JPH0636862B2 - Solubilized composition of oil-soluble substance - Google Patents
Solubilized composition of oil-soluble substanceInfo
- Publication number
- JPH0636862B2 JPH0636862B2 JP60074090A JP7409085A JPH0636862B2 JP H0636862 B2 JPH0636862 B2 JP H0636862B2 JP 60074090 A JP60074090 A JP 60074090A JP 7409085 A JP7409085 A JP 7409085A JP H0636862 B2 JPH0636862 B2 JP H0636862B2
- Authority
- JP
- Japan
- Prior art keywords
- oil
- soluble substance
- acid ester
- solubilized composition
- weight
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
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- Emulsifying, Dispersing, Foam-Producing Or Wetting Agents (AREA)
- General Preparation And Processing Of Foods (AREA)
Description
【発明の詳細な説明】 ［産業上の利用分野］ 本発明は油溶性物質の可溶化組成物に関するものであ
る。更に詳しくは、油溶性物質１〜１５重量％、炭素数
１６〜２２のポリグリセリン不飽和脂肪酸エステル１〜
２５重量％、糖類又は／及び糖アルコール類０〜４０重
量％を残余部の水中に混合攪拌してなる油溶性物質の可
溶化組成物に関するものである。本発明により、透明感
の必要な食品分野において水分の多い系の中に油溶性物
質の添加が可能となるものである。TECHNICAL FIELD The present invention relates to an oil-soluble substance-solubilizing composition. More specifically, 1 to 15% by weight of an oil-soluble substance, polyglycerin unsaturated fatty acid ester having 16 to 22 carbon atoms 1 to
The present invention relates to a solubilized composition of an oil-soluble substance obtained by mixing 25% by weight and 0 to 40% by weight of sugar or / and sugar alcohol in the balance of water. INDUSTRIAL APPLICABILITY According to the present invention, an oil-soluble substance can be added to a system having a high water content in a food field where transparency is required.
［従来の技術］ 油溶性物質を可溶化する方法としては、親水性の高い界
面活性剤を用い、又は／及び親水性溶媒を用いて、高速
回転剪断型撹拌機等の機械による強剪断力を作用させる
方法等がある。[Prior Art] As a method for solubilizing an oil-soluble substance, a strong shearing force by a machine such as a high-speed rotary shearing stirrer is used by using a highly hydrophilic surfactant and / or a hydrophilic solvent. There are ways to make it work.
しかしながら、食品工業分野においては食品衛生法上用
いることのできる界面活性剤、親水性溶媒には制限があ
る。However, in the field of food industry, there are restrictions on the surfactants and hydrophilic solvents that can be used in the Food Sanitation Law.
又、親水性の高い界面活性剤でも現在実用化されている
ものは可溶化力が低く劣っている。食品工業分野への油
溶性物質の可溶化組成物の応用は、ショ糖脂肪酸エステ
ル及び親水性溶媒を用いる方法（特公昭５８−５１７４
４）、キラヤサポニンを用いる（特開昭５９−４８４１
４）等ほんの僅かであり、ほとんど行われていないのが
現状である。Further, even the highly hydrophilic surfactants currently put into practical use have poor solubilizing power and are inferior. The application of the solubilized composition of an oil-soluble substance to the field of food industry is carried out by a method using sucrose fatty acid ester and a hydrophilic solvent (Japanese Patent Publication No. 58-5174).
4), Quillaja saponin is used (Japanese Patent Laid-Open No. 59-4841).
4) There are only a few, and the current situation is that almost nothing is done.
［発明が解決しようとする問題点］ 食品工業分野において、用いることのできる界面活性剤
には制限があり、親水性の高いと言われている界面活性
剤でも可溶化力に関しては効果が劣る。[Problems to be Solved by the Invention] In the food industry, the surfactants that can be used are limited, and even surfactants that are said to have high hydrophilicity are inferior in terms of solubilizing power.
この為に、界面活性剤の配合量は多量となり、可溶化組
成物の添加量によっては界面活性剤の風味が問題とな
る。For this reason, the amount of the surfactant blended becomes large, and the flavor of the surfactant becomes a problem depending on the amount of the solubilizing composition added.
特公昭５８−５１７４４ではショ糖脂肪酸エステルを水
難溶性物質の５倍量以上必要であり、風味の点から添加
量が限定されてしまうという問題点がある。Japanese Examined Patent Publication No. 58-51744 requires a sucrose fatty acid ester in an amount 5 times or more that of a poorly water-soluble substance, and thus has a problem in that the amount added is limited from the viewpoint of flavor.
［問題点を解決する為の手段］ 本発明者等は、これらの問題点を解決する為鋭意研究を
重ねた結果、油溶性物質１〜１５重量％、炭素数１６〜
２２のポリグリセリン不飽和脂肪酸エステル１〜２５重
量％、糖類又は／及び糖アルコール類０〜４０重量％を
残余部の水中に混合攪拌することにより、界面活性剤の
配合量を減少でき風味に問題のない可溶化組成物が得ら
れることを見出し本発明を完成した。更に、極性の強い
油溶性物質の場合、有機溶剤又は／及び油脂に分散させ
たポリグリセリン不飽和脂肪酸エステルのモノエステル
含量の高い不溶部分を使用すると効果の上がることが判
明した。[Means for Solving Problems] The inventors of the present invention have conducted extensive studies to solve these problems, and as a result, 1 to 15% by weight of an oil-soluble substance and 16 to 16 carbon atoms have been obtained.
By mixing and stirring 1 to 25% by weight of polyglycerin unsaturated fatty acid ester 22 and 0 to 40% by weight of sugars and / or sugar alcohols in the balance of water, the compounding amount of the surfactant can be reduced and the flavor problem will occur. The present invention has been completed by the finding that a solubilized composition free of the problem can be obtained. Further, in the case of an oil-soluble substance having a strong polarity, it has been found that the use of an insoluble portion having a high monoester content of polyglycerin unsaturated fatty acid ester dispersed in an organic solvent or / and an oil / fat enhances the effect.
本発明に使用される油溶性物質としては、着色料、着香
料、強化剤、酸化防止剤、保存料、殺菌料および油脂等
が挙げられる。Examples of the oil-soluble substance used in the present invention include a colorant, a flavoring agent, a strengthening agent, an antioxidant, a preservative, a bactericidal agent and fats and oils.
着色料としては例えばβ−カロチン、アナトー色素、ウ
コン色素等、着香料としては例えばメントール、オレオ
レジン等、強化剤としては、ビタミンＡ、カルシフェロ
ール、ビタミンＥ等、酸化防止剤としては例えばミック
ストコフェロール、アスコルビン酸ステアリン酸エステ
ル、γ−オリザノール、天然抽出抗酸化剤等、保存料殺
菌料としては例えばデヒドロ酢酸等、油脂類としては各
種動・植物油脂，中鎖トリグリセリド（ＭＣＴ）等が挙
げられる。Examples of coloring agents include β-carotene, annatto pigments, turmeric pigments, etc., examples of flavoring agents include menthol, oleoresin, etc., enhancers such as vitamin A, calciferol, vitamin E, and antioxidants such as mixed tocopherols. , Ascorbic acid stearic acid ester, γ-oryzanol, natural extract antioxidants, etc., preservative bactericides such as dehydroacetic acid, and oils and fats include various animal and vegetable oils, medium chain triglycerides (MCT) and the like.
油溶性物質の使用量は１〜１５重量％で１重量％以下で
は可溶化できても濃度が低く実用上使用できない。又１
５重量％以上では可溶化できない。The amount of the oil-soluble substance used is 1 to 15% by weight, and if it is 1% by weight or less, the concentration is low even if it can be solubilized and it cannot be practically used. Again 1
If it exceeds 5% by weight, it cannot be solubilized.
本発明に使用されるポリグリセリン不飽和脂肪酸エステ
ルとしては、グリセリン重合度５〜２０、好ましくは６
以上のポリグリセリンに炭素数１６〜２２の不飽和脂肪
酸をエステル化したものでモノエステル、ジエステルの
１種又は２種以上の混合物である。ポリグリセリン飽和
脂肪酸エステルでは油溶性物質の可溶化が出来ない。The polyglycerin unsaturated fatty acid ester used in the present invention has a glycerin polymerization degree of 5 to 20, preferably 6
The above polyglycerin is esterified with an unsaturated fatty acid having 16 to 22 carbon atoms, which is one kind or a mixture of two or more kinds of monoester and diester. Polyglycerin saturated fatty acid ester cannot solubilize oil-soluble substances.
ポリグリセリン不飽和脂肪酸エステルの使用量は１〜２
５重量％であり、油溶性物質に対し等量以上が好ましい
が、２５重量％以上では効果と経済性の面から適当でな
い。The amount of polyglycerin unsaturated fatty acid ester used is 1-2.
It is 5% by weight, which is preferably equal to or more than the amount of the oil-soluble substance, but 25% by weight or more is not suitable from the viewpoint of effect and economy.
又、ビタミンＥのように極性の強い油溶性物質の場合に
は、上記ポリグリセリン不飽和脂肪酸エステルを有機溶
剤又は／及び油脂に分散させ、モノエステル含量の高い
不溶部分を分別、精製して使用することにより、ポリグ
リセリン不飽和脂肪酸エステルの配合量を減少できる。In the case of a highly polar oil-soluble substance such as vitamin E, the polyglycerin unsaturated fatty acid ester is dispersed in an organic solvent or / and oil / fat, and the insoluble portion having a high monoester content is separated and purified before use. By doing so, the blending amount of polyglycerin unsaturated fatty acid ester can be reduced.
本発明で使用される糖類又は／及び糖アルコール類とし
ては、ブドウ糖、ショ糖、果糖、アルドース、乳糖、転
化糖、異性化糖、デキストリン、ソルビトール、グリセ
リンなどが使用できる。As sugars and / or sugar alcohols used in the present invention, glucose, sucrose, fructose, aldose, lactose, invert sugar, isomerized sugar, dextrin, sorbitol, glycerin and the like can be used.
糖類又は／及び糖アルコール類の使用量は０〜４０重量
％であり、糖類又は／及び糖アルコール類を使用しなく
ても可溶化可能であるが、使用したほうが安定性が良く
なる。又、４０重量％以上になると粘度が高くなり実用
上好ましくない。The amount of the saccharide or / and the sugar alcohol used is 0 to 40% by weight, and the saccharide can be solubilized without using the saccharide or / and the sugar alcohol, but the stability is better when it is used. On the other hand, if it exceeds 40% by weight, the viscosity becomes high, which is not preferable in practice.
本発明の油溶性物質の可溶化組成物は次のようにして製
造する。すなわち、ポリグリセリン不飽和脂肪酸エステ
ル、糖類又は／及び糖アルコール類を水に加え４０〜９
０℃に加温して溶解、分散させる。これに加温した油溶
性物質を混合し、ホモミキサー等の攪拌機で攪拌して可
溶化した後、室温まで冷却し油溶性物質の可溶化組成物
が得られる。The solubilized composition of the oil-soluble substance of the present invention is produced as follows. That is, polyglycerin unsaturated fatty acid ester, sugar or / and sugar alcohol are added to water to 40 to 9
Heat to 0 ° C. to dissolve and disperse. A heated oil-soluble substance is mixed with this, and the mixture is stirred with a stirrer such as a homomixer to solubilize it, and then cooled to room temperature to obtain a solubilized composition of the oil-soluble substance.
尚、極性の強い油溶性物質を可溶化する場合、ポリグリ
セリン不飽和脂肪酸エステルを３〜５倍量の有機溶剤又
は／及び油脂に分散し、デカンテーションして不溶部と
可溶部に分け、不溶部を減圧乾燥する。When solubilizing a highly polar oil-soluble substance, polyglycerin unsaturated fatty acid ester is dispersed in 3 to 5 times the amount of organic solvent or / and oil and fat, and decanted to separate the insoluble portion and the soluble portion, The insoluble portion is dried under reduced pressure.
これを水中に加え加温分散させ、これに加温した極性の
強い油溶性物質と混合、さらにホモミキサーで２０分間
攪拌して可溶化物を得る。This is added to water and dispersed by heating, mixed with the heated oil-soluble substance having strong polarity, and further stirred for 20 minutes with a homomixer to obtain a solubilized product.
［発明の効果］ 本発明で得られた油溶性物質の可溶化組成物は、油溶性
物質を水溶液で実質的に透明な状態で用いることが可能
となり、界面活性剤の配合量が少い事から風味も良好で
ある。EFFECTS OF THE INVENTION The solubilizing composition of the oil-soluble substance obtained in the present invention allows the oil-soluble substance to be used in an aqueous solution in a substantially transparent state, and the compounding amount of the surfactant is small. The flavor is also good.
以下実施例によって本発明を説明する。The present invention will be described below with reference to examples.
実施例１ デカグリセリンモノオレイン酸エステル１２ｇ、グリセ
リン２０ｇを水６３ｇに加え、加温溶解分散させ、加温
したｄ−ミックストコフェロール（純度９０％）５ｇを
混合し、ホモミキサーで２０分間攪拌してビタミンＥ可
溶化組成物を得た。Example 1 12 g of decaglycerin monooleate and 20 g of glycerin were added to 63 g of water, dissolved and dispersed by heating, mixed with 5 g of heated d-mix tocopherol (purity 90%), and stirred with a homomixer for 20 minutes. A vitamin E solubilized composition was obtained.
実施例２ デカグリセリンモノリノール酸エステル１２ｇ、マルト
ース１３ｇを水６９ｇに加え、加温溶解分散させ、加温
したｄ−ミックストコフェロール（純度７０％）６ｇを
混合し、ホモミキサーで２０分間攪拌してビタミンＥ可
溶化組成物を得た。Example 2 12 g of decaglycerin monolinoleic acid ester and 13 g of maltose were added to 69 g of water, dissolved by heating and dispersed, and 6 g of heated d-mix tocopherol (purity 70%) was mixed, followed by stirring with a homomixer for 20 minutes. A vitamin E solubilized composition was obtained.
実施例３ デカグリセリンモノリノール酸エステル３０ｇを１５０
ccのアセトンに分散し、デカンテーションして不溶部と
可溶部に分離し、減圧乾燥して得られたアセトン不溶部
８ｇ、ソルビトール３０ｇを水５６ｇ中に加えて、加温
溶解分散させ、加温したｄ−ミックストコフェロール
（純度７０％）６ｇを混合し、ホモミキサーで２０分間
攪拌してビタミンＥ可溶化組成物を得た。Example 3 150 g of decaglycerin monolinoleic acid ester
8 g of acetone-insoluble part and 30 g of sorbitol obtained by dispersing in cc of acetone, decanting to separate into an insoluble part and a soluble part, and drying under reduced pressure were added to 56 g of water to dissolve and disperse under heating. 6 g of warm d-mix tocopherol (purity 70%) was mixed and stirred with a homomixer for 20 minutes to obtain a vitamin E solubilized composition.
実施例４ デカグリセリンモノリノール酸エステル６０ｇを１８０
ccのアセトンに分散し、デカンテーションして不溶部と
可溶部に分離し、減圧乾燥して得られたアセトン不溶部
２４ｇを水５８ｇ中に加え、加温溶解分散させ、加温し
たｄ−ミックストコフェロール（純度７０％）１８ｇを
混合し、ホモミキサーで２０分間攪拌してビタミンＥ可
溶化組成物を得た。Example 4 180 g of 60 g of decaglycerin monolinoleic acid ester
Dispersed in acetone of cc, separated by decantation into an insoluble part and a soluble part, and dried under reduced pressure, 24 g of acetone insoluble part was added to 58 g of water, dissolved by heating and dispersed, and heated d- 18 g of mixed tocopherol (purity 70%) was mixed and stirred with a homomixer for 20 minutes to obtain a vitamin E solubilized composition.
実施例５ デカグリセリンモノリノール酸エステル１０ｇ、グルコ
ース１５ｇを水７０ｇ中に加え、加温溶解分散させ、加
温したｄｌ−α−トコフェロールアセテート５ｇを混合
し、ホモミキサーで２０分間攪拌して、ｄｌ−α−トコ
フェロールアセテート可溶化組成物を得た。Example 5 10 g of decaglycerin monolinoleic acid ester and 15 g of glucose were added to 70 g of water, dissolved by heating and dispersed, and 5 g of heated dl-α-tocopherol acetate was mixed, followed by stirring with a homomixer for 20 minutes, and dl. A -α-tocopherol acetate solubilized composition was obtained.
実施例６ デカグリセリンジリノール酸エステル８ｇ、ショ糖１０
ｇを水７７ｇ中に加え、加温溶解分散させ、加温したビ
タミンＡパルミテート５ｇを混合し、ホモミキサーで２
０分間攪拌して、ビタミンＡパルミテート可溶化組成物
を得た。Example 6 8 g of decaglycerin dilinoleic acid ester, 10 sucrose
g in 77 g of water, dissolved and dispersed by heating, mixed with 5 g of heated vitamin A palmitate, and 2 with a homomixer.
The mixture was stirred for 0 minutes to obtain a vitamin A palmitate solubilized composition.
実施例７ デカグリセリンモノリノール酸エステル１０ｇ、ソルビ
トール２０ｇ、アスコルビン酸ナトリウム0.5ｇを水64.
45ｇ中に加え、加温溶解分散させ、加温したビタミンＡ
パルミテート５ｇ、ｄ−ミックストコフェロール0.05ｇ
を混合し、ホモミキサーで２０分間攪拌して、ビタミン
Ａパルミテート可溶化組成物を得た。Example 7 10 g of decaglycerin monolinoleic acid ester, 20 g of sorbitol, 0.5 g of sodium ascorbate and water 64.
Added to 45g, dissolved and dispersed by heating, heated vitamin A
Palmitate 5g, d-mix tocopherol 0.05g
Were mixed and stirred with a homomixer for 20 minutes to obtain a vitamin A palmitate solubilized composition.
実施例８ ヘキサグリセリンモノオレイン酸エステル８ｇ、ソルビ
トール２０ｇを水６５ｇ中に加え、加温溶解分散させ、
加温した中鎖トリグリセライド７ｇを混合し、ホモミキ
サーで２０分間混合攪拌して、中鎖トリグリセライド可
溶化組成物を得た。Example 8 8 g of hexaglycerin monooleate and 20 g of sorbitol were added to 65 g of water to dissolve and disperse under heating.
7 g of warmed medium chain triglyceride was mixed and mixed and stirred for 20 minutes with a homomixer to obtain a medium chain triglyceride solubilized composition.
実施例９ オクタグリセリンモノオレイン酸エステル１０ｇ、フラ
クトース１５ｇを水６８ｇ中に加え、加温溶解分散さ
せ、加温した大豆油７ｇを混合し、ホモミキサーで２０
分間混合攪拌して、大豆油可溶化組成物を得た。Example 9 10 g of octaglycerin monooleate and 15 g of fructose were added to 68 g of water, dissolved and dispersed by heating, and 7 g of heated soybean oil was mixed, followed by 20 with a homomixer.
The mixture was stirred for 1 minute to obtain a soybean oil-solubilized composition.
実施例１０ デカグリセリンモノリノール酸エステル１０ｇ、グリセ
リン１０ｇを水74.5ｇ中に加え、加温溶解分散させ、加
温したβ−カロチン（純度３０％）５ｇ、アスコルビン
酸ステアリン酸エステル0.5ｇを混合し、ホモミキサー
で２０分間混合攪拌して、β−カロチン可溶化組成物を
得た。Example 10 10 g of decaglycerin monolinoleic acid ester and 10 g of glycerin were added to 74.5 g of water, dissolved by heating and dispersed, and 5 g of heated β-carotene (purity 30%) and 0.5 g of ascorbic acid stearic acid ester were mixed. Then, the mixture was stirred for 20 minutes with a homomixer to obtain a β-carotene solubilized composition.
比較例 ｄ−ミックストコフェロール（純度７０％）１０ｇ、モ
ノエステル９５％含有ショ糖ステアリン酸エステル５０
ｇ、エチルアルコール４０ｇを混合、４０〜６０℃で加
温溶解し均一溶液とした。次に減圧下でエチルアルコー
ルを留去し、乾燥、粉砕して粉末化し、ビタミンＥ製剤
を得た。Comparative Example 10 g of d-mix tocopherol (purity 70%), sucrose stearate 50 containing 95% monoester 50
g and 40 g of ethyl alcohol were mixed and dissolved by heating at 40 to 60 ° C. to obtain a uniform solution. Next, the ethyl alcohol was distilled off under reduced pressure, dried, pulverized and powdered to obtain a vitamin E preparation.
試験例１ 実施例１〜１０の油溶性物質の可溶化組成物１ｇ、及び
比較例のビタミンＥ製剤0.36ｇをｐＨ４のクエン酸溶液
１００mlに溶解分散し、分光光度計波長６００ｎｍで透
過度を測定した結果は次の通りであった。Test Example 1 1 g of the solubilized composition of the oil-soluble substances of Examples 1 to 10 and 0.36 g of the vitamin E preparation of Comparative Example were dissolved and dispersed in 100 ml of a citric acid solution having a pH of 4, and the transmittance was measured at a spectrophotometer wavelength of 600 nm. The results were as follows.
実験区 透過率 実施例 １ ９２．３％ ２ ９２．５％ ３ ９２．６％ ４ ９０．８％ ５ ９６．８％ ６ ９１．０％ ７ ９１．９％ ８ ９４．０％ ９ ９５．１％ １０ ９２．２％ 比較例 ３０．８％ 試験例２ 実施例１〜１０の油溶性物質の可溶化組成物を４０℃の
恒温機中に密栓して保存し、１５日目および３０日目に
実施例１〜１０の油溶性物質の可溶化組成物は１ｇ、比
較例は0.36ｇをとり、ｐＨ４のクエン酸水溶液１００ml
に混合し、６００ｎｍで透過度を測定した結果は次の通
りであった。Experimental Section Transmittance Example 1 92. 3 % 2 92. 5 % 3 92. 6 % 4 90. 8 % 5 96. 8 % 6 91. 0 % 7 91. 9 % 8 94. 0 % 9 95. 1 % 10 92. 2 % Comparative Example 30. 8 % Test Example 2 The solubilized compositions of the oil-soluble substances of Examples 1 to 10 were sealed and stored in a thermostat at 40 ° C., and stored on the 15th and 30th days. 1 g of the solubilized composition of the above and 0.36 g of the comparative example, and 100 ml of an aqueous citric acid solution having a pH of 4
The results of measuring the transmittance at 600 nm were as follows.
０日 １５日 ３０日 実施例１ ９２．３％ ９１．６％ ８９．４％ ２ ９２．５％ ９２．０％ ９０．１％ ３ ９２．６％ ９２．３％ ９１．２％ ４ ９０．８％ ８９．４％ ８８．３％ ５ ９６．８％ ９４．３％ ９２．６％ ６ ９１．０％ ９０．１％ ８９．２％ ７ ９１．９％ ９１．０％ ８８．５％ ８ ９４．０％ ９３．３％ ９２．３％ ９ ９５．１％ ９４．０％ ９２．８％ １０ ９２．２％ ９０．５％ ８９．７％ 比較例 ３０．８％ ２９．９％ ２９．５％ 以上の結果により、本発明の油溶性物質の可溶化組成物
の透明度はｐＨ４の酸性溶液中でも極めて良好であり、
また経時的にもほとんど変化しなかった。Day 0 15 days 30 days Example 1 92. 3 % 91. 6 % 89. 4 % 2 92. 5 % 92. 0 % 90. 1 % 3 92. 6 % 92. 3 % 91. 2 % 4 90. 8 % 89. 4 % 88. 3 % 5 96. 8 % 94. 3 % 92. 6 % 6 91. 0 % 90. 1 % 89. 2 % 7 91. 9 % 91. 0 % 88. 5 % 8 94. 0 % 93. 3 % 92. 3 % 9 95. 1 % 94. 0 % 92. 8 % 10 92. 2 % 90. 5 % 89. 7 % Comparative Example 30. 8 % 29. 9 % 29. From the result of 5 % or more, the transparency of the solubilized composition of the oil-soluble substance of the present invention is extremely good even in an acidic solution of pH 4,
Moreover, it hardly changed with time.
フロントページの続き (56)参考文献 特開 昭59−95847（ＪＰ，Ａ) 特開 昭60−51104（ＪＰ，Ａ)Continuation of front page (56) References JP-A-59-95847 (JP, A) JP-A-60-51104 (JP, A)
Claims (1)
存料、殺菌料又は油脂等の油溶性物質１〜15重量％、ポ
リグリセリンに炭素数16〜22の不飽和脂肪酸をエステル
化したモノエステル及び／又はジエステル１〜25重量
％、糖類又は／及び糖アルコール類０〜40重量％を残余
部の水中に混合撹拌してなる油溶性物質の可溶化組成
物。1. A coloring agent, a flavoring agent, a toughening agent, an antioxidant, a preservative, a bactericidal agent or an oil-soluble substance such as oil or fat 1 to 15% by weight, and polyglycerin with an unsaturated fatty acid having 16 to 22 carbon atoms. A solubilized composition of an oil-soluble substance, which is obtained by mixing 1 to 25% by weight of the converted monoester and / or diester and 0 to 40% by weight of saccharide or / and sugar alcohol in the balance of water and stirring.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP60074090A JPH0636862B2 (en) | 1985-04-08 | 1985-04-08 | Solubilized composition of oil-soluble substance |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP60074090A JPH0636862B2 (en) | 1985-04-08 | 1985-04-08 | Solubilized composition of oil-soluble substance |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPS61234920A JPS61234920A (en) | 1986-10-20 |
| JPH0636862B2 true JPH0636862B2 (en) | 1994-05-18 |
Family
ID=13537130
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP60074090A Expired - Lifetime JPH0636862B2 (en) | 1985-04-08 | 1985-04-08 | Solubilized composition of oil-soluble substance |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPH0636862B2 (en) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2009078245A1 (en) * | 2007-12-19 | 2009-06-25 | Foodtech Trading Co., Ltd. | Transparent emulsified composition and cosmetic and food containing the same |
| KR101508375B1 (en) * | 2007-12-19 | 2015-04-03 | (주)뉴트리 | Transparent emulsified composition and cosmetics or food comprising the same |
Families Citing this family (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2848830B2 (en) * | 1988-09-02 | 1999-01-20 | 旭電化工業株式会社 | Method of solubilizing fatty acid esters that are hardly soluble in water |
| WO2005034913A1 (en) | 2003-10-10 | 2005-04-21 | Eisai Co., Ltd. | Novel liquid preparation composition |
| JP4554981B2 (en) * | 2004-04-28 | 2010-09-29 | 理研ビタミン株式会社 | L-ascorbic acid fatty acid ester-containing composition |
| JP5189519B2 (en) * | 2009-02-06 | 2013-04-24 | 株式会社ヤクルト本社 | Fat-packed vitamin-containing hermetically sealed beverage and method for producing the same |
Family Cites Families (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS5995847A (en) * | 1982-11-25 | 1984-06-02 | Kazuo Matsushita | Preparation of coffee drink |
| JPS6051104A (en) * | 1983-08-30 | 1985-03-22 | Ajinomoto Co Inc | Vitamin e-containing aqueous solution |
-
1985
- 1985-04-08 JP JP60074090A patent/JPH0636862B2/en not_active Expired - Lifetime
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2009078245A1 (en) * | 2007-12-19 | 2009-06-25 | Foodtech Trading Co., Ltd. | Transparent emulsified composition and cosmetic and food containing the same |
| KR101508375B1 (en) * | 2007-12-19 | 2015-04-03 | (주)뉴트리 | Transparent emulsified composition and cosmetics or food comprising the same |
Also Published As
| Publication number | Publication date |
|---|---|
| JPS61234920A (en) | 1986-10-20 |
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