JPH0791414B2 - Resin composition having a stone tone - Google Patents
Resin composition having a stone toneInfo
- Publication number
- JPH0791414B2 JPH0791414B2 JP63309101A JP30910188A JPH0791414B2 JP H0791414 B2 JPH0791414 B2 JP H0791414B2 JP 63309101 A JP63309101 A JP 63309101A JP 30910188 A JP30910188 A JP 30910188A JP H0791414 B2 JPH0791414 B2 JP H0791414B2
- Authority
- JP
- Japan
- Prior art keywords
- resin
- resins
- parts
- weight
- resin composition
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
- 239000004575 stone Substances 0.000 title claims description 8
- 239000011342 resin composition Substances 0.000 title claims description 5
- 229910052782 aluminium Inorganic materials 0.000 claims description 14
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 claims description 14
- 229920005992 thermoplastic resin Polymers 0.000 claims description 14
- 239000002245 particle Substances 0.000 claims description 6
- 229920005989 resin Polymers 0.000 description 18
- 239000011347 resin Substances 0.000 description 18
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 description 14
- 239000000203 mixture Substances 0.000 description 7
- 229920000122 acrylonitrile butadiene styrene Polymers 0.000 description 6
- 229920001971 elastomer Polymers 0.000 description 6
- 239000008188 pellet Substances 0.000 description 6
- 239000005060 rubber Substances 0.000 description 6
- 238000002156 mixing Methods 0.000 description 5
- 239000000975 dye Substances 0.000 description 4
- 239000000049 pigment Substances 0.000 description 4
- 239000004417 polycarbonate Substances 0.000 description 4
- -1 polyethylene Polymers 0.000 description 4
- 229920005669 high impact polystyrene Polymers 0.000 description 3
- 239000004797 high-impact polystyrene Substances 0.000 description 3
- 229910052751 metal Inorganic materials 0.000 description 3
- 239000002184 metal Substances 0.000 description 3
- 238000000034 method Methods 0.000 description 3
- 229920000515 polycarbonate Polymers 0.000 description 3
- 229920005668 polycarbonate resin Polymers 0.000 description 3
- 239000000843 powder Substances 0.000 description 3
- KAKZBPTYRLMSJV-UHFFFAOYSA-N Butadiene Chemical compound C=CC=C KAKZBPTYRLMSJV-UHFFFAOYSA-N 0.000 description 2
- 238000004040 coloring Methods 0.000 description 2
- 230000000052 comparative effect Effects 0.000 description 2
- 229920001577 copolymer Polymers 0.000 description 2
- 238000011156 evaluation Methods 0.000 description 2
- 239000010438 granite Substances 0.000 description 2
- JEIPFZHSYJVQDO-UHFFFAOYSA-N iron(III) oxide Inorganic materials O=[Fe]O[Fe]=O JEIPFZHSYJVQDO-UHFFFAOYSA-N 0.000 description 2
- 230000000704 physical effect Effects 0.000 description 2
- 229920003023 plastic Polymers 0.000 description 2
- 239000004033 plastic Substances 0.000 description 2
- 239000004431 polycarbonate resin Substances 0.000 description 2
- RNFJDJUURJAICM-UHFFFAOYSA-N 2,2,4,4,6,6-hexaphenoxy-1,3,5-triaza-2$l^{5},4$l^{5},6$l^{5}-triphosphacyclohexa-1,3,5-triene Chemical compound N=1P(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP=1(OC=1C=CC=CC=1)OC1=CC=CC=C1 RNFJDJUURJAICM-UHFFFAOYSA-N 0.000 description 1
- NLHHRLWOUZZQLW-UHFFFAOYSA-N Acrylonitrile Chemical compound C=CC#N NLHHRLWOUZZQLW-UHFFFAOYSA-N 0.000 description 1
- JHWNWJKBPDFINM-UHFFFAOYSA-N Laurolactam Chemical compound O=C1CCCCCCCCCCCN1 JHWNWJKBPDFINM-UHFFFAOYSA-N 0.000 description 1
- PEEHTFAAVSWFBL-UHFFFAOYSA-N Maleimide Chemical compound O=C1NC(=O)C=C1 PEEHTFAAVSWFBL-UHFFFAOYSA-N 0.000 description 1
- 229920000299 Nylon 12 Polymers 0.000 description 1
- 229920002292 Nylon 6 Polymers 0.000 description 1
- 229920002302 Nylon 6,6 Polymers 0.000 description 1
- 239000004952 Polyamide Substances 0.000 description 1
- 239000004698 Polyethylene Substances 0.000 description 1
- 239000004721 Polyphenylene oxide Substances 0.000 description 1
- 239000004743 Polypropylene Substances 0.000 description 1
- 239000004793 Polystyrene Substances 0.000 description 1
- 229920001893 acrylonitrile styrene Polymers 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 125000001931 aliphatic group Chemical group 0.000 description 1
- XYLMUPLGERFSHI-UHFFFAOYSA-N alpha-Methylstyrene Chemical compound CC(=C)C1=CC=CC=C1 XYLMUPLGERFSHI-UHFFFAOYSA-N 0.000 description 1
- 239000003963 antioxidant agent Substances 0.000 description 1
- 230000003078 antioxidant effect Effects 0.000 description 1
- 239000002216 antistatic agent Substances 0.000 description 1
- 125000003118 aryl group Chemical group 0.000 description 1
- 239000006229 carbon black Substances 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 238000013329 compounding Methods 0.000 description 1
- 238000005260 corrosion Methods 0.000 description 1
- 230000007797 corrosion Effects 0.000 description 1
- 230000007423 decrease Effects 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 239000010419 fine particle Substances 0.000 description 1
- 239000003063 flame retardant Substances 0.000 description 1
- 229920006015 heat resistant resin Polymers 0.000 description 1
- 238000002347 injection Methods 0.000 description 1
- 239000007924 injection Substances 0.000 description 1
- 239000000314 lubricant Substances 0.000 description 1
- 238000002844 melting Methods 0.000 description 1
- 230000008018 melting Effects 0.000 description 1
- 239000012778 molding material Substances 0.000 description 1
- 239000000178 monomer Substances 0.000 description 1
- 239000004014 plasticizer Substances 0.000 description 1
- 229920003229 poly(methyl methacrylate) Polymers 0.000 description 1
- 229920002647 polyamide Polymers 0.000 description 1
- 229920006122 polyamide resin Polymers 0.000 description 1
- 229920001707 polybutylene terephthalate Polymers 0.000 description 1
- 229920001225 polyester resin Polymers 0.000 description 1
- 239000004645 polyester resin Substances 0.000 description 1
- 229920000573 polyethylene Polymers 0.000 description 1
- 229920000139 polyethylene terephthalate Polymers 0.000 description 1
- 239000005020 polyethylene terephthalate Substances 0.000 description 1
- 239000004848 polyfunctional curative Substances 0.000 description 1
- 230000000379 polymerizing effect Effects 0.000 description 1
- 239000004926 polymethyl methacrylate Substances 0.000 description 1
- 229920005672 polyolefin resin Polymers 0.000 description 1
- 229920006380 polyphenylene oxide Polymers 0.000 description 1
- 229920001155 polypropylene Polymers 0.000 description 1
- 229920002223 polystyrene Polymers 0.000 description 1
- 239000004800 polyvinyl chloride Substances 0.000 description 1
- 229920000915 polyvinyl chloride Polymers 0.000 description 1
- SCUZVMOVTVSBLE-UHFFFAOYSA-N prop-2-enenitrile;styrene Chemical compound C=CC#N.C=CC1=CC=CC=C1 SCUZVMOVTVSBLE-UHFFFAOYSA-N 0.000 description 1
- 239000004576 sand Substances 0.000 description 1
- 239000011145 styrene acrylonitrile resin Substances 0.000 description 1
- 238000004381 surface treatment Methods 0.000 description 1
- 229920001169 thermoplastic Polymers 0.000 description 1
- 229920002803 thermoplastic polyurethane Polymers 0.000 description 1
- 239000004416 thermosoftening plastic Substances 0.000 description 1
- 239000006097 ultraviolet radiation absorber Substances 0.000 description 1
- 229920002554 vinyl polymer Polymers 0.000 description 1
Landscapes
- Compositions Of Macromolecular Compounds (AREA)
- Pigments, Carbon Blacks, Or Wood Stains (AREA)
Description
【発明の詳細な説明】 （産業上の利用分野） 本発明は、熱可塑性樹脂をベースとしてなる石目調を有
する樹脂組成物に関する。TECHNICAL FIELD The present invention relates to a resin composition having a stone tone based on a thermoplastic resin.
（従来の技術） ABS樹脂（ブタジエン系ゴム強化アクリロニトリル−ス
チレン）に代表されるゴム強化スチレン系樹脂ならびに
ポリカーボネート、ポリアミドなどの熱可塑性樹脂は、
車両部品、事務機部品、雑貨などに広く用いられてお
り、一般に使用に際しては、染顔料の配合によって着色
されている。通常これら染顔料は微粒子状となって樹脂
中に均一分散しており、単色成形品として用いられてい
る。又、一部の用途においては、金属粉を分散させるこ
とによってメタクリック調の成形品を得ている。(Prior Art) Rubber-reinforced styrene resins represented by ABS resin (butadiene rubber-reinforced acrylonitrile-styrene) and thermoplastic resins such as polycarbonate and polyamide are
It is widely used for vehicle parts, office machine parts, sundries, etc. When used, it is generally colored by blending dyes and pigments. Usually, these dyes and pigments are in the form of fine particles and uniformly dispersed in the resin, and they are used as monochromatic molded articles. Further, in some applications, a metal click-like molded product is obtained by dispersing metal powder.
しかしながら、生活様式の変化等にともない従来の単色
品、特にいかにもプラスチックといった感じを与える着
色品やメタリック調の成形品よりも、落ちつきのある外
観、例えば大理石調の成形品が求められている。さら
に、金属粉配合によるメタリック調成形品は、使用にと
もない錆を発生させるといった欠点を有している。However, there is a demand for a more calm appearance, for example, a marble-like molded product, as compared with a conventional single-colored product, especially a colored product or a metallic-like molded product that gives a feeling of plastic, due to a change in lifestyle. Further, the metallic-like molded product containing the metal powder has a drawback that rust is generated during use.
（発明が解決しようとする問題点） 大理石調の成形品は、一般に溶融年度ならびに色相の異
なる２種以上の樹脂を溶融混合することによって得られ
るが、樹脂の流れ方向に対する模様となることよりその
用途に制限があった。(Problems to be solved by the invention) A marble-like molded article is generally obtained by melt-mixing two or more kinds of resins having different melting years and hues. There was a limitation in usage.
（問題点を解決するための手段） 本発明者らは、上述の問題点に鑑み、落ちついた感覚を
もたらす成形材料に関し鋭意研究した結果、特定の着色
されたアルミニウム粒子（カラーアルミ）を熱可塑性樹
脂に配合した組成物が、従来のプラスチック感を与える
着色品や金属感を与えるメタリック調の成形品とは趣を
異にする砂石や御影石の様な石目調を有していることを
見い出し、本発明に到達したものである。また、本発明
の組成物は、熱可塑性樹脂本来の優れた特性を保持して
おり、さらにウエルド部の外観（ウエルド外観）にも優
れたものである。(Means for Solving Problems) In view of the above-mentioned problems, the present inventors have earnestly studied a molding material that brings a calm feeling, and as a result, have found that specific colored aluminum particles (colored aluminum) are thermoplastic. The composition blended with the resin has a stone tone like sand stone or granite, which is different from conventional colored products that give a plastic feel and metallic-like molded products that give a metallic feel. The present invention has been found and has reached the present invention. Further, the composition of the present invention retains the original excellent properties of the thermoplastic resin, and is also excellent in the appearance of the welded portion (weld appearance).
すなわち、本発明は、熱可塑性樹脂（Ａ）100重量部当
り、平均形状比が1:1〜20であり、14メッシュのタイラ
ー標準篩通過率が90％以上であり、かつ150メッシュの
タイラー標準篩通過率が10％以下である着色されたアル
ミニウム粒子（Ｂ）を0.1〜30重量部を分散してなるこ
とを特徴とする石目調を有する樹脂組成物を提供するも
のである。That is, the present invention has an average shape ratio of 1: 1 to 20 per 100 parts by weight of the thermoplastic resin (A), a 14 mesh Tyler standard sieve passage rate of 90% or more, and a 150 mesh Tyler standard. It is intended to provide a resin composition having a stone tone, characterized by comprising 0.1 to 30 parts by weight of colored aluminum particles (B) having a sieve passage rate of 10% or less.
以下に、本発明の樹脂組成物について詳細に説明する。Hereinafter, the resin composition of the present invention will be described in detail.
本発明における熱可塑性樹脂（Ａ）としては、ポリスチ
レン、AS樹脂、MS樹脂などのスチレン系樹脂、ゴムの存
在下に芳香族ビニルと必要により他の共重合可能な単量
体を重合して得らる、例えばハイインパクトポリスチレ
ン（HIPS）、ABS、MBS、ABSM、AES、AAS、ACS樹脂、さ
らにはα−メチルスチレンやマレイミドを共重合してな
る耐熱あるいは超耐熱樹脂などのゴム強化スチレン系樹
脂、ポリエチレン、ポリプロピレンなどのポリオレフィ
ン樹脂、ナイロン６、ナイロン66、ナイロン12などのポ
リアミド樹脂、脂肪族、芳香族または脂肪族−芳香族ポ
リカーボネート、さらにそれらのハロゲン置換ポリカー
ボネートなどのポリカーボネート樹脂、ポリブチレンテ
レフタレート、ポリエチレンテレフタレートなどのポリ
エステル樹脂、さらにはポリアセタール樹脂、ポリ塩化
ビニル樹脂、ポリメチルメタクリレート樹脂、熱可塑性
ポリウレタン樹脂、ポリフェニレンオキサイド樹脂など
が挙げられ、一種又は二種以上用いることができるが、
耐衝撃性、加工性などの物性バランス面より、ゴム強化
スチレン系樹脂またはゴム強化スチレン系樹脂と他の熱
可塑性樹脂との混合物であることが好ましい。The thermoplastic resin (A) in the present invention is obtained by polymerizing styrene resin such as polystyrene, AS resin and MS resin, aromatic vinyl and optionally other copolymerizable monomer in the presence of rubber. Such as high-impact polystyrene (HIPS), ABS, MBS, ABSM, AES, AAS, ACS resins, and rubber-reinforced styrene resins such as heat-resistant or super-heat-resistant resins obtained by copolymerizing α-methylstyrene or maleimide. Polyolefin resins such as polyethylene and polypropylene, polyamide resins such as nylon 6, nylon 66 and nylon 12, aliphatic, aromatic or aliphatic-aromatic polycarbonates, polycarbonate resins such as halogen-substituted polycarbonates thereof, polybutylene terephthalate, Polyester resin such as polyethylene terephthalate, Tar resins, polyvinyl chloride resins, polymethyl methacrylate resins, thermoplastic polyurethane resins, and polyphenylene oxide resins. May be used one or two or more,
From the viewpoint of the balance of physical properties such as impact resistance and workability, the rubber-reinforced styrene-based resin or a mixture of the rubber-reinforced styrene-based resin and another thermoplastic resin is preferable.
本発明における熱可塑性樹脂（Ａ）は、無着色品でもよ
いが、従来より公知の染顔料によって着色しておくこと
もできる。The thermoplastic resin (A) in the present invention may be a non-colored product, but may be colored with a conventionally known dye or pigment.
本発明においては平均形状比が1:1〜20であり、14メッ
シュのタイラー標準篩通過率が90％以上であり、かつ15
0メッシュのタイラー標準篩通過率が10％以下であるカ
ラーアルミ（Ｂ）を熱可塑性樹脂（Ａ）中に分散させ
る。In the present invention, the average shape ratio is 1: 1 to 20, the Tyler standard sieve passage ratio of 14 mesh is 90% or more, and 15
Color aluminum (B) having a 0 mesh Tyler standard sieve passage rate of 10% or less is dispersed in the thermoplastic resin (A).
平均形状比が該範囲外では、ウエルド外観に劣り、ま
た、14メッシュのタイラー標準篩通過率が90％未満では
熱可塑性樹脂の耐衝撃性が低下し、さらに、150メッシ
ュのタイラー標準篩通過率が10％を超すと鮮明な石目調
を有する成形品を得ることが困難であるので好ましくな
い。If the average shape ratio is out of the range, the weld appearance is inferior, and if the Tyler standard sieve passage ratio of 14 mesh is less than 90%, the impact resistance of the thermoplastic resin decreases, and further, the 150 mesh Tyler standard sieve passage ratio Is more than 10%, it is difficult to obtain a molded product having a clear stone tone, which is not preferable.
また、カラーアルミ（Ｂ）の着色方法には何ら制限はな
く、通常の表面処理方法により着色することができる。Further, there is no limitation on the method for coloring the colored aluminum (B), and it can be colored by an ordinary surface treatment method.
カラーアルミ（Ｂ）は、熱可塑性樹脂（Ａ）100重量部
当り0.1〜30重量部の範囲で分散される。0.1重量部未満
では良好な石目調とならず、又30重量部を超すと組成物
の耐衝撃性と加工性に劣り好ましくない。好ましくは0.
3〜10重量部である。The color aluminum (B) is dispersed in the range of 0.1 to 30 parts by weight per 100 parts by weight of the thermoplastic resin (A). If the amount is less than 0.1 parts by weight, a good grain tone is not obtained, and if it exceeds 30 parts by weight, the composition is inferior in impact resistance and processability, which is not preferable. Preferably 0.
3 to 10 parts by weight.
熱可塑性樹脂（Ａ）へのカラーアルミ（Ｂ）の分散方法
としては、バンバリミキサー、ロール、押出機等公知の
配合装置を採用することができる。As a method for dispersing the color aluminum (B) in the thermoplastic resin (A), a known compounding device such as a Banbury mixer, a roll or an extruder can be adopted.
なお、混合時に必要に応じて、ゴム強化スチレン系樹脂
（Ａ）を着色するための染顔料をはじめ、組成物のため
の酸化防止剤、紫外線吸収剤、帯電防止剤、滑剤、可塑
剤、難燃剤、離型剤等の添加剤を配合する事ができる。It should be noted that, at the time of mixing, if necessary, dyes and pigments for coloring the rubber-reinforced styrene resin (A), an antioxidant for the composition, an ultraviolet absorber, an antistatic agent, a lubricant, a plasticizer, a hardener Additives such as a flame retardant and a release agent can be added.
次に実施例および比較例により本発明を具体的に説明す
る。尚、部数およびパーセントについてはいずれも重量
基準で示した。Next, the present invention will be specifically described with reference to Examples and Comparative Examples. The numbers of parts and percentages are shown on a weight basis.
実施例および比較例 市販の熱可塑性樹脂とカラーアルミとを溶融混合し、ペ
レット化した後射出成形にてアイゾット衝撃強度測定用
試験片と外観評価用の平板（70mm×120mm×3mm）を作成
した。Examples and Comparative Examples Commercially available thermoplastic resins and color aluminum were melt mixed, pelletized, and then injection molded to prepare test pieces for measuring Izod impact strength and flat plates (70 mm x 120 mm x 3 mm) for appearance evaluation. .
組成比率ならびに評価結果を第１表に示す。The composition ratio and the evaluation results are shown in Table 1.
熱可塑性樹脂（Ａ） Ａ−1: ゴム分約５％の白色耐衝撃性ポリスチレンペレット Ａ−2: ゴム分約15％の灰色ABS樹脂パウダー Ａ−3: α−メチルスチレン−アクリロニトリル共重合体を配合
してなるゴム分約15％の白色耐熱ABS樹脂ペレット Ａ−4: メチルメタクリレート−アクリロニトリル−スチレン共
重合体を配合してなるゴム分約15％の白色ABS樹脂ペレ
ット。Thermoplastic resin (A) A-1: White high impact polystyrene pellets with rubber content of about 5% A-2: Gray ABS resin powder with rubber content of about 15% A-3: α-methylstyrene-acrylonitrile copolymer White heat-resistant ABS resin pellets having a rubber content of about 15% A-4: White ABS resin pellets having a rubber content of about 15% formed by mixing a methyl methacrylate-acrylonitrile-styrene copolymer.
Ａ−5: ゴム分約15％の灰色AES樹脂ペレット。A-5: Gray AES resin pellets having a rubber content of about 15%.
Ａ−6: 白色ポリカーボネート樹脂ペレット。A-6: White polycarbonate resin pellet.
Ａ−7: 白色ポリカーボネート/ABS樹脂（重量比:50/50）ペレッ
ト カラーアルミ（Ｂ） Ｂ−1: 平均形状比1:12 14メッシュ通過率95％ 150メッシュ通過率６％の赤色カラーアルミ Ｂ−2: 平均形状比1:6 14メッシュ通過率98％ 150メッシュ通過率８％の青色カラーアルミ Ｂ−i: 平均形状比1:30 14メッシュ通過率91％ 150メッシュ通過率５％の赤色カラーアルミ Ｂ−ii: 平均形状比1:10 14メッシュ通過率76％ 150メッシュ通過率２％の赤色カラーアルミ Ｂ−iii: 平均形状比1:8 14メッシュ通過率98％ 150メッシュ通過率22％ スチレン系樹脂粒子（ｂ） ｂ−1: スチレン−アクリロニトリル樹脂（アクリロニトリル含
有量約28％）99％とカーボンブラック１％とを溶融混合
してなる黒色粒子。（平均粒子径;50μ） ＜発明の効果＞ 本発明の組成物は、砂石や御影石の如き石目調ならびに
優れた物性（耐衝撃性等）を有する成形品をもたらす。A-7: White polycarbonate / ABS resin (weight ratio: 50/50) Pellet color aluminum (B) B-1: Average shape ratio 1:12 14 mesh pass rate 95% 150 mesh pass rate 6% red color aluminum B -2: Average shape ratio 1: 6 14 mesh pass rate 98% 150 mesh pass rate 8% blue color aluminum B-i: Average shape ratio 1:30 14 mesh pass rate 91% 150 mesh pass rate 5% red color Aluminum B-ii: Average shape ratio 1:10 14 mesh pass rate 76% 150 mesh pass rate 2% red color aluminum B-iii: Average shape ratio 1: 8 14 mesh pass rate 98% 150 mesh pass rate 22% Styrene Resin Particles (b) b-1: Black particles obtained by melt-mixing 99% of styrene-acrylonitrile resin (acrylonitrile content of about 28%) and 1% of carbon black. (Average particle size; 50μ) <Effects of the Invention> The composition of the present invention brings about a molded product having a stone tone such as sandstone and granite and excellent physical properties (impact resistance, etc.).
又、かかる成形品は従来のメタリック調成形品における
腐食（錆）といった問題を有しない。Further, such a molded product does not have the problem of corrosion (rust) in the conventional metallic-like molded product.
Claims (1)
形状比が1:1〜20であり、14メッシュのタイラー標準篩
通過率が90％以上であり、かつ150メッシュのタイラー
標準篩通過率が10％以下である着色されたアルミニウム
粒子（Ｂ）を0.1〜30重量部を分散してなることを特徴
とする石目調を有する樹脂組成物。1. An average shape ratio of 1: 1 to 20 per 100 parts by weight of a thermoplastic resin (A), a 14-mesh Tyler standard sieve passage rate of 90% or more, and a 150-mesh Tyler standard sieve. A resin composition having a stone tone, comprising 0.1 to 30 parts by weight of colored aluminum particles (B) having a passage rate of 10% or less.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP63309101A JPH0791414B2 (en) | 1988-12-06 | 1988-12-06 | Resin composition having a stone tone |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP63309101A JPH0791414B2 (en) | 1988-12-06 | 1988-12-06 | Resin composition having a stone tone |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPH02153971A JPH02153971A (en) | 1990-06-13 |
| JPH0791414B2 true JPH0791414B2 (en) | 1995-10-04 |
Family
ID=17988900
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP63309101A Expired - Fee Related JPH0791414B2 (en) | 1988-12-06 | 1988-12-06 | Resin composition having a stone tone |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPH0791414B2 (en) |
Family Cites Families (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS52144041A (en) * | 1976-05-27 | 1977-12-01 | Kansai Paint Co Ltd | Method of metallic coating |
-
1988
- 1988-12-06 JP JP63309101A patent/JPH0791414B2/en not_active Expired - Fee Related
Also Published As
| Publication number | Publication date |
|---|---|
| JPH02153971A (en) | 1990-06-13 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |
|
| LAPS | Cancellation because of no payment of annual fees |