JPS591434B2 - surface purifier - Google Patents
surface purifierInfo
- Publication number
- JPS591434B2 JPS591434B2 JP6813076A JP6813076A JPS591434B2 JP S591434 B2 JPS591434 B2 JP S591434B2 JP 6813076 A JP6813076 A JP 6813076A JP 6813076 A JP6813076 A JP 6813076A JP S591434 B2 JPS591434 B2 JP S591434B2
- Authority
- JP
- Japan
- Prior art keywords
- acid
- polishing
- abrasive grains
- mixed
- liquid
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 239000002245 particle Substances 0.000 claims description 4
- 239000012459 cleaning agent Substances 0.000 claims description 3
- -1 hydroxy-3.4-dicarboxypentadecanoic acid Chemical compound 0.000 claims description 3
- 150000002148 esters Chemical class 0.000 claims 1
- 150000002596 lactones Chemical class 0.000 claims 1
- 150000003839 salts Chemical class 0.000 claims 1
- 239000002253 acid Substances 0.000 description 24
- 238000005498 polishing Methods 0.000 description 13
- 239000006061 abrasive grain Substances 0.000 description 10
- 239000007788 liquid Substances 0.000 description 7
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 6
- 238000001179 sorption measurement Methods 0.000 description 6
- 239000000843 powder Substances 0.000 description 4
- 239000012629 purifying agent Substances 0.000 description 4
- 239000004927 clay Substances 0.000 description 3
- 239000003086 colorant Substances 0.000 description 3
- 230000000694 effects Effects 0.000 description 3
- 230000035699 permeability Effects 0.000 description 3
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 2
- 125000000896 monocarboxylic acid group Chemical group 0.000 description 2
- 239000007787 solid Substances 0.000 description 2
- WRIDQFICGBMAFQ-UHFFFAOYSA-N (E)-8-Octadecenoic acid Natural products CCCCCCCCCC=CCCCCCCC(O)=O WRIDQFICGBMAFQ-UHFFFAOYSA-N 0.000 description 1
- LQJBNNIYVWPHFW-UHFFFAOYSA-N 20:1omega9c fatty acid Natural products CCCCCCCCCCC=CCCCCCCCC(O)=O LQJBNNIYVWPHFW-UHFFFAOYSA-N 0.000 description 1
- QSBYPNXLFMSGKH-UHFFFAOYSA-N 9-Heptadecensaeure Natural products CCCCCCCC=CCCCCCCCC(O)=O QSBYPNXLFMSGKH-UHFFFAOYSA-N 0.000 description 1
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 1
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 1
- ZQPPMHVWECSIRJ-UHFFFAOYSA-N Oleic acid Natural products CCCCCCCCC=CCCCCCCCC(O)=O ZQPPMHVWECSIRJ-UHFFFAOYSA-N 0.000 description 1
- 239000005642 Oleic acid Substances 0.000 description 1
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 1
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 1
- 229910021536 Zeolite Inorganic materials 0.000 description 1
- 150000007513 acids Chemical class 0.000 description 1
- 125000000217 alkyl group Chemical group 0.000 description 1
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 1
- 230000003373 anti-fouling effect Effects 0.000 description 1
- 159000000007 calcium salts Chemical class 0.000 description 1
- 125000004432 carbon atom Chemical group C* 0.000 description 1
- 125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 229910052570 clay Inorganic materials 0.000 description 1
- 238000004140 cleaning Methods 0.000 description 1
- 239000011248 coating agent Substances 0.000 description 1
- 238000000576 coating method Methods 0.000 description 1
- HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 description 1
- 239000000839 emulsion Substances 0.000 description 1
- 239000004744 fabric Substances 0.000 description 1
- 239000011521 glass Substances 0.000 description 1
- JEIPFZHSYJVQDO-UHFFFAOYSA-N iron(III) oxide Inorganic materials O=[Fe]O[Fe]=O JEIPFZHSYJVQDO-UHFFFAOYSA-N 0.000 description 1
- QXJSBBXBKPUZAA-UHFFFAOYSA-N isooleic acid Natural products CCCCCCCC=CCCCCCCCCC(O)=O QXJSBBXBKPUZAA-UHFFFAOYSA-N 0.000 description 1
- 239000000314 lubricant Substances 0.000 description 1
- 239000007769 metal material Substances 0.000 description 1
- 238000000034 method Methods 0.000 description 1
- 239000003921 oil Substances 0.000 description 1
- ZQPPMHVWECSIRJ-KTKRTIGZSA-N oleic acid Chemical compound CCCCCCCC\C=C/CCCCCCCC(O)=O ZQPPMHVWECSIRJ-KTKRTIGZSA-N 0.000 description 1
- 239000004033 plastic Substances 0.000 description 1
- 229920000137 polyphosphoric acid Polymers 0.000 description 1
- 229910052700 potassium Inorganic materials 0.000 description 1
- 239000011591 potassium Substances 0.000 description 1
- 230000001681 protective effect Effects 0.000 description 1
- 229910052814 silicon oxide Inorganic materials 0.000 description 1
- 229910052708 sodium Inorganic materials 0.000 description 1
- 239000011734 sodium Substances 0.000 description 1
- 159000000000 sodium salts Chemical class 0.000 description 1
- 239000002023 wood Substances 0.000 description 1
- 239000010457 zeolite Substances 0.000 description 1
Landscapes
- Detergent Compositions (AREA)
- Cleaning And De-Greasing Of Metallic Materials By Chemical Methods (AREA)
Description
【発明の詳細な説明】
本発明はガラス、プラスチック、金属材、木材等の表面
を浄化する表面浄化剤の改良に関する。DETAILED DESCRIPTION OF THE INVENTION The present invention relates to improvements in surface purifying agents for cleaning the surfaces of glass, plastic, metal materials, wood, and the like.
従来、パラ研摩に使用する研摩粒入りのワックス・液状
油あるいは乳状液等各種の表面浄化剤が知られている。
これらは研磨粒によるパラ研摩作用で表面浄化乃至は研
摩を行なうと同時に、研摩後、表面に付着していて表面
の汚れ、発錆を保護する構成されたものが多いが、従来
市販されているものはいずれも吸着力が弱いために、容
易に短時間に流失したり剥離する欠点がある。本発明は
この点を改良するために提案されたもので、多ＣＯＯＨ
基、ＯＨ基等極性基を有して吸着力の強い酸を利用する
ものである。Conventionally, various surface purifying agents such as wax, liquid oil, or emulsion containing abrasive grains used in para-polishing have been known.
Many of these have a structure that cleans or polishes the surface through the para-polishing action of abrasive particles, and at the same time protects the surface from dirt and rust by adhering to the surface after polishing. All of them have weak adsorption power, so they have the disadvantage of being easily washed away or peeled off in a short period of time. The present invention was proposed to improve this point.
This method utilizes an acid that has a polar group such as a group or an OH group and has a strong adsorption power.
かゝる酸は、例えばその分子構造が
ＣＯＯＨＣＯＯＨ
ＣＨ３（ＣＨ２）９−Ｃ−Ｃ−（ＣＨ２）２−ＣＯＯＨ
であり、ＣＯＯＨ基、ＯＨ基等の極性基を有して極めて
吸着性が高い酸であり、この酸の構造上の特徴は一級、
二級、三級の３個のＣＯＯＨ基を有し、三級の１つのＯ
Ｈ基を有する。Such acids, for example, have the molecular structure COOHCOOH CH3(CH2)9-C-C-(CH2)2-COOH
It is an acid that has polar groups such as COOH and OH groups and has extremely high adsorption properties.The structural characteristics of this acid are first class,
It has three COOH groups, secondary and tertiary, and one tertiary O
It has an H group.
また長鎖アルキル基を持つて炭素数の大きい（１０以上
）、このような構造から酸は吸着性が高く、親水性であ
り、浸透分散性も極めて高い。本発明はかゝる酸の特性
を利用し、この酸を含有させて液状、粘土状乃至固形化
し、粉体化したものである。Furthermore, it has a long chain alkyl group and has a large number of carbon atoms (10 or more), and because of this structure, it has high acid adsorption properties, is hydrophilic, and has extremely high permeability and dispersibility. The present invention takes advantage of the properties of such an acid, and contains this acid to form a liquid, clay, or solid state into a powder.
前記酸は通常粉体であり、粉体のまゝ混合する場合もあ
るが、一般にはメチールアルコールに良く溶解するので
アルコール溶液として利用し、またナトリウムで溶解し
透明けん状のナトリウム塩として、またカリウム、カル
シウム塩として利用し、またメタノールに常温でも良く
溶解し、エステル化して利用する。The acid is usually a powder, and may be mixed as a powder, but generally it dissolves well in methyl alcohol, so it is used as an alcohol solution, and it can also be dissolved in sodium to form a transparent sulfur-like sodium salt. It is also used as potassium and calcium salts, and dissolves well in methanol even at room temperature, and is used after being esterified.
研磨粒はゼオライト、活性白土粘土、アルミナ、酸化硅
素等の砥粒が利用され、粒径１〜３μφ程度の微粒末が
混合される。Abrasive grains such as zeolite, activated clay, alumina, and silicon oxide are used as the abrasive grains, and fine powder with a particle size of about 1 to 3 μΦ is mixed therein.
前記酸とこの研磨粒の混合によつて、酸はその強い浸透
分散性によつて研磨粒と均一に分散混合し、しかも研摩
粒全体をこの酸で包むようになる。By mixing the acid with the abrasive grains, the acid is uniformly dispersed and mixed with the abrasive grains due to its strong permeability and dispersibility, and moreover, the entire abrasive grains are surrounded by the acid.
勿論浄化剤にはポリリン酸、オレイン酸等が混合されて
いることもある。酸は通常１００ｐｐｍ〜１％程度の溶
液として用いられ、これに研摩材を混合するが、酸と研
磨粒の混合率は、研磨粒に対して酸を１〜３０％程度混
合する。以上のようにして得られた浄化剤の使用は、例
えばこれを織編布等に付着させてパラ研摩等に利用する
が、研磨粒による表面研摩時に混合した酸は潤滑剤とし
て研摩効果を高め、また研磨粒を包むようをこして均一
介在する酸が、研摩粒によつて浄化された後の表面に直
ちに強く吸着レＣ表面を包み強い被覆膜を形成してしま
うから、以後防錆、防汚効果を高め、酸のその吸着力に
より長く長期に亘つてその保護膜を形成維持する効果が
ある。Of course, the purifying agent may also contain polyphosphoric acid, oleic acid, etc. The acid is usually used as a solution of about 100 ppm to 1%, and the abrasive is mixed with this solution, and the mixing ratio of the acid and the abrasive grains is about 1 to 30% of the acid to the abrasive grains. The cleaning agent obtained as described above can be used, for example, by attaching it to a woven or knitted cloth and using it for para-polishing, etc. However, the acid mixed during surface polishing with abrasive particles acts as a lubricant and enhances the polishing effect. In addition, the acid that is uniformly present around the abrasive grains is immediately strongly adsorbed to the surface after it has been purified by the abrasive grains, forming a strong coating film that wraps around the surface. , it has the effect of increasing the antifouling effect and forming and maintaining the protective film for a long time due to its adsorption power of acid.
また浄化剤は、固体、粘土、液体等いずれも利用できる
が、液状体の場合、研摩、研摩液として利用され、バレ
ル、ラツピング、ハブ研摩等に利用されるが、この場合
、コーダミン等の着色料を液中に混合しておけば、研摩
液の着色模様によつて傷も検出することができる。即ち
、前記混合した酸は濡れ性が良く、傷等への浸透性が非
常に良い、しかも吸着力が高いため、着色料を傷部分へ
容易に浸透させ、且つそれを強く付着維持することがで
きる。このため被加工体の研摩加工中に着色料を傷部分
に浸透させ、加工後表面を拭き取れば傷の検査が同時に
できる効果がある。なお以上は一実施例の酸について説
明したが、本発明に利用される酸は、前記実施例の３−
ヒドロキシ−３．４デイカルボキシ・ベンタデ゛カノイ
ツク酸でなくても、そのラクトン型構造のもの、あるい
は酸もしくはラクトンの塩、酸もしくはラクトンのエス
テルが同様に利用でき、前記説明の如く極性基の吸着効
果等により実用上有効である。In addition, the purifying agent can be used in solid, clay, liquid, etc., but in the case of liquid, it is used as a polishing liquid, and is used for barrel, lapping, hub polishing, etc. In this case, it is used as a coloring agent such as cordamine. If a polishing agent is mixed in the polishing liquid, scratches can also be detected by the colored pattern of the polishing liquid. That is, the mixed acid has good wettability and very good permeability to scratches, etc., and also has high adsorption power, so that it can easily penetrate the colorant into the scratches and maintain a strong adhesion. can. For this reason, it is possible to simultaneously inspect the scratches by infiltrating the scratched part with a colorant during polishing of the workpiece and wiping the surface after polishing. Although the acid of one example has been described above, the acid used in the present invention is the acid of Example 3-3 above.
Even if hydroxy-3.4-dicarboxybentadecanoic acid is not used, its lactone-type structure, acid or lactone salt, or acid or lactone ester can be used in the same way, and as explained above, it can be used to adsorb polar groups. It is practically effective due to its effects, etc.
Claims (1)
ヒドロキシ−３．４デイカルボキシ・ペンタデカノイツ
ク酸またはラクトン、あるいはそれらの塩、それらのエ
ステルの少なくとも１種を添加してなる表面浄化剤。1. In surface cleaning agents using abrasive particles, 3-
A surface cleaning agent containing at least one of hydroxy-3.4-dicarboxypentadecanoic acid or lactone, a salt thereof, or an ester thereof.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP6813076A JPS591434B2 (en) | 1976-06-09 | 1976-06-09 | surface purifier |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP6813076A JPS591434B2 (en) | 1976-06-09 | 1976-06-09 | surface purifier |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPS52150405A JPS52150405A (en) | 1977-12-14 |
| JPS591434B2 true JPS591434B2 (en) | 1984-01-12 |
Family
ID=13364843
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP6813076A Expired JPS591434B2 (en) | 1976-06-09 | 1976-06-09 | surface purifier |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPS591434B2 (en) |
Families Citing this family (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2008150679A1 (en) * | 2007-05-30 | 2008-12-11 | Dow Global Technologies Inc. | Method of preparing glass and ceramic enamels on glass for adhesive bonding |
-
1976
- 1976-06-09 JP JP6813076A patent/JPS591434B2/en not_active Expired
Also Published As
| Publication number | Publication date |
|---|---|
| JPS52150405A (en) | 1977-12-14 |
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