JPS5847435B2 - grinding paste - Google Patents
grinding pasteInfo
- Publication number
- JPS5847435B2 JPS5847435B2 JP8891776A JP8891776A JPS5847435B2 JP S5847435 B2 JPS5847435 B2 JP S5847435B2 JP 8891776 A JP8891776 A JP 8891776A JP 8891776 A JP8891776 A JP 8891776A JP S5847435 B2 JPS5847435 B2 JP S5847435B2
- Authority
- JP
- Japan
- Prior art keywords
- acid
- abrasive grains
- grinding paste
- mixed
- paste
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 239000002253 acid Substances 0.000 claims description 17
- 239000006061 abrasive grain Substances 0.000 claims description 11
- 150000002596 lactones Chemical class 0.000 claims description 4
- 150000003839 salts Chemical class 0.000 claims description 3
- 150000002148 esters Chemical class 0.000 claims description 2
- 238000001179 sorption measurement Methods 0.000 description 6
- 150000007513 acids Chemical class 0.000 description 4
- 230000000052 comparative effect Effects 0.000 description 4
- 230000000694 effects Effects 0.000 description 4
- 239000002609 medium Substances 0.000 description 4
- 239000002245 particle Substances 0.000 description 4
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 3
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 3
- 229910003460 diamond Inorganic materials 0.000 description 3
- 239000010432 diamond Substances 0.000 description 3
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 3
- JEIPFZHSYJVQDO-UHFFFAOYSA-N iron(III) oxide Inorganic materials O=[Fe]O[Fe]=O JEIPFZHSYJVQDO-UHFFFAOYSA-N 0.000 description 3
- 238000005498 polishing Methods 0.000 description 3
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 3
- HZAXFHJVJLSVMW-UHFFFAOYSA-N 2-Aminoethan-1-ol Chemical class NCCO HZAXFHJVJLSVMW-UHFFFAOYSA-N 0.000 description 2
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 2
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 2
- MCMNRKCIXSYSNV-UHFFFAOYSA-N Zirconium dioxide Chemical compound O=[Zr]=O MCMNRKCIXSYSNV-UHFFFAOYSA-N 0.000 description 2
- 239000000853 adhesive Substances 0.000 description 2
- 230000001070 adhesive effect Effects 0.000 description 2
- 125000004432 carbon atom Chemical group C* 0.000 description 2
- 238000010586 diagram Methods 0.000 description 2
- 229910002804 graphite Inorganic materials 0.000 description 2
- 239000010439 graphite Substances 0.000 description 2
- 239000000463 material Substances 0.000 description 2
- 229910052751 metal Inorganic materials 0.000 description 2
- 239000002184 metal Substances 0.000 description 2
- 239000007787 solid Substances 0.000 description 2
- 239000000243 solution Substances 0.000 description 2
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 description 1
- 239000004593 Epoxy Substances 0.000 description 1
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 1
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 description 1
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 1
- 230000001476 alcoholic effect Effects 0.000 description 1
- 150000001336 alkenes Chemical class 0.000 description 1
- 125000000217 alkyl group Chemical group 0.000 description 1
- 239000000956 alloy Substances 0.000 description 1
- 229910045601 alloy Inorganic materials 0.000 description 1
- 150000001408 amides Chemical class 0.000 description 1
- 150000001412 amines Chemical class 0.000 description 1
- 239000007864 aqueous solution Substances 0.000 description 1
- 239000011230 binding agent Substances 0.000 description 1
- 239000011575 calcium Substances 0.000 description 1
- 229910052791 calcium Inorganic materials 0.000 description 1
- YACLQRRMGMJLJV-UHFFFAOYSA-N chloroprene Chemical compound ClC(=C)C=C YACLQRRMGMJLJV-UHFFFAOYSA-N 0.000 description 1
- 239000002612 dispersion medium Substances 0.000 description 1
- 238000005553 drilling Methods 0.000 description 1
- 238000010894 electron beam technology Methods 0.000 description 1
- 239000012530 fluid Substances 0.000 description 1
- 239000004519 grease Substances 0.000 description 1
- 229910052742 iron Inorganic materials 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 239000000314 lubricant Substances 0.000 description 1
- 239000011777 magnesium Substances 0.000 description 1
- 229910052749 magnesium Inorganic materials 0.000 description 1
- 239000002075 main ingredient Substances 0.000 description 1
- 239000007769 metal material Substances 0.000 description 1
- 238000000034 method Methods 0.000 description 1
- 229910052961 molybdenite Inorganic materials 0.000 description 1
- CWQXQMHSOZUFJS-UHFFFAOYSA-N molybdenum disulfide Chemical compound S=[Mo]=S CWQXQMHSOZUFJS-UHFFFAOYSA-N 0.000 description 1
- 229910052982 molybdenum disulfide Inorganic materials 0.000 description 1
- 125000000896 monocarboxylic acid group Chemical group 0.000 description 1
- JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 description 1
- 239000011591 potassium Substances 0.000 description 1
- 229910052700 potassium Inorganic materials 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 239000011734 sodium Substances 0.000 description 1
- 229910052708 sodium Inorganic materials 0.000 description 1
- 159000000000 sodium salts Chemical class 0.000 description 1
- 229920003002 synthetic resin Polymers 0.000 description 1
- 239000000057 synthetic resin Substances 0.000 description 1
Description
【発明の詳細な説明】
本発明は工具と被加工物、摺合せ研摩する被加工物同志
間等の加工部分に供給介在させて加工する研削ペースト
に関する。DETAILED DESCRIPTION OF THE INVENTION The present invention relates to a grinding paste that is supplied to and interposed between a tool and a workpiece, or between workpieces to be rubbed and polished.
従来、超音波振動で穴明け、切断、研削、彫刻などを行
なうとき、加工部分に砥粒を適当な加工液に混合して供
給するようにしているが、研摩効果が高くない。Conventionally, when performing drilling, cutting, grinding, engraving, etc. using ultrasonic vibration, abrasive grains are mixed with a suitable processing fluid and supplied to the processing part, but the polishing effect is not high.
本発明は砥粒の分散媒体として吸着、親水性等が高い特
殊な酸を主剤として利用したものである。The present invention utilizes a special acid with high adsorption, hydrophilicity, etc. as a main ingredient as a dispersion medium for abrasive grains.
かSる酸は、例えばその分子構造が、
であり、COOH基、OH基等多数の極性基を有して極
めて吸着性が高く、親水、親油性の高い酸であり、これ
が粒子表面に強く吸着して分散せしめる。For example, an acid having a molecular structure of Adsorb and disperse.
この酸の構造上の特徴は一級、二級、三級の3個のCO
OH基を有し、三級のOH基を有する。The structural characteristics of this acid are three COs: primary, secondary, and tertiary.
It has an OH group, and it has a tertiary OH group.
また長鎖アルキル基を持って炭素数が大きい(10以上
)ものである。It also has a long chain alkyl group and has a large number of carbon atoms (10 or more).
この酸は通常粉末であり、メチルアルコールに良く溶解
するので、アルコール溶液として利用し、また−2.5
COONa以上のナトリウムで溶解度が増大しナトリウ
ム塩として、またカリウム、カルシウム、マグネシウム
等の塩として利用し、エステル化して利用する。This acid is usually in powder form and dissolves well in methyl alcohol, so it can be used as an alcoholic solution.
Solubility increases with sodium COONa or higher, and it is used as a sodium salt, or as a salt of potassium, calcium, magnesium, etc., and esterified.
砥粒は通常利用されているZrO2,B4C,SiC,
Al203,BN,ダイヤモンド等の硬質粒子が用いら
れる。Abrasive grains are commonly used ZrO2, B4C, SiC,
Hard particles such as Al203, BN, and diamond are used.
これらの砥粒は単独で、あるいは数種混合して用い、こ
れを10〜50%の体積比で前記酸の媒体と混合する。These abrasive grains may be used alone or in combination, and mixed with the acid medium at a volume ratio of 10 to 50%.
また場合によってはW2S,MoS2,BN等の固体潤
滑剤を混合利用することもできる。In some cases, solid lubricants such as W2S, MoS2, and BN may be used in combination.
またエポキシ、アミン、アミド、クロロブレン、レジノ
イド、ハロゲン化オレフイン、エタノールアミン等の合
成樹fJ訳接着剤を混合利用し、また電子線照射して共
重合して利用することができる。In addition, synthetic resin adhesives such as epoxy, amine, amide, chloroprene, resinoid, halogenated olefin, and ethanolamine can be mixed and used, and copolymerized by electron beam irradiation.
実施゛例 1
砥粒として400メッシュのダイヤモンド粒子を用い、
前記した3−ビドロキシー3,4デイカルボキシ・ペン
タデイカノイソクアシドをNaOHに溶した溶液に混合
する。Example 1 Using 400 mesh diamond particles as abrasive grains,
The 3-hydroxy 3,4 dicarboxy pentadecanoisoquaside described above is mixed into a solution in NaOH.
媒体はこの酸を400mに氷を加え、これにダイヤ粒を
体積比25多混合して、よく混練して研削ペーストをつ
くった。As a medium, ice was added to 400 m of this acid, and diamond grains were mixed therein at a volume ratio of 25, and thoroughly kneaded to prepare a grinding paste.
この場合、酸の有する強い吸着力によって、粒子表面に
酸が全体に吸着して皮膜をつくり、濡れ性を高め、全体
が均一に混合され、粒子は媒体全体に均一分散した研削
ペーストが得られた。In this case, due to the strong adsorption power of the acid, the acid is completely adsorbed to the surface of the particles, forming a film, increasing wettability, and making it possible to obtain a grinding paste that is evenly mixed throughout and the particles are uniformly dispersed throughout the medium. Ta.
次にこの研削ペーストによる研削加工は、0.2朋φの
高抗張力線の表面に付着してPOCOグラファイ(ポコ
社製商品名)切削において、極めて高性能であった。Next, the grinding process using this grinding paste exhibited extremely high performance in cutting POCO Graphite (trade name, manufactured by Poco Corporation) by adhering to the surface of a high tensile strength wire of 0.2 mm diameter.
板厚4QmmのPOCOグラファイト切削時の比較性能
は第1図の通りであった。The comparative performance when cutting POCO graphite with a plate thickness of 4Qmm is shown in Figure 1.
図において横軸は比較した砥粒媒体であり、この比較テ
ストから本発明のものは砥粒の飛散が少なく加工効果が
高いことがわかる。In the figure, the horizontal axis indicates the compared abrasive grain media, and it can be seen from this comparative test that the one of the present invention has less scattering of abrasive grains and has a high processing effect.
これは酸の吸着力によって強いファンデルワールスカを
作用して砥粒を工具に吸着させ、且つ加工母材に濡れ性
を高めて砥粒を近接々触させる等、媒体の酸の吸着力に
よって研削性を高める。This is because the adsorption power of the acid acts as a strong van der Waalska to adsorb the abrasive grains to the tool, and increases the wettability of the workpiece material to bring the abrasive grains into close contact. enhance sexuality.
また濡れ性を良くすることにより加工部外への飛散を防
止する。In addition, by improving the wettability, scattering outside the processed area is prevented.
また第2図は鉄材等の金属面の研摩に使用したときの研
摩面の錆の発生状態を比較したものである。Moreover, FIG. 2 compares the state of rust on the polished surface when used for polishing metal surfaces such as iron materials.
前記酸を用いた本発明では媒体中に水を混合していても
、油(ケコシン)使用のものと同様、全く錆の発生はみ
られなかった。In the present invention using the above-mentioned acid, no rust was observed even if water was mixed in the medium, as in the case using oil (Kekoshin).
これは酸の吸着性、親水性により砥粒によって研摩され
た無垢の面を、研摩と同時に酸が強く吸着して被覆して
しまい、研摩面を完全に水、空気等から保護する、この
酸の吸着効果によるものである。This acid strongly adsorbs and coats the solid surface polished by abrasive grains due to its adsorption and hydrophilic properties, completely protecting the polished surface from water, air, etc. This is due to the adsorption effect of
このように本発明のペーストは錆の発生が必配なく、研
削性も高いから任意の金属、合金、その他非金属材の研
摩加工に利用でき、効果的である。As described above, the paste of the present invention does not necessarily cause rust and has high grindability, so it can be effectively used for polishing any metal, alloy, or other non-metallic material.
またペーストは水、その他水溶液を混ぜて液状にも、ま
た粘結剤を混ぜてグリース状にしたり、任意に使用目的
に応じて硬度調整して使用できる。Further, the paste can be used in a liquid form by mixing with water or other aqueous solution, or in a grease form by mixing with a binder, or by adjusting the hardness as desired depending on the purpose of use.
なお、前記実施例のように工具に付着させて利用する場
合はペースト中に接着剤を混合しておけば更に良く、接
着して更に焼付けて利用することもできる。In addition, when using it by adhering it to a tool as in the above embodiment, it is better to mix an adhesive into the paste, and it is also possible to use it by adhering it and then baking it.
本発明に利用される酸は、前記した酸とは構造が一致し
なくても、3個のCOOH基を有し、1個のOH基を持
ち、炭素数が10以上の酸であれば、前記説明の如く極
性基の吸着効果により実用上有効である。Even if the acid used in the present invention does not have the same structure as the above-mentioned acids, as long as it has three COOH groups, one OH group, and has 10 or more carbon atoms, As explained above, it is practically effective due to the adsorption effect of polar groups.
また酸はラクトン型構造のものも同様に有効であり、ま
た前記したように酸またはラクトンの塩類、酸またはラ
クトンのエステル等が実用される。Furthermore, acids having a lactone type structure are equally effective, and as mentioned above, salts of acids or lactones, esters of acids or lactones, etc. are practically used.
第1図は本発明と従来例の比較性能図、第2図はまた他
の比較性能図である。FIG. 1 is a comparative performance diagram of the present invention and a conventional example, and FIG. 2 is another comparative performance diagram.
Claims (1)
力ノイツク酸またはラクトン、あるいはその塩、エステ
ル、その他誘導体の少なくとも1種を主体とし、これと
研摩粒を混合してなる研削ペースト。1. A grinding paste consisting mainly of at least one kind of 3-hydroxy-3,4-dicarboxypentadenic acid or lactone, or its salts, esters, and other derivatives, and mixed with abrasive grains.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP8891776A JPS5847435B2 (en) | 1976-07-26 | 1976-07-26 | grinding paste |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP8891776A JPS5847435B2 (en) | 1976-07-26 | 1976-07-26 | grinding paste |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPS5314488A JPS5314488A (en) | 1978-02-09 |
| JPS5847435B2 true JPS5847435B2 (en) | 1983-10-22 |
Family
ID=13956265
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP8891776A Expired JPS5847435B2 (en) | 1976-07-26 | 1976-07-26 | grinding paste |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPS5847435B2 (en) |
Families Citing this family (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH07114994B2 (en) * | 1990-02-17 | 1995-12-13 | 新日本製鐵株式会社 | Coating steel plate baking equipment |
-
1976
- 1976-07-26 JP JP8891776A patent/JPS5847435B2/en not_active Expired
Also Published As
| Publication number | Publication date |
|---|---|
| JPS5314488A (en) | 1978-02-09 |
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