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JPS6259453B2 - - Google Patents
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JPS6259453B2 - - Google Patents

Info

Publication number
JPS6259453B2
JPS6259453B2 JP55108530A JP10853080A JPS6259453B2 JP S6259453 B2 JPS6259453 B2 JP S6259453B2 JP 55108530 A JP55108530 A JP 55108530A JP 10853080 A JP10853080 A JP 10853080A JP S6259453 B2 JPS6259453 B2 JP S6259453B2
Authority
JP
Japan
Prior art keywords
coil
resin
solvent
coating film
electromagnetic
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
JP55108530A
Other languages
Japanese (ja)
Other versions
JPS5732615A (en
Inventor
Akinobu Tamaoki
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Mitsubishi Electric Corp
Original Assignee
Mitsubishi Electric Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Mitsubishi Electric Corp filed Critical Mitsubishi Electric Corp
Priority to JP10853080A priority Critical patent/JPS5732615A/en
Publication of JPS5732615A publication Critical patent/JPS5732615A/en
Publication of JPS6259453B2 publication Critical patent/JPS6259453B2/ja
Granted legal-status Critical Current

Links

Classifications

    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01FMAGNETS; INDUCTANCES; TRANSFORMERS; SELECTION OF MATERIALS FOR THEIR MAGNETIC PROPERTIES
    • H01F41/00Apparatus or processes specially adapted for manufacturing or assembling magnets, inductances or transformers; Apparatus or processes specially adapted for manufacturing materials characterised by their magnetic properties
    • H01F41/02Apparatus or processes specially adapted for manufacturing or assembling magnets, inductances or transformers; Apparatus or processes specially adapted for manufacturing materials characterised by their magnetic properties for manufacturing cores, coils, or magnets
    • H01F41/04Apparatus or processes specially adapted for manufacturing or assembling magnets, inductances or transformers; Apparatus or processes specially adapted for manufacturing materials characterised by their magnetic properties for manufacturing cores, coils, or magnets for manufacturing coils
    • H01F41/12Insulating of windings
    • H01F41/127Encapsulating or impregnating

Landscapes

  • Engineering & Computer Science (AREA)
  • Power Engineering (AREA)
  • Manufacturing & Machinery (AREA)
  • Insulating Of Coils (AREA)

Description

【発明の詳細な説明】 本発明はコイルの絶縁処理方法に関する。さら
に詳しくは、絶縁処理作業が簡単であり、しかも
高性能の絶縁コイルを与えうるコイルの絶縁処理
方法に関する。
DETAILED DESCRIPTION OF THE INVENTION The present invention relates to a coil insulation treatment method. More specifically, the present invention relates to a method for insulating a coil, which is simple to insulate and can provide a high-performance insulated coil.

電磁用コイルは電気機器製品に必ず用いられる
部品であり、その電気絶縁も簡単なものからきび
しい特性が要求されるものまで広い範囲にわたつ
ている。
Electromagnetic coils are components that are always used in electrical equipment products, and their electrical insulation ranges widely from simple to demanding properties.

簡単な電磁用コイルでは、銅線やアルミ線(以
下、アルミ線は略す)の絶縁に損傷がないよう外
部からコイルを遮断するために、なんらかの保護
兼用の絶縁、一般にはテーピングが行なわれてい
るものが多い。また電磁用コイル内の線間の絶縁
としては、銅線の絶縁のみですますものから、巻
線加工により損傷欠陥を補なつたりするものや、
線間の電磁振動を防止するために、絶縁ワニスを
浸漬せしめてコイル線同士を固着させているもの
などがある。
In simple electromagnetic coils, some type of protective insulation, generally taping, is used to isolate the coil from the outside so that the insulation of the copper wire or aluminum wire (hereinafter, aluminum wire is omitted) is not damaged. There are many things. In addition, insulation between wires in electromagnetic coils ranges from those that require only copper wire insulation to those that compensate for damage and defects through winding processing.
In order to prevent electromagnetic vibration between the wires, some coil wires are dipped in insulating varnish to fix the coil wires together.

またきびしい特性が要求される電磁用コイルで
は、電磁用コイル全体を外部より絶縁するか、ま
たは電磁用コイルのコイル線同士を絶縁する方法
が採用される。一般に前者の方法においては絶縁
材としてフイルム材、テープ材、パテ材、デイツ
ピング材、注型材、プレプリグ剤、成形材〔バル
クモールデイングコンパウンド(BMC)、シート
モールデイングコンパウンド(SMC)を含む〕
などが用いられ、後者の方法においては含浸材が
用いられるのが普通である。
Furthermore, for electromagnetic coils that require strict characteristics, a method is adopted in which the entire electromagnetic coil is insulated from the outside, or the coil wires of the electromagnetic coil are insulated from each other. Generally, in the former method, insulating materials include film materials, tape materials, putty materials, dipping materials, casting materials, prepreg materials, and molding materials [including bulk molding compound (BMC) and sheet molding compound (SMC)].
In the latter method, an impregnating material is usually used.

この含浸材としては一般に透明なレジンが多
く、無溶剤型エポキシ樹脂、不飽和ポリエステル
樹脂、ポリウレタン樹脂、シリコーン樹脂、ポリ
イミド樹脂などの含浸樹脂が用いられる。含浸樹
脂に必要な性質としては、低粘度で含浸しやす
く、ポツトライフが長いことであり、また含浸樹
脂の種類としては浸漬のみに用いるものからの金
型を用い真空含浸に用いるものまである。
Generally, transparent resins are used as the impregnating material, and impregnating resins such as solvent-free epoxy resins, unsaturated polyester resins, polyurethane resins, silicone resins, and polyimide resins are used. The properties necessary for the impregnating resin are low viscosity, easy impregnation, and long pot life.The types of impregnating resins range from those used only for immersion to those used for vacuum impregnation using a mold.

また絶縁される銅線にはエナメル線、ガラス巻
線、紙巻線などが用いられる。
Moreover, enamelled wire, glass-wound wire, paper-wound wire, etc. are used as the copper wire to be insulated.

しかしこれらの絶縁組織を形成させるには、金
型を用いて真空含浸させ、硬化後注型樹脂を注型
するといつた作業工程の多いものから、絶縁ワニ
スの浸漬処理だけや、外部との絶縁としてテーピ
ングのみのものまで種々の方法が採用されている
が、いずれの絶縁処理方法においても充分に絶縁
された電磁用コイルはほとんどえられず、作業性
も必ずしも充分ではない。とくに金型を用いない
含浸処理方法では、含浸樹脂が硬化時に粘度低下
して電磁用コイル内から流出するという欠点があ
る。含浸樹脂の電磁用コイル内からの流出を防止
するために、含浸樹脂として紫外線硬化樹脂を用
いたり、樹脂と硬化剤または触媒を分離させたも
のを一体化する触媒分離方式や回転硬化方式など
の絶縁処理方法が検討されているが、いまだ充分
なものとはいえず、えられる電磁用コイル内には
部分的に空げきや含浸不良が生じる。
However, in order to form these insulating structures, there are many work steps such as vacuum impregnation using a mold and casting resin after hardening. A variety of methods have been adopted, including one that involves only taping, but with any of these insulation treatment methods, it is almost impossible to obtain a sufficiently insulated electromagnetic coil, and the workability is not always sufficient. In particular, an impregnation treatment method that does not use a mold has the disadvantage that the impregnated resin decreases in viscosity during curing and flows out from the electromagnetic coil. In order to prevent the impregnated resin from leaking out of the electromagnetic coil, we use ultraviolet curing resin as the impregnating resin, a catalyst separation method that integrates the resin and the curing agent or catalyst separately, and a rotary curing method. Although insulation treatment methods have been studied, they are not yet satisfactory, and the resulting electromagnetic coils often have gaps or poor impregnation.

本発明者は叙上の欠点を排除し、絶縁作業が簡
単であり、しかも高性能の絶縁コイルを与えうる
コイルの絶縁処理方法を提供するべく鋭意研究を
重ねた結果、本発明を完成するにいたつた。
The present inventor has conducted extensive research in order to eliminate the above-mentioned drawbacks, provide a method for insulating a coil that is simple to insulate, and can provide a high-performance insulated coil, and as a result has completed the present invention. It was it.

すなわち、本発明は電磁用コイルに通電加熱し
ながら該コイル表面に流動浸漬塗装法により厚さ
0.1〜10mmを有する粉体塗料塗膜を形成させたの
ち、室温でチクソトロピツク性を有する無溶剤型
含浸樹脂を真空含浸させ、ついで硬化せしめるこ
とを特徴とするコイルの絶縁処理方法に関するも
のであつて、電磁用コイルの絶縁に前記特定の絶
縁処理方法を適用することにより、従来法におけ
るがごとき含浸樹脂の硬化時に含浸樹脂が電磁用
コイル内から流出したり、また硬化処理操作が煩
雑であるなどといつた叙上の欠点が排除され、温
度上昇により含浸樹脂の粘度が低下しても、含浸
樹脂が電磁用コイル内から流出することなくコイ
ル線間が充分絶縁され、硬化処理操作が簡単であ
り、しかも高性能の絶縁コイルがえられるという
きわめて顕著な効果が奏される。
That is, in the present invention, the electromagnetic coil is electrically heated and the surface of the coil is coated to a thickness using a fluidized dip coating method.
The method relates to a method for insulating a coil, which comprises forming a powder coating film having a thickness of 0.1 to 10 mm, then vacuum impregnating it with a solvent-free impregnating resin having thixotropic properties at room temperature, and then curing it. By applying the above-mentioned specific insulation treatment method to the insulation of the electromagnetic coil, the impregnated resin may flow out from inside the electromagnetic coil when the impregnated resin is cured, as in the conventional method, and the curing operation is complicated. The above-mentioned drawbacks have been eliminated, and even if the viscosity of the impregnated resin decreases due to temperature rise, the impregnated resin will not flow out of the electromagnetic coil and the coil wires will be sufficiently insulated, making the curing process easy. However, the very remarkable effect that a high-performance insulated coil can be obtained is achieved.

本発明の方法においては、電磁用コイルを加熱
して粉体塗装を施す第1工程とチクソトロピツク
性を有する無溶剤型含浸樹脂を真空含浸させる第
2工程と含浸樹脂を硬化させる第3工程により目
的が達成されうる。
In the method of the present invention, a first step of heating an electromagnetic coil to apply powder coating, a second step of vacuum impregnation with a solvent-free impregnating resin having thixotropic properties, and a third step of curing the impregnated resin achieve the desired purpose. can be achieved.

本発明の方法において、粉体塗装される電磁用
コイルの加熱には絶縁するコイルのみを加熱しう
る通電加熱が採用される。
In the method of the present invention, electrical heating is used to heat the electromagnetic coil to be powder coated, which can heat only the coil to be insulated.

一般に電磁用コイルは、絶縁線をたばねたよう
なコイル単体または巻わく(すなわちボビン)に
巻回されたり、絶縁された鉄心に巻回されている
のが普通である。
Generally, electromagnetic coils are wound on a single coil such as a coil made of a coil of insulated wire, a winding frame (ie, a bobbin), or wound on an insulated iron core.

この加熱された電磁用コイルは流動浸漬法によ
り塗装され、コイル表面に厚さ0.1〜10mmの塗膜
が形成される。形成される塗膜は半硬化状または
硬化状のいずれでもよい。なお、電磁用コイルに
通電加熱して流動浸漬させながら粉体塗装するこ
とにより塗膜が形成されやすく、厚膜がえられし
かも塗装時間がいちじるしく短縮される。形成さ
れる塗膜はコイルと外部との絶縁材としての役割
をはたす。
This heated electromagnetic coil is coated by a fluidized dipping method to form a coating film with a thickness of 0.1 to 10 mm on the coil surface. The coating film formed may be either semi-cured or cured. By applying powder coating while heating the electromagnetic coil and fluidizing it, a coating film can be easily formed, a thick film can be obtained, and the coating time can be significantly shortened. The coating film formed serves as an insulator between the coil and the outside.

本発明の方法に用いる粉体塗料としては、たと
えばエポキシ粉体塗料、ポリエステル粉体塗料、
アクリル粉体塗料、ウレタン粉体塗料があげられ
る。それらの粉体塗料のうち、エポキシ粉体塗料
を用いるのが、塗膜の速硬化が可能であり、しか
も電気的特性および機械的特性にすぐれた塗膜が
えられるので好ましい。また電磁用コイルのコイ
ル表面に形成される塗膜の厚さとしては0.1〜10
mmが採用され、それにより電磁用コイルの外部か
らの保護、絶縁がなされ、絶縁された銅線をいた
めない絶縁コイルがえられる。塗膜の厚さが10mm
より大きいときは塗膜が脱落(タレ)することと
なり、また0.1mmより小さいときは外部との絶縁
が充分なものがえがたくなり、いずれも好ましく
ない。
Examples of powder coatings used in the method of the present invention include epoxy powder coatings, polyester powder coatings,
Examples include acrylic powder paint and urethane powder paint. Among these powder coatings, it is preferable to use epoxy powder coatings because they enable rapid curing of the coating film and provide a coating film with excellent electrical and mechanical properties. Also, the thickness of the coating film formed on the coil surface of the electromagnetic coil is 0.1 to 10
mm is adopted, which protects and insulates the electromagnetic coil from the outside, and provides an insulated coil that does not damage the insulated copper wire. Paint film thickness is 10mm
If it is larger than this, the paint film will fall off (sagging), and if it is smaller than 0.1 mm, it will be difficult to maintain sufficient insulation from the outside, both of which are undesirable.

本発明の方法に用いる室温でチクソトロピツク
性を有する無溶剤型含浸樹脂としては、せん断
力、すなわち力を加えると粘度が低下して流動す
るが、静止時には流動性を示さないものであり、
たとえば不飽和ポリエステル樹脂、エポキシ樹
脂、シリコーン樹脂、ポリウレタン樹脂などの無
溶剤型含浸樹脂にチクソトロピツク性をもたせる
ために、微粒状シリカ〔たとえばエロジール(日
本アエロジル(株)製〕やゲルオールD〔新日本理化
(株)製〕、タルクなどが添加されたものである。チ
クソトロピツク性は、室温および加熱硬化時に充
分その性質を保持する。その添加量は、樹脂の種
類や粘度により異なるが充分なチクソトロピツク
性を有しなければ、真空含浸された樹脂が外部に
流出するので望ましくない。一般に前記添加物の
添加量は、無溶剤型含浸樹脂100重量部に対し
て、0.5〜30重量部の範囲が用いられる。
The solvent-free impregnating resin having thixotropic properties at room temperature used in the method of the present invention is one that decreases in viscosity and flows when shear force, that is, force is applied, but does not show fluidity when it is stationary.
For example, in order to impart thixotropic properties to solvent-free impregnating resins such as unsaturated polyester resins, epoxy resins, silicone resins, and polyurethane resins, fine particulate silica [such as Erosil (manufactured by Nippon Aerosil Co., Ltd.)] and Gelol D [Shin Nippon Chemical Co., Ltd.] are used.
Co., Ltd.], to which talc and other substances are added. The thixotropic property sufficiently retains its properties at room temperature and during heat curing. The amount added varies depending on the type and viscosity of the resin, but if the resin does not have sufficient thixotropic properties, the vacuum-impregnated resin will flow out, which is not desirable. Generally, the amount of the additive added is in the range of 0.5 to 30 parts by weight per 100 parts by weight of the solvent-free impregnating resin.

本発明においては、塗膜が形成された電磁用コ
イルを真空含浸槽に入れ、該含浸槽を真空にした
のちチクソトロピツク性を有する無溶剤型含浸樹
脂が電磁用コイル内に注入され、該コイル内に完
全に充填される。そのばあい、鉄心に巻かれたコ
イルにあつては鉄心とコイルの界面より無溶剤型
含浸樹脂がコイル内に浸入する。またコイル表面
に形成された塗膜により無溶剤型含浸樹脂のコイ
ル内への浸入が妨げられるばあいには、無溶剤型
含浸樹脂をコイル内に浸入させるために前記塗膜
に小さい孔が設けられる。
In the present invention, an electromagnetic coil on which a coating film has been formed is placed in a vacuum impregnation tank, and after the impregnation tank is evacuated, a solvent-free impregnating resin having thixotropic properties is injected into the electromagnetic coil. is completely filled. In that case, in the case of a coil wound around an iron core, the solvent-free impregnating resin penetrates into the coil from the interface between the iron core and the coil. In addition, if the coating film formed on the coil surface prevents the solvent-free impregnating resin from penetrating into the coil, small holes are provided in the coating film to allow the solvent-free impregnating resin to penetrate into the coil. It will be done.

前記無溶剤型含浸樹脂は、真空含浸時には圧力
差による加圧圧力により流動して鉄心とコイルと
の界面や塗膜の小孔を通してコイル内に入り、一
方静止時には無溶剤型含浸樹脂が流動しないので
コイル内から流出しない。しかしながら無溶剤型
含浸樹脂がチクソトロピツク性を有していても、
自重や温度上昇により流動性を示すことがしばし
ばある。本発明の方法においては、電磁用コイル
のコイル表面に塗膜が形成されているために、電
磁用コイル内に含浸された含浸樹脂が電磁用コイ
ル内から流出してくることはない。
During vacuum impregnation, the solvent-free impregnating resin flows due to pressure difference and enters the coil through the interface between the core and the coil or through the small holes in the coating film, while when it is stationary, the solvent-free impregnating resin does not flow. Therefore, it does not flow out from inside the coil. However, even if the solvent-free impregnating resin has thixotropic properties,
It often shows fluidity due to its own weight or temperature rise. In the method of the present invention, since the coating film is formed on the surface of the electromagnetic coil, the impregnated resin impregnated into the electromagnetic coil does not flow out from inside the electromagnetic coil.

つぎに含浸処理された電磁用コイルは、コイル
や鉄心に付着せる余分な無溶剤型含浸樹脂が取り
除かれ、通常の方法によりコイル内に含浸された
無溶剤型含浸樹脂が硬化される。
Next, from the impregnated electromagnetic coil, excess solvent-free impregnating resin adhering to the coil or iron core is removed, and the solvent-free impregnating resin impregnated into the coil is cured by a normal method.

本発明の方法においては、電磁用コイルに通電
加熱しながら該コイル表面に流動浸漬法により粉
体塗料塗膜が形成されるため、塗膜の形成が短時
間で容易になされ、この塗膜がコイル内に含浸さ
れた無溶剤型含浸樹脂の流出を防止するととも
に、外部との絶縁に有効に役立ち、しかもコイル
内の無溶剤型含浸樹脂が該コイル内部に完全に充
填された状態で硬化されてコイル線間の絶縁およ
び振動防止の役割をはたすので、性能上きわめて
すぐれた絶縁コイルがえられる。
In the method of the present invention, a powder coating film is formed on the surface of the electromagnetic coil by a fluidized dipping method while heating the electromagnetic coil. Therefore, the coating film can be easily formed in a short time, and this coating film can be easily formed. In addition to preventing the solvent-free impregnated resin impregnated into the coil from flowing out, it is also effective in insulating the coil from the outside.Moreover, the solvent-free impregnated resin in the coil is cured while being completely filled inside the coil. This serves to insulate between the coil wires and prevent vibrations, so an insulated coil with extremely excellent performance can be obtained.

本発明の方法は、電磁用コイルの絶縁処理のほ
かに、マグネツトコイル、界磁コイル、水中モー
タなどの絶縁処理に適する。
The method of the present invention is suitable for insulating magnetic coils, field coils, underwater motors, etc. in addition to insulating electromagnetic coils.

つぎに実施例をあげて本発明のコイルの絶縁処
理方法を説明する。
Next, the coil insulation treatment method of the present invention will be described with reference to examples.

実施例 1 150mmフレームでマグネツトワイヤ(線経:1
mm)をパラ巻きされた防食モータのステータ絶縁
について述べる(スロツトはポリエチレンテレフ
タレートフイルムで絶縁されている)。
Example 1 Magnet wire (wire diameter: 1
We will discuss the stator insulation of a corrosion-protected motor with parallel windings (slots are insulated with polyethylene terephthalate film).

まず3相200Vを20秒間通電加熱し、コイル温
度約200℃でエポキシ粉体塗料〔菱電化成(株)製、
VEP 46−2〕を流動浸漬法により塗装し、コイ
ル表面に厚さ1〜3mmを有する塗膜を形成せしめ
た。そのコイルを真空含浸槽に入れ、無溶剤型エ
ポキシ樹脂〔エピコート828(シエル化学社
製)/ヘキサヒドロ酸無水物/ベンジルジメチル
アミン(100/80/0.5重量部)〕100重量部にエロ
ジール#380(前出)7重量部を添加、混合した
室温でチクソトロピツク性を有する無溶剤型含浸
樹脂を真空含浸せしめたのち、フレームやコイル
の表面に付着している余分な前記含浸樹脂を取り
除き、150℃の熱風循環式オーブン中で約3時間
硬化処理した。
First, heat the 3-phase 200V for 20 seconds to heat the coil at a coil temperature of approximately 200℃.
VEP 46-2] was applied by a fluidized dipping method to form a coating film having a thickness of 1 to 3 mm on the surface of the coil. The coil was placed in a vacuum impregnation tank, and Erosil #380 ( After adding and mixing 7 parts by weight of the solvent-free impregnating resin having thixotropic properties at room temperature, the excess impregnating resin adhering to the surface of the frame and coil was removed, and the impregnating resin was heated at 150°C. Curing was performed in a hot air circulation oven for about 3 hours.

えられたステータは、内部が完全に硬化樹脂に
より充填されたものであつた。またえられたステ
ータは、水中での絶縁抵抗が1012Ω以上を示し、
水中放置後のメグ低下もほとんどなかつた。
The interior of the obtained stator was completely filled with cured resin. The obtained stator also has an insulation resistance of 10 12 Ω or more in water.
There was almost no decrease in MEG after being left in water.

以上述べたごとく、本発明の方法にあつては、
絶縁作業が簡単であり、しかも高性能の絶縁コイ
ルがえられ、工業上きわめて有利である。
As mentioned above, in the method of the present invention,
The insulation work is simple and a high-performance insulation coil can be obtained, which is extremely advantageous industrially.

Claims (1)

【特許請求の範囲】 1 電磁用コイルに通電加熱しながら該コイル表
面に流動浸漬塗装法により厚さ0.1〜10mmを有す
る粉体塗料塗膜を形成させたのち、室温でチクソ
トロピツク性を有する無溶剤型含浸樹脂を真空含
浸させ、ついで硬化せしめることを特徴とするコ
イルの絶縁処理方法。 2 無溶剤型含浸樹脂が不飽和ポリエステル樹
脂、エポキシ樹脂、シリコーン樹脂またはポリウ
レタン樹脂である特許請求の範囲第1項記載の方
法。
[Scope of Claims] 1. A powder coating film having a thickness of 0.1 to 10 mm is formed on the surface of the electromagnetic coil by a fluidized dip coating method while being energized and heated, and then a solvent-free coating having thixotropic properties at room temperature is applied. A method for insulating a coil, characterized by vacuum impregnation with mold impregnating resin and then curing. 2. The method according to claim 1, wherein the solvent-free impregnating resin is an unsaturated polyester resin, an epoxy resin, a silicone resin, or a polyurethane resin.
JP10853080A 1980-08-04 1980-08-04 Insulating process for coil Granted JPS5732615A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP10853080A JPS5732615A (en) 1980-08-04 1980-08-04 Insulating process for coil

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP10853080A JPS5732615A (en) 1980-08-04 1980-08-04 Insulating process for coil

Publications (2)

Publication Number Publication Date
JPS5732615A JPS5732615A (en) 1982-02-22
JPS6259453B2 true JPS6259453B2 (en) 1987-12-11

Family

ID=14487131

Family Applications (1)

Application Number Title Priority Date Filing Date
JP10853080A Granted JPS5732615A (en) 1980-08-04 1980-08-04 Insulating process for coil

Country Status (1)

Country Link
JP (1) JPS5732615A (en)

Family Cites Families (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS4927212A (en) * 1972-06-30 1974-03-11
JPS5135054A (en) * 1974-09-19 1976-03-25 Matsushita Electric Industrial Co Ltd Jushihomaikoirunoseizohoho

Also Published As

Publication number Publication date
JPS5732615A (en) 1982-02-22

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