JPS6147703B2 - - Google Patents
Info
- Publication number
- JPS6147703B2 JPS6147703B2 JP56126170A JP12617081A JPS6147703B2 JP S6147703 B2 JPS6147703 B2 JP S6147703B2 JP 56126170 A JP56126170 A JP 56126170A JP 12617081 A JP12617081 A JP 12617081A JP S6147703 B2 JPS6147703 B2 JP S6147703B2
- Authority
- JP
- Japan
- Prior art keywords
- base material
- fine
- film layer
- cooling roll
- resin
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 239000011347 resin Substances 0.000 claims description 22
- 229920005989 resin Polymers 0.000 claims description 22
- 239000000463 material Substances 0.000 claims description 21
- 238000000034 method Methods 0.000 claims description 13
- 238000001816 cooling Methods 0.000 claims description 11
- 239000010419 fine particle Substances 0.000 claims description 7
- 239000002985 plastic film Substances 0.000 claims description 7
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 6
- 229920006255 plastic film Polymers 0.000 claims description 6
- 229910052814 silicon oxide Inorganic materials 0.000 claims description 6
- 238000003475 lamination Methods 0.000 claims description 4
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 claims description 2
- 238000001125 extrusion Methods 0.000 claims description 2
- 239000012943 hotmelt Substances 0.000 claims description 2
- OGIDPMRJRNCKJF-UHFFFAOYSA-N titanium oxide Inorganic materials [Ti]=O OGIDPMRJRNCKJF-UHFFFAOYSA-N 0.000 claims description 2
- 239000002585 base Substances 0.000 description 18
- 239000002904 solvent Substances 0.000 description 9
- 239000008188 pellet Substances 0.000 description 4
- 239000004743 Polypropylene Substances 0.000 description 2
- 229910052784 alkaline earth metal Inorganic materials 0.000 description 2
- 150000001342 alkaline earth metals Chemical class 0.000 description 2
- 238000007796 conventional method Methods 0.000 description 2
- 229920000728 polyester Polymers 0.000 description 2
- -1 polypropylene Polymers 0.000 description 2
- 229920001155 polypropylene Polymers 0.000 description 2
- 239000003513 alkali Substances 0.000 description 1
- 239000011248 coating agent Substances 0.000 description 1
- 238000000576 coating method Methods 0.000 description 1
- 238000010586 diagram Methods 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 238000007756 gravure coating Methods 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 239000000155 melt Substances 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- 238000007645 offset printing Methods 0.000 description 1
- 238000005096 rolling process Methods 0.000 description 1
- 238000007788 roughening Methods 0.000 description 1
- 239000000758 substrate Substances 0.000 description 1
- 239000011882 ultra-fine particle Substances 0.000 description 1
- 239000002699 waste material Substances 0.000 description 1
Landscapes
- Laminated Bodies (AREA)
Description
【発明の詳細な説明】
この発明はプラスチツクフイルムや紙等の長尺
基材の一面に光線乱反射膜層(マツト化層)を形
成する方法に係り、更に詳しくは前記基材の一面
にエキストル−ジヨンラミネート法により基材面
に添着した酸化硅素やアルカリ土類等の微細粒子
混入の熱溶融樹脂を冷却固化するための冷却ロー
ルの表面を粗面化することにより前記基材上に微
細二重粗面の乱反射膜層(マツト化層)を連続的
に形成する方法に関するものである。DETAILED DESCRIPTION OF THE INVENTION The present invention relates to a method of forming a light ray diffusely reflecting film layer (matting layer) on one side of a long base material such as a plastic film or paper, and more specifically, it relates to a method for forming a light ray diffusely reflecting film layer (matting layer) on one side of a long base material such as a plastic film or paper. By roughening the surface of the cooling roll for cooling and solidifying the hot molten resin containing fine particles of silicon oxide, alkaline earth, etc. attached to the surface of the base material by the John lamination method, fine double layers are formed on the base material. The present invention relates to a method of continuously forming a rough reflective film layer (matte layer).
従来の長尺基材の一面に乱反射膜層を形成する
方法としては、すべて樹脂(ベヒクル)を溶剤に
溶かしグラビアコート法シルクスクリーン法等に
より塗着コートし熱乾燥して微細粗面の乱反射膜
層を形成していた。 Conventional methods for forming a diffusely reflective film layer on one side of a long base material include dissolving the resin (vehicle) in a solvent, applying it using a gravure coating method, silk screen method, etc., and drying with heat to form a diffusely reflective film layer on a finely rough surface. It formed a layer.
しかしながらこれら従来方法では前記版胴に樹
脂溶液が付着しやすく版胴目づまりやスクリーン
目づまりが生じて均一なる微細粗面が得られず、
また製品に溶剤が残留しこの製品の加工時や、そ
の二次製品の製造時または使用時にそれぞれ周囲
に有機公害を与えるという欠点と、溶剤に溶解し
ない樹脂(ベヒクル)では実現できないという大
きな欠点があつた。またこの他に時間と共に前記
溶剤に溶かした樹脂の濃度が溶剤の放散により大
となつてしまい前記の濃度管理が繁雑困難を極
め、この種工程の隘路となつていたという欠点も
あつた。 However, in these conventional methods, the resin solution tends to adhere to the plate cylinder, causing clogging of the plate cylinder and screen, making it impossible to obtain a uniform finely roughened surface.
Another disadvantage is that the solvent remains in the product and causes organic pollution to the surrounding area during processing, manufacturing or use of secondary products, and the other major disadvantage is that this cannot be achieved with resins (vehicles) that do not dissolve in solvents. It was hot. Another disadvantage is that the concentration of the resin dissolved in the solvent increases over time due to the dissipation of the solvent, making concentration control extremely complicated and difficult, which has become a bottleneck in this type of process.
この発明は前記従来例による各種欠点をすべて
除去するためになされたもので、その特徴とする
ところは、プラスチツクフイルムや紙などの基材
の一面にエキストル−ジヨンラミネート法によつ
て酸化硅素やアルカリ土類等の微細粒子混入の熱
溶融樹脂を表面が微細粗面の冷却ロールを介して
添着することにより、前記基材の一面に表面が微
細二重粗面の光線乱反射膜層を形成する方法を提
供することにある。 This invention was made in order to eliminate all the various drawbacks of the above-mentioned conventional examples, and its feature is that silicon oxide or alkali is coated on one side of a base material such as a plastic film or paper by an extrusion lamination method. A method of forming a light ray diffused reflection film layer with a fine double rough surface on one side of the base material by applying a hot melt resin mixed with fine particles such as earth through a cooling roll with a fine rough surface. Our goal is to provide the following.
以下この発明を図示の実施例について詳細に説
明する。 The present invention will be described in detail below with reference to the illustrated embodiments.
第1図中Aはポリプロピレンやポリエステルな
どのプラスチツクフイルムや紙等の長尺基材で肉
厚は約8〜200μmで均一に製品化されている。 In FIG. 1, A is a long base material such as a plastic film made of polypropylene or polyester, or paper, and the thickness thereof is approximately 8 to 200 μm and is uniformly manufactured into a product.
第2図はこの発明の実施態様を示し、同図中1
はホツパーで酸化硅素やアルカリ土類、酸化チタ
ン等の極微細粒子D混入の加熱溶融性樹脂例えば
ポリプロピレンやポリエステルのペレツトの投入
口1aを有している。2は押出機で前記樹脂ペレ
ツトを加熱溶融し、下段のTダイ3に押圧し供給
するものである。そして上記Tダイ3の長尺スリ
ツト3aから一定の厚みでしかも一定の幅でフイ
ルム状に押し出された溶融樹脂カーテン部4が形
成されるようにする。 FIG. 2 shows an embodiment of this invention, in which 1
The hopper is a hopper and has an inlet 1a for feeding pellets of heat-meltable resin such as polypropylene or polyester containing ultrafine particles D of silicon oxide, alkaline earth metal, titanium oxide, etc. Reference numeral 2 is an extruder which heats and melts the resin pellets and presses and supplies the resin pellets to the lower T-die 3. A molten resin curtain portion 4 is extruded from the elongated slit 3a of the T-die 3 into a film shape with a constant thickness and width.
一方前記第1図に示す基材Aを巻装したサプラ
イドラム5から引出した基材Aを圧圧ロール6を
経てテイクアツプドラム7に一定の速度で巻取る
ように構成する。そして前記圧力ロール6の表面
に密接して送られる長尺基材Aの表面に所定の圧
力で転接するように設けられた表面が極微細粗面
の冷却ロール8が用意されている。 On the other hand, the structure is such that the base material A drawn from the supply drum 5 on which the base material A shown in FIG. A cooling roll 8 having a very finely roughened surface is provided so as to be in rolling contact with the surface of the elongated base material A that is fed in close contact with the surface of the pressure roll 6 at a predetermined pressure.
さらに前記溶融樹脂カーテン部4が圧力ロール
6の表面を所定速度で矢印方向に移動する基材A
の表面と前記冷却ロール8との間にまんべんなく
落入させることにより、圧力ロール6を経た基材
Aの一面に添着された前記溶融樹脂の表面が冷却
ロール8の微細粗面に応じて冷却固化し微細粒子
Dの混在と相俟つて表面が微細二重粗面Bを有す
る乱反射膜層(マツト化層)Cが第3図に示すよ
うに均一な平均厚み(10〜20μm)で形成され、
フイルムや紙等の基材Aの一面に第4図aに示す
ように微細粒子D混入の二重粗面による乱反射膜
層(マツト化層)Bが美しく形成されたこの発明
による製品9が得られる。 Further, the base material A on which the molten resin curtain portion 4 moves on the surface of the pressure roll 6 at a predetermined speed in the direction of the arrow.
By allowing the molten resin to fall evenly between the surface of the substrate A and the cooling roll 8, the surface of the molten resin attached to one side of the base material A that has passed through the pressure roll 6 is cooled and solidified according to the fine roughness of the cooling roll 8. In combination with the mixture of fine particles D, a diffusely reflective film layer (matte layer) C having a fine double rough surface B is formed with a uniform average thickness (10 to 20 μm) as shown in FIG.
A product 9 according to the present invention is obtained in which a diffusely reflective film layer (matte layer) B is beautifully formed on one surface of a base material A such as a film or paper as shown in FIG. It will be done.
この製品9は例えばトレーシングフイルムやオ
フセツト印刷用のプラスチツクシート等として使
用でき、応用範囲は広い。 This product 9 can be used, for example, as a tracing film or a plastic sheet for offset printing, and has a wide range of applications.
なお、冷却ロール8の表面に先端円弧状の極微
細粗面を形成し酸化硅素やアルカリ土類等の微細
粒子を略球形のものを用いれば第4図bに示すよ
うに先端円弧形の微細二重粗面の光線乱反射膜層
Bを得ることができる。 In addition, if an extremely fine roughened surface with an arcuate tip is formed on the surface of the cooling roll 8 and the fine particles of silicon oxide, alkaline earth, etc. are used in a substantially spherical shape, the tip will have an arcuate tip as shown in FIG. 4b. A light ray diffused reflection film layer B having a fine double rough surface can be obtained.
以上述べたようにこの発明によればプラスチツ
クフイルムや紙などの基材の一面にエキストル−
ジヨンラミネート法によつて酸化硅素やアルカリ
土類等の微細粒子混入の熱溶融樹脂を表面が微細
粗面の冷却ロールを介して添着することにより、
前記基材の一面に表面が微細二重粗面の効線乱反
射膜層を形成するようにしたので前記従来例のよ
うな溶剤溶融樹脂法に比べて溶剤を使用しないの
で冷却ロールの目づまりがなくしかもコートむら
も生じない。 As described above, according to the present invention, an extract can be applied to one side of a base material such as a plastic film or paper.
By applying hot molten resin mixed with fine particles such as silicon oxide and alkaline earth metal through a cooling roll with a finely rough surface using the John lamination method,
Since an effective ray diffused reflection film layer with a fine double rough surface is formed on one side of the base material, no solvent is used compared to the conventional solvent-melted resin method, so there is no clogging of the cooling roll. Moreover, no uneven coating occurs.
この他に本発明によれば、溶剤を使用しないの
で溶剤放散による資源の無駄や周囲に与える有機
公害が全くない。しかもこの発明では加熱溶融し
た樹脂による乱反射二重粗面を基材上に強固に添
着形成できるので、極めて美しく乱反射させるこ
とができ、さらに溶剤に溶解しない樹脂でも実現
でき、しかも溶融樹脂の濃度管理が不要で、マイ
コン等による溶融樹脂の粘度管理を最適条件で自
動化でき均一製品を安価に多量製造できるという
工業的に新規かつ有用な効果を有する。 In addition, according to the present invention, since no solvent is used, there is no waste of resources due to solvent dissipation and no organic pollution to the surrounding area. Moreover, in this invention, a double rough reflection surface made of heated and molten resin can be firmly adhered to the base material, making it possible to achieve extremely beautiful diffused reflection.Furthermore, it can be achieved using a resin that does not dissolve in solvents, and the concentration of the molten resin can be controlled. This method has new and useful industrial effects, such as eliminating the need for viscosity management of molten resin using a microcomputer, etc., and automating the viscosity control of the molten resin under optimal conditions, allowing uniform products to be produced in large quantities at low cost.
図はいずれもこの発明の実施例を示すもので第
1図は基材の拡大断面図、第2図はこの発明の実
施態様を示す構成図、第3図はこの発明による製
品の一例を示す拡大断面図、第4図aはこの発明
による製品の要部をさらに拡大した断面図、第4
図bは変形例による製品の要部の拡大断面図であ
る。
A……長尺基材、B……表面微細二重粗面、C
……乱反射膜層、D……微細粒子、1……ホツパ
ー、1a……ペレツトの投入口、2……押出機、
3……Tダイ、3a……スリツト、4……溶融樹
脂カーテン部、5……サプライドラム、6……圧
力ロール、7……テイクアツプドラム、8……冷
却ロール、9……製品。
The figures all show examples of the present invention; Fig. 1 is an enlarged sectional view of a base material, Fig. 2 is a configuration diagram showing an embodiment of the invention, and Fig. 3 shows an example of a product according to the invention. An enlarged cross-sectional view, FIG.
FIG. b is an enlarged sectional view of a main part of a product according to a modified example. A...Long base material, B...Surface fine double rough surface, C
...Diffuse reflection film layer, D...Fine particles, 1...Hopper, 1a...Pellet inlet, 2...Extruder,
3... T-die, 3a... slit, 4... molten resin curtain section, 5... supply drum, 6... pressure roll, 7... take-up drum, 8... cooling roll, 9... product.
Claims (1)
エキストル−ジヨンラミネート法によつて酸化硅
素や酸化チタン等の微細粒子混入の熱溶融樹脂を
表面が微細粗面の冷却ロールを介して添着するこ
とにより、基材の面に表面が微細二重粗面の光線
乱反射膜層を形成する方法。1. By applying a hot melt resin mixed with fine particles such as silicon oxide or titanium oxide to the surface of a base material such as plastic film or paper using an extrusion lamination method via a cooling roll with a finely roughened surface. , a method of forming a light ray diffused reflection film layer with a fine double rough surface on the surface of a base material.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP56126170A JPS5828373A (en) | 1981-08-12 | 1981-08-12 | Method of forming beam diffused reflection film layer onto surface of base material |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP56126170A JPS5828373A (en) | 1981-08-12 | 1981-08-12 | Method of forming beam diffused reflection film layer onto surface of base material |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPS5828373A JPS5828373A (en) | 1983-02-19 |
| JPS6147703B2 true JPS6147703B2 (en) | 1986-10-21 |
Family
ID=14928408
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP56126170A Granted JPS5828373A (en) | 1981-08-12 | 1981-08-12 | Method of forming beam diffused reflection film layer onto surface of base material |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPS5828373A (en) |
Families Citing this family (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2717128B2 (en) * | 1988-11-17 | 1998-02-18 | 三菱レイヨン株式会社 | Polyester-based different shrinkage mixed yarn |
| CN109650118A (en) * | 2019-02-28 | 2019-04-19 | 安徽皖升力环保股份有限公司 | A kind of production method of anti-aging HDPE matte antiseepage film |
-
1981
- 1981-08-12 JP JP56126170A patent/JPS5828373A/en active Granted
Also Published As
| Publication number | Publication date |
|---|---|
| JPS5828373A (en) | 1983-02-19 |
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