JPH0354975B2 - - Google Patents
Info
- Publication number
- JPH0354975B2 JPH0354975B2 JP14995485A JP14995485A JPH0354975B2 JP H0354975 B2 JPH0354975 B2 JP H0354975B2 JP 14995485 A JP14995485 A JP 14995485A JP 14995485 A JP14995485 A JP 14995485A JP H0354975 B2 JPH0354975 B2 JP H0354975B2
- Authority
- JP
- Japan
- Prior art keywords
- membered heterocyclic
- oxygen
- oxidizing agent
- heterocyclic compound
- solvent
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 239000007800 oxidant agent Substances 0.000 claims description 11
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims description 8
- 239000001301 oxygen Substances 0.000 claims description 8
- 229910052760 oxygen Inorganic materials 0.000 claims description 8
- 239000002904 solvent Substances 0.000 claims description 8
- 150000002391 heterocyclic compounds Chemical class 0.000 claims description 7
- 238000004519 manufacturing process Methods 0.000 claims description 7
- 238000002156 mixing Methods 0.000 claims description 4
- 239000000758 substrate Substances 0.000 claims description 2
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 15
- 238000000034 method Methods 0.000 description 11
- 239000010408 film Substances 0.000 description 8
- 239000010409 thin film Substances 0.000 description 5
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 4
- KAESVJOAVNADME-UHFFFAOYSA-N Pyrrole Chemical compound C=1C=CNC=1 KAESVJOAVNADME-UHFFFAOYSA-N 0.000 description 4
- 229920000642 polymer Polymers 0.000 description 4
- 150000000565 5-membered heterocyclic compounds Chemical class 0.000 description 3
- 239000012456 homogeneous solution Substances 0.000 description 3
- 239000012528 membrane Substances 0.000 description 3
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 2
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 2
- KDLHZDBZIXYQEI-UHFFFAOYSA-N Palladium Chemical compound [Pd] KDLHZDBZIXYQEI-UHFFFAOYSA-N 0.000 description 2
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 2
- 238000006243 chemical reaction Methods 0.000 description 2
- 239000011248 coating agent Substances 0.000 description 2
- 238000000576 coating method Methods 0.000 description 2
- 230000000052 comparative effect Effects 0.000 description 2
- 150000001875 compounds Chemical class 0.000 description 2
- 239000003792 electrolyte Substances 0.000 description 2
- 239000011521 glass Substances 0.000 description 2
- 150000002736 metal compounds Chemical class 0.000 description 2
- 150000007522 mineralic acids Chemical class 0.000 description 2
- 239000000203 mixture Substances 0.000 description 2
- 229910052757 nitrogen Inorganic materials 0.000 description 2
- BASFCYQUMIYNBI-UHFFFAOYSA-N platinum Chemical compound [Pt] BASFCYQUMIYNBI-UHFFFAOYSA-N 0.000 description 2
- 238000006116 polymerization reaction Methods 0.000 description 2
- 150000003233 pyrroles Chemical class 0.000 description 2
- 238000003756 stirring Methods 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- POILWHVDKZOXJZ-ARJAWSKDSA-M (z)-4-oxopent-2-en-2-olate Chemical class C\C([O-])=C\C(C)=O POILWHVDKZOXJZ-ARJAWSKDSA-M 0.000 description 1
- KEQGZUUPPQEDPF-UHFFFAOYSA-N 1,3-dichloro-5,5-dimethylimidazolidine-2,4-dione Chemical compound CC1(C)N(Cl)C(=O)N(Cl)C1=O KEQGZUUPPQEDPF-UHFFFAOYSA-N 0.000 description 1
- OXHNLMTVIGZXSG-UHFFFAOYSA-N 1-Methylpyrrole Chemical compound CN1C=CC=C1 OXHNLMTVIGZXSG-UHFFFAOYSA-N 0.000 description 1
- -1 4-substituted pyrroles Chemical class 0.000 description 1
- VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 description 1
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 1
- MYMOFIZGZYHOMD-UHFFFAOYSA-N Dioxygen Chemical compound O=O MYMOFIZGZYHOMD-UHFFFAOYSA-N 0.000 description 1
- 239000002841 Lewis acid Substances 0.000 description 1
- ZOKXTWBITQBERF-UHFFFAOYSA-N Molybdenum Chemical compound [Mo] ZOKXTWBITQBERF-UHFFFAOYSA-N 0.000 description 1
- 150000001422 N-substituted pyrroles Chemical class 0.000 description 1
- GRYLNZFGIOXLOG-UHFFFAOYSA-N Nitric acid Chemical compound O[N+]([O-])=O GRYLNZFGIOXLOG-UHFFFAOYSA-N 0.000 description 1
- KJTLSVCANCCWHF-UHFFFAOYSA-N Ruthenium Chemical compound [Ru] KJTLSVCANCCWHF-UHFFFAOYSA-N 0.000 description 1
- ATJFFYVFTNAWJD-UHFFFAOYSA-N Tin Chemical compound [Sn] ATJFFYVFTNAWJD-UHFFFAOYSA-N 0.000 description 1
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 description 1
- QCWXUUIWCKQGHC-UHFFFAOYSA-N Zirconium Chemical compound [Zr] QCWXUUIWCKQGHC-UHFFFAOYSA-N 0.000 description 1
- 150000001298 alcohols Chemical class 0.000 description 1
- 229910052782 aluminium Inorganic materials 0.000 description 1
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 1
- 150000004945 aromatic hydrocarbons Chemical class 0.000 description 1
- 150000001805 chlorine compounds Chemical class 0.000 description 1
- XTHPWXDJESJLNJ-UHFFFAOYSA-N chlorosulfonic acid Substances OS(Cl)(=O)=O XTHPWXDJESJLNJ-UHFFFAOYSA-N 0.000 description 1
- 229910052804 chromium Inorganic materials 0.000 description 1
- 239000011651 chromium Substances 0.000 description 1
- 238000004891 communication Methods 0.000 description 1
- 238000007796 conventional method Methods 0.000 description 1
- 229910052802 copper Inorganic materials 0.000 description 1
- 239000010949 copper Substances 0.000 description 1
- 238000010908 decantation Methods 0.000 description 1
- 239000012954 diazonium Substances 0.000 description 1
- 150000001989 diazonium salts Chemical class 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 150000002170 ethers Chemical class 0.000 description 1
- 229940044631 ferric chloride hexahydrate Drugs 0.000 description 1
- 150000002240 furans Chemical class 0.000 description 1
- 239000007789 gas Substances 0.000 description 1
- 150000008282 halocarbons Chemical class 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 125000000623 heterocyclic group Chemical group 0.000 description 1
- 239000011261 inert gas Substances 0.000 description 1
- 229910052742 iron Inorganic materials 0.000 description 1
- FBAFATDZDUQKNH-UHFFFAOYSA-M iron chloride Chemical compound [Cl-].[Fe] FBAFATDZDUQKNH-UHFFFAOYSA-M 0.000 description 1
- NQXWGWZJXJUMQB-UHFFFAOYSA-K iron trichloride hexahydrate Chemical compound O.O.O.O.O.O.[Cl-].Cl[Fe+]Cl NQXWGWZJXJUMQB-UHFFFAOYSA-K 0.000 description 1
- 150000007517 lewis acids Chemical class 0.000 description 1
- WPBNNNQJVZRUHP-UHFFFAOYSA-L manganese(2+);methyl n-[[2-(methoxycarbonylcarbamothioylamino)phenyl]carbamothioyl]carbamate;n-[2-(sulfidocarbothioylamino)ethyl]carbamodithioate Chemical compound [Mn+2].[S-]C(=S)NCCNC([S-])=S.COC(=O)NC(=S)NC1=CC=CC=C1NC(=S)NC(=O)OC WPBNNNQJVZRUHP-UHFFFAOYSA-L 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 150000002739 metals Chemical class 0.000 description 1
- 229910052750 molybdenum Inorganic materials 0.000 description 1
- 239000011733 molybdenum Substances 0.000 description 1
- 150000002823 nitrates Chemical class 0.000 description 1
- 229910017604 nitric acid Inorganic materials 0.000 description 1
- 150000002894 organic compounds Chemical class 0.000 description 1
- 229910052763 palladium Inorganic materials 0.000 description 1
- JRKICGRDRMAZLK-UHFFFAOYSA-N peroxydisulfuric acid Chemical compound OS(=O)(=O)OOS(O)(=O)=O JRKICGRDRMAZLK-UHFFFAOYSA-N 0.000 description 1
- 229910052697 platinum Inorganic materials 0.000 description 1
- 229920000128 polypyrrole Polymers 0.000 description 1
- 230000009257 reactivity Effects 0.000 description 1
- 229910052707 ruthenium Inorganic materials 0.000 description 1
- 239000000523 sample Substances 0.000 description 1
- 150000005082 selenophenes Chemical class 0.000 description 1
- 238000000926 separation method Methods 0.000 description 1
- MWNQXXOSWHCCOZ-UHFFFAOYSA-L sodium;oxido carbonate Chemical class [Na+].[O-]OC([O-])=O MWNQXXOSWHCCOZ-UHFFFAOYSA-L 0.000 description 1
- 150000003467 sulfuric acid derivatives Chemical class 0.000 description 1
- 150000005087 tellurophenes Chemical class 0.000 description 1
- 229930192474 thiophene Natural products 0.000 description 1
- 150000003577 thiophenes Chemical class 0.000 description 1
- 229910052718 tin Inorganic materials 0.000 description 1
- 229910052719 titanium Inorganic materials 0.000 description 1
- 239000010936 titanium Substances 0.000 description 1
- WFKWXMTUELFFGS-UHFFFAOYSA-N tungsten Chemical compound [W] WFKWXMTUELFFGS-UHFFFAOYSA-N 0.000 description 1
- 229910052721 tungsten Inorganic materials 0.000 description 1
- 239000010937 tungsten Substances 0.000 description 1
- 238000005406 washing Methods 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
- 229910052726 zirconium Inorganic materials 0.000 description 1
Landscapes
- Moulding By Coating Moulds (AREA)
- Polyoxymethylene Polymers And Polymers With Carbon-To-Carbon Bonds (AREA)
- Non-Insulated Conductors (AREA)
- Manufacturing Of Electric Cables (AREA)
- Manufacture Of Macromolecular Shaped Articles (AREA)
Description
【発明の詳細な説明】
〔産業上の利用分野〕
本発明は導電性膜の製造方法に関する。詳しく
は、特定の方法で複素５員環式化合物重合体の膜
を製造する方法に関する。DETAILED DESCRIPTION OF THE INVENTION [Field of Industrial Application] The present invention relates to a method for manufacturing a conductive film. Specifically, the present invention relates to a method for producing a membrane of a five-membered heterocyclic compound polymer using a specific method.
複素５員環式化合物が酸化剤によつて重合体を
生成することはすでに知られている（アドバンシ
ス イン ヘテロサイクリツク ケミストリー
15巻 67ページ（1973））。又、電解重合法によつ
て複素５員環式化合物の膜を製造する方法もすで
に知られている（例えば、ジヤーナル オブ ケ
ミカル ソサエテイ ケミカル コミユニケーシ
ヨン（1979）635ページ、ジヤパン ジヤーナル
オブ アプライド フイジツクス21巻L562
（1982）及び同誌23巻L527（1984））。
It is already known that five-membered heterocyclic compounds form polymers by oxidizing agents (Advances in Heterocyclic Chemistry).
Volume 15, page 67 (1973)). In addition, a method for producing membranes of five-membered heterocyclic compounds by electrolytic polymerization is already known (for example, Journal of Chemical Society Chemical Communication (1979) p. 635, Japan Journal of Applied Physics Vol. 21). L562
(1982) and the same magazine, Vol. 23, L527 (1984)).
しかしながら、電解重合法による方法で特殊な
装置及び電解質が必要であるという問題がある。
そこで本発明者らは、特定の方法で酸化剤を用い
て複素５員環式化合物の重合体の膜を製造する方
法を先に提案した（特願昭59−171430号）。 However, there is a problem in that the electrolytic polymerization method requires special equipment and electrolytes.
Therefore, the present inventors have previously proposed a method for producing a membrane of a polymer of a five-membered heterocyclic compound using a specific method using an oxidizing agent (Japanese Patent Application No. 171,430/1982).
この方法は高価な電解質とか特別の電解反応用
の装置を必要としないなど優れた方法であるが、
均一の膜を製造するためにはかなりの熟練を必要
とする上に、反応に一定の時間を要するという問
題があつた。
This method is an excellent method as it does not require expensive electrolytes or special electrolytic reaction equipment;
In addition to requiring considerable skill to produce a uniform film, there were problems in that the reaction required a certain amount of time.
本発明者らは上記問題点を解決して、簡便に導
電性膜を製造する方法について鋭意検討し、本発
明を完成した。
The present inventors solved the above-mentioned problems and conducted extensive studies on a method for simply manufacturing a conductive film, and completed the present invention.
即ち、本発明は酸化剤を溶解した溶液中に複素
５員環式化合物を加え混合した後不溶分をを分離
して得た溶液を基材上に塗布あるいは流延した
後、酸素の存在下で溶媒を除去することを特徴と
する導電性膜の製造方法である。 That is, in the present invention, a five-membered heterocyclic compound is added to a solution in which an oxidizing agent is dissolved, mixed, the insoluble components are separated, the obtained solution is applied or cast onto a substrate, and then the compound is mixed in the presence of oxygen. This method of manufacturing a conductive film is characterized in that the solvent is removed in a step.
本発明において使用する酸化剤としては、無機
酸、金属化合物が有効であり、硫酸、塩酸、硝
酸、クロルスルホン酸などが無機酸の具体例とし
て挙げられ、金属化合物としてはルイス酸として
知られる化合物が好ましく用いられ、アルミニウ
ム、錫、チタン、ジルコニウム、クロム、マンガ
ン、鉄、銅、モリブデン、タングステン、ルテニ
ウム、パラジウム、白金などの金属の塩化物、硫
酸塩、硝酸塩、アセチルアセトナート化合物など
が具体例として挙げられる。又、ペルオキソニ硫
酸あるいは過炭酸の塩なども好ましく使用でき
る。さらに、ペンゾキノン、ジアゾニウム塩など
の有機化合物も使用可能である。これらの酸化剤
は２種以上混合して用いることも可能である。 Inorganic acids and metal compounds are effective as the oxidizing agent used in the present invention, and specific examples of inorganic acids include sulfuric acid, hydrochloric acid, nitric acid, and chlorosulfonic acid. Examples of metal compounds include compounds known as Lewis acids. Preferred examples include chlorides, sulfates, nitrates, and acetylacetonate compounds of metals such as aluminum, tin, titanium, zirconium, chromium, manganese, iron, copper, molybdenum, tungsten, ruthenium, palladium, and platinum. It is mentioned as. Also, peroxodisulfuric acid or percarbonate salts can also be preferably used. Furthermore, organic compounds such as penzoquinone and diazonium salts can also be used. It is also possible to use a mixture of two or more of these oxidizing agents.
上記酸化剤を溶解せしめる溶媒としては、アル
コール類、ハロゲン化炭化水素類、芳香族炭化水
素類、エーテル類、水などが使用でき、好ましく
は、１当り上記酸化剤を0.01ｇ以上 溶解し得
るものである。 As the solvent for dissolving the oxidizing agent, alcohols, halogenated hydrocarbons, aromatic hydrocarbons, ethers, water, etc. can be used, preferably solvents that can dissolve 0.01 g or more of the oxidizing agent per solvent. It is.
本発明において複素５員環式化合物としては、
ピロール類、チオフエン類、フラン類、セレノフ
エン類、テルロフエン類が具体例として挙げられ
中でもピロール、Ｎ−置換ピロール、３−及び／
又は４−置換ピロール類が反応性も高く好まし
い。 In the present invention, the 5-membered heterocyclic compound includes:
Specific examples include pyrroles, thiophenes, furans, selenophenes, and tellurophenes, among which pyrroles, N-substituted pyrroles, 3- and/or
Alternatively, 4-substituted pyrroles are preferable because of their high reactivity.
複素５員環式化合物の使用量としては酸化剤１
モル当り0.1〜100モル、通常当モル〜10モルが適
当である。 The amount of the 5-membered heterocyclic compound used is oxidizing agent 1
A suitable amount per mole is 0.1 to 100 mol, usually equimolar to 10 mol.
酸化剤溶液中と複素５員環式化合物の混合は温
度、時間、混合方法については特に限定はなく、
室温で数分〜数十分行えば充分である。混合後不
溶分は分離除去される。分離法としてはデカンテ
ーシヨン、あるいは別など通常の方法が採用でき
る。こうして得られた均一溶液は、適当な基材上
に塗布あるいは流し込むことで一定の形状とし、
次いで溶媒を除去することで導電性の膜とするこ
とができる。 There are no particular limitations on the temperature, time, or mixing method for mixing the oxidizing agent solution and the 5-membered heterocyclic compound.
A few minutes to several tens of minutes at room temperature is sufficient. After mixing, insoluble matter is separated and removed. As a separation method, a conventional method such as decantation or another method can be used. The homogeneous solution thus obtained is shaped into a certain shape by coating or pouring it onto a suitable base material.
Then, by removing the solvent, a conductive film can be obtained.
本発明において肝要なのは溶媒を除去する操作
を酸素の存在下に行うことにある。酸素としては
純酸素のみならず他の不活性ガスで希釈して用い
ることも可能であり、空気を酸素源として使用す
ることもできる。溶媒の除去は、酸素又は酸素含
有ガスの気流下に必要に応じ塗膜等を加熱するこ
とで達成される。 What is important in the present invention is that the operation for removing the solvent is performed in the presence of oxygen. As oxygen, it is possible to use not only pure oxygen but also diluted with other inert gases, and air can also be used as an oxygen source. Removal of the solvent is achieved by heating the coating film or the like under a stream of oxygen or oxygen-containing gas, if necessary.
本発明の方法を実施することによつて複素５員
環式化合物重合体からなる導電性膜を簡単に製造
することが可能となり、工業的に極めて価値があ
る。
By carrying out the method of the present invention, it becomes possible to easily produce a conductive film made of a five-membered heterocyclic compound polymer, which is extremely valuable industrially.
以下、実施例を挙げ本発明をさらに説明する。 The present invention will be further explained below with reference to Examples.
実施例 １
酸化剤として塩化第二鉄・６水和物10ｇをメタ
ノール50mlに溶解した溶液をピロール５mlをメタ
ノール20mlに溶解した溶液に撹拌しながらゆつく
り加えた。約１時間撹拌した後過し不溶分を除
いた。こうして得られた均一溶液をガラス板上に
塗布し、酸素気流下でメタノールを除去した。ガ
ラス板上に生成したポリピロール膜の厚みは約
10μｍであり、その四探針法による比抵抗は1.1×
100Ωcmであつた。Example 1 A solution of 10 g of ferric chloride hexahydrate as an oxidizing agent dissolved in 50 ml of methanol was slowly added to a solution of 5 ml of pyrrole dissolved in 20 ml of methanol while stirring. After stirring for about 1 hour, the mixture was filtered to remove insoluble matter. The homogeneous solution thus obtained was applied onto a glass plate, and methanol was removed under an oxygen stream. The thickness of the polypyrrole film formed on the glass plate is approximately
10μm, and its resistivity by four-point probe method is 1.1×
It was 100 Ωcm.
実施例 ２
実施例１と同様にして調製した均一溶液をシヤ
ーレに薄く入れ、空気中で乾燥した後、メタノー
ルを入れて薄膜をはがした。薄膜の厚みは0.1mm
であつた。メタノールで塩化鉄を洗い流した後の
比抵抗は2.4×101Ωcmであつた。Example 2 A thin layer of a homogeneous solution prepared in the same manner as in Example 1 was placed in a shear dish, and after drying in the air, methanol was added and the thin film was peeled off. Thin film thickness is 0.1mm
It was hot. The specific resistance after washing away iron chloride with methanol was 2.4×10 1 Ωcm.
比較例 １
実施例２と同様の操作を窒素気流下で行つた。
得られた薄膜の比抵抗は6.7×102Ωcmであつた。Comparative Example 1 The same operation as in Example 2 was carried out under a nitrogen stream.
The specific resistance of the obtained thin film was 6.7×10 2 Ωcm.
実施例 ３
実施例１と同様の操作を、ピロールのかわりに
Ｎ−メチルピロールを用いて行つた。得られた薄
膜の比抵抗は3.8×104Ωcmであつた。Example 3 The same operation as in Example 1 was carried out using N-methylpyrrole instead of pyrrole. The specific resistance of the obtained thin film was 3.8×10 4 Ωcm.
比較例 ２
実施例３と同様の操作を窒素気流下で行つた。
得られた薄膜の比抵抗は4.6×106Ωcmであつた。Comparative Example 2 The same operation as in Example 3 was performed under a nitrogen stream.
The specific resistance of the obtained thin film was 4.6×10 6 Ωcm.
Claims (1)
を混合した後、不溶分を分離して得た溶液を基材
上に塗布あるいは流延した後、酸素の存在下に溶
媒を除去することを特徴とする導電性膜の製造方
法。1. After mixing a solution in which an oxidizing agent is dissolved and a five-membered heterocyclic compound, the insoluble matter is separated, the resulting solution is applied or cast onto a substrate, and then the solvent is removed in the presence of oxygen. A method for producing a conductive film characterized by:
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP14995485A JPS6211733A (en) | 1985-07-10 | 1985-07-10 | Production of electrically conductive film |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP14995485A JPS6211733A (en) | 1985-07-10 | 1985-07-10 | Production of electrically conductive film |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPS6211733A JPS6211733A (en) | 1987-01-20 |
| JPH0354975B2 true JPH0354975B2 (en) | 1991-08-21 |
Family
ID=15486223
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP14995485A Granted JPS6211733A (en) | 1985-07-10 | 1985-07-10 | Production of electrically conductive film |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPS6211733A (en) |
Families Citing this family (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS63284219A (en) * | 1987-05-18 | 1988-11-21 | Hoechst Gosei Kk | Manufacture of pyrrole polymer |
-
1985
- 1985-07-10 JP JP14995485A patent/JPS6211733A/en active Granted
Also Published As
| Publication number | Publication date |
|---|---|
| JPS6211733A (en) | 1987-01-20 |
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