JPS6140753B2 - - Google Patents
Info
- Publication number
- JPS6140753B2 JPS6140753B2 JP4285981A JP4285981A JPS6140753B2 JP S6140753 B2 JPS6140753 B2 JP S6140753B2 JP 4285981 A JP4285981 A JP 4285981A JP 4285981 A JP4285981 A JP 4285981A JP S6140753 B2 JPS6140753 B2 JP S6140753B2
- Authority
- JP
- Japan
- Prior art keywords
- film
- metal vapor
- double
- vapor deposited
- deposited film
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 229910052751 metal Inorganic materials 0.000 claims description 27
- 239000002184 metal Substances 0.000 claims description 27
- 229920005989 resin Polymers 0.000 claims description 21
- 239000011347 resin Substances 0.000 claims description 21
- 239000000463 material Substances 0.000 claims description 8
- 239000011882 ultra-fine particle Substances 0.000 claims description 5
- 238000000034 method Methods 0.000 claims description 4
- 238000007740 vapor deposition Methods 0.000 claims description 4
- 229920003002 synthetic resin Polymers 0.000 description 8
- 239000000057 synthetic resin Substances 0.000 description 8
- 238000001035 drying Methods 0.000 description 3
- 239000002245 particle Substances 0.000 description 3
- 238000001771 vacuum deposition Methods 0.000 description 3
- 230000000694 effects Effects 0.000 description 2
- 239000005022 packaging material Substances 0.000 description 2
- 239000000049 pigment Substances 0.000 description 2
- 229920003023 plastic Polymers 0.000 description 2
- 238000007738 vacuum evaporation Methods 0.000 description 2
- 229910001316 Ag alloy Inorganic materials 0.000 description 1
- 229910018072 Al 2 O 3 Inorganic materials 0.000 description 1
- 229910017061 Fe Co Inorganic materials 0.000 description 1
- -1 InO 2 Inorganic materials 0.000 description 1
- 229910003271 Ni-Fe Inorganic materials 0.000 description 1
- 229910018487 Ni—Cr Inorganic materials 0.000 description 1
- 229910004298 SiO 2 Inorganic materials 0.000 description 1
- 229910021607 Silver chloride Inorganic materials 0.000 description 1
- 229910010413 TiO 2 Inorganic materials 0.000 description 1
- 229910052782 aluminium Inorganic materials 0.000 description 1
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 1
- 230000004888 barrier function Effects 0.000 description 1
- 229910052804 chromium Inorganic materials 0.000 description 1
- 230000006837 decompression Effects 0.000 description 1
- 238000005034 decoration Methods 0.000 description 1
- 238000010586 diagram Methods 0.000 description 1
- 229910052737 gold Inorganic materials 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 150000002736 metal compounds Chemical class 0.000 description 1
- 229910044991 metal oxide Inorganic materials 0.000 description 1
- 150000004706 metal oxides Chemical class 0.000 description 1
- 150000002739 metals Chemical class 0.000 description 1
- 229910001120 nichrome Inorganic materials 0.000 description 1
- 238000004806 packaging method and process Methods 0.000 description 1
- 230000000704 physical effect Effects 0.000 description 1
- 239000002985 plastic film Substances 0.000 description 1
- 229920000728 polyester Polymers 0.000 description 1
- 229920000098 polyolefin Polymers 0.000 description 1
- 229910052709 silver Inorganic materials 0.000 description 1
- ADZWSOLPGZMUMY-UHFFFAOYSA-M silver bromide Chemical compound [Ag]Br ADZWSOLPGZMUMY-UHFFFAOYSA-M 0.000 description 1
- HKZLPVFGJNLROG-UHFFFAOYSA-M silver monochloride Chemical compound [Cl-].[Ag+] HKZLPVFGJNLROG-UHFFFAOYSA-M 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 229910052719 titanium Inorganic materials 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
- 229910052725 zinc Inorganic materials 0.000 description 1
Landscapes
- Laminated Bodies (AREA)
- Physical Vapour Deposition (AREA)
Description
【発明の詳細な説明】
この発明はシートやフイルム部材の表面に乱反
射蒸着膜を形成する方法に関するものである。DETAILED DESCRIPTION OF THE INVENTION The present invention relates to a method for forming a diffusely reflective vapor deposited film on the surface of a sheet or film member.
装飾あるいは包装材として透明プラスチツクフ
イルムの一面にアルミ等の金属蒸着膜を形成させ
たのち、紙葉の一面にこれを貼着せしめた貼合せ
加工紙が実用化されている。この場合表面が美麗
で印刷効果もすぐれ、防湿、防水、気密性を有し
ている反面紙面は鏡面化されてしまい、入射光を
その入射角度に応じ一定の方向にのみに反射させ
てしまい、この反射光が直接に顧客の目に入つた
り、けばけばし過ぎるきらいがあり、また擦過傷
がつき易く装飾紙として不適当な場合がある。 Laminated processed paper has been put into practical use as a decoration or packaging material, in which a metal vapor-deposited film such as aluminum is formed on one side of a transparent plastic film and then affixed to one side of a paper sheet. In this case, the surface is beautiful, the printing effect is excellent, and it is moisture-proof, waterproof, and airtight, but on the other hand, the paper surface has a mirror finish, and the incident light is reflected only in a certain direction depending on the angle of incidence. This reflected light may directly enter the customer's eyes, be too flashy, and be easily scratched, making it unsuitable for use as decorative paper.
この発明は従来の金属蒸着膜を形成させた包装
材と同じようにガス、水蒸気および熱線に対する
遮断特性をそこなうことなく、しかも本発明独特
の、今迄類例のない白く美しく輝くような感じの
乱反射面を備え、かつ上述した欠点を除去するこ
とを目的とするもので、その特徴とするところ
は、シートやフイルム素材の一面にこれ等素材と
親和性の大にして微小粒子物質を混在させた樹脂
を表面を粗面とした版胴で塗着させ表面が二重に
粗面である樹脂膜を形成する第１の工程と前記工
程により得た前記フイルム素材上の二重に粗面の
樹脂膜転着面に金属蒸着手段を用いて金属蒸着膜
を形成せしめる第２の工程と、この第２の工程に
より金属蒸着膜の表面を前記二重の粗面に対応し
た二重の粗面とし、乱反射金属蒸着膜を形成せし
めるようにしたことを特徴とするフイルム状部材
の表面に乱反射蒸着膜を形成する方法を供給する
ものである。 This invention does not impair its barrier properties against gas, water vapor, and heat rays like the conventional packaging materials formed with metal vapor-deposited films, and it also produces diffused reflection that is unique to this invention and has an unprecedented white and beautiful shine. The purpose is to eliminate the above-mentioned drawbacks, and its feature is that one side of the sheet or film material is mixed with microscopic particle substances that have a high affinity with these materials. A first step of applying the resin using a plate cylinder with a rough surface to form a resin film with a double rough surface, and a double rough resin on the film material obtained by the above step. a second step of forming a metal vapor deposited film on the film transfer surface using a metal vapor deposition means; and a second step that makes the surface of the metal vapor deposited film a double rough surface corresponding to the double rough surface. The present invention provides a method for forming a diffusely reflective vapor deposited film on the surface of a film-like member, characterized in that a diffusely reflective metal vapor deposited film is formed.
以下この発明を図に示す一実施例について詳述
する。 An embodiment of the present invention shown in the drawings will be described in detail below.
第１図において１はポリオレフイン類、ポリエ
ステル等よりなる一面に金属蒸着膜を形成させよ
うとする臨界表面張力が可成り小さく表面が極平
滑で透明あるいは不透明な合成樹脂フイルムでこ
のフイルムは予じめサプライドラム２に巻回され
ておりテイクアツプドラム３に巻取られるように
なつている。４は表面に例えば１インチ当り30〜
100線程度の網目模様を施した版胴で５はドクタ
ー歯である。６は前記フイルムに対し親和性のよ
い可溶性透明プラスチツクに顔料粒子等の極微細
粒子と溶融樹脂を入れた容器、７は前記版胴４に
合成樹脂フイルム１を圧着する加圧ローラ、８ａ
〜８ｆはガイドローラ、９は前記フイルムに塗着
した樹脂膜を乾燥させる乾燥装置、１０は連続真
空蒸着装置で前後に２室づつの減圧室１１ａ〜１
１ｄを有し、中央に真空蒸着室１２を備え、該蒸
着室内には外部より加熱温度をコントロールし得
るヒータ１３、ルツボ１４および蒸発金属をフイ
ルム面に導くガイド板１５ａ，１５ｂが配設され
ている。前記真空蒸着室１２内は、例えば
10-4Torr程度の真空度を保ち得るようになつて
おり、前記真空下でルツボ１４内に入れたAl、
Au、Ag、Cn、Sn、Zn、Cr、Ni、Se、Ti等の単
体金属、Ni−Cr、Ni−Fe、Fe−Co、Au−Ag−
Cu等の合金類、SiO2、TiO2、InO2、Al2O3、
Fe2O3等の金属酸化物その他AgBr、AgClの如き
金属化合物等を熱に強いニクローム線でできたヒ
ータ１３で加熱させてこれを蒸発させる。この蒸
発金属は原子、分子状態を含む極微小粒子化して
真空蒸発室１２内をガイド板１５ａ，１５ｂに添
つて直進し、前記した一面に樹脂膜層１８を塗着
された合成樹脂フイルム１の二重粗面の樹脂膜層
１８に衝突して静止し二重粗面の樹脂膜層１８上
に金属蒸着膜層１９が形成する。尚金属蒸着膜厚
はフイルムの移送速度および金属蒸気の発生量を
コントロールすることにより加減できる。 In Figure 1, 1 is a transparent or opaque synthetic resin film made of polyolefins, polyester, etc., which has a fairly low critical surface tension and an extremely smooth surface to form a metal vapor deposited film on one surface. It is wound on a supply drum 2 and is adapted to be taken up on a take-up drum 3. 4 is for example 30 to 1 inch on the surface
The plate cylinder has a mesh pattern of about 100 lines, and number 5 is a doctor tooth. 6 is a container containing ultrafine particles such as pigment particles and molten resin in a soluble transparent plastic having good affinity for the film; 7 is a pressure roller for pressing the synthetic resin film 1 onto the plate cylinder 4; 8a;
~8f is a guide roller, 9 is a drying device for drying the resin film applied to the film, and 10 is a continuous vacuum evaporation device, with two decompression chambers 11a to 1 at the front and back.
1d, and has a vacuum deposition chamber 12 in the center, in which a heater 13 whose heating temperature can be controlled from the outside, a crucible 14, and guide plates 15a and 15b for guiding the evaporated metal to the film surface are arranged. There is. The inside of the vacuum deposition chamber 12 is, for example,
It is designed to maintain a degree of vacuum of approximately 10 -4 Torr, and the Al placed in the crucible 14 under the vacuum,
Simple metals such as Au, Ag, Cn, Sn, Zn, Cr, Ni, Se, Ti, Ni-Cr, Ni-Fe, Fe-Co, Au-Ag-
Alloys such as Cu, SiO 2 , TiO 2 , InO 2 , Al 2 O 3 ,
Metal oxides such as Fe 2 O 3 and other metal compounds such as AgBr and AgCl are heated by a heater 13 made of a heat-resistant nichrome wire to evaporate them. The evaporated metal is turned into ultra-fine particles containing atoms and molecules, and travels straight through the vacuum evaporation chamber 12 along guide plates 15a and 15b, forming the synthetic resin film 1 with the resin film layer 18 coated on one side. It collides with the double-roughened resin film layer 18 and comes to rest, and a metal vapor deposited film layer 19 is formed on the double-roughened resin film layer 18 . The thickness of the metal vapor deposited film can be adjusted by controlling the film transport speed and the amount of metal vapor generated.
この間合成樹脂フイルム１は駆動ローラ１６、
加圧ローラ１７によりサプライドラム２よりテイ
クアツプドラム３に等速で巻取られる。 During this time, the synthetic resin film 1 is moved by the driving roller 16,
The pressure roller 17 winds the material from the supply drum 2 onto the take-up drum 3 at a constant speed.
第２図ａは前述した第１の工程を用いて合成樹
脂フイルム１の一面に二重粗面の樹脂膜層１８を
形成した拡大断面図で、第２図ｂ，ｃ，ｄはそれ
ぞれ樹脂膜１８の上に金属蒸着膜層１９を形成し
た場合のさらに拡大した断面図で、合成樹脂フイ
ルム１の一面には樹脂層１８とその上に金属蒸着
膜層１９が重なり、版胴４の表面に形成した網目
と、樹脂に混入した顔料粒子等の極微細粒子と樹
脂の粘度および流れ特性により前記樹脂膜層１８
の表面には第２図ａ，ｂで示すような極微小な凹
凸面ａを有する比較的大きい凹凸面ｂが形成さ
れ、この二重の凹凸粗面ａ，ｂに従うように金属
蒸着層１９の表面にも二重の凹凸粗面が形成され
るため、このままの状態においても金属蒸着膜層
面１９への入射光は極めて白く輝くような感じで
効果的に乱反射する。 FIG. 2a is an enlarged cross-sectional view of a resin film layer 18 with a double rough surface formed on one surface of the synthetic resin film 1 using the first step described above, and FIGS. 2b, c, and d are respectively This is a further enlarged cross-sectional view of the case where a metal vapor deposited film layer 19 is formed on the surface of the plate cylinder 4, with the resin layer 18 and the metal vapor deposited film layer 19 overlapping on one side of the synthetic resin film 1. The resin film layer 18 is formed by the formed network, ultrafine particles such as pigment particles mixed in the resin, and the viscosity and flow characteristics of the resin.
A relatively large uneven surface b having extremely small uneven surfaces a as shown in FIG. Since a double uneven rough surface is also formed on the surface, even in this state, the light incident on the metal vapor deposited film layer surface 19 is effectively diffusely reflected with an extremely white shining appearance.
特にこの発明によれば金属蒸着膜層１９は第２
図ｃおよび第２図ｄに示すように前述した第１お
よび第２の工程で二重に凹凸化されているため入
射光は金属蒸着膜層１９の二重の凹凸のため白く
輝くような感じで美しく乱反射する従来見られな
い本件独特のきめ細かい光線反射包装装飾フイル
ム等が得られる。 In particular, according to this invention, the metal vapor deposited film layer 19 is
As shown in Figure c and Figure 2D, since the metal vapor deposited film layer 19 is doubly textured in the first and second steps, the incident light appears to shine white due to the double texture of the metal vapor deposited film layer 19. A unique fine-grained light-reflecting packaging decorative film, etc., which is unique to this invention and which has not been seen before, can be obtained with beautiful diffused reflection.
以上述べたようにこの発明はシートやフイルム
素材の一面に極微小粒子物質を混在させた樹脂を
表面を粗面とした版胴で転着させ表面が二重粗面
の樹脂膜を形成する第１の工程と、前記第１の工
程により得た前記フイルム素材上の二重粗面の樹
脂膜転着面に金属蒸着手段を用いて金属蒸着膜を
形成せしめる第２の工程と、この第２の工程によ
り金属蒸着膜の表面を前記粗面に対応した二重粗
面とし乱反射金属蒸着膜を形成せしめるようにし
たので天然または合成の樹脂の如き有機または無
機物質からなるフイルムやシート部材の表面に白
く輝くような感じの従来みられない本発明独特
の、光線が極めて美しく乱反射し得る金属蒸着膜
を容易に形成できる上に従来の貼合せ加工紙と同
等の物理特性以上のものが安価に加工できる等の
効果を有する。 As described above, the present invention involves transferring a resin mixed with ultrafine particles onto one surface of a sheet or film material using a plate cylinder with a rough surface to form a resin film with a double rough surface. a second step of forming a metal vapor deposited film on the double roughened resin film transfer surface of the film material obtained in the first step using a metal vapor deposition means; In this process, the surface of the metal vapor deposited film is made into a double rough surface corresponding to the rough surface described above, and a diffusely reflective metal vapor deposited film is formed. It is possible to easily form a metal vapor deposited film that is unique to the present invention and can reflect light rays extremely beautifully and diffusely, giving it a white, shining feel, and it also has physical properties equivalent to or better than conventional laminated paper at a lower cost. It has effects such as being able to be processed.
図はいずれもこの発明の一実施例を示すもの
で、第１図は合成樹脂フイルムの一面に二重粗面
の樹脂膜および蒸着膜を連続的に形成する装置の
構成図、第２図ａ〜ｄは前記フイルムと各膜の関
係を示す拡大断面図である。
１……合成樹脂フイルム、２……サプライドラ
ム、３……テイクアツプドラム、４……版胴、７
……加圧ローラ、８ａ〜８ｄ……ガイドローラ、
９……乾燥装置、１０……連続真空蒸着装置、１
８……樹脂膜層、１９……蒸着膜層、ａ……極微
小な凹凸粗面、ｂ……比較的大きい凹凸粗面。
Each of the figures shows an embodiment of the present invention; Fig. 1 is a block diagram of an apparatus for continuously forming a double-roughened resin film and a vapor deposited film on one surface of a synthetic resin film, and Fig. 2 a -d are enlarged cross-sectional views showing the relationship between the film and each film. 1... Synthetic resin film, 2... Supply drum, 3... Take-up drum, 4... Print cylinder, 7
...Pressure roller, 8a to 8d...Guide roller,
9...Drying device, 10...Continuous vacuum deposition device, 1
8...Resin film layer, 19...Vapor deposited film layer, a...Rough surface with extremely small unevenness, b...Rough surface with relatively large unevenness.
Claims (1)
質を混在させた樹脂を表面を粗面とした版胴で転
着させ表面が二重粗面の樹脂膜を形成する第１の
工程と、前記第１の工程により得た前記フイルム
素材上の二重粗面の樹脂膜転着面に金属蒸着手段
を用いて金属蒸着膜を形成せしめる第２の工程と
を備え、この第２の工程により金属蒸着膜の表面
を前記粗面に対応した二重粗面とし乱反射金属蒸
着膜を形成せしめるようにしたことを特徴とする
フイルム状部材の表面に乱反射蒸着膜を形成する
方法。1. A first step of transferring a resin mixed with ultrafine particles onto one surface of a sheet or film material using a plate cylinder with a rough surface to form a resin film with a double rough surface; a second step of forming a metal vapor deposition film on the double-rough resin film transfer surface of the film material obtained in step 1 using a metal vapor deposition means; A method for forming a diffusely reflective vapor deposited film on the surface of a film-like member, characterized in that the surface of the film is a double roughened surface corresponding to the rough surface to form a diffusely reflective metal vapor deposited film.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP4285981A JPS57158238A (en) | 1981-03-24 | 1981-03-24 | Method for forming irregularly reflecting metallized coating on surface of film member |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP4285981A JPS57158238A (en) | 1981-03-24 | 1981-03-24 | Method for forming irregularly reflecting metallized coating on surface of film member |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPS57158238A JPS57158238A (en) | 1982-09-30 |
| JPS6140753B2 true JPS6140753B2 (en) | 1986-09-10 |
Family
ID=12647748
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP4285981A Granted JPS57158238A (en) | 1981-03-24 | 1981-03-24 | Method for forming irregularly reflecting metallized coating on surface of film member |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPS57158238A (en) |
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS6186848U (en) * | 1984-11-12 | 1986-06-06 | ||
| JPS61202386A (en) * | 1985-03-05 | 1986-09-08 | Tokyo Electric Co Ltd | Disk cassette shutter opening/closing device |
| JPS6229680U (en) * | 1985-08-02 | 1987-02-23 | ||
| JPH0643853U (en) * | 1992-10-30 | 1994-06-10 | アイワ株式会社 | Cartridge shutter opener |
Families Citing this family (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP5199162B2 (en) * | 2009-03-27 | 2013-05-15 | 富士フイルム株式会社 | Functional film manufacturing method and manufacturing apparatus |
-
1981
- 1981-03-24 JP JP4285981A patent/JPS57158238A/en active Granted
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS6186848U (en) * | 1984-11-12 | 1986-06-06 | ||
| JPS61202386A (en) * | 1985-03-05 | 1986-09-08 | Tokyo Electric Co Ltd | Disk cassette shutter opening/closing device |
| JPS6229680U (en) * | 1985-08-02 | 1987-02-23 | ||
| JPH0643853U (en) * | 1992-10-30 | 1994-06-10 | アイワ株式会社 | Cartridge shutter opener |
Also Published As
| Publication number | Publication date |
|---|---|
| JPS57158238A (en) | 1982-09-30 |
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