JPH0355425B2 - - Google Patents
Info
- Publication number
- JPH0355425B2 JPH0355425B2 JP57117740A JP11774082A JPH0355425B2 JP H0355425 B2 JPH0355425 B2 JP H0355425B2 JP 57117740 A JP57117740 A JP 57117740A JP 11774082 A JP11774082 A JP 11774082A JP H0355425 B2 JPH0355425 B2 JP H0355425B2
- Authority
- JP
- Japan
- Prior art keywords
- inorganic
- resin
- particles
- film
- properties
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
Landscapes
- Laminated Bodies (AREA)
- Manufacture Of Porous Articles, And Recovery And Treatment Of Waste Products (AREA)
Description
【発明の詳細な説明】
この発明は炭酸カルシウム粉末等の無機質系骨
材を主原料とし、この骨材を塩化ビニル樹脂をも
つて一体的に凝結するに於いて骨材組成粒子間に
発泡空隙を構成して、組成粒子相互を塩化ビニル
樹脂の皮膜をもつて相互に緊密に止着し、粒子相
互間に於ける止着力の強化を期すと同時に使用樹
脂素材量を必要最小限のものとして成形板に於け
る特性を純粋な無機質板に極力近づけるようにし
たものである。Detailed Description of the Invention This invention uses inorganic aggregate such as calcium carbonate powder as the main raw material, and when this aggregate is integrally coagulated with vinyl chloride resin, foamed voids are created between the aggregate composition particles. The composition particles are tightly attached to each other with a film of vinyl chloride resin, and the adhesive strength between the particles is strengthened, while at the same time minimizing the amount of resin material used. The properties of the molded plate are made to be as close as possible to those of a pure inorganic plate.
而して、従前に於けるこの種の無機質板は、ツ
ナギ素材をセメント、石膏等としたことにより成
形特性が悪く、又軽量板の成形提供が困難とされ
たものである。又、かかる純粋な無機質板に於い
ては耐衝撃特性、曲げ強度特性等が充分なものと
されず、更に切削、穴開け、あるいは釘打ち等の
施工特性が極端に劣つたものである。 Conventional inorganic boards of this type have poor molding properties due to the use of cement, gypsum, etc. as the filler material, and it has been difficult to mold lightweight boards. Moreover, such pure inorganic boards do not have sufficient impact resistance properties, bending strength properties, etc., and furthermore, they have extremely poor construction properties such as cutting, drilling, and nailing.
これに比し、無機質系粉末中に樹脂接着剤を混
入、型付けして提供される無機質板に於いては当
然のこと乍ら骨材間を完全に接着樹脂をもつて埋
めつくすことが要請され、樹脂使用量が必然的に
多量のものとされ、これが無機質板としての使用
に多くの不都合を誘起したものである。 In contrast, with inorganic boards that are provided by mixing resin adhesive into inorganic powder and molding, it is of course necessary to completely fill the spaces between aggregates with adhesive resin. However, a large amount of resin is inevitably used, which causes many problems when used as an inorganic board.
本発明に係る無機質板の成形方法は、かかる従
前無機質板に於ける不都合に鑑み特に案出された
ものであつて、炭酸カルシウム等の無機質系微粉
末を成形骨材とし、この骨材表面に付着される塩
化ビニル等の樹脂皮膜をもつて該骨材を確実に連
結するようになすと共に、この連結に供される皮
膜部分以外の間隙を発泡間隙として、骨材相互間
に不要の樹脂素材の介在される余地を一掃し、殆
ど純粋な無機質板に於けると同様の機能の奏効を
約束せしめるようになすと共に板自体の軽量化
と、曲げ特性、耐衝撃特性の助長等を期したもの
である。 The method for forming an inorganic board according to the present invention was specially devised in view of the disadvantages of the conventional inorganic board. The aggregates are reliably connected using a resin film such as vinyl chloride that is attached, and the gaps other than the film part used for this connection are used as foam gaps to remove unnecessary resin material between the aggregates. It is designed to eliminate the possibility of intervening materials and to ensure the same functional effect as that of almost pure inorganic plates, as well as to reduce the weight of the plates themselves and to improve bending and impact resistance properties. It is.
而して本発明に係る無機質板の典型的な製造方
法の一実施例を詳細に説明するに、塩化ビニル等
の発泡に伴つて引張り強度等の機械的特性が比較
的毀損され難い樹脂素材に対し20%前後のトルエ
ン等の溶剤を添加し、撹拌混入した後樹脂素材15
〜25%に対し炭酸カルシウム等の無機質系粉末を
75〜85%混入し、更に、この両素材の混合物に対
し6〜8%発泡剤を混入し、充分な練込みをなし
た後型内に充填して150〜170℃/30分程度の範囲
に於いて加熱発泡して無機質板を得たものであ
る。 To explain in detail one example of a typical manufacturing method of an inorganic board according to the present invention, it is possible to use a resin material such as vinyl chloride whose mechanical properties such as tensile strength are relatively less likely to be damaged by foaming. After adding around 20% of a solvent such as toluene and stirring it, the resin material 15
Add inorganic powder such as calcium carbonate to ~25%
Mix 75 to 85%, and further mix 6 to 8% of a blowing agent to the mixture of both materials, and after thorough kneading, fill it into a mold and heat at 150 to 170℃ for about 30 minutes. The inorganic plate was obtained by heating and foaming in the process.
尚、叙上に於ける溶剤は、使用される樹脂素材
の特性に合せてメチルアルコール、アセトン、ベ
ンゼン、トリクレン、ギ酸ないしはテトラヒドロ
フラン等が適宜選別使用されると共に、発泡剤に
於いても同様に炭酸ソーダ、フレオン、プロパ
ン、ブタンあるいはペンタン等が選別使用された
ものである。 The solvents used in the above are methyl alcohol, acetone, benzene, trichlene, formic acid, or tetrahydrofuran, etc., depending on the characteristics of the resin material used, and carbonic acid is used as the blowing agent. Soda, freon, propane, butane, or pentane are selectively used.
又、かゝる混入発泡剤と共に無機質素材を炭酸
カルシウムとした場合に於いては、それ自体に於
いて発泡機能を呈し、粒子相互間に完全な空隙を
構成したものである。 In addition, when calcium carbonate is used as the inorganic material together with such a foaming agent, it exhibits a foaming function by itself, and complete voids are formed between the particles.
本発明に係る無機質板は叙上に於ける特長ある
構成よりなり板を構成する粒子1〜1の表面に樹
脂皮膜2が確実に積層構成されると共に、この樹
脂皮膜2が一連のものとして連続して所定の接着
強度を出したものであり、又、この粒子1〜1間
に於ける間隙が完全な発泡空隙3とされたもので
ある。 The inorganic board according to the present invention has the characteristic structure described above, and the resin film 2 is reliably laminated on the surface of the particles 1 to 1 constituting the board, and this resin film 2 is continuous as a series. In addition, the gaps between the particles 1 to 1 are completely foamed voids 3.
かゝる粒子構成は、使用骨材が炭酸カルシウム
である場合に於いて更に顕著に見られたものであ
り、加熱に伴つて発生する炭酸ガスにより粒子1
〜1間に於いて確実に空隙3が構成されると共
に、この発生炭酸ガスにより樹脂素材は皮膜2と
して確実に粒子1周面に押圧着されたものであ
る。 Such a particle structure was even more noticeable when the aggregate used was calcium carbonate, and the carbon dioxide gas generated during heating caused the particle size to increase.
A gap 3 is reliably formed between 1 and 1, and the resin material is reliably pressed and bonded as a film 2 to the circumferential surface of the particle 1 by the generated carbon dioxide gas.
かゝる無機質板の発泡構造体に於いては粒子1
〜1が皮膜2をもつて完全に一体のものとして連
設されると共に皮膜2が蜂の巣状の構造体とな
り、板自体に特有の耐衝撃特性、曲げ強度特性を
付与し、従前無機質板に見られない良好な機械的
特性を有したものである。 In such a foamed structure of an inorganic plate, particles 1
~ 1 are completely integrated with the coating 2, and the coating 2 forms a honeycomb-like structure, giving the plate itself unique impact resistance and bending strength characteristics, unlike conventional inorganic plates. It has excellent mechanical properties.
又、かゝる粒子1の皮膜構造体に於いては粒子
1がカルシウム粉末である場合に於いても外部か
ら確実に遮断されたものとして含水時等に於ける
強度劣化が確実に防止されると共に完全な耐水構
造板とされたものである。 In addition, in the film structure of the particles 1, even when the particles 1 are calcium powder, it is reliably shielded from the outside, and strength deterioration due to moisture absorption etc. is reliably prevented. Together with this, it is a completely water-resistant structural board.
更に叙上に於ける皮膜2を有する発泡構造体と
したことをもつて、板に於ける断熱特性並びに遮
音特性は極端に良好とされたものであり、又、
かゝる皮膜2構造による樹脂使用素材の割愛をも
つて不燃機能を更に確実なものになすと共に加熱
時に於ける有害ガス等の発生を極力抑止したもの
である。 Furthermore, by using the foamed structure having the film 2 mentioned above, the heat insulation and sound insulation properties of the board are extremely good, and
By omitting the use of resin materials due to such a two-layer structure, the non-combustibility function is further ensured, and the generation of harmful gases etc. during heating is suppressed as much as possible.
添附の図面は本発明に係る成形方法をもつて提
供される無機質板の典型的な一実施例を示す要部
拡大断面図である。
尚、図中1……粒子、2……皮膜、3……発泡
空隙を示したものである。
The accompanying drawing is an enlarged sectional view of a main part showing a typical example of an inorganic plate provided by the molding method according to the present invention. In the figure, 1...particles, 2...film, 3...foamed voids.
Claims (1)
%の塩化ビニル樹脂素材15〜25%と、炭酸カルシ
ウム等の無機質系粉末骨材75〜85%とに対し6〜
8%の発泡剤を混入練成して、150℃〜170℃/30
分程度の範囲において加熱発泡したことを特徴と
する無機質発泡板の成形方法。1 Solid content dissolved in a solvent such as toluene 80
% of vinyl chloride resin material and 75-85% of inorganic powder aggregate such as calcium carbonate.
Mix 8% blowing agent and knead to 150℃~170℃/30
A method for forming an inorganic foam board characterized by heating and foaming within a range of about minutes.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP11774082A JPS598661A (en) | 1982-07-08 | 1982-07-08 | Formation of inorganic foamed board |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP11774082A JPS598661A (en) | 1982-07-08 | 1982-07-08 | Formation of inorganic foamed board |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPS598661A JPS598661A (en) | 1984-01-17 |
| JPH0355425B2 true JPH0355425B2 (en) | 1991-08-23 |
Family
ID=14719123
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP11774082A Granted JPS598661A (en) | 1982-07-08 | 1982-07-08 | Formation of inorganic foamed board |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPS598661A (en) |
Families Citing this family (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| FR2575743A1 (en) * | 1985-01-07 | 1986-07-11 | Sitger Gerard | Synthetic binder based on thermoplastic resins and process for its manufacture |
| GB9814231D0 (en) * | 1998-07-01 | 1998-09-02 | Ecc Int Ltd | Foamed inorganic materials |
Family Cites Families (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS537944A (en) * | 1976-07-08 | 1978-01-24 | Nat Jutaku Kenzai | Rain door |
-
1982
- 1982-07-08 JP JP11774082A patent/JPS598661A/en active Granted
Also Published As
| Publication number | Publication date |
|---|---|
| JPS598661A (en) | 1984-01-17 |
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