JPH0825856B2 - Cosmetics - Google Patents

Description

Detailed Description of the Invention

[0001]

BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to a cosmetic composition, more specifically, a cosmetic composition which has water and oil repellency, has an excellent feeling of use, and prevents the makeup from being damaged by sweat, sebum, etc. Regarding fees.

[0002]

2. Description of the Related Art Conventionally, the problems to be solved by the invention
Many water- and oil-repellent powders obtained by treating a powder with a fluorine compound are known (Japanese Patent Laid-Open Nos. 55-167209 and 6-67209).
2-250074, JP-A-1-180811, U.S. Pat. No. 3,632,744).

On the other hand, cosmetics, especially make-up cosmetics, are required to have water and oil repellency and excellent makeup durability. However, in order to obtain a cosmetic having excellent water and oil repellency, even if an attempt is made to blend an oil agent that is usually used in cosmetics and powder surface-treated with the above-mentioned fluorine compound, It is difficult to obtain a cosmetic composition which is not well compatible with powder and does not mix uniformly, has an excellent feeling in use, has water and oil repellency, and has excellent makeup durability.

[0004] Therefore, an object of the present invention is to provide a cosmetic having water and oil repellency, an excellent feeling of use, and preventing the makeup from being damaged by sweat, sebum, etc., and remarkably improving the durability of makeup. is there.

[0005]

Means for Solving the Problems As a result of intensive studies by the present inventors, by using a powder treated with a fluorine compound, a fluorine-based oil agent and an organic plate-like powder in a cosmetic composition, The present invention has been completed by finding that the above object can be achieved.

That is, the present invention provides (A) a fluorine compound-treated powder, (B) 0.01% by weight or more and less than 5% by weight of a fluorine-based oil agent, and (C) a minor axis of 1/1 to a major axis. 1/100
The present invention provides a cosmetic characterized by containing an organic powder having a thickness of 1/2 or less of the major axis.

The cosmetic material of the present invention will be described in detail below.
The fluorine compound-treated powder which is the component (A) of the cosmetic of the present invention is obtained by treating the powder with a fluorine compound.

Examples of the above-mentioned fluorine compound used for treating the above-mentioned powder are polyfluoroalkyl phosphoric acid represented by the following general formula (I) (Chemical Formula 1) (US Pat. No. 363).
No. 2744), fluoroalkyl di (oxyethyl) amine phosphate ester (JP-A-6-264).
2-250074), and polymers having a fluoroalkyl group (JP-A-55-167209 and 61-5548).
1, No. 61-48803), fluororesins such as tetrafluoroethylene resin (JP-A-57-38707), fluoroalcohols (JP-A-63-2251, 63-2).
No. 252), perfluoroepoxy compounds, sulfoamide type fluorophosphoric acid, perfluorosulfates, perfluorocarboxylates, perfluoroalkylsilanes (JP-A-1-180070, JP-A-2-218603, JP-A-1).
No. 60907, No. 2-127477, Shin-Etsu Silicone Co., Ltd., LP-1T, LP-4T, LP-8T and other silane coupling agents), trifluorotrifluoroethane and other fluorine-containing halogenated hydrocarbons (CFCs) (JP-A-1
-318070), fluoroalkyl-containing polyhydric alcohols, and fluoroalkyl-containing polyoxyethylene compounds (JP-A-1-180810 and 1-180811).
No.), a fluoroalkyl-containing sulfamidocarboxylic acid,
Fluorine compounds containing a fluorine atom in the molecule, such as fluoroalkyl-containing acrylate copolymers (US Pat. No. 3,632,744), may be mentioned.

[0009]

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The powder used for the fluorine compound-treated powder as the component (A) is an organic powder having a short diameter of 1/1 to 1/100 and a thickness of 1/2 or less. It is not particularly limited as long as it is a powder other than powder and is a substance that is substantially insoluble in water and oil such as pigments and ultraviolet absorbers, and examples thereof include the following powders.

That is, talc, mica, sericite, kaolin, bentonite, vermiculite, hectorite, zeolite, silica, alumina, hydilite, aluminum silicate, magnesium silicate, calcium silicate, magnesium aluminum silicate, magnesium carbonate, Inorganic pigments such as calcium carbonate, barium sulfate, hydroxyapatite, boron nitride, barium sulfate treated mica; nylon powder, polymethylmethacrylate powder, polyethylene powder, polystyrene powder, benzoguanamine powder, fluororesin powder, polymethylsilsesquioxane powder Polymer powder such as; zirconium oxide-coated nylon powder, organic oxide-inorganic composite powder such as titanium oxide-coated nylon powder; spherical polymethylmethacrylate-mica composite powder, spherical poly Spherical-plate-like powder composite pigments such as tylmethacrylate-sericite composite powder, spherical polymethylmethacrylate-talc composite powder, spherical silica-mica composite powder; inorganic white such as titanium dioxide, zinc oxide, zirconium oxide Pigments; Inorganic red pigments such as iron oxide (red iron oxide), iron titanate and calamine; Inorganic brown pigments such as γ-iron oxide; Inorganic yellow pigments such as yellow iron oxide and ocher; Black iron oxide, carbon black, Inorganic black pigments such as low-order titanium oxide; inorganic purple pigments such as mango violet and cobalt violet; inorganic green pigments such as chromium oxide, chromium hydroxide and cobalt titanate; inorganic blue pigments such as ultramarine blue and dark blue. Titanium oxide coated mica, bismuth oxychloride, titanium oxide coated bismuth oxychloride, titanium oxide coated talc, colored titanium oxide Pearl pigments such as uncoated mica and fish scale foil; metal powder pigments such as aluminum powder and copper powder; cellulose,
Organic pigments such as silk; surfactant polyvalent metal salt powder such as metal soap such as zinc stearate; red 201, red 202, red 203, red 204, red 205
No., Red 213, Red 219, Red 220, Red 226, Red 228, Red 405, Orange 203
No. 204, Orange No. 204, Yellow No. 205, Yellow No. 401, Blue No. 404, Red No. 3, Red No. 104, Red No. 106, Red No. 227, Red No. 230, Red No. 401, Red No. 505
No. 205, Orange No. 205, Yellow No. 4, Yellow No. 5, Yellow 202
No., yellow No. 203, green No. 3, and blue No. 1 and their lake pigments such as zirconium, barium or aluminum; natural pigments such as chlorophyll and β-carotene, fine particles of titanium oxide, fine particles of zinc oxide, flaky oxidation. UV protective powder such as zinc, fine particle zirconium oxide, fine particle cerium oxide and the like can be mentioned.

The method of treating the above powder with a fluorine compound to obtain the above component (A) of the cosmetic of the present invention is not particularly limited. For example, the fluorine compound may be water and / or alcohol, acetone, toluene, hexane or the like. Dissolve or disperse in the medium of, and add the powder into it and stir to process
Examples thereof include a method of distilling or filtering the treatment medium to coat the powder with a fluorine compound. In this case, the treatment may be carried out under heating, or a reaction aid such as an acid, an alkali or a catalyst may be added if necessary. It is also possible to dissolve or disperse a fluorine compound in a volatile solvent and spray it on powder using a flow coater or the like for coating. In the case of a volatile fluorine compound such as CFC, the vapor of the fluorine compound is used. It is also possible to directly contact the powder with the powder for coating. Alternatively, the fluorine compound and the powder to be treated may be mixed by a ball mill or the like and the treatment may be carried out in a dry system.

After the above-mentioned treatment operation, post-treatments such as baking treatment, heat treatment and aging treatment may be carried out in order to enhance the treatment effect, as long as the effect of the present invention is not impaired. Further, as a pretreatment, the powder may be subjected to firing treatment, heat treatment, hydrothermal treatment, depressurization treatment, plasma treatment or the like, if necessary.

In the above coating treatment, two or more kinds of the above powders may be mixed and used at the same time.
Further, within a range that does not impair the effects of the present invention, silicones other than fluorine compounds, higher fatty acids and metal salts thereof, higher alcohols, esters, waxes, acylglutamic acid,
Amino acids such as N-mono long-chain acyl basic amino acids and metal salts thereof, hydrogenated lecithin, polyethylene, polyacrylic acid, acylated collagen, alkyl phosphates, triglycerides, diglyceride, silica, alumina, alumina silica, titania, sulfuric acid It may be simultaneously or doubly treated with another known coating agent such as barium.

The treatment amount of the above-mentioned fluorine compound varies depending on the kind thereof, but is preferably 0.01 to 50% by weight (hereinafter, simply expressed as%) of the powder, and particularly preferably 0.5 to 20%. If the content of the fluorine compound is less than 0.01%, it is difficult to obtain sufficient water and oil repellency, and if it exceeds 50%, the usability may be impaired.

The above component (A) can be used alone or in combination of two or more, and the amount of the component (A) is preferably 0.1 in the total composition of the cosmetic of the present invention. ~
It is 99.8%, more preferably 5 to 95%.

As the fluorine-based oil agent which is the component (B) of the cosmetic composition of the present invention, a perfluoro organic compound which is liquid at room temperature is preferable, and examples thereof include perfluorodecalin, perfluoroadamantane, perfluorobutyltetrahydrofuran and perfluoroorganic compounds. Fluorooctane, perfluorononane,
Examples thereof include perfluoropentane, perfluorodecane, perfluorododecane, and perfluoropolyether represented by the following general formula (II).

[0018]

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In the general formula (II), the perfluoro groups shown in parentheses do not have to be arranged in this order, and random polymerization or block polymerization may be used. As such a perfluoropolyether, a liquid one having a viscosity of 5 to 5,000 cSt is particularly preferable,
For example, FO represented by the following general formula (III)
MBLIN HC-04 (average molecular weight 1,500), HC-25 (3,200) and HC-R (660)
0) (manufactured by Montefloss Co., Ltd.) or Demnum S-20 (weight average molecular weight 25,000) represented by the following general formula (IV) of [Chemical Formula 4], S-65 (4,500) and S
-100 (5,600) and S-200 (8,4)
00) (all manufactured by Daikin Industries, Ltd.) and the like can be used.

[0020]

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[0021]

[Chemical 4]

The blending amount of the above-mentioned component (B), a fluorinated oil, is 0.01 to 5% by weight based on the total composition of the cosmetic of the present invention.
Less, preferably 0.1 to less than 5% by weight, more preferably 0.1 to less than 4% by weight.

The component (C) of the cosmetic of the present invention, which is an organic powder having a minor axis of 1/1 to 1/100 of the major axis and a thickness of 1/2 or less of the major axis, includes sodium zinc cetylphosphate and lauryl. Polyvalent metal salts of alkyl phosphates such as zinc phosphate and calcium lauryl phosphate (JP-A-60-248605, JP-A-61-229889 and JP-A-3-178987).
Manufactured according to the method described in each of the publications); N
Amylated amino acid polyvalent metal salts such as -lauroyl-β-alanine calcium, N-lauroyl-β-alanine zinc, calcium N-lauroylaminohexanoate (produced according to the method described in JP-A-4-5216) ); N-lauroyl-taurine calcium, N-palmitoyl-taurine calcium, and other polyamidoamidosulfonic acid salts (produced according to the method described in JP-A-3-294210); Nε-lauroyl-L-lysine N-acyl lysine such as Nε-palmitoyl lysine (manufactured according to the method described in JP-A-60-67406, Amihop LL manufactured by Ajinomoto Co., Inc. as a commercial product); α-aminocaprylic acid, α -Α-amino fatty acids such as aminolauric acid (according to the method described in JP-A-62-4211). Manufactured by the present invention); polyethylene, polypropylene, nylon, polymethylmethacrylate, polystyrene, divinylbenzene / styrene copolymer, flat or plate-like resin powder such as tetrafluoroethylene (JP-A-57-78466, JP-A-57-78466) Sho 62-1901
No. 12, and those disclosed in JP-A No. 62-104706) can be used.

The average particle size of the organic powder as the component (C) is not particularly limited, but 0.1 to 50 μ is preferable in terms of cosmetic performance.

The above-mentioned component (C) may be blended into the cosmetic composition as it is, or may be blended into the cosmetic composition after being treated with a fluorine compound. In this case, the fluorine compound treatment is
It can be carried out by using a fluorine compound and a treatment method which can be used for obtaining the component (A).

The above-mentioned component (C) can be used alone or in combination of two or more, and the compounding amount of the component (C) is preferably 0.1 in the total composition of the cosmetic of the present invention. ~
It is 99.8%, more preferably 5 to 95%.

The ratio (weight ratio) of the above-mentioned component (A) and the above-mentioned component (C), which are powder components, is (A) component /
Component (C) = 0.1 / 99.8 to 99.8 / 0.1 is preferable, and 5/95 to 95/5 is more preferable.

Further, the ratio (weight ratio) of the powder component which is a combination of the component (A) and the component (C) and the component (B).
Is (A) + (C) component / (B) component = 2/5 to 99.
9 / 0.1 is preferable, and 10/5 to 99.5 is preferable.
It is more preferable to set it to /0.5.

In the cosmetic of the present invention, in addition to the above-mentioned essential components, components used in ordinary cosmetics can be appropriately added within a range that does not impair the effects of the present invention.

Examples of powders that can be appropriately added to the cosmetic of the present invention include the following powders.

That is, talc, mica, sericite, kaolin, bentonite, vermiculite, hectorite, zeolite, silica, alumina, hydilite, aluminum silicate, magnesium silicate, calcium silicate, magnesium aluminum silicate, magnesium carbonate, Inorganic pigments such as calcium carbonate, barium sulfate, hydroxyapatite, boron nitride, fluorocarbon, barium sulfate-treated mica; nylon powder, polymethylmethacrylate powder, polyethylene powder, polystyrene powder, benzoguanamine powder, fluororesin powder, polymethylsil Polymer powder such as sesquioxane powder; organic-inorganic composite powder such as zirconium oxide-coated nylon powder and titanium oxide-coated nylon powder; spherical polymethylmethacrylate-mica composite powder , Spherical polymethyl methacrylate - sericite composite powders, spherical polymethyl methacrylate - Talc composite powders, spherical silica - spherical mica composite powder or the like - a plate-like powder composite pigment; titanium dioxide, zinc oxide,
Inorganic white pigments such as zirconium oxide; inorganic red pigments such as iron oxide (red iron oxide), iron titanate and calamine; γ-
Inorganic brown pigments such as iron oxide; Inorganic yellow pigments such as yellow iron oxide and ocher; Inorganic black pigments such as black iron oxide, carbon black and low order titanium oxide; Inorganic purple pigments such as mango violet and cobalt violet Inorganic green pigments such as chromium oxide, chromium hydroxide, and cobalt titanate; ultramarine blue;
Inorganic blue pigments such as navy blue; titanium oxide coated mica, bismuth oxychloride, titanium oxide coated bismuth oxychloride, titanium oxide coated talc, colored titanium oxide coated mica, pearl pigments such as fish scale foils; metals such as aluminum powder and copper powder Powder pigment; Organic pigment such as cellulose and silk; Metal soap such as zinc stearate; Red No. 201, Red No. 202,
Red No. 203, Red No. 204, Red No. 205, Red No. 21
No. 3, Red 219, Red 220, Red 226, Red 228, Red 405, Orange 203, Orange 204
No. Yellow 205, Yellow 401, Blue 404, Red 3, Red 104, Red 106, Red 227, Red 230, Red 401, Red 505, Orange 205
No., Yellow No. 4, Yellow No. 5, Yellow No. 202, Yellow No. 203
No. 3, Green No. 3 and Blue No. 1 and their lake pigments such as zirconium, barium or aluminum;
Examples thereof include natural pigments such as chlorophyll and β-carotene, UV protective powders such as particulate titanium oxide, particulate zinc oxide, flaky zinc oxide, particulate zirconium oxide, and particulate cerium oxide.

These powders can be used as they are, but surface treatment with an inorganic treating agent such as silica treatment, alumina treatment, silica-alumina treatment, titania treatment, barium sulfate treatment and / or silicon treatment, Metal soap treatment, amino acid treatment such as acylglutamic acid, N-mono long-chain acyl basic amino acid, lecithin treatment, collagen treatment, polyethylene treatment, polyacrylic acid treatment,
It is also possible to use a powder which has been surface-treated with an organic treating agent such as an alkyl phosphate ester treatment or an alkyl phosphate metal salt treatment.

Examples of components other than powder that can be appropriately blended with the cosmetic of the present invention include liquid oil, solid fat (wax), semi-solid oil, ultraviolet absorber, humectant, water-soluble polymer, oil. Soluble polymers, polymer latexes, various surfactants, fragrances, antioxidants, preservatives, drugs, thickeners, pH adjusters, water and the like can be used.

The liquid oil is not particularly limited as long as it is a liquid oil usually used in cosmetics and the like, and examples thereof include vegetable oils such as avocado oil, olive oil and jojoba oil; oleic acid,
Fatty acids such as isostearic acid; alcohols such as hexadecyl alcohol and oleyl alcohol; cetyl 2-ethylhexanoate, 2-ethylhexyl palmitate, 2-octyldodecyl myristate, neopentyl glycol di-2-ethylhexanoate, Glycerol tri-2-ethylhexanoate, 2-octyldodecyl oleate, isopropyl myristate, glycerol triisostearate, diglyceride 2-ethylhexanoate, di-paramethoxycinnamic acid-glyceryl mono-2-ethylhexanoate, etc. Esters; Silicone oils such as dimethylpolysiloxane, methylhydrogenpolysiloxane, methylphenylpolysiloxane, octamethylcyclotetrasiloxane; Liquids such as liquid paraffin, squalene, squalane. Hydrocarbon oils and the like, may be used alone or in combination.

Examples of the above solid fat or semi-solid oil include petrolatum, lanolin, ceresin, microcrystalline wax, carnauba wax, candelilla wax and the like.

Examples of the above-mentioned surfactants include polyoxyethylene alkyl ether, polyoxyethylene fatty acid ester, polyoxyethylene sorbitan fatty acid ester, glycerin fatty acid ester, polyglycerin fatty acid ester, polyoxyethylene glycerin fatty acid ester, and polyoxyethylene. Nonionic surfactants such as hydrogenated castor oil and polyoxyethylene sorbitol fatty acid ester; anionic surfactants represented by fatty acid soaps such as sodium stearate and triethanolamine palmitate; and cationic surfactants, amphoteric Examples include surfactants that are commonly used in cosmetics such as surfactants.

Examples of the water-soluble polymer include carboxymethyl cellulose, methyl cellulose, hydroxymethyl cellulose, polyvinyl alcohol, polyvinylpyrrolidone, transgant gum, carrageenan, locust bean gum, dextrin, dextrin fatty acid ester, carboxyvinyl polymer, xanthan gum, gelatin. , Water-soluble polymers commonly used in cosmetics such as sodium alginate and gum arabic.

Examples of the moisturizer include sorbitol, xylitol, glycerin, maltitol, propylene glycol, 1,3-butylene glycol, 1,4.
Moisturizers commonly used in cosmetics such as butylene glycol, sodium pyrrolidonecarboxylate, lactic acid, sodium lactate, polyethylene glycol and the like can be mentioned.

Examples of the above preservatives include preservatives commonly used in cosmetics such as alkyl paraoxybenzoate, sodium benzoate and potassium sorbate.

Examples of the drug include vitamins,
Examples include drugs that are commonly used in cosmetics such as crude drugs, antiphlogistics, and bactericides.

The above-mentioned UV absorbers are widely used in cosmetics such as para-aminobenzoic acid UV absorbers, anthranyl UV absorbers, salicylic UV absorbers, cinnamic acid UV absorbers, and benzophenone UV absorbers. UV absorbers.

The cosmetics of the present invention can be produced by a conventional method, and make-up cosmetics such as liquid foundations, cream foundations, oil foundations, powder foundations, powder powders, solid powders, blushers and eye shadows, sunscreens. It can be applied as a cosmeceutical such as a screen agent and an external medicine such as an anti-inflammatory agent and a skin protectant.

[0043]

EXAMPLES Next, the cosmetics of the present invention will be specifically described with reference to production examples and examples. The following Production Examples 1 to 3 are production examples of the fluorine compound-treated powder used in the following Examples, and two or more kinds of pigments are shown as the pigment of the fluorine compound-treated powder used in the Examples. The fluorine compound-treated powder is a mixture of the fluorine compound-treated products of each pigment. The following Production Example 4 is an example of producing a fluorine compound-treated organic powder.

Production Example 1 A round-bottomed flask (or kneader) was charged with 150 g of the pigment and heated to 60 ° C. while mixing. In addition, ₁₃ g of (C ₆ F ₁₃ CH ₂ CH ₂ O) ₂ P (O) OH was previously added.
Is dissolved in 1500 g of isopropyl ether and heated (50
C.) were added and mixed at 60.degree. C. for 4 hours. Then, isopropyl ether was distilled off under reduced pressure at 50 to 60 ° C., and dried to obtain 157 g of a fluorine compound-treated pigment.

Production Example 2 A round bottom flask (or kneader) was charged with (C ₈ F ₁₇ CH ₂ C
17 g of H ₂ O) ₂ P (O) OH and 1500 g of isopropyl alcohol were put and dissolved by heating to 60 ° C., 150 g of the pigment was added thereto, and mixed at 60 ° C. for 4 hours. Then, isopropyl alcohol was distilled off under reduced pressure at 50 to 60 ° C., and dried to obtain 161 g of a fluorine compound-treated pigment.

Production Example 3 150 g of pigment and Nε-lauroyl-L-lysine [Ajinomoto
Amihope LL] (7.5g)
Put in a mixer and stir and mix for 10 minutes to treat the surface of the above pigment.
And N-lauroyl lysine treated pigment (155 g)
Got Next obtained N-lauroyl lysine treated pigment 1
Add 55g to a round bottom flask (or kneader)
(C₆F₁₇CH₂CH₂OP (O) (OH)₂And (C₈
F₁₇CH ₂CH₂O)₂1: 1 mixing with P (O) OH
7.5g of the product was added to 1500g of isopropyl alcohol.
Add what was heat-dissolved (50 ℃), 4 hours at 60 ℃
Mixed for a while. Then, isopropyl acetate at 40-50 ° C.
Fluorol compound-treated pigment
160 g are obtained.

Preparation Example 4 50 g of Nε-lauroyl-L-lysine [Amihope LL, manufactured by Ajinomoto Co., Inc.] was placed in a round bottom flask, and a 15% aqueous solution of perfluoroalkyl phosphate diethanolamine salt [Asahi Glass Co., Ltd. Manufactured by AG530] 6.7
What was melt | dissolved in 500 g of water was added, and it mixed at 60 degreeC for 4 hours. Then, after adding hydrochloric acid, it is filtered, washed with water several times, and dried to obtain a fluorine compound-treated organic powder (average size of powder: major axis 9 μ, minor axis 7 μ, thickness 0.3).
μ) was obtained.

Example 1 Loose Powder Loose powder having the composition shown in the following [Table 1] was produced according to the method described later.

[0049]

[Table 1]

(Production method) The powder components were mixed and pulverized, then transferred to a Henschel mixer, and the fluorine-based oil agent [(4)] and perfume were added with stirring and uniformly mixed to obtain a mixture. The obtained mixture was crushed and passed through a sieve to obtain a desired product (loose powder).

The manufactured product (loose powder) was used by a panel of 10 people, and the makeup retention and the feeling of use were evaluated by scoring according to the evaluation criteria shown in [Table 2] below. The results are shown in [Table 3] below. The results shown in [Table 3] are the results obtained by averaging the scores of the 10 expert panels.

[0052]

[Table 2]

[0053]

[Table 3]

As is clear from the above [Table 3], the loose powder, which is the cosmetic material of the present invention produced as described above, has a good feeling of use such as long-lasting makeup, spreadability, stickiness and familiarity. It was a thing.

Example 2 Powder Foundation A powder foundation having the following composition was produced according to the following (Production Method).

(Component) (wt%) (1) Fluorine compound-treated pigment (Production Example 2) -Titanium oxide 10.0-Serisite 30.0-Mica residue-Kaolin 5.0-Bengala 2.5-Yellow Iron oxide 2.0 / Black iron oxide 0.1 (2) Nε-lauroyl-L-lysine ^{* 1} 8.0 (Ajinomoto Co., Amihope LL) (3) Squalane 2.0 (4) Perfluoropoly Ether 4 (FOMBLIN HC-04, manufactured by Montefloss) (5) Preservative 0.1 (6) Perfume proper amount * 1 Average size of powder: major axis 9 µ, minor axis 7 µ, thickness 0.3 µ.

(Production method) The pigments were mixed and pulverized through a pulverizer. This was transferred to a high-speed blender, and a fluorine-based oil agent [(4)], other oil agents, preservatives, perfumes, etc. were mixed and uniformly mixed. This was treated with a crusher, and the particle size was made uniform through a sieve, followed by compression molding in a container such as a gold plate to obtain the desired powder foundation.

Example 3 Blusher A blusher having the following composition was produced in the same manner as in Example 2.

(Component) (% by weight) (1) Fluorine compound-treated pigment (Production Example 1) -Talc balance-Titanium oxide 12.0-Iron oxide (red, black, yellow) 5.0 (2) N- Lauroyl-taurine calcium ^{* 1} 10.0 (3) Organic pigment (Red No. 202) 2.4 (4) Squalane 7.5 (5) Perfluoropolyether 3 (Fomblin HC-04, Montefloss) (6) Preservative 0.1 (7) Perfume Suitable amount * 1 Average size of powder: major axis 9 μ, minor axis 6 μ, thickness 0.5 μ.

Example 4 Powder Eye Shadow A powder eye shadow having the following composition was produced according to the following (production method).

(Component) (wt%) (1) Fluorine compound-treated pigment (Production Example 1) -Titanium mica 35.0-Residual amount of sericite-Mica 10.0-Color pigment 15.0 (2) N-lauroyl -Β-Alanine calcium ^{* 1} 20.0 (3) Zinc laurate 3.0 (4) Perfluoropolyether 2.0 (FOMBLIN HC-04, manufactured by Montefloss) (5) Dimethylpolysiloxane 2 (Shin-Etsu Chemical Co., Ltd.) (KF-96A, 6cs manufactured by Co., Ltd.) (6) Preservative 0.1 (7) Perfume proper amount * 1 Average size of powder: major axis 3 μ, minor axis 2 μ, thickness 0.1 μ.

(Production Method) Example 2 except that pigments other than titanium mica were mixed and crushed first, and titanium mica was then mixed.
The target powder eye shadow was obtained in the same manner as.

Example 5 Sunscreen emulsion (W / O
Type) A sunscreen emulsion (W / O type) having the following composition was produced according to the following (Production method).

(Component) (% by weight) (1) Octamethylcyclotetrasiloxane 25.0 (2) Perfluoropolyether 4.0 (FOMBLIN HC-04, manufactured by Montefloss) (3) Dimethylpolysiloxane poly 1. 0 Oxyalkylene copolymer (SH3775C manufactured by Toray Silicone Co., Ltd.) (4) Glycerin 20.0 (5) Ethanol 5.0 (6) Water balance (7) Fluorine compound-treated zinc oxide (Production Example 1) 7 .5 (8) N [epsilon] -lauroyl-L-lysine 2.0 (Ajinomoto Co., Inc., Amihope LL) (9) Octyl methoxycinnamate 2.0 (10) Fragrance Suitable amount

(Production Method) After dissolving the oil phase at room temperature, a pigment was added and dispersed by a disper. The aqueous phase was added with stirring to emulsify to obtain the desired sunscreen emulsion.

Example 6 Dual-use powder foundation In the same manner as in Example 2, a dual-use powder foundation having the following composition was produced.

(Component) (% by weight) (1) Fluorine compound-treated pigment (Production Example 1) -Residual amount of mica-Talc 4.8-Titanium oxide 14.0-Mica titanium 3.5-Iron oxide (red, yellow) , Black) 8.2 ・ Zinc oxide 4.5 ・ Barium sulfate 5.0 ・ Polyethylene powder 1.0 (2) Dimethylpolysiloxane 4.0 (KF-96A, 6cs manufactured by Shin-Etsu Chemical Co., Ltd.) ( 3) Lanolin 5.0 (4) Vaseline 1.0 (5) Perfluoropolyether 1.0 (FOMBLIN HC-04 manufactured by Montefloss) (6) Zinc sodium cetylphosphate ^{* 1} 5.0 (7) Preservative 1.5 (8) Perfume 0.1 * 1 Same as that used in Example 1.

Example 7 Loose-type face powder The powder components were mixed and pulverized, transferred to a Henschel mixer, and the fluorinated oil agent [(3)] and perfume were added and mixed uniformly, and then sieved. Then, a loose type face powder having the following composition was produced.

(Component) (% by weight) (1) Fluorine compound-treated pigment (Production Example 1) -Residual amount of talc-Barium sulfate 20.0-Titanium oxide 1.0-Iron oxide (red, yellow, black) 1. 5 (2) Fluorine compound-treated organic powder (Production Example 4) 70.0 (3) Perfluoropolyether 0.4 (FOMBLIN HC-04 manufactured by Montefloss) (4) Dimethylpolysiloxane 0.4 (Shin-Etsu Chemical) KF-96A, 6cs manufactured by Kogyo Co., Ltd. (5) Perfume 0.1

Example 8 Two-layer separation type liquid foundation After dissolving the oil phase at room temperature, a pigment was added and dispersed with a disper. The aqueous phase was added with stirring and emulsified to produce a liquid foundation having the following composition.

(Component) (wt%) (1) Fluorine compound-treated pigment (Production Example 1) -Titanium oxide 6.0-Serisite 9.0-Iron oxide (red, yellow, black) 1.2 (2) Flat polyethylene ^{* 1} 2.0 (3) Octylmethylcyclotetrasiloxane 20.0 (4) Dimethylpolysiloxane 2.0 (KF-96A, 6cs, manufactured by Shin-Etsu Chemical Co., Ltd.) (5) Dimethylpolysiloxane 1.0 Polyoxyalkylene Copolymer (6) Perfluoropolyether 2.0 (FOMBLIN HC-04, manufactured by Montefloss) (7) Glycerin 2.0 (8) Ethanol 15.0 (9) Purified water Residual amount (10) Perfume proper amount * 1 Average size of powder: major axis 20 μ, minor axis 12 μ, thickness 0.5 μ.

Example 9 Presto Powder In the same manner as in Example 2, a pressed powder having the following composition was produced.

(Component) (wt%) (1) Fluorine compound-treated sericite (Production Example 2) 20.0 (2) Zinc sodium cetylphosphate 30.0 (3) Nε-lauroyl-L-lysine 30.0 ( Amihope LL manufactured by Ajinomoto Co., Inc. (4) Remaining amount of talc (5) Titanium oxide 0.5 (6) Bengala 0.7 (7) Perfluoropolyether 0.8 (Fomblin HC-04 manufactured by Montefloss) (8) Suitable amount of fragrance

Example 10 Creamy foundation A pulverized powder component was added to and dispersed in a material obtained by heating and dissolving the oil phase component. This was added to the heated aqueous phase with stirring to emulsify, and further cooled to add a fragrance to produce a cream foundation having the following composition.

(Component) (% by weight) (1) Stearic acid 5.0 (2) Lipophilic glyceryl monostearate 0.5 (3) Cetostearyl alcohol 1.0 (4) Propylene glycol monolaurate 3.0 (5) Squalane 6.0 (6) Olive oil 7.0 (7) Perfluoropolyether 0.5 (FOMBLIN HC-04, manufactured by Montefloss) (8) Fluorine compound-treated pigment (Production Example 1) -Talc 10. 0-Titanium oxide 6.0-Iron oxide (red, yellow, black) 2.2 (9) Nε-lauroyl-L-lysine 5.0 (Ajinomoto Co., Inc., Amihope LL) (10) Purified water residual amount (111 Preservative Suitable amount (12) Triethanolamine 1.2 (13) Solbit 3.0 (14) Perfume Suitable amount

Example 11 Oily foundation Powder components were mixed and pulverized, and the mixture was added to an oil phase which was heated and dissolved,
Dispersed well. After adding a fragrance | flavor to this and mixing, it filled in the gold plate and cooled, and manufactured the oily foundation of the following composition.

(Component)
(% By weight) (1) Fluorine compound-treated pigment (Production Example 1) -Talc balance-Titanium oxide 12.0-Iron oxide (red, yellow, black) 4.1 (2) Fluorine compound-treated organic powder (Production) Example 4) 20.0 (3) Perfluoropolyether 4.5 (FOMBLIN HC-04, manufactured by Montefloss) (4) Liquid paraffin 15.0 (5) Isopropyl palmitate 10.0 (6) Lanolin alcohol 3. 0 (7) Microcristan wax 7.0 (8) Ozokerite 8.0 (9) Preservative Suitable amount (10) Perfume Suitable amount

Example 12 Body Powder A body powder having the following composition was produced in the same manner as in Example 1.

(Component) (wt%) (1) Fluorine compound-treated talc (Production Example 2) Residual amount (2) Nε-lauroyl-L-lysine 40.0 (Amihope LL, Ajinomoto Co., Inc.) (3) Dipotassium glycyrrhizinate 0.1 (4) Perfluoropolyether 0.5 (FOMBLIN HC-04, manufactured by Montefloss) (5) Perfume proper amount

The cosmetics of the present invention obtained in Examples 2 to 12 were all excellent in the feeling of use and had very good makeup retention.

[0081]

The cosmetic material of the present invention has water and oil repellency,
It has an excellent feeling of use, prevents makeup from being damaged by sweat, sebum, etc., and has significantly improved makeup durability.

Claims (1)

[Claims] 1. (A) Fluorine compound treated powder, (B)
Include 0.01% by weight or more and less than 5% by weight of a fluorine-based oil agent, and (C) an organic powder having a minor axis of 1/1 to 1/100 and a thickness of 1/2 or less. Cosmetics characterized by: