JPS5911527B2 - Shaped dry ice manufacturing equipment - Google Patents
Shaped dry ice manufacturing equipmentInfo
- Publication number
- JPS5911527B2 JPS5911527B2 JP56170563A JP17056381A JPS5911527B2 JP S5911527 B2 JPS5911527 B2 JP S5911527B2 JP 56170563 A JP56170563 A JP 56170563A JP 17056381 A JP17056381 A JP 17056381A JP S5911527 B2 JPS5911527 B2 JP S5911527B2
- Authority
- JP
- Japan
- Prior art keywords
- dry ice
- shutter
- cylinder
- snow
- regular
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B32/00—Carbon; Compounds thereof
- C01B32/50—Carbon dioxide
- C01B32/55—Solidifying
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Inorganic Chemistry (AREA)
- Carbon And Carbon Compounds (AREA)
- Separation By Low-Temperature Treatments (AREA)
Description
【発明の詳細な説明】
本発明は液状炭酸ガスを原料として定形ドライアイスを
製造する装置に関する。DETAILED DESCRIPTION OF THE INVENTION The present invention relates to an apparatus for producing shaped dry ice using liquid carbon dioxide as a raw material.
即ち、ドライアイスメーカがレストラン・アイスクリー
ム工場・菓子屋等を対称に定形ドライアイスを量産する
のに使用する定形ドライアイス製造装置に関するもので
ある。That is, the present invention relates to a shaped dry ice manufacturing apparatus used by a dry ice maker to mass-produce shaped dry ice for restaurants, ice cream factories, confectionery shops, and the like.
定形ドライアイス製造装置のうち、本願発明に係る装置
に近似している従来装置は、英国特許慮433018号
公報(「固形ドライアイス製造プレスにおける改良」)
に記載されており、その概要を第7図と第8図に示す。Among regular shaped dry ice manufacturing devices, a conventional device similar to the device according to the present invention is disclosed in British Patent No. 433018 (“Improvements in solid dry ice manufacturing press”).
The outline is shown in Fig. 7 and Fig. 8.
チャージングシリンダ50の頂部のノズル51から液状
炭酸ガスを噴出させて断熱膨張により雪状ドライアイス
を発生させてチャージングシリンダ50内に充満し、シ
ャッタ52を開いてこの雪状ドライアイスをプレスシリ
ンダ53内に重力落下させた後、再びシャッタ52を閉
じて、プレスプランジャ55で圧縮してドライアイスブ
ロック57に成形する。Liquid carbon dioxide is ejected from the nozzle 51 at the top of the charging cylinder 50 to generate snow-like dry ice through adiabatic expansion, which fills the charging cylinder 50. The shutter 52 is opened and the snow-like dry ice is transferred to the press cylinder. After falling into the dry ice block 53 by gravity, the shutter 52 is closed again, and the dry ice block 57 is compressed by the press plunger 55 and formed into a dry ice block 57.
この時プレスシリンダ53内での圧縮と並行してチャー
ジングシリンダ50内へは次のサイクルの雪状ドライア
イスを充填する。At this time, in parallel with the compression in the press cylinder 53, the charging cylinder 50 is filled with snow-like dry ice for the next cycle.
その後プレスシリンダ53をその下部の円筒状ピストン
58で下降させることにより、プレスプランジャ55上
のドライアイスブロック57をプレスシリンダ53外に
露出させて外部へ取出すようにしたものである。Thereafter, the press cylinder 53 is lowered by the cylindrical piston 58 at its lower part, so that the dry ice block 57 on the press plunger 55 is exposed outside the press cylinder 53 and taken out.
しかしながら、この従来装置には次のような諸欠点が残
っている。However, this conventional device still has the following drawbacks.
(1)プレスシリンダ53内からドライアイスブロック
57を取り出す為に、プレスシリンダ53内体を昇降さ
せるので、円筒状ピストン58の駆動手段が不可欠とな
るから、構造が複雑化し、耐久性も低下し、高価になる
。(1) In order to take out the dry ice block 57 from inside the press cylinder 53, the inside of the press cylinder 53 is raised and lowered, so a driving means for the cylindrical piston 58 is essential, which complicates the structure and reduces durability. , becomes expensive.
(2)自動運転する場合、プレスプランジャ55上に残
ったドライアイスブロック57を取り出す為の移送手段
を付設する必要があるから、装置の構造が更に複雑化す
る。(2) In the case of automatic operation, it is necessary to provide a transfer means for taking out the dry ice block 57 remaining on the press plunger 55, which further complicates the structure of the apparatus.
(3)プレスシリンダ53内に供給した雪状ドライアイ
スを圧縮固結するので、大形のドライアイスブロック5
7を製造しようとすれば、プレスシリンダ53め高さを
高くするとともに、大出力のプレス駆動装置56を大ス
トローク化する必要があるから、装置が大形化して、極
めて高価になる。(3) Since the snow-like dry ice supplied into the press cylinder 53 is compressed and solidified, the large dry ice block 5
7, it is necessary to increase the height of the press cylinder 53 and to increase the stroke of the high-output press drive device 56, making the device large and extremely expensive.
(4)プレスシリンダ53内で雪状ドライアイスを圧縮
する際に雪状ドライアイス中の炭酸ガスがドライアイス
内に封じ込められてしまうので、この炭酸ガスで圧縮が
妨げられるため、圧縮の密度が小さくなるうえ、圧縮作
業速度が遅くなる。(4) When the snow-like dry ice is compressed in the press cylinder 53, the carbon dioxide gas in the snow-like dry ice is trapped within the dry ice, and this carbon dioxide gas prevents compression, so the density of compression is reduced. Not only will it be smaller, but the compression work speed will be slower.
ドライアイスブロック57がその内部に封じ込んだ炭酸
ガスの高い圧力で割れたり欠けたりし易いものとなる。The dry ice block 57 becomes easily cracked or chipped due to the high pressure of the carbon dioxide gas sealed inside.
(5)二枚のシャッター52を設けることにより、ドラ
イアイスブロック57を定量化する場合にも、雪状ドラ
イアイスの一部がチャージングシリンダ50の内壁に付
着して残留するので、ドライアイスブロック57を定量
化することが難しい。(5) By providing two shutters 52, even when quantifying the dry ice block 57, some of the snow-like dry ice adheres to the inner wall of the charging cylinder 50 and remains, so the dry ice block 57 is difficult to quantify.
本発明は、上記の諸欠点を解消する為に、雪状ドライア
イス生成筒を定形ドライアイス成形筒とをシャッタ空間
を空けて上下に配設し、生成筒の下端の送出口の成形筒
の上端の受入口とを同時に開閉するシャッタをシャッタ
空間に前後移動可能に配設し、生成筒内に予圧抑具を上
下動可能に内装し、生成筒内の雪状ドライアイスを予圧
搾してから成形筒内へ供給するようにするとともに、シ
ャッタの上部より前方へ補助シャッタを連出させること
により、送出口を閉じたまま受入口のみを開放可能にし
、生成筒内では雪状ドライアイスの生成を続けながら成
形筒内では定形ドライアイスを成形し、成形後の定形ド
ライアイスを圧搾具でシャッタ空間へ押出し、これをシ
ャッタの前面の製品押出面で押すことにより定形ドライ
アイスを取出すようにしたものである。In order to solve the above-mentioned drawbacks, the present invention arranges a snow-like dry ice generating cylinder and a regular dry ice forming cylinder above and below each other with a shutter space in between, and forms the forming cylinder at the outlet at the lower end of the generating cylinder. A shutter that simultaneously opens and closes the intake port at the upper end is arranged so as to be movable back and forth in the shutter space, and a preload suppressor is installed inside the production cylinder so that it can be moved up and down, and the snow-like dry ice in the production cylinder is pre-compressed. By supplying dry ice into the forming cylinder from the top of the shutter, and by moving an auxiliary shutter forward from the top of the shutter, it is possible to open only the receiving port while keeping the sending port closed. While the production continues, regular-shaped dry ice is formed in the molding cylinder, and the shaped dry ice is extruded into the shutter space by a pressing tool, and the regular-shaped dry ice is taken out by pushing it with the product extrusion surface on the front of the shutter. This is what I did.
以下、本発明の実施例を図面に基き説明する。Embodiments of the present invention will be described below with reference to the drawings.
第1図に示すように、雪状ドライアイス生成筒1ど定型
ドライアイス成形筒2とがシャッター空間3を空けて上
下に直列状に配置さ札生成筒1の下端の送出口4及び成
形筒2の上端の受入口5とはシャッタ空間3に開放され
、この送出口4と受入口5とを同時に開閉するシャッタ
6がシャッター空間3内を前後移動可能に配設される。As shown in FIG. 1, a snow-like dry ice generating cylinder 1 and a regular dry ice forming cylinder 2 are arranged vertically in series with a shutter space 3 in between. A receiving port 5 at the upper end of the shutter space 3 is opened to the shutter space 3, and a shutter 6 that simultaneously opens and closes the sending port 4 and the receiving port 5 is disposed so as to be movable back and forth within the shutter space 3.
上記生成筒1内には予圧神具8が油圧シリンダからなる
予圧搾駆動装置9を介して上下動可能に内装され、成形
筒2内に圧搾具10が油圧シリンダからなる成形駆動装
置11を介して上下動可能に内装される。A preload tool 8 is installed inside the production cylinder 1 so as to be able to move up and down via a pre-squeezing drive device 9 consisting of a hydraulic cylinder, and a compression tool 10 is installed inside the forming cylinder 2 via a forming drive device 11 consisting of a hydraulic cylinder. The interior is movable up and down.
生成筒1の上部に斜上向きに対称に付設された1対の雪
状ドライアイス吹込筒12の頂部には液状炭酸ガス噴出
用ノズル13が付設され、このノズル13で発生された
雪状ドライアイスを生成筒1内へ吹き込んで充満させて
から、予圧神具8で予圧搾して雪状ドライアイスを低密
度に圧搾し、これを成形筒2内に重力落下させ、成形筒
2内で圧搾具10で高密度に圧縮固結して定型ドライア
イスを成形するものであり、生成筒1内での雪状ドライ
アイスの生成と予圧搾の工程期間中に成形筒2内での圧
縮及び定形ドライアイスの成形筒2外への取出しの工程
を並行して行なわせることにより、高能率で高品質の定
形ドライアイスを製造するものである。A pair of snow-like dry ice blowing cylinders 12 are attached symmetrically upward to the upper part of the generation cylinder 1. A liquid carbon dioxide gas spouting nozzle 13 is attached to the top of the pair, and the snow-like dry ice generated by this nozzle 13 is is blown into the production cylinder 1 to fill it, and then pre-squeezed with the pre-loading tool 8 to compress snow-like dry ice to a low density, which is then allowed to fall by gravity into the forming cylinder 2 and compressed within the forming cylinder 2. The device 10 compresses and solidifies the ice to a high density to form a regular-shaped dry ice.During the process of producing snow-like dry ice in the production cylinder 1 and pre-squeezing, the compressing and shaping process takes place in the forming cylinder 2. By performing the process of taking the dry ice out of the molding cylinder 2 in parallel, high-quality regular-shaped dry ice is manufactured with high efficiency.
ここで、第2図及び第3図に基き、定形ドライアイス製
造装置の詳細構造について説明する。Here, the detailed structure of the regular shaped dry ice production apparatus will be explained based on FIGS. 2 and 3.
雪状ドライアイス生成筒1及び定形ドライアイス成形筒
2とは各々金属製角筒から形成さ札前後1対の鋼板から
なる支持枠17間に支持される。The snow-like dry ice producing cylinder 1 and the regular dry ice forming cylinder 2 are each formed from a rectangular metal cylinder and are supported between a support frame 17 made of a pair of steel plates at the front and rear.
生成筒1はステンレス鋼板製であって、その上端寄部に
は雪状ドライアイスから昇華した炭酸ガスを放出する為
の全網製のガス逃し口18が開口され、ガス逃し口18
の外側を囲繞するダクト19で炭酸ガスを集めて、ダク
トのガス放出口20から外部へ放出するようになってい
る。The generation cylinder 1 is made of a stainless steel plate, and a full-mesh gas vent 18 is opened near its upper end to release carbon dioxide sublimated from the snow-like dry ice.
The carbon dioxide gas is collected in a duct 19 surrounding the outside of the duct and released to the outside through a gas discharge port 20 of the duct.
ま外液状炭酸ガス噴出用ノズル13は、断熱膨張の原理
で液状炭酸ガスから雪状ドライアイスを発生させるもの
であって、雪状ドライアイス吹込筒12の奥端部に装着
され、液状炭酸ガス供給路22を介して液状炭酸ガスボ
ンベ21に接続されている。The outer liquid carbon dioxide blowing nozzle 13 generates snow-like dry ice from liquid carbon dioxide using the principle of adiabatic expansion, and is attached to the rear end of the snow-like dry ice blowing tube 12 to generate liquid carbon dioxide. It is connected to a liquid carbon dioxide gas cylinder 21 via a supply path 22 .
雪状ドライアイス吹込筒12は斜下向きの末広がり状の
角筒で形成され、ガス逃し穴18の下側で雪状ドライア
イス吹込口14が生成筒に開口している。The snow-like dry ice blowing tube 12 is formed of a rectangular tube that is slanted downward and widens toward the end, and a snow-like dry ice blowing port 14 opens into the production tube below the gas relief hole 18.
定形ドライアイス成形筒2はステンレス鋼板製であって
、その上部の外側には補強リブ兼吸熱フィン24が形成
される。The regular dry ice forming cylinder 2 is made of a stainless steel plate, and reinforcing ribs and heat-absorbing fins 24 are formed on the outside of its upper part.
即ち、成形筒2内で雪状ドライアイスを圧縮する工程の
終り項には、雪状ドライアイスを高圧で圧縮するので、
成形筒2の上部の強度を大きく形成する必要がある。That is, at the end of the process of compressing the snow-like dry ice in the forming tube 2, the snow-like dry ice is compressed under high pressure.
It is necessary to increase the strength of the upper part of the molding cylinder 2.
また、定形ドライアイス16をシャッター空間3へ押出
す際に、成形筒2の内周壁面と定形ドライアイス16の
外周面との間が融解して剥離し易くなるように、上記補
強リブ24の表面積を極力大きくして吸熱性能を太きく
し、補強リブ兼吸熱フィン24に形成する。In addition, the reinforcing ribs 24 are arranged so that when the regular-shaped dry ice 16 is pushed out into the shutter space 3, the inner circumferential wall surface of the forming cylinder 2 and the outer peripheral surface of the regular-shaped dry ice 16 are easily melted and peeled off. The surface area is made as large as possible to increase the heat absorption performance, and the reinforcing ribs and heat absorption fins 24 are formed.
また、上記定形ドライアイス16の剥離をよくする為に
、成形筒2の内周面を平滑面に形成することが必要であ
る。Further, in order to improve the peeling off of the regular shaped dry ice 16, it is necessary to form the inner circumferential surface of the molding cylinder 2 into a smooth surface.
シャッター6は生成筒1と生形筒2との間のシャッター
空間3に油圧シリンダからなるシャッター駆動装置25
を介して水平に前後移動可能に付設され、このシャッタ
ー6で生成筒1の下端の送出口4と成形筒2の上端の受
入口5とが同時に開閉可能である。The shutter 6 is provided with a shutter drive device 25 consisting of a hydraulic cylinder in the shutter space 3 between the production cylinder 1 and the green cylinder 2.
The shutter 6 is attached so as to be horizontally movable back and forth through the shutter 6, and the outlet port 4 at the lower end of the production cylinder 1 and the receiving port 5 at the upper end of the forming cylinder 2 can be opened and closed at the same time.
また、シャッタ6の前面上部から前方へ連出された補助
シャッター7で送出口4を閉じるとともに受入口5を開
放可能であり、またシャッター6を後方に引き寄せると
送出口4及び受入口5とが共に開放される。In addition, the auxiliary shutter 7 extended forward from the upper front surface of the shutter 6 can close the outlet 4 and open the inlet 5, and when the shutter 6 is pulled rearward, the outlet 4 and the inlet 5 are closed. will be released together.
つまり、シャッター6及び補助シャッター7とは、シャ
ッター6で送出口4及び受入口5とを閉じる全閉位置と
、シャッター6が後退して受入口5を開けるとともに補
助シャッター7で送出口4を閉じる下開き上閉じ位置と
、シャッター6も補助シャッター7も後退して送出口4
も受入口5も開放する全開位置との3位置にシャッター
駆動装置25を介して切換可能に構成する。In other words, the shutter 6 and the auxiliary shutter 7 are in a fully closed position where the shutter 6 closes the outlet 4 and the intake 5, and a fully closed position where the shutter 6 moves back to open the intake 5 and the auxiliary shutter 7 closes the outlet 4. The bottom opening position and the top closing position, and the shutter 6 and auxiliary shutter 7 are moved back and the outlet port 4 is closed.
It is configured to be switchable between three positions via a shutter drive device 25, including a fully open position in which both the opening and the receiving port 5 are opened.
ここで、第4図に基き、定形ドライアイス製造工程につ
いて説明する。Here, the process for manufacturing regular shaped dry ice will be explained based on FIG.
初期の始動時には、(I)に示すように、シャッター6
を全閉位置にするとともに、予圧抑具8を雪状ドライア
イス吹込口14より上方の待機位置に切換えて生成筒1
内に雪状ドライアイスが生成され、次に(II)に於い
て予圧抑具8を待機位置から雪状ドライアイス吹込口よ
り下方の予圧搾位置に下降駆動させて雪状ドライアイス
を予圧押抜、(1)に於いてシャッター6及び補助シャ
ッター7を全開位置に切換えてから、予圧抑具8を予圧
搾位置からこれよりも低い突き落し位置に下降させて、
予圧搾された雪状ドライアイス15を成形筒2内に落下
させ、次に■に於いて再びシャッター6を全閉位置にし
て成形筒2内では予圧押抜の雪状ドライアイス15を例
えば約150kg/fflの面圧で圧搾して定形ドライ
アイス16を成形しながら、これと並行して生成筒1内
には雪状ドライアイスを充満させる。At the initial startup, as shown in (I), the shutter 6
is set to the fully closed position, and the preload suppressor 8 is switched to the standby position above the snow-like dry ice inlet 14 to close the production cylinder 1.
Then, in (II), the pre-pressing device 8 is driven downward from the standby position to the pre-squeezing position below the snow-like dry ice inlet to pre-press the snow-like dry ice. After switching the shutter 6 and the auxiliary shutter 7 to the fully open position in step (1), lowering the preload suppressor 8 from the preloading position to a lower push-down position,
The pre-squeezed snow-like dry ice 15 is dropped into the forming tube 2, and then in step 2, the shutter 6 is again set to the fully closed position, and the pre-pressed snow-like dry ice 15 is dropped into the forming tube 2, for example, about approx. While compressing with a surface pressure of 150 kg/ffl to form regular dry ice 16, the production cylinder 1 is simultaneously filled with snow-like dry ice.
その後(■に於いては下開き上閉じ位置にして定形ドラ
イアイス16を成形筒2内からシャッター空間3に押出
してから、シャッター6を全閉位置へ移行させる際にこ
の定形ドライアイス16をシャッター6の前面の製品押
出面28で前方へ押出して製品取出台29上を滑らせて
シャッター空間3の前側へ移送する。After that (in (■), the regular-shaped dry ice 16 is pushed out from the inside of the molding cylinder 2 into the shutter space 3 with the bottom open and top closed position, and when the shutter 6 is moved to the fully closed position, the regular-shaped dry ice 16 is The product is pushed forward by the product extrusion surface 28 on the front side of 6, slid on the product take-out table 29, and transferred to the front side of the shutter space 3.
また、上記と並行して生成筒1内では継続して雪状ドラ
イアイスを発生させて所定量の雪状ドライアイスを生成
筒1内に充満させる。Further, in parallel with the above, snow-like dry ice is continuously generated in the production cylinder 1 to fill the production cylinder 1 with a predetermined amount of snow-like dry ice.
その後、(■(IIHI)−4)の工程を周期的に繰り
返していって、高能率でドライアイスを製造するのであ
る。Thereafter, the process (■(IIHI)-4) is repeated periodically to produce dry ice with high efficiency.
ここで、再び第2図及び第3図に基く説明を続行する。Here, the explanation based on FIGS. 2 and 3 will be continued again.
生成筒1内で雪状ドライアイスを予圧搾する際に、雪状
ドライアイス中の炭酸ガスが逃げ易くするとともに、成
形筒2内で定形ドライアイス16に成形する際にドライ
アイス中の炭酸ガスが逃げ易くする為に、シャッター6
は通気性の多孔質材料である焼結金属で形成され、その
内部には外部に開放しているガス抜き空間30が形成さ
れる。When pre-squeezing the snow-like dry ice in the production cylinder 1, carbon dioxide gas in the snow-like dry ice is made easy to escape, and when molded into regular-shaped dry ice 16 in the forming cylinder 2, the carbon dioxide gas in the dry ice is Shutter 6 to make it easier for the person to escape.
is made of sintered metal, which is a porous material with air permeability, and has a gas venting space 30 open to the outside formed therein.
このようにして、炭酸ガスのガス圧に妨げられることな
く能率よく定形ドライアイスを成形でき、製品の定形ド
ライアイス16も高密度化し、割れにくい高品質のもの
となる。In this way, shaped dry ice can be efficiently formed without being hindered by the gas pressure of carbon dioxide gas, and the shaped dry ice 16 as a product also has a high density and is of high quality and difficult to break.
上記の観点から、第5図に示すように、生成筒1の下部
31を上記焼結金属で形成することも出来る。From the above point of view, as shown in FIG. 5, the lower part 31 of the generating cylinder 1 can also be formed of the above-mentioned sintered metal.
更に、成形筒2の上部をも焼結金属でつくるのが望まし
い。Furthermore, it is desirable that the upper part of the forming tube 2 is also made of sintered metal.
次に、成形駆動装置11と圧搾具10、予圧搾駆動装置
9と予圧抑具8との間の断熱構造について説明する。Next, a heat insulation structure between the forming drive device 11 and the pressing tool 10, and between the pre-squeezing drive device 9 and the pre-suppressing tool 8 will be explained.
圧搾具10と予圧抑具8とは殆んど常時−70℃程度の
両極低温のドライアイスに接触しているので、油圧シリ
ンダの作動油が冷却され、その粘性が増すので、油圧供
給装置31の出力低下を招くばかりでなく、′油圧シリ
ンダから圧搾具10及び予圧抑具8を経て吸熱して、ド
ライアイスの昇華が促進され歩留が低下する。Since the squeezing tool 10 and the preload suppressor 8 are almost always in contact with dry ice at an extremely low temperature of about -70°C, the hydraulic oil in the hydraulic cylinder is cooled and its viscosity increases. Not only does this result in a decrease in output, but also heat is absorbed from the hydraulic cylinder through the compressor 10 and the preload suppressor 8, promoting sublimation of the dry ice and reducing yield.
これを防ぐ為に、予圧抑具8及び圧搾具10のステンレ
ス鋼製受圧板8c、10cと基板8a。In order to prevent this, stainless steel pressure receiving plates 8c and 10c of the preload suppressing tool 8 and the pressing tool 10 and the base plate 8a.
10aとの間に断熱性に優れるFRP製の断熱材からな
る断熱板8b、10bを介在させた構造とする。The structure is such that heat insulating plates 8b and 10b made of FRP heat insulating material with excellent heat insulating properties are interposed between the heat insulating plates 10a and 10a.
また、シャッター駆動装置25の油圧シリンダも補助シ
ャッター7、ピストンロッドを介して冷却されるので、
補助シャッター7とピストンロッドとの間に断熱材(図
示路)を介装するのが望ましい。Furthermore, the hydraulic cylinder of the shutter drive device 25 is also cooled via the auxiliary shutter 7 and the piston rod.
It is desirable to interpose a heat insulating material (path shown) between the auxiliary shutter 7 and the piston rod.
上記に於いて、各油圧シリンダへ圧油を供給する油圧供
給装置31は、油タンク、油圧ポンプ、電動機、その他
方向切換電磁弁、圧力スイッチ等から構成される。In the above, the hydraulic supply device 31 for supplying pressure oil to each hydraulic cylinder is composed of an oil tank, a hydraulic pump, an electric motor, a direction switching solenoid valve, a pressure switch, and the like.
また、制御装置32にはシーケンス制御回路が内装され
ており、リミットスイッチLS1〜LS8の検出信号に
基いて圧油供給油路33の方向切換電磁弁及び液状炭酸
ガス供給路22の開閉電磁弁23を開閉制御することに
より、定形ドライアイス製造装置が自動運転される。Furthermore, the control device 32 is equipped with a sequence control circuit, and the direction switching solenoid valve of the pressure oil supply passage 33 and the opening/closing solenoid valve 23 of the liquid carbon dioxide supply passage 22 are based on the detection signals of the limit switches LS1 to LS8. By controlling the opening and closing of the dry ice, the regular dry ice manufacturing equipment is automatically operated.
但し、必要に応じて手動運転も可能である。However, manual operation is also possible if necessary.
ここで、上記制御系統の詳細については、説明を省略す
るが、予圧抑具8、圧搾具10、シャッター6及び補助
シャッター7の各作動シーケンスの1サイクルについて
、第2図及び第6図面の簡単な説明する。Here, detailed explanation of the control system is omitted, but for one cycle of each operation sequence of the preload suppressing tool 8, the pressing tool 10, the shutter 6, and the auxiliary shutter 7, the simple explanation shown in FIG. 2 and FIG. Explain.
成形筒2内を上下動する圧搾具10の上限位置、加圧限
位置及び下限位置は各々リミットスイッチLSI、リミ
ットスイッチLS2と圧力スイッチ(図示路)及びリミ
ットスイッチLS3で検出される。The upper limit position, pressurization limit position, and lower limit position of the compression tool 10 that moves up and down in the forming cylinder 2 are detected by a limit switch LSI, a limit switch LS2, a pressure switch (path shown), and a limit switch LS3, respectively.
生成筒1内の予圧神具8の待機位置、予圧搾位置及び突
落し位置は、各々リミットスイッチLS7、圧力スイッ
チ(図示路)及びリミットスイッチLS8で検出される
。The standby position, precompression position, and falling position of the preload tool 8 in the production cylinder 1 are detected by a limit switch LS7, a pressure switch (path shown), and a limit switch LS8, respectively.
また、シャッター6と補助シャッター7の全開位置、下
開き上閉じ位置及び全閉位置は各々リミットスイッチL
S4゜LS5及びLS6で検出されるようになっている
。In addition, the fully open position, bottom open top close position, and fully closed position of the shutter 6 and the auxiliary shutter 7 are controlled by limit switches L, respectively.
S4° is detected at LS5 and LS6.
自動スタート押釦を押すと、液状炭酸ガス供給路の開閉
電磁弁22が開いて、生成筒1内に雪状ドライアイスが
充填され、各リミットスイッチLS1〜LS8と圧力ス
イッチからの検出信号及びシーケンス制御回路中のタイ
マーやリレーからの信号に基き、次のように作動制御さ
れる。When the automatic start button is pressed, the opening/closing solenoid valve 22 of the liquid carbon dioxide gas supply path opens, filling the production cylinder 1 with snow-like dry ice, and detecting signals from each limit switch LS1 to LS8 and the pressure switch and sequence control. The operation is controlled as follows based on signals from timers and relays in the circuit.
即ち、予圧神具8が下降して雪状ドライアイスが予圧搾
され(符号aで図示)、シャッター6及び補助シャッタ
ー7が全開位置(符号すで図示)に開かれた後、上記予
圧搾された雪状ドライアイス15は生成筒1内から成形
筒2内へ重力落下される(符号Cで図示)。That is, the pre-loading tool 8 is lowered to pre-squeeze the snow-like dry ice (indicated by the symbol a), and after the shutter 6 and the auxiliary shutter 7 are opened to the fully open position (already illustrated), the pre-squeezed dry ice is The snow-like dry ice 15 falls by gravity from the inside of the production cylinder 1 into the formation cylinder 2 (indicated by symbol C).
次にシャッター6が全開位置に切換えられ(符号dで図
示)、成形筒2内で圧搾具10を上昇駆動させて上記予
圧押抜雪状ドライアイス15が定形ドライアイス16に
圧縮成形される(符号eで図示)。Next, the shutter 6 is switched to the fully open position (indicated by reference numeral d), and the compressing tool 10 is driven upward within the molding cylinder 2 to compress and mold the preloaded snow-like dry ice 15 into regular-shaped dry ice 16 ( (Illustrated with symbol e).
そして、この圧縮成形後待機しく符号fで図示)、シャ
ッター6及び補助シャッター7が下開き上閉じ位置に切
換えられてから(符号gで図示)圧搾具10を上限位置
に上昇させることにより定形ドライアイス16がシャッ
ター空間3に移され(符号りで図示)、シャッター6を
前進させて全閉位置に切換える際に、シャッター6の前
面の製品押出面28で定形ドライアイス16が押されて
製品取出台29上の製品取出位置に移される(符号iで
図示)。After this compression molding, the shutter 6 and the auxiliary shutter 7 are switched to the downward opening position (indicated by symbol f), and then the pressing tool 10 is raised to the upper limit position (indicated by symbol g) to dry the regular shape. When the ice 16 is transferred to the shutter space 3 (indicated by the reference numerals) and the shutter 6 is moved forward and switched to the fully closed position, the shaped dry ice 16 is pushed by the product extrusion surface 28 on the front of the shutter 6, and the product is removed. The product is moved to the product take-out position on the platform 29 (indicated by reference numeral i).
同符号Jで図示するように、上記符号e=iの工程と並
行して、液状炭酸ガス供給路22の開閉電磁弁23が開
くことにより生成筒1内に次の工程サイクルの為の雪状
ドライアイスが供給される。As shown by the same reference numeral J, in parallel with the step e=i, the opening/closing solenoid valve 23 of the liquid carbon dioxide gas supply path 22 is opened to create a snow formation in the production cylinder 1 for the next process cycle. Dry ice is provided.
本発明は、上記のように構成され作用するので、次の効
果を奏する。Since the present invention is configured and operates as described above, it has the following effects.
1)成形後の定形ドライアイスを成形筒外へ取り出すに
当り、圧搾具を利用してシャッター空間に押し上げ、シ
ャッターを利用して製品数出合上へ移送するようになっ
ている。1) When taking the shaped dry ice out of the molding cylinder, a compressor is used to push it up into the shutter space, and a shutter is used to transport the product to the top.
これにより、成形筒を固設できるため、成形筒の駆動装
置を省略することができる。As a result, the forming cylinder can be fixedly installed, so that a driving device for the forming cylinder can be omitted.
そして、定形ドライアイス取出し専用の装置を省略し、
シャッターで押出すことができるので、装置の全体構造
が簡素化・小形化して安価に製作できる。In addition, a device dedicated to taking out regular dry ice is omitted,
Since it can be pushed out using a shutter, the overall structure of the device can be simplified and miniaturized, and it can be manufactured at low cost.
2)生成筒内で雪状ドライアイスを予圧搾してから、成
形筒内に供給するので、生成筒内の雪状ドライアイスは
、予圧搾されてその高さが縮少されるので成形筒の全高
を低くでき、これに伴って大出力の成形駆動装置のスト
ロークをも短縮して小形化することができる。2) Since the snow-like dry ice is pre-squeezed in the production cylinder and then fed into the forming cylinder, the snow-like dry ice in the production cylinder is pre-squeezed and its height is reduced. The total height of the molding device can be reduced, and the stroke of the high-output molding drive device can also be shortened and the molding device can be made smaller.
従って、装置の全高を低くするとともに軽量化し、安価
に製作できる。Therefore, the overall height of the device can be reduced, the weight can be reduced, and it can be manufactured at low cost.
3)そして、生成筒内に生成した定重量の雪状ドライア
イスを、予圧神具で予圧搾してから突落すことにより、
成形筒へ全部供給することができ、定重量の定形ドライ
アイスを安定的に製造することができる。3) Then, by pre-squeezing the constant weight of snow-like dry ice produced in the production cylinder with a pre-loading tool and then letting it fall,
All of the ice can be fed into the molding cylinder, and regular shaped dry ice of constant weight can be stably produced.
4)シかも、雪状ドライアイスを予圧押抜、生成筒から
成形筒に移して圧搾開始するまでの間に、予圧搾ドライ
アイス中に封じ込められかけた炭酸ガスの一部が容易に
逃げ出すので、定形ドライアイス中に封じ込められる炭
酸ガスの量が大幅に減少する。4) Possibly, some of the carbon dioxide gas trapped in the pre-pressed dry ice easily escapes between the time when the snow-like dry ice is pre-pressed and transferred from the production cylinder to the forming cylinder and the start of compression. , the amount of carbon dioxide trapped in regular dry ice is significantly reduced.
これにより、圧搾成形の際にドライアイス中に封じ込め
られた炭酸ガスで圧搾成形が妨げられることが殆んどな
くなるので、成形駆動装置の出力を小形化し成形能率を
高め、定形ドライアイスの品質を高めることができる。As a result, compression molding is almost never hindered by the carbon dioxide gas trapped in the dry ice during compression molding, so the output of the molding drive device is reduced, improving molding efficiency, and improving the quality of shaped dry ice. can be increased.
5)シャッターを通気性のある多孔質材料で形成する場
合には、雪状ドライアイス圧搾時に雪状ドライアイス中
の炭酸ガスがシャッターを通って外部へ逃げるので、炭
酸ガスのガス圧で圧搾が妨げられなくなるから、成形駆
動装置を小形化でき、かつ成形能率を高めることができ
るばかりでなく、定形ドライアイスの品質を高めること
ができる。5) If the shutter is made of a porous material with air permeability, the carbon dioxide gas in the snow-like dry ice escapes to the outside through the shutter when the snow-like dry ice is compressed, so that the compression is carried out by the gas pressure of the carbon dioxide gas. Since it is no longer obstructed, the molding drive device can be downsized, molding efficiency can be increased, and the quality of shaped dry ice can be improved.
第1図〜第6図は本発明の実施例を示し、第1図は基本
構成の概略斜視図、第2図は縦断側面図、第3図は正面
図、第4図は定形ドライアイス製造工程の説明図、第5
図は変形例の第2図V部相当部分図、第6図は各リミツ
、トスイツチ等の検出信号に基いて駆動制御される圧搾
具、予圧抑具、シャッターと補助シャッターの作動シー
ケンスの線図、第7図、第8図は従来装置の縦断正面図
である。
1・・・・・・雪状ドライアイス生成筒、2・・−・・
・定形ドライアイス成形筒、3・・・・・・シャッター
空間、4・・・・・・送出口、5・・・・・・受入口、
6・・・・・・シャッター、7ユ;J”“79−.8
“71°°゛
)、9・・・・・・予圧搾駆動装置、10・・・・・・
圧搾具、(1ob・・・・・・断熱材)、11・・・・
・・成形駆動装置、13・・・・・・ノズル、14・・
・・・・雪状ドライアイス吹込口、16・・・・・・定
形ドライアイス、24・・・・・・補強兼吸熱フィン、
25・・・・・・シャッター駆動装置、28・・・・・
・押出面、29・・・・・・取出台。Fig. 1 to Fig. 6 show examples of the present invention, Fig. 1 is a schematic perspective view of the basic configuration, Fig. 2 is a vertical side view, Fig. 3 is a front view, and Fig. 4 is production of regular dry ice. Explanatory diagram of the process, 5th
The figure is a partial view corresponding to section V in Figure 2 of a modified example, and Figure 6 is a diagram of the operating sequence of the squeezing tool, pre-pressure suppressor, shutter and auxiliary shutter whose drive is controlled based on the detection signals of each limit, tosswitch, etc. , FIG. 7, and FIG. 8 are longitudinal sectional front views of the conventional device. 1... Snow-like dry ice generation cylinder, 2...
・Standard dry ice forming cylinder, 3... Shutter space, 4... Delivery port, 5... Receiving port,
6...Shutter, 7yu;J""79-. 8
“71°°゛), 9... Pre-squeezing drive device, 10...
Pressing tool, (1ob...insulation material), 11...
... Molding drive device, 13... Nozzle, 14...
... Snow-shaped dry ice inlet, 16 ... Regular-shaped dry ice, 24 ... Reinforcement and heat absorption fin,
25... Shutter drive device, 28...
・Extrusion surface, 29...Ejection stand.
Claims (1)
ス成形筒2をシャッター空間3を空けて配置し、生成筒
1の下面に雪状ドライアイスの送出口4を開放し、生成
筒2の上面に雪状ドライアイスの受入口5を開放し、送
出口4と受入口5とを同時に開閉するシャッター6を前
記シャッター空間3に配置し、生成筒1の上部に液状炭
酸ガス噴出用ノズル13を臨ませ、シャッター6をシャ
ッター駆動装置25で前後に開閉駆動可能にし、成形筒
2に圧搾具10を上下に摺動自在に挿入し、圧搾具10
を成形駆動装置11で上下駆動可能にし、ノズル13か
ら液体炭酸ガスを噴出させて、生成筒1内に雪状ドライ
アイスを生成し、シャッター6をシャッター駆動装置2
5で開いて、生成筒1内の雪状ドライアイスを送出口4
、シャッター空間3及び受入口5から成形筒2゛に注入
し、シャッター6をシャッター駆動装置25で閉じ、圧
搾具10を成形駆動装置11で上向きに圧搾駆動して、
成形筒2内で雪状ドライアイスを圧搾して定形ドライア
イス16に成形するように構成した定形ドライアイスの
製造装置において、生成筒1内に予圧抑具8を上下に摺
動自在に挿入し、予圧抑具8を予圧搾駆動装置9でノズ
ル13が臨んでいる雪状ドライアイス吹込口14より高
い待機位置、該吸込口14よりも低い予圧搾位置及び予
圧搾位置よりも低い突落し位置とに切換可能に構成し、
シャッター6の上部から補助シャッター7を前向きに突
設し、シャッター6の前面を定形ドライアイス16の押
出面28として形成し、この押出面28の高さを定形ド
ライアイス16の高さよりも高く設定し、シャッター空
間3の前側の下面に定形ドライアイス16の取出台29
を配置し、シャッター6が送出口4及び受入口5を閉じ
る全閉位置と、シャッター6が後退して受入口5を開け
るとともに、補助シャッターTが送出口4を閉じる下開
き上閉じ位置と、シャッター6も補助シャッター7も後
退して送出口4も受入口5も開放する全開位置との3位
置に、シャッター6と補助シャッター7とをシャッター
駆動装置25で切換駆動可能に構成した事を特徴とする
定形ドライアイスの製造装置。 2、特許請求の範囲第1項に記載した定形ドライアイス
製造装置において、上記駆動装置9,11゜25が各々
油圧シリンダからなり、成形駆動装置11を成形筒2の
真下に、予圧搾駆動装置9を生成筒1の真上に、シャッ
タ駆動装置25をシャッタ空間3の後側に配設したもの
。 3 特許請求の範囲第2項に記載した定形ドライアイス
製造装置において、圧搾具10及び予圧抑具8を各々成
形駆動装置11及び予圧搾駆動装置9ノ各油圧シリンダ
のピストンロッドに断熱材10b 、8bを介して接続
したもの。 4 特許請求の範囲第1項乃至第3項のうちのどれか1
項に記載した定形ドライアイス製造装置において、定形
ドライアイス成形筒2と雪状ドライアイス生成筒1とを
各々角筒で形成したもの。 5 特許請求の範囲第1項乃至第4項のうちのどれか1
項に記載した定形ドライアイス製造装置において、定形
ドライアイス成形筒2の上部の外側に補強リブ兼吸熱フ
ィン24を付設したもの。 6 特許請求の範囲第1項記載乃至第5項のうちのどれ
か1項に記載した定形ドライアイス製造装置において、
定形ドライアイス成形筒2の少なくとも内周面の上部を
ステンレス鋼で平滑面に形成したもの。 7 特許請求の範囲第1項乃至第6項のうちのどれか1
項に記載した定形ドライアイス製造装置において、シャ
ッター6を通気性の多孔質材料で形成したもの。 8 特許請求の範囲第7項に記載した定形ドライアイス
製造装置において、多孔質材料が焼結金属であるもの。 9 特許請求の範囲第1項乃至第8項のうちのどれか1
項に記載した定形ドライアイス製造装置において、雪状
ドライアイス生成筒1の一部に2個の液状炭酸ガス噴出
用ノズル13を対称に臨ませたもの。 10特許請求の範囲第1項乃至第9項のうちのどれか1
項に記載した定形ドライアイス製造装置において、雪状
ドライアイス生成筒1の少なくとも下周壁部を通気性の
多孔質材料で形成したもの。[Claims] 1. A regular shaped dry ice forming cylinder 2 is arranged below the snow-like dry ice generating cylinder 1 with a shutter space 3 left open, and a snow-like dry ice outlet 4 is opened at the bottom surface of the generating cylinder 1. A receiving port 5 for snow-like dry ice is opened on the upper surface of the generating cylinder 2, and a shutter 6 that opens and closes the sending port 4 and the receiving port 5 at the same time is arranged in the shutter space 3. The carbon dioxide gas jetting nozzle 13 is faced, the shutter 6 is driven to open and close back and forth by the shutter drive device 25, and the pressing tool 10 is inserted into the molding cylinder 2 so as to be slidable up and down.
is made vertically movable by the molding drive device 11, liquid carbon dioxide is ejected from the nozzle 13 to generate snow-like dry ice in the generation cylinder 1, and the shutter 6 is moved by the shutter drive device 2.
5 to open the snow-like dry ice in the generation cylinder 1 to the outlet 4.
, inject into the molding cylinder 2'' from the shutter space 3 and the intake port 5, close the shutter 6 with the shutter drive device 25, drive the compressing tool 10 upward with the molding drive device 11,
In a shaped dry ice manufacturing apparatus configured to compress snow-like dry ice and form it into shaped dry ice 16 in a shaping tube 2, a preload suppressor 8 is inserted into the production tube 1 so as to be slidable up and down. , the precompression suppressor 8 is moved by the precompression driving device 9 to a standby position higher than the snow-like dry ice inlet 14 facing the nozzle 13, a precompression position lower than the suction inlet 14, and a plunge position lower than the precompression position. configured so that it can be switched between
An auxiliary shutter 7 is provided to protrude forward from the top of the shutter 6, and the front surface of the shutter 6 is formed as an extrusion surface 28 for the regular dry ice 16, and the height of the extrusion surface 28 is set higher than the height of the regular dry ice 16. A take-out table 29 for the regular dry ice 16 is installed on the lower surface of the front side of the shutter space 3.
a fully closed position in which the shutter 6 closes the outlet port 4 and the inlet port 5, and a bottom-open top closed position in which the shutter 6 retreats to open the inlet port 5 and the auxiliary shutter T closes the outlet port 4; A feature is that the shutter 6 and the auxiliary shutter 7 can be switched and driven by a shutter drive device 25 in three positions: a fully open position in which both the shutter 6 and the auxiliary shutter 7 are moved back and both the outlet port 4 and the inlet port 5 are opened. A manufacturing device for shaped dry ice. 2. In the shaped dry ice production apparatus described in claim 1, each of the drive devices 9, 11°25 is composed of a hydraulic cylinder, and the forming drive device 11 is located directly below the forming cylinder 2, and the pre-squeezing drive device 9 is disposed directly above the generating cylinder 1, and a shutter drive device 25 is disposed at the rear side of the shutter space 3. 3. In the shaped dry ice manufacturing apparatus set forth in claim 2, the compressing tool 10 and the pre-compression suppressing tool 8 are each provided with a heat insulating material 10b on the piston rod of each hydraulic cylinder of the forming drive device 11 and the pre-squeezing drive device 9, respectively. Connected via 8b. 4 Any one of claims 1 to 3
In the regular-shaped dry ice production apparatus described in 1., the regular-shaped dry ice forming cylinder 2 and the snow-like dry ice producing cylinder 1 are each formed by a rectangular cylinder. 5 Any one of claims 1 to 4
In the shaped dry ice production apparatus described in 2. above, reinforcing ribs and heat-absorbing fins 24 are attached to the outside of the upper part of the shaped dry ice forming cylinder 2. 6. In the shaped dry ice manufacturing apparatus described in any one of claims 1 to 5,
At least the upper part of the inner circumferential surface of the regular dry ice forming cylinder 2 is made of stainless steel and formed into a smooth surface. 7 Any one of claims 1 to 6
In the regular shaped dry ice production apparatus described in 2. above, the shutter 6 is made of an air-permeable porous material. 8. The shaped dry ice manufacturing apparatus according to claim 7, wherein the porous material is a sintered metal. 9 Any one of claims 1 to 8
In the regular shaped dry ice production apparatus described in 2.2, two liquid carbon dioxide gas ejection nozzles 13 are arranged symmetrically in a part of the snow-like dry ice production cylinder 1. 10 Any one of claims 1 to 9
In the shaped dry ice production apparatus described in 2. above, at least the lower peripheral wall of the snow-like dry ice production cylinder 1 is formed of an air-permeable porous material.
Priority Applications (4)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP56170563A JPS5911527B2 (en) | 1981-10-24 | 1981-10-24 | Shaped dry ice manufacturing equipment |
| GB08137499A GB2111895B (en) | 1981-10-24 | 1981-12-11 | Moulding bricks of dry ice |
| CA000392170A CA1166859A (en) | 1981-10-24 | 1981-12-14 | Apparatus for producing brick shaped dry ice from liquid carbon dioxide |
| DE3200346A DE3200346A1 (en) | 1981-10-24 | 1982-01-08 | DEVICE FOR PRODUCING SQUARE DRY ICE FROM LIQUID CARBON DIOXIDE |
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP56170563A JPS5911527B2 (en) | 1981-10-24 | 1981-10-24 | Shaped dry ice manufacturing equipment |
| GB08137499A GB2111895B (en) | 1981-10-24 | 1981-12-11 | Moulding bricks of dry ice |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPS5874516A JPS5874516A (en) | 1983-05-06 |
| JPS5911527B2 true JPS5911527B2 (en) | 1984-03-16 |
Family
ID=26281533
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP56170563A Expired JPS5911527B2 (en) | 1981-10-24 | 1981-10-24 | Shaped dry ice manufacturing equipment |
Country Status (4)
| Country | Link |
|---|---|
| JP (1) | JPS5911527B2 (en) |
| CA (1) | CA1166859A (en) |
| DE (1) | DE3200346A1 (en) |
| GB (1) | GB2111895B (en) |
Families Citing this family (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4911362A (en) * | 1989-02-28 | 1990-03-27 | David Delich | Method and apparatus for making carbon dioxide snow |
| JPH07143906A (en) * | 1993-11-24 | 1995-06-06 | Katsuhiko Nishimoto | Receiving device for foldaway umbrella |
| US8869551B2 (en) | 2010-10-19 | 2014-10-28 | Cold Jet Llc | Method and apparatus for forming carbon dioxide particles into blocks |
| DE102016003800A1 (en) * | 2016-03-26 | 2017-09-28 | Messer France S.A.S. | Device for dosing carbon dioxide snow |
| DE102017008488B4 (en) * | 2017-09-09 | 2019-07-04 | Messer Belgium N.V. | Device for dosing carbon dioxide snow |
| JP7267031B2 (en) * | 2019-02-21 | 2023-05-01 | 大阪瓦斯株式会社 | Dry ice manufacturing method and manufacturing apparatus |
| DE102019005745A1 (en) * | 2019-08-16 | 2021-02-18 | Messer Group Gmbh | Device and method for metering carbon dioxide snow |
| JP7706969B2 (en) * | 2021-07-26 | 2025-07-14 | エア・ウォーター株式会社 | Dry ice pellet manufacturing equipment |
| US20240369275A1 (en) * | 2023-05-05 | 2024-11-07 | Tomco2 Systems Company | Block press for producing solid carbon dioxide |
Family Cites Families (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB433018A (en) * | 1933-11-13 | 1935-08-07 | G A Schuetz | Improvements in presses for producing solid carbon dioxide |
| US2253880A (en) * | 1940-04-27 | 1941-08-26 | York Ice Machinery Corp | Apparatus for producing carbon dioxide snow blocks |
-
1981
- 1981-10-24 JP JP56170563A patent/JPS5911527B2/en not_active Expired
- 1981-12-11 GB GB08137499A patent/GB2111895B/en not_active Expired
- 1981-12-14 CA CA000392170A patent/CA1166859A/en not_active Expired
-
1982
- 1982-01-08 DE DE3200346A patent/DE3200346A1/en active Granted
Also Published As
| Publication number | Publication date |
|---|---|
| CA1166859A (en) | 1984-05-08 |
| DE3200346A1 (en) | 1983-05-05 |
| GB2111895A (en) | 1983-07-13 |
| GB2111895B (en) | 1985-06-26 |
| JPS5874516A (en) | 1983-05-06 |
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