JPH0813989B2 - Deodorant and cleanser composition - Google Patents

Description

TECHNICAL FIELD The present invention relates to a deodorant / cleanser composition. More specifically, the present invention relates to a deodorant / cleanser composition that is effectively used for deodorizing raw garbage and deodorizing and cleaning dirty cookware and tableware.

[Prior Art] and [Problems to be Solved by the Invention] Garbage generated from kitchens of ordinary households, kitchens of restaurants, etc. often gives off a strong odor over time.

In particular, raw garbage such as seafood and meat storage, which easily rot, has a strong odor. Also, in vegetables, onions and garlic have a strong odor. Almost no problem of odor occurs when throwing raw garbage into a closed type garbage container immediately, but generally it is left for half a day to 1 day in general, and in this case, especially in summer, the raw garbage generates a strong odor. There are many.

Conventionally, a deodorant liquid for food waste has been proposed and marketed. However, although these deodorant liquids also have a deodorizing effect when sprinkled on raw garbage, they gradually lose their effect as the liquid flows, and emit the smell of raw garbage with time.

Moreover, the odors emitted from raw garbage are various complex odors such as sulfur compounds, nitrogen compounds, etc., and it is difficult to deal with this odor with one type of deodorant liquid, and when various types of deodorant liquids are mixed,
React with each other and gradually lose their effect.

In kitchens and kitchens, fine powder of inorganic substances mixed with a surfactant is used as a cleanser for cleaning dishes. Tableware with miscellaneous leftovers often has a strong unpleasant odor when collected in one place. However, even if a commercially available cleanser is sprinkled before washing, the deodorizing effect cannot be expected, and therefore, the odor is masked with a perfume.

The present inventors have studied the deodorant / cleaning agent capable of continuously deodorizing the odor of leftover foods attached to raw garbage, tableware and the like, and have completed the present invention. .

[Means for solving problems]

Accordingly, the present invention relates to a deodorant / cleanser composition, which comprises a liquid deodorant containing ferrous sulfate as a main component and a liquid deodorant containing betaine-type amphoteric surfactant as a main component. Odorant, liquid deodorant consisting of cyclodextrin aqueous solution, anticorrosion agent containing amino acid type amphoteric surfactant and sorbitan type nonionic surfactant as main components, sodium alkyl ether sulfate ester type surfactant and fatty acid alkanolamide A microporous bead is separately impregnated with a detergent containing a type surfactant as a main component, and these are mixed at a desired ratio.

As the microporous beads, SiO ₂ microporous beads are preferable, and the pore volume: about 0.2 to 2.0 ml / g,
An average particle size: about 2 to 150 μm, a bead shape: an indefinite shape is generally used, and commercially available products are Fuji DeVison Chemical's Cyloid 63 to 978, Microbeads silica gel 3A, 4
B, 5D, etc. are used as they are.

As a deodorant, liquid deodorant mainly composed of ferrous sulfate that deodorizes by reacting with nitrogen compounds such as ammonia, betaine-type amphoteric surface active that deodorizes by reacting with sulfides such as hydrogen sulfide A liquid deodorant containing the agent as a main component, and an aqueous cyclodextrin solution for inclusion-removing various malodorous substances are used.

As the anti-corrosion agent, an amino acid type amphoteric surfactant, for example, a surfactant containing alkyl polyaminoethylglycine hydrochloride and a sorbitan type nonionic surfactant as main components is used. This prevents the generation of malodor due to the progress of decay.

In addition, as the detergent, a surfactant containing a sodium alkyl ether sulfate ester type surfactant and a fatty acid alkanolamide type surfactant as main components is used.

These are separately adsorbed and supported on the microporous beads in an amount of 20 to 97% by volume based on the pore volume of the microporous beads to form a mixed component of the deodorant / cleanser composition.

As a method for adsorbing and supporting, a ribbon blender, a stirrer with a rotary blade, or the like is used as an apparatus, and microporous beads are charged into the apparatus and a desired liquid is sprayed or dropped while rotating the blade. Thus,
A mixed component in which a desired liquid agent is adsorbed and supported on microporous beads is produced.

The deodorant / cleanser composition can be obtained by mixing the above-mentioned components in a desired ratio according to the intended use. In this case, each mixed component is not effective unless it is blended at a minimum of about 5%.

As for the mixing method, required amounts of the respective components are taken and mixed by stirring using a ribbon blender or a stirrer with a rotary blade.

The deodorant / cleanser composition of the present invention is used, for example, as follows.

Sprinkle directly to deodorize garbage. When used dishes are piled up and left for a while, they are sprinkled from the top to the side, and when they are immediately put in the water tank, they are sprinkled on the water surface to deodorize. Furthermore,
When washing dishes, sprinkle them on a scrubbing brush, sponge, etc. and wash the dishes in the usual manner.At this time, the dishes are more effective than the cleansing effect of the microporous beads and the washing effect caused by the detergent contained in the microporous beads oozing out. It becomes clean, and the deodorizing effect is exerted during that time to improve the environment of the kitchen.

〔The invention's effect〕

INDUSTRIAL APPLICABILITY The present invention provides a deodorant / cleanser composition which has a persistent deodorizing effect against a wide range of malodors and a mechanical / chemical cleaning effect, is applicable to various purposes, and is solid and easy to handle. It

〔Example〕

Next, the present invention will be described in more detail with reference to Examples. The raw materials used in the reference examples are as follows.

(1) SiO ₂ microporous beads: Syloid 404
(Manufactured by Fuji Davison Chemical Co., Ltd.); Pore solution: 1.25 ml / g, average pore size: 170Å, average particle size: 6 μm, shape: amorphous, color: white (2) Ferrous sulfate deodorant: Keska ( (Miyaki) (3) Betaine-type amphoteric surfactant; Epolion S (Ayu) (4) Cyclodextrin; Dixie Pearl K-100
(Made by Taiyo Fisheries) (5) Anti-corruption agent; Jolive A-1 (Made by Jolive) (6) Cleaning agent; Living Master (Made by Duskin) Reference example 1 2 kg of Syloid 404 Henschel mixer FM20 / L (Mitsui Miike Seisakusho) ) And stirring at 800 rpm,
20 ml of a 20% aqueous solution of keska was supplied by spraying, and after 10 minutes, stirring was stopped and the sample was taken out (Sample A).

Reference Examples 2-5 In place of the 1800 ml of 20% aqueous solution of keska of Reference Example 1, 20% aqueous solution of Epolion S (Reference Example 2), jolive A-1
The same procedure as in Reference Example 1 was carried out except that 1800 ml of each of a 20% aqueous solution (Reference Example 3), a living master 100% solution (Reference Example 4) or a 10% DEXY pearl K-100 aqueous solution (Reference Example 5) was used. (Samples B, C, D, E).

Reference Example 6 The above samples A to E in weight% are A = 35 B = 35 C = 15 D =
They were mixed so that 10 E = 5 (Sample F).

Reference Example 7 As raw garbage, in weight percent, mackerel internal organs 25, mackerel head 15, chicken meat 25, green onion 10, onion 10, tofu 5, rice 10 (mackerel internal organs and head, chicken meat, green onion, onion 5 mm A predetermined number of 50 g of a dish 15 cm in diameter was mixed and stirred. The product immediately after preparation was designated as G-1, and the product 24 hours after preparation was designated as G-2.

Example 1 Sample F was placed in a polyethylene bottle with a lid having three holes each having a diameter of 3 mm. Sample G on a precision balance with a sensitivity of 0.01
-1 was placed thereon, the polyethylene bottle was shaken, and 5 g of sample F was evenly sprinkled on sample G-1 (sample H-1). Sample H
The change with time of the odor of -1 was measured, and the values quantified according to the following criteria are shown in the table in comparison with Example 2 and Comparative Examples 1 to 4.

The odor was evaluated by sniffing the odor emitted from a height of about 30 cm above the sample.

[Status of odor] [Evaluation] Strong odor and nausea 10 Odor is slightly weak but irritating and also nausea 6 Odor is weak but stimulating odor 5 Odor is weak and irritating odor Weak 4 Slight odor, no irritating odor 3 Slight odor 2 Understanding odor 1 No odor 0 Example 2 In Example 1, G-2 was used instead of Sample G-1 (Sample H-2).

Comparative Example 1 The liquids used in the preparation of Samples A to E were placed on a precision balance with a sensitivity of 0.01, weighed in a spray container, and A, B, C,
0.83, 0.83, 0.35, 0.24, 0.12g each in the order of D and E G-
1 was uniformly sprayed (Sample I-1). Then, the change with time of the odor was measured in the same manner as in Example 1.

Comparative Example 2 In Comparative Example 1, G-2 was used instead of Sample G-1.

Comparative Examples 3 to 4 Samples G-1 (Comparative Example 3) and G-2 (Comparative Example 4) were subjected to the same odor measurement with time as they were without treatment.

Claims (2)

[Claims] 1. A liquid deodorant having ferrous sulfate as a main component, a liquid deodorant having a betaine-type amphoteric surfactant as a main component, a liquid deodorant comprising an aqueous cyclodextrin solution, and an amino acid-type amphoteric surfactant. Anti-corrosion agent containing a detergent and a sorbitan type nonionic surfactant as a main component, and a cleaning agent containing a sodium alkyl ether sulfate ester type surfactant and a fatty acid alkanolamide type surfactant as main components, respectively, are separately microporous What is impregnated in beads,
A deodorant / cleanser composition obtained by mixing in a desired ratio. 2. The deodorant / cleanser composition according to claim 1, wherein the microporous beads are SiO ₂ -based microporous beads.