JPH0124007B2 - - Google Patents
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- Publication number
- JPH0124007B2 JPH0124007B2 JP56129218A JP12921881A JPH0124007B2 JP H0124007 B2 JPH0124007 B2 JP H0124007B2 JP 56129218 A JP56129218 A JP 56129218A JP 12921881 A JP12921881 A JP 12921881A JP H0124007 B2 JPH0124007 B2 JP H0124007B2
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- vinyl chloride
- chloride resin
- post
- parts
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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- Laying Of Electric Cables Or Lines Outside (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Description
本発明は地中線用ケーブル防護管に関するもの
である。配電設備等は公衆安全、美観等のために
地中に埋設することが盛んに行われるようになつ
てきている。
そして埋設にあたつては、電力ケーブルを保護
するために、鋼管、ヒユーム管、石綿管、塩化ビ
ニル管等が防護管として使用されている。しかし
ながら、鋼管は管の重量が大きいため、運搬や据
付け等に重機を必要とするうえ、接続の際には切
断およびねじ切りに専用の工具が必要であり、配
管の作業性がよくない。ヒユーム管はケーブル防
護管の中では最も重量が大きく運搬や据付け等は
鋼管同様に作業性がよくなく、また重くて脆い素
材であるため、落体衝撃強度に劣り運搬や配管現
場でロスが生じやすく、また接続部の水密性と接
続強度が不十分であるため、接続部のコンクリー
ト胴締めが必要である。一方、布設後において
も、つるはし等による衝撃に弱く、ケーブル損傷
のために電力の安定供給に支障をきたすことがあ
る。石綿セメント管は比較的軽量であるが吸水率
が大きいため物理的性質の変化が大きく強度も低
い素材であるため、コンクリート胴締工法により
保護しなければならず、コンクリートの養生期間
中は管の埋戻しが行なえないため、市街地や商店
街、交通量の多い道路等では工事期間中周辺住民
や市民生活に与える影響が大きくなり、適当な材
料とはいえない。また一般の塩化ビニル管は地中
線用ケーブル保護管として用いた場合、ケーブル
の発熱によつて70℃以上の高温になるため、これ
らの条件下では剛性及び偏平圧縮強度が低下して
埋設強度が低下するとともに、鋭利なつるはし等
による衝撃に対して、ひび割れ又は貫通等破損し
やすいという欠点を有していた。
このような一般の塩化ビニル管の欠点を改良す
るために、塩化ビニル樹脂よりも熱変形温度の高
い後塩素化塩化ビニル樹脂を塩化ビニル樹脂と併
用し、この混合物に塩素化ポリエチレンを少量
(5〜10重量%)添加することにより、前記後塩
素化塩化ビニル樹脂の有する耐熱性をあまり低下
させることなく衝撃強度を向上させる塩化ビニル
系樹脂組成物が提案されている。しかしながら、
このような樹脂組成物より押出成形して得られる
管は、低温での衝撃強度が低く、より過酷な性能
が要求される地中線用ケーブル防護管として実用
上満足して使用できるものではなかつた。
本発明の目的は、管の運搬、据付けが人力で行
うことができること、配管作業が容易でコンクリ
ート胴締め等の補助工法を必要としないこと、通
電時の発熱による管体温度が少なくとも80℃程度
に耐え且つ土圧や輪荷重で変形しない強度がある
こと、水道、下水、ガス等の他企業の工事の際、
受けるつるはし等の衝撃荷重によつて管が破壊し
ないこと等、作業性、衝撃強度および耐熱強度に
おいてのバランスがとれた地中線用ケーブル防護
管を提供することにある。
本発明の要旨は後塩素化塩化ビニル樹脂、又は
塩化ビニル樹脂を20重量%以下含有する後塩素化
塩化ビニル樹脂混合物100重量部に、塩素化ポリ
エチレンが12重量部以上にして且つ前記後塩素化
塩化ビニル樹脂100重量部に対して20重量部以下
の範囲で添加されてなる組成物からなる地中線用
ケーブル防護管に存する。
本発明において使用される後塩素化塩化ビニル
樹脂は塩化ビニル樹脂が後塩素化処理されたもの
であつて、特に限定されるものではないが、塩素
含量が64〜68重量%のものが好ましく、より好ま
しくは65〜67重量%のものである。又重合度も特
に限定されるものではないが、800〜1400である
のが好ましい。
本発明において使用される塩化ビニル樹脂は特
に限定されるものではなく、一般にパイプ、成型
品等に使用されているものでよいが、懸濁重合で
合成された重合度1000〜1500のものが好ましい。
本発明において使用される塩素化ポリエチレン
はポリエチレンが後塩素化処理されたものであつ
て、特に限定されるものではないが、塩素含量が
30〜40重量%のものが好ましく、より好ましくは
33〜37重量%のものである。
本発明においては、上記後塩素化塩化ビニル樹
脂、又は上記塩化ビニル樹脂を20重量%以下含有
する上記後塩素化塩化ビニル樹脂混合物100重量
部に、上記塩素化ポリエチレンが12重量部以上に
して且つ前記後塩素化塩化ビニル樹脂100重量部
に対して20重量部以下の範囲で添加され、得られ
た組成物が押出成形されて地中線用ケーブル防護
管が得られるのである。
後塩素化塩化ビニル樹脂混合物中の塩化ビニル
樹脂の含有量が20重量%を越えると、熱変形温度
が低下し高温での偏平耐圧縮強度が低下するの
で、前記塩化ビニル樹脂の含有量は20重量%以下
の範囲に定められるのである。
又、塩素化ポリエチレンは添加量が少ないと低
温での耐衝撃性が低下し、われやすくなり、逆に
添加量が多いと熱変形温度が低下し高温での偏平
耐圧縮強度が低下するので、塩素化ポリエチレン
は前記後塩素化塩化ビニル樹脂、又は塩化ビニル
樹脂を20重量%以下含有する後塩素化塩化ビニル
樹脂混合物100重量部に対して12重量部以上であ
つて且つ前記後塩素化塩化ビニル樹脂100重量部
に対して20重量部以下の範囲で添加されるのであ
る。
本発明で使用される組成物の構成は上述の通り
であるが、さらに安定剤、滑剤、顔料、充填材等
が適宜添加され得る。
又本発明においては上記組成物がパイプ状に押
出成形されて地中線用ケーブル防護管が製造され
るが、押出成形法は特に限定されるものではな
く、公知の任意の方法が採用されてよい。
更に、前記地中線用ケーブル防護管の肉厚は、
低温及び高温における衝撃強度及び耐熱強度等の
特性面からは厚いほど好ましく、一方、運搬、据
付け、配管現場での作業性及びコスト等の特性面
からは薄いほど好ましいが、本発明においてはこ
れらの特性面におけるバランスがとれるように前
記地中線用ケーブル防護管の内径D/肉厚t比を
目安として、この比D/tが16以下の条件を満足
する(例えばD=130mmのとき、130/t≦16、即
ちt≧130/16≒8.1mmの条件を満足する)よう
に、地中線用ケーブル防護管の肉厚を適宜決めれ
ばよい。
上述の如くして得られた本発明地中線用ケーブ
ル防護管の使用方法は特に限定されるものではな
く公知の任意の方法が採用されてよい。
本発明地中線用ケーブル防護管は上述の通りの
構成であるから、ヤング率は80℃又は85℃におい
ても1.3×104Kg/cm2以上あり、80℃又は85℃にお
ける偏平圧縮強度も非常に高く、地中に埋設され
て管体温度が80℃又はそれ以上の高温になつても
埋設荷重に耐えうる強度を有している。又シヤル
ピー衝撃値も20Kg・cm/cm2以上と高く、つるはし
等で衝撃が加わつてもひび割れや貫通がなく耐衝
撃性が優れている。又サンシヤイン100時間照射
後のシヤルピー衝撃値も14.5Kg・cm/cm2以上と高
く耐候性も優れている。そして塩化ビニル系樹脂
を主体とするものであるから鋼管等に比して軽量
であつて配管や埋戻しの作業性がよい。しかして
作業性、衝撃強度および耐熱強度等バランスのと
れた地中線用ケーブルの防護管として好適に使用
されるのである。
以下本発明を実施例により説明する。なお以下
単に「部」とあるのは「重量部」を意味する。
実施例 1
第1表に示した所定量の塩化ビニル樹脂(重合
度1000)、後塩素化塩化ビニル樹脂(塩素含有量
67重量%)及び塩素化ポリエチレン(塩素含有量
35重量%)にスズ系安定剤2.5部、ステアリン酸
カルシウム1部、ステアリン酸1部及びパラフイ
ンワツクス1部を添加し、均一に混合した後2軸
押出機で押出して外径147mm、内径130mm(肉厚
8.5mm)のパイプを得た。
得られたパイプを使用し、JISC−8430に準拠
して80℃及び85℃で偏平圧縮試験(2.5%偏平時
の荷重)を行つた結果を第1表に示した。又
JISK−7111に準拠して20℃でシヤルビー衝撃強
度を測定し、JISC−3801に準拠して0℃、80℃
及び85℃でつるはし試験を行つた結果を実施例1
として第1表に示した。
上記したJISC−3801は電路に用いる磁器製が
いしの試験方法について規定したものであるが、
ここでは7.1.4打撃耐荷重試験の項に記載された
打撃試験機と同様の装置により、作業者が頭上後
方よりつるはしを振り下した時の衝撃エネルギー
に相当するように、先端に16.16Kgの端子を設け
た1m長の振子を95゜振り上げ角度で離して、該
端子をパイプに打ちつけるという試験を行つた。
なお比較のために塩化ビニル樹脂、後塩素化塩
化ビニル樹脂及び塩素化ポリエチレンの比率を変
化させ、実施例1で行つたと同様にして測定を行
い、その結果を比較例1として第1表に示した。
第1表より塩化ビニル樹脂含有量が10〜20重量
%の範囲の樹脂組成物からなる本発明地中線用ケ
ーブル防護管は80℃での偏平圧縮強度(2.5%偏
平時)が20.9〜23.6Kg/5cm巾と要求強度の20.7
Kg/5cm巾以上あるので、実用上80℃の耐熱温度
が要求される状況下、例えば2列2段(4条)の
配管条数を2列3段(6条)と増加させた状況下
で使用できる。又、塩化ビニル樹脂含有量が10重
量%以下の範囲の樹脂組成物、又は後塩素化塩化
ビニル樹脂単独からなる本発明地中線用ケーブル
防護管は、塩素化ポリエチレンの添加量を最適化
することにより、85℃での偏平圧縮強度(2.5%
偏平時)が20.8〜23.5Kg/5cm巾と要求強度の
20.7Kg/5cm巾以上あるので、実用上80℃の耐熱
温度が要求される前記状況下での使用は勿論、実
用上85℃の耐熱温度が要求される状況下例えば配
管条数を3列3段(9段)と増加させた状況下で
使用できる。
実施例 2
塩化ビニル樹脂(重合度1000)10部、後塩素化
塩化ビニル樹脂(塩素含有量67重量%)90部及び
塩素化ポリエチレン(塩素含有量35重量%)14重
量部にスズ系安定剤2.5部、ステアリン酸カルシ
ウム1部、ステアリン酸1部及びパラフインワツ
クス1部を添加し、均一に混合した後2軸押出機
で押出して内径130mm、肉厚8.0,8.5,9.0,9.5mm
のそれぞれのパイプを得た。得られたパイプを使
用し、JISC−8430に準拠して80℃で偏平圧縮試
験(2.5%偏平時の荷重)を行つた結果を実施例
2として第2表に示した。
The present invention relates to a cable protection pipe for underground cables. BACKGROUND OF THE INVENTION It has become common practice to bury power distribution equipment underground for reasons of public safety, aesthetics, and the like. When burying power cables, steel pipes, fume pipes, asbestos pipes, vinyl chloride pipes, etc. are used as protective pipes to protect power cables. However, since steel pipes are heavy, they require heavy equipment for transportation and installation, and special tools are required for cutting and threading when making connections, making piping work difficult. Huium pipes are the heaviest among cable protection pipes, and are not as easy to transport and install as steel pipes.Also, because they are heavy and brittle materials, they have poor impact strength against falling objects and are prone to losses during transport and piping sites. Also, since the watertightness and connection strength of the joints are insufficient, it is necessary to tighten the joints with concrete. On the other hand, even after installation, cables are susceptible to impact from pickaxes and the like, and damage to the cables may impede the stable supply of power. Although asbestos-cement pipes are relatively lightweight, they have a high water absorption rate, so their physical properties change greatly and their strength is low. Therefore, they must be protected using the concrete shoring method, and the pipes must be protected during the concrete curing period. Since backfilling cannot be performed, it is not an appropriate material for urban areas, shopping streets, roads with heavy traffic, etc., as it will have a significant impact on surrounding residents and citizens' lives during the construction period. In addition, when ordinary PVC pipes are used as cable protection pipes for underground cables, the heat generated by the cables causes them to reach high temperatures of over 70°C.Under these conditions, the rigidity and flat compressive strength decrease, reducing the strength of the underground cables. It has the drawback that it is susceptible to damage such as cracking or penetration when subjected to impact from a sharp pickaxe or the like. In order to improve these drawbacks of general PVC pipes, post-chlorinated PVC resin, which has a higher heat distortion temperature than PVC resin, is used in combination with PVC resin, and a small amount (55%) of chlorinated polyethylene is added to this mixture. A vinyl chloride resin composition has been proposed that improves the impact strength without significantly reducing the heat resistance of the post-chlorinated vinyl chloride resin by adding (up to 10% by weight). however,
Tubes obtained by extrusion molding from such resin compositions have low impact strength at low temperatures, and cannot be used satisfactorily as cable protection tubes for underground cables, which require more severe performance. Ta. The objects of the present invention are that the pipe can be transported and installed manually, that the piping work is easy and does not require auxiliary construction methods such as concrete clamping, and that the pipe body temperature due to heat generated when energized is at least 80°C. It must be strong enough to withstand and not deform due to earth pressure or wheel loads, and must be strong enough to withstand construction by other companies such as water, sewage, gas, etc.
An object of the present invention is to provide a cable protection pipe for underground cables that is well-balanced in terms of workability, impact strength, and heat resistance, such as preventing the pipe from being destroyed by the impact load of a pickaxe or the like. The gist of the present invention is to add 12 parts by weight or more of chlorinated polyethylene to 100 parts by weight of post-chlorinated vinyl chloride resin or post-chlorinated vinyl chloride resin mixture containing 20% by weight or less of vinyl chloride resin, and The present invention relates to a cable protection tube for underground cables, which is made of a composition in which 20 parts by weight or less is added to 100 parts by weight of vinyl chloride resin. The post-chlorinated vinyl chloride resin used in the present invention is a vinyl chloride resin that has been subjected to post-chlorination treatment, and is not particularly limited, but preferably has a chlorine content of 64 to 68% by weight, More preferably, it is 65 to 67% by weight. The degree of polymerization is also not particularly limited, but is preferably 800 to 1,400. The vinyl chloride resin used in the present invention is not particularly limited and may be one commonly used for pipes, molded products, etc., but one synthesized by suspension polymerization and having a polymerization degree of 1000 to 1500 is preferable. . The chlorinated polyethylene used in the present invention is polyethylene that has been subjected to post-chlorination treatment, and is not particularly limited, but has a low chlorine content.
Preferably 30 to 40% by weight, more preferably
33-37% by weight. In the present invention, the chlorinated polyethylene is added to 100 parts by weight of the post-chlorinated vinyl chloride resin or the post-chlorinated vinyl chloride resin mixture containing 20% by weight or less of the vinyl chloride resin, and It is added in an amount of 20 parts by weight or less to 100 parts by weight of the post-chlorinated vinyl chloride resin, and the resulting composition is extruded to obtain a cable protection pipe for underground cables. If the content of vinyl chloride resin in the post-chlorinated vinyl chloride resin mixture exceeds 20% by weight, the heat distortion temperature will decrease and the flat compressive strength at high temperatures will decrease. It is set within a range of % by weight or less. In addition, if the amount of chlorinated polyethylene added is small, the impact resistance at low temperatures will decrease and it will break easily, while if the amount added is too large, the heat distortion temperature will decrease and the flat compressive strength at high temperatures will decrease. The chlorinated polyethylene is 12 parts by weight or more based on 100 parts by weight of the post-chlorinated vinyl chloride resin or the post-chlorinated vinyl chloride resin mixture containing 20% by weight or less of the vinyl chloride resin, and It is added in an amount of 20 parts by weight or less per 100 parts by weight of the resin. The structure of the composition used in the present invention is as described above, but stabilizers, lubricants, pigments, fillers, etc. may be added as appropriate. Further, in the present invention, the above composition is extruded into a pipe shape to produce a cable protection pipe for underground cables, but the extrusion method is not particularly limited, and any known method may be adopted. good. Furthermore, the wall thickness of the underground cable protection pipe is
The thicker the material, the more preferable it is from the viewpoint of properties such as impact strength and heat resistance strength at low and high temperatures, while the thinner it is from the viewpoint of properties such as transportation, installation, workability at piping sites, and cost. However, in the present invention, these In order to maintain a balance in terms of characteristics, this ratio D/t satisfies the condition of 16 or less (for example, when D = 130 mm, 130 /t≦16, that is, t≧130/16≈8.1 mm), the wall thickness of the underground cable protection pipe may be appropriately determined. The method of using the underground cable protection tube of the present invention obtained as described above is not particularly limited, and any known method may be employed. Since the underground cable protection pipe of the present invention has the above-mentioned configuration, the Young's modulus is 1.3×10 4 Kg/cm 2 or more even at 80°C or 85°C, and the flat compressive strength at 80°C or 85°C is also It has the strength to withstand the buried load even if it is buried underground and the temperature of the pipe reaches 80℃ or higher. It also has a high Shalpy impact value of 20Kg・cm/cm 2 or more, and has excellent impact resistance without cracking or penetrating even when subjected to impact with a pickaxe, etc. In addition, after 100 hours of sunshine irradiation, the shear pea impact value is as high as 14.5 Kg・cm/cm 2 or more, and the weather resistance is also excellent. Since it is mainly made of vinyl chloride resin, it is lighter than steel pipes and has good workability in piping and backfilling. Therefore, it is suitably used as a protective tube for underground cables, which has a good balance of workability, impact strength, and heat resistance. The present invention will be explained below with reference to Examples. Note that the term "parts" hereinafter simply means "parts by weight." Example 1 Predetermined amounts of vinyl chloride resin (polymerization degree 1000) shown in Table 1, post-chlorinated vinyl chloride resin (chlorine content
67% by weight) and chlorinated polyethylene (chlorine content
35% by weight), 2.5 parts of tin-based stabilizer, 1 part of calcium stearate, 1 part of stearic acid, and 1 part of paraffin wax were mixed uniformly and then extruded using a twin-screw extruder to form a product with an outer diameter of 147 mm and an inner diameter of 130 mm ( wall thickness
8.5mm) pipe was obtained. Using the obtained pipe, a flattening compression test (load at 2.5% flattening) was conducted at 80°C and 85°C in accordance with JISC-8430, and the results are shown in Table 1. or
Shalby impact strength was measured at 20℃ in accordance with JISK-7111, and at 0℃ and 80℃ in accordance with JISK-3801.
The results of the pickaxe test at 85°C are shown in Example 1.
It is shown in Table 1 as follows. JISC-3801 mentioned above stipulates the testing method for porcelain insulators used in electrical circuits.
Here, using a device similar to the impact tester described in section 7.1.4 Impact Load Resistance Test, 16.16 kg was applied to the tip to correspond to the impact energy when a worker swings the pickaxe from behind overhead. A test was conducted in which a 1 m long pendulum equipped with a terminal was swung up at an angle of 95 degrees, and the terminal was struck against a pipe. For comparison, the ratios of vinyl chloride resin, post-chlorinated vinyl chloride resin, and chlorinated polyethylene were changed and measurements were carried out in the same manner as in Example 1. The results are shown in Table 1 as Comparative Example 1. Indicated. Table 1 shows that the underground cable protection pipe of the present invention, which is made of a resin composition with a vinyl chloride resin content in the range of 10 to 20% by weight, has a flattened compressive strength (2.5% flattened) of 20.9 to 23.6 at 80°C. Kg/5cm width and required strength of 20.7
Kg/5cm width or more, so in a situation where a heat resistance temperature of 80℃ is required in practical use, for example, when increasing the number of piping lines from 2 rows and 2 tiers (4 lines) to 2 rows and 3 tiers (6 lines). Can be used in In addition, the underground cable protection pipe of the present invention, which is made of a resin composition with a vinyl chloride resin content of 10% by weight or less, or a post-chlorinated vinyl chloride resin alone, optimizes the amount of chlorinated polyethylene added. By this, the flat compressive strength at 85℃ (2.5%
(when flat) is 20.8~23.5Kg/5cm width and the required strength.
Since it is more than 20.7Kg/5cm wide, it can be used not only in the above-mentioned situation where a heat resistance temperature of 80℃ is required in practice, but also in situations where a heat resistance temperature of 85℃ is required in practice, for example, when the number of pipes is 3 rows and 3. It can be used in situations where it has increased to 9 stages. Example 2 10 parts of vinyl chloride resin (degree of polymerization 1000), 90 parts of post-chlorinated vinyl chloride resin (chlorine content 67% by weight), and 14 parts by weight of chlorinated polyethylene (chlorine content 35% by weight) and tin-based stabilizer Add 2.5 parts of calcium stearate, 1 part of stearic acid, and 1 part of paraffin wax, mix uniformly, and extrude with a twin screw extruder to make a product with an inner diameter of 130 mm and a wall thickness of 8.0, 8.5, 9.0, and 9.5 mm.
obtained each pipe. Using the obtained pipe, a flattening compression test (load at 2.5% flattening) was conducted at 80°C in accordance with JISC-8430, and the results are shown in Table 2 as Example 2.
【表】【table】
【表】【table】
Claims (1)
脂を20重量%以下含有する後塩素化塩化ビニル樹
脂混合物100重量部に、塩素化ポリエチレンが12
重量部以上にして且つ前記後塩素化塩化ビニル樹
脂100重量部に対して20重量部以下の範囲で添加
されてなる組成物からなる地中線用ケーブル防護
管。 2 後塩素化塩化ビニル樹脂の塩素含量が64〜68
重量%である特許請求の範囲第1項記載の地中線
用ケーブル防護管。 3 塩素化ポリエチレンの塩素含量が30〜40重量
%である特許請求の範囲第1項または第2項記載
の地中線用ケーブル防護管。[Claims] 1. 100 parts by weight of a post-chlorinated vinyl chloride resin or a post-chlorinated vinyl chloride resin mixture containing 20% by weight or less of a vinyl chloride resin, and 12 parts by weight of a post-chlorinated polyethylene.
1. A cable protection pipe for underground cables comprising a composition which is added in an amount of not less than 20 parts by weight and not more than 20 parts by weight per 100 parts by weight of the post-chlorinated vinyl chloride resin. 2 The chlorine content of the post-chlorinated vinyl chloride resin is 64-68
% by weight of the underground cable protection pipe according to claim 1. 3. The underground cable protection pipe according to claim 1 or 2, wherein the chlorine content of the chlorinated polyethylene is 30 to 40% by weight.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP56129218A JPS5833917A (en) | 1981-08-18 | 1981-08-18 | Cable protecting tube for underground line |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP56129218A JPS5833917A (en) | 1981-08-18 | 1981-08-18 | Cable protecting tube for underground line |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPS5833917A JPS5833917A (en) | 1983-02-28 |
| JPH0124007B2 true JPH0124007B2 (en) | 1989-05-09 |
Family
ID=15004054
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP56129218A Granted JPS5833917A (en) | 1981-08-18 | 1981-08-18 | Cable protecting tube for underground line |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPS5833917A (en) |
Family Cites Families (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE1544782A1 (en) * | 1965-05-21 | 1969-08-07 | Dynamit Nobel Ag | Process for the production of deformable compositions based on post-chlorinated polyvinyl chloride |
| JPS6040248B2 (en) * | 1980-02-20 | 1985-09-10 | 積水化学工業株式会社 | Underground cable protection pipe |
-
1981
- 1981-08-18 JP JP56129218A patent/JPS5833917A/en active Granted
Also Published As
| Publication number | Publication date |
|---|---|
| JPS5833917A (en) | 1983-02-28 |
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