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JPH07112613B2 - Tundish for continuous casting of steel - Google Patents
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JPH07112613B2 - Tundish for continuous casting of steel - Google Patents

Tundish for continuous casting of steel

Info

Publication number
JPH07112613B2
JPH07112613B2 JP27718488A JP27718488A JPH07112613B2 JP H07112613 B2 JPH07112613 B2 JP H07112613B2 JP 27718488 A JP27718488 A JP 27718488A JP 27718488 A JP27718488 A JP 27718488A JP H07112613 B2 JPH07112613 B2 JP H07112613B2
Authority
JP
Japan
Prior art keywords
tundish
steel
nozzle
porous material
continuous casting
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
JP27718488A
Other languages
Japanese (ja)
Other versions
JPH02121758A (en
Inventor
忠 斎藤
順一郎 勝田
雅保 木村
俊之 石倉
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Kobe Steel Ltd
Original Assignee
Kobe Steel Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Kobe Steel Ltd filed Critical Kobe Steel Ltd
Priority to JP27718488A priority Critical patent/JPH07112613B2/en
Publication of JPH02121758A publication Critical patent/JPH02121758A/en
Publication of JPH07112613B2 publication Critical patent/JPH07112613B2/en
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

Links

Classifications

    • BPERFORMING OPERATIONS; TRANSPORTING
    • B22CASTING; POWDER METALLURGY
    • B22DCASTING OF METALS; CASTING OF OTHER SUBSTANCES BY THE SAME PROCESSES OR DEVICES
    • B22D11/00Continuous casting of metals, i.e. casting in indefinite lengths
    • B22D11/10Supplying or treating molten metal
    • B22D11/11Treating the molten metal
    • B22D11/116Refining the metal
    • B22D11/117Refining the metal by treating with gases

Landscapes

  • Engineering & Computer Science (AREA)
  • Mechanical Engineering (AREA)
  • Continuous Casting (AREA)

Description

【発明の詳細な説明】 〔産業上の利用分野〕 本発明は、鋼の連続鋳造用タンディッシュに関し、詳細
には、タンディッシュから鋳型へ浸漬ノズルを介して溶
鋼を注湯するに際し、浸漬ノズル内を通る溶鋼に不活性
ガスを吹き込む改良された注湯ノズル構造を具備する鋼
の連続鋳造用タンディッシュに関するものである。
Description: TECHNICAL FIELD The present invention relates to a tundish for continuous casting of steel, and in particular, when pouring molten steel from a tundish into a mold through a dipping nozzle, the dipping nozzle is used. The present invention relates to a tundish for continuous casting of steel having an improved pouring nozzle structure in which an inert gas is blown into a molten steel passing therethrough.

〔従来の技術〕 従来、鋼の連続鋳造は、取鍋から注湯された溶鋼を、堰
により仕切られたタンディッシュの受湯部に受け、堰を
通して注湯部に移湯すると共に、注湯部の底に設けられ
ている浸漬ノズルを通して鋳型内に注湯し、この鋳型内
に注湯された溶鋼を鋳型内および鋳型の下方に続く冷却
帯により冷却し、この冷却により得られた鋳片を連続し
て引き出して行われている。
[Prior Art] Conventionally, in continuous casting of steel, the molten steel poured from a ladle is received by a tundish receiving part partitioned by a weir, and transferred to the pouring part through the weir. Molten steel is poured into the mold through an immersion nozzle provided at the bottom of the mold, and the molten steel poured into this mold is cooled in the mold and by a cooling zone below the mold, and a slab obtained by this cooling It is carried out by continuously pulling out.

上記鋼の連続鋳造過程において、溶鋼中に存在する非金
属介在物、特にAl23等が浸漬ノズル内を通る際にその
内壁に付着し、ノズル閉塞を起こす問題のあることが知
られ、このノズル閉塞防止策として、タンディッシュか
ら鋳型の間で、不活性ガスの吹き込みが一般的に行われ
ている。具体的には、タンディッシュの内底にポーラス
材からなるインサートノズルを設け、ポーラス材の気孔
を通して外周面から内周面に向け加圧した不活性ガスを
吹き込む方法等が行われている。
In the continuous casting process of the steel, non-metallic inclusions present in the molten steel, especially Al 2 O 3 etc. are attached to the inner wall when passing through the immersion nozzle, and it is known that there is a problem of nozzle clogging, As a measure for preventing the nozzle clogging, an inert gas is generally blown between the tundish and the mold. Specifically, a method is provided in which an insert nozzle made of a porous material is provided on the inner bottom of the tundish, and a pressurized inert gas is blown from the outer peripheral surface to the inner peripheral surface through the pores of the porous material.

そして、上述の不活性ガスの吹き込みにより吹き込まれ
た不活性ガスは、その大半が鋳型内溶鋼湯面まで浮上し
て分離するが、極一部はメニスカス部分で捕捉され、鋳
造される鋳片の表面にピンホールになって現れることが
知られている。
Then, the inert gas blown by the above-mentioned blowing of the inert gas, most of which floats up to the molten steel molten metal surface in the mold and is separated, but a very small portion is captured by the meniscus portion, and the cast slab is cast. It is known to appear as pinholes on the surface.

〔発明が解決しようとする課題〕[Problems to be Solved by the Invention]

ところが、近年、加工性を高めた極低炭素鋼(C≦0.01
wt%)等の軟質鋼製冷延材のニーズが高まり、この種軟
質鋼を上述の方法で連続鋳造し、得た鋳片を冷延材まで
加工すると、冷延材の表面に膨れ線状の欠陥が顕れる問
題が発生し、その原因を究明するために、膨れ線状欠陥
部を調査したところ、Arガスが検出され、さらに調査を
した結果、鋳造時ノズル閉塞防止のために吹き込んだAr
ガスのガス気泡が、鋳片内部の表皮下数十mm以上の深い
部位にまで及び捕捉されて冷延材の表面に膨れ線状の欠
陥になって顕れることが判明した。
However, in recent years, ultra-low carbon steel with improved workability (C ≦ 0.01
wt%) and other needs for cold rolled materials made of soft steel have increased, and when this type of soft steel is continuously cast by the above-mentioned method and the obtained slab is processed into cold rolled materials, the surface of the cold rolled material is swollen and linear. In order to investigate the cause, the swelling linear defect part was investigated and Ar gas was detected.As a result of further investigation, Ar gas blown to prevent nozzle clogging during casting was found.
It was found that the gas bubbles of the gas were caught up to a deep part of the epidermis under the epidermis of several tens of mm or more and appeared as swelling linear defects on the surface of the cold rolled material.

そこで、本発明者等は、上記の問題を解決するために、
鋳片内に捕捉されたArガスの状態をつぶさに調査した。
その結果、鋳型サイズとArガス流量を一定にした条件下
における鋳型への溶鋼の吐出流量とその吐出流量で鋳造
して得た鋳片の表皮下15〜30mmのピンホールの大きさお
よび個数との関係において、第7図に示す結果を得た。
Therefore, in order to solve the above problems, the present inventors have
The state of Ar gas trapped in the slab was thoroughly investigated.
As a result, the size and number of pinholes of the subcutaneous 15 to 30 mm pinhole of the cast piece obtained by casting the molten steel into the mold under the conditions where the mold size and the Ar gas flow rate were constant and the discharge rate. The relationship shown in FIG. 7 was obtained.

第7図に示す結果から明らかなように、鋳片内に捕捉さ
れるArガスによるピンホールは、ピンホール径1.5mm以
下と1.6mm以上とで個数に明確な差が認められ、ピンホ
ール径1.5mm以下のものは溶鋼吐出流量が増すにつれ際
立って増加するが、ピンホール径1.6mm以上のものは殆
ど増加することが無い上に、溶鋼吐出流量に関係なく個
数が殆ど無い状態であった。
As is clear from the results shown in Fig. 7, there is a clear difference in the number of pin holes due to Ar gas trapped in the slab between a pin hole diameter of 1.5 mm or less and 1.6 mm or more. Those with a diameter of 1.5 mm or less markedly increased as the molten steel discharge flow rate increased, but those with a pinhole diameter of 1.6 mm or more hardly increased and the number was almost irrespective of the molten steel discharge flow rate. .

本発明者等は、上記の把握された結果から、鋳造時ノズ
ル閉塞防止のために吹き込む不活性ガスの気泡径を1.6m
m以上になるように生成して吹き込めば、溶鋼吐出流量
に関わらずガス気泡の浮上分離が容易になり、上記軟質
鋼が有する膨れ等の品質欠陥が解消し得ると考え、さら
に鋭意研究し、その具体的な手段として、本発明に係わ
る鋼の連続鋳造用タンディッシュの開発をなしたもので
ある。
The present inventors, from the above grasped results, the bubble diameter of the inert gas blown to prevent nozzle clogging during casting is 1.6 m
If it is generated and blown so that it becomes m or more, the floating separation of gas bubbles is facilitated regardless of the molten steel discharge flow rate, and it is thought that quality defects such as swelling of the soft steel can be resolved, further intensive research, As a concrete means thereof, the tundish for continuous casting of steel according to the present invention has been developed.

〔課題を解決するための手段〕[Means for Solving the Problems]

本発明は、上述した事情によりなされたもので、その要
旨は、内底に位置する注湯口部が平均気孔径30μm以上
のポーラス材よりなり、且つ、このポーラス材の注湯孔
の最小内径部の断面積がこのポーラス材の下方に続く注
湯孔の最小内径部の断面積の1.5倍以上である注湯ノズ
ル構造を具備する鋼の連続鋳造用タンディッシュであ
る。
The present invention has been made under the circumstances described above, and the gist thereof is that the pouring port portion located at the inner bottom is made of a porous material having an average pore diameter of 30 μm or more, and the minimum inner diameter portion of the pouring hole of the porous material. Is a tundish for continuous casting of steel having a pouring nozzle structure having a cross-sectional area of 1.5 times or more of the cross-sectional area of the minimum inner diameter portion of the pouring hole continuing below the porous material.

次に、本発明について詳細に説明する。Next, the present invention will be described in detail.

ポーラス材から溶鋼に吹き込まれる不活性ガスの気泡
は、不活性ガスがポーラス材の表面の気孔から溶鋼中に
噴出して気泡として成長する過程で、ポーラス材の表面
に沿って流れる溶鋼流により剪断され生成するものと考
えられ、従って、気泡の大きさ(気泡径)は、気泡の成
長速度と溶鋼流による剪断力(溶鋼流速)とのバランス
により決定されるものと考えられる。
The inert gas bubbles blown from the porous material into the molten steel are sheared by the molten steel flow flowing along the surface of the porous material in the process in which the inert gas is ejected from the pores on the surface of the porous material into the molten steel and grows as bubbles. Therefore, it is considered that the bubble size (bubble diameter) is determined by the balance between the bubble growth rate and the shear force (molten steel flow rate) due to the molten steel flow.

そこで、第4図に概要を示す水モデル装置を使用して、
タンディッシュ15の下に設けるポーラス材製インサート
ノズル16のポーラス材の平均気孔径およびポーラス材の
設ける部位を変え、生成されるガス気泡径の変化を調査
した。
So, using the water model device outlined in Figure 4,
The average pore diameter of the porous material of the porous material insert nozzle 16 provided below the tundish 15 and the site where the porous material is provided were changed, and changes in the diameter of gas bubbles generated were investigated.

尚、第4図中、17はスライディングノズル、18は浸漬ノ
ズル、19は鋳型、20は水の循環装置を示す。
In FIG. 4, 17 is a sliding nozzle, 18 is a dipping nozzle, 19 is a mold, and 20 is a water circulating device.

また、水モデルと実溶鋼とにおけるガス気泡径の相似則
としては、R0/R1=1/1.35を用いた。但し、R0:水に
おけるガス気泡径、R1:溶鋼におけるガス気泡径であ
る。
Further, R 0 / R 1 = 1 / 1.35 was used as the similarity rule of the gas bubble diameter between the water model and the actual molten steel. However, R 0 : gas bubble diameter in water, R 1 : gas bubble diameter in molten steel.

従って、水モデルにおいて観察されるガス気泡径は、1.
15mm以上のものが得られる条件が、実装置において、1.
6mm以上のガス気泡径となり鋳片内に捕捉されることを
防止し得る条件となる。
Therefore, the gas bubble diameter observed in the water model is 1.
In actual equipment, the conditions for obtaining a thickness of 15 mm or more are 1.
The gas bubble diameter is 6 mm or more, which is a condition that can prevent the gas bubbles from being trapped in the slab.

先ず、第3図に示す形状のインサートノズル16を使用
し、インサートノズル16を構成するポーラス材21の平均
気孔径(23μmおよび40μm)と、このインサートノズ
ルにより生成されたガス気泡径と、吐出流量との関係を
上記水モデル装置により調査し、第5図に示す結果を得
た。この結果から、1.15mm以上の大きさのガス気泡径を
得るためには、ポーラス材の平均気孔径を大きく且つ吐
出流量を小さくすれば良いことが分かる。
First, using the insert nozzle 16 having the shape shown in FIG. 3, the average pore diameter (23 μm and 40 μm) of the porous material 21 constituting the insert nozzle 16, the gas bubble diameter generated by this insert nozzle, and the discharge flow rate. The relationship between and was investigated by the water model device, and the results shown in FIG. 5 were obtained. From this result, it is understood that in order to obtain the gas bubble diameter of 1.15 mm or more, the average pore diameter of the porous material should be increased and the discharge flow rate should be decreased.

次に、第2図に示す上記と同形状のインサートノズル16
であって、ポーラス部16aの最小内径部の断面積(S1
をストレート整流部の断面積(S0)に対し、インサー
トノズル16のストレート整流部22まで段階的に変えたも
のを準備し、上記水モデル装置により、吐出流量350l/m
inの条件下での気泡の発生状況を調査し、第6図に示す
結果を得た。この結果から、1.15mm以上の大きさのガス
気泡径を得るためには、上述のポーラス材の平均気孔径
を大きくすると同時に、気泡を剪断する溶鋼流速の小さ
いインサートノズルの上部にポーラス部を設ければ良い
ことが分かる。
Next, the insert nozzle 16 having the same shape as that shown in FIG.
And the cross-sectional area (S 1 ) of the smallest inner diameter portion of the porous portion 16a
Is prepared by gradually changing the sectional area (S 0 ) of the straight rectifying section up to the straight rectifying section 22 of the insert nozzle 16, and the discharge flow rate of 350 l / m
The generation of bubbles under the in condition was investigated and the results shown in FIG. 6 were obtained. From this result, in order to obtain a gas bubble diameter of 1.15 mm or more, at the same time as increasing the average pore diameter of the porous material, a porous portion is provided above the insert nozzle with a small molten steel flow velocity to shear the bubbles. I understand that it is good.

上述の水モデル装置により得られた第5図および第6図
に示す調査結果より推して、実装置において1.6mm以上
の大きさのガス気泡径をうるためには、ポーラス材の平
均気孔径は、30μm以上であれば良く、好ましくは40μ
m以上であれば良い。また、そのポーラス材の適用部位
は、気泡を剪断する溶鋼流速ノズルで最も小さくでき、
且つ、ガス気泡径1.6mm以上が安定して得られるノズル
の上部、即ちタンディッシュ内底の注湯口部が良く、し
かもポーラス材の注湯孔の最小内径部の断面積(S1
がこのポーラス材の下方に続く注湯孔の最小内径部の断
面積(S0)の1.5倍以上になるように適用するのが好ま
しい。
Inferring from the investigation results shown in FIGS. 5 and 6 obtained by the above water model device, in order to obtain a gas bubble diameter of 1.6 mm or more in an actual device, the average pore diameter of the porous material is , 30 μm or more, preferably 40 μm
It may be m or more. In addition, the application site of the porous material can be minimized with a molten steel flow velocity nozzle that shears bubbles,
In addition, the top of the nozzle that can stably obtain a gas bubble diameter of 1.6 mm or more, that is, the pouring port at the bottom of the tundish is good, and the cross-sectional area of the minimum inner diameter of the pouring hole of the porous material (S 1 )
Is preferably 1.5 times or more of the cross-sectional area (S 0 ) of the minimum inner diameter portion of the pouring hole continuing below the porous material.

〔実施例〕〔Example〕

以下、本発明に係わる実施例を図面に基づいて説明す
る。
Hereinafter, embodiments according to the present invention will be described with reference to the drawings.

第1図は、上述した水モデル装置で確認した注湯ノズル
構造を具備する鋼の連続鋳造用タンディッシュの要部断
面図である。
FIG. 1 is a cross-sectional view of essential parts of a tundish for continuous casting of steel having a pouring nozzle structure confirmed by the above water model device.

1は、タンディッシュであって、鉄皮2の内面に耐火物
3が張られている。4は、インサートノズルであって、
ポーラス部4aと非ポーラス部4bとの積層構造からなり、
鉄皮2上に設けられた鉄板5に段部6を載せると共にそ
の周囲に耐火モルタル7を詰めて固定されている。8
は、浸漬ノズルであって、浸漬ノズル8の上端とインサ
ートノズル4の下端とを密に当接して、鉄皮2上に設け
られた鉄板5と浸漬ノズル8の固定用鉄板9との間に設
けた三本の固定ボルト10により固定されている。
Reference numeral 1 is a tundish, in which a refractory 3 is stretched on the inner surface of a steel skin 2. 4 is an insert nozzle,
It has a laminated structure of a porous portion 4a and a non-porous portion 4b,
A step portion 6 is placed on an iron plate 5 provided on the iron skin 2, and a refractory mortar 7 is packed and fixed around the step portion 6. 8
Is a submerged nozzle, in which the upper end of the submerged nozzle 8 and the lower end of the insert nozzle 4 are in close contact with each other, and between the iron plate 5 provided on the iron shell 2 and the fixing iron plate 9 of the submerged nozzle 8. It is fixed by three fixing bolts 10 provided.

尚、11は、インサートノズル4のポーラス部4aに不活性
ガスを送気するための管である。
Reference numeral 11 is a pipe for feeding an inert gas to the porous portion 4a of the insert nozzle 4.

次に、上述の構成のタンディッシュにおいて、インサー
トノズル4を、第2図に示す本発明に係わるもの(ポー
ラス部の平均気孔径40μm,S1/S0=1.65)と、比較のた
め第3図に示す従来構造のもの(ポーラス部の平均気孔
径23μm,S1/S0=1)とを使用し、C:30ppm,Si:tr,Mn:0.
25wt%,P:0.010wt%,S:0.007wt%,Al:0.030wt板,Ti:0.0
6wt%の成分組成の極低炭素Ti入りキルド鋼を吐出流量
2.7ton/minの条件で連続鋳造した。
Next, in the tundish having the above-mentioned structure, the insert nozzle 4 is the third one for comparison with that according to the present invention shown in FIG. 2 (average pore diameter of porous portion 40 μm, S 1 / S 0 = 1.65). Using the conventional structure shown in the figure (average pore diameter of the porous part 23 μm, S 1 / S 0 = 1), C: 30ppm, Si: tr, Mn: 0.
25wt%, P: 0.010wt%, S: 0.007wt%, Al: 0.030wt plate, Ti: 0.0
Discharge flow rate of killed steel containing 6 wt% ultra-low carbon Ti
Continuous casting was performed under the condition of 2.7 ton / min.

この連続鋳造中、両者共ノズル閉塞は無かったが、連続
鋳造により得られた鋳片を冷延材まで加工し、膨れ疵の
発生状況を調査した結果、本発明に係わるタンディッシ
ュを使用して得た冷延材は、従来構造のタンディッシュ
を使用して得た冷延材に比較して、60%強の膨れ疵の低
減がなされていた。
During this continuous casting, there was no nozzle clogging in both cases, but the slab obtained by continuous casting was processed into a cold rolled material, and the result of investigating the state of occurrence of blisters and defects, using the tundish according to the present invention The obtained cold-rolled material had a reduction of blisters of more than 60% compared with the cold-rolled material obtained by using the tundish of the conventional structure.

〔発明の効果〕〔The invention's effect〕

上述したように、本発明に係わるタンディッシュによれ
ば、鋳造時ノズル閉塞防止のために吹き込む不活性ガス
の気泡径を1.6mm以上に生成して吹き込め、鋳型内溶鋼
中からのガス気泡の浮上分離が容易になり、軟質鋼が有
する膨れ等の品質欠陥を大幅に低減し得る鋼の連続鋳造
ができる。
As described above, according to the tundish of the present invention, the bubble diameter of the inert gas blown to prevent nozzle clogging during casting is generated to be 1.6 mm or more and blown in, and the gas bubbles float from the molten steel in the mold. Separation is facilitated, and continuous casting of steel that can significantly reduce quality defects such as swelling of soft steel can be performed.

【図面の簡単な説明】[Brief description of drawings]

第1図は、本発明にかかわる鋼の連続鋳造用タンディッ
シュの要部断面図、第2図は、本発明に係わるインサー
トノズル、第3図は、従来構造のインサートノズル、第
4図は、水モデル装置の概要図、第5図は、吐出流量と
最小ガス気泡径との関係説明図、第6図は、インサート
ノズル形状と最小ガス気泡径との関係説明図、第7図
は、鋳型への溶鋼の吐出流量とその吐出流量で鋳造して
得た鋳片の表皮下15〜30mmのピンホールの大きさおよび
個数との関係説明図である 1……タンディッシュ、2……鉄皮 3……耐火物、4……インサートノズル 4a……ポーラス部、4b……非ポーラス部 5……鉄板、6……段部 7……耐火モルタル、8……浸漬ノズル 9……固定用鉄板、10……固定ボルト 11……不活性ガスの送気管
FIG. 1 is a sectional view of a main part of a tundish for continuous casting of steel according to the present invention, FIG. 2 is an insert nozzle according to the present invention, FIG. 3 is an insert nozzle having a conventional structure, and FIG. FIG. 5 is a schematic diagram of the water model device, FIG. 5 is an explanatory diagram of the relationship between the discharge flow rate and the minimum gas bubble diameter, FIG. 6 is an explanatory diagram of the relationship between the insert nozzle shape and the minimum gas bubble diameter, and FIG. It is an explanatory view of the relationship between the discharge flow rate of molten steel and the size and number of pinholes of 15 to 30 mm in the epidermis of a slab obtained by casting at the discharge flow rate 1 ... Tundish, 2 ... Iron skin 3 ... Refractory, 4 ... Insert nozzle 4a ... Porous part, 4b ... Non-porous part 5 ... Iron plate, 6 ... Step part 7 ... Refractory mortar, 8 ... Immersion nozzle 9 ... Fixing iron plate , 10 ...... Fixing bolt 11 ...... Inert gas supply pipe

Claims (1)

【特許請求の範囲】[Claims] 【請求項1】内底に位置する注湯口部が平均気孔径30μ
m以上のポーラス材よりなり、且つ、このポーラス材の
注湯孔の最小内径部の断面積がこのポーラス材の下方に
続く注湯孔の最小内径部の断面積の1.5倍以上である注
湯ノズル構造を具備することを特徴とする鋼の連続鋳造
用タンディッシュ。
1. A pouring port located at the inner bottom has an average pore diameter of 30 μm.
Pouring made of porous material of m or more, and the cross-sectional area of the minimum inner diameter portion of the pouring hole of this porous material is 1.5 times or more of the cross-sectional area of the minimum inner diameter portion of the pouring hole that follows the porous material. A tundish for continuous casting of steel, characterized by having a nozzle structure.
JP27718488A 1988-10-31 1988-10-31 Tundish for continuous casting of steel Expired - Lifetime JPH07112613B2 (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP27718488A JPH07112613B2 (en) 1988-10-31 1988-10-31 Tundish for continuous casting of steel

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP27718488A JPH07112613B2 (en) 1988-10-31 1988-10-31 Tundish for continuous casting of steel

Publications (2)

Publication Number Publication Date
JPH02121758A JPH02121758A (en) 1990-05-09
JPH07112613B2 true JPH07112613B2 (en) 1995-12-06

Family

ID=17579978

Family Applications (1)

Application Number Title Priority Date Filing Date
JP27718488A Expired - Lifetime JPH07112613B2 (en) 1988-10-31 1988-10-31 Tundish for continuous casting of steel

Country Status (1)

Country Link
JP (1) JPH07112613B2 (en)

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* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP4815821B2 (en) * 2005-02-28 2011-11-16 Jfeスチール株式会社 Continuous casting method of aluminum killed steel
JP7252066B2 (en) * 2019-06-10 2023-04-04 日本製鉄株式会社 tundish interior nozzle

Also Published As

Publication number Publication date
JPH02121758A (en) 1990-05-09

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