JPH0696507B2 - Hair dye - Google Patents
Hair dyeInfo
- Publication number
- JPH0696507B2 JPH0696507B2 JP755186A JP755186A JPH0696507B2 JP H0696507 B2 JPH0696507 B2 JP H0696507B2 JP 755186 A JP755186 A JP 755186A JP 755186 A JP755186 A JP 755186A JP H0696507 B2 JPH0696507 B2 JP H0696507B2
- Authority
- JP
- Japan
- Prior art keywords
- hair
- dyeing
- dye
- organic solvent
- acid
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 239000000118 hair dye Substances 0.000 title description 23
- 239000003960 organic solvent Substances 0.000 claims description 18
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 15
- 239000000980 acid dye Substances 0.000 claims description 8
- 239000002253 acid Substances 0.000 claims description 5
- -1 and (c) Substances 0.000 claims description 4
- WVDDGKGOMKODPV-ZQBYOMGUSA-N phenyl(114C)methanol Chemical compound O[14CH2]C1=CC=CC=C1 WVDDGKGOMKODPV-ZQBYOMGUSA-N 0.000 claims description 3
- POAOYUHQDCAZBD-UHFFFAOYSA-N 2-butoxyethanol Chemical compound CCCCOCCO POAOYUHQDCAZBD-UHFFFAOYSA-N 0.000 claims description 2
- QCDWFXQBSFUVSP-UHFFFAOYSA-N 2-phenoxyethanol Chemical compound OCCOC1=CC=CC=C1 QCDWFXQBSFUVSP-UHFFFAOYSA-N 0.000 claims description 2
- WRMNZCZEMHIOCP-UHFFFAOYSA-N 2-phenylethanol Chemical compound OCCC1=CC=CC=C1 WRMNZCZEMHIOCP-UHFFFAOYSA-N 0.000 claims description 2
- MSHFRERJPWKJFX-UHFFFAOYSA-N 4-Methoxybenzyl alcohol Chemical compound COC1=CC=C(CO)C=C1 MSHFRERJPWKJFX-UHFFFAOYSA-N 0.000 claims description 2
- 229920003171 Poly (ethylene oxide) Polymers 0.000 claims description 2
- 239000004372 Polyvinyl alcohol Substances 0.000 claims description 2
- HDSBZMRLPLPFLQ-UHFFFAOYSA-N Propylene glycol alginate Chemical compound OC1C(O)C(OC)OC(C(O)=O)C1OC1C(O)C(O)C(C)C(C(=O)OCC(C)O)O1 HDSBZMRLPLPFLQ-UHFFFAOYSA-N 0.000 claims description 2
- 239000004373 Pullulan Substances 0.000 claims description 2
- 229920001218 Pullulan Polymers 0.000 claims description 2
- LHGVFZTZFXWLCP-UHFFFAOYSA-N guaiacol Chemical compound COC1=CC=CC=C1O LHGVFZTZFXWLCP-UHFFFAOYSA-N 0.000 claims description 2
- 235000010987 pectin Nutrition 0.000 claims description 2
- 239000001814 pectin Substances 0.000 claims description 2
- 229920001277 pectin Polymers 0.000 claims description 2
- 229960005323 phenoxyethanol Drugs 0.000 claims description 2
- 229940067107 phenylethyl alcohol Drugs 0.000 claims description 2
- 229920002451 polyvinyl alcohol Polymers 0.000 claims description 2
- 235000019422 polyvinyl alcohol Nutrition 0.000 claims description 2
- 239000001267 polyvinylpyrrolidone Substances 0.000 claims description 2
- 229920000036 polyvinylpyrrolidone Polymers 0.000 claims description 2
- 235000013855 polyvinylpyrrolidone Nutrition 0.000 claims description 2
- 239000000770 propane-1,2-diol alginate Substances 0.000 claims description 2
- 235000010409 propane-1,2-diol alginate Nutrition 0.000 claims description 2
- 235000019423 pullulan Nutrition 0.000 claims description 2
- 238000004043 dyeing Methods 0.000 description 45
- 230000000694 effects Effects 0.000 description 9
- 239000000975 dye Substances 0.000 description 7
- 238000002156 mixing Methods 0.000 description 7
- 150000001875 compounds Chemical class 0.000 description 6
- 239000000203 mixture Substances 0.000 description 6
- 229920000642 polymer Polymers 0.000 description 6
- 230000000052 comparative effect Effects 0.000 description 5
- 239000004615 ingredient Substances 0.000 description 4
- 238000000034 method Methods 0.000 description 4
- 239000000243 solution Substances 0.000 description 4
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 description 3
- MUBZPKHOEPUJKR-UHFFFAOYSA-N Oxalic acid Chemical compound OC(=O)C(O)=O MUBZPKHOEPUJKR-UHFFFAOYSA-N 0.000 description 3
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 description 3
- 238000013329 compounding Methods 0.000 description 3
- 239000000126 substance Substances 0.000 description 3
- 238000005406 washing Methods 0.000 description 3
- PWMWNFMRSKOCEY-UHFFFAOYSA-N 1-Phenyl-1,2-ethanediol Chemical compound OCC(O)C1=CC=CC=C1 PWMWNFMRSKOCEY-UHFFFAOYSA-N 0.000 description 2
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 2
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 2
- MHAJPDPJQMAIIY-UHFFFAOYSA-N Hydrogen peroxide Chemical compound OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 description 2
- LRHPLDYGYMQRHN-UHFFFAOYSA-N N-Butanol Chemical compound CCCCO LRHPLDYGYMQRHN-UHFFFAOYSA-N 0.000 description 2
- SJEYSFABYSGQBG-UHFFFAOYSA-M Patent blue Chemical compound [Na+].C1=CC(N(CC)CC)=CC=C1C(C=1C(=CC(=CC=1)S([O-])(=O)=O)S([O-])(=O)=O)=C1C=CC(=[N+](CC)CC)C=C1 SJEYSFABYSGQBG-UHFFFAOYSA-M 0.000 description 2
- NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 description 2
- SMWDFEZZVXVKRB-UHFFFAOYSA-N Quinoline Chemical compound N1=CC=CC2=CC=CC=C21 SMWDFEZZVXVKRB-UHFFFAOYSA-N 0.000 description 2
- 238000005562 fading Methods 0.000 description 2
- 239000002994 raw material Substances 0.000 description 2
- 229920002134 Carboxymethyl cellulose Polymers 0.000 description 1
- 206010040880 Skin irritation Diseases 0.000 description 1
- DBMJMQXJHONAFJ-UHFFFAOYSA-M Sodium laurylsulphate Chemical compound [Na+].CCCCCCCCCCCCOS([O-])(=O)=O DBMJMQXJHONAFJ-UHFFFAOYSA-M 0.000 description 1
- FEWJPZIEWOKRBE-UHFFFAOYSA-N Tartaric acid Natural products [H+].[H+].[O-]C(=O)C(O)C(O)C([O-])=O FEWJPZIEWOKRBE-UHFFFAOYSA-N 0.000 description 1
- 230000002378 acidificating effect Effects 0.000 description 1
- 229910000147 aluminium phosphate Inorganic materials 0.000 description 1
- 239000001000 anthraquinone dye Substances 0.000 description 1
- 239000007864 aqueous solution Substances 0.000 description 1
- 239000000987 azo dye Substances 0.000 description 1
- 239000001768 carboxy methyl cellulose Substances 0.000 description 1
- 235000010948 carboxy methyl cellulose Nutrition 0.000 description 1
- 239000008112 carboxymethyl-cellulose Substances 0.000 description 1
- 239000001913 cellulose Substances 0.000 description 1
- 229920006184 cellulose methylcellulose Polymers 0.000 description 1
- 239000002738 chelating agent Substances 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 230000002950 deficient Effects 0.000 description 1
- 230000003111 delayed effect Effects 0.000 description 1
- 239000010419 fine particle Substances 0.000 description 1
- 239000003205 fragrance Substances 0.000 description 1
- 230000003700 hair damage Effects 0.000 description 1
- 230000001771 impaired effect Effects 0.000 description 1
- 230000003340 mental effect Effects 0.000 description 1
- 150000007522 mineralic acids Chemical class 0.000 description 1
- 239000001005 nitro dye Substances 0.000 description 1
- 239000001006 nitroso dye Substances 0.000 description 1
- 150000007524 organic acids Chemical class 0.000 description 1
- 235000005985 organic acids Nutrition 0.000 description 1
- 235000006408 oxalic acid Nutrition 0.000 description 1
- 230000001590 oxidative effect Effects 0.000 description 1
- 238000010979 pH adjustment Methods 0.000 description 1
- 238000006116 polymerization reaction Methods 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 239000003755 preservative agent Substances 0.000 description 1
- 230000002335 preservative effect Effects 0.000 description 1
- 210000004761 scalp Anatomy 0.000 description 1
- 238000004904 shortening Methods 0.000 description 1
- 230000036556 skin irritation Effects 0.000 description 1
- 231100000475 skin irritation Toxicity 0.000 description 1
- 235000019333 sodium laurylsulphate Nutrition 0.000 description 1
- 230000003068 static effect Effects 0.000 description 1
- 238000003756 stirring Methods 0.000 description 1
- 235000002906 tartaric acid Nutrition 0.000 description 1
- 239000011975 tartaric acid Substances 0.000 description 1
- 238000010998 test method Methods 0.000 description 1
- AAAQKTZKLRYKHR-UHFFFAOYSA-N triphenylmethane Chemical compound C1=CC=CC=C1C(C=1C=CC=CC=1)C1=CC=CC=C1 AAAQKTZKLRYKHR-UHFFFAOYSA-N 0.000 description 1
- 239000001018 xanthene dye Substances 0.000 description 1
Landscapes
- Cosmetics (AREA)
Description
【発明の詳細な説明】 （技術分野） 本発明は、染色堅牢性に優れ、短時間にかつ均一に染毛
し得る染毛剤に関する。TECHNICAL FIELD The present invention relates to a hair dye having excellent dyeing fastness and capable of uniformly dyeing hair in a short time.
（従来技術） 従来、汎用されている酸化染毛剤は、施術時、アルカリ
性下に過酸化水素を作用させるために、扱い方によって
は毛髪損傷や一次皮膚刺激を示す危険性がある。このた
め酸性染料を用いた頭皮，頭髪に対して影響の少ない染
毛剤が開発されてきた。しかしながら現在、市販されて
いる酸性染料を使用した染毛剤は、染着性や洗髪時の染
色堅牢性などが低い欠点があった。(Prior Art) Conventionally used oxidative hair dyes have a risk of causing hair damage or primary skin irritation depending on how they are handled, because hydrogen peroxide acts under alkaline conditions during treatment. Therefore, hair dyes that use acid dyes and have little effect on the scalp and hair have been developed. However, currently, hair dyes using commercially available acid dyes have the drawback of low dyeing properties and dyeing fastness during washing.
従来、毛髪を酸性染料で染色する場合は、染毛が完了す
るまで約30〜50分の長時間を必要としていた。この間、
被施術者は、染液が周囲へ飛び散らないようにできるだ
け不動静座の状態を保持しなければならず、その精神
的，肉体的負担は、はかり知れないものがある。従っ
て、頭髪染色の所要時間を少しでも短縮できれば、被施
術者にとって安楽これ以上のものはなく、その改良が需
要者等をして広く要望されている。In the past, when dyeing hair with an acid dye, it took about 30 to 50 minutes to complete the dyeing. During this time,
The subject must maintain the state of immovable and static seat as much as possible so that the dye solution does not scatter to the surroundings, and the mental and physical burden thereof is immeasurable. Therefore, if the time required for hair dyeing can be shortened as much as possible, there is nothing more comfortable for the person to be treated, and improvement thereof is widely demanded by consumers and the like.
尚、染毛所要時間を短縮する方法として、染毛処理温度
を高くする方法（染毛する間、頭髪部をキャップ等によ
り覆い、所要の染毛温度を永く保持すること。）や染毛
促進剤（例えば、スチレングリコール）の添加併用が知
られているが、前者の方法では非常に手間がかかり、し
かも効果が少ない等で実用性に乏しく、又後者の方法で
は、未だ充分な効果が得られていない。In addition, as a method of shortening the time required for hair dyeing, a method of increasing the hair dyeing treatment temperature (cover the hair with a cap or the like while dyeing hair to keep the hair dyeing temperature required for a long time) and promote hair dyeing. It is known to add and use an agent (for example, styrene glycol), but the former method is very time-consuming and less effective, resulting in poor practicality. The latter method still produces sufficient effect. Has not been done.
（発明の開示） そこで、本発明者は、前記の問題点に鑑み鋭意研究した
結果、後記特定の有機溶剤と高分子化合物の各々の少く
とも１つを水中に均一に分散或いは溶解し、更に酸性染
料と酸とを配合し、しかも、有機溶剤と水との配合重量
比が5:95〜80:20である染毛剤は、染色堅牢性に優れ、
短時間に、かつ均一に染毛し得ることを見出し本発明を
完成した。DISCLOSURE OF THE INVENTION Therefore, as a result of intensive studies in view of the above problems, the present inventor uniformly dispersed or dissolved at least one of a specific organic solvent and a polymer compound described below in water, and A hair dye that contains an acid dye and an acid, and the compounding weight ratio of the organic solvent and water is 5:95 to 80:20 is excellent in dyeing fastness,
The present invention has been completed by finding that hair can be dyed uniformly in a short time.
（発明の目的） 本発明の目的は、染色堅牢性に優れ、短時間に、かつ均
一に染毛し得る染毛剤を提供することである。(Object of the Invention) An object of the present invention is to provide a hair dye having excellent dyeing fastness and capable of uniformly dyeing hair in a short time.
（発明の構成） すなわち、本発明は、（イ）、ベンジルアルコール、Ｉ
−ブタノール、Ｉ−フェニルエチルアルコール、２−フ
ェニルエチルアルコール、アニスアルコール、エチレン
グリコールモノフェニルエーテル、エチレングリコール
モノブチルエーテル、Ｏ−メトキシフェノールからなる
群から選択された少くとも１つの有機溶剤と、（ロ）、
プルラン、ペクチン、アルギン酸プロピレングリコー
ル、ポリビニルアルコール、ポリビニルピロリドン、ポ
リエチレンオキサイドからなる群から選択された少くと
も１つの高分子化合物と、（ハ）、酸性染料と、
（ニ）、酸と、（ホ）、水とからなり、そして前記有機
溶剤と水との重量比が5:95〜80:20であることを特徴と
する染毛剤である。(Structure of Invention) That is, the present invention provides (a), benzyl alcohol, I
At least one organic solvent selected from the group consisting of butanol, I-phenylethyl alcohol, 2-phenylethyl alcohol, anis alcohol, ethylene glycol monophenyl ether, ethylene glycol monobutyl ether, O-methoxyphenol; ),
At least one polymer compound selected from the group consisting of pullulan, pectin, propylene glycol alginate, polyvinyl alcohol, polyvinylpyrrolidone, and polyethylene oxide; (c) an acid dye;
A hair dye comprising (d), an acid, (e), and water, and the weight ratio of the organic solvent to water is 5:95 to 80:20.
（構成の具体的な説明） 本発明で説明する前記有機溶剤は公知の物質であり、こ
の有機溶剤の適度な水との親和性及び水中分散性は、本
発明の染毛剤に於いて、後述の酸性染料の染毛効果、染
色堅牢度を著しく向上するものである。(Detailed Description of Configuration) The organic solvent described in the present invention is a known substance, and the proper affinity and dispersibility in water of this organic solvent in the hair dye of the present invention are: It significantly improves the hair dyeing effect and dyeing fastness of the acid dye described below.
有機溶剤の配合量、単独または二種以上の合計量で組成
物の総量を基準として2.5〜80重量％（以下、wt％と略
記する）である。また、水との配合重量比は、有機溶
剤：＝5:95〜80:20であり、好ましくは10:90〜60:40の
範囲である。The amount of the organic solvent is 2.5 to 80% by weight (hereinafter abbreviated as wt%) based on the total amount of the composition, either alone or as a total amount of two or more kinds. Further, the blending weight ratio with water is organic solvent: = 5: 95 to 80:20, preferably 10:90 to 60:40.
有機溶剤の配合量が上記の特定する配合量以外である場
合、後述の染毛完了時間は著しく遅くなり、染色所要時
間を短縮する事ができず、染色堅牢度も著しく低下する
ため、好ましくない。When the blending amount of the organic solvent is other than the above-mentioned blending amount, the hair dyeing completion time described below is significantly delayed, the dyeing required time cannot be shortened, and the dyeing fastness is also significantly reduced, which is not preferable. .
高分子化合物は公知の物質であり、第１表に記載のもの
が適用され、本発明の染毛剤に於いて、水中に均一に溶
解して前記有機溶剤を微小粒子として安定に分散せしめ
ることに優れている。The polymer compound is a known substance, and those listed in Table 1 are applied. In the hair dye of the present invention, the organic solvent is uniformly dissolved in water to stably disperse the organic solvent as fine particles. Is excellent.
高分子化合物の配合量は、単独または二種以上の合計量
で、0.5〜20wt％（総量基準）であり、0.5wt％未満では
前記有機溶剤を安定に均一分散することが困難となり、
また、20wt％を超えては、染毛剤の粘度が高くなり染毛
作業が容易でなく、染毛効果、染色堅牢度を低減せしめ
る。The blending amount of the polymer compound, alone or in a total amount of two or more kinds, is 0.5 to 20 wt% (based on the total amount), and if it is less than 0.5 wt%, it becomes difficult to stably and uniformly disperse the organic solvent,
On the other hand, if it exceeds 20% by weight, the viscosity of the hair dye becomes so high that the hair dyeing work is not easy, and the hair dyeing effect and dyeing fastness are reduced.
本発明で使用する酸性染料は、公知のタール色素であ
り、化学構造から大別すると、ニトロ染料、アゾ染料、
ニトロソ染料、トリフェニルメタン染料、キサンテン染
料、キノリン染料、アントラキノン染料、インジゴイド
染料などが挙げられる。 The acidic dye used in the present invention is a known tar dye, and when roughly classified from the chemical structure, a nitro dye, an azo dye,
Examples include nitroso dyes, triphenylmethane dyes, xanthene dyes, quinoline dyes, anthraquinone dyes and indigoid dyes.
酸性染料の配合量は、通常0.01〜20wt％（総量基準）で
ある。The amount of the acid dye compounded is usually 0.01 to 20 wt% (based on the total amount).
本発明のpH調整に使用する酸としては、例えば酒石酸、
酢酸、クエン酸、修酸等の有機酸及びリン酸、塩酸等の
無機酸などが挙げられるが、特にこれらに限るものでは
ない。酸の配合量は、組成物のpHが1.2〜4.0に調整する
にたる必要量である。Examples of the acid used for pH adjustment of the present invention include tartaric acid,
Examples thereof include organic acids such as acetic acid, citric acid and oxalic acid, and inorganic acids such as phosphoric acid and hydrochloric acid, but are not particularly limited thereto. The amount of the acid compounded is the amount necessary to adjust the pH of the composition to 1.2 to 4.0.
本発明に使用する水の配合量は、11.0〜95.0wt％（総量
基準）であればよい。The amount of water used in the present invention may be 11.0 to 95.0 wt% (based on the total amount).
また、本発明の染毛剤は、系の安定性、pH値を損わない
範囲であれば、上記の必須成分の他に防腐剤、キレート
剤、香料などを配合する事も可能である。In addition, the hair dye of the present invention may contain a preservative, a chelating agent, a fragrance and the like in addition to the above-mentioned essential components as long as the stability of the system and the pH value are not impaired.
（実施例） 以下実施例によって、本発明を更に詳細に説明する。
尚、実施例に示した染毛完了時間（染着速度）、染毛効
果、染色堅牢度の試験法は下記の通りである。(Examples) The present invention will be described in more detail with reference to Examples below.
In addition, the test methods for the hair dyeing completion time (dying speed), hair dyeing effect, and dyeing fastness shown in the examples are as follows.
（１）染色完了時間（染着速度）試験 毛束（白色毛髪の束）2gを、試料染液（30℃）の中に浸
漬して、該染液を毛髪に含浸した後、30℃の恒温室内に
放置し、所定時間毎に取出して、水洗し、風乾する。こ
の染毛束について高速色差計（村上色材（株）製CMS-10
00型）を用いて測色を行ない、染毛束のX,Y,Z値をハン
ター（Hunter）のL,a,b表色系へ変換し、下記の式より
染色前の白毛束との色差（ΔＥ）を測定し、色差がほぼ
一定となった時点（色差の変曲点）を染毛完了時間とし
た。表示した数値の小さい程（染色完了時間（分）の短
かい程）、毛髪の染色速度が早いことを意味する。(1) Dyeing completion time (dyeing speed) test 2 g of a hair bundle (bundle of white hair) was immersed in a sample dyeing solution (30 ° C.) to impregnate the hair with the dyeing solution, and then at 30 ° C. It is left in a temperature-controlled room, taken out at regular intervals, washed with water, and air-dried. High-speed color difference meter (CMS-10 manufactured by Murakami Color Materials Co., Ltd.)
(00 type) is used to convert the X, Y, Z values of the dyed hair bundle into the L, a, b color system of Hunter, and the white hair bundle before dyeing is converted from the following formula. The color difference (ΔE) was measured, and the time when the color difference became almost constant (the inflection point of the color difference) was taken as the hair dyeing completion time. The smaller the displayed numerical value (the shorter the dyeing completion time (minute)), the faster the dyeing speed of hair.
（２）染毛効果試験 専門検査員３人によって染色した毛髪を肉眼観察し、均
染性（均一に染色されているか）および染着性（染色の
濃淡）を調べた。 (2) Hair dyeing effect test The hair dyed by three expert inspectors was visually inspected, and the level dyeing property (whether or not it was dyed uniformly) and the dyeing property (shading of dyeing) were examined.
（３）染色堅牢度（洗髪堅牢性）試験 前記（１）の染毛完了時間試験のところで得られた染色
した毛髪をラウリル硫酸ナトリウムの５％水溶液（30
℃）の中に浸漬して、10回の手もみ洗いを行なった後、
水洗し、風乾した。これを１回として、20回繰り返した
後、下記の式より洗髪試験後の褪色率を求めた。(3) Dyeing fastness (washing fastness) test The dyed hair obtained in the hair dyeing completion time test of (1) above was treated with a 5% aqueous solution of sodium lauryl sulfate (30%).
℃), and after hand-washing 10 times,
It was washed with water and air dried. After repeating this 20 times, the fading rate after the hair wash test was calculated from the following formula.
褪色率20％までを「良好」、21〜50％未満を「不良」、
50％以上を「著しく不良」として表わした。 A fading rate of up to 20% is "good", 21 to less than 50% is "poor",
50% or more was expressed as "remarkably defective".
比較例１〜2,実施例１〜６ 下記の原料組成に於いて、有機溶剤及び高分子化合物の
種類と配合量、水の配合量を第２表に記載の通りに配合
して、各々の染毛剤を調製し、前記諸試験より得た特性
を第２表右欄に記載した。Comparative Examples 1-2, Examples 1-6 In the following raw material compositions, the types and blending amounts of the organic solvent and the polymer compound, and the blending amount of water were blended as shown in Table 2, The hair dye was prepared and the properties obtained from the above-mentioned tests are shown in the right column of Table 2.
（１）組成 （２）調製法 成分に成分を均一に溶解し、この溶液の中に成分
，，を順次添加して、均一に撹拌混合して各々の
染毛剤を調製した。得られた染毛剤のpH値3.0〜3.5の範
囲を示した。(1) Composition (2) Preparation method Each of the hair dyes was prepared by uniformly dissolving the ingredients in the ingredients, adding the ingredients in this solution in order, and stirring and mixing the ingredients uniformly. The pH value of the obtained hair dye was in the range of 3.0 to 3.5.
（３）特性 第２表右欄に示すごとく、比較例1,2の有機溶剤である
ベンジルアルコールと水との配合重量比率が5:95〜80:2
0の本発明の特定する範囲以外の染毛剤では、染毛完了
時間は長時間を要し、染毛効果、染色堅牢度も良好な結
果が得られなかった。(3) Properties As shown in the right column of Table 2, the compounding weight ratio of benzyl alcohol, which is the organic solvent of Comparative Examples 1 and 2, and water is 5:95 to 80: 2.
With hair dyes outside the range specified by No. 0 of the present invention, it took a long time to complete the hair dyeing, and the hair dyeing effect and dyeing fastness were not satisfactory.
実施例１〜６の本発明の染毛剤は、有機溶剤と水との配
合重合比率が5:95〜80:20であり、諸試験に於いて良好
なる特性が明らかに認められた。In the hair dyes of the present invention of Examples 1 to 6, the compounding polymerization ratio of the organic solvent and water was 5:95 to 80:20, and good characteristics were clearly recognized in various tests.
比較例３〜6,実施例７〜17 下記の原料組成に於いて、前記実施例１と同様にして、
各々の染毛剤を調製し、諸試験を行った。Comparative Examples 3 to 6, Examples 7 to 17 In the following raw material compositions, in the same manner as in Example 1,
Each hair dye was prepared and various tests were conducted.
尚、得られた各々の染毛剤のpH値は2.5〜3.0の範囲であ
った。The pH value of each obtained hair dye was in the range of 2.5 to 3.0.
（１）組成 （２）特性 第３表に示すごとく比較例3,4の本発明に係る有機溶剤
以外のエタノール、スチレングリコールを用いた染毛
剤、及び、比較例5,6の本発明に係る高分子化合物以外
のビトロキシエチルセルローズ、カルボキシメチルセル
ローズを用いた染毛剤は、諸試験に於いて良好な結果が
得られなかった。(1) Composition (2) Properties As shown in Table 3, hair dyes using ethanol and styrene glycol other than the organic solvent according to the present invention in Comparative Examples 3 and 4, and polymer compounds according to the present invention in Comparative Examples 5 and 6 Other than the above, hair dyes using vitroxyethyl cellulose and carboxymethyl cellulose did not give good results in various tests.
実施例７〜17の本発明の染毛剤は諸試験のすべてに亘っ
て良好なる特性を示した。The inventive hair dyes of Examples 7 to 17 showed good properties over all the tests.
（発明の効果） 上記の如く、本発明の染毛剤は毛髪を短時間でかつ均一
に染着して、染色所要時間を短縮し、しかも、染色堅牢
度を向上し得るものであり、その作用効果は著しく、商
品価値は極めて高い。 (Effects of the Invention) As described above, the hair dye of the present invention can dye the hair uniformly in a short time, shorten the dyeing time, and improve the dyeing fastness. The effects are remarkable, and the commercial value is extremely high.
Claims (1)
ール、Ｉ−フェニルエチルアルコール、２−フェニルエ
チルアルコール、アニスアルコール、エチレングリコー
ルモノフェニルエーテル、エチレングリコールモノブチ
ルエーテル、Ｏ−メトキシフェノールからなる群から選
択された少くとも１つの有機溶剤と、（ロ）、プルラ
ン、ペクチン、アルギン酸プロピレングリコール、ポリ
ビニルアルコール、ポリビニルピロリドン、ポリエチレ
ンオキサイドからなる群から選択された少くとも１つの
高分子化合物と、（ハ）、酸性染料と、（ニ）、酸と、
（ホ）、水とからなり、そして前記有機溶剤と水との重
量比が5:95〜80:20であることを特徴とする染毛剤。1. A group consisting of (a), benzyl alcohol, I-butanol, I-phenylethyl alcohol, 2-phenylethyl alcohol, anise alcohol, ethylene glycol monophenyl ether, ethylene glycol monobutyl ether, and O-methoxyphenol. (B) at least one organic solvent selected from (b), pullulan, pectin, propylene glycol alginate, polyvinyl alcohol, polyvinylpyrrolidone, and polyethylene oxide, and (c) , Acid dye, (d), acid,
(E), water, and the weight ratio of the organic solvent to water is 5:95 to 80:20.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP755186A JPH0696507B2 (en) | 1986-01-16 | 1986-01-16 | Hair dye |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP755186A JPH0696507B2 (en) | 1986-01-16 | 1986-01-16 | Hair dye |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPS62164612A JPS62164612A (en) | 1987-07-21 |
| JPH0696507B2 true JPH0696507B2 (en) | 1994-11-30 |
Family
ID=11668931
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP755186A Expired - Lifetime JPH0696507B2 (en) | 1986-01-16 | 1986-01-16 | Hair dye |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPH0696507B2 (en) |
Families Citing this family (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH01279819A (en) * | 1988-01-18 | 1989-11-10 | Hoyu Co Ltd | Hair dye composition |
| JP2571490B2 (en) * | 1991-02-15 | 1997-01-16 | 株式会社資生堂 | Acid hair coloring composition for hair |
| JP3424086B2 (en) * | 1994-12-29 | 2003-07-07 | 株式会社コーセー | Hair dye composition |
| JP3638490B2 (en) * | 2000-01-07 | 2005-04-13 | 花王株式会社 | Treatment composition for dyeing hair |
| US6506374B1 (en) * | 2000-05-11 | 2003-01-14 | Hair Marker Llc | Hair coloring composition and method |
| JP2002037718A (en) * | 2000-07-25 | 2002-02-06 | Kao Corp | Hair dye composition |
| JP5796966B2 (en) * | 2011-02-17 | 2015-10-21 | ホーユー株式会社 | Hair dye composition and hair dyeing method using the same |
-
1986
- 1986-01-16 JP JP755186A patent/JPH0696507B2/en not_active Expired - Lifetime
Also Published As
| Publication number | Publication date |
|---|---|
| JPS62164612A (en) | 1987-07-21 |
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