JPS644308B2 - - Google Patents
Info
- Publication number
- JPS644308B2 JPS644308B2 JP56011872A JP1187281A JPS644308B2 JP S644308 B2 JPS644308 B2 JP S644308B2 JP 56011872 A JP56011872 A JP 56011872A JP 1187281 A JP1187281 A JP 1187281A JP S644308 B2 JPS644308 B2 JP S644308B2
- Authority
- JP
- Japan
- Prior art keywords
- gasket
- negative electrode
- button
- manufacturing
- liquid sealant
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 239000007788 liquid Substances 0.000 claims description 14
- 239000000565 sealant Substances 0.000 claims description 13
- 238000004519 manufacturing process Methods 0.000 claims description 9
- 238000000034 method Methods 0.000 claims description 6
- 238000001035 drying Methods 0.000 claims description 3
- 229920006122 polyamide resin Polymers 0.000 claims description 3
- 239000003960 organic solvent Substances 0.000 claims 2
- 239000003795 chemical substances by application Substances 0.000 claims 1
- 238000007789 sealing Methods 0.000 claims 1
- NDVLTYZPCACLMA-UHFFFAOYSA-N silver oxide Chemical compound [O-2].[Ag+].[Ag+] NDVLTYZPCACLMA-UHFFFAOYSA-N 0.000 description 10
- 230000010354 integration Effects 0.000 description 5
- 229910001923 silver oxide Inorganic materials 0.000 description 5
- 238000007796 conventional method Methods 0.000 description 4
- 239000003792 electrolyte Substances 0.000 description 4
- 239000000203 mixture Substances 0.000 description 4
- 229920002302 Nylon 6,6 Polymers 0.000 description 3
- KWYUFKZDYYNOTN-UHFFFAOYSA-M Potassium hydroxide Chemical compound [OH-].[K+] KWYUFKZDYYNOTN-UHFFFAOYSA-M 0.000 description 3
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 3
- 239000000463 material Substances 0.000 description 3
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 description 2
- 230000001070 adhesive effect Effects 0.000 description 2
- 239000007864 aqueous solution Substances 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- NUJOXMJBOLGQSY-UHFFFAOYSA-N manganese dioxide Chemical compound O=[Mn]=O NUJOXMJBOLGQSY-UHFFFAOYSA-N 0.000 description 2
- 229910052725 zinc Inorganic materials 0.000 description 2
- 239000011701 zinc Substances 0.000 description 2
- 229910000497 Amalgam Inorganic materials 0.000 description 1
- 239000004743 Polypropylene Substances 0.000 description 1
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 1
- 239000011149 active material Substances 0.000 description 1
- 239000000853 adhesive Substances 0.000 description 1
- 229910052793 cadmium Inorganic materials 0.000 description 1
- BDOSMKKIYDKNTQ-UHFFFAOYSA-N cadmium atom Chemical compound [Cd] BDOSMKKIYDKNTQ-UHFFFAOYSA-N 0.000 description 1
- 239000003518 caustics Substances 0.000 description 1
- 238000007791 dehumidification Methods 0.000 description 1
- 238000010586 diagram Methods 0.000 description 1
- 239000008151 electrolyte solution Substances 0.000 description 1
- 239000003822 epoxy resin Substances 0.000 description 1
- 239000003292 glue Substances 0.000 description 1
- 238000005470 impregnation Methods 0.000 description 1
- 229910052738 indium Inorganic materials 0.000 description 1
- APFVFJFRJDLVQX-UHFFFAOYSA-N indium atom Chemical compound [In] APFVFJFRJDLVQX-UHFFFAOYSA-N 0.000 description 1
- 229910000474 mercury oxide Inorganic materials 0.000 description 1
- UKWHYYKOEPRTIC-UHFFFAOYSA-N mercury(ii) oxide Chemical compound [Hg]=O UKWHYYKOEPRTIC-UHFFFAOYSA-N 0.000 description 1
- 239000007773 negative electrode material Substances 0.000 description 1
- 229910000480 nickel oxide Inorganic materials 0.000 description 1
- GNRSAWUEBMWBQH-UHFFFAOYSA-N oxonickel Chemical compound [Ni]=O GNRSAWUEBMWBQH-UHFFFAOYSA-N 0.000 description 1
- 229920000647 polyepoxide Polymers 0.000 description 1
- 229920013716 polyethylene resin Polymers 0.000 description 1
- -1 polypropylene Polymers 0.000 description 1
- 229920001155 polypropylene Polymers 0.000 description 1
- 239000007774 positive electrode material Substances 0.000 description 1
- 229910052700 potassium Inorganic materials 0.000 description 1
- 239000011591 potassium Substances 0.000 description 1
- 235000011118 potassium hydroxide Nutrition 0.000 description 1
- 229920005989 resin Polymers 0.000 description 1
- 239000011347 resin Substances 0.000 description 1
- 235000011121 sodium hydroxide Nutrition 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
Classifications
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M50/00—Constructional details or processes of manufacture of the non-active parts of electrochemical cells other than fuel cells, e.g. hybrid cells
- H01M50/10—Primary casings; Jackets or wrappings
- H01M50/147—Lids or covers
- H01M50/166—Lids or covers characterised by the methods of assembling casings with lids
- H01M50/171—Lids or covers characterised by the methods of assembling casings with lids using adhesives or sealing agents
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/10—Energy storage using batteries
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Electrochemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Sealing Battery Cases Or Jackets (AREA)
Description
本発明は、負極缶とガスケツトとを予め一体化
した後組立てるボタン型電池の製造方法に関する
ものである。
近年、ボタン型電池は、腕時計をはじめとする
各種小型電子機器の発達に伴い、ますます注目さ
れその需要が高まつてきている。これらの電池
は、正極に酸化銀、２価酸化銀、酸化水銀、二酸
化マンガン、酸化ニツケル、負極にアマルガム亜
鉛、インジウム、カドミウム、等のうち、それぞ
れ１種または複数種の活物質を有し、電解液とし
ては、苛性カリ、または苛性ソーダ水溶液等を使
用したものである。これらの電池は、アルカリ電
解液を用いているために耐漏液性の点で完全では
ない。特に、使用電子機器の小型薄型化に伴う電
池の小型薄型化、またはこれらの機器の低消費電
流化に伴う電池の長寿命化の傾向は、ますます電
池の耐漏液性の向上を要求することになる。
従来のボタン型電池の製造法を、第１図に示す
断面図をもとに説明する。
液体シール剤８を介して負極缶３とガスケツト
７とを予め一体化し、負極合剤４を充てんして負
極ユニツトとする。正極缶１に正極合剤２を充て
んして加圧成形し、正極ユニツトとする。正極ユ
ニツトにセパレータ５、電解液を含浸させた含浸
材６を介して前述の負極ユニツトを押し込み、正
極缶の開口部を内方にかしめて封口する。
このような従来方法で作つたボタン型電池は、
第２図のＡに示すように、ガスケツトと負極缶の
喰い合いが大きいため、ガスケツトと負極缶の一
体化に際し、ガスケツトの底部７ａと負極缶の底
部３ａとの密着が悪く、電池とした場合の耐漏液
性が充分ではなかつた。
本発明は、ガスケツトと負極缶の一体化時の喰
い合いを小さくして、かかる欠点を改善する目的
で為されたものである。
以下、実施例に基づき本発明の製造方法を詳細
に説明する。
実施例 １
シンナーで希釈した液体シール剤を塗布したナ
イロン66よりなるガスケツトを、80％以上の相対
湿度中に放置して膨張させると共に、シンナーを
蒸発させた後、負極缶を押し込み一体化する。そ
の後、湿度30％の雰囲気中に放置してガスケツト
を収縮させたガスケツト付負極缶を、従来方法と
同一の方法で第１図に示した構造のボタン型電池
に組立てた。尚、電池は、正極活物質として酸化
銀、負極活物質として亜鉛、電解液として苛性カ
リ水溶液を用いた直径11.6mm、厚み2.0mmのボタ
ン型酸化銀電池である。
実施例 ２
シンナーで希釈した液体シール剤を塗布したナ
イロン66より成るガスケツトを、80％以上の相対
湿度中に放置して膨張させると共に、シンナーを
蒸発させた後、負極缶を押し込み一体化する。高
湿状態のまま温度を60℃に上昇させて液体シール
剤を硬化させ、その後、湿度30％中でガスケツト
を収縮させる。このようにして得られたガスケツ
ト付負極缶を、実施例１と同様にして、実施例１
と同サイズのボタン型酸化銀電池を組み立てた。
このようにして得られた電池と、従来方法によ
つて製造した電池との耐漏液性を比較したのが、
第１表である。第１表は、40℃、相対湿度95％雰
囲気中に500時間、あるいは1000時間放置した場
合の漏液不良発生率を示すもので、サンプル数は
それぞれ100個×３ロツト、合計300個である。
The present invention relates to a method for manufacturing a button type battery in which a negative electrode can and a gasket are integrated in advance and then assembled. In recent years, with the development of various small electronic devices such as wristwatches, button-type batteries have been attracting more and more attention, and the demand for them has been increasing. These batteries each have one or more types of active materials among silver oxide, divalent silver oxide, mercury oxide, manganese dioxide, nickel oxide, etc. in the positive electrode, and amalgam zinc, indium, cadmium, etc. in the negative electrode, As the electrolyte, caustic potash, caustic soda aqueous solution, or the like is used. Since these batteries use an alkaline electrolyte, they are not perfect in terms of leakage resistance. In particular, the tendency for batteries to become smaller and thinner due to the smaller and thinner electronic devices used, and for longer battery life due to the lower current consumption of these devices, increasingly demands improved leakage resistance of batteries. become. A conventional method for manufacturing a button-type battery will be explained based on the cross-sectional view shown in FIG. The negative electrode can 3 and the gasket 7 are integrated in advance through a liquid sealant 8, and the negative electrode mixture 4 is filled to form a negative electrode unit. A positive electrode can 1 is filled with a positive electrode mixture 2 and press-molded to form a positive electrode unit. The aforementioned negative electrode unit is pushed into the positive electrode unit through the separator 5 and the impregnated material 6 impregnated with an electrolytic solution, and the opening of the positive electrode can is caulked inward to seal it. Button batteries made using this conventional method are
As shown in A of Fig. 2, the gasket and the negative electrode can have a large interlocking relationship, so when the gasket and the negative electrode can are integrated, the bottom 7a of the gasket and the bottom 3a of the negative electrode can have poor adhesion, and when used as a battery. The leakage resistance was not sufficient. The present invention was made for the purpose of improving this drawback by reducing the meshing between the gasket and the negative electrode can when they are integrated. Hereinafter, the manufacturing method of the present invention will be explained in detail based on Examples. Example 1 A gasket made of nylon 66 coated with a liquid sealant diluted with thinner is left to expand in a relative humidity of 80% or higher, and after the thinner has evaporated, a negative electrode can is pushed in and integrated. Thereafter, the gasketed negative electrode can, which was left in an atmosphere with a humidity of 30% to cause the gasket to shrink, was assembled into a button-type battery having the structure shown in FIG. 1 in the same manner as the conventional method. The battery is a button-type silver oxide battery with a diameter of 11.6 mm and a thickness of 2.0 mm, using silver oxide as a positive electrode active material, zinc as a negative electrode active material, and a caustic potassium aqueous solution as an electrolyte. Example 2 A gasket made of nylon 66 coated with a liquid sealant diluted with thinner is left to expand in a relative humidity of 80% or higher, and after the thinner has evaporated, a negative electrode can is pushed in and integrated. The liquid sealant is cured by raising the temperature to 60°C in a highly humid state, and then the gasket is contracted in a humidity of 30%. The gasketed negative electrode can thus obtained was prepared in the same manner as in Example 1.
A button-shaped silver oxide battery of the same size was assembled. A comparison of the leakage resistance between the battery obtained in this way and a battery manufactured by a conventional method revealed that:
This is Table 1. Table 1 shows the leakage failure rate when left in an atmosphere of 40℃ and 95% relative humidity for 500 hours or 1000 hours.The number of samples is 100 pieces each x 3 lots, a total of 300 pieces. .
【表】
第１表で明らかなように、本発明の製造方法に
よる電池は、高温多湿中での耐漏液性が非常に良
い。
次に、本発明の作用効果について説明する。
ガスケツトと負極缶を一体化する場合、第２図
のＡに示したように、ガスケツトと負極缶の喰い
合いが大きいと、押し込み時の抵抗が大きく、完
全に押し込まれたとしても、押し込み時に生じた
ガスケツトの残留応力のために、短時間のうち
に、負極缶はガスケツトから押し出されてしま
う。従つて、従来の製造方法では、負極缶底部３
ａとガスケツト底部７ａとの間にスキ間が生じ、
電池組立時に、そのスキ間を通つて内部の電解液
が漏れ出し易く、耐漏液性が悪いものである。そ
れに対し本発明の方法では、予めガスケツトを加
湿処理によつて膨張させるので、組込時のガスケ
ツトと負極缶の喰い合いが小さく、押し込み時の
残留応力も非常に小さい。従つてガスケツトと負
極缶は完全に一体化され、第２図のＣのように、
負極缶底部とガスケツト底部にスキマが生じな
い。更に一体化後、乾燥処理により除湿してガス
ケツトを収縮させると、第２図のＤに示すよう
に、負極缶の開口端部３ｂがガスケツトの内面７
ｂに喰い込み、その後の加工中にも容易にはガス
ケツト底部と負極缶底部にスキマが生ずることが
なく、耐漏液性が良いのである。
電池用ガスケツト材料としては、ナイロン66等
のポリアミド樹脂、ポリエチレン樹脂、ポリプロ
ピレン樹脂等があるが、加湿時の膨張が特に大き
いポリアミド樹脂製ガスケツトを用いれば、本発
明の効果が更に顕著になる。
また、耐漏液性改善のために、ガスケツトと負
極缶の間に液体シール剤を塗布することが近年提
案され、一部実施されているが、従来方法では、
液体シール剤を塗布すると、ガスケツトと負極缶
の摩擦抵抗が小となり、液体シール剤なしの場合
よりも負極缶はガスケツトから押し出され易くな
る。本発明は、このような場合にも、実施例１に
示したように有効である。
エポキシ樹脂等の接着効果を有する物質を含む
液体シール剤を用いる場合は、加湿状態でシンナ
ーを除いて、一体化後そのまま加湿状態で温度を
上げて、液体シール剤を硬化させ、負極缶とガス
ケツトを接着する。前述したように、高湿状態で
は負極缶とガスケツトは喰い合いの小さい状態な
のであるから、ガスケツトの負極缶を上方に押し
上げようとする力は働き得ない。その状態で液体
シール剤が硬化し負極缶とガスケツトが接着され
るために、高湿状態より取り出し除湿による乾燥
処理を施して、ガスケツトが収縮した後も、液体
シール剤の接着力により負極缶の浮きは生じ得な
いのである。そのために、耐漏液性の信頼度は増
し、実施例２に示したように有効な結果を得られ
るのである。
以上述べたように、本発明によれば、負極缶と
ガスケツトを一体化する場合、ガスケツトを予め
加湿し、一体化後の負極缶の浮きをなくすことが
でき、耐漏液性を改善できるのである。[Table] As is clear from Table 1, the battery manufactured by the manufacturing method of the present invention has very good leakage resistance in high temperature and high humidity environments. Next, the effects of the present invention will be explained. When integrating the gasket and negative electrode can, as shown in A in Figure 2, if the gasket and negative electrode can have a large amount of interlock, there will be a large resistance when pushing in, and even if the gasket is pushed in completely, there will be a problem when pushing in. Due to the residual stress in the gasket, the negative electrode can is pushed out of the gasket within a short time. Therefore, in the conventional manufacturing method, the negative electrode can bottom 3
A gap is created between a and the gasket bottom 7a,
When the battery is assembled, the internal electrolyte tends to leak through the gaps, resulting in poor leakage resistance. In contrast, in the method of the present invention, since the gasket is expanded in advance by humidification treatment, the meshing between the gasket and the negative electrode can during assembly is small, and the residual stress during pushing is also very small. Therefore, the gasket and negative electrode can are completely integrated, as shown in C in Figure 2.
There is no gap between the bottom of the negative electrode can and the bottom of the gasket. Furthermore, after the integration, when the gasket is shrunk by dehumidifying it through a drying process, the open end 3b of the negative electrode can is brought into contact with the inner surface 7 of the gasket, as shown in FIG. 2D.
Even during subsequent processing, a gap does not easily form between the bottom of the gasket and the bottom of the negative electrode can, resulting in good leakage resistance. Gasket materials for batteries include polyamide resins such as nylon 66, polyethylene resins, polypropylene resins, etc., but the effects of the present invention will be even more pronounced if a gasket made of polyamide resin, which has a particularly large expansion during humidification, is used. In addition, in recent years, it has been proposed and partially implemented to apply a liquid sealant between the gasket and the negative electrode can in order to improve leakage resistance.
When the liquid sealant is applied, the frictional resistance between the gasket and the negative electrode can is reduced, and the negative electrode can is more easily pushed out of the gasket than in the case without the liquid sealant. The present invention is effective even in such cases as shown in Example 1. When using a liquid sealant containing a substance that has an adhesive effect such as epoxy resin, remove the thinner in a humidified state, and after integrating, raise the temperature in a humidified state to harden the liquid sealant and bond the anode can and gasket. Glue. As mentioned above, in high humidity conditions, the negative electrode can and the gasket are in a state where there is little interlocking, so the force of the gasket to push the negative electrode can upward cannot work. In this state, the liquid sealant hardens and the negative electrode can and gasket are bonded together, so even after the gasket shrinks after being taken out from the high humidity and dried by dehumidification, the adhesive force of the liquid sealant will keep the negative electrode can intact. No floating can occur. Therefore, the reliability of leakage resistance increases, and as shown in Example 2, effective results can be obtained. As described above, according to the present invention, when the negative electrode can and the gasket are integrated, the gasket is humidified in advance, and the floating of the negative electrode can after integration can be eliminated, and leakage resistance can be improved. .
第１図は、本発明で製造したボタン型電池の全
体構成を示す縦断面図である。
１……正極缶、２……正極合剤、３……負極
缶、４……負極合剤、５……セパレータ、６……
含浸材、７……ガスケツト、８……液体シール
剤。
第２図は、本発明の実施例を示す負極缶とガス
ケツトの図であり、Ａはガスケツト加湿前、Ｂは
ガスケツト加湿後、一体化直前、Ｃは一体化直
後、Ｄは一体化後乾燥してガスケツトを収縮させ
た状態を示す断面図である。
FIG. 1 is a longitudinal cross-sectional view showing the overall structure of a button-type battery manufactured according to the present invention. 1...Positive electrode can, 2...Positive electrode mixture, 3...Negative electrode can, 4...Negative electrode mixture, 5...Separator, 6...
Impregnation material, 7... gasket, 8... liquid sealant. FIG. 2 is a diagram of a negative electrode can and gasket showing an embodiment of the present invention, where A is before gasket humidification, B is after gasket humidification and immediately before integration, C is immediately after integration, and D is after drying after integration. FIG. 3 is a sectional view showing a state in which the gasket is contracted.
Claims (1)
乾燥処理を施した後、正極缶に組み込んだことを
特徴とするボタン型電池の製造方法。 ２ 前記ガスケツトが、ポリアミド樹脂である特
許請求の範囲第１項記載のボタン型電池の製造方
法。 ３ 前記ガスケツトが、予め有機溶媒で希釈した
液体シール一剤が塗布され、前記有機溶媒を前記
加湿処理で蒸発させた特許請求の範囲第１項もし
くは第２項記載のボタン型電池の製造方法。 ４ 前記乾燥処理にさきだつて高湿状態で温度を
あげて液体シール剤を硬化させる特許請求の範囲
第３項記載のボタン型電池の製造方法。[Scope of Claims] 1. A method for manufacturing a button-type battery, characterized in that a gasket is humidified, assembled into a negative electrode can, dried, and then assembled into a positive electrode can. 2. The method for manufacturing a button battery according to claim 1, wherein the gasket is made of polyamide resin. 3. The method of manufacturing a button-type battery according to claim 1 or 2, wherein the gasket is coated with a liquid sealing agent diluted in advance with an organic solvent, and the organic solvent is evaporated in the humidification process. 4. The method for manufacturing a button-type battery according to claim 3, wherein the liquid sealant is cured by raising the temperature in a high humidity state prior to the drying process.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP56011872A JPS57126063A (en) | 1981-01-29 | 1981-01-29 | Manufacture of button type battery |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP56011872A JPS57126063A (en) | 1981-01-29 | 1981-01-29 | Manufacture of button type battery |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPS57126063A JPS57126063A (en) | 1982-08-05 |
| JPS644308B2 true JPS644308B2 (en) | 1989-01-25 |
Family
ID=11789809
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP56011872A Granted JPS57126063A (en) | 1981-01-29 | 1981-01-29 | Manufacture of button type battery |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPS57126063A (en) |
Families Citing this family (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2001222983A (en) * | 2000-02-08 | 2001-08-17 | Toshiba Battery Co Ltd | Button type battery and method of applying sealing material to gasket thereof |
Family Cites Families (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS5713101B2 (en) * | 1974-05-29 | 1982-03-15 |
-
1981
- 1981-01-29 JP JP56011872A patent/JPS57126063A/en active Granted
Also Published As
| Publication number | Publication date |
|---|---|
| JPS57126063A (en) | 1982-08-05 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| US6752842B2 (en) | Manufacture of flexible thin layer electrochemical cell | |
| US7776468B2 (en) | Wafer alkaline cell | |
| GB2242565A (en) | Manufacture of alkali metal batteries having solid electrolytes containing volatile constituents. | |
| EP1205985A4 (en) | LITHIUM SECONDARY CELL AND MANUFACTURING METHOD THEREFOR | |
| DE3854899T2 (en) | Cylindrical alkaline batteries | |
| JPS644308B2 (en) | ||
| JPH05151951A (en) | Battery with nonaqueous electrolytic solution | |
| JPS6050030B2 (en) | thin battery | |
| JPS59160953A (en) | Manufacture of alkaline battery | |
| US1205392A (en) | Electric battery. | |
| JPH01320769A (en) | Manufacture of organic electrolyte battery | |
| JPH04206460A (en) | Manufacture of button type alkaline battery | |
| JPS6050032B2 (en) | Alkaline battery manufacturing method | |
| JPS628450A (en) | Manufacturing method of button type alkaline battery | |
| JPS5772261A (en) | Button type alkaline battery | |
| US5401597A (en) | Battery and a method of manufacture therefor | |
| JPS6050031B2 (en) | thin battery | |
| JPS62115661A (en) | Sealed battery | |
| JPS58220369A (en) | Button air battery | |
| JPS56128569A (en) | Fabrication of battery | |
| JPS5818867A (en) | Manufacture of battery | |
| JPS5818869A (en) | Button-type battery | |
| JPH0636773A (en) | Manufacture of flat organic electrolyte battery | |
| JPS5854550A (en) | Method of sealing chemical battery | |
| JPH1040883A (en) | Flat organic electrolyte battery and method of applying adhesive to sealing plate of the battery |