JPS6156203B2 - - Google Patents
Info
- Publication number
- JPS6156203B2 JPS6156203B2 JP15820577A JP15820577A JPS6156203B2 JP S6156203 B2 JPS6156203 B2 JP S6156203B2 JP 15820577 A JP15820577 A JP 15820577A JP 15820577 A JP15820577 A JP 15820577A JP S6156203 B2 JPS6156203 B2 JP S6156203B2
- Authority
- JP
- Japan
- Prior art keywords
- montmorillonite
- powder
- humidity
- vinegar
- smoke liquid
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- GUJOJGAPFQRJSV-UHFFFAOYSA-N dialuminum;dioxosilane;oxygen(2-);hydrate Chemical compound O.[O-2].[O-2].[O-2].[Al+3].[Al+3].O=[Si]=O.O=[Si]=O.O=[Si]=O.O=[Si]=O GUJOJGAPFQRJSV-UHFFFAOYSA-N 0.000 claims description 22
- 229910052901 montmorillonite Inorganic materials 0.000 claims description 21
- 239000000779 smoke Substances 0.000 claims description 20
- 239000000843 powder Substances 0.000 claims description 19
- 239000000052 vinegar Substances 0.000 claims description 18
- 235000021419 vinegar Nutrition 0.000 claims description 18
- 239000007788 liquid Substances 0.000 claims description 17
- 239000003795 chemical substances by application Substances 0.000 claims description 13
- 239000000203 mixture Substances 0.000 claims description 13
- 238000001179 sorption measurement Methods 0.000 claims description 9
- 241000607479 Yersinia pestis Species 0.000 claims description 8
- 239000000463 material Substances 0.000 claims description 8
- 238000004519 manufacturing process Methods 0.000 claims description 7
- 230000002401 inhibitory effect Effects 0.000 claims description 4
- 230000000749 insecticidal effect Effects 0.000 claims description 4
- 238000000034 method Methods 0.000 claims description 4
- 241000238631 Hexapoda Species 0.000 claims description 3
- 239000003638 chemical reducing agent Substances 0.000 claims description 3
- 230000002147 killing effect Effects 0.000 claims description 3
- 238000002156 mixing Methods 0.000 claims description 3
- 230000008569 process Effects 0.000 claims description 2
- 238000007670 refining Methods 0.000 claims description 2
- 239000002917 insecticide Substances 0.000 claims 2
- 230000000844 anti-bacterial effect Effects 0.000 claims 1
- 239000003899 bactericide agent Substances 0.000 claims 1
- 239000000417 fungicide Substances 0.000 claims 1
- 239000002023 wood Substances 0.000 description 16
- 241000196324 Embryophyta Species 0.000 description 14
- 201000010099 disease Diseases 0.000 description 9
- 208000037265 diseases, disorders, signs and symptoms Diseases 0.000 description 9
- 239000002689 soil Substances 0.000 description 9
- 230000000694 effects Effects 0.000 description 8
- 238000009833 condensation Methods 0.000 description 7
- 230000005494 condensation Effects 0.000 description 7
- 230000036541 health Effects 0.000 description 6
- 230000006872 improvement Effects 0.000 description 6
- 239000000575 pesticide Substances 0.000 description 6
- 230000007721 medicinal effect Effects 0.000 description 5
- 230000008635 plant growth Effects 0.000 description 5
- 230000005068 transpiration Effects 0.000 description 5
- 230000015572 biosynthetic process Effects 0.000 description 4
- 230000000711 cancerogenic effect Effects 0.000 description 4
- 231100000315 carcinogenic Toxicity 0.000 description 4
- 230000000116 mitigating effect Effects 0.000 description 4
- 239000000126 substance Substances 0.000 description 4
- 241000894006 Bacteria Species 0.000 description 3
- 230000037429 base substitution Effects 0.000 description 3
- 239000003337 fertilizer Substances 0.000 description 3
- 229910052500 inorganic mineral Inorganic materials 0.000 description 3
- 239000011707 mineral Substances 0.000 description 3
- 230000029553 photosynthesis Effects 0.000 description 3
- 238000010672 photosynthesis Methods 0.000 description 3
- 230000002829 reductive effect Effects 0.000 description 3
- 230000009471 action Effects 0.000 description 2
- 230000003213 activating effect Effects 0.000 description 2
- 230000002411 adverse Effects 0.000 description 2
- 244000052616 bacterial pathogen Species 0.000 description 2
- 230000007812 deficiency Effects 0.000 description 2
- 238000001704 evaporation Methods 0.000 description 2
- 230000001976 improved effect Effects 0.000 description 2
- 239000002245 particle Substances 0.000 description 2
- 238000005507 spraying Methods 0.000 description 2
- 238000003756 stirring Methods 0.000 description 2
- 230000008961 swelling Effects 0.000 description 2
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 description 1
- 241001124076 Aphididae Species 0.000 description 1
- 208000008035 Back Pain Diseases 0.000 description 1
- 241000424000 Berberomeloe majalis Species 0.000 description 1
- 235000003801 Castanea crenata Nutrition 0.000 description 1
- 244000209117 Castanea crenata Species 0.000 description 1
- 241000221785 Erysiphales Species 0.000 description 1
- 206010019233 Headaches Diseases 0.000 description 1
- 241001465754 Metazoa Species 0.000 description 1
- 206010028980 Neoplasm Diseases 0.000 description 1
- 241000233679 Peronosporaceae Species 0.000 description 1
- 241000576755 Sclerotia Species 0.000 description 1
- 206010047700 Vomiting Diseases 0.000 description 1
- 238000009825 accumulation Methods 0.000 description 1
- 239000000443 aerosol Substances 0.000 description 1
- 230000004075 alteration Effects 0.000 description 1
- 230000002421 anti-septic effect Effects 0.000 description 1
- 201000011510 cancer Diseases 0.000 description 1
- 239000002781 deodorant agent Substances 0.000 description 1
- 230000001877 deodorizing effect Effects 0.000 description 1
- 239000000645 desinfectant Substances 0.000 description 1
- 235000005911 diet Nutrition 0.000 description 1
- 230000037213 diet Effects 0.000 description 1
- 238000009792 diffusion process Methods 0.000 description 1
- 208000002173 dizziness Diseases 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 230000008020 evaporation Effects 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- 230000002349 favourable effect Effects 0.000 description 1
- 238000007667 floating Methods 0.000 description 1
- 235000013305 food Nutrition 0.000 description 1
- 239000000446 fuel Substances 0.000 description 1
- 230000005484 gravity Effects 0.000 description 1
- 230000012010 growth Effects 0.000 description 1
- 238000003306 harvesting Methods 0.000 description 1
- 231100000869 headache Toxicity 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 238000003898 horticulture Methods 0.000 description 1
- 230000008595 infiltration Effects 0.000 description 1
- 238000001764 infiltration Methods 0.000 description 1
- 239000000077 insect repellent Substances 0.000 description 1
- 230000001678 irradiating effect Effects 0.000 description 1
- QSHDDOUJBYECFT-UHFFFAOYSA-N mercury Chemical compound [Hg] QSHDDOUJBYECFT-UHFFFAOYSA-N 0.000 description 1
- 229910052753 mercury Inorganic materials 0.000 description 1
- 239000003992 organochlorine insecticide Substances 0.000 description 1
- 244000052769 pathogen Species 0.000 description 1
- 230000001717 pathogenic effect Effects 0.000 description 1
- 230000001766 physiological effect Effects 0.000 description 1
- 230000035790 physiological processes and functions Effects 0.000 description 1
- 244000000003 plant pathogen Species 0.000 description 1
- 230000002265 prevention Effects 0.000 description 1
- 230000003449 preventive effect Effects 0.000 description 1
- 230000002250 progressing effect Effects 0.000 description 1
- 238000010298 pulverizing process Methods 0.000 description 1
- 230000002040 relaxant effect Effects 0.000 description 1
- 230000000391 smoking effect Effects 0.000 description 1
- 230000007480 spreading Effects 0.000 description 1
- 238000003892 spreading Methods 0.000 description 1
- 230000001954 sterilising effect Effects 0.000 description 1
- 238000004659 sterilization and disinfection Methods 0.000 description 1
- 238000005728 strengthening Methods 0.000 description 1
- 230000002522 swelling effect Effects 0.000 description 1
- 208000024891 symptom Diseases 0.000 description 1
- 239000006188 syrup Substances 0.000 description 1
- 235000020357 syrup Nutrition 0.000 description 1
- 235000013311 vegetables Nutrition 0.000 description 1
- 210000003462 vein Anatomy 0.000 description 1
- 238000009423 ventilation Methods 0.000 description 1
- 230000008673 vomiting Effects 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
Landscapes
- Solid-Sorbent Or Filter-Aiding Compositions (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
- Drying Of Gases (AREA)
Description
本願の発明は、殺虫、植物の病害菌抑止ならび
に温室などの湿度緩和剤およびその製造方法に関
し、とくに、栽培植物の害虫、病害菌の抑止およ
び温室などにおける湿度を速やかに緩和調節する
ことによつて植物の成育上良好な還境を醸成する
と共に、温室作業従事者の作業条件の改善、保険
衛生上健康保持に有効なる組成物およびその製造
方法に関する。
従来、農、園芸上育苗、早期栽培或いは季節外
れ栽培等において、温室利用による栽培が一般化
し、その規模も大型化し、栽培漁業と共に今や吾
国における食生活上の重要なる供給源となり、総
合的な温室栽培技術として日々進歩しつつある。
そして肥料、土壌の改良、病虫害の予防、駆除
薬剤の進歩、その他温室内の温度の自動調節、換
気等栽培植物の種類、栽培目的に適応する栽培育
成上の環境の良化改善が行われ、良質の作物を随
時多収獲することが可能になつて来た。
しかし、それらの施設ならびに総合技術は、栽
培植物の育成上および栽培従事者の作業条件、保
険衛生上必ずしも完壁な技術とは言えず多々改善
の余地が残されている。
例えば、太陽光線の有効確保による光合成の強
化、燃費の改善、湿度調節による植物の生理作用
の活性化或いは除湿による栽培従事者の労働環境
の快適化および保健衛生上有害条件の排除、その
他高温多湿、病虫害駆除薬剤に基因する所謂温室
病(ハウス病)の予防措置、ならびに土壌の改良
手段等の技術の欠陥から、就中高温多湿に基く霧
の発生によつて室内の透視が困難となり、作業の
円滑化は阻害され、又は病中害駆除農薬剤の蒸化
拡散による健康上有害物質の継続吸引等によつて
生ずる目まい、頭痛、腰痛、嘔吐等の温室病の多
発、とくに撒布農薬に含有する有機塩素系殺虫
剤、有機水銀剤或いはタール分等の発ガン性物質
の蒸散からは、未だ学問的には充分解明されてい
ないが、ガン患者発生のおそれがあることを憂慮
する声が次第の高まりつつあり、種々の欠点が免
れなかつた。
上記に鑑み、発明者は多年研究の結果それらの
欠陥のいくつかを克服除去することのできる本発
明を完成したものである。
したがつて本発明の目的は、より簡単な方法
で、かつより安価に提供できる温室内の湿度を緩
和調節し、発生中の霧又は結露を速かに消去し、
或いは霧の発生を防止できる湿度緩和剤およびそ
の製造方法を供することであり、本発明の次の目
的は、撒布沈降後は土壌中の肥料成分を吸着し緩
効性とすると共に、その置換性塩基により土壌を
改良し、植物を育生に寄与せしめることのできる
組成分およびその製造方法を供することであり、
さらに本発明の次の目的は、植物の病虫害の発生
を抑止し、駆除することができ、したがつて、在
来使用中の有害な農薬剤に代替せしめ或いはその
使用量を減少できる組成物およびその製造方法を
供することである。
本発明の前記の目的およびその他の目的ならび
に特徴は次の説明によつて知ることができる。
本発明における組成物は、天然産モンモリロナ
イト(Montmorillonite)又は同類の多孔質鉱物
に微粉に、所謂粗木酢液の蒸溜燻液を一定の条件
下にて吸着させることを特徴とするもので、この
モンモリロナイトは、島根県太田市地域の中新世
石見層群久利累層の斜長流紋岩々脈および凝灰岩
〜火山角礫岩が変質して形成されたものと推定さ
れる鉱床より白色又は灰白色の微細な粉末の塊状
で産出され、下記の組成および膨潤度、塩基置換
容量などの特性を有する。
The invention of the present application relates to an agent for killing insects, suppressing plant pathogens, controlling humidity in greenhouses, etc., and a method for producing the same. The present invention relates to a composition that is effective in creating a favorable environment for the growth of plants, improving the working conditions of greenhouse workers, and maintaining health in terms of health and hygiene, and a method for producing the same. Conventionally, cultivation using greenhouses has become common in agriculture, horticulture, seedling raising, early cultivation, out-of-season cultivation, etc., and its scale has also increased, and together with cultivation and fishing, it has now become an important source of food for our country's diet, and has become a comprehensive Greenhouse cultivation technology is progressing day by day. Improvements have also been made in fertilizers, soil improvement, prevention of pests and diseases, advances in pesticides, automatic temperature control in greenhouses, ventilation, and other improvements to the cultivation environment that is adapted to the type of cultivated plants and the purpose of cultivation. It has become possible to harvest large amounts of high-quality crops at any time. However, these facilities and comprehensive techniques are not necessarily perfect in terms of the cultivation of cultivated plants, the working conditions of cultivation personnel, health and hygiene, and there is still room for improvement. For example, strengthening photosynthesis by ensuring effective sunlight, improving fuel efficiency, activating the physiological functions of plants by controlling humidity, making the working environment of cultivation workers more comfortable and eliminating conditions harmful to health and hygiene by dehumidifying, and other measures such as high temperature and high humidity. Due to deficiencies in preventive measures against so-called greenhouse disease (house disease) caused by pesticides and soil improvement methods, it is difficult to see through indoor spaces due to the formation of fog caused by high temperatures and high humidity, making work difficult. The facilitation of the process is hindered, and the frequent occurrence of greenhouse diseases such as dizziness, headaches, back pain, and vomiting caused by continuous inhalation of substances harmful to health due to evaporation and diffusion of disease control pesticides, especially those contained in sprayed pesticides. The transpiration of carcinogenic substances such as organochlorine insecticides, organic mercury agents, and tar is not fully understood academically, but there are increasing voices of concern that it may cause cancer patients. The situation was increasing, and various drawbacks were unavoidable. In view of the above, after many years of research, the inventors have completed the present invention which overcomes and eliminates some of these deficiencies. Therefore, the object of the present invention is to moderately adjust the humidity in a greenhouse in a simpler way and at a lower cost, quickly eliminate any fog or condensation that is occurring, and
Alternatively, it is an object of the present invention to provide a humidity reducing agent that can prevent the generation of fog, and a method for producing the same.The next object of the present invention is to adsorb fertilizer components in the soil after spreading and settling, to make it slow-release, and to improve its replacement properties. It is an object of the present invention to provide a composition that can improve soil with a base and contribute to the growth of plants, and a method for producing the composition.
Furthermore, the next object of the present invention is to provide a composition and a composition capable of suppressing and exterminating the occurrence of pests and diseases of plants, and therefore capable of replacing harmful pesticides currently in use or reducing the amount of the pesticides used. An object of the present invention is to provide a manufacturing method thereof. The above objects and other objects and features of the present invention can be learned from the following description. The composition of the present invention is characterized in that distilled smoke of so-called crude wood vinegar is adsorbed to fine powder on naturally produced montmorillonite or similar porous minerals under certain conditions. is a white or grayish-white fine ore deposit estimated to have been formed by alteration of oblique rhyolite veins and tuff to volcanic breccia of the Miocene Iwami Group Kuri Formation in the Ota City area of Shimane Prefecture. It is produced in the form of a lump of powder, and has the following properties such as composition, degree of swelling, and base substitution capacity.
【表】【table】
【表】
又、吸着される木酢液は、木材を乾溜して得ら
れる殺菌、防腐、防虫、脱臭、動植物の生理作用
の改善等に効果的な公知の粗木酢液を蒸溜精製
し、その燻液中の溶解タールの含有量0.05%以下
とした燻液を100〜150メツシユの微粉状にしたモ
ンモリロナイト100量に対し、20〜40量の重量比
の燻液を混和し吸着せしめて、燻液中の気発性分
の散逸を防ぎその薬効を持続せしめる。
本発明の特徴として、上記粗木酢液を蒸溜精製
した燻液を吸着させるのは、従来殺菌剤或いは消
臭剤用としては粗木酢液をそのまま使用していた
が、粗木酢液中には通常2%位いの発ガン性の溶
解タール分を含んで居り、この溶解タール分を含
む粗木酢液を使用していては、撒布沈降後、継続
撒布の累積によつて、発ガン性物質の付着或いは
蒸散により悪影響を受け、将来ガン性疾患の発生
が危惧されるからで、末だ粗木酢液中の発ガン性
溶解タール分による被害歴は問題視されていない
が、人体に悪影響を及ぼすおそれがあると認めら
れる物質の使用は、極力避けるべきであるとの知
見から、とくに本発明において粗木酢液の使用を
採用しないものである。
しかし、本発明における粗木酢液の蒸溜燻液の
吸着による製品の殺虫、病害菌の抑止効果は、後
記するように、粗木酢液使用に比し差異は認めら
れなかつた。又、モンモリロナイト100量に対
し、燻液20〜40重量比としたのは、燻液20量以下
では、殺虫等の薬効は期し難く、又40量以上を混
和しなくとも薬効が充分期待できることが判つた
結果である。
次に実施例につき説明する。
実施例 1
天然産モンモリロナイトの塊状鉱物を一旦風乾
し10〜20m/mの細片としたものを、粉枠機にて
150メツシユの微粉状に粉砕した後、ロータリー
キルン乾燥機にて80℃にて10分間加熱脱水した主
材100量に対し、粗木酢液を蒸溜してその溶解タ
ール分0.05%以下の燻液30量を重量比にて散布混
和し、モンモリロナイトの微粉に燻液を吸着させ
たものを常温下にて5日間放置し、モンモリロナ
イト主材に燻液の吸着を均霑化させた上、さらに
このものをロータリーキルン乾燥機にて60℃にて
10分間加熱脱水し微粉状の製品基剤を得た。
次に上記基剤20量に対し、基剤に用いたモンモ
リロナイトと同一の150メツシユとし加熱脱水し
た燻液吸着前のモンモリロナイト80量を重量比に
混合撹拌して製品を得た。
実施例 2
天然産モンモリロナイトの塊状鉱物を一旦風乾
し10〜20m/mの細片としたものを、100メツシユ
の微粉状に粉砕した後、ロータリーキルン乾燥機
にて100℃にて10分間加熱脱水した主材100量に対
し、粗木酢液を蒸溜してその溶解タール0.05%以
下の燻液40量を重量比にて散布混和し、モンモリ
ロナイトの微粉に燻液を吸着させたものを常温下
にて7日間放置し、燻液の吸着を均霑化させた
上、さらにこのものを乾燥機にて50℃にて10分間
加熱脱水し、微粉状の製品基剤を得た。
上記基剤20量に対し、100メツシユとし加熱脱
水した燻液吸着前のモンモリロナイト100量を重
量比にて混合撹拌して製品を得た。
上記第1実施例によつて得た基剤にモンモリロ
ナイトを混合撹拌して得た製品を粉末のまま公知
の粉剤撒布器を介して、広さ30アール、室温18
℃、湿度85度、室内に霧が発生し10m先透視困
難、側壁部に結露状態下の温室に20Kgの緩和剤を
撒布したところ約10分間にて、結露は側壁部を流
下し、霧は消去され透視良行となり、湿度65度室
内は爽快となり、太陽光線の照射は良行となり熱
費の改善ができた。
従来室温の温度は、窓を開き換気して除湿する
ことでもできるが、窓を開放することにより、室
温を低下さすこととなり、恒温化上適切と言えな
い。
上記のことは、室内に充満した霧の液層中に撒
布した緩和剤が均霑化されて浮遊中に、その多孔
性吸着能によつて水分が急速に吸着され、その浮
遊分は重力を増し、地上又は植物の葉茎上に沈降
する結果であつて、その後長時間霧の発生は見ら
れなかつた。
又、別に上記30アール、室温16℃、湿度80度、
霧の発生は見られないが、翌朝の外気の冷却に伴
い、室内に霧の発生の予想される温室内に20Kgの
緩和剤を撒布しておき、翌朝迄放置し室内を検し
たところ霧の発生および結露等は見られなかつ
た。
即ち、室内に撒布され浮遊中の緩和剤の粒子
が、室内に蒸散中の水蒸気を吸着した結果湿度が
緩和されたものと認められる。
したがつて、早朝温室内の栽培植物は、霧の発
生或いは側壁部又は天井部の結露によつて、太陽
光線を遮断されることがなくなり、太陽の光源に
よる光合成の生理作用の継続延時間の労費が妨げ
られる結果、葉温を高め、葉の気孔を開く生理作
用を促進し植物の育成上好結果を齎らすことがで
きる。
又、室内の多湿状態を緩和し湿度を適宜に低下
させ室温を適宜適温とすることによつて植物の蒸
散作用が旺盛となり、植物の育成上きわめて効果
的である。
上記により、栽培植物に適した室温とした温室
に湿度を調節のため、本発明による緩和剤を使用
し、実験栽培の結果、従来の温室に比し育苗の歩
留り、蔬菜類の生育、結実歩留り等は良好となり
多収獲の成績を揚げることができた。
さらに又、高温多湿によつて発生が誘発される
菌核、ベト、ウドン粉病等の温室内において多発
する病害菌および油虫(アリマキ)等の害虫類
は、撒布沈降後地面および葉茎上に付着し、その
木醋液の薬効により、害虫および病害菌の活動を
抑止し被害を少なくすることができた。
このことは、沈降した緩和剤の吸着性および膨
潤性能によつて土壌中に浸透中に木酢液が植物に
吸収され或いは室内に蒸散されることによつて、
その薬効が作用するものと認められる。
又、沈降した緩和剤は土壌中において膨潤する
と共に土壌中に吸収され雑菌を減少し、その塩基
置換特性によつて、土壌が改良され、肥料成分を
吸着し緩効性ならしめ、植物の育成環境を改善す
る結果と認められる。
さらに又、この緩和剤を温室内に限らず、露地
栽培中の植物或いは地面に粉剤のまま或いは液状
として撒布することによつて、害虫の駆除又は病
害菌による病状を抑止することもできる。
次に第2実施例による緩和剤を用いて実験した
結果は、第1実施例における結果と大差はなかつ
たが、第1実施例における150メツシユのモンモ
リロナイトに比し、100メツシユのモンモリロナ
イトを主材とした第2実施例の緩和剤の方が除湿
効果および、殺虫、病害菌の抑止効果がやや劣る
ことが認められた。したがつて主材モンモリロナ
イトの粒子は100メツシユ以上とすることや望ま
しい。
上述のように、本発明による湿度緩和剤は、温
室内の湿度を緩和することによつて、霧又は結露
を消去し或いはその発生を予防し、これによつて
温室内を快適にすることにより、作業環境を改善
して、作業員の保険衛生に寄与しかつ霧又は結露
をなくすることによつて、太陽光線の照射を有効
にし、よつて植物の光合成を有効活溌化すると共
に室内の湿度を緩和調節することによつて、その
植物の蒸散作用に適した湿度の撰択により、蒸散
作用を適格ならしめ、植物育成上の環境を著しく
改善することができる。
さらに又、吸着する木酢燻液の薬効による殺
虫、病害菌の発生の抑止、ならびにモンモリロナ
イトの吸着、膨潤、塩基置換特性等による土壌の
改良作用等に好結果を齎らすことができ多収獲が
期待できる。[Table] In addition, the adsorbed wood vinegar is obtained by distilling and refining the known crude wood vinegar that is effective for sterilization, antiseptic, insect repellent, deodorizing, improving the physiological effects of animals and plants, etc. obtained by dry distilling wood, and then smoking it. Smoke liquid with a dissolved tar content of 0.05% or less is mixed with 20 to 40 weight ratio of 100 pieces of montmorillonite made into fine powder of 100 to 150 mesh and adsorbed. Prevents the dissipation of the aerosol content and maintains its medicinal efficacy. As a feature of the present invention, the above-mentioned crude wood vinegar solution is distilled and purified to adsorb smoke liquid. Conventionally, crude wood vinegar solution was used as it is for disinfectants or deodorants, but crude wood vinegar solution usually contains It contains about 2% carcinogenic dissolved tar, and if crude wood vinegar containing this dissolved tar is used, the carcinogenic substances will accumulate after being sprayed and settled, due to the accumulation of continuous spraying. This is because there is a risk of cancerous disease occurring in the future due to adverse effects due to adhesion or transpiration.Although there has been no history of damage caused by the carcinogenic dissolved tar in the crude wood vinegar, there is a risk that it may have an adverse effect on the human body. Based on the knowledge that the use of substances that are recognized to be harmful should be avoided as much as possible, the use of crude wood vinegar is not particularly adopted in the present invention. However, as will be described later, no difference was observed in the product's insecticidal and pathogen-inhibiting effects due to the adsorption of distilled smoke to crude wood vinegar in the present invention compared to the use of crude wood vinegar. In addition, the weight ratio of the liquid smoke is 20 to 40 per 100 amounts of montmorillonite because it is difficult to expect medicinal effects such as insecticidal effects if the amount of smoke is less than 20, and sufficient medicinal effects can be expected even if the amount of smoke is less than 40. This is the result. Next, an example will be explained. Example 1 Naturally produced montmorillonite lump mineral is air-dried and made into small pieces of 10 to 20 m/m, and then processed using a powder frame machine.
After pulverizing into 150 mesh fine powder, 100 volumes of the main material are heated and dehydrated in a rotary kiln dryer at 80℃ for 10 minutes, and 30 volumes of smoke liquid with a dissolved tar content of 0.05% or less obtained by distilling crude wood vinegar are used. The mixture was sprayed and mixed in a weight ratio, and the fine powder of montmorillonite was adsorbed with liquid smoke.The mixture was left at room temperature for 5 days to even out the adsorption of liquid smoke onto the main montmorillonite material, and then this mixture was heated in a rotary kiln. Dryer at 60℃
The mixture was heated and dehydrated for 10 minutes to obtain a fine powder product base. Next, 20 amounts of the above base material were mixed with 80 amounts of montmorillonite, which had been heat-dehydrated and heated to 150 mesh as the montmorillonite used as the base material and had not yet been adsorbed with liquid smoke, mixed and stirred in a weight ratio to obtain a product. Example 2 Naturally produced montmorillonite lump mineral was once air-dried into pieces with a size of 10 to 20 m/m, which was ground into a fine powder of 100 mesh, and then heated and dehydrated at 100°C for 10 minutes in a rotary kiln dryer. For 100 parts of the main material, 40 parts of smoke liquid containing 0.05% or less of dissolved tar obtained by distilling crude wood vinegar solution is sprayed and mixed in a weight ratio, and the smoke liquid is adsorbed on fine montmorillonite powder at room temperature. After being left to stand for 7 days to equalize the adsorption of liquid smoke, this product was further heated and dehydrated in a dryer at 50°C for 10 minutes to obtain a fine powder product base. A product was obtained by mixing and stirring in a weight ratio of 100 meshes of heated and dehydrated montmorillonite before smoke liquid adsorption to 20 amounts of the above base. A product obtained by mixing and stirring montmorillonite into the base obtained in the first example above was passed through a known powder spreader as a powder to an area of 30 are and at a room temperature of 18 cm.
℃, humidity is 85 degrees, fog has formed inside the room and it is difficult to see 10 meters ahead, and when 20 kg of mitigation agent is sprayed in a greenhouse with dew condensation on the side walls, the condensation flows down the side walls and the fog disappears in about 10 minutes. It was erased and the visibility was good, the humidity inside the room was 65 degrees, it was refreshing, and the sunlight was irradiating well, making it possible to improve heating costs. Conventionally, the room temperature can be reduced by opening windows to ventilate and dehumidify, but opening the windows lowers the room temperature and is not appropriate for maintaining constant temperature. The above is due to the fact that when the relaxation agent sprinkled in the liquid layer of fog that fills the room is homogenized and suspended, moisture is rapidly adsorbed due to its porous adsorption ability, and the suspended content increases the gravity. , the fog settled on the ground or on the leaves and stems of plants, and no fog was observed for a long time afterwards. In addition, above 30 are, room temperature 16℃, humidity 80℃,
No fog was observed, but as the outside air cooled down the next morning, 20 kg of a mitigating agent was sprinkled inside the greenhouse where fog was expected to form indoors.The room was left until the next morning, and when the room was inspected, no fog was detected. No formation or condensation was observed. That is, it is recognized that the humidity was alleviated as a result of the particles of the relaxing agent sprayed and floating in the room adsorbing the water vapor that was evaporating into the room. Therefore, plants cultivated in the greenhouse early in the morning will not be blocked from sunlight due to fog formation or dew condensation on the side walls or ceiling, and the duration of the physiological action of photosynthesis by the sun's light source will be reduced. As a result of the labor cost being reduced, the leaf temperature can be increased and the physiological action of opening the leaf stomata can be promoted, resulting in good results in terms of plant growth. In addition, by alleviating the humid condition in the room, appropriately lowering the humidity, and adjusting the room temperature to an appropriate temperature, the transpiration effect of plants becomes active, which is extremely effective for the growth of plants. As a result of the above, the relaxation agent of the present invention was used to adjust the humidity in a greenhouse with a room temperature suitable for cultivated plants, and as a result of experimental cultivation, the yield of seedlings, growth of vegetables, and fruiting yield were improved compared to conventional greenhouses. etc., and we were able to achieve high yield results. Furthermore, pathogenic bacteria such as sclerotia, downy mildew, powdery mildew, etc., which occur frequently in greenhouses due to high temperature and humidity, and pests such as oil beetles (aphids) can be found on the ground and on leaves and stems after being sprayed and settled. Due to the medicinal properties of the wood syrup, it was possible to suppress the activity of pests and disease-causing bacteria and reduce damage. This means that the pyroligneous acid solution can be absorbed by plants or transpired indoors during infiltration into the soil due to the adsorption and swelling properties of the precipitated relaxation agent.
It is recognized that its medicinal effects work. In addition, the precipitated mitigation agent swells in the soil and is absorbed into the soil, reducing bacteria, and its base substitution properties improve the soil, adsorb fertilizer components, make them slow-release, and improve plant growth. This is recognized as a result of improving the environment. Furthermore, by spraying this mitigating agent not only in a greenhouse but also on plants being cultivated outdoors or on the ground in powder or liquid form, pests can be exterminated or symptoms caused by pathogenic bacteria can be suppressed. Next, the results of an experiment using the relaxation agent according to the second example were not much different from the results in the first example, but compared to the 150 mesh montmorillonite in the first example, the main material was 100 mesh montmorillonite. It was found that the dehumidifying effect and the insecticidal and pest-inhibiting effects of the relaxation agent of Example 2 were slightly inferior. Therefore, it is desirable that the number of particles of the main material montmorillonite be 100 meshes or more. As mentioned above, the humidity reducing agent according to the present invention reduces the humidity in the greenhouse, eliminates fog or condensation, or prevents its occurrence, thereby making the greenhouse comfortable. , improves the working environment, contributes to the health and hygiene of workers, and eliminates fog or condensation, making sunlight irradiation more effective, thereby effectively activating photosynthesis of plants, and reducing indoor humidity. By moderately adjusting the humidity, the transpiration effect can be made suitable by selecting a humidity suitable for the transpiration effect of the plant, and the environment for growing plants can be significantly improved. Furthermore, the medicinal effects of adsorbing wood vinegar smoke can bring about good results such as killing insects and suppressing the outbreak of disease-causing bacteria, as well as soil improvement effects due to the adsorption, swelling, and base substitution properties of montmorillonite, resulting in high yields. You can expect it.
Claims (1)
着させた殺虫・殺菌剤において、天然産モンモリ
ロナイト100〜150メツシユの粉末に、粗木酢液を
蒸溜し溶解タール0.05%以下に精製した燻液20〜
40%を重量比にて混和し吸着させて得た基剤20〜
30%に上記燻液吸着前のモンモリロナイト100〜
150メツシユの粉末を70〜80%を重量比にて混合
したことを特徴とする殺虫・病害菌抑止ならびに
温室などの湿度緩和剤。 2 木酢液をモンモリロナイトの粉末に混和し吸
着させた殺虫・殺菌剤の製法において、天然産モ
ンモリロナイト100〜150メツシユの粉末を加熱脱
水したものに、粗木酢液を蒸溜し溶解タール0.05
%以下に精製した燻液20〜40%を重量比にて混和
し吸着させる第1工程、および上記第1工程を経
た混和物を5〜7日間常温下にて放置後さらに加
熱脱水する第2工程により基剤を得、次に該基剤
20〜30%に、上記燻液吸着前のモンモリロナイト
の粉末70〜80%を重量比にて混和し密封する第3
工程とを結合したことを特徴とする殺虫・病害菌
抑止ならびに温室などの湿度緩和剤の製造方法。[Scope of Claims] 1. An insecticide/bactericide in which pyroligneous vinegar is mixed and adsorbed to montmorillonite powder, which is obtained by distilling crude pyroligneous vinegar into powder of 100 to 150 mesh of naturally produced montmorillonite and refining it to 0.05% or less of dissolved tar. Smoke liquid 20~
Base material obtained by mixing and adsorbing 40% by weight 20~
Montmorillonite before adsorption of the above smoke liquid to 30% ~ 100%
An agent for killing insects, inhibiting pests, and reducing humidity in greenhouses, etc., characterized by a mixture of 70 to 80% of 150 mesh powder by weight. 2. In the method for producing insecticides and fungicides in which pyroligneous vinegar is mixed and adsorbed to montmorillonite powder, crude pyroligneous vinegar is distilled into 100 to 150 mesh powder of naturally produced montmorillonite, heated and dehydrated, and dissolved tar 0.05
The first step is to mix and adsorb 20 to 40% of smoke liquid purified to less than 20% by weight, and the second step is to leave the mixture that has passed through the first step at room temperature for 5 to 7 days, and then further heat and dehydrate it. A base is obtained by the process, and then the base is
The third step is to mix 70 to 80% of the montmorillonite powder before adsorption of the smoke liquid in a weight ratio of 20 to 30% and seal it.
A method for producing an insecticidal, pest-inhibiting, and humidity-reducing agent for greenhouses, etc., characterized by combining the above steps.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP15820577A JPS5489020A (en) | 1977-12-27 | 1977-12-27 | Pesticide * phatogenic bacteria controlling agent * abirritant agent of humidity of greenhouse and production |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP15820577A JPS5489020A (en) | 1977-12-27 | 1977-12-27 | Pesticide * phatogenic bacteria controlling agent * abirritant agent of humidity of greenhouse and production |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPS5489020A JPS5489020A (en) | 1979-07-14 |
| JPS6156203B2 true JPS6156203B2 (en) | 1986-12-01 |
Family
ID=15666571
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP15820577A Granted JPS5489020A (en) | 1977-12-27 | 1977-12-27 | Pesticide * phatogenic bacteria controlling agent * abirritant agent of humidity of greenhouse and production |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPS5489020A (en) |
Families Citing this family (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS5614558A (en) * | 1979-07-12 | 1981-02-12 | Nippon Synthetic Chem Ind Co Ltd:The | Thixotropic aqueous resin composition |
| JPS5659702A (en) * | 1979-10-22 | 1981-05-23 | Chugai Pharmaceut Co Ltd | Rearing agent of good rice plant seedling |
| JPS6263505A (en) * | 1985-09-17 | 1987-03-20 | Hootoku Bussan Kk | Microorganism multiplication promoter for soil |
| JPH0651613B2 (en) * | 1989-04-14 | 1994-07-06 | 三朗 苗村 | How to get rid of moles in open spaces such as golf courses and parks |
-
1977
- 1977-12-27 JP JP15820577A patent/JPS5489020A/en active Granted
Also Published As
| Publication number | Publication date |
|---|---|
| JPS5489020A (en) | 1979-07-14 |
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