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JPS6035260B2 - Method of adhering and forming a diffusely reflective vapor deposited film on the surface of a member to be adhered - Google Patents
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JPS6035260B2 - Method of adhering and forming a diffusely reflective vapor deposited film on the surface of a member to be adhered - Google Patents

Method of adhering and forming a diffusely reflective vapor deposited film on the surface of a member to be adhered

Info

Publication number
JPS6035260B2
JPS6035260B2 JP56042857A JP4285781A JPS6035260B2 JP S6035260 B2 JPS6035260 B2 JP S6035260B2 JP 56042857 A JP56042857 A JP 56042857A JP 4285781 A JP4285781 A JP 4285781A JP S6035260 B2 JPS6035260 B2 JP S6035260B2
Authority
JP
Japan
Prior art keywords
adhered
film
deposited film
vapor deposited
resin film
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
JP56042857A
Other languages
Japanese (ja)
Other versions
JPS57157746A (en
Inventor
禎美 伊藤
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Individual
Original Assignee
Individual
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Individual filed Critical Individual
Priority to JP56042857A priority Critical patent/JPS6035260B2/en
Publication of JPS57157746A publication Critical patent/JPS57157746A/en
Publication of JPS6035260B2 publication Critical patent/JPS6035260B2/en
Expired legal-status Critical Current

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  • Laminated Bodies (AREA)
  • Physical Vapour Deposition (AREA)
  • Other Surface Treatments For Metallic Materials (AREA)

Description

【発明の詳細な説明】 この発明は被貼着部材の表面に乱反射蒸着膜を貼着形成
する方法に関するものである。
DETAILED DESCRIPTION OF THE INVENTION The present invention relates to a method of adhering and forming a diffusely reflective vapor deposited film on the surface of a member to be adhered.

装飾あるいは包装材として透明プラスチックフィルムの
一面にアルミ等の金属蒸着膜を形成さてたのち、級葵の
一面にこれを貼着せしめた貼合せ加工紙が実用化されて
いる。
Laminated processed paper has been put into practical use as a decoration or packaging material by forming a vapor-deposited metal film such as aluminum on one side of a transparent plastic film and then pasting this on one side of a hollyhock.

この場合表面が美麗で印刷効果もすぐれ、防湿、防水、
気密性を有している反面紙面は鏡面化されてしまい、入
射光をその入射角度に応じ一定の方向にのみに反射させ
てしまい、この反射光が直接に顧客の目に入ったり、け
ばけばし過ぎるきらいがあり、また擦過傷がつき易く装
飾紙として不適当な場合がある。この発明は従来の金属
蒸着膜を形成させた包装材と同じようにガス、水蒸気お
よび熱線に対する遮断特性をそこなうことなく、しかも
本発明独特の今迄類例のない白く美しく輝くような感じ
の乱反射面を備え、かつ上述した欠点を除去することを
目的とするもので、その特徴とするところは、シートや
フィルム素材の一面にこれ等素材と親和性の大にして微
づ・粒子物質を混在させた樹脂を表面を粗面とした版胴
で塗着させ表面が二重に粗面でありかつ蒸着膜と剥離性
のよい樹脂膜を形成する第1の工程と前記工程により得
た前記フィルム素材上の二重に粗面の樹脂膜転着面に金
属蒸着手段を用いて金属蒸着膜を形成せしめる第2の工
程と、この第2の工程により金属蒸着膜の表面を前記二
重の粗面に対応した二重の粗面とし、乱反射金属蒸着膜
を形成せしめたあと前記二重の粗面の金属蒸着膜を前記
樹脂膜面より剥離させて被貼着部村の一面に転移貼着さ
せる第3の工程とからなる乱反射蒸着膜を形成する方法
を提供するものである。以下この発明を図に示す一実施
例について詳述する。
In this case, the surface is beautiful, the printing effect is excellent, moisture-proof, waterproof,
Although it is airtight, the surface of the paper is mirrored, and the incident light is reflected only in a certain direction depending on the angle of incidence, and this reflected light may not directly enter the customer's eyes or cause glare. It tends to be too thick and is easily scratched, making it unsuitable as a decorative paper. This invention does not impair the barrier properties against gas, water vapor, and heat rays like the conventional packaging materials formed with metal vapor deposition films, and has a diffused reflection surface that has an unprecedented white and beautiful shine unique to this invention. The purpose is to eliminate the above-mentioned drawbacks, and its feature is that fine particles and particles that have a high affinity with these materials are mixed on one side of the sheet or film material. a first step of coating the resin on a plate cylinder with a rough surface to form a resin film that has a doubly rough surface and has good releasability from the vapor deposited film; and the film material obtained by the above step. a second step of forming a metal vapor deposited film on the double rough resin film transfer surface using a metal vapor deposition means; After forming a diffusely reflecting metal vapor deposited film, the metal vapor deposited film on the double rough surface is peeled off from the resin film surface and transferred and adhered to one surface of the target area. The present invention provides a method for forming a diffusely reflective vapor deposited film, which comprises a third step. An embodiment of the present invention shown in the drawings will be described in detail below.

第1図において1はポリオレフィン類、ポリエステル等
よりなる一面に金属蒸着膜を形成させようとする臨界表
面張力が可成り小さく表面が極平タ滑で透明あるいは不
透明な合成樹脂フィルムでこのフィルムは予じめサプラ
イドラム2に巻回されておりテイクアップドラム3に巻
取られるようになっている。
In Fig. 1, 1 is a transparent or opaque synthetic resin film made of polyolefins, polyester, etc., which has a fairly low critical surface tension and an extremely flat and smooth surface to form a metal vapor deposited film on one surface. The water is wound around a supply drum 2, and is adapted to be taken up on a take-up drum 3.

4は表面に例えば1インチ当り30〜10雌嫁程度の網
目模様を施した版8同で、5はドクター歯である。
4 is a plate 8 having a mesh pattern of, for example, 30 to 10 dots per inch on the surface, and 5 is a doctor tooth.

6は前記フィルムに対し親和性のよい可溶性透明プラス
チックに顔料粒子等の極微細粒子と溶融樹脂を入れた容
器、7は前記版胴4に合成樹脂フィルムーを圧着する加
圧ローラ、8a〜8fはガイドローラ、9は前記フィル
ムに塗着した樹脂膜を乾燥させる乾燥装置、10は連続
真空蒸着装層で前後に2室づつの減圧室11a〜11d
を有し、中央に真空蒸着室12を備え、該蒸着室内には
外部より加熱温度をコントロールし得るヒータ13、ル
ッボ14および蒸発金属をフィルム面に導くガイド板1
5a,15bが配設されている。
6 is a container containing ultrafine particles such as pigment particles and molten resin in a soluble transparent plastic that has good affinity for the film; 7 is a pressure roller that presses the synthetic resin film onto the plate cylinder 4; 8a to 8f are A guide roller, 9 a drying device for drying the resin film applied to the film, 10 a continuous vacuum evaporation layer, two decompression chambers 11a to 11d at the front and rear.
It has a vacuum evaporation chamber 12 in the center, and inside the evaporation chamber there are a heater 13 whose heating temperature can be controlled from the outside, a rubbo 14, and a guide plate 1 that guides the evaporated metal to the film surface.
5a and 15b are provided.

前記真空蒸着室12内は、例えば10‐4Torr程度
の真空度を保ち得るようになっており、前記真空下でル
ッボ14内に入れたAI,Au,Ag,Cu,Sn,Z
n,Cr,Ni,Se,Ti等の単体金属、Nj−Cr
,Nj−Fe,Fe−Co,Au−Ag−Cu等の合金
類、Si02,Ti02,ln02,AI203,Fe
203等の金属酸化物その他A燈r,A&1の如き金属
化合物等を熱に強いニクローム線でできたヒ−夕13で
加熱させてこれを蒸発させる。この蒸発金属は原子、分
子状態を含む極微小粒子化して真空蒸発室12内をガイ
ド板15a,15bに添って直進し、前記した一面に樹
脂膜層18を塗着された合成樹脂フィルムーの二重粗面
の樹脂膜層18に衝突して静止し二重相面の樹脂膜層1
8上に金属蒸着膜層19が形成する。尚金属蒸着膜層は
フィルムの移送速度および金属蒸気の発生量をコントロ
ールすることにより加減できる。この間合成樹脂フィル
ム1は駆動ローラ16、加圧oーラ17によりサプライ
ドラム2よりテイクアップドラム3に等速で巻取られる
The inside of the vacuum deposition chamber 12 is designed to maintain a degree of vacuum of, for example, about 10-4 Torr, and the AI, Au, Ag, Cu, Sn, and Z placed in the rubbo 14 under the vacuum are
Single metals such as n, Cr, Ni, Se, Ti, Nj-Cr
, Nj-Fe, Fe-Co, Au-Ag-Cu and other alloys, Si02, Ti02, ln02, AI203, Fe
Metal oxides such as 203 and other metal compounds such as A light r and A&1 are heated with a heater 13 made of a heat-resistant nichrome wire to evaporate them. The evaporated metal is turned into ultra-fine particles containing atoms and molecules, and travels straight through the vacuum evaporation chamber 12 along guide plates 15a and 15b, forming two synthetic resin films coated with a resin film layer 18 on one side. The resin film layer 1 of the double phase surface collides with the resin film layer 18 of the heavy rough surface and comes to rest.
A metal vapor deposition film layer 19 is formed on 8 . The thickness of the metal vapor deposited film layer can be adjusted by controlling the film transport speed and the amount of metal vapor generated. During this time, the synthetic resin film 1 is wound from the supply drum 2 onto the take-up drum 3 at a constant speed by a drive roller 16 and a pressure roller 17.

第2図aは前述した第1の工程を用いて合成樹脂フィル
ムーの一面に二重粗面の樹脂膜層18を形成した拡大断
面図で、第2図b,c,dはそれぞれ樹脂被膜18の上
に金属蒸着膜層19を形成した場合のさらに拡大した断
面図で、合成樹脂フィルムーの一面には樹脂層18とそ
の上に金属蒸着膜層19が重なり、版胴4の表面に形成
した網目と、樹脂に混入した顔料粒子等の極微細粒子と
樹脂の粘度および流れ特性により前記樹脂膜層18の表
面には第2図a,bで示すような極微小な凹凸面aを有
する比較的大きい凹凸面bが形成され、この二重の凹凸
組面a,bに従うように金属黍着膜層19の表面にも二
重の凹凸組面が形成されるため、このままの状態におい
ても金属蒸着膜層面19への入射光は極めて白く輝くよ
うな感じで効果的に乱反射する。
FIG. 2a is an enlarged cross-sectional view of a double roughened resin film layer 18 formed on one side of a synthetic resin film using the first step described above, and FIGS. 2b, c, and d are respectively views of the resin film 18. This is a further enlarged cross-sectional view of the case where a metal vapor deposited film layer 19 is formed on the surface of the plate cylinder 4, and the resin layer 18 is overlapped on one side of the synthetic resin film, and the metal vapor deposited film layer 19 is overlapped thereon. Due to the network, ultrafine particles such as pigment particles mixed in the resin, and the viscosity and flow characteristics of the resin, the surface of the resin film layer 18 has an extremely small uneven surface a as shown in FIGS. 2a and b. A large uneven surface b is formed, and a double uneven surface b is also formed on the surface of the metal coating layer 19 in accordance with the double uneven surfaces a and b. The light incident on the vapor-deposited film layer surface 19 is effectively diffused and reflected in an extremely white and shining manner.

次に前述した二重粗面樹脂膜層18を塗着する第1の工
程と二重粗面の金属蒸着膜層を形成する第2の工程だけ
のものでも乱反射蒸着フィルムとして製品化し得るが、
一面に二重の粗面a,bを有する樹脂膜層18を介して
金属蒸着膜層を形成せしめた合成樹脂フィルムより紙等
の被貼着部材の一面に蒸着膜層19を樹脂膜層18から
剥離して接着させる第3工程について述べる。
Next, even if only the first step of applying the double-roughened resin film layer 18 and the second step of forming the double-roughened metal vapor-deposited film layer described above can be commercialized as a diffused reflection vapor-deposited film,
A vapor-deposited film layer 19 is formed on one surface of a member to be adhered such as paper using a synthetic resin film on which a metal vapor-deposited film layer is formed via a resin film layer 18 having double rough surfaces a and b on one surface. The third step of peeling and adhering will be described.

第3図は前記した第3の工程の実行装置で、テイクアッ
プドラム3に巻取られた二重相面の蒸着膜層19を形成
した合成樹脂フィルム1は臨界表面張力の大きい被貼着
部材(例えば、紙、布、ガラス、金属等)20を巻いた
サプライドラム21からの前記部材と共に加圧およびラ
ミネータ冷却oーラ22,23と分離ローラ24a,2
4b間を通り、合成樹脂フィルム1はテイクアップドラ
ム3に、被貼着部材2川まテイクアップドラム25に巻
付けられるようにしてある。
FIG. 3 shows an apparatus for carrying out the third step described above, in which the synthetic resin film 1 on which the double-phase vapor deposited film layer 19 is formed and wound around the take-up drum 3 is attached to an adhered material having a large critical surface tension. (For example, paper, cloth, glass, metal, etc.) 20 is wound on the supply drum 21 together with the pressurizing and laminator cooling rollers 22, 23 and separation rollers 24a, 2.
4b, the synthetic resin film 1 is wound around the take-up drum 3, and the member to be adhered 2 is wound around the take-up drum 25.

同じドラム径のテイクテイクアップドラム3,25に図
示してない共通の駆動源を介して回動力を付与しサプラ
イドラム2,21から合成樹脂フィルムーと被貼着部材
20を等速で巻取るようにする。また、この巻取り作業
に合せて例えばェクストルダー26により溶融ポリエチ
レン膜cを前記被貼着部材20の一面にェクストルージ
ョン法により塗着し惨み込ませ金属蒸着膜層19に前記
熔融ポリエチレン膜cを介して被貼着部材20を加圧お
よびラミネータン冷却ローラ22,23で圧着冷却し、
いわゆる投錨効果を生じせしめる。
A rotating force is applied to the take-up drums 3 and 25 having the same drum diameter through a common drive source (not shown), so that the synthetic resin film and the adhered member 20 are wound up at a constant speed from the supply drums 2 and 21. Make it. In addition, in conjunction with this winding operation, the molten polyethylene film c is coated on one surface of the adhered member 20 by the extrusion method using an extruder 26, for example, to make the molten polyethylene film c spread on the metal vapor deposited film layer 19. Pressure is applied to the adhered member 20 through the laminate cooling rollers 22 and 23, and the member is cooled by pressing.
This causes a so-called anchoring effect.

したがって、分離ローラ24a,24bを通過したとこ
ろで合成樹脂フィルム1と被貼着部材20がそれぞれテ
イクアップドラム3と25側に分離される際合成樹脂フ
ィルム上の樹脂膜層18から蒸着腰層19が樹脂膜層1
8と被貼着部村の臨界表面張力の差を利用して前記樹脂
膜層組面より剥離されて被貼着部材20側に貼着し、テ
イクアップドラム25に巻取られ、前記樹脂膜層18の
蒸着膜層19が剥離された樹脂膜層18および合成樹脂
フィルム1はテイクアップドラム3に巻取られる。尚蒸
着膜層19に例えばテトラブチルチタネートの如き婆着
助剤をコートしておけば溶融ポリエチレンcと合せて強
固な接着ができる。第4図はこの第3の工程を経た被貼
着部材20の拡大断面図で、前記被貼着部材20上にポ
リエチレン溶融膜層27を介して金属蒸着膜層19が取
付けられるが、金属蒸着膜層19は前述した第1および
第2の工程で二重に凹凸化されているため入射光は金属
蒸着膜層19の二重の凹凸のため白く輝くような感じで
美しく乱反射する従釆見られない本件独特のきめ細かい
光線乱反射包装装飾紙等が得られる。
Therefore, when the synthetic resin film 1 and the adhered member 20 are separated into the take-up drums 3 and 25 after passing through the separation rollers 24a and 24b, the vapor-deposited waist layer 19 is removed from the resin film layer 18 on the synthetic resin film. Resin film layer 1
Utilizing the difference in critical surface tension between the resin film 8 and the adhered part, the resin film is peeled off from the assembly surface and adhered to the adhered member 20 side, and wound around the take-up drum 25, and the resin film The resin film layer 18 and the synthetic resin film 1 from which the vapor-deposited film layer 19 of the layer 18 has been peeled off are wound up on the take-up drum 3. If the vapor deposited film layer 19 is coated with an adhesion aid such as tetrabutyl titanate, strong adhesion can be achieved in combination with the molten polyethylene c. FIG. 4 is an enlarged sectional view of the adhered member 20 that has undergone this third step, in which a metal vapor deposited film layer 19 is attached on the adhered member 20 via a polyethylene melt film layer 27. Since the film layer 19 is doubly textured in the first and second steps described above, the incident light is beautifully diffused and reflected as if it shines white due to the double unevenness of the metal vapor deposited film layer 19. A unique, fine-grained light diffused reflection packaging decorative paper, etc., which is unique to the present invention, can be obtained.

以上述べたようにこの発明はシートやフィルム素材の一
面に極微小粒子物質を混在させた樹脂を表面を粗面とし
た版耳同で転着させ表面が二重組面の樹脂膜を形成する
第1の工程と、前記第1の工程により得た前記フィルム
素材上の二重組面の樹脂膜転着面に金属蒸着手段を用い
て金属蒸着膜を形成せしめる第2の工程と、この第2の
工程により金属蒸着膜の表面を前記粗面に対応した二重
組面とし乱反射金属蒸着膜を形成せしめたあと前記二重
粗面の蒸着膜を前記樹脂膜面より剥離させて被貼着部材
の一面に転移貼着させる第3の工程とからなるため、天
然または合成の紙、布類、ガラス、金属類または合成樹
脂の如き有機または無機物質からなる被貼着部材の表面
に白く輝くような感じの従来みられない本発明独特の光
線が極めて美しく乱反射し得る金属蒸着膜を容易に形成
できる上に従来の貼合せ加工紙と同等の物理特性以上の
ものが安価に加工できる等の効果を有する。
As described above, the present invention is a process in which a resin mixed with ultrafine particles is transferred onto one side of a sheet or film material using a roughened plate to form a resin film with a double-layered surface. a second step of forming a metal vapor deposition film on the resin film transfer surface of the double assembly surface on the film material obtained in the first step using a metal vapor deposition means; In the process, the surface of the metal vapor deposited film is made into a double surface corresponding to the rough surface to form a diffusely reflective metal vapor deposited film, and then the vapor deposited film on the double rough surface is peeled off from the resin film surface to form one surface of the adhered member. and a third step of transference and adhesion to the surface of the material to be adhered, such as natural or synthetic paper, cloth, glass, metals, or synthetic resins. It has the effect that it is possible to easily form a metal vapor deposited film that can diffusely reflect the light rays unique to the present invention, which has not been seen before, and that it can be processed at a low cost to have physical properties equivalent to or better than conventional laminated paper. .

【図面の簡単な説明】[Brief explanation of the drawing]

図はいずれもこの発明の一実施例を示すもので、第1図
は合成樹脂フィルムの一面に二重粗面の樹脂膜および蒸
着膜を連続的に形成する装置の構成図、第2図a〜bは
前記フィルムを各膜の関係を示す拡大断面図、第3図は
前記極微細粗面に形成した蒸着膜を被貼着部材の一面に
劉雛貼着する装置の構成図、第4図は被貼着部材の一面
に貼着された極微細粗面の蒸着膜の拡大断面図である。 1・・・・・・合成樹脂フィルム、2,21・・・・・
・サプライドラム、3,25……テイクアップドラム、
4……版胴、7,22……加圧ローラ、8a〜8f・・
・・・・ガイドローラ、9・・・・・・乾燥装置、10
・・・・・・連続真空蒸着装層、18・・・・・・樹脂
膜層、19・・…・蒸着膜層、20…・・・被貼着部材
、23・・・・・・ラミネータ冷却ローラ、26・・・
・・・ェクストルダー、27・・・・・・ポリエチレン
溶融膜層、a・・・・・・極微小な凹凸組面、b・・・
・・・比較的大きい凹凸組面、c・・・・・・熔融ポリ
エチレン膜。苑′図 衆2図(Q) 精2図(〆) 発z図(c) 兼2図(〆) 弟J図 兼々図
Each of the figures shows an embodiment of the present invention; Fig. 1 is a block diagram of an apparatus for continuously forming a double-roughened resin film and a vapor deposited film on one surface of a synthetic resin film, and Fig. 2 a -b is an enlarged sectional view of the film showing the relationship between each film, FIG. 3 is a configuration diagram of an apparatus for pasting the vapor deposited film formed on the ultrafine rough surface onto one surface of a member to be pasted, and FIG. The figure is an enlarged cross-sectional view of a deposited film with an extremely fine rough surface that is adhered to one surface of a member to be adhered. 1...Synthetic resin film, 2,21...
・Supply drum, 3, 25...take-up drum,
4... Plate cylinder, 7, 22... Pressure roller, 8a to 8f...
... Guide roller, 9 ... Drying device, 10
...Continuous vacuum deposition layer, 18...Resin film layer, 19...Vapor deposited film layer, 20...Member to be adhered, 23...Laminator Cooling roller, 26...
...extruder, 27...polyethylene melt film layer, a...microscopic uneven surface, b...
. . . Relatively large uneven surface, c . . . Molten polyethylene film. En' Zushu 2nd drawing (Q) Sei 2nd drawing (〆) Departure z drawing (c) Ken 2nd drawing (〆) Younger brother J drawing and also drawing

Claims (1)

【特許請求の範囲】[Claims] 1 シートやフイルム素材の一面に極微小粒子物質を混
在させた樹脂を表面を粗面とした版胴で転着させ表面が
二重粗面の樹脂膜を形成する第1の工程と、前記第1の
工程により得た前記フイルム素材上の二重粗面の樹脂膜
転着面に金属蒸着手段を用いて金属蒸着膜を形成せしめ
る第2の工程と、この第2の工程により金属蒸着膜の表
面を前記粗面に対応した二重粗面とし乱反射金属蒸着膜
を形成せしめたあと前記二重粗面の蒸着膜を前記樹脂膜
面より剥離させて被貼着部材の一面に転移貼着させる第
3の工程とからなることを特徴とする被貼着部材の表面
に乱反射蒸着膜を貼着形成する方法。
1. A first step of transferring a resin mixed with ultrafine particles onto one surface of a sheet or film material using a plate cylinder with a rough surface to form a resin film with a double rough surface; a second step of forming a metal vapor deposited film on the double rough resin film transfer surface of the film material obtained in step 1 using a metal vapor deposition means; The surface is made into a double rough surface corresponding to the rough surface, and a diffusely reflecting metal vapor deposited film is formed, and then the vapor deposited film on the double rough surface is peeled off from the resin film surface and transferred and adhered to one surface of the adhered member. A method for adhering and forming a diffusely reflective vapor deposited film on the surface of a member to be adhered, the method comprising a third step.
JP56042857A 1981-03-24 1981-03-24 Method of adhering and forming a diffusely reflective vapor deposited film on the surface of a member to be adhered Expired JPS6035260B2 (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP56042857A JPS6035260B2 (en) 1981-03-24 1981-03-24 Method of adhering and forming a diffusely reflective vapor deposited film on the surface of a member to be adhered

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP56042857A JPS6035260B2 (en) 1981-03-24 1981-03-24 Method of adhering and forming a diffusely reflective vapor deposited film on the surface of a member to be adhered

Publications (2)

Publication Number Publication Date
JPS57157746A JPS57157746A (en) 1982-09-29
JPS6035260B2 true JPS6035260B2 (en) 1985-08-13

Family

ID=12647688

Family Applications (1)

Application Number Title Priority Date Filing Date
JP56042857A Expired JPS6035260B2 (en) 1981-03-24 1981-03-24 Method of adhering and forming a diffusely reflective vapor deposited film on the surface of a member to be adhered

Country Status (1)

Country Link
JP (1) JPS6035260B2 (en)

Also Published As

Publication number Publication date
JPS57157746A (en) 1982-09-29

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