JPS6156353B2 - - Google Patents
Info
- Publication number
- JPS6156353B2 JPS6156353B2 JP9428679A JP9428679A JPS6156353B2 JP S6156353 B2 JPS6156353 B2 JP S6156353B2 JP 9428679 A JP9428679 A JP 9428679A JP 9428679 A JP9428679 A JP 9428679A JP S6156353 B2 JPS6156353 B2 JP S6156353B2
- Authority
- JP
- Japan
- Prior art keywords
- weight
- isostearic
- finishing
- clothing
- starch
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 239000003795 chemical substances by application Substances 0.000 claims description 17
- 229920000881 Modified starch Polymers 0.000 claims description 6
- 239000007864 aqueous solution Substances 0.000 claims description 6
- 235000019426 modified starch Nutrition 0.000 claims description 6
- 229920002134 Carboxymethyl cellulose Polymers 0.000 claims description 5
- 239000004354 Hydroxyethyl cellulose Substances 0.000 claims description 5
- 229920000663 Hydroxyethyl cellulose Polymers 0.000 claims description 5
- 239000004372 Polyvinyl alcohol Substances 0.000 claims description 5
- 239000001768 carboxy methyl cellulose Substances 0.000 claims description 5
- 235000010948 carboxy methyl cellulose Nutrition 0.000 claims description 5
- 239000008112 carboxymethyl-cellulose Substances 0.000 claims description 5
- 235000019447 hydroxyethyl cellulose Nutrition 0.000 claims description 5
- 239000001923 methylcellulose Substances 0.000 claims description 5
- 235000010981 methylcellulose Nutrition 0.000 claims description 5
- 239000001254 oxidized starch Substances 0.000 claims description 5
- 235000013808 oxidized starch Nutrition 0.000 claims description 5
- 229920002451 polyvinyl alcohol Polymers 0.000 claims description 5
- 229920001479 Hydroxyethyl methyl cellulose Polymers 0.000 claims description 4
- 239000004368 Modified starch Substances 0.000 claims description 4
- 229940032977 isostearic diethanolamide Drugs 0.000 claims description 4
- XHUUHJFOYQREKL-UHFFFAOYSA-N n,n-bis(2-hydroxyethyl)-16-methylheptadecanamide Chemical compound CC(C)CCCCCCCCCCCCCCC(=O)N(CCO)CCO XHUUHJFOYQREKL-UHFFFAOYSA-N 0.000 claims description 4
- 235000019422 polyvinyl alcohol Nutrition 0.000 claims description 4
- 150000001408 amides Chemical class 0.000 claims 1
- 229920002472 Starch Polymers 0.000 description 6
- 239000008107 starch Substances 0.000 description 6
- 235000019698 starch Nutrition 0.000 description 6
- 239000000443 aerosol Substances 0.000 description 5
- 238000010409 ironing Methods 0.000 description 3
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 description 2
- MHAJPDPJQMAIIY-UHFFFAOYSA-N Hydrogen peroxide Chemical compound OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 description 2
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 2
- XSQUKJJJFZCRTK-UHFFFAOYSA-N Urea Chemical compound NC(N)=O XSQUKJJJFZCRTK-UHFFFAOYSA-N 0.000 description 2
- 239000004202 carbamide Substances 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 239000003205 fragrance Substances 0.000 description 2
- 239000007789 gas Substances 0.000 description 2
- 239000003292 glue Substances 0.000 description 2
- 239000003755 preservative agent Substances 0.000 description 2
- 238000005507 spraying Methods 0.000 description 2
- 238000006467 substitution reaction Methods 0.000 description 2
- 229920000742 Cotton Polymers 0.000 description 1
- IMROMDMJAWUWLK-UHFFFAOYSA-N Ethenol Chemical compound OC=C IMROMDMJAWUWLK-UHFFFAOYSA-N 0.000 description 1
- IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical compound C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 description 1
- 101000999373 Homo sapiens Interferon-related developmental regulator 2 Proteins 0.000 description 1
- 102100036480 Interferon-related developmental regulator 2 Human genes 0.000 description 1
- GOOHAUXETOMSMM-UHFFFAOYSA-N Propylene oxide Chemical compound CC1CO1 GOOHAUXETOMSMM-UHFFFAOYSA-N 0.000 description 1
- 239000005708 Sodium hypochlorite Substances 0.000 description 1
- 239000001569 carbon dioxide Substances 0.000 description 1
- 229910002092 carbon dioxide Inorganic materials 0.000 description 1
- 125000002057 carboxymethyl group Chemical group [H]OC(=O)C([H])([H])[*] 0.000 description 1
- KYKAJFCTULSVSH-UHFFFAOYSA-N chloro(fluoro)methane Chemical compound F[C]Cl KYKAJFCTULSVSH-UHFFFAOYSA-N 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 238000007598 dipping method Methods 0.000 description 1
- 230000032050 esterification Effects 0.000 description 1
- 238000005886 esterification reaction Methods 0.000 description 1
- 238000006266 etherification reaction Methods 0.000 description 1
- 125000002791 glucosyl group Chemical group C1([C@H](O)[C@@H](O)[C@H](O)[C@H](O1)CO)* 0.000 description 1
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 1
- -1 hydroxyethyl groups Chemical group 0.000 description 1
- 229910052742 iron Inorganic materials 0.000 description 1
- 229920000609 methyl cellulose Polymers 0.000 description 1
- 239000007800 oxidant agent Substances 0.000 description 1
- 229920001296 polysiloxane Polymers 0.000 description 1
- 230000002335 preservative effect Effects 0.000 description 1
- FDRCDNZGSXJAFP-UHFFFAOYSA-M sodium chloroacetate Chemical compound [Na+].[O-]C(=O)CCl FDRCDNZGSXJAFP-UHFFFAOYSA-M 0.000 description 1
- SUKJFIGYRHOWBL-UHFFFAOYSA-N sodium hypochlorite Chemical compound [Na+].Cl[O-] SUKJFIGYRHOWBL-UHFFFAOYSA-N 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 125000001424 substituent group Chemical group 0.000 description 1
- 239000012209 synthetic fiber Substances 0.000 description 1
- 229920002994 synthetic fiber Polymers 0.000 description 1
- 239000002562 thickening agent Substances 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
Landscapes
- Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
Description
【発明の詳細な説明】
本発明は薄物衣料用仕上げ剤に関する。詳しく
は、薄物衣料用として好適な新しいタイプの仕上
げ剤に関する。DETAILED DESCRIPTION OF THE INVENTION The present invention relates to finishing agents for light clothing. Specifically, the present invention relates to a new type of finishing agent suitable for thin clothing.
従来、ワイシヤツ、ブラウス、ズボン等の衣料
の仕上げ剤は多数知られている。これらは衣料に
張りを与え、型を整えるとともに糊付けすること
を目的としたものである。一方、ハンカチ、ネツ
カチーフ、スカーフ又は夏物衣類等の木綿、麻、
合繊製の薄物衣料、とくにシルク製衣料のおしや
れ仕上げの場合には、従来の仕上げ剤とは趣向が
異なり、むしろ平滑性、柔軟性等のしなやかさが
望まれる。 Conventionally, many finishing agents for clothing such as shirts, blouses, and pants are known. These are intended to give tension to clothing, adjust its shape, and glue. On the other hand, cotton, linen, such as handkerchiefs, netskerchiefs, scarves, or summer clothing,
When finishing synthetic fiber thin clothing, especially silk clothing, the purpose is different from conventional finishing agents, and rather smoothness, flexibility, and other suppleness are desired.
本発明者等は、薄物衣料の仕上げ剤について、
種々検討を重ねた結果、特定の化合物を特定の割
合で使用することにより、上記の目的が容易に達
成されることを知見し本発明に到達した。 Regarding finishing agents for thin clothing, the present inventors have
As a result of various studies, it was discovered that the above object can be easily achieved by using specific compounds in specific proportions, and the present invention was achieved.
すなわち、本発明の要旨は、化工澱粉、酸化澱
粉、ポリビニールアルコール、ヒドロキシエチル
セルローズ、メチルセルローズ及びカルボキシメ
チルセルローズからなる群より選ばれた１種以上
を0.5〜5.0重量％含み、かつイソステアリツクア
ルカノールアマイドを0.05〜2.5重量％を含む水
溶液からなることを特徴とする薄物衣料用仕上げ
剤に存する。 That is, the gist of the present invention is to contain 0.5 to 5.0% by weight of one or more selected from the group consisting of modified starch, oxidized starch, polyvinyl alcohol, hydroxyethyl cellulose, methyl cellulose, and carboxymethyl cellulose, and isostearic starch. A finishing agent for thin clothing characterized by comprising an aqueous solution containing 0.05 to 2.5% by weight of alkanolamide.
以下、本発明を詳細に説明する。 The present invention will be explained in detail below.
本発明の仕上げ剤は、先ず薄物衣料の仕上げ後
のこしを与えるため、化工澱粉、酸化澱粉、ポリ
ビニールアルコール、ヒドロキシエチルセルロー
ズ、メチルセルローズ或はカルボキシメチルセル
ローズの特定量を含む低粘度水溶液を使用する。
粘度としては25℃に於て30センチポイズ以下、好
ましくは20センチポイズ以下、更に好ましくは10
センチポイズ以下が選ばれる。 The finishing agent of the present invention first uses a low viscosity aqueous solution containing a specific amount of modified starch, oxidized starch, polyvinyl alcohol, hydroxyethyl cellulose, methyl cellulose, or carboxymethyl cellulose to provide texture after finishing the thin clothing. .
The viscosity at 25°C is 30 centipoise or less, preferably 20 centipoise or less, more preferably 10 centipoise or less.
A centipoise or less is selected.
化工澱粉としては、澱粉にエチレンオキサイ
ド、プロピレンオキサイド、モノクロル酢酸ナト
リウム等を反応させて得られるヒドロキシエチル
化澱粉、ヒドロキシプロピル化澱粉、カルボキシ
メチル化澱粉等が挙げられ、ヒドロキシエチル
基、カルボキシメチル基等の置換基による置換度
は、0.1〜0.3程度、とくに0.12〜0.25程度のもの
が用いられる。（置換度とは澱粉誘導体のエステ
ル化、エーテル化度を云う。すなわち、グルコー
ス残基１個当りの置換水酸基の平均値を示す。）
酸化澱粉としては、上記の化工澱粉を過酸化水
素、次亜塩素酸ナトリウム等の酸化剤で処理した
ものが挙げられる。また、ポリビニールアルコー
ル、ヒドロキシエチルセルローズ、メチルセルロ
ーズ、カルボキシメチルセルローズとしては合成
糊料として知られている市販品が用いられる。合
成糊料としては他にも多数知られているが、本発
明の場合は特定のものに限られる。 Modified starches include hydroxyethylated starch, hydroxypropylated starch, carboxymethylated starch, etc. obtained by reacting starch with ethylene oxide, propylene oxide, sodium monochloroacetate, etc., and contain hydroxyethyl groups, carboxymethyl groups, etc. The degree of substitution by the substituent used is about 0.1 to 0.3, particularly about 0.12 to 0.25. (The degree of substitution refers to the degree of esterification or etherification of the starch derivative. In other words, it indicates the average value of substituted hydroxyl groups per glucose residue.)
Examples of oxidized starch include those obtained by treating the above-mentioned modified starch with an oxidizing agent such as hydrogen peroxide and sodium hypochlorite. Furthermore, as polyvinyl alcohol, hydroxyethyl cellulose, methyl cellulose, and carboxymethyl cellulose, commercially available products known as synthetic glues are used. Although many other synthetic thickeners are known, the present invention is limited to specific ones.
これらの低粘度成分は、通常0.5〜5.0重量％、
好ましくは1.0〜3.0重量％、更に好ましくは1.0〜
2.5重量％の水溶液として用いられる。この濃度
が0.5重量％以下では、本発明の目的が達成され
ず、また、5.0重量％以上では仕上げ後の薄物衣
料が過剰に堅牢になり好ましくない。 These low viscosity components are usually 0.5 to 5.0% by weight,
Preferably 1.0 to 3.0% by weight, more preferably 1.0 to 3.0% by weight
Used as a 2.5% by weight aqueous solution. If the concentration is less than 0.5% by weight, the object of the present invention will not be achieved, and if it is more than 5.0% by weight, the finished thin clothing will become excessively strong, which is not preferable.
本発明の仕上げ剤は、更にイソステアリツクア
ルカノールアマイドを含むことにより、一層仕上
げ効果を達成することができる。すなわち、薄物
衣料として最も必要な要件である仕上げ後の平滑
性、柔軟性と云つたソフトな肌ざわり効果が得ら
れる。また、アイロンがけを行なうときの滑りも
良くなり操作が容易となる。更に本発明の仕上げ
剤は後述のように、エアロゾルとして用いる場
合、LPG等と併用されるが、この場合には優れた
防錆効果が達成される。 The finishing agent of the present invention can achieve even higher finishing effects by further containing isostearic alkanolamide. That is, the most necessary requirements for thin clothing, such as smoothness and flexibility after finishing, which are soft to the touch, can be achieved. In addition, the iron has better slippage when ironing, making it easier to operate. Furthermore, as described below, when the finishing agent of the present invention is used as an aerosol, it is used in combination with LPG, etc., and in this case, an excellent antirust effect is achieved.
イソステアリツクアルカノールアマイドとして
は、例えば、イソステアリツクエタノールアマイ
ド、イソステアリツクジエタノールアマイド等で
あり、アルカノール成分としてはC1〜C4程度が
用いられる。とくにイソステアリツクジエタノー
ルアマイドが好ましく用いられる。このイソステ
アリツクアルカノールアマイドは、通常0.05〜
2.5重量％、好ましくは0.1〜1.0重量％が用いられ
る。 Examples of the isostearic alkanolamide include isostearic ethanolamide and isostearic diethanolamide, and the alkanol component used is about C 1 to C 4 . Isostearic diethanolamide is particularly preferably used. This isostearic alkanolamide is usually 0.05~
2.5% by weight is used, preferably 0.1-1.0% by weight.
本発明の仕上げ剤は、これに薄物衣料を浸漬す
るか、薄物衣料に直接スプレーして用いられる。
また必要に応じ、アイロン仕上げを行なう。とく
にエアゾール型として使用するのが好ましい。こ
の場合にはLPG、炭酸ガス、フロンガス等を併用
して用いられることは云うまでもない。なお、本
仕上げ剤中には必要に応じ、香料、シリコン、防
腐剤、尿素等々を含むこともできる。 The finishing agent of the present invention is used by dipping thin clothing in it or by spraying it directly onto thin clothing.
Also, ironing will be done if necessary. It is particularly preferable to use it as an aerosol type. In this case, it goes without saying that LPG, carbon dioxide gas, chlorofluorocarbon gas, etc. are used in combination. Incidentally, this finishing agent may also contain fragrances, silicone, preservatives, urea, etc., if necessary.
本発明の仕上げ剤は、仕上げ後しなやかな腰と
ソフトな肌ざわりを衣料に与え美しいシルエツト
に仕上げることができるので、薄物衣料とくにお
しやれ小物用として好適に用いられる。 The finishing agent of the present invention can impart a supple waist and a soft touch to clothing after finishing, giving it a beautiful silhouette, so it is suitably used for thin clothing, especially for toiletry accessories.
次に実施例により本発明を更に詳細に説明する
が、本発明はその要旨を超えない限り以下の実施
例に限定されるものではない。なお以下の実施例
において、「部」及び「％」はすべて重量部及び
重量％を示す。 Next, the present invention will be explained in more detail with reference to examples, but the present invention is not limited to the following examples unless it exceeds the gist thereof. In addition, in the following examples, "parts" and "%" all indicate parts by weight and weight %.
実施例 １
ペニツク、アンド、フオード社製のペンフオー
ドガム280（化工澱粉）を2.00部、モナ・インダ
ストリー社製のイソステアリツクジエタノールア
マイド0.20部、PFW.SL75―776（香料）0.03
部、大和化学社製アモルデンBS（防腐剤）0.10
部及び尿素3.00部を水に溶解し100部の水溶液を
得た。この水溶液85部を内面コートしたエアゾー
ル缶（AUS280、東洋製缶）内に入れ、LPG15部
を圧入してバルブをとりつけエアゾール型仕上げ
剤とした。Example 1 2.00 parts of Pennford Gum 280 (chemical starch) manufactured by Penick, & Ford, 0.20 parts of isostearic diethanolamide manufactured by Mona Industries, and 0.03 parts of PFW.SL75-776 (fragrance).
Amolden BS (preservative) 0.10 manufactured by Daiwa Chemical Co., Ltd.
1 part and 3.00 parts of urea were dissolved in water to obtain 100 parts of an aqueous solution. 85 parts of this aqueous solution was put into an aerosol can (AUS280, Toyo Seikan) whose inside surface was coated, 15 parts of LPG was press-fitted, a valve was attached, and an aerosol type finishing agent was obtained.
これをシルク製ハンカチにスプレーし仕上げを
行なつたところ、ハンカチはソフトな肌ざわりに
仕上げることができた。 When this was sprayed onto a silk handkerchief to give it a finishing touch, the handkerchief had a soft texture.
実施例 ２
実施例１のペンフオードガム280の代りに、味
の素（株）製のネオサイザーNo.700（酸化澱
粉）、日本合成（株）製のゴーセノールGM―14L
（ポリビニールアルコール）、ユニオンカーバイド
製セロサイズQP09（ヒドロキシエチルセルロー
ズ）、信越化学（株）製メトローズSM15（メチル
セルローズ）及び第一工業製薬（株）製セロヂン
7A（カルボキシメチルセルローズ）を同量を用
い、その他は全く実施例１の場合と同様にして、
夫々エアゾール型仕上げ剤を作成した。Example 2 Instead of Pennford Gum 280 in Example 1, Neosizer No. 700 (oxidized starch) manufactured by Ajinomoto Co., Inc. and Gohsenol GM-14L manufactured by Nippon Gosei Co., Ltd.
(polyvinyl alcohol), Cellosize QP09 (hydroxyethyl cellulose) manufactured by Union Carbide, Metrose SM15 (methylcellulose) manufactured by Shin-Etsu Chemical Co., Ltd., and Celodine manufactured by Daiichi Kogyo Seiyaku Co., Ltd.
The same amount of 7A (carboxymethyl cellulose) was used, and everything else was the same as in Example 1.
Aerosol type finishing agents were created for each.
これらの仕上げ剤を薄物のブラウスにスプレー
し、アイロン仕上げを行なつたが、ブラウスはソ
フトな肌ざわりの美しいシルエツトに仕上げるこ
とができた。 By spraying these finishing agents on a thin blouse and ironing it, the blouse was finished with a beautiful silhouette and a soft texture.
Claims (1)
ル、ヒドロキシエチルセルローズ、メチルセルロ
ーズ及びカルボキシメチルセルローズからなる群
より選ばれた１種以上を0.5〜5.0重量％含み、か
つイソステアリツクアルカノールアマイドを0.05
〜2.5重量％を含む水溶液からなることを特徴と
する薄物衣料用仕上げ剤。 ２ 特許請求の範囲第１項記載のイソステアリツ
クアルカノールアマイドがイソステアリツクジエ
タノールアマイドであることを特徴とする薄物衣
料用仕上げ剤。[Scope of Claims] 1. Contains 0.5 to 5.0% by weight of one or more selected from the group consisting of modified starch, oxidized starch, polyvinyl alcohol, hydroxyethyl cellulose, methyl cellulose, and carboxymethyl cellulose, and isostearic alkanol. Amide 0.05
A finishing agent for thin clothing comprising an aqueous solution containing ~2.5% by weight. 2. A finishing agent for thin clothing, characterized in that the isostearic alkanolamide according to claim 1 is isostearic diethanolamide.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP9428679A JPS5620681A (en) | 1979-07-26 | 1979-07-26 | Finishing agent for thin garment |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP9428679A JPS5620681A (en) | 1979-07-26 | 1979-07-26 | Finishing agent for thin garment |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPS5620681A JPS5620681A (en) | 1981-02-26 |
| JPS6156353B2 true JPS6156353B2 (en) | 1986-12-02 |
Family
ID=14106007
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP9428679A Granted JPS5620681A (en) | 1979-07-26 | 1979-07-26 | Finishing agent for thin garment |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPS5620681A (en) |
-
1979
- 1979-07-26 JP JP9428679A patent/JPS5620681A/en active Granted
Also Published As
| Publication number | Publication date |
|---|---|
| JPS5620681A (en) | 1981-02-26 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| LU90636I2 (en) | Voluven 6% | |
| HK1046634A1 (en) | Hair conditioning composition comprising hydrophobically modified cellulose ether | |
| JP3349219B2 (en) | Cosmetic base material | |
| CN103334296A (en) | Antibacterial finishing agent for cotton textiles and preparation method thereof | |
| CN100529246C (en) | Process for preparing poly modified chitosan anti-bacteria wet keeping finishing agent | |
| US4023978A (en) | Aerosol spray starch formulation | |
| JPS6156353B2 (en) | ||
| US4784848A (en) | Waving lotion composition | |
| US2953498A (en) | Alcoholic polyvinylimidazole aerosol hair preparation | |
| JPH0559672A (en) | Spray-type sizing agent composition | |
| US4238057A (en) | Sizing composition of spraying type | |
| JPH0138912B2 (en) | ||
| JPS593585B2 (en) | Aerosol glue composition | |
| JPS63183519A (en) | Liquid detergent composition | |
| JPS5930161B2 (en) | Cationized dextran derivatives, their preparation and use | |
| JP3026129B2 (en) | Spray type paste composition | |
| CN102978927A (en) | Sweat-proof and wear-resistant antifouling clean-keeping sol and production method thereof | |
| JP2002105861A (en) | Finishes for spray-type clothing | |
| JPS6342974A (en) | Spray type size composition | |
| JP3100781B2 (en) | Liquid soft finish | |
| JP2010095811A (en) | Wrinkle remover composition | |
| CN108102802A (en) | A kind of wallpaper mildew-proof cleaner | |
| JPS58136660A (en) | Composition for masking paint | |
| JPS6366377A (en) | Spray type size composition | |
| JPS6054432B2 (en) | Glue composition for spray |