JPS5916710B2 - Sea heater - Google Patents
Sea heaterInfo
- Publication number
- JPS5916710B2 JPS5916710B2 JP12156176A JP12156176A JPS5916710B2 JP S5916710 B2 JPS5916710 B2 JP S5916710B2 JP 12156176 A JP12156176 A JP 12156176A JP 12156176 A JP12156176 A JP 12156176A JP S5916710 B2 JPS5916710 B2 JP S5916710B2
- Authority
- JP
- Japan
- Prior art keywords
- heater
- sheathed heater
- metal pipe
- formula
- borazole
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
Landscapes
- Resistance Heating (AREA)
- Polymers With Sulfur, Phosphorus Or Metals In The Main Chain (AREA)
Description
【発明の詳細な説明】
本発明は吸湿によるシーズヒータの絶縁抵抗特性の改良
に関するものである。DETAILED DESCRIPTION OF THE INVENTION The present invention relates to improving the insulation resistance characteristics of a sheathed heater due to moisture absorption.
従来のシーズヒータは、一般に第1図に示すように、金
属パイプ1と、端子棒2を溶接したコイル状ヒータ3と
の間に電気絶縁材料4を充填している。In a conventional sheathed heater, as shown in FIG. 1, an electrically insulating material 4 is generally filled between a metal pipe 1 and a coiled heater 3 to which a terminal bar 2 is welded.
この際電気絶縁材料4としてはマグネシア5 粉末が最
も広く使用されろが、マグネシア粉末は吸湿性があるた
め、室内雰囲気で容易に吸湿し絶縁抵抗を劣化させると
いう欠点があつた。そこでこのマグネシア粉末にシリコ
ン樹脂を混合した後加熱し、マグネシア粉末表面にシリ
コン樹脂被膜’0 を形成させることにより、充填材表
面が撥水性を持ち、外部の湿気を容易に吸湿しなくなり
、絶縁性能の劣化を防止する方法が提案されている。し
かし、この方法では、シリコン樹脂の耐熱洞度が約35
0’Cと低いため、高温使用後において’5 は、シリ
コン樹脂の分解により撥水性が低下し、室内雰囲気中で
充填材が吸湿をおこし、絶縁特性の劣化をおこしやすい
という欠点があつた。本発明は、かかる欠点を克服する
もので、すなわちシーズヒータの高温使用によつても絶
縁特性j0が劣化しないように、電気絶縁材料に用いる
マグネシア粉末など自体の表面に高温加熱後も劣化しな
い撥水性を附与し、かつ長期間の使用によつても変質し
ないシーズヒータを提供するものである。以下、本発明
の一実施例を第2図に基ずいて説■5 明すると、第2
図において5はシーズヒータの外筐体を構成する金属パ
イプで、その中央にはヒータ6を有し、かつこのヒータ
6の両端にはそれぞれ金属パイプ5より突出する端子棒
1を設けている。8は金属パイプ5内に充填されたマグ
ネシア■0 粉末に、ボラゾール重合物を混合混和させ
た電気絶縁材料である。In this case, magnesia 5 powder is most widely used as the electrical insulating material 4, but since magnesia powder is hygroscopic, it has the disadvantage that it easily absorbs moisture in the indoor atmosphere and deteriorates the insulation resistance. Therefore, by mixing silicone resin with this magnesia powder and heating it to form a silicone resin film '0 on the surface of the magnesia powder, the surface of the filler becomes water repellent, does not easily absorb moisture from the outside, and has insulation performance. Methods have been proposed to prevent the deterioration of However, with this method, the heat resistance of the silicone resin is approximately 35.
Because of its low temperature of 0'C, '5 had the disadvantage that after high temperature use, its water repellency deteriorated due to the decomposition of the silicone resin, and the filler absorbed moisture in the indoor atmosphere, causing deterioration of its insulation properties. The present invention is intended to overcome such drawbacks, that is, to prevent the insulation properties j0 from deteriorating even when the sheathed heater is used at high temperatures, the surface of the magnesia powder used as an electrical insulating material itself has a repellent material that does not deteriorate even after high-temperature heating. To provide a sheathed heater that is water-based and does not deteriorate even after long-term use. Hereinafter, one embodiment of the present invention will be explained based on FIG.
In the figure, reference numeral 5 denotes a metal pipe constituting the outer casing of the sheathed heater, which has a heater 6 at its center, and terminal rods 1 protruding from the metal pipe 5 at both ends of the heater 6, respectively. Reference numeral 8 denotes an electrical insulating material in which a borazole polymer is mixed with magnesia 0 powder filled in the metal pipe 5.
上記の如く作られたシーズヒータに通電する事によV)
混合附与されたボラゾール重合物は加熱され粘度が低下
しマグネシア表面に被着しボラゾー5 ル重合体層を形
成する事により充填材は撥水性を発揮する。By energizing the sheathed heater made as above, V)
The mixed and applied borazole polymer is heated to lower its viscosity and adheres to the magnesia surface to form a borazole polymer layer, thereby making the filler water repellent.
かかるボラゾール重合物は、その一般式を下記に示すよ
うに、ボラゾールを重合させて得た無機高分子化合物で
あり、約600℃まで安定な撥水性高分子である。The borazole polymer is an inorganic polymer compound obtained by polymerizing borazole, and is a water-repellent polymer that is stable up to about 600°C, as its general formula is shown below.
上記の重合体を被着させたマグネシアを絶縁材料として
用いたシーズヒータは、シリコン樹脂を被着させたもの
より耐熱・撥水性の向上が見られ約600℃までの使用
に耐えるものが得られた。A sheathed heater using magnesia coated with the above polymer as an insulating material has improved heat resistance and water repellency than one coated with silicone resin, and can withstand use up to approximately 600°C. Ta.
以上のように、本発明シーズヒータは、金属パイプ内に
ヒータおよび端子部を絶縁保持する充填材料の粒子表面
にボラゾール重合体層を施しているため、撥水性を持ち
、かつ高温に充填材料が加熱された後も撥水性を失わな
い。さらに、その重合物が分解しても電気絶縁体となり
、電気絶縁特性を保持させるなどの特長を有し、その工
業的価値は大である。As described above, the sheathed heater of the present invention has a borazole polymer layer on the surface of the particles of the filling material that insulates and holds the heater and the terminal part in the metal pipe, so it has water repellency and the filling material does not resist at high temperatures. It does not lose its water repellency even after being heated. Furthermore, even when the polymer decomposes, it becomes an electrical insulator and retains its electrical insulation properties, making it of great industrial value.
第1図は従来のシーズヒータを示す断面図、第2図は本
発明の一実施例を示すシーズヒータの断面図である。
5・・・・・・金属パイプ、6・・・・・・ヒータ、r
・・・・・・端子棒、8・・・・・・電気絶縁材料。FIG. 1 is a sectional view of a conventional sheathed heater, and FIG. 2 is a sectional view of a sheathed heater according to an embodiment of the present invention. 5... Metal pipe, 6... Heater, r
...Terminal bar, 8...Electrical insulating material.
Claims (1)
間にマグネシア粉末などの電気絶縁材料を充填してなる
シーズヒータにおいて、前記充填材に一般式▲数式、化
学式、表等があります▼ 式中に示すRは有機基) で表わされるボラゾール重合物を混合附与させ、前記金
属パイプ内に充填することを特徴とするシーズヒータ。[Scope of Claims] 1. In a sheathed heater in which an electrical insulating material such as magnesia powder is filled between a coiled heater equipped with a terminal bar and a metal pipe, the filling material contains a general formula ▲mathematical formula, chemical formula, or table. etc.▼ A sheathed heater characterized in that a borazole polymer represented by the following formula (R in the formula is an organic group) is mixed and filled into the metal pipe.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP12156176A JPS5916710B2 (en) | 1976-10-08 | 1976-10-08 | Sea heater |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP12156176A JPS5916710B2 (en) | 1976-10-08 | 1976-10-08 | Sea heater |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPS5345744A JPS5345744A (en) | 1978-04-24 |
| JPS5916710B2 true JPS5916710B2 (en) | 1984-04-17 |
Family
ID=14814272
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP12156176A Expired JPS5916710B2 (en) | 1976-10-08 | 1976-10-08 | Sea heater |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPS5916710B2 (en) |
Families Citing this family (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4578283A (en) * | 1982-09-23 | 1986-03-25 | Allied Corporation | Polymeric boron nitrogen dopant |
| JP4915930B2 (en) * | 2007-03-27 | 2012-04-11 | 独立行政法人産業技術総合研究所 | Composition for forming borazine diamine polymer thin film and method for producing borazine diamine polymer thin film |
| JP4915929B2 (en) * | 2007-03-27 | 2012-04-11 | 独立行政法人産業技術総合研究所 | Borazine-diamine polymer, polymerizable composition therefor, and method for producing the same |
-
1976
- 1976-10-08 JP JP12156176A patent/JPS5916710B2/en not_active Expired
Also Published As
| Publication number | Publication date |
|---|---|
| JPS5345744A (en) | 1978-04-24 |
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