JPH0613669B2 - Modified epoxy resin paint - Google Patents
Modified epoxy resin paintInfo
- Publication number
- JPH0613669B2 JPH0613669B2 JP62088747A JP8874787A JPH0613669B2 JP H0613669 B2 JPH0613669 B2 JP H0613669B2 JP 62088747 A JP62088747 A JP 62088747A JP 8874787 A JP8874787 A JP 8874787A JP H0613669 B2 JPH0613669 B2 JP H0613669B2
- Authority
- JP
- Japan
- Prior art keywords
- epoxy resin
- paint
- metal foil
- resin coating
- modified epoxy
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 239000003822 epoxy resin Substances 0.000 title claims description 75
- 229920000647 polyepoxide Polymers 0.000 title claims description 75
- 239000003973 paint Substances 0.000 title description 51
- 238000000576 coating method Methods 0.000 claims description 58
- 239000011248 coating agent Substances 0.000 claims description 53
- 239000011888 foil Substances 0.000 claims description 47
- 229910052751 metal Inorganic materials 0.000 claims description 36
- 239000002184 metal Substances 0.000 claims description 36
- 229920005989 resin Polymers 0.000 claims description 29
- 239000011347 resin Substances 0.000 claims description 29
- OEPOKWHJYJXUGD-UHFFFAOYSA-N 2-(3-phenylmethoxyphenyl)-1,3-thiazole-4-carbaldehyde Chemical compound O=CC1=CSC(C=2C=C(OCC=3C=CC=CC=3)C=CC=2)=N1 OEPOKWHJYJXUGD-UHFFFAOYSA-N 0.000 claims description 23
- 239000000839 emulsion Substances 0.000 claims description 21
- 229910001220 stainless steel Inorganic materials 0.000 claims description 15
- 239000010935 stainless steel Substances 0.000 claims description 15
- 239000008199 coating composition Substances 0.000 claims description 9
- 229910000570 Cupronickel Inorganic materials 0.000 claims description 6
- 239000007787 solid Substances 0.000 claims description 4
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 claims 1
- 125000002573 ethenylidene group Chemical group [*]=C=C([H])[H] 0.000 claims 1
- 239000000463 material Substances 0.000 description 22
- 230000000694 effects Effects 0.000 description 13
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 11
- 239000003795 chemical substances by application Substances 0.000 description 7
- ZWEHNKRNPOVVGH-UHFFFAOYSA-N 2-Butanone Chemical compound CCC(C)=O ZWEHNKRNPOVVGH-UHFFFAOYSA-N 0.000 description 6
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 6
- 230000005856 abnormality Effects 0.000 description 6
- 239000002253 acid Substances 0.000 description 6
- 239000010779 crude oil Substances 0.000 description 6
- 239000000126 substance Substances 0.000 description 6
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 5
- 235000013305 food Nutrition 0.000 description 5
- 150000002576 ketones Chemical class 0.000 description 5
- 239000003921 oil Substances 0.000 description 5
- 150000003839 salts Chemical class 0.000 description 5
- 239000007788 liquid Substances 0.000 description 4
- XNGIFLGASWRNHJ-UHFFFAOYSA-N phthalic acid Chemical compound OC(=O)C1=CC=CC=C1C(O)=O XNGIFLGASWRNHJ-UHFFFAOYSA-N 0.000 description 4
- 239000004593 Epoxy Substances 0.000 description 3
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 3
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 3
- 150000007513 acids Chemical class 0.000 description 3
- 239000002585 base Substances 0.000 description 3
- 238000009835 boiling Methods 0.000 description 3
- 230000000052 comparative effect Effects 0.000 description 3
- 238000007689 inspection Methods 0.000 description 3
- 238000000034 method Methods 0.000 description 3
- 229910052757 nitrogen Inorganic materials 0.000 description 3
- 239000003507 refrigerant Substances 0.000 description 3
- 239000008399 tap water Substances 0.000 description 3
- 235000020679 tap water Nutrition 0.000 description 3
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 2
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 2
- 229910000831 Steel Inorganic materials 0.000 description 2
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 2
- 229910052802 copper Inorganic materials 0.000 description 2
- 239000010949 copper Substances 0.000 description 2
- 229910052742 iron Inorganic materials 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- 239000000203 mixture Substances 0.000 description 2
- 238000010422 painting Methods 0.000 description 2
- 239000002245 particle Substances 0.000 description 2
- 229920000962 poly(amidoamine) Polymers 0.000 description 2
- 239000002904 solvent Substances 0.000 description 2
- 238000005507 spraying Methods 0.000 description 2
- 239000010959 steel Substances 0.000 description 2
- IHCCLXNEEPMSIO-UHFFFAOYSA-N 2-[4-[2-(2,3-dihydro-1H-inden-2-ylamino)pyrimidin-5-yl]piperidin-1-yl]-1-(2,4,6,7-tetrahydrotriazolo[4,5-c]pyridin-5-yl)ethanone Chemical compound C1C(CC2=CC=CC=C12)NC1=NC=C(C=N1)C1CCN(CC1)CC(=O)N1CC2=C(CC1)NN=N2 IHCCLXNEEPMSIO-UHFFFAOYSA-N 0.000 description 1
- 239000004215 Carbon black (E152) Substances 0.000 description 1
- VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 description 1
- YCKRFDGAMUMZLT-UHFFFAOYSA-N Fluorine atom Chemical compound [F] YCKRFDGAMUMZLT-UHFFFAOYSA-N 0.000 description 1
- 229910001209 Low-carbon steel Inorganic materials 0.000 description 1
- 239000006087 Silane Coupling Agent Substances 0.000 description 1
- 229920006328 Styrofoam Polymers 0.000 description 1
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 description 1
- BZHJMEDXRYGGRV-UHFFFAOYSA-N Vinyl chloride Chemical compound ClC=C BZHJMEDXRYGGRV-UHFFFAOYSA-N 0.000 description 1
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 description 1
- 239000003513 alkali Substances 0.000 description 1
- 229910021529 ammonia Inorganic materials 0.000 description 1
- NEHMKBQYUWJMIP-NJFSPNSNSA-N chloro(114C)methane Chemical compound [14CH3]Cl NEHMKBQYUWJMIP-NJFSPNSNSA-N 0.000 description 1
- 238000007796 conventional method Methods 0.000 description 1
- 239000007822 coupling agent Substances 0.000 description 1
- 238000005238 degreasing Methods 0.000 description 1
- 238000007865 diluting Methods 0.000 description 1
- 238000007922 dissolution test Methods 0.000 description 1
- 229920001971 elastomer Polymers 0.000 description 1
- 239000011737 fluorine Substances 0.000 description 1
- 229910052731 fluorine Inorganic materials 0.000 description 1
- 230000004927 fusion Effects 0.000 description 1
- 229930195733 hydrocarbon Natural products 0.000 description 1
- 150000002430 hydrocarbons Chemical class 0.000 description 1
- 238000007654 immersion Methods 0.000 description 1
- 230000001678 irradiating effect Effects 0.000 description 1
- 239000004816 latex Substances 0.000 description 1
- 229920000126 latex Polymers 0.000 description 1
- 238000005339 levitation Methods 0.000 description 1
- 230000007774 longterm Effects 0.000 description 1
- 229910052759 nickel Inorganic materials 0.000 description 1
- 238000005057 refrigeration Methods 0.000 description 1
- 235000011121 sodium hydroxide Nutrition 0.000 description 1
- 239000007921 spray Substances 0.000 description 1
- 238000003860 storage Methods 0.000 description 1
- 239000008261 styrofoam Substances 0.000 description 1
- 239000000758 substrate Substances 0.000 description 1
- 239000012756 surface treatment agent Substances 0.000 description 1
- 238000010998 test method Methods 0.000 description 1
- 239000011701 zinc Substances 0.000 description 1
- 229910052725 zinc Inorganic materials 0.000 description 1
Landscapes
- Paints Or Removers (AREA)
Description
【発明の詳細な説明】 ［産業上の利用分野］ 本発明は変成エポキシ樹脂塗料に関するものである。TECHNICAL FIELD The present invention relates to a modified epoxy resin coating material.
［従来の技術］ 従来から耐久性を求めて各種の塗料が提案されている
が、塩水やガソリン、ケトンあるいは原油、強酸、強ア
ルカリ等の薬品に対し耐久性のある塗料は少なく、しい
て挙げるとすれば、僅かにエポキシ樹脂塗料等を挙げる
ことができる。しかしながら、当該エポキシ樹脂塗料で
あっても、その塗装面は長期の使用に耐えるものではな
かった。また、食品用塗料は、きびしい規格に合格しな
ければ使用できないので、食品用に適した塗料は極めて
限られていた。更にまた、従来のエポキシ樹脂塗料は＋
５度Ｃ以下の温度では硬化が進まないので、特に外部で
使用する場合に冬期には我が国本州北部で使用できなか
った。また−180 度Ｃ程度の超低温に耐える塗料は従来
見出されていなかった。[Prior Art] Various paints have been proposed for durability, but few paints are durable against chemicals such as salt water, gasoline, ketones or crude oil, strong acids, and strong alkalis. If so, epoxy resin paints and the like can be mentioned slightly. However, even with the epoxy resin coating, the coated surface is not durable for long-term use. Further, food paints cannot be used unless they pass strict standards, so paints suitable for foods have been extremely limited. Furthermore, the conventional epoxy resin paint is +
Since the curing does not proceed at a temperature of 5 ° C. or lower, it cannot be used in the northern part of Honshu of Japan, especially when used outside. In addition, no paint has been found that can withstand ultra-low temperatures of about -180 ° C.
本出願人は先に、ステンレス含有エポキシ樹脂塗料（特
願昭59−162872号、特開昭61−42578号）、コンクリー
ト塗装方法（特願昭60−115414号）、電極板（特願昭60
−277937号）、耐薬品性塗膜形成方法（特願昭61−2597
4号）、電極板（特願昭61−79242 号）、耐酸塗膜形成
方法（特願昭61−114683号）等を出願しているが、本発
明はこれら出願に係る発明と関連する発明である。The applicant of the present invention has previously described that a stainless steel-containing epoxy resin coating (Japanese Patent Application No. 59-162872, Japanese Patent Application Laid-Open No. 61-42578), a concrete coating method (Japanese Patent Application No. 60-115414), an electrode plate (Japanese Patent Application No. 60-115414).
-277937), chemical resistant coating film forming method (Japanese Patent Application No. 61-2597)
No. 4), an electrode plate (Japanese Patent Application No. 61-79242), an acid-resistant coating film forming method (Japanese Patent Application No. 61-114683), etc., but the present invention relates to the inventions related to these applications. Is.
［発明が解決しようとする問題点］ 上記のように従来は、塩水やガソリン、ケトンあるいは
原油、強酸、強アルカリ等の薬品に長期間耐えるエポキ
シ樹脂塗料がなかったので、更に耐久性のある塗料が要
望されているという問題点があった。[Problems to be Solved by the Invention] As described above, conventionally, there was no epoxy resin paint capable of withstanding chemicals such as salt water, gasoline, ketones or crude oil, strong acids, strong alkalis for a long time. There was a problem that was requested.
また、従来のエポキシ樹脂塗料は＋５度Ｃ以下の温度で
は硬化が進まないので、特に外部で使用する場合に冬期
には我が国本州北部で使用できないという問題点があっ
た。そして−５度Ｃでも硬化するエポキシ樹脂塗料があ
れば我が国本州北部でも一年中使用可能であるので、こ
のようなエポキシ樹脂塗料が望まれていた。Further, since the conventional epoxy resin paint does not cure at a temperature of + 5 ° C. or less, there is a problem that it cannot be used in the northern part of Honshu of Japan, especially when used outside. Further, if there is an epoxy resin coating that can be cured even at -5 ° C, it can be used all year round in the northern part of Honshu of Japan, and such an epoxy resin coating has been desired.
更にまた、−180 度Ｃ程度の超低温に耐える塗料が望ま
れていた。Furthermore, there has been a demand for a coating that can withstand ultra-low temperatures of about -180 ° C.
本発明はこのような問題点を解決し、塩水やガソリン、
ケトンあるいは原油、強酸、強アルカリ等の薬品に長期
間耐え、しかも食品用として適した変成エポキシ樹脂塗
料を提供することを目的とする。また−５度Ｃでも硬化
し、我が国本州北部でも一年中使用可能であり、また−
180 度Ｃ程度の超低温にも耐える変成エポキシ樹脂塗料
を提供することを目的とする。The present invention solves such problems, salt water, gasoline,
It is an object of the present invention to provide a modified epoxy resin coating which can withstand chemicals such as ketones, crude oil, strong acids and strong alkalis for a long period of time and is suitable for food. It also hardens at -5 ° C and can be used all year round in northern Honshu, Japan.
The purpose is to provide a modified epoxy resin paint that can withstand ultra-low temperatures of about 180 ° C.
［問題点を解決するための手段］ 本発明に係る変成エポキシ樹脂塗料は、上記のような従
来の問題点を解決し、本発明の目的を達成するために、
次のように構成したことを特徴とする。[Means for Solving Problems] The modified epoxy resin coating material according to the present invention solves the above conventional problems and achieves the object of the present invention.
It is characterized by being configured as follows.
すなわち、比表面積1000cm2／g 以上の金属箔片が５〜
４０重量％、塩化ビニリデン系樹脂エマルジョン（固形
分４３〜４７重量％）が０．５〜１０重量％、エポキシ
樹脂塗料（固形分４６〜１００重量％であり、エポキシ
樹脂１００重量部に対し塩化ビニリデン系樹脂を０．３
〜１２重量部含む）が９５〜５０重量％から成ることを
特徴とする。That is, metal foil pieces with a specific surface area of 1000 cm 2 / g or more are 5 to 5
40% by weight, vinylidene chloride resin emulsion (solid content 43 to 47% by weight) 0.5 to 10% by weight, epoxy resin coating (solid content 46 to 100% by weight, vinylidene chloride based on 100 parts by weight of epoxy resin) 0.3-based resin
.About.12 parts by weight) is composed of 95 to 50% by weight.
本発明に係る変成エポキシ樹脂塗料はその 5〜40％を比
表面積1000cm2/g以上の金属箔片が占める。金属箔片と
しては、ステンレス箔片、キュプロニッケル箔片等を挙
げることができ、ステンレスとしてはSUS 316L、 SUS
304L等、キュプロニッケルとしては銅が90〜70％、ニッ
ケルが10〜30％の組成のもの等を挙げることができる。
また箔片の形状としては、例えば、厚さ３ミクロン以
下、幅 100ミクロン以下、長さ 100ミクロン以下の小判
形あるいは葉っぱ形の箔片等を挙げることができ、比表
面積1000cm2/g以上の箔片が良好である。The modified epoxy resin paint according to the present invention occupies 5 to 40% of the metal foil pieces having a specific surface area of 1000 cm 2 / g or more. Examples of metal foil pieces include stainless steel foil pieces and cupronickel foil pieces. Stainless steel includes SUS 316L and SUS.
Examples of cupro nickel, such as 304L, are those having a composition of 90 to 70% copper and 10 to 30% nickel.
The shape of the foil piece may be, for example, an oval or leaf-shaped foil piece having a thickness of 3 μm or less, a width of 100 μm or less, and a length of 100 μm or less, and a specific surface area of 1000 cm 2 / g or more. The foil pieces are good.
これら金属箔片は、金属箔片製造の際に、水や少量のエ
マルジョン、油剤等を添加して製造される場合がある
が、当該油剤等がビヒクルであるエポキシ樹脂に影響を
与えないものであれば油剤等を除去せずにそのまま使用
して差支えない。また、金属箔片の表面を処理して、ビ
ヒクルであるエポキシ樹脂との密着を良好ならしめたも
のでもよい。表面処理剤としては、シランカップリング
剤、チタネートカップリング剤等を挙げることができ
る。These metal foil pieces may be produced by adding water, a small amount of emulsion, an oil agent, or the like at the time of manufacturing the metal foil piece, but the oil agent or the like does not affect the epoxy resin as the vehicle. If there is, you can use it as it is without removing the oil. Alternatively, the surface of the metal foil piece may be treated so as to have good adhesion to the epoxy resin as a vehicle. Examples of the surface treatment agent include silane coupling agents and titanate coupling agents.
比表面積1000cm2/g以下の場合には、箔片が塗料のビヒ
クル中にただ存在するのみで、箔片による塗膜の充分な
耐久効果を挙げることができない。比表面積1000cm2/g
以上の場合には、箔片が塗料のビヒクル中に層状をなし
て存在し、当該層状の箔片によって塗膜の充分な耐久効
果を挙げることができる。また金属箔片が 4％以下の場
合には、金属箔片による効果が充分にあらわれず、金属
箔片が41％以上の場合には、塗装が困難で、充分な塗膜
強度を得ることができない。When the specific surface area is 1000 cm 2 / g or less, the foil pieces are merely present in the vehicle of the paint, and the sufficient effect of durability of the coating film by the foil pieces cannot be achieved. Specific surface area 1000 cm 2 / g
In the above cases, the foil pieces are present in the vehicle of the coating in a layered form, and the layered foil pieces can provide a sufficient durability effect of the coating film. Further, when the metal foil piece is 4% or less, the effect of the metal foil piece is not sufficiently exhibited, and when the metal foil piece is 41% or more, it is difficult to apply the coating, and sufficient coating strength can be obtained. Can not.
本発明に係る変成エポキシ樹脂塗料はその0.5 ％〜10％
を塩化ビニリデン系樹脂エマルジョンが占める。塩化ビ
ニリデン系樹脂エマルジョンとしては、例えば、旭化成
工業株式会社製のサランラテックスＲタイプＬ 321（商
標）を挙げることができる。塩化ビニリデン系樹脂エマ
ルジョンは硬化剤を含まないエポキシ樹脂塗料と混合さ
れる。硬化剤を含まないエポキシ樹脂塗料にはあらかじ
め金属箔片を加えてあってもよい。塩化ビニリデン系樹
脂エマルジョンの添加量が10％を越えると、塩化ビニリ
デン系樹脂エマルジョンとエポキシ樹脂塗料との親和性
が悪くなり、所期の効果を達成することができず、また
添加量が0.5 ％未満では、耐久性の効果が充分でない。
なお、塩化ビニリデン系樹脂エマルジョンの添加量は３
％程度が最も適当である。また、塩化ビニリデン系樹脂
エマルジョンを含有するエポキシ樹脂塗料の溶剤として
は、エポキシシンナーが良好である。なお、本発明に係
る変成エポキシ樹脂塗料から得られた塗膜は、電子顕微
鏡で観察しても、赤外線をあてて観察しても、塩化ビニ
リデン系樹脂の粒が見出せず、エポキシ樹脂と塩化ビニ
リデン系樹脂とは反応しているか、あるいは強固な結合
をしていると考えられる。The modified epoxy resin coating composition according to the present invention is 0.5% to 10%.
Is occupied by vinylidene chloride resin emulsion. Examples of the vinylidene chloride resin emulsion include Saran latex R type L 321 (trademark) manufactured by Asahi Kasei Corporation. The vinylidene chloride resin emulsion is mixed with a curing agent-free epoxy resin coating. A metal foil piece may be added in advance to the epoxy resin paint containing no curing agent. If the amount of vinylidene chloride resin emulsion added exceeds 10%, the affinity between vinylidene chloride resin emulsion and epoxy resin coating deteriorates, and the desired effect cannot be achieved, and the addition amount is 0.5%. If it is less than the above, the effect of durability is not sufficient.
The amount of vinylidene chloride resin emulsion added is 3
% Is the most suitable. Epoxy thinner is a good solvent for the epoxy resin paint containing the vinylidene chloride resin emulsion. Incidentally, the coating film obtained from the modified epoxy resin coating material according to the present invention, when observed by an electron microscope or by irradiating with infrared rays, no vinylidene chloride resin particles are found, and the epoxy resin and vinylidene chloride are not found. It is considered that they are reacting with the system resin or forming a strong bond.
本発明に係る変成エポキシ樹脂塗料はその95〜50％をエ
ポキシ樹脂塗料が占める。エポキシ樹脂塗料としては組
成や硬化剤の異なる各種のエポキシ樹脂塗料が使用可能
である。またエポキシ樹脂塗料はタールを５％乃至30％
含有するタールエポキシ樹脂塗料等であっても差支えな
い。エポキシ樹脂塗料としては例えば大日本塗料株式会
社製造のエポニックス（商標）＃10クリヤー、またター
ルエポキシ樹脂塗料としては大日本塗料株式会社製造の
ＳＤＣコート（商標）＃402 を挙げることができる。The modified epoxy resin paint according to the present invention occupies 95 to 50% of the epoxy resin paint. As the epoxy resin coating material, various epoxy resin coating materials having different compositions and curing agents can be used. In addition, the epoxy resin paint contains 5% to 30% tar.
It does not matter even if it contains tar epoxy resin paint or the like. Examples of the epoxy resin paint include Eponix (trademark) # 10 clear manufactured by Dainippon Paint Co., Ltd., and examples of the tar epoxy resin paint include SDC coat (trademark) # 402 manufactured by Dainippon Paint Co., Ltd.
本発明に係る変成エポキシ樹脂塗料は、使用に当ってエ
ポキシ樹脂塗料の硬化剤を加えて常法により塗装する。
うすめる場合は溶剤としてエポキシシンナーが適してい
る。The modified epoxy resin coating material according to the present invention is applied by a conventional method by adding a curing agent for the epoxy resin coating material before use.
When diluting, epoxy thinner is suitable as a solvent.
［実施例１］ 巾70mm、長さ 150mmの軟鋼板をケトンにより素地調整
し、下塗として市販のエポキシジンクリッチペイントを
塗装し、その上に本発明に係る変成エポキシ樹脂塗料を
塗装して、試験片を作成した。試験片を塩水濃度５％、
500時間噴霧の試験条件で試験した。膜厚はマイクロメ
ーターで実測し平均値を求め値とした。一次密着試験値
は試験前に塗膜引張り試験器（アドヒージョンテスタ
ー）にて測定した値、二次密着試験値は塩水噴霧試験装
置（ JIS Z 2371 に規定する噴霧装置）を用い５００時
間噴霧試験後にアドヒージョンテスターにて測定した値
である。本発明に係る変成エポキシ樹脂塗料は、金属箔
片が15％、塩化ビニリデン系樹脂エマルジョンが３％、
エポキシ樹脂塗料が82％から成る塗料を使用した。[Example 1] A mild steel plate having a width of 70 mm and a length of 150 mm was prepared by using a ketone as a base material, a commercially available epoxy zinc rich paint was applied as a base coat, and the modified epoxy resin paint according to the present invention was applied thereon to conduct a test. Created a piece. 5% salt water concentration,
The test was conducted under the test conditions of spraying for 500 hours. The film thickness was measured by a micrometer, and the average value was calculated. The primary adhesion test value is a value measured by a coating film tensile tester (adhesion tester) before the test, and the secondary adhesion test value is a salt spray tester (spraying device specified in JIS Z 2371) for 500 hours. It is a value measured by an adhesion tester after the test. The modified epoxy resin coating composition according to the present invention comprises 15% metal foil pieces, 3% vinylidene chloride resin emulsion,
A paint consisting of 82% epoxy resin paint was used.
ステンレスSUS 304L、比表面積3800cm2/gの金属箔片を
使用した場合、膜厚 160μ、一次密着28kg/cm2、二次密
着 1kg/cm2で塗膜面は良好であった。When stainless steel SUS 304L and a metal foil piece having a specific surface area of 3800 cm 2 / g were used, the coating surface was good with a film thickness of 160 μ, primary adhesion of 28 kg / cm 2 , and secondary adhesion of 1 kg / cm 2 .
ステンレスSUS 304L、比表面積5750cm2/gの金属箔片を
使用した場合、膜厚 160μ、一次密着25kg/cm2、二次密
着 1〜 2kg/cm2で塗膜面は良好であった。When stainless steel SUS 304L and a metal foil piece having a specific surface area of 5750 cm 2 / g were used, the film thickness was 160 μ, the primary adhesion was 25 kg / cm 2 , and the secondary adhesion was 1 to 2 kg / cm 2 , and the coating surface was good.
ステンレスSUS 316L、比表面積3000〜3500cm2/gの金属
箔片を使用した場合、膜厚 180μ、一次密着28kg/cm2、
二次密着 1〜 4kg/cm2で塗膜面は良好であった。Stainless SUS 316L, when using a metal foil strip having a specific surface area 3000~3500cm 2 / g, a thickness of 180 microns, the primary contact 28 kg / cm 2,
The coating surface was good with a secondary adhesion of 1 to 4 kg / cm 2 .
キュプロニッケル比表面積3140cm2/gの金属箔片を使用
した場合、膜厚 130μ、一次密着30kg/cm2、二次密着 3
kg/cm2で塗膜面は良好であった。Cupronickel with a specific surface area of 3140 cm 2 / g, a film thickness of 130 μ, primary adhesion of 30 kg / cm 2 , secondary adhesion of 3
The coating surface was good at kg / cm 2 .
キュプロニッケル比表面積9250cm2/gの金属箔片を使用
した場合、膜厚 130μ、一次密着20kg/cm2、二次密着 7
〜13kg/cm2で塗膜面は良好であった。Cupronickel with a specific surface area of 9250 cm 2 / g, a film thickness of 130 μ, primary adhesion 20 kg / cm 2 , secondary adhesion 7
The coating surface was good at about 13 kg / cm 2 .
上記に対し、塩化ビニリデン系樹脂エマルジョンを加え
ないで、ステンレスSUS 316L、比表面積3000〜3500cm2/
gの金属箔片をエポキシ樹脂塗料に加えたのみ塗料を使
用した場合、膜厚 180μ、一次密着28kg/cm2、二次密着
1〜 4kg/cm2であったが塗膜面に多数のフクレを生じ、
上記の結果より劣っていた。In contrast to the above, without adding vinylidene chloride resin emulsion, stainless SUS 316L, specific surface area 3000 ~ 3500 cm 2 /
When the coating is used only by adding the metal foil piece of g to the epoxy resin coating, the film thickness is 180μ, the primary adhesion is 28kg / cm 2 , and the secondary adhesion is
Although it was 1 to 4 kg / cm 2 , many blisters were generated on the coating surface,
It was inferior to the above result.
［実施例２］ 基材として、ホットコイル製または熱延鋼板である黒皮
の鉄板を使用した。当該鉄板の表面を脱脂した後、その
面にステンレス含有エポキシ樹脂塗料を塗装して下塗塗
装部を形成した。下塗塗装部の上に、塩化ビニリデン系
樹脂エマルジョンを３％、ステンレスSUS 316L、比表面
積3000〜3500cm2/gの金属箔片を15％、エポキシ樹脂塗
料が82％から成る本発明に係る変成エポキシ樹脂塗料を
塗装した。[Example 2] As a base material, a black skin iron plate made of a hot coil or a hot rolled steel plate was used. After degreasing the surface of the iron plate, a stainless steel-containing epoxy resin paint was applied to the surface to form an undercoat coating part. Modified epoxy resin according to the present invention comprising 3% of vinylidene chloride resin emulsion, 15% of stainless steel 316L, 15% of metal foil piece having a specific surface area of 3000 to 3500 cm 2 / g, and 82% of epoxy resin coating on the undercoating portion. Resin paint was applied.
かくして形成された塗装面は、基板目試験を行なったと
ころ、 100／100 であって良好であった。また、水道水
で１時間煮沸しても全く異常がなかった。更に、煮沸後
碁板目試験を行なったところ、50／100 であり良好であ
った。The coated surface thus formed was 100/100, which was good when a substrate eye test was conducted. In addition, there was no abnormality even after boiling for 1 hour in tap water. Furthermore, when the cross-cut test was conducted after boiling, it was 50/100, which was good.
またメチルエチルケトン（純度99％以上）に25目以上浸
漬しても異常がなかった。ガソリンの場合には60日以
上、原油の場合には６箇月以上浸漬しても異常がなかっ
た。There was no abnormality when immersed in methyl ethyl ketone (purity 99% or more) for 25 or more eyes. There was no abnormality after 60 days or more in the case of gasoline and 6 months or more in the case of crude oil.
［実施例３］ 塩化ビニリデン系樹脂エマルジョンが３％、ステンレス
SUS 316L、比表面積3000〜3500cm2/gの金属箔片を15
％、エポキシ樹脂塗料が82％から成る本発明に係る変成
エポキシ樹脂塗料を使用した。試験方法としては、JWWA
K−115 水道用タールエポキシ樹脂塗料塗装方法の溶解
試験の方法により試験水を作成した。ただし水は水道水
を使用した。[Example 3] 3% vinylidene chloride resin emulsion, stainless steel
SUS 316L, specific surface area 3000 ~ 3500 cm 2 / g of metal foil piece 15
%, And the modified epoxy resin coating material according to the present invention was used in which the epoxy resin coating material was 82%. As a test method, JWWA
Test water was prepared by the dissolution test method of K-115 tar epoxy resin paint coating method for waterworks. However, tap water was used as water.
結果は次の第１表、第２表の通りであり、水道法に基づ
く水質基準（昭和53年厚生省令第56号）に適合し、本発
明に係る変成エポキシ樹脂塗料は食品用として適する。The results are as shown in Tables 1 and 2 below, which meet the water quality standards based on the Water Supply Act (Ministry of Health and Welfare Ordinance No. 56 of 1978), and the modified epoxy resin coating material according to the present invention is suitable for food.
［実施例４］ 塩化ビニリデン系樹脂エマルジョンを３％、ステンレス
SUS 316L、比表面積3000〜3500cm2/gの金属箔片を15
％、エポキシ樹脂塗料が82％から成る本発明に係る変成
エポキシ樹脂塗料を使用した。 Example 4 3% of vinylidene chloride resin emulsion, stainless steel
SUS 316L, specific surface area 3000 ~ 3500 cm 2 / g of metal foil piece 15
%, And the modified epoxy resin coating material according to the present invention was used in which the epoxy resin coating material was 82%.
苛性ソーダ濃度20％、温度50度Ｃの条件で試験したとこ
ろ、40日間全く異常がなかった。また硫酸濃度20％、温
度50度Ｃの条件で試験したところ、４０日間後に部分的
にフクレの発生が認められた。これらの結果は従来の塗
料より優れたものであった。When tested under the conditions of a caustic soda concentration of 20% and a temperature of 50 ° C., there was no abnormality for 40 days. Further, when the test was conducted under the conditions of a sulfuric acid concentration of 20% and a temperature of 50 ° C, partial blistering was observed after 40 days. These results were superior to conventional paints.
［実施例５］ 塩化ビニリデン系樹脂エマルジョンが３％、ステンレス
SUS 316L、比表面積3000〜3500cm2/gの金属箔片を15
％、タールを約25％含有するタールエポキシ樹脂塗料が
82％からなる本発明に係る変成エポキシ樹脂塗料を使用
し、脱脂目荒しした銅板に刷毛で２回塗り試験片とし
た。Example 5 Vinylidene chloride resin emulsion 3%, stainless steel
SUS 316L, specific surface area 3000 ~ 3500 cm 2 / g of metal foil piece 15
%, Tar epoxy resin paint containing about 25% tar
Using the modified epoxy resin coating material of the present invention consisting of 82%, a degreased and roughened copper plate was applied twice with a brush to give a test piece.
かくして形成された塗装面は、碁板目試験を行なったと
ころ、 100／100 であって良好であった。また、水道水
で１時間煮沸したところ色あせするが塗膜は変化がなか
った。更に、煮沸後碁板目試験を行なったところ、 100
／100 であり良好であった。The coated surface thus formed was 100/100, which was good when a cross-cut test was conducted. In addition, when it was boiled in tap water for 1 hour, it faded but the coating film did not change. Furthermore, when a cross-cut test was performed after boiling, 100
It was / 100, which was good.
またメチルエチルケトン（純度99％以上）に25日以上浸
漬しても異常がなかった。ガソリンの場合には60日以
上、原油の場合には６箇月以上浸漬しても異常がなかっ
た。There was no abnormality even when immersed in methyl ethyl ketone (purity 99% or more) for 25 days or more. There was no abnormality after 60 days or more in the case of gasoline and 6 months or more in the case of crude oil.
［実施例６］ 塩化ビニリデン系樹脂エマルジョンを３％、ステンレス
SUS 316L、比表面積3000〜3500cm2/gの金属箔片あるい
はステンレスSUS 304L、比表面積3800cm2/gの金属箔片
を15％、エポキシ樹脂塗料が82％から成る本発明に係る
変成エポキシ樹脂塗料を使用した。なおエポキシ樹脂塗
料としては大日本塗料株式会社製造のエポニックス（商
標）＃10クリヤーを使用し、その硬化剤としてはポリア
ミドアミンを使用した。Example 6 Vinylidene chloride resin emulsion 3%, stainless steel
SUS 316L, a specific surface area 3000~3500cm 2 / g of metal foil pieces or stainless SUS 304L, 15% of the metal foil pieces having a specific surface area of 3800 cm 2 / g, modified epoxy resin coating material according to the present invention that the epoxy resin coating material is made of 82% It was used. Eponics (trademark) # 10 clear manufactured by Dainippon Paint Co., Ltd. was used as the epoxy resin paint, and polyamidoamine was used as the curing agent.
試験は建物の北側で１日中日が当らない風通しのよい場
所で行なった。塗装は刷毛で１回塗りとした。温度は塗
装時−5.5 度Ｃ、３時間後−4.0 度Ｃ、４時間後−3.5
度Ｃ、５時間後−4.0 度Ｃ、８時間後−5.0 度Ｃ、22時
間後−8.5 度Ｃ、24時間後−5.0 度Ｃ、25時間後−3.5
度Ｃ、27時間後−2.0 度Ｃであった。この時点（27時間
後）でいずれも重ね塗りができる程度まで硬化した。The test was carried out on the north side of the building in a well-ventilated place where the sun was not exposed all day. The paint was applied once with a brush. The temperature is −5.5 ° C at the time of painting, −4.0 ° C after 3 hours, −3.5 after 4 hours.
C after 5 hours-4.0 C, after 8 hours-5.0 C, after 22 hours-8.5 C, after 24 hours-5.0 C, after 25 hours-3.5
C was -2.0 C after 27 hours. At this point (after 27 hours), both were cured to the extent that multiple coatings were possible.
比較例としてステンレス金属箔片の代りにニッケル粉末
あるいはクロム粉末あるいは鉄粉末（いずれも40μ以
下）を加えたものを試験したが、いずれも同じ条件では
硬化しなかった。またエポキシ樹脂塗料も同時に試験し
たが、これも同じ条件では硬化しなかった。As a comparative example, a test was conducted by adding nickel powder, chromium powder, or iron powder (each 40 μm or less) in place of the stainless metal foil piece, but none of them cured under the same conditions. An epoxy resin coating was also tested at the same time and it did not cure under the same conditions.
［実施例７］ また実施例６と別の日に、塩化ビニリデン系樹脂エマル
ジョンを３％、ステンレスSUS 316L、比表面積3000〜35
00cm2/gの金属箔片あるいはステンレスSUS 304L、比表
面積3800cm2/gの金属箔片を15％、エポキシ樹脂塗料が8
2％から成る本発明に係る変成エポキシ樹脂塗料を実施
例６と同様の条件で試験した。温度は塗装時−0.5 度
Ｃ、夜中を経て16時間後−0.5 度Ｃであった。この時点
（16時間後）でいずれも重ね塗りができる程度まで硬化
した。[Example 7] On a different day from Example 6, 3% of vinylidene chloride resin emulsion, SUS 316L stainless steel, specific surface area 3000 to 35
00cm 2 / g metal foil piece or stainless SUS 304L, 15% metal foil piece with specific surface area 3800cm 2 / g, 8% epoxy resin paint
A modified epoxy resin coating according to the invention consisting of 2% was tested under the same conditions as in Example 6. The temperature was −0.5 ° C. at the time of coating and −0.5 ° C. after 16 hours through the night. At this point (after 16 hours), both were cured to the extent that multiple coatings were possible.
比較例として上記塗料からステンレス金属箔片を除いた
ものと、上記塗料のステンレス金属箔片の代りにキュプ
ロニッケル金属箔片を加えたものおよびエポキシ樹脂塗
料を同時に試験したが、これらは同じ条件では硬化しな
かった。As a comparative example, the one obtained by removing the stainless metal foil piece from the above paint, the one in which the cupro nickel metal foil piece was added in place of the stainless metal foil piece of the above paint and the epoxy resin paint were simultaneously tested, but under the same conditions. Did not cure.
なお別の試験結果から、ステンレスSUS 316Lの金属箔片
を使用した本発明に係る変成エポキシ樹脂塗料の方がス
テンレスSUS 304Lの金属箔片を使用したものよりも低温
で硬化し易いことが分った。From another test result, it is found that the modified epoxy resin coating material using the metal foil piece of stainless SUS 316L is easier to cure at a lower temperature than the one using the metal foil piece of stainless SUS 304L. It was
［実施例８］ また実施例６、実施例７と別の日に、塩化ビニリデン系
樹脂エマルジョンを３％、ステンレスSUS 316L、比表面
積3000〜3500cm2/gの金属箔片を15％、エポキシ樹脂塗
料が82％から成る本発明に係る変成エポキシ樹脂塗料を
実施例６と同様の条件で試験した。温度は塗装時−6.5
度Ｃ、３時間後−1.5 度Ｃ、５時間後−0.5 度Ｃ、７時
間後−1.5 度Ｃ、夜中を経て24時間後−2.5 度Ｃであっ
た。この時点（24時間後）で重ね塗りができる程度まで
硬化した。[Example 8] On a day different from Examples 6 and 7, 3% vinylidene chloride resin emulsion, 15% stainless steel SUS 316L, a metal foil piece having a specific surface area of 3000 to 3500 cm 2 / g, and an epoxy resin. A modified epoxy resin coating composition according to the present invention comprising 82% coating composition was tested under the same conditions as in Example 6. Temperature is −6.5 during painting
C, 3 hours later -1.5 C, 5 hours later -0.5 C, 7 hours later -1.5 C, and 24 hours later at night -2.5 C. At this point (after 24 hours), it was cured to the extent that multiple coatings were possible.
比較例として上記塗料から塩化ビニリデン系樹脂エマル
ジョンを除いたものを同時に試験したが、これは同じ条
件では硬化しなかった。As a comparative example, the above paint except the vinylidene chloride resin emulsion was tested at the same time, but it did not cure under the same conditions.
［実施例９］ 塩化ビニリデン系樹脂エマルジョンを３％、ステンレス
SUS 316L、比表面積3000〜3500cm2/gの金属箔片あるい
はステンレスSUS 304L、比表面積3800cm2/gの金属箔片
を15％、エポキシ樹脂塗料が82％から成る本発明に係る
変成エポキシ樹脂塗料を使用した。なおエポキシ樹脂塗
料としては大日本塗料株式会社製造のエポニックス（商
標）＃10クリヤーを使用し、その硬化剤としてはポリア
ミドアミンを使用した。テストピースとしては70mm×15
0mm ×1.6 〜2.2mm の鋼板に上記塗料を塗装したものを
使用した。[Example 9] 3% of vinylidene chloride resin emulsion, stainless steel
SUS 316L, a specific surface area 3000~3500cm 2 / g of metal foil pieces or stainless SUS 304L, 15% of the metal foil pieces having a specific surface area of 3800 cm 2 / g, modified epoxy resin coating material according to the present invention that the epoxy resin coating material is made of 82% It was used. Eponics (trademark) # 10 clear manufactured by Dainippon Paint Co., Ltd. was used as the epoxy resin paint, and polyamidoamine was used as the curing agent. 70mm x 15 as a test piece
A 0 mm × 1.6 to 2.2 mm steel plate coated with the above paint was used.
超低温耐久性試験は、厚さ50mmの発泡スチロールの外函
に液体窒素を入れた容器を入れ、この液体窒素にテスト
ピースを入れて一定時間浸漬した後、取り出し点検ハン
マーにて10回強く叩き、塗膜の状態を観察した。液体窒
素内の温度は約−180 度Ｃであった。For the ultra-low temperature durability test, put a container filled with liquid nitrogen in a 50 mm thick Styrofoam outer box, put the test piece in this liquid nitrogen and immerse it for a certain period of time, then tap it with a hammer for inspection 10 times and apply it. The state of the film was observed. The temperature in liquid nitrogen was about -180 ° C.
上記ステンレスSUS 316Lの金属箔片を使用したもの及び
ステンレスSUS 304Lの金属箔片を使用したものは、いず
れも60分間浸漬後強く叩いても塗面が破壊されなかっ
た。本実施例の場合の塗膜の厚さはいずれも200 ミクロ
ンであった。The coated surface was not destroyed in both the case where the metal foil piece of stainless SUS 316L and the case where the metal foil piece of stainless SUS 304L was used were soaked for 60 minutes and struck strongly. In the case of this example, the thickness of each coating film was 200 μm.
これに対し、大日本塗料株式会社製造のエポキシ樹脂塗
料であるエポニックス（商標）＃10クリヤー、タールエ
ポキシ樹脂塗料、耐酸塗料により作成したテストピース
は、いずれも10分間の浸漬後点検ハンマーで叩くと塗面
が破壊された。On the other hand, test pieces made of epoxy resin paint Eponix (trademark) # 10 clear, tar epoxy resin paint, and acid-resistant paint manufactured by Dainippon Paint Co., Ltd. were all dipped for 10 minutes and then hit with an inspection hammer. The paint surface was destroyed.
また、短油性フタル酸樹脂塗料、長油性フタル酸樹脂塗
料、塩化ビニル樹脂塗料、塩化ゴム樹脂塗料、関西ペイ
ント株式会社製造の耐薬品型エポキシ樹脂塗料により作
成したテストピースは、いずれも10分間の浸漬後ペンチ
ではさんで取り出したときに塗面が壊れており点検ハン
マーで叩く必要がなかった。In addition, the test pieces made of short oil phthalic acid resin paint, long oil phthalic acid resin paint, vinyl chloride resin paint, chlorinated rubber resin paint, chemical resistant epoxy resin paint manufactured by Kansai Paint Co., Ltd. After immersion, the paint surface was broken when it was taken out with pliers and it was not necessary to hit it with an inspection hammer.
［発明の効果］ 本発明に係る変成エポキシ樹脂塗料は上記のように構成
されているので、次のような効果を有する。EFFECTS OF THE INVENTION Since the modified epoxy resin coating material according to the present invention is configured as described above, it has the following effects.
第１に、容易に剥離することがなく、塩水やガソリン、
ケトンあるいは原油、強酸、強アルカリ等の薬品に長期
間耐える塗装面を得ることができるという効果を有す
る。First, it does not peel off easily,
It has an effect that it is possible to obtain a coated surface that can withstand a chemical such as a ketone, crude oil, strong acid or strong alkali for a long time.
第２に、水道法に基づく水質基準（昭和53年厚生省令第
56号）に適合し、食品用に適した塗装面を得ることがで
きるという効果を有する。Secondly, water quality standards based on the Water Supply Act (Ministry of Health and Welfare Ordinance 1978
No. 56), and has the effect that a coated surface suitable for food can be obtained.
第３に、−５度Ｃ程度の低温でも24時間程で硬化すると
いう効果を有するので、我が国本州北部でも一年中使用
可能となり、我が国の殆ど全域において使用時期の制限
を心配することなく使用できるという効果を有する。Thirdly, since it has the effect of hardening in about 24 hours even at a low temperature of about -5 ° C, it can be used throughout the year in northern Honshu of Japan, and can be used in almost all areas of Japan without worrying about restrictions on the time of use. It has the effect of being able to.
第４に、−180 度Ｃ程度の超低温にも耐えるという効果
を有するので、現在直ちに、低温冷蔵庫、冷凍機械、あ
るいは冷媒としてアンモニア、メチルクロライド、フッ
ソ系冷媒、LPG 等の炭化水素系冷媒が使用される冷凍用
機器としての圧縮機、凝縮機、蒸発機、受液槽等、更に
これらを製造するプラントからタンカー、タンクローリ
ー、漁船冷凍庫、陸上冷凍庫、シベリア等の極寒地に於
けるパイプライン等に使用でき、また将来は物質の超伝
導を利用する磁気浮上列車、あるいは電力貯蔵、核融
合、粒子加速器等に利用可能であるという効果を有す
る。Fourth, since it has the effect of withstanding ultra-low temperatures of about -180 degrees Celsius, currently, low-temperature refrigerators, refrigerators, or hydrocarbon refrigerants such as ammonia, methyl chloride, fluorine-based refrigerants, and LPG are used as refrigerants. Compressors, condensers, evaporators, liquid receiving tanks, etc. as refrigeration equipment used, and from plants that manufacture these, to tankers, tank trucks, fishing boat freezers, land freezers, pipelines in extreme cold areas such as Siberia It has the effect that it can be used, and in the future, it can be used for magnetic levitation trains that use superconductivity of materials, or for power storage, nuclear fusion, particle accelerators, etc.
このように本発明に係る変成エポキシ樹脂塗料は有用な
塗料である。Thus, the modified epoxy resin paint according to the present invention is a useful paint.
Claims (3)
〜４０重量％、塩化ビニリデン系樹脂エマルジョン（固
形分４３〜４７重量％）が０．５〜１０重量％、エポキ
シ樹脂塗料（固形分４６〜１００重量％であり、エポキ
シ樹脂１００重量部に対し塩化ビニリデン系樹脂を０．
３〜１２重量部含む）が９５〜５０重量％から成る変成
エポキシ樹脂塗料。1. Five pieces of metal foil having a specific surface area of 1000 cm 2 / g or more
-40% by weight, vinylidene chloride resin emulsion (solid content 43 to 47% by weight) is 0.5 to 10% by weight, epoxy resin coating (solid content is 46 to 100% by weight, and chloride based on 100 parts by weight of epoxy resin). Vinylidene-based resin was added to 0.
A modified epoxy resin coating composition containing 95 to 50% by weight (including 3 to 12 parts by weight).
ニッケル箔片である特許請求の範囲第１項記載の変成エ
ポキシ樹脂塗料。2. The modified epoxy resin coating composition according to claim 1, wherein the metal foil pieces are stainless steel foil pieces or cupronickel foil pieces.
料である特許請求の範囲第１項記載の変成エポキシ樹脂
塗料。3. The modified epoxy resin coating composition according to claim 1, wherein the epoxy resin coating composition is a tar epoxy resin coating composition.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP62088747A JPH0613669B2 (en) | 1986-11-12 | 1987-04-13 | Modified epoxy resin paint |
Applications Claiming Priority (4)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP26768886 | 1986-11-12 | ||
| JP62-22480 | 1987-02-04 | ||
| JP61-267688 | 1987-02-04 | ||
| JP62088747A JPH0613669B2 (en) | 1986-11-12 | 1987-04-13 | Modified epoxy resin paint |
Publications (3)
| Publication Number | Publication Date |
|---|---|
| JPH01166A JPH01166A (en) | 1989-01-05 |
| JPS64166A JPS64166A (en) | 1989-01-05 |
| JPH0613669B2 true JPH0613669B2 (en) | 1994-02-23 |
Family
ID=26430098
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP62088747A Expired - Lifetime JPH0613669B2 (en) | 1986-11-12 | 1987-04-13 | Modified epoxy resin paint |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPH0613669B2 (en) |
Families Citing this family (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP4814812B2 (en) * | 2007-02-14 | 2011-11-16 | ステンレスペイント有限会社 | Anti-rust paint |
| JP5909891B2 (en) * | 2010-09-29 | 2016-04-27 | Ｊｆｅスチール株式会社 | High corrosion resistant black skin steel |
| CN104449204A (en) * | 2014-09-16 | 2015-03-25 | 天长市银狐漆业有限公司 | Toughness and elasticity improved epoxy paint and preparation method thereof |
| EP3578606A1 (en) * | 2018-06-06 | 2019-12-11 | Jotun A/S | Particulate coating composition |
Family Cites Families (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS5236198A (en) * | 1975-09-17 | 1977-03-19 | Nichireki Chem Ind Co Ltd | Curable compositions based on modified epoxy resins |
-
1987
- 1987-04-13 JP JP62088747A patent/JPH0613669B2/en not_active Expired - Lifetime
Also Published As
| Publication number | Publication date |
|---|---|
| JPS64166A (en) | 1989-01-05 |
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