made in order to further expand the scope of use of aluminum hydroxide sludge. This is sprayed together with an adhesive using a spray machine to spray onto the walls and ceilings of warehouses for the purpose of providing materials for construction use.
細ち、近年エネルギー節約のために保温断熱硅に秀れた
低床な壁材や天井材の開発が切望されている所であるが
、本発明は従来は単なる工場廃棄物にすぎなかった水酸
化アルミニウムスラッジを有効利用して、壁や天井の吹
付は材として要求される保温断熱性、不燃性、防音性等
を満足させる吹付は材を提供することを目的とするもの
であり、殊にゲル状水酸化アルミニウムが屑綿状故紙や
繊維屑等の有機繊維を一定のPH範囲内において容易に
包み込むようにして凝結する性質があり、かかる性質に
より可燃性の有機繊維の不燃化が達成されることに着目
してなされたものである。In recent years, there has been a strong need for the development of low-profile wall and ceiling materials that are excellent at heat-insulating silicon in order to save energy. The purpose of this project is to effectively utilize aluminum oxide sludge to provide a material for walls and ceilings that satisfies the heat-retaining properties, non-combustibility, soundproofing properties, etc. Gelled aluminum hydroxide has the property of easily enveloping and condensing organic fibers such as fluffy waste paper and fiber waste within a certain pH range, and this property makes flammable organic fibers nonflammable. This was done with a focus on
以下、本発明を実施例に沿って説明する。Hereinafter, the present invention will be explained along with examples.
故紙を解きほぐして屑綿状としたものを水槽中に投入し
、更にゲル状の水酸化アルミニウムを加えて攪拌する。The waste paper is loosened and turned into fluff, and then put into a water tank, and gelled aluminum hydroxide is added and stirred.
このとき、PHは6〜7であり、PHがこのように太き
いと膠着物質であるゲル状水酸化アルミニウムは屑綿状
故紙を十分に包み込むことなく短時間で凝集沈降する性
質がある。At this time, the pH is 6 to 7, and when the pH is high, gelled aluminum hydroxide, which is an adhesive substance, has the property of coagulating and sedimenting in a short period of time without fully enveloping the fluffy waste paper.
そこで、硫酸またはリン酸等の酸を加えてPHを4〜6
に低下させる。Therefore, add acid such as sulfuric acid or phosphoric acid to adjust the pH to 4-6.
decrease to.
すると水酸化アルミニウムの凝集沈降は遅くなり、水槽
中に広く分散して長時間浮遊し、その間に屑綿状故紙を
十分に包み込んで凝集することとなる。As a result, the coagulation and sedimentation of aluminum hydroxide slows down, and it is widely dispersed in the water tank and floats for a long time, during which time it fully envelops the fluffy waste paper and coagulates.
尚、PHが6〜7であってもゲル状水酸化アルミニウム
は屑綿状故紙を包み込むことができるが、上記したよう
にPHが6〜7では凝集沈降速度が早いため、十分に屑
綿状故紙を包み込むことはできない。In addition, even if the pH is 6 to 7, gelled aluminum hydroxide can wrap waste paper in the form of waste paper, but as mentioned above, at a pH of 6 to 7, the rate of coagulation and sedimentation is fast, so it is not enough to wrap the waste paper in the form of waste paper. You cannot wrap up waste paper.
従ってPHは4〜6に低下させることが望ましいのであ
る。Therefore, it is desirable to lower the pH to 4-6.
次に、水酸化アルミニウムスラッジを乾燥させて生成し
た粉末状の水酸化アルミニウムを投入して攪拌する。Next, powdered aluminum hydroxide produced by drying the aluminum hydroxide sludge is added and stirred.
すると、粉末状の水酸化アルミニウムはゲル状の水酸化
アルミニウムと混合され、このようにして生成される故
紙と水酸化アルミニウムの混合物は濾水性、透水性が大
巾に改善されて比較的容易に乾燥固化するようになるの
である。Then, the powdered aluminum hydroxide is mixed with the gelled aluminum hydroxide, and the mixture of waste paper and aluminum hydroxide produced in this way has greatly improved freeness and water permeability, and can be processed relatively easily. It becomes dry and solidified.
尚、上記した屑綿状故紙、ゲル状水酸化アツベニウム、
粉末状水酸化アルミニウムは下記の割合にて配合するこ
とが望ましい。In addition, the above-mentioned fluffy waste paper, gelatinous atbenium hydroxide,
It is desirable to mix powdered aluminum hydroxide in the following proportions.
故紙(屑綿状) 15〜25%水酸化
アルミニウム(ゲル状) 3〜5%水酸化アルミニ
ウム(粉末状) 70〜80%またその無水換算した
具体的配合例は下記のとおりである、その倍数量を計量
猷合する。Waste paper (fluffy) 15-25% Aluminum hydroxide (gel) 3-5% Aluminum hydroxide (powder) 70-80% The specific blending examples calculated on an anhydrous basis are as follows. Weigh and match the quantity.
故紙(屑綿状) 2.5kg(査5%)水酸化
アルミニウム(ゲル状) 0.5kg(5%)水酸化ア
ルミニウム(粉末状) 7.0ky(70%)次に上記
のようにして混合生成されたものを屑綿して繊維状とな
し、これをセメントガン等の吹付は機械によって接着材
とともに倉庫や家屋の壁や天井等に1m2当り400〜
500g程度吹付ける。Waste paper (fluffy) 2.5kg (5%) Aluminum hydroxide (gel) 0.5kg (5%) Aluminum hydroxide (powder) 7.0ky (70%) Next, mix as above. The generated material is turned into fibrous waste, which is then sprayed with a cement gun or other machine onto the walls and ceilings of warehouses and houses at a rate of 400 to 100 ml per square meter.
Spray about 500g.
この接着材としてはアクリル系樹脂やエチレン酢酸ビニ
ール系樹脂が望ましく、具体的には例えば樹脂量50%
のエチレン酢酸ビニール(エマルジョン)を水にて15
〜20%に稀釈して使用する。As this adhesive material, acrylic resin or ethylene vinyl acetate resin is preferable, and specifically, for example, the amount of resin is 50%.
of ethylene vinyl acetate (emulsion) in water
Use diluted to ~20%.
以上説明したように、本発明は従来キの処理に苦慮して
いた水酸化アルミニウムスラッジが、故紙等の可燃性の
有機繊維を包み込むようにして凝結して不燃化する性質
があることに着目し、これの有効利用を達成したもので
あって;従来保温性、防音性、軽量性等の秀れた性質を
有するも、可燃性であるために建築用材としてその使途
が限られていた故紙、繊維屑等の有機繊維を不燃性、耐
熱性の水酸化アルミ−ラムで包み込ん辱凝結させるよう
にしているから、有機繊維の有する秀れた諸性質を生か
しつつ、その欠点である可燃性を克服しているのである
。As explained above, the present invention focuses on the fact that aluminum hydroxide sludge, which had been difficult to dispose of in the past, has the property of condensing to envelop flammable organic fibers such as waste paper and making it non-combustible. , which has achieved the effective use of waste paper, which previously had excellent properties such as heat retention, sound insulation, and lightness, but its use as a construction material was limited due to its flammability. Organic fibers such as textile waste are wrapped in non-combustible, heat-resistant aluminum hydroxide ram and allowed to coagulate, making use of the excellent properties of organic fibers while overcoming their drawback of flammability. That's what I'm doing.
また、乾燥固化が困難であるゲル状水酸化アルミニウム
に粉末状水酸化アルミニウムを大量に混入するようにし
ているので、濾水性;透水性が大巾に改善されており、
従って壁や天井等に吹付けた場合、比較的短時間で乾燥
固化するのである。In addition, since a large amount of powdered aluminum hydroxide is mixed into the gelled aluminum hydroxide, which is difficult to dry and solidify, the freeness and water permeability are greatly improved.
Therefore, when sprayed on walls, ceilings, etc., it dries and solidifies in a relatively short time.
依って、本発明によれば保温性、断熱性、防音性、軽量
性等に秀れた吹付は材が低コストにて大量に生産できる
のである。Therefore, according to the present invention, a sprayed material with excellent heat retention, heat insulation, sound insulation, lightness, etc. can be produced in large quantities at low cost.
Claims (1)
た後、これにゲル状水酸化アルミニウムスラッジを乾燥
させて生成した粉末状水酸化アルミニウムを加えて混合
攪拌し、これに接着材を添加することを特徴とする建築
用吹付は材。1. After mixing and stirring organic fibers and gelled aluminum hydroxide, powdered aluminum hydroxide produced by drying gelled aluminum hydroxide sludge is added, mixed and stirred, and an adhesive is added to this. The characteristic architectural spraying is wood.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP55059268A JPS5815459B2 (en) | 1980-04-30 | 1980-04-30 | architectural spraying material |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP55059268A JPS5815459B2 (en) | 1980-04-30 | 1980-04-30 | architectural spraying material |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPS56155054A JPS56155054A (en) | 1981-12-01 |
| JPS5815459B2 true JPS5815459B2 (en) | 1983-03-25 |
Family
ID=13108447
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP55059268A Expired JPS5815459B2 (en) | 1980-04-30 | 1980-04-30 | architectural spraying material |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPS5815459B2 (en) |
-
1980
- 1980-04-30 JP JP55059268A patent/JPS5815459B2/en not_active Expired
Also Published As
| Publication number | Publication date |
|---|---|
| JPS56155054A (en) | 1981-12-01 |
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