JPS5932097B2 - Cotton candy and its manufacturing method - Google Patents
Cotton candy and its manufacturing methodInfo
- Publication number
- JPS5932097B2 JPS5932097B2 JP52012008A JP1200877A JPS5932097B2 JP S5932097 B2 JPS5932097 B2 JP S5932097B2 JP 52012008 A JP52012008 A JP 52012008A JP 1200877 A JP1200877 A JP 1200877A JP S5932097 B2 JPS5932097 B2 JP S5932097B2
- Authority
- JP
- Japan
- Prior art keywords
- candy
- manufacturing
- cotton
- candy material
- fibrous
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 235000009508 confectionery Nutrition 0.000 title claims description 88
- 229920000742 Cotton Polymers 0.000 title claims description 24
- 238000004519 manufacturing process Methods 0.000 title claims description 15
- 239000000463 material Substances 0.000 claims description 48
- 235000000346 sugar Nutrition 0.000 claims description 19
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 18
- 229920002472 Starch Polymers 0.000 claims description 14
- 239000008107 starch Substances 0.000 claims description 14
- 235000019698 starch Nutrition 0.000 claims description 14
- 150000001720 carbohydrates Chemical class 0.000 claims description 11
- 239000000835 fiber Substances 0.000 claims description 9
- 238000010438 heat treatment Methods 0.000 claims description 5
- 150000002772 monosaccharides Chemical class 0.000 claims description 3
- 150000008163 sugars Chemical class 0.000 claims description 3
- 150000004043 trisaccharides Chemical class 0.000 claims description 3
- 108010009736 Protein Hydrolysates Proteins 0.000 claims 1
- 238000000034 method Methods 0.000 description 14
- 230000001055 chewing effect Effects 0.000 description 9
- 239000000203 mixture Substances 0.000 description 8
- 238000005259 measurement Methods 0.000 description 5
- 239000000155 melt Substances 0.000 description 4
- 238000002844 melting Methods 0.000 description 4
- 230000008018 melting Effects 0.000 description 4
- 230000001953 sensory effect Effects 0.000 description 4
- 235000020357 syrup Nutrition 0.000 description 4
- 239000006188 syrup Substances 0.000 description 4
- 102000004190 Enzymes Human genes 0.000 description 3
- 108090000790 Enzymes Proteins 0.000 description 3
- CZMRCDWAGMRECN-UGDNZRGBSA-N Sucrose Chemical compound O[C@H]1[C@H](O)[C@@H](CO)O[C@@]1(CO)O[C@@H]1[C@H](O)[C@@H](O)[C@H](O)[C@@H](CO)O1 CZMRCDWAGMRECN-UGDNZRGBSA-N 0.000 description 3
- 229930006000 Sucrose Natural products 0.000 description 3
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 description 3
- 238000005520 cutting process Methods 0.000 description 3
- 238000005516 engineering process Methods 0.000 description 3
- 125000002791 glucosyl group Chemical group C1([C@H](O)[C@@H](O)[C@H](O)[C@H](O1)CO)* 0.000 description 3
- 239000005720 sucrose Substances 0.000 description 3
- 238000012360 testing method Methods 0.000 description 3
- FBPFZTCFMRRESA-FSIIMWSLSA-N D-Glucitol Natural products OC[C@H](O)[C@H](O)[C@@H](O)[C@H](O)CO FBPFZTCFMRRESA-FSIIMWSLSA-N 0.000 description 2
- SRBFZHDQGSBBOR-IOVATXLUSA-N D-xylopyranose Chemical compound O[C@@H]1COC(O)[C@H](O)[C@H]1O SRBFZHDQGSBBOR-IOVATXLUSA-N 0.000 description 2
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 2
- 238000010521 absorption reaction Methods 0.000 description 2
- 238000011161 development Methods 0.000 description 2
- 238000007599 discharging Methods 0.000 description 2
- 238000011156 evaluation Methods 0.000 description 2
- 239000000796 flavoring agent Substances 0.000 description 2
- 235000019634 flavors Nutrition 0.000 description 2
- 239000001257 hydrogen Substances 0.000 description 2
- 229910052739 hydrogen Inorganic materials 0.000 description 2
- 239000002245 particle Substances 0.000 description 2
- 235000019685 rice crackers Nutrition 0.000 description 2
- 239000000600 sorbitol Substances 0.000 description 2
- 229910001220 stainless steel Inorganic materials 0.000 description 2
- 239000010935 stainless steel Substances 0.000 description 2
- 150000005846 sugar alcohols Chemical class 0.000 description 2
- OWEGMIWEEQEYGQ-UHFFFAOYSA-N 100676-05-9 Natural products OC1C(O)C(O)C(CO)OC1OCC1C(O)C(O)C(O)C(OC2C(OC(O)C(O)C2O)CO)O1 OWEGMIWEEQEYGQ-UHFFFAOYSA-N 0.000 description 1
- MIDXCONKKJTLDX-UHFFFAOYSA-N 3,5-dimethylcyclopentane-1,2-dione Chemical compound CC1CC(C)C(=O)C1=O MIDXCONKKJTLDX-UHFFFAOYSA-N 0.000 description 1
- GUBGYTABKSRVRQ-XLOQQCSPSA-N Alpha-Lactose Chemical compound O[C@@H]1[C@@H](O)[C@@H](O)[C@@H](CO)O[C@H]1O[C@@H]1[C@@H](CO)O[C@H](O)[C@H](O)[C@H]1O GUBGYTABKSRVRQ-XLOQQCSPSA-N 0.000 description 1
- FBPFZTCFMRRESA-KVTDHHQDSA-N D-Mannitol Chemical compound OC[C@@H](O)[C@@H](O)[C@H](O)[C@H](O)CO FBPFZTCFMRRESA-KVTDHHQDSA-N 0.000 description 1
- FBPFZTCFMRRESA-JGWLITMVSA-N D-glucitol Chemical compound OC[C@H](O)[C@@H](O)[C@H](O)[C@H](O)CO FBPFZTCFMRRESA-JGWLITMVSA-N 0.000 description 1
- 229930091371 Fructose Natural products 0.000 description 1
- 239000005715 Fructose Substances 0.000 description 1
- RFSUNEUAIZKAJO-ARQDHWQXSA-N Fructose Chemical compound OC[C@H]1O[C@](O)(CO)[C@@H](O)[C@@H]1O RFSUNEUAIZKAJO-ARQDHWQXSA-N 0.000 description 1
- WQZGKKKJIJFFOK-GASJEMHNSA-N Glucose Natural products OC[C@H]1OC(O)[C@H](O)[C@@H](O)[C@@H]1O WQZGKKKJIJFFOK-GASJEMHNSA-N 0.000 description 1
- GUBGYTABKSRVRQ-QKKXKWKRSA-N Lactose Natural products OC[C@H]1O[C@@H](O[C@H]2[C@H](O)[C@@H](O)C(O)O[C@@H]2CO)[C@H](O)[C@@H](O)[C@H]1O GUBGYTABKSRVRQ-QKKXKWKRSA-N 0.000 description 1
- GUBGYTABKSRVRQ-PICCSMPSSA-N Maltose Natural products O[C@@H]1[C@@H](O)[C@H](O)[C@@H](CO)O[C@@H]1O[C@@H]1[C@@H](CO)OC(O)[C@H](O)[C@H]1O GUBGYTABKSRVRQ-PICCSMPSSA-N 0.000 description 1
- 229930195725 Mannitol Natural products 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 230000004931 aggregating effect Effects 0.000 description 1
- PYMYPHUHKUWMLA-UHFFFAOYSA-N arabinose Natural products OCC(O)C(O)C(O)C=O PYMYPHUHKUWMLA-UHFFFAOYSA-N 0.000 description 1
- SRBFZHDQGSBBOR-UHFFFAOYSA-N beta-D-Pyranose-Lyxose Natural products OC1COC(O)C(O)C1O SRBFZHDQGSBBOR-UHFFFAOYSA-N 0.000 description 1
- WQZGKKKJIJFFOK-VFUOTHLCSA-N beta-D-glucose Chemical compound OC[C@H]1O[C@@H](O)[C@H](O)[C@@H](O)[C@@H]1O WQZGKKKJIJFFOK-VFUOTHLCSA-N 0.000 description 1
- GUBGYTABKSRVRQ-QUYVBRFLSA-N beta-maltose Chemical compound OC[C@H]1O[C@H](O[C@H]2[C@H](O)[C@@H](O)[C@H](O)O[C@@H]2CO)[C@H](O)[C@@H](O)[C@@H]1O GUBGYTABKSRVRQ-QUYVBRFLSA-N 0.000 description 1
- 235000015895 biscuits Nutrition 0.000 description 1
- 238000009835 boiling Methods 0.000 description 1
- 235000013736 caramel Nutrition 0.000 description 1
- 235000019219 chocolate Nutrition 0.000 description 1
- 239000000470 constituent Substances 0.000 description 1
- 238000001816 cooling Methods 0.000 description 1
- 230000007423 decrease Effects 0.000 description 1
- 230000007547 defect Effects 0.000 description 1
- 230000002542 deteriorative effect Effects 0.000 description 1
- 239000008157 edible vegetable oil Substances 0.000 description 1
- 235000013305 food Nutrition 0.000 description 1
- 235000003084 food emulsifier Nutrition 0.000 description 1
- 239000008103 glucose Substances 0.000 description 1
- 239000008101 lactose Substances 0.000 description 1
- XMGQYMWWDOXHJM-UHFFFAOYSA-N limonene Chemical compound CC(=C)C1CCC(C)=CC1 XMGQYMWWDOXHJM-UHFFFAOYSA-N 0.000 description 1
- 239000000845 maltitol Substances 0.000 description 1
- 235000010449 maltitol Nutrition 0.000 description 1
- VQHSOMBJVWLPSR-WUJBLJFYSA-N maltitol Chemical compound OC[C@H](O)[C@@H](O)[C@@H]([C@H](O)CO)O[C@H]1O[C@H](CO)[C@@H](O)[C@H](O)[C@H]1O VQHSOMBJVWLPSR-WUJBLJFYSA-N 0.000 description 1
- 229940035436 maltitol Drugs 0.000 description 1
- 239000000594 mannitol Substances 0.000 description 1
- 235000010355 mannitol Nutrition 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- 239000007968 orange flavor Substances 0.000 description 1
- 238000003825 pressing Methods 0.000 description 1
- -1 quinlitol Chemical compound 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 238000011160 research Methods 0.000 description 1
- 238000005070 sampling Methods 0.000 description 1
- 238000007493 shaping process Methods 0.000 description 1
- 235000011888 snacks Nutrition 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 238000009423 ventilation Methods 0.000 description 1
Landscapes
- Confectionery (AREA)
Description
【発明の詳細な説明】
本発明は表面が相互接合されて、所望の形状を呈した綿
状構造を有するもので、しかも噛食時に適度なもろさと
軟らかさがあり、更に口どけのよい良好な食感を呈する
綿状キャンデー及びその製造法に関するものである。DETAILED DESCRIPTION OF THE INVENTION The present invention has a flocculent structure with mutually joined surfaces and a desired shape, and has appropriate brittleness and softness when chewing, and has a good melt-in-the-mouth texture. The present invention relates to a cotton-like candy with a pleasant texture and a method for producing the same.
従来、綿状キャンデーは砂糖が繊維状に吐出したものを
回収集合させたものがほとんどであり、表面が相互接合
されて所望の形状を呈しているものは現在提案されて居
らない、又回収集合径吸湿により表面が溶解されたとし
ても部分的に相互接合が起るのみで、完全に連続した二
層断面構造(表面が密で内面が疎)を呈さす最後には溶
解、消滅してしまう、又噛食時に日中で瞬時に溶解して
充分に賞味出来ない欠点がある。Conventionally, most cotton-like candy has been made by collecting and aggregating sugar discharged in the form of fibers, and currently no candy has been proposed in which the surfaces are joined together to form a desired shape. Even if the surface is dissolved due to moisture absorption, only partial bonding will occur, and a completely continuous two-layer cross-sectional structure (the surface is dense and the inner surface is sparse) will eventually dissolve and disappear. Moreover, it has the disadvantage that it dissolves instantaneously during the day when chewing, making it difficult to fully enjoy it.
また、従来綿状キャンデーの連続製造法は、加熱部並び
に吐出口と投入口を有する回転体に砂糖を添加し、砂糖
を溶融させた後、遠心力により繊維状に吐出し綿状構造
を呈したものを採取している方法がほとんどである。In addition, in the conventional continuous manufacturing method for cotton candy, sugar is added to a rotating body that has a heating section, a discharge port, and an input port, and after the sugar is melted, centrifugal force is used to discharge it in the form of fibers to form a cotton-like structure. Most of the methods are to collect the raw material.
だが該方法では綿状キャンデーを採取する際、綿状キャ
ンデーが吸湿したり又、繊維状に吐出後1品温低下が不
充分であったりすると採取壁に付着が促進し、再に綿状
キャンデーが集積して、密度が部分的に不均一な綿状キ
ャンデーを生起させる事が多く又綿状キャンデーを連続
採取する場合、吐出口が回転しているため繊維状に吐出
されたキャンデー材料が再び該回転体に巻き込まれたり
、綿状キャンデーの吸湿及び品温低下が不充分であると
採取壁に付着並びに集積が生起し、連続採取時につまり
易く、送風等の繰作を実施したとしても完全に綿状キャ
ンデーを連続的に回収集合することは非常に困難であり
、収率もわるく問題である。However, with this method, when collecting the cotton candy, if the cotton candy absorbs moisture or the temperature of the candy is not lowered enough after being discharged into fibers, it will adhere to the collection wall and the cotton candy will re-produce. This often results in fluffy candy with partially uneven density.Also, when cottony candy is collected continuously, since the discharge port is rotating, the candy material that has been discharged in the form of fibers is recycled. If the cotton candy gets caught in the rotating body or the cotton candy absorbs moisture and temperature is insufficient, it will stick and accumulate on the collection wall, and it will easily become clogged during continuous collection, and even if repeated ventilation etc. It is very difficult to collect and collect cotton candy continuously, and the yield is also low.
そこで上述の欠点を解消せんとして特公昭41−217
42号に示す如く送風機により圧力空気を送入する様に
したエアーチャンバーの出口に、砂糖を溶融するための
ヒーターとその溶体を噴出するためのノズル孔を備えて
、エアーチャンバー内に投入された砂糖が前記ヒーター
によって溶融され、同時に空気圧によってノズル孔から
繊維状に噴出し、連続採取する方法が提案されている。Therefore, in order to eliminate the above-mentioned drawbacks, the special public
As shown in No. 42, the outlet of the air chamber was equipped with a heater for melting sugar and a nozzle hole for spouting out the solution, and the sugar was placed in the air chamber. A method has been proposed in which sugar is melted by the heater and at the same time is ejected in the form of fibers from a nozzle hole using air pressure to continuously collect the sugar.
しかしながら該方法も圧力空気温度並びに送風量及びノ
ズル孔径の調整操作等に高度の技術を必要とし、又設備
が超大型で精度の高い装置を必要とするので経済的な方
法ではな(、更に溶融した砂糖がノズルチャンバー及び
/又はノズル孔内でカラメル化される欠点を有し、風味
を低下させるので問題である。However, this method also requires advanced technology to adjust the pressure air temperature, air flow rate, and nozzle hole diameter, and requires extremely large and highly accurate equipment, so it is not an economical method (furthermore, it is not an economical method). This is a problem because the sugar that has been removed has the disadvantage of being caramelized in the nozzle chamber and/or nozzle orifice, reducing the flavor.
そこで本発明者等は上述の如き欠点を改良すべく鋭意研
究した結果、本発明を完成した。Therefore, the inventors of the present invention have completed the present invention as a result of intensive research to improve the above-mentioned drawbacks.
本発明の目的は表面が相互接合されて所望の形状を呈し
た綿状構造を有するもので、しかも噛食時に適度なもろ
さと軟らかさがあり、更に口どけのよい良好な食感を呈
する綿状キャンデーを提供するにある。The object of the present invention is to provide a cotton that has a cotton-like structure with mutually bonded surfaces and a desired shape, has appropriate brittleness and softness when chewing, and has a good texture that melts in the mouth. It's there to provide shaped candy.
又他の目的は工業的容易且つ安価に連続して該綿状キャ
ンデーの成型品を製造する方法を提供するものである。Another object of the present invention is to provide a method for continuously producing molded cotton candy products industrially easily and inexpensively.
即ち本発明は100℃に於いて200〜
12000ポイズの粘度を有し、水分含有量が0.5〜
50重量%で、少なくとも一種類の糖類を含む、繊維状
キャンデー材料が綿状構造を有し、表面が相互接合され
た所望の形状を呈している見掛は密度2.0〜90.0
X10−2グ/dの綿状キャンデーである。That is, the present invention has a viscosity of 200 to 12,000 poise at 100°C and a water content of 0.5 to 12,000 poise.
The fibrous candy material containing at least one type of saccharide at 50% by weight has a flocculent structure and a desired shape with interconnected surfaces and an apparent density of 2.0 to 90.0.
It is a cotton candy of X10-2 g/d.
又本発明は少なくとも一種類の糖類を含むキャンデー材
料を加熱して溶解、溶融した後、繊維状に吐出し、次に
該繊維状キャンデー材料を所望の形状にした後、表面を
加熱するか又は吸湿により相互接合させて成型する事を
特徴とする綿状キャンデーの製造法である。In addition, the present invention involves heating a candy material containing at least one type of saccharide, melting it, discharging it in the form of fibers, shaping the fibrous candy material into a desired shape, and then heating the surface or melting the candy material. This is a method for producing cotton-like candy, which is characterized in that it is molded by being bonded together due to moisture absorption.
以下本発明の実施の態様を詳説する。Embodiments of the present invention will be explained in detail below.
本発明で云う粘度とは、メルトインデクサ−により求め
た粘度を云い、水分含有量はカールフィッシャー法によ
り求めた水分含有量を意味する。In the present invention, the viscosity refers to the viscosity determined by a melt indexer, and the water content refers to the water content determined by the Karl Fischer method.
また繊維状キャンデー材料の径とは長手方向に対して直
角に切断した断面の外径を云い、更に見掛は密度とは綿
状キャンデーの総重量に対する綿状キャンデーの見掛は
総体積の比を云う。In addition, the diameter of a fibrous candy material refers to the outer diameter of a cross section cut at right angles to the longitudinal direction, and the apparent density is the ratio of the apparent volume of cotton candy to the total weight of cotton candy material. says.
本発明の糖類は単糖類としてグルコース、フラクトース
、キシロース等を挙げることが出来、又三糖類としては
蔗糖、マルトース、ラクトース等を挙げることが出来る
。Examples of the saccharides of the present invention include glucose, fructose, xylose, etc. as monosaccharides, and sucrose, maltose, lactose, etc. as trisaccharides.
更に澱粉加水分解物としては酸及び/又は酵素糖化水飴
、グルコース単位(平均)7〜18の澱粉加水分解物等
を挙げる事が出来る。Further, examples of the starch hydrolyzate include acid and/or enzyme saccharified starch syrup, starch hydrolyzate having 7 to 18 glucose units (on average), and the like.
又非還元性澱粉加水分解物としては、ソルビトール、マ
ンニトール、キンリトール、マルチトール及びグルコー
ス単位(平均)7〜18の澱粉加水分解物を更に水素還
元した糖アルコール等を挙げる事が出来、そしてこれら
の各単体及び/又はその組合せからなるものを意味する
。Examples of non-reducible starch hydrolysates include sorbitol, mannitol, quinlitol, maltitol, and sugar alcohols obtained by further hydrogen reduction of starch hydrolysates having 7 to 18 glucose units (on average). Refers to each element and/or a combination thereof.
また繊維状キャンデー材料は上述の粘度と水分含有量並
びに、少なくとも一種類の糖類より構成されており、必
要に応じて香料及び呈味物質が添加されているものを意
味する。In addition, the fibrous candy material has the above-mentioned viscosity and water content, and is composed of at least one type of saccharide, with flavoring and taste substances added as necessary.
また綿状キャンデーは見掛は密度が2.0〜90.0X
10−2グ/dの綿状構造を有し、表面が均一に相互接
合された立方体、直方体、円柱体等の所望の形状を呈し
ている事を意味し、表面が密で内面が疎の連続した断面
構造を有している事が望ましい。Also, the apparent density of cotton candy is 2.0 to 90.0X.
It has a cotton-like structure of 10-2 g/d and has a desired shape such as a cube, rectangular parallelepiped, cylinder, etc. with uniformly interconnected surfaces, and the surface is dense and the inner surface is sparse. It is desirable to have a continuous cross-sectional structure.
本発明の繊維状キャンデー材料の粘度は100’GK於
いて200〜12000ポイズであり、好ましくは10
00〜10000ポイズ、更に好ましくは、2000〜
7000ポイズである。The viscosity of the fibrous candy material of the present invention is 200 to 12,000 poise at 100'GK, preferably 10
00 to 10,000 poise, more preferably 2,000 to
It is 7000 poise.
キャンデー材料の粘度が12000ポイズより高くなる
と、キャンデー材料をノズルへ供給する過程で所定の供
給粘度(2000ポイズ以下)まで低下させる必要があ
り、キャンデー材料を高温で保持しなくてはならないの
で、熱により糖類が熱分解されてカラメルが生起し、こ
げつきを生じてキャンデー材料が吐出しない欠点が生じ
る。When the viscosity of the candy material becomes higher than 12,000 poise, it is necessary to reduce the supply viscosity to a predetermined value (below 2,000 poise) during the process of supplying the candy material to the nozzle, and the candy material must be kept at a high temperature. As a result, sugars are thermally decomposed and caramel is produced, resulting in burntness and the drawback that the candy material cannot be discharged.
また粘度が200ポイズより小さくなると固形点(成型
した際一定の形状をもつ温度)が常温附近になり固化さ
れるのに長時間を要し、常温で綿状構造を形成する事が
出来ない。Furthermore, if the viscosity is lower than 200 poise, the solid point (the temperature at which a certain shape is formed when molded) reaches around room temperature, and it takes a long time to solidify, making it impossible to form a flocculent structure at room temperature.
又繊維状キャンデー材料の水分含有量は0.5〜5重量
%、好ましくは1〜4重量%である。The moisture content of the fibrous candy material is 0.5 to 5% by weight, preferably 1 to 4% by weight.
水分含有量が5重量%より多くなると噛食時に歯に付着
して食感を低下させる欠点を有し、又0.5重量%より
少なくなるとキャンデー材料は、加熱時に糖類の一部が
熱分解してカラメルが生起し、着色が犬になると共に風
味を低下させる欠点を有して来る。If the water content is more than 5% by weight, it will stick to the teeth when chewing and reduce the texture, and if it is less than 0.5% by weight, some of the sugars in the candy material will be thermally decomposed when heated. This results in caramelization, which has the disadvantage of imparting color and deteriorating flavor.
なお上述のキャンデー材料に食用油脂及び/又は食品乳
化剤を適量添加することによって水分含有量が5重量%
より多くなっても噛食時に歯に付着しないキャンデー材
料を得ることが可能である。By adding an appropriate amount of edible oil and fat and/or food emulsifier to the above-mentioned candy material, the water content can be reduced to 5% by weight.
It is possible to obtain a candy material that does not adhere to the teeth during chewing even if the amount is increased.
更に上述の繊維状キャンデー材料を得るためには、ステ
ンレス製平鍋、又は真空煮詰機に少なくとも一種類の糖
類と糖類を溶解させるに必要量の水を添加し、加熱して
溶解、溶融した後、少な(とも1ケ所の小孔を有するノ
ズルから連続して吐出する事によって得る事が出来る。Furthermore, in order to obtain the above-mentioned fibrous candy material, at least one type of saccharide and the amount of water necessary to dissolve the saccharide are added to a stainless steel pan or a vacuum boiling machine, and the mixture is heated to melt and melt. It can be obtained by continuously ejecting from a nozzle with a small hole (at least one small hole).
この時糖類を溶解させるに必要量の水は糖類に対して少
なくとも10重量%添加するのが望ましい。At this time, it is desirable that the amount of water necessary to dissolve the saccharides is at least 10% by weight based on the saccharides.
10重量%より少なくなるとキャンデー材料を加熱して
も完全に溶解されないために例えば結晶性糖類を多量に
使用した組成のものは糖化な起し綿状構造を形成しえな
い場合がある。If the amount is less than 10% by weight, it will not be completely dissolved even when the candy material is heated, and therefore, for example, compositions containing a large amount of crystalline saccharide may not undergo saccharification and may not be able to form a flocculent structure.
又ノズルの孔径は0.05〜2.0mm、好ましくは0
.07〜1.6mm、更に好ましくは0.1〜1.0m
mである。Also, the hole diameter of the nozzle is 0.05 to 2.0 mm, preferably 0.
.. 07-1.6mm, more preferably 0.1-1.0m
It is m.
孔径が0.05mmより小さくなるとキャンデー材料を
吐出する際、圧力が過大になり、吐出しない場合があり
好ましくない、またノズルの作製も高度の技術を要する
。If the hole diameter is smaller than 0.05 mm, the pressure will be too high when discharging the candy material, which may not be possible, which is undesirable, and the production of the nozzle also requires advanced technology.
なおノズルの工作技術の向上及びさらに耐圧性のある装
置が開発されればノズル孔径をさらに小さくして実施す
る事も可能である。Note that if the nozzle manufacturing technology improves and a pressure-resistant device is developed, it is possible to make the nozzle hole diameter even smaller.
また2rIL1rtより大きくなるとノズル吐出直後の
キャンデー材料各部の温度むらが大きくなり吐出前の圧
力と吐出後の圧力差が顕著に出てキャンデー材料が吐出
後過度に膨張してノズルの吐出面に付着する場合があり
好ましくない。In addition, if it is larger than 2rIL1rt, the temperature unevenness of each part of the candy material immediately after being discharged from the nozzle becomes large, and the difference in pressure before and after discharge becomes significant, causing the candy material to expand excessively after being discharged and adhere to the discharge surface of the nozzle. There are cases where this is not desirable.
また吐出時のキャンデー材料の吐出粘度は少なくとも1
000ポイズあればよく、好ましくは2000〜150
000ポイズの範囲にする事が望ましい。Furthermore, the discharge viscosity of the candy material at the time of discharge is at least 1
000 poise is sufficient, preferably 2000 to 150
It is desirable to set it in the range of 000 poise.
本発明のキャンデー材料の吐出は、公知のギヤーポンプ
、スクリューポンプ等を使用するか又は加圧する事によ
って行なわれる。The candy material of the present invention is discharged using a known gear pump, screw pump, etc., or by applying pressure.
しかし吐出方法についてはこれらの方法に限定されるも
のではない。However, the ejection method is not limited to these methods.
またキャンデー材料の吐出流量は高々10cc/m1y
t/ノズル孔、好ましくはBcc/min/ノズル孔以
下にする事孔型下しい。Also, the discharge flow rate of candy material is at most 10cc/m1y.
t/nozzle hole, preferably less than Bcc/min/nozzle hole.
吐出流量が10cc/m1yt/ノズル孔より大きくな
ると、吐出前の圧力と吐出後の圧力差が大きくなりキャ
ンデー材料が吐出後過度に膨張して吐出口に付着する場
合があるので好ましくない。If the discharge flow rate is greater than 10 cc/ml/nozzle hole, the difference between the pressure before discharge and the pressure after discharge will become large, and the candy material may expand excessively after discharge and adhere to the discharge port, which is not preferable.
上述の条件で吐出した繊維状キャンデー材料は自然落下
させて、自重により径が高々1.、Omm、好ましくは
0.8 mm以下まで延伸し、集合させる。The fibrous candy material discharged under the above conditions is allowed to fall naturally, and its diameter decreases by at most 1.5 mm due to its own weight. , Omm, preferably 0.8 mm or less, and aggregated.
径の大小は落下距離を適宜変化させる事により調整すれ
ばよい。The size of the diameter may be adjusted by appropriately changing the falling distance.
径がLOmrnより大きくなると噛食時に適宜なもろさ
及び軟らかさがなくなり口どけが悪くなる場合があるの
で好ましくない。If the diameter is larger than LOmrn, it is not preferable because it may not have appropriate brittleness and softness during chewing and may not melt in the mouth.
また該キャンデー材料は、ノズルより連続して吐出する
ため吐出後、多少吸湿が起っても、従来の綿状キャンデ
ーの様な付着並びに集積が起らず密度が均一な該キャン
デー材料の集合体を容易に採取する事が出来るこの事は
本発明の特長の一つでもある。In addition, since the candy material is continuously discharged from the nozzle, even if it absorbs some moisture after being discharged, it does not adhere or accumulate like conventional cotton-like candy, resulting in an aggregate of the candy material with a uniform density. This fact that can be easily collected is also one of the features of the present invention.
次に上述の集合された繊維状キャンデー材料を立方体、
直方体、円柱体等の所望の形状の型に充填するか又は型
抜きした後、表面を熱風、又は赤外線等で加熱して溶融
させるか又は表面に水を噴霧させたり、また恒温恒湿機
に放置させる等の操作を実施する事により表面を吸湿さ
せ溶解する事によって繊維状キャンデー材料を相互接合
させた後、常温の室内で放冷又は放置する事により固化
されて見掛は密度が2.0〜90.0X10−29/c
燃好ましくは10.0〜80.0X10−2?/ant
、更に好ましくは40〜70×10−27/c111の
綿状キャンデーを得る事が出来る。Next, the aggregated fibrous candy material mentioned above is cubed,
After filling or cutting into a mold of a desired shape such as a rectangular parallelepiped or cylinder, the surface is heated with hot air or infrared rays to melt it, or the surface is sprayed with water, or placed in a constant temperature and humidity machine. After the fibrous candy materials are mutually bonded by allowing the surface to absorb moisture and melting by performing an operation such as allowing it to stand, it is solidified by cooling or standing in a room at room temperature, with an apparent density of 2. 0~90.0X10-29/c
Preferably 10.0~80.0X10-2? /ant
, more preferably a cotton candy having a particle size of 40 to 70×10 −27 /c111.
見掛は密度が90.0xlO−2?/critより大き
くなると噛食時に適度なもろさ及び軟らかさがなくなり
、口どけが悪くなる欠点を有し、又2.0X10 ”
?/critより小さくなると綿状キャンデーの組織
強度が弱くなり、型くずれ等の欠点を有する。The apparent density is 90.0xlO-2? If it is larger than /crit, it will not have appropriate brittleness and softness when chewing, and it will not melt in the mouth.
? If it is smaller than /crit, the tissue strength of the cotton candy becomes weak, resulting in defects such as deformation.
この様に綿状キャンデーを上述の方法により所望の形状
に成型し得た事は本発明の特長の一つでもある。It is one of the features of the present invention that cotton-like candy can be molded into a desired shape by the above-described method.
本発明の綿状キャンデーは上述の如く表面が相互接合さ
れて所望の形状を呈した綿状構造を有するもので、しか
も噛食時に適度なもろさと軟らかさかあり更に口どけの
よい良好な食感を呈するものであるので、この物自身商
品価値が高く、又これらのキャンデーをチョコレートあ
るいはスナック菓子(ビスケット、せんべい、おかき等
)などと組合せる事により更に商品価値をたかめられ、
その応用開発分野は広く、工業的価値は極めて太きいも
のである。The cotton-like candy of the present invention has a cotton-like structure in which the surfaces are joined together to form a desired shape, as described above, and has appropriate brittleness and softness when chewing, and also has a good texture that melts in the mouth. Therefore, this product itself has high commercial value, and by combining these candies with chocolate or snack foods (biscuits, rice crackers, rice crackers, etc.), the commercial value can be further increased.
Its application and development fields are wide-ranging, and its industrial value is extremely significant.
又本発明で特筆すべき事項は、在来なかった所望の形状
を有する綿状キャンデーの成型品が連続且つ容易にしか
も安価に製造出来る事を確立し得た事である。Another noteworthy feature of the present invention is that it has been established that a cotton-like candy molded product having a desired shape, which has not been seen before, can be produced continuously, easily, and at low cost.
この事により今後の応用開発分野が巾広くなり、その工
業的価値は極めて重要視されるものである。This will expand the field of application development in the future, and its industrial value will be extremely important.
以下、本発明の詳細な説明する。The present invention will be explained in detail below.
実施例に示す部とは重量部を、%とは重量%を意味する
。In the examples, parts mean parts by weight, and % means weight %.
又粘度、水分、繊維状キャンデー材料の径、見掛は密度
、官能検査を次の如〈実施した。In addition, viscosity, water content, diameter of the fibrous candy material, apparent density, and sensory tests were conducted as follows.
(1)粘度測定
メルトインデクサ−を使用して試料57、試料粒度10
0メツシユ以下、測定温度100℃、加重量216kg
、オリフィス半径0.0256rfL。(1) Viscosity measurement using a melt indexer, sample 57, sample particle size 10
0 mesh or less, measurement temperature 100℃, weight 216kg
, orifice radius 0.0256rfL.
オリフィス長さ0.1 cm、シリンダー断面積0.7
05部mfの条件下で3分間の吐出量を測定し次式によ
り粘度を算出した。Orifice length 0.1 cm, cylinder cross-sectional area 0.7
The discharge amount for 3 minutes was measured under the condition of 0.05 parts mf, and the viscosity was calculated using the following formula.
4.6 μ:粘度(ポイズ) Q:吐出量(cc/ sec ) (2)水分測定 カールフィッシャ水分測定機を使用して測定した。4.6 μ: Viscosity (poise) Q: Discharge amount (cc/sec) (2) Moisture measurement Measured using a Karl Fischer moisture meter.
(3)繊維状キャンデー材料の径の測定
ランダムにサンプリングした繊維状キャンデー材料50
本を長手方向に対して直角に切断した後、30倍工具顕
微鏡を使用して測定しその平均値をもって径とした。(3) Measurement of diameter of fibrous candy material 50 randomly sampled fibrous candy materials
After cutting the book at right angles to the longitudinal direction, it was measured using a 30x tool microscope, and the average value was taken as the diameter.
(4)見掛は密度の測定 次式により見掛は密度を算出した。(4) Appearance is a measurement of density The apparent density was calculated using the following formula.
綿状キャンデーの総重量(7)
見掛は密度(秩d)−□
綿状キャンデーの総体積(d)
(5)官能検査
食感評価点は噛食時の官能評価を示し、パネル50人が
判定したもので非常に良いを10点、良いを8点、普通
を6点、悪いを4点、非常に悪いを2点として平均値で
表わした。Total weight of cotton candy (7) Appearance is density (chichi d) - □ Total volume of cotton candy (d) (5) Sensory test The texture evaluation score indicates the sensory evaluation during chewing, and was evaluated by a panel of 50 people. 10 points for very good, 8 points for good, 6 points for fair, 4 points for poor, and 2 points for very poor, and the average value is expressed.
(小数点以下四捨五入)また「歯に付着する、硬すぎる
、軟らかすぎる」の食感感想事項は、パネル50人中で
指摘(感知)した人数を示した。(Rounded to the nearest whole number) In addition, the number of people who pointed out (sensed) the texture impressions of ``sticks to teeth, too hard, too soft'' out of 50 panelists is shown.
実施例 1
ステンレス製平鍋に蔗糖600部、酵素糖化水飴(ME
73)400部、水180部を添加し、次に加熱して完
全に溶解した後、水分含有量が3%になるまで煮詰め冷
却後、クエン酸6部、オレンジ香料5部を添加し、よく
混合して、100℃に於ける粘度が3000ポイズのキ
ャンデー材料、1040部を得た。Example 1 In a stainless steel pan, 600 parts of sucrose and enzyme saccharified starch syrup (ME
73) Add 400 parts and 180 parts of water, then heat to completely dissolve, boil until the water content is 3%, cool, add 6 parts of citric acid and 5 parts of orange flavor, and mix well. Mixing yielded 1040 parts of a candy material having a viscosity of 3000 poise at 100°C.
更にキャンデー材料の吐出粘度を3000ポイズに保持
しながらノズル孔径0、25 mmを有する12ケ所の
ノズルより吐出流量2 cc /min/ノズル孔で連
続して繊維状に吐出した後、自重延伸しながら落下間隔
1.2 mの採取面に自然落下させて径0.1 mrn
の繊維状キャンデー材料を得た。Furthermore, while maintaining the discharge viscosity of the candy material at 3000 poise, it was continuously discharged in the form of fibers from 12 nozzles with nozzle diameters of 0 and 25 mm at a discharge flow rate of 2 cc/min/nozzle hole, and then stretched under its own weight. A diameter of 0.1 mrn was obtained by letting it fall naturally onto a sampling surface with a falling interval of 1.2 m.
A fibrous candy material was obtained.
該キャンデー材料を型抜きした後、六方より赤外線ラン
プで照射し表面のみ溶融した後、25℃の室内に放冷し
、5mmX5關×5mrILの立方体形状を有した見掛
は密度60.OX 10−”ifΔ需の綿状キャンデー
を得た(本発明品)。After cutting out the candy material, it was irradiated with an infrared lamp from hexagonal directions to melt only the surface, and then left to cool in a room at 25°C. It had an apparent cubic shape of 5mm x 5mm x 5ml and had a density of 60. A fluffy candy with OX 10-"ifΔ demand was obtained (product of the present invention).
次に実施例1(本発明品)と市販の綿状キャンデーにつ
いて径並びに見掛は密度の測定及び官能検査、写真観察
を実施し、その結果を表−1に示した。Next, the diameter and apparent density of Example 1 (product of the present invention) and commercially available cotton candy were measured, and sensory tests and photographic observations were carried out, and the results are shown in Table 1.
以上の結果からも明らかな様に、本発明品は食感が非常
に良好なものである事が判明し、又第1図より綿状キャ
ンデーの成型品として完成されたものである事は明白で
あり、本発明の目的を達成するものである。As is clear from the above results, the product of the present invention was found to have a very good texture, and it is clear from Figure 1 that it is a completed product as a cotton candy molded product. This achieves the object of the present invention.
実施例 2
実施例1の糖組成を表−2に示す様な糖組成に変える他
は実施例1と同様に実施し、その結果を表−2に示した
。Example 2 The same procedure as in Example 1 was carried out except that the sugar composition of Example 1 was changed to the sugar composition shown in Table 2, and the results are shown in Table 2.
尚、砂糖600部、酵素糖化水飴400部の組成は実施
例1である。The composition of 600 parts of sugar and 400 parts of enzyme-saccharified starch syrup was as in Example 1.
又、非還元性澱粉加水分解物は、グルコース単位(平均
)7〜18の澱粉加水分解物を更に水素還元した糖アル
コールを使用した。As the non-reducible starch hydrolyzate, a sugar alcohol obtained by further hydrogen reduction of a starch hydrolyzate having 7 to 18 glucose units (on average) was used.
以上の結果からも明らかな様にいずれの糖組成のものも
本発明の目的及び構成要件を満足する綿状キャンデーで
ある事が判明した。As is clear from the above results, it was found that all sugar compositions were cotton-like candies that satisfied the objectives and constituent requirements of the present invention.
実施例 3
実施例1の糖組成をソルビトール200部、蔗糖400
部、酵素糖化水飴400部と水分含有量を表−3に示す
様に変える他は実施例1と同様に実施し、その結果を表
−3に示した。Example 3 The sugar composition of Example 1 was changed to 200 parts of sorbitol and 400 parts of sucrose.
Example 1 was carried out in the same manner as in Example 1, except that the enzyme saccharified starch syrup was changed to 400 parts and the water content was changed as shown in Table 3, and the results are shown in Table 3.
以上の結果からも明らかな様に水分含有量は、0.5〜
5重量%好ましくは1〜4重量%にする必要がある。As is clear from the above results, the water content ranges from 0.5 to
It should be 5% by weight, preferably 1-4% by weight.
実施例 4
実施例1の水分含有量を変化させる事により、100℃
に於ける粘度を表−4に示す様に変える他は実施例1と
同様に実施しその結果を表−4に示した。Example 4 By changing the water content of Example 1, the temperature at 100°C
Example 1 was carried out in the same manner as in Example 1, except that the viscosity was changed as shown in Table 4, and the results are shown in Table 4.
以上の結果からも明らかな様に100℃に於ける粘度は
200〜12000ポイズ、好ましくは、1000〜1
0000ポイズ、更に好ましくは2000〜7000ポ
イズにする必要がある。As is clear from the above results, the viscosity at 100°C is 200 to 12,000 poise, preferably 1,000 to 1
0,000 poise, more preferably 2,000 to 7,000 poise.
実施例 5
実施例1のノズル孔径を表−5に示す様に変える他は、
実施例1と同様に実施し、その結果を表−5に示した。Example 5 Except for changing the nozzle hole diameter of Example 1 as shown in Table 5,
It was carried out in the same manner as in Example 1, and the results are shown in Table 5.
以上の結果から明らかな様にノズル孔径は0、05〜2
.0mm、好ましくは0.07〜1.6mm、更に好ま
しくは0.1〜1.0mmが好ましい。As is clear from the above results, the nozzle hole diameter is 0.05~2.
.. 0 mm, preferably 0.07 to 1.6 mm, more preferably 0.1 to 1.0 mm.
実施例 6
実施例1の見掛は密度を表−6に示す様に変える他は、
実施例1と同様に実施し、その結果を表−6に示した。Example 6 The apparent density of Example 1 was changed as shown in Table 6.
It was carried out in the same manner as in Example 1, and the results are shown in Table 6.
以上の結果からも明らかな様に見掛は密度は、2.0〜
90. OX 10−2 グ/d好ましくは10.0
〜80.OX]、O−2グ/l、更に好ましくは40〜
70X 1.0 ” fZ/crttにする必要があ
る。As is clear from the above results, the apparent density is 2.0~
90. OX 10-2 g/d preferably 10.0
~80. OX], O-2 g/l, more preferably 40~
It is necessary to set it to 70X 1.0” fZ/crtt.
実施例 7
実施例1のノズル孔径を表−7に示す様に変化させる事
により繊維径を表−7に示す様に変える他は実施例1と
同様に実施し、その結果を表−7に示した。Example 7 The procedure was carried out in the same manner as in Example 1, except that the nozzle hole diameter of Example 1 was changed as shown in Table 7, and the fiber diameter was changed as shown in Table 7. The results are shown in Table 7. Indicated.
以上の結果からも明らかな様に繊維状キャンデー材料の
径は高々1.0mm、好ましくは0.8 mrn以下に
することが好ましい。As is clear from the above results, the diameter of the fibrous candy material is preferably at most 1.0 mm, preferably 0.8 mrn or less.
第1図は実施例1(本発明品)で得られた綿状キャンデ
ーの一部を剥離した斜視図である。FIG. 1 is a partially peeled perspective view of the cotton candy obtained in Example 1 (product of the present invention).
Claims (1)
有し、水分含有量が0.5〜5.0重量%で、少なくと
も一種類の糖類を含む繊維状キャンデー材料が綿状構造
を有し、表面が相互接合された所望の形状を呈している
見掛は密度2.0X90.0Xio”y/=の綿状キャ
ンデー。 2 糖類は単糖類、三糖類、澱粉加水分解物、非還元性
澱粉加水分解物の各単体及びその組合せからなる特許請
求の範囲第1項記載の綿状キャンプ0 3 粘度が100℃に於いて、1000〜1ooooポ
イズである特許請求の範囲第1項記載の綿状キャンデー
。 4 水分含有量が1〜4重量%である特許請求の範囲第
1項記載の綿状キャンデー。 5 繊維状キャンデー材料は径が高々1.0mmである
特許請求の範囲第1項記載の綿状キャンデー。 6 綿状キャンデーは表面が密で、内面が疎の連続した
断面を有する特許請求の範囲第1項記載の綿状キャンデ
ー。 7 少なくとも一種類の糖類な含むキャンデー材料を加
熱して溶解・溶融した後、繊維状に吐出し、次に該繊維
状キャンデー材料を所望の形状にした後、表面を加熱す
るか又は吸湿により、相互接合させて、成型する事を特
徴とする綿状キャンデーの製造法。 8 糖類は単糖類、三糖類、澱粉加水分解物、非還元性
澱粉加水分解物の各単体及びその組合せからなる特許請
求の範囲第7項記載の製造法。 9 キャンデー材料を加熱する除水を添加する特許請求
の範囲第7項記載の製造法。 10 糖類を溶解する水の添加量は糖類に対して少な
くとも10重量%である特許請求の範囲第9項記載の製
造法。 11 吐出は少なくとも一つの小孔を有するノズルに
て行なう特許請求の範囲第7項記載の製造法。 12 ノズルの孔径は0.05〜2.0 mynであ
る特許請求の範囲第11項記載の製造法。 13 キャンデー材料の吐出粘度が少なくとも100
0ポイズである特許請求の範囲第7項記載の製造法。 14 キャンデー材料の吐出流量が高々10 cc7
fnm/ノズル孔である特許請求の範囲第7項記載の製
造法。 15 繊維状キャンデー材料の径が高々1.、Omm
である特許請求の範囲第7項記載の製造法。 16 綿状キャンデーは表面が密で、内面が疎の連続
した断面を有する特許請求の範囲第7項記載の製造法。[Scope of Claims] A fibrous candy material having a viscosity of 200 to 12,000 poise at 1,100°C, a water content of 0.5 to 5.0% by weight, and containing at least one type of saccharide is in the form of a flocculent. It is a flocculent candy with an apparent density of 2.0 x 90.0 Xio"y/= which has a desired shape with interconnected surfaces. 2. The sugars are monosaccharides, trisaccharides, starch hydrolysates, A cotton-like camp 03 according to claim 1, comprising each individual non-reducible starch hydrolyzate and a combination thereof.Claim 1 having a viscosity of 1000 to 100 poise at 100°C. 4. The cotton-like candy according to claim 1, wherein the moisture content is 1 to 4% by weight. 5. The cotton-like candy according to claim 1, wherein the fibrous candy material has a diameter of at most 1.0 mm. The cotton candy according to claim 1. 6. The cotton candy according to claim 1, which has a continuous cross section with a dense surface and a sparse inner surface. 7. A candy material containing at least one type of sugar. The fibrous candy material is melted and melted by heating, then discharged in the form of fibers, and then the fibrous candy material is shaped into a desired shape, and then bonded to each other by heating the surface or absorbing moisture, and then molded. 8. The manufacturing method according to claim 7, wherein the saccharide is a monosaccharide, a trisaccharide, a starch hydrolyzate, a non-reducible starch hydrolyzate, or a combination thereof. 9. The manufacturing method according to claim 7, in which water removal is added to heat the candy material. 10. Claim 9, wherein the amount of water added to dissolve the sugar is at least 10% by weight based on the sugar. 11. The manufacturing method according to claim 7, wherein the discharge is carried out using a nozzle having at least one small hole. 12. The manufacturing method according to claim 7, wherein the nozzle has a hole diameter of 0.05 to 2.0 myn. The manufacturing method according to item 11. 13. The candy material has a discharge viscosity of at least 100.
The manufacturing method according to claim 7, which has 0 poise. 14 The discharge flow rate of candy material is at most 10 cc7
The manufacturing method according to claim 7, which is fnm/nozzle hole. 15 The diameter of the fibrous candy material is at most 1. , Omm
The manufacturing method according to claim 7. 16. The manufacturing method according to claim 7, wherein the cotton candy has a continuous cross section with a dense surface and a sparse inner surface.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP52012008A JPS5932097B2 (en) | 1977-02-04 | 1977-02-04 | Cotton candy and its manufacturing method |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP52012008A JPS5932097B2 (en) | 1977-02-04 | 1977-02-04 | Cotton candy and its manufacturing method |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPS5399360A JPS5399360A (en) | 1978-08-30 |
| JPS5932097B2 true JPS5932097B2 (en) | 1984-08-06 |
Family
ID=11793549
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP52012008A Expired JPS5932097B2 (en) | 1977-02-04 | 1977-02-04 | Cotton candy and its manufacturing method |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPS5932097B2 (en) |
-
1977
- 1977-02-04 JP JP52012008A patent/JPS5932097B2/en not_active Expired
Also Published As
| Publication number | Publication date |
|---|---|
| JPS5399360A (en) | 1978-08-30 |
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