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JPS6011426B2 - Fuel cell - Google Patents
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JPS6011426B2 - Fuel cell - Google Patents

Fuel cell

Info

Publication number
JPS6011426B2
JPS6011426B2 JP55017123A JP1712380A JPS6011426B2 JP S6011426 B2 JPS6011426 B2 JP S6011426B2 JP 55017123 A JP55017123 A JP 55017123A JP 1712380 A JP1712380 A JP 1712380A JP S6011426 B2 JPS6011426 B2 JP S6011426B2
Authority
JP
Japan
Prior art keywords
cell
inert gas
gas
fuel cell
supply valve
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
JP55017123A
Other languages
Japanese (ja)
Other versions
JPS56114285A (en
Inventor
長之 堀内
力雄 石川
博之 田島
和雄 小関
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Denryoku Chuo Kenkyusho
Fuji Electric Co Ltd
Original Assignee
Denryoku Chuo Kenkyusho
Fuji Electric Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Denryoku Chuo Kenkyusho, Fuji Electric Co Ltd filed Critical Denryoku Chuo Kenkyusho
Priority to JP55017123A priority Critical patent/JPS6011426B2/en
Publication of JPS56114285A publication Critical patent/JPS56114285A/en
Publication of JPS6011426B2 publication Critical patent/JPS6011426B2/en
Expired legal-status Critical Current

Links

Classifications

    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00Fuel cells; Manufacture thereof
    • H01M8/04Auxiliary arrangements, e.g. for control of pressure or for circulation of fluids
    • H01M8/04082Arrangements for control of reactant parameters, e.g. pressure or concentration
    • H01M8/04089Arrangements for control of reactant parameters, e.g. pressure or concentration of gaseous reactants
    • H01M8/04104Regulation of differential pressures
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00Fuel cells; Manufacture thereof
    • H01M8/04Auxiliary arrangements, e.g. for control of pressure or for circulation of fluids
    • H01M8/04223Auxiliary arrangements, e.g. for control of pressure or for circulation of fluids during start-up or shut-down; Depolarisation or activation, e.g. purging; Means for short-circuiting defective fuel cells
    • H01M8/04228Auxiliary arrangements, e.g. for control of pressure or for circulation of fluids during start-up or shut-down; Depolarisation or activation, e.g. purging; Means for short-circuiting defective fuel cells during shut-down
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00Fuel cells; Manufacture thereof
    • H01M8/04Auxiliary arrangements, e.g. for control of pressure or for circulation of fluids
    • H01M8/04223Auxiliary arrangements, e.g. for control of pressure or for circulation of fluids during start-up or shut-down; Depolarisation or activation, e.g. purging; Means for short-circuiting defective fuel cells
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00Fuel cells; Manufacture thereof
    • H01M8/04Auxiliary arrangements, e.g. for control of pressure or for circulation of fluids
    • H01M8/04298Processes for controlling fuel cells or fuel cell systems
    • H01M8/043Processes for controlling fuel cells or fuel cell systems applied during specific periods
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02EREDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/30Hydrogen technology
    • Y02E60/50Fuel cells

Landscapes

  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Manufacturing & Machinery (AREA)
  • Sustainable Development (AREA)
  • Sustainable Energy (AREA)
  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Electrochemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Fuel Cell (AREA)

Description

【発明の詳細な説明】 本発明は、外部から不活性ガスを供給することにより少
なくとも一方のガス室内の反応ガスを不活性ガスで置換
することのできる燃料電池に関する。
DETAILED DESCRIPTION OF THE INVENTION The present invention relates to a fuel cell capable of replacing a reactive gas in at least one gas chamber with an inert gas by supplying an inert gas from the outside.

燃料電池にインバータを組み合わせて交流系統へ電力を
供給する燃料電池発電システムにおいて、インバータ転
流失敗時の過電流保護のために直流回路をしや断する方
法は、大容量システムにあっては技術的に非常に困難を
ともなう低圧大電流の高速直流しや断器を必要とする。
In a fuel cell power generation system that combines a fuel cell with an inverter to supply power to an AC system, the method of cutting off the DC circuit to protect against overcurrent in the event of an inverter commutation failure is a technological challenge for large-capacity systems. This requires low-voltage, high-current, high-speed direct current and disconnection, which is extremely difficult.

この問題を克服すべく種々の検討を重ねた結果、燃料電
池の酸化剤側か燃料側かの少なくともいずれか一方のガ
ス室内の反応ガスを不活性ガスで置換することにより燃
料電池の放電を停止させる方法が極めて有効であること
を見し、出した。ガス室内の反応ガスを不活性ガスで置
換するやり方としては、外部から不活性ガス源を供V給
するやり方と、酸化剤として空気を使用する燃料電池に
あってはガス室内からのガス排出を停止することにより
空気中の不活性ガスである窒素をガス室内に蓄積させる
やり方とが考えられるが、本発明は前者のやり方により
給電を停止することができるようにした燃料電池を対象
とするものであり、その目的とする′−ろは、反応ガス
と不活性ガスとの遠い置換と、直換中および置換後のセ
ル内圧力の一定保持とを配慮した燃料電池を提供するこ
とにある。この目的は、本発明によれば、特許請求の範
囲に記載の構成によって達成される。以下、図面に示す
実施例を参照しながら本発明を詳細に説明する。
As a result of various studies to overcome this problem, we decided to stop the discharge of the fuel cell by replacing the reactive gas in the gas chamber on either the oxidizer side or the fuel side of the fuel cell with an inert gas. We discovered that this method was extremely effective and developed it. There are two ways to replace the reactive gas in the gas chamber with an inert gas: supplying an inert gas source from outside, and in fuel cells that use air as an oxidizer, replacing the gas from the gas chamber. One possible method is to accumulate nitrogen, which is an inert gas in the air, in the gas chamber by stopping the fuel cell, but the present invention is directed to a fuel cell in which the power supply can be stopped using the former method. The purpose of this invention is to provide a fuel cell that takes into consideration the distant replacement of reactant gas and inert gas and the constant maintenance of the cell internal pressure during and after direct exchange. This object is achieved according to the invention by the features described in the claims. Hereinafter, the present invention will be explained in detail with reference to embodiments shown in the drawings.

図には本発明による燃料電池の一方の反応ガスのための
ガス回路系のみが概略的に示してある。
The figure only schematically shows the gas circuit system for one of the reactant gases of the fuel cell according to the invention.

この図において、6にて示されセルには燃料および酸化
剤の両反応ガスが供給されるが、本発明によるガス回路
系によって案内される反応ガスはそのうちの一方であっ
てよく、したがって他方の反応ガスのガス回路系は従来
と全く同じ構成であってよい。例えば一方の反応ガスと
して酸化剤である空気もしくは酸素が供給弁1および排
出弁2を開くことによってセル6内に供給され、セル内
からは未反応ガスおよび反応生成物が排出される。供給
弁1とセル6のガス入口との間には反応ガス調圧器3が
配設されている。この調圧器3はセル内圧力とほぼ一定
に調整する働きをする。このために例えばセル入口付近
の圧力がフィードバックされる。さらに、燃料電池の発
電停止のために、本発明にしたがって、図示されていな
い不活性ガス源から不活性ガス供給弁4を介して、反応
ガス調圧器3に対してセル6側に不活性ガスを供給する
ことを可能にする配管が設けられ、この配管は別の調圧
器5を介して不活性ガス供給弁4に接続されている。調
圧器5もそれの出口側の圧力、したがってセル内圧力を
ほぼ一定に保持する働きをする。′両論圧器3,5は通
常の如く逆流阻止機能を持たされている。不活性ガス認
圧器5は反応ガス調圧器3よりも高い圧力を設定するこ
ともできる。燃料電池の図示されていない電気系もしく
は燃料電池から給電を受ける負荷回路における何らかの
故障による過電流が検出されたときなどに発せられる発
電停止指令に基づいて図示されていない制御装置によっ
て反応ガス供給弁1が閉じられると同時に不活性ガス供
給弁4が開かれる。
In this figure, the cell indicated at 6 is supplied with both reactant gases, fuel and oxidizer, but the reactant gases guided by the gas circuit system according to the invention may be one of them and therefore the other. The gas circuit system for the reaction gas may have exactly the same configuration as the conventional one. For example, air or oxygen, which is an oxidizing agent, is supplied as one of the reaction gases into the cell 6 by opening the supply valve 1 and the discharge valve 2, and unreacted gas and reaction products are discharged from the cell. A reaction gas pressure regulator 3 is disposed between the supply valve 1 and the gas inlet of the cell 6 . This pressure regulator 3 functions to adjust the pressure within the cell to be substantially constant. For this purpose, for example, the pressure near the cell inlet is fed back. Further, in order to stop the power generation of the fuel cell, in accordance with the present invention, inert gas is supplied from an inert gas source (not shown) to the cell 6 side with respect to the reaction gas pressure regulator 3 via the inert gas supply valve 4. A pipe is provided, which is connected to the inert gas supply valve 4 via another pressure regulator 5. The pressure regulator 5 also serves to maintain the pressure on its outlet side, and therefore the pressure inside the cell, approximately constant. 'Both pressure regulators 3 and 5 are provided with a backflow prevention function as usual. The pressure of the inert gas pressure regulator 5 can also be set higher than that of the reaction gas pressure regulator 3. The reaction gas supply valve is activated by a control device (not shown) based on a power generation stop command issued when an overcurrent due to some kind of failure is detected in the electrical system of the fuel cell (not shown) or in the load circuit that receives power from the fuel cell. 1 is closed, and at the same time, the inert gas supply valve 4 is opened.

これによって、セル6内には不活性ガスが供給される。
セル内ガス室の不活性ガス濃度の上昇にともなって燃料
電池電圧は低下してゆき、最終的には発電が停止する。
したがって、燃料電池の出力側の直流回路をしや断する
ことないこ過電流が危検しベルに到達させないで給電停
止を行なわせることができる。本発明による燃料電池に
よれば、反応ガス調圧器3の入口側ではなくて出口側に
おいて反応ガスと不活性ガスとの切換えが行なわれる構
造であるのでセル内での不活性ガスへの置換動作の立上
がりの遅れを僅かにすることができる。
As a result, inert gas is supplied into the cell 6.
As the inert gas concentration in the gas chamber within the cell increases, the fuel cell voltage decreases, and power generation eventually stops.
Therefore, the power supply can be stopped without interrupting the direct current circuit on the output side of the fuel cell, and without allowing the overcurrent to reach the alarm level. According to the fuel cell according to the present invention, the structure is such that switching between the reactive gas and the inert gas is performed not at the inlet side of the reactive gas pressure regulator 3 but at the outlet side, so that the replacement operation with the inert gas within the cell is performed. The delay in the rise of can be minimized.

また、不活性ガス調圧器5を設けたことにより置換動作
中およびその完了後にもセル内圧力をほぼ一定に保つこ
とができ、セル内の電極の変形などによる特性劣化を防
ぐことができる。しかも、そればかりでなく反応ガスと
不活性ガスとに別々の調圧器を設けたことにより、互い
に異なる圧力設定を与えることができる。つまり、ガス
室内での反応ガスを不活性ガスで置換するのに要する時
間を一層短縮するために不活性ガス調圧器の圧力設定を
高くすることができるのである。排出弁2はその都度に
おける所要不活性ガス量を減らすためには発電停止指令
信号により閉じられるべきである。
Further, by providing the inert gas pressure regulator 5, the pressure inside the cell can be kept almost constant during the replacement operation and after the replacement operation is completed, and characteristic deterioration due to deformation of the electrodes inside the cell can be prevented. Moreover, by providing separate pressure regulators for the reaction gas and the inert gas, different pressure settings can be given to each other. In other words, the pressure setting of the inert gas pressure regulator can be increased in order to further reduce the time required to replace the reaction gas in the gas chamber with inert gas. The discharge valve 2 should be closed by a power generation stop command signal in order to reduce the amount of inert gas required each time.

しかしながら、排出弁2の閉は反応ガス供給弁1の閉お
よび不活性ガス供給弁4の関と同時に行なうのではなく
て、適当な時限要素により遅延させて行なわせるように
すれば、セル内および配管の残留反応ガスを不活性ガス
供給により強制的に外部へ押出すことができ、したがっ
て置換速度を高めることができる。
However, instead of closing the discharge valve 2 at the same time as the reaction gas supply valve 1 and the inert gas supply valve 4, if the discharge valve 2 is delayed by a suitable time element, it is possible to The residual reaction gas in the piping can be forcibly pushed out by supplying an inert gas, and therefore the replacement rate can be increased.

【図面の簡単な説明】[Brief explanation of the drawing]

図は本発明による燃料電池の要部についての概略図であ
る。 1・・・・・・反応ガス供給弁、2・・・・・・排出弁
、3・・・・・・反応ガス調圧器、4・・・・・・不活
性ガス供給弁、5・・・・・・不活性ガス調圧器、6・
…・・セル。
The figure is a schematic diagram of the main parts of a fuel cell according to the present invention. 1...Reaction gas supply valve, 2...Discharge valve, 3...Reaction gas pressure regulator, 4...Inert gas supply valve, 5... ...Inert gas pressure regulator, 6.
…··cell.

Claims (1)

【特許請求の範囲】 1 セル内圧をほぼ一定に保ちながらセル内へ反応ガス
を供給するために反応ガス供給弁とセルのガス入口との
間に調圧要素が配設されているような燃料電池において
、燃料電池の給電停止を指令する信号により反応ガス供
給弁が閉じられたときに開かれる不活性ガス供給弁と、
この不活性ガス供給弁とセルのガス入口との間に設けら
れセル内圧をほぼ一定に保ちながら不活性ガスをセル内
へ導く別の調圧要素とを設けたことを特徴とする燃料電
池。 2 特許請求の範囲第1項記載の燃料電池において、不
活性ガス側の調圧要素によって調整されるセル内圧は反
応ガス側の調圧要素によって調整されるセル内圧に比べ
て高く設定することを特徴とする燃料電池。
[Scope of Claims] 1. A fuel in which a pressure regulating element is disposed between a reaction gas supply valve and a gas inlet of the cell in order to supply the reaction gas into the cell while keeping the internal pressure of the cell substantially constant. In the battery, an inert gas supply valve that is opened when the reaction gas supply valve is closed by a signal instructing to stop power supply to the fuel cell;
A fuel cell characterized in that another pressure regulating element is provided between the inert gas supply valve and the gas inlet of the cell and guides the inert gas into the cell while keeping the cell internal pressure substantially constant. 2. In the fuel cell according to claim 1, the cell internal pressure adjusted by the inert gas side pressure regulating element is set higher than the cell internal pressure adjusted by the reactant gas side pressure regulating element. Characteristic fuel cells.
JP55017123A 1980-02-14 1980-02-14 Fuel cell Expired JPS6011426B2 (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP55017123A JPS6011426B2 (en) 1980-02-14 1980-02-14 Fuel cell

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP55017123A JPS6011426B2 (en) 1980-02-14 1980-02-14 Fuel cell

Publications (2)

Publication Number Publication Date
JPS56114285A JPS56114285A (en) 1981-09-08
JPS6011426B2 true JPS6011426B2 (en) 1985-03-26

Family

ID=11935247

Family Applications (1)

Application Number Title Priority Date Filing Date
JP55017123A Expired JPS6011426B2 (en) 1980-02-14 1980-02-14 Fuel cell

Country Status (1)

Country Link
JP (1) JPS6011426B2 (en)

Families Citing this family (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS5968179A (en) * 1982-10-08 1984-04-18 Toshiba Corp Fuel cell power generating system
JPS6132363A (en) * 1984-07-23 1986-02-15 Hitachi Ltd Fuel cell power generation system

Also Published As

Publication number Publication date
JPS56114285A (en) 1981-09-08

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