JP3466779B2 - Sweetener composition and method for producing sugar-coated product using the same - Google Patents
Sweetener composition and method for producing sugar-coated product using the sameInfo
- Publication number
- JP3466779B2 JP3466779B2 JP15410195A JP15410195A JP3466779B2 JP 3466779 B2 JP3466779 B2 JP 3466779B2 JP 15410195 A JP15410195 A JP 15410195A JP 15410195 A JP15410195 A JP 15410195A JP 3466779 B2 JP3466779 B2 JP 3466779B2
- Authority
- JP
- Japan
- Prior art keywords
- erythritol
- sugar
- sweetener composition
- sugar coating
- manufactured
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
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- 239000003765 sweetening agent Substances 0.000 title claims description 65
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- 235000019414 erythritol Nutrition 0.000 claims description 74
- UNXHWFMMPAWVPI-ZXZARUISSA-N erythritol Chemical compound OC[C@H](O)[C@H](O)CO UNXHWFMMPAWVPI-ZXZARUISSA-N 0.000 claims description 74
- 229940009714 erythritol Drugs 0.000 claims description 74
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- 238000002360 preparation method Methods 0.000 description 1
- 235000019423 pullulan Nutrition 0.000 description 1
- HELXLJCILKEWJH-NCGAPWICSA-N rebaudioside A Chemical compound O([C@H]1[C@H](O)[C@@H](CO)O[C@H]([C@@H]1O[C@H]1[C@@H]([C@@H](O)[C@H](O)[C@@H](CO)O1)O)O[C@]12C(=C)C[C@@]3(C1)CC[C@@H]1[C@@](C)(CCC[C@]1([C@@H]3CC2)C)C(=O)O[C@H]1[C@@H]([C@@H](O)[C@H](O)[C@@H](CO)O1)O)[C@@H]1O[C@H](CO)[C@@H](O)[C@H](O)[C@H]1O HELXLJCILKEWJH-NCGAPWICSA-N 0.000 description 1
- 238000005096 rolling process Methods 0.000 description 1
- 102200004779 rs2232775 Human genes 0.000 description 1
- 235000019204 saccharin Nutrition 0.000 description 1
- 229940081974 saccharin Drugs 0.000 description 1
- CVHZOJJKTDOEJC-UHFFFAOYSA-N saccharin Chemical compound C1=CC=C2C(=O)NS(=O)(=O)C2=C1 CVHZOJJKTDOEJC-UHFFFAOYSA-N 0.000 description 1
- 239000000901 saccharin and its Na,K and Ca salt Substances 0.000 description 1
- 229940085605 saccharin sodium Drugs 0.000 description 1
- 238000000926 separation method Methods 0.000 description 1
- 229940013618 stevioside Drugs 0.000 description 1
- OHHNJQXIOPOJSC-UHFFFAOYSA-N stevioside Natural products CC1(CCCC2(C)C3(C)CCC4(CC3(CCC12C)CC4=C)OC5OC(CO)C(O)C(O)C5OC6OC(CO)C(O)C(O)C6O)C(=O)OC7OC(CO)C(O)C(O)C7O OHHNJQXIOPOJSC-UHFFFAOYSA-N 0.000 description 1
- 239000000979 synthetic dye Substances 0.000 description 1
- 235000010491 tara gum Nutrition 0.000 description 1
- 239000000213 tara gum Substances 0.000 description 1
- 239000000892 thaumatin Substances 0.000 description 1
- 235000010436 thaumatin Nutrition 0.000 description 1
- 239000002562 thickening agent Substances 0.000 description 1
- 150000003641 trioses Chemical class 0.000 description 1
- 239000000811 xylitol Substances 0.000 description 1
- 235000010447 xylitol Nutrition 0.000 description 1
- HEBKCHPVOIAQTA-SCDXWVJYSA-N xylitol Chemical compound OC[C@H](O)[C@@H](O)[C@H](O)CO HEBKCHPVOIAQTA-SCDXWVJYSA-N 0.000 description 1
- 229960002675 xylitol Drugs 0.000 description 1
Landscapes
- General Preparation And Processing Of Foods (AREA)
- Jellies, Jams, And Syrups (AREA)
- Seasonings (AREA)
- Formation And Processing Of Food Products (AREA)
- Medicinal Preparation (AREA)
- Confectionery (AREA)
- Grain Derivatives (AREA)
Description
【0001】[0001]
【産業上の利用分野】本発明は、糖衣用甘味料組成物及
びそれを用いる糖衣生成物の製造方法に関し、詳しくは
低カロリーで非う蝕性のエリスリトールを使用した糖衣
用甘味料組成物及び該組成物を用いる糖衣生成物の製造
方法に関する。更に詳しくは、エリスリトールの微結晶
を含有し、保存安定性の改良された流動性甘味料組成物
及びエリスリトールの微結晶を含有し、清涼感が高く、
しかも食感の改良された糖衣生成物の製造方法に関す
る。TECHNICAL FIELD The present invention relates to a sweetener composition for sugar coating and a method for producing a sugar coating product using the same, and more particularly to a sugar coating using low-calorie, non-cariogenic erythritol.
The present invention relates to a sweetener composition for use and a method for producing a sugar-coated product using the composition. More specifically, it contains microcrystals of erythritol, contains a liquid sweetener composition having improved storage stability and microcrystals of erythritol, and has a high refreshing feeling,
Moreover, the present invention relates to a method for producing a sugar-coated product having an improved texture.
【0002】[0002]
【従来の技術】近年、日本においても糖類、とりわけ砂
糖の取り過ぎにより肥満,糖尿病,虫歯などの種々の健
康上の弊害が発生している。そこで、あらゆる食品,菓
子類に使用されている砂糖などの糖類を低カロリー、か
つ非う蝕性の糖アルコール類に置き換える試みがなされ
ている。また、医薬品においても同様の試みがなされて
いる。このような目的に供される糖質のうち特にエリス
リトールは、糖アルコールの中でもとりわけカロリーが
低く、砂糖4kcal/gに対して0kcal/gとさ
れている。また、エリスリトール粉末は、水への溶解熱
が−42.9cal/gと高く、口に入れた時に高い清
涼感が得られると言う他の糖質では見られない特色を有
している。しかし、このような特性を有しているにも拘
らず、エリスリトールは結晶性が著しく高いため、糖衣
の様な結晶化を伴う製造工程をもつ製品の場合は、使用
が制限されている。これは、砂糖などを使用する通常の
方法でエリスリトールを使用した場合、微結晶を析出さ
せることができず、結晶サイズが大きくなり、好ましく
ない物性や食感になるという欠点があるからである。こ
のように、従来はエリスリトールの使用範囲、対象が著
しく制限されている。2. Description of the Related Art In recent years, too many sugars, especially sugar, have caused various adverse health effects such as obesity, diabetes and tooth decay in Japan. Therefore, attempts have been made to replace sugars and other sugars used in all foods and confectioneries with low-calorie, non-cariogenic sugar alcohols. Similar attempts have also been made for pharmaceutical products. Among the sugars used for such purpose, erythritol is particularly low in calories among sugar alcohols, and is set to 0 kcal / g with respect to 4 kcal / g of sugar. Further, the erythritol powder has a high heat of dissolution in water of -42.9 cal / g, and has a characteristic not found in other sugars that it gives a high refreshing feeling when placed in the mouth. However, despite having such characteristics, erythritol has a remarkably high crystallinity, so that its use is limited in the case of a product having a manufacturing process involving crystallization such as sugar coating. This is because when erythritol is used by a usual method using sugar or the like, fine crystals cannot be precipitated, the crystal size becomes large, and unfavorable physical properties and texture are caused. As described above, conventionally, the use range and target of erythritol have been significantly limited.
【0003】エリスリトールを食品に用いた例として、
特公昭56−18180号公報があり、これにはエリス
リトールとサッカリンを用いた低カロリー、非う蝕性の
フォンダンの製法が提案されている。しかし、実際に調
製してみると、大きな双目状の結晶エリスリトールが生
じ、砂糖を用いて製造したフォンダンの滑らかさにはほ
ど遠い食感である。また、特開平1−225458号公
報にはエリスリトールと他の糖類を一定の量比で用い、
かつ水を一定の割合で含有させることによって口当たり
の滑らかなフォンダンを調製する方法が提案されてい
る。さらに、特開平5−137535号公報にはエリス
リトールと糖アルコールを所定の割合で含む甘味料組成
物に寒天又はファーセレランを配合したフォンダン様の
微結晶甘味料組成物が示されている。As an example of using erythritol in foods,
Japanese Patent Publication No. 56-18180 discloses a method for producing a low-calorie, non-cariogenic fondant using erythritol and saccharin. However, when actually prepared, large binocular crystalline erythritol is produced, and the texture is far from the smoothness of fondant produced using sugar. Further, in JP-A-1-225458, erythritol and other saccharides are used in a fixed amount ratio,
In addition, a method for preparing a fondant with a smooth mouthfeel by incorporating water in a fixed ratio has been proposed. Further, JP-A-5-137535 discloses a fondant-like microcrystalline sweetener composition in which agar or furceleran is mixed with a sweetener composition containing erythritol and sugar alcohol in a predetermined ratio.
【0004】また、低カロリーで非う蝕性の糖衣生成物
を製造する場合には、エリスリトールほどカロリーは低
くないが、結晶性が低く、しかも砂糖と比較的似た物性
を持つマルチトール,ラクチトール,ソルビトールなど
が使用されているのが現状である。例えば、マルチトー
ルは特開昭61−249349号公報,特開昭61−2
63915号公報,特開平3−90020号公報などに
提案され、ラクチトールは特開平4−281748号公
報,特開平6−70688号公報などに提案され、また
ソルビトールは特公平5−63131号公報に提案され
ている。しかし、エリスリトールを用いた糖衣生成物に
関しては、特開平7−23759号公報にエリスリトー
ルと還元澱粉糖化物よりなる糖衣層で芯材を被覆したも
のが記載されているにすぎない。Further, in the case of producing a low-calorie, non-cariogenic sugar-coated product, maltitol and lactitol, which are not as low in calories as erythritol but have low crystallinity and have physical properties relatively similar to those of sugar. Currently, sorbitol is used. For example, maltitol is disclosed in JP-A-61-249349 and JP-A-61-2.
No. 63915, Japanese Patent Application Laid-Open No. 3-90020, etc., Lactitol is proposed in Japanese Patent Application Laid-Open No. 4-281748, Japanese Patent Application No. 6-70688, etc., and sorbitol is proposed in Japanese Patent Publication No. 5-63131. Has been done. However, regarding the sugar-coated product using erythritol, JP-A-7-23759 only discloses a product in which a core material is coated with a sugar-coated layer composed of erythritol and a reduced starch saccharified product.
【0005】[0005]
【発明が解決しようとする課題】前記したように、四炭
糖の糖アルコールであるエリスリトールは、低カロリー
で、かつ非う蝕性であるという時代の要請に適った特性
を有している上に、その結晶粉末は、口に入れると、非
常に清涼感が高いという他に類を見ない物性を持ち合わ
せている。しかしながら、エリスリトールを使用してガ
ム,チョコレート,タブレットなどの菓子類や医薬品の
錠剤に低カロリーで、かつ非う蝕性の糖衣を形成しよう
とすると、エリスリトールの低い溶解度、高い結晶性等
の物性により、糖衣の生成を困難にしている。すなわ
ち、エリスリトールは20℃の水に対して約33%(w
/w)しか溶解しないため、水分の多い状態で糖衣シロ
ップとして使用する必要があるが、これは後工程で乾燥
の手間がより多くかかることになり、糖衣の製造上非常
に不利である。また、エリスリトールは結晶性が極めて
良いため、前記乾燥工程中に析出するエリスリトールの
結晶が大粒になり、滑らかな外観および食感の糖衣生成
物が得られないのが現状である。従って、この課題を解
決するために、より高濃度のエリスリトール溶液の調製
方法と微結晶を析出させる方法が求められていた。As described above, erythritol, which is a sugar alcohol of four-carbon sugar, has properties suitable for the needs of the times that it is low in calories and non-cariogenic. In addition, the crystalline powder has a very high refreshing sensation when put in the mouth, and has unique physical properties. However, if erythritol is used to form sugar coatings with low calorie and non-cariogenic properties on gums, chocolates, tablets such as tablets and pharmaceuticals, erythritol has low physical properties such as low solubility and high crystallinity. , Making sugar coating difficult. That is, erythritol is about 33% (w
Since it only dissolves / w), it needs to be used as a sugar-coated syrup in a water-rich state, but this requires a great deal of time and effort for drying in the subsequent step, which is extremely disadvantageous in the manufacture of sugar coating. Further, since erythritol has extremely good crystallinity, the crystals of erythritol precipitated during the drying step become large particles, and it is the current situation that a sugar-coated product having a smooth appearance and texture cannot be obtained. Therefore, in order to solve this problem, a method for preparing a erythritol solution having a higher concentration and a method for precipitating fine crystals have been demanded.
【0006】[0006]
【課題を解決するための手段】本発明者らは、前記の課
題を解決すべく、鋭意検討を行った結果、エリスリトー
ルを主成分とする甘味料に微量の多糖類の増粘安定剤を
添加、共存させることにより、エリスリトールが多量に
配合されているにもかかわらず、エリスリトールの大き
な結晶が析出することなく、微細な結晶のみが析出、分
散した高濃度で実質的に均一な組成の安定した状態を維
持することができることを見出した。さらに、エリスリ
トールおよび多糖類の増粘安定剤を含有する甘味料組成
物を調製し、そのシロップを予め糖衣パン内に供給した
芯材に噴霧し、次いで乾燥するという操作を所望の厚さ
になるまで繰り返すことによって、芯材の表面に糖衣層
が形成されることを見出して、本発明を完成したのであ
る。Means for Solving the Problems As a result of intensive studies to solve the above problems, the present inventors have added a trace amount of a polysaccharide thickening stabilizer to a sweetener containing erythritol as a main component. By coexisting, even though a large amount of erythritol is blended, large crystals of erythritol do not precipitate, and only fine crystals precipitate, and a stable, substantially uniform composition with high concentration is dispersed. It was found that the state can be maintained. Furthermore, a sweetener composition containing erythritol and a polysaccharide thickening stabilizer is prepared, and the syrup is sprayed onto a core material previously supplied in a sugar-coated bread, and then dried to obtain a desired thickness. The present invention has been completed by finding that a sugar coating layer is formed on the surface of the core material by repeating the above process.
【0007】すなわち、請求項1記載の本発明は、主成
分としてエリスリトールを35〜65%(w/w)及び
カラギーナン,寒天,ファーセレラン,ペクチン,カー
ドラン,ジェランガム,キサンタンガム,アルギン酸ナ
トリウム及びタマリンドガムよりなる群から選ばれた少
なくとも1種の多糖類の増粘安定剤を0.03〜0.7
%(w/w)含有し、かつエリスリトール以外の糖質を
含まないか又はエリスリトール100重量部に対して4
3重量部以下の割合で含有し、かつエリスリトールの微
結晶が均一に分散した液状の糖衣用甘味料組成物であ
る。請求項3記載の本発明は、上記請求項1記載の糖衣
用甘味料組成物を糖衣パン内の芯材の表面に供給し、乾
燥することを特徴とする糖衣生成物の製造方法である。That is, the present invention according to claim 1 is based on 35-65% (w / w) of erythritol as a main component and carrageenan, agar, furceleran, pectin, curdlan, gellan gum, xanthan gum, sodium alginate and tamarind gum. 0.03 to 0.7 of a thickening stabilizer of at least one polysaccharide selected from the group consisting of
% (W / w) and contains no sugars other than erythritol, or 4 per 100 parts by weight of erythritol.
Contains less than 3 parts by weight and a small amount of erythritol.
A liquid sweetener composition for sugar coating in which crystals are uniformly dispersed . The present invention according to claim 3 provides the sugar coating according to claim 1.
A method for producing a sugar-coated product, which comprises supplying the sweetener composition for use to a surface of a core material in a sugar-coated bread and drying the composition.
【0008】以下に本発明を詳細に説明する。本発明の
甘味料組成物に用いられるエリスリトールは、公知の糖
アルコールであり、例えば日研化学株式会社から発売さ
れている市販品を用いることができる。エリスリトール
の構造は、炭素数が4つの糖アルコールで、分子量は1
22、融点119℃の無色透明の結晶で、甘味度は砂糖
の75〜80%程度で、非着色性、非消化性、非う蝕性
である。また、甘味質は砂糖に近いが、砂糖に比べて後
味が残らないという特性がある。市販品にはグラニュー
糖と外観がよく似た粒度のものと微粉タイプのものがあ
るが、本発明においてはいずれの形状のものもそのまま
使用できる。本発明の甘味料組成物においてエリスリト
ールは35〜65%(w/w)、好ましくは40〜60
%(w/w)の割合で含有させることができる。The present invention will be described in detail below. Erythritol used in the sweetener composition of the present invention is a known sugar alcohol, and for example, a commercially available product sold by Nikken Chemical Co., Ltd. can be used. The structure of erythritol is a sugar alcohol having 4 carbon atoms and a molecular weight of 1
It is a colorless and transparent crystal with a melting point of 119 ° C. and a sweetness of about 75 to 80% of sugar, and is non-coloring, non-digestive, and non-cariogenic. Also, although the sweetness is similar to sugar, it has the characteristic that aftertaste does not remain as compared with sugar. Commercially available products include those with a particle size similar to that of granulated sugar and those with a fine powder type, but in the present invention, any shape can be used as it is. In the sweetener composition of the present invention, erythritol is 35 to 65% (w / w), preferably 40 to 60.
% (W / w).
【0009】また、本発明の甘味料組成物中にはエリス
リトールの他に各種の糖質を目的に応じて使用すること
ができる。例えば、低カロリーや非う蝕性の製品を目的
とする場合には、マルチトール,ラクチトール,キシリ
トール,還元水飴,還元パラチノース,ソルビトールな
どの糖アルコールやポリデキストロースが適している。
なお、ノンカロリーの製品を目的とする場合には、エリ
スリトールと多糖類の増粘安定剤のみとすることは言う
までもない。また、エリスリトールの冷感や清涼感を目
的とする場合や単にカロリーを抑制させるだけの場合に
は、前記糖アルコール類やポリデキストロースのみでな
く、ぶどう糖,果糖,砂糖,水飴,パラチノース,マル
トース,マルトトリオース,イソマルトオリゴ糖,フラ
クトオリゴ糖などの各種オリゴ糖や、デキストリン,コ
ーンスターチなどを使用することができる。以上のよう
に、目的に応じて前記の糖質を単独であるいは複数を選
択して使用することができる。In addition to erythritol, various sugars can be used in the sweetener composition of the present invention depending on the purpose. For example, when a low-calorie or non-cariogenic product is intended, sugar alcohols such as maltitol, lactitol, xylitol, reduced starch syrup, reduced palatinose, and sorbitol, and polydextrose are suitable.
Needless to say, when a non-calorie product is intended, only thickening stabilizers of erythritol and polysaccharides are used. In addition, in the case of aiming at a cooling sensation or a refreshing sensation of erythritol or simply suppressing calories, not only the above sugar alcohols and polydextrose, but also glucose, fructose, sugar, starch syrup, palatinose, maltose, maltose. Various oligosaccharides such as triose, isomaltooligosaccharide, fructooligosaccharide, dextrin, corn starch and the like can be used. As described above, the above-mentioned saccharides can be used alone or in combination of two or more depending on the purpose.
【0010】これらの糖質を使用する場合、その使用量
はエリスリトール100重量部に対して43重量部以下
の範囲とすることが好ましい。これら糖類の使用量が4
3重量部を超えると、乾燥工程でのエリスリトールの結
晶化が非常に遅くなり、生産効率が落ちるとともに、糖
衣層に粘着性が出て商品の物性として好ましくない結果
となる。When these sugars are used, it is preferable that the amount thereof be 43 parts by weight or less based on 100 parts by weight of erythritol. The amount of these sugars used is 4
When it exceeds 3 parts by weight, crystallization of erythritol in the drying step becomes extremely slow, production efficiency is lowered, and the sugar coating layer becomes sticky, resulting in unfavorable physical properties of the product.
【0011】次に、本発明の甘味料組成物に添加、配合
する多糖類の増粘安定剤としては粉末状,固形状等いず
れの形態でもよく、また市販製品を使用することができ
る。使用できる多糖類の増粘安定剤としては、通常食品
分野で使用されているものが挙げられ、具体的にはカラ
ギーナン,寒天,ファーセレラン,ペクチン,カードラ
ン,ジェランガム,キサンタンガム,アルギン酸ナトリ
ウム,タマリンドガムなどがある。これらはゲル化作用
を有するものであり、単独もしくは複数を組み合わせて
使用できる。本発明では、これらの増粘安定剤と共に、
アラビアガム,ローカストビーンガム,タラガム,プル
ラン,グアーガム,カルボキシメチルセルロースなどの
増粘剤の1種もしくは複数を適宜組み合わせて用いるこ
とができる。なお、本発明の甘味料組成物において、エ
リスリトールの微結晶をより長い期間安定な状態に維持
させる必要がある場合には、上記の増粘安定剤のうち、
寒天及びファーセレランの両方または一方を使用するこ
とが望ましい。本発明の甘味料組成物において増粘安定
剤は0.03〜0.7%(w/w)、好ましくは0.05〜0.
5%(w/w)、より好ましくは0.1〜0.3%(w/
w)含有させることができる。Next, the polysaccharide thickening stabilizer to be added to and blended with the sweetener composition of the present invention may be in the form of powder, solid or the like, and commercially available products may be used. Examples of thickening stabilizers for polysaccharides that can be used include those commonly used in the food field, and specifically, carrageenan, agar, furceleran, pectin, curdlan, gellan gum, xanthan gum, sodium alginate, tamarind gum and the like. There is. These have a gelling action, and can be used alone or in combination. In the present invention, together with these thickening stabilizers,
One or more thickeners such as gum arabic, locust bean gum, tara gum, pullulan, guar gum, and carboxymethyl cellulose may be used in an appropriate combination. In the sweetener composition of the present invention, when it is necessary to maintain the microcrystals of erythritol in a stable state for a longer period, among the above thickening stabilizers,
It is desirable to use either or both agar and furceleran. In the sweetener composition of the present invention, the thickening stabilizer is 0.03 to 0.7% (w / w), preferably 0.05 to 0.5%.
5% (w / w), more preferably 0.1-0.3% (w /
w) can be included.
【0012】本発明においては、甘味料組成物の甘味を
増強するため、または甘味質を改良・調整するために、
必要に応じてアスパルテーム,ステビオサイド類,サッ
カリンナトリウム,アセスルファムK,ソーマチン,グ
リチルリチン,ネオヘスペリジンDCなどの高甘味度甘
味料を単独または複数で適宜配合することができる。ま
た、製品の味付けや味質の改良のため、マルトール,シ
ュガーフレーバー,ペパーミント,フルーツフレーバー
などの香料を添加したり、カラメル,ビートレット,ク
チナシ,ベニバナなどの天然色素や黄色4号,赤色2号
などの合成色素を適宜添加することもできる。In the present invention, in order to enhance the sweetness of the sweetener composition, or to improve or adjust the sweetness quality,
If necessary, high-intensity sweeteners such as aspartame, steviosides, saccharin sodium, acesulfame K, thaumatin, glycyrrhizin, and neohesperidin DC can be appropriately added alone or in combination. To improve the flavor and quality of the product, add flavors such as maltitol, sugar flavor, peppermint, and fruit flavors, and natural pigments such as caramel, beetlet, gardenia, safflower and yellow No. 4, red No. 2 It is also possible to appropriately add a synthetic dye such as.
【0013】次に、本発明の甘味料組成物の製造方法の
1例を示す。エリスリトールとポリデキストロースを固
形分重量比100:0〜100:43で含む糖質原料
に、所定量の水を加えて加熱、混合、溶解し、固形分濃
度35〜65%(w/w)の糖液を調製する。次いで、
この糖液に増粘安定剤を0.03〜0.7%(w/w)、好
ましくは0.05〜0.5%(w/w)、より好ましくは0.
1〜0.3%(w/w)になるように添加し、均一に加熱
溶解したのち冷却する。その後、必要により少量のエリ
スリトールを結晶種として添加し、攪拌してエリスリト
ールの微結晶を析出させることにより目的とする甘味料
組成物を製造することができる。なお、本発明でいう微
結晶とは70μm以下、平均粒子径30〜40μmのサ
イズの結晶を意味する。上記甘味料組成物を製造するに
あたって使用される原料の混合、溶解などの操作、装置
等は既知の方法、装置等をそのまま用いればよく、何ら
特別な要件を必要としない。Next, an example of a method for producing the sweetener composition of the present invention will be shown. To a sugar raw material containing erythritol and polydextrose at a solid content weight ratio of 100: 0 to 100: 43, a predetermined amount of water was added, heated, mixed and dissolved to obtain a solid content concentration of 35 to 65% (w / w). Prepare sugar solution. Then
A thickening stabilizer is added to this sugar solution in an amount of 0.03 to 0.7% (w / w), preferably 0.05 to 0.5% (w / w), and more preferably 0.05.
Add 1 to 0.3% (w / w), heat and dissolve uniformly, and then cool. Thereafter, if necessary, a small amount of erythritol is added as a crystal seed, and the mixture is stirred to precipitate fine crystals of erythritol, whereby the desired sweetener composition can be produced. The term "fine crystals" used in the present invention means crystals having a size of 70 µm or less and an average particle diameter of 30 to 40 µm. For the operations such as mixing and dissolution of raw materials used for producing the above-mentioned sweetener composition, equipment, etc., known methods, equipment, etc. may be used as they are without any special requirements.
【0014】次に、上記の甘味料組成物を用いて糖衣生
成物を製造する方法について説明する。予め糖衣パン内
に収容した芯材を回転させながら、甘味料組成物を糖衣
パン内に滴下、噴霧等により供給する。この場合の甘味
料組成物は常温でよい。本発明の甘味料組成物の主成分
であるエリスリトールは、砂糖に比較して分子量が非常
に小さく、水溶液の粘度が低く、加温することによって
微結晶の一部が溶解する可能性があることなどから、常
温で甘味料組成物を供給することが望ましい。ここで、
芯材としてはチョコレート,錠菓,チューインガム,キ
ャンディー(グミキャンディー,ハード又はソフトキャ
ンディーなど),薬効成分を配合した経口用の医薬品
(トローチなど)等を挙げることができる。このよう
に、甘味料組成物を常温で供給できることは、チョコレ
ートなどのように商品の特性上加温することが好ましく
ないもの、また薬効成分などのように変質が心配される
医薬品の錠剤等への糖衣コーティングに有利である。次
いで、糖衣パンを回転させながら乾燥する。乾燥は、例
えば糖衣パンに乾燥用の風を当てて乾燥し、糖衣を生成
させる。乾燥用の風の温度は60℃以下が好ましく、本
発明の甘味料組成物は結晶化が速いため、常温(10〜
30℃)の風でも十分である。Next, a method for producing a sugar-coated product using the above sweetener composition will be described. While the core material previously stored in the sugar-coated bread is rotated, the sweetener composition is supplied into the sugar-coated bread by dropping, spraying or the like. In this case, the sweetener composition may be at room temperature. Erythritol, which is the main component of the sweetener composition of the present invention, has a very small molecular weight as compared with sugar, the viscosity of the aqueous solution is low, and a part of the microcrystal may be dissolved by heating. Therefore, it is desirable to supply the sweetener composition at room temperature. here,
Examples of the core material include chocolate, tablet confectionery, chewing gum, candy (gummy candy, hard or soft candy, etc.), orally-administered pharmaceuticals (troche, etc.) containing a medicinal component. In this way, being able to supply the sweetener composition at room temperature means that it is not desirable to heat the product due to the characteristics of the product, such as chocolate, and tablets such as medicinal ingredients that may be deteriorated. It is advantageous for sugar coating. Next, the sugar-coated bread is dried while rotating. Drying is performed by, for example, applying a drying wind to a sugar-coated bread to dry the sugar-coated bread. The temperature of the air for drying is preferably 60 ° C. or lower, and the sweetener composition of the present invention is rapidly crystallized, so that the room temperature (10 to 10
A wind of 30 ° C is also sufficient.
【0015】糖衣を生成させるには、上記のように、糖
質を主剤とするシロップを供給する工程と、送風により
乾燥、結晶化させる工程の2工程があり、これらの工程
を目的とする糖衣の厚さまたは重量になるまで繰り返し
行うものである。このようにして製造した糖衣生成物
に、仕上げ工程として艶出しのために、カルナバロウ,
ミツロウなどのワックス剤を必要に応じて添加すること
もできる。In order to produce sugar coating, there are two steps, as described above, a step of supplying a syrup containing a sugar as a main ingredient and a step of drying and crystallization by blowing air. Is repeated until the thickness or weight is reached. The sugar-coated product produced in this manner was treated with carnauba wax,
A wax agent such as beeswax can also be added if necessary.
【0016】なお、糖衣生成物の製造方法には、上記2
工程よりなる方法の他に、芯材と糖衣層の間にコーンス
ターチ等のデンプンを粉体のまま掛けて一旦薄いデンプ
ンの層を形成させてから上記の工程に移る方法や、上記
の2工程の後にエリスリトールの微粉末を掛ける工程を
入れて3工程を繰り返す方法(ソフト掛け)、又は、こ
れらを組み合わせる方法などが知られているが、いずれ
の方法も本発明に適用することができる。The method for producing a sugar-coated product is described in the above 2
In addition to the method consisting of steps, a method in which starch such as cornstarch is applied as a powder between the core material and the sugar coating layer to once form a thin starch layer and then the above step is carried out, Although a method of adding a step of applying fine powder of erythritol afterwards and repeating 3 steps (soft application), a method of combining these, or the like is known, any method can be applied to the present invention.
【0017】[0017]
【実施例】次に、本発明を実施例により詳しく説明する
が、本発明はこれらによって限定されるものではない。
実施例1
エリスリトール(日研化学株式会社製)800g、還元
水飴(商品名:エスイー20、日研化学株式会社製、濃
度70%製品)286g、寒天(米山薬品工業株式会社
製、試薬一級)4.6g及び水450gを混合し、95
℃で加熱、溶解した。次いで、この溶解物を40℃まで
冷却して、攪拌しながらエリスリトールの微結晶を析出
させた。その結果、微結晶が均一に分散した液状の甘味
料組成物が得られた。EXAMPLES Next, the present invention will be described in more detail with reference to examples, but the present invention is not limited thereto. Example 1 Erythritol (manufactured by Nikken Chemical Co., Ltd.) 800 g, reduced starch syrup (trade name: S20, manufactured by Nikken Chemical Co., Ltd., 70% concentration product) 286 g, agar (manufactured by Yoneyama Pharmaceutical Co., Ltd., first-class reagent) 4 Mix 0.6 g and 450 g of water to obtain 95
It melted by heating at ℃. Next, this melt was cooled to 40 ° C., and fine crystals of erythritol were deposited while stirring. As a result, a liquid sweetener composition in which fine crystals were uniformly dispersed was obtained.
【0018】実施例2
エリスリトール(日研化学株式会社製)100g、ファ
ーセレラン(商品名:ゲルアップJ−1915、三栄源
エフエフアイ株式会社製)0.5g、ステビオサイド(商
品名:ステビアスィート日研95S、日研化学株式会社
製)0.5g及び水100gを混合し、95℃で加熱、溶
解した。次いで、この溶解物を攪拌しながら20℃まで
冷却したところ、微結晶が均一に分散した液状の甘味料
組成物が得られた。Example 2 Erythritol (manufactured by Nikken Chemical Co., Ltd.) 100 g, Furceleran (trade name: Gelup J-1915, Sanei Gen FFI Co., Ltd.) 0.5 g, Stevioside (trade name: Stevia Sweet Nikken 95S) 0.5 g and water 100 g were mixed and heated at 95 ° C. to dissolve. Next, this melt was cooled to 20 ° C. with stirring, and a liquid sweetener composition in which fine crystals were uniformly dispersed was obtained.
【0019】実施例3
エリスリトール(日研化学株式会社製)50g、ポリデ
キストロース(商品名:ライテス、ファイザー株式会社
製、濃度70%製品)10g、寒天(米山薬品工業株式
会社製、試薬一級)0.05g及び水40gを混合し、9
4℃で加熱、溶解した。次いで、この溶解物を攪拌しな
がら20℃まで冷却したところ、微結晶が均一に分散し
た液状の甘味料組成物が得られた。Example 3 50 g of erythritol (manufactured by Niken Chemical Co., Ltd.), 10 g of polydextrose (trade name: Lites, manufactured by Pfizer, 70% concentration product), agar (manufactured by Yoneyama Pharmaceutical Co., Ltd., first-class reagent) 0 Mix 0.05 g and 40 g water to give 9
It melt | dissolved by heating at 4 degreeC. Next, this melt was cooled to 20 ° C. with stirring, and a liquid sweetener composition in which fine crystals were uniformly dispersed was obtained.
【0020】実施例4
エリスリトール(日研化学株式会社製)40g、ポリデ
キストロース(商品名:ライテスIII 、ファイザー株式
会社製、濃度70%製品)2.1g、還元乳糖粉末(商
品名:ラクチトールLC−0、日研化学株式会社製)
1.5g、ファーセレラン(商品名:ゲルアップJ−1
915、三栄源エフエフアイ株式会社製)0.5g及び水
56.4gを混合し、95℃で加熱、溶解した。次い
で、この溶解物を攪拌しながら20℃まで冷却したとこ
ろ、微結晶が均一に分散した液状の甘味料組成物が得ら
れた。Example 4 40 g of erythritol (manufactured by Nikken Chemicals Co., Ltd.), 2.1 g of polydextrose (trade name: Lites III, product of Pfizer, 70% concentration), reduced lactose powder (trade name: lactitol LC- 0, manufactured by Niken Chemical Co., Ltd.)
1.5g, fur cerelan (trade name: Gel Up J-1
915, manufactured by San-Ei Gen FFI Co., Ltd.) (0.5 g) and water (56.4 g) were mixed and heated at 95 ° C. to dissolve. Next, this melt was cooled to 20 ° C. with stirring, and a liquid sweetener composition in which fine crystals were uniformly dispersed was obtained.
【0021】実施例5
エリスリトール(日研化学株式会社製)35g、粉末還
元水飴(商品名:エスイーP、日研化学株式会社製)1
0g、ファーセレラン(商品名:ゲルアップJ−191
5、三栄源エフエフアイ株式会社製)0.2g及び水55
gを混合した後、96℃で加熱、溶解した。次いで、こ
の溶解物を40℃まで冷却し、約0.5gのエリスリトー
ル微粉を結晶種として添加し、攪拌しながら20℃まで
冷却したところ、微結晶が均一に分散した液状の甘味料
組成物が得られた。Example 5 Erythritol (manufactured by Nikken Chemical Co., Ltd.) 35 g, powdered starch syrup (trade name: S-P, manufactured by Nikken Chemical Co., Ltd.) 1
0 g, fur cerelan (trade name: Gel Up J-191
5, Saneigen FFI Co., Ltd.) 0.2 g and water 55
After mixing g, it heated and melt | dissolved at 96 degreeC. Next, the melt was cooled to 40 ° C., about 0.5 g of erythritol fine powder was added as a crystal seed, and the mixture was cooled to 20 ° C. with stirring. As a result, a liquid sweetener composition in which fine crystals were uniformly dispersed was obtained. Was obtained.
【0022】実施例6
エリスリトール(日研化学株式会社製)63g、ソルビ
トール(商品名:ソルビトールFP、日研化学株式会社
製)3g、ファーセレラン(商品名:ゲルアップJ−1
915、三栄源エフエフアイ株式会社製)0.2g及び水
34gを混合して96℃で加熱、溶解した。次いで、こ
の溶解物を40℃まで冷却し、約0.5gのエリスリトー
ル微粉を結晶種として添加し、攪拌しながら20℃まで
冷却したところ、微結晶が均一に分散した液状の甘味料
組成物が得られた。Example 6 63 g of erythritol (manufactured by Nikken Chemicals Co., Ltd.), 3 g of sorbitol (trade name: Sorbitol FP, manufactured by Nikken Chemical Co., Ltd.), furceleran (trade name: Gel Up J-1)
915, manufactured by Saneigen FFI Co., Ltd.) 0.2 g and water 34 g were mixed and heated at 96 ° C. to dissolve. Next, the melt was cooled to 40 ° C., about 0.5 g of erythritol fine powder was added as a crystal seed, and the mixture was cooled to 20 ° C. with stirring. As a result, a liquid sweetener composition in which fine crystals were uniformly dispersed was obtained. Was obtained.
【0023】実施例7
エリスリトール(日研化学株式会社製)50g、結晶ぶ
どう糖(サンエイ糖化株式会社製)10g、キサンタン
ガム(商品名:サンエース、三栄源エフエフアイ株式会
社製)0.2g及び水40gを混合し、96℃で加熱、溶
解した。次いで、この溶解物を40℃まで冷却し、約0.
5gのエリスリトール微粉を結晶種として添加し、攪拌
しながら20℃まで冷却したところ、微結晶が均一に分
散した液状の甘味料組成物が得られた。Example 7 50 g of erythritol (manufactured by Niken Chemical Co., Ltd.), 10 g of crystalline glucose (manufactured by Sanei Saccharification Co., Ltd.), 0.2 g of xanthan gum (trade name: San Ace, Saneigen FFI Co., Ltd.) and 40 g of water. Mix and heat at 96 ° C. to dissolve. The lysate is then cooled to 40 ° C. and about 0.
When 5 g of erythritol fine powder was added as a crystal seed and cooled to 20 ° C. with stirring, a liquid sweetener composition in which fine crystals were uniformly dispersed was obtained.
【0024】実施例8
エリスリトール(日研化学株式会社製)360g、ポリ
デキストロース(商品名:ライテスIII 、ファイザー株
式会社製、濃度70%製品)44g、還元水飴(商品
名:エスイー20、日研化学株式会社製、濃度70%製
品)176g、アラビアガム(米山薬品工業株式会社
製)40g、ファーセレラン(商品名:ゲルアップJ−
1915、三栄源エフエフアイ株式会社製)1g及び水
329gを混合し、94℃で加熱、溶解した。次いで、
この溶解物を40℃まで冷却し、結晶種としてエリスリ
トール微粉10gを添加、混合し、さらに冷却した。2
0℃まで冷却したところ、微結晶が均一に分散した液状
の甘味料組成物(ソフト掛け配合)が得られた。この微
結晶含有甘味料組成物は、経時的(15〜20℃で約1
ヶ月保存)にも安定なものであった。Example 8 360 g of erythritol (manufactured by Nikko Chemical Co., Ltd.), 44 g of polydextrose (trade name: Lites III, product of Pfizer Co., 70% concentration), reduced starch syrup (trade name: S20, Niken Chemical Co., Ltd.) 176g manufactured by Co., Ltd. with a concentration of 70%), 40g gum arabic (manufactured by Yoneyama Yakuhin Kogyo Co., Ltd.), Furceleran (trade name: Gel Up J-
1915, manufactured by San-Ei Gen FFI Co., Ltd.) and 329 g of water were mixed and heated at 94 ° C. to dissolve. Then
The melt was cooled to 40 ° C., 10 g of erythritol fine powder was added as a crystal seed, mixed, and further cooled. Two
When cooled to 0 ° C., a liquid sweetener composition (soft-applied formulation) in which fine crystals were uniformly dispersed was obtained. The microcrystal-containing sweetener composition was prepared over time (about 1 at 15 to 20 ° C.).
It was stable even after a month's storage.
【0025】実施例9
エリスリトール(日研化学株式会社製)500g、ポリ
デキストロース(商品名:ライテスIII 、ファイザー株
式会社製、濃度70%製品)75g、アラビアガム(米
山薬品工業株式会社製)40g、ファーセレラン(商品
名:ゲルアップJ−1915、三栄源エフエフアイ株式
会社製)4g及び水226gを混合して95℃で加熱、
溶解した。次いで、この溶解物を40℃まで冷却した
後、クチナシ黄色色素(商品名:サンイエローNo.3、三
栄源エフエフアイ株式会社製)8g、結晶種としてエリ
スリトール微粉5gを添加、混合し、さらに冷却した。
20℃まで冷却したところ、微結晶が均一に分散した液
状の甘味料組成物(ハード掛け配合)が得られた。この
微結晶含有甘味料組成物は、経時的(15〜20℃で約
3ヶ月保存)にも安定なものであった。Example 9 Erythritol (manufactured by Nikken Chemical Co., Ltd.) 500 g, polydextrose (trade name: Lites III, Pfizer Co., 70% concentration product) 75 g, gum arabic (manufactured by Yoneyama Pharmaceutical Co., Ltd.) 40 g, Fur Celeran (trade name: Gelup J-1915, Sanei Gen FFI Co., Ltd.) 4 g and water 226 g are mixed and heated at 95 ° C.,
Dissolved. Next, after cooling this melt to 40 ° C., 8 g of gardenia yellow pigment (trade name: Sun Yellow No. 3, manufactured by San-Ei Gen FFI Co., Ltd.) and 5 g of erythritol fine powder as a crystal seed were added and mixed, followed by cooling. did.
When cooled to 20 ° C., a liquid sweetener composition (hard coating composition) in which fine crystals were uniformly dispersed was obtained. The microcrystal-containing sweetener composition was stable over time (stored at 15 to 20 ° C. for about 3 months).
【0026】実施例10
常法により砂糖のみで製造した錠菓(直径6mm,重量
0.15g)500gを糖衣用のパンに入れ、20R/M
(r.p.m.)で転動させ、その錠菓に実施例8で調製した
甘味料組成物10gを噴霧し、60℃の風を当てて乾燥
させた。次に、エリスリトールの微粉末10gを錠菓に
振り掛けた。この操作を十数回繰り返し(いわゆるソフ
ト掛け)行い、糖衣層を形成させた。さらにその上に、
実施例9で調製した甘味料組成物10gを噴霧し、60
℃の風を当てて乾燥させる操作を十数回繰り返し(いわ
ゆるハード掛け)行い、微細な結晶を生成させ、非常に
滑らかな糖衣層を形成させた。Example 10 Tablet confectionery (diameter 6 mm, weight) produced only by sugar by a conventional method
0.15g) Put 500g in a pan for sugar coating, 20R / M
It was rolled at (rpm), and 10 g of the sweetener composition prepared in Example 8 was sprayed on the tablet confectionery, which was dried by blowing air at 60 ° C. Next, 10 g of fine powder of erythritol was sprinkled on the tablet confectionery. This operation was repeated dozens of times (so-called soft application) to form a sugar coating layer. On top of that,
Spray with 10 g of the sweetener composition prepared in Example 9, 60
The operation of applying a wind at ℃ to dry was repeated ten times (so-called hard application) to generate fine crystals and form a very smooth sugar coating layer.
【0027】実施例11
塩化リゾチーム2.5g、乳糖(商品名:DCL−2
1、DMV製)400gと結晶セルロース(商品名:ア
ビセル301、旭化成工業株式会社製)100gを混合
後、滑沢剤としてステアリン酸マグネシウム1.5gを
加え、常法により打錠して製造したトローチ剤(直径6
mm,重量0.14g)400gを芯材として糖衣用のパ
ンに入れ、15R/Mで転動させ、該トローチ剤に実施
例3で調製した甘味料組成物3.2gを噴霧し、20℃
の風を当てて乾燥させた。この操作を数十回繰り返し
(いわゆるハード掛け)行い、糖衣層を形成させた。こ
の方法で得られた糖衣生成物は微細な結晶で構成され、
非常に滑らかな食感のトローチ剤であった。さらに、そ
の糖衣トローチ剤の表面にワックスを均一に塗布し、光
沢のあるトローチ錠が得られた。Example 11 2.5 g of lysozyme chloride, lactose (trade name: DCL-2
1. A troche produced by mixing 400 g of DMV) with 100 g of crystalline cellulose (trade name: Avicel 301, manufactured by Asahi Kasei Kogyo Co., Ltd.), adding 1.5 g of magnesium stearate as a lubricant, and tableting by a conventional method. Agent (diameter 6
mm, weight 0.14 g) 400 g as a core material was put in a pan for sugar coating, tumbled at 15 R / M, and 3.2 g of the sweetener composition prepared in Example 3 was sprayed on the troche, and the temperature was 20 ° C.
It was dried by applying wind. This operation was repeated several tens of times (so-called hard application) to form a sugar coating layer. The sugar-coated product obtained by this method is composed of fine crystals,
It was a lozenge with a very smooth texture. Further, wax was uniformly applied to the surface of the sugar-coated lozenge to obtain a troche tablet having gloss.
【0028】実施例12
エリスリトール(日研化学株式会社製)600g、アラ
ビアガム(米山薬品工業株式会社製)40g、ファーセ
レラン(商品名:ゲルアップJ−1915、三栄源エフ
エフアイ株式会社製)2g及び水358gを混合し、9
5℃で加熱、溶解した。次いで、この溶解物を20℃ま
で冷却したところ、微結晶が均一に分散した液状の甘味
料組成物が得られた。この甘味料組成物は、経時的(1
0〜15℃で2ヶ月保存)にも安定なものであった。Example 12 Erythritol (manufactured by Nikken Chemical Co., Ltd.) 600 g, gum arabic (manufactured by Yoneyama Pharmaceutical Co., Ltd.) 40 g, Farceleran (trade name: Gelup J-1915, manufactured by Sanei Gen FFI Co., Ltd.) and Mix 358 g of water, and
It melt | dissolved by heating at 5 degreeC. Then, the melt was cooled to 20 ° C. to obtain a liquid sweetener composition in which fine crystals were uniformly dispersed. This sweetener composition is
It was stable even when stored at 0 to 15 ° C for 2 months.
【0029】実施例13
常法により砂糖のみで製造した錠菓(直径6mm,重量
0.15g)500gを糖衣用のパンに入れ、20R/M
で転動させ、その錠菓に実施例12で調製した甘味料組
成物15gを噴霧し、30℃の風を当てて乾燥させた。
この噴霧と乾燥の操作を20回繰り返し行い、糖衣層を
形成させた。得られた糖衣生成物は、微細な結晶が積み
重なった非常に食感の滑らかなものであった。Example 13 Tablet confectionery (diameter 6 mm, weight, produced only with sugar by a conventional method)
0.15g) Put 500g in a pan for sugar coating, 20R / M
Then, 15 g of the sweetener composition prepared in Example 12 was sprayed onto the tablet confectionery and dried by blowing air at 30 ° C.
The operations of spraying and drying were repeated 20 times to form a sugar coating layer. The obtained sugar-coated product had a very smooth texture with a stack of fine crystals.
【0030】比較例1
エリスリトール(日研化学株式会社製)580g、アラ
ビアガム(米山薬品工業株式会社製)40g及び水38
0gを混合し、95℃で加熱、溶解した。次いで、この
溶解物を60℃の恒温槽に入れて保温した。一方、常法
により砂糖のみで製造した錠菓(直径6mm,重量0.1
5g)500gを糖衣用のパンに入れ、20R/Mで転
動させ、その錠菓に前記の60℃に保温した溶解液15
gを噴霧し、30℃の風を当てて乾燥させた。この噴霧
と乾燥の操作を20回繰り返し行い、糖衣層を形成させ
た。得られた糖衣生成物は、一部に大きな結晶が生成し
ているのが見られた。食べたときには少し舌にザラつき
を感じた。また、この糖衣生成物と実施例13で得られ
た本発明の糖衣生成物の表面を走査型電子顕微鏡(日本
電子株式会社製,JSM−5200型)にて観察(倍
率:350倍)した。その結果、図1に示したように、
本発明の糖衣生成物の方が明らかに細かく緻密な結晶が
形成されていることが確認できた。Comparative Example 1 Erythritol (manufactured by Niken Chemical Co., Ltd.) 580 g, gum arabic (manufactured by Yoneyama Pharmaceutical Co., Ltd.) 40 g and water 38
0 g was mixed and heated at 95 ° C. to dissolve. Then, the melt was placed in a thermostat bath at 60 ° C. to keep it warm. On the other hand, tablets made from sugar only by a conventional method (diameter 6 mm, weight 0.1
5 g) 500 g was put in a sugar-coated bread, tumbled at 20 R / M, and the tablet confection was kept at 60 ° C. as the dissolution solution 15
g was sprayed and blown at 30 ° C. to dry. The operations of spraying and drying were repeated 20 times to form a sugar coating layer. It was found that large crystals were partially formed in the obtained sugar-coated product. When I ate it, I felt a little rough on my tongue. The surfaces of this sugar coating product and the sugar coating product of the present invention obtained in Example 13 were observed with a scanning electron microscope (JSM-5200, manufactured by JEOL Ltd.) (magnification: 350 times). As a result, as shown in FIG.
It was confirmed that the sugar-coated product of the present invention clearly formed finer and denser crystals.
【0031】比較例2
寒天を添加しないこと以外は実施例1と同様にして甘味
料組成物を調製し、実施例1で得られた甘味料組成物と
共に20℃で保存し、経時的な安定性を検討した。その
結果、7日後には寒天を添加していない対照の甘味料組
成物は上部に結晶の存在しない水層が見られ始めたのに
対して、実施例1で得られた本発明の甘味料組成物は全
く分離しなかった。Comparative Example 2 A sweetener composition was prepared in the same manner as in Example 1 except that agar was not added, and the sweetener composition obtained in Example 1 was stored at 20 ° C. to stabilize with time. The sex was examined. As a result, after 7 days, the control sweetener composition to which agar was not added started to show an aqueous layer without crystals at the top, whereas the sweetener of the present invention obtained in Example 1 The composition did not separate at all.
【0032】実施例14
第1表に示した組成を有する4種類の本発明の甘味料組
成物を調製し、それらを試験管に液量が80mmの高さ
になるように入れて20℃で保存し、経時的な安定性を
検討した。なお、対照として、それぞれの甘味料組成物
から増粘安定剤を除いたものも調製し、それらも同一条
件で保存して本発明の甘味料組成物と安定性の比較を行
った。結果を第2表に示した。第2表から明らかなよう
に、調製後3時間後には増粘安定剤を添加していない対
照の甘味料組成物は上部に結晶の存在しない水層が見ら
れ始めたのに対して、本発明の甘味料組成物はこのよう
な現象が認められず、非常に安定性が高いことが判っ
た。すなわち、増粘安定剤の有無により甘味料組成物の
安定性が大きく異なっている。また、表示していない
が、増粘安定剤無添加のものは、分離面付近にグラニュ
ー糖状の大きな結晶が析出した。これは、単に甘味料組
成物としての均一性が損なわれること以外に、微結晶を
必要とする用途に使用する場合、製品の食感、形状など
に重大な問題を生じることを意味する。Example 14 Four kinds of sweetener compositions of the present invention having the compositions shown in Table 1 were prepared, and they were placed in a test tube at a liquid volume of 80 mm at 20 ° C. It was stored and examined for stability over time. As a control, the sweetener compositions obtained by removing the thickening stabilizer from the respective sweetener compositions were also prepared and stored under the same conditions to compare the stability with the sweetener composition of the present invention. The results are shown in Table 2. As is apparent from Table 2, after 3 hours from the preparation, the control sweetener composition to which the thickening stabilizer was not added began to show an aqueous layer without crystals at the top, whereas It was found that the sweetener composition of the invention did not show such a phenomenon and was extremely stable. That is, the stability of the sweetener composition greatly differs depending on the presence or absence of the thickening stabilizer. In addition, although not shown, in the case where the thickening stabilizer was not added, large granulated sugar-like crystals were deposited near the separation surface. This means that, in addition to simply impairing the uniformity as a sweetener composition, when used in an application requiring microcrystals, a serious problem occurs in the texture and shape of the product.
【0033】[0033]
【表1】 [Table 1]
【0034】[0034]
【表2】 [Table 2]
【0035】実施例15
市販の大豆をフライパンで直火で炒って作成した炒り大
豆500gを糖衣用のパンに入れ、20R/Mで転動さ
せ、該炒り大豆に実施例8で得た甘味料組成物10gを
噴霧して全体に行き渡らせ、微粉砕したエリスリトール
を16g加えて十分に転動し、乾燥させた。この噴霧、
乾燥を15回繰り返した後、35℃で湿度20%以下の
乾燥室で一晩静置、乾燥した。これにより、冷たい食感
を有する舌触りの良い製品が得られた。Example 15 500 g of roasted soybeans prepared by roasting commercially available soybeans in a frying pan in an open flame were put in a pan for sugar coating and rolled at 20 R / M, and the sweetener obtained in Example 8 was added to the roasted soybeans. 10 g of the composition was sprayed and spread over the whole, 16 g of finely ground erythritol was added thereto, and the mixture was sufficiently rolled and dried. This spray,
After drying was repeated 15 times, it was allowed to stand overnight in a drying room at 35 ° C. and a humidity of 20% or less for drying. This gave a product with a cool texture and a pleasant texture.
【0036】実施例16
市販のチョコベビー(明治製菓株式会社製)500gを
糖衣パンに入れ、20R/Mで転動させ、これに実施例
8で得た甘味料組成物10gを噴霧して全体に行き渡ら
せ、エリスリトール微粉末とコーンスターチを重量比で
75:25に予め混合した色消し用の糖衣用粉末10g
を振りかけ、十分に転動、乾燥させた。この操作を10
回繰り返した後、30℃で湿度20%以下の乾燥室で一
晩静置、乾燥した。翌日、これを再び糖衣パンに戻し、
20R/Mで転動させ、これに実施例9で得た甘味料組
成物10gを噴霧し、次いで常温で風を当てて乾燥させ
る操作を12回繰り返し、微細な結晶を生成させ、非常
に滑らかな食感の糖衣チョコレートを得た。Example 16 500 g of a commercially available chocolate baby (manufactured by Meiji Seika Co., Ltd.) was put in a sugar-coated bread and rolled at 20 R / M, and 10 g of the sweetener composition obtained in Example 8 was sprayed on the whole. Erythritol fine powder and cornstarch were premixed at a weight ratio of 75:25, and 10 g of powder for sugar coating for achromatization
, Sprinkled with the powder, rolled sufficiently, and dried. Do this operation 10
After repeating the operation once, it was left to stand overnight in a drying room at 30 ° C. and a humidity of 20% or less for drying. The next day, put it back in the sugar-coated bread,
The operation of rolling at 20 R / M, spraying with 10 g of the sweetener composition obtained in Example 9 and then blowing at room temperature for drying was repeated 12 times to produce fine crystals, which were very smooth. A sugar-coated chocolate with a pleasant texture was obtained.
【0037】本発明の糖衣用甘味料組成物は低カロリ
ー、かつ非う蝕性のエリスリトールを主成分とし、エリ
スリトールの溶解度を越えた濃度域であってもエリスリ
トールを微結晶の形で均一に含有し、長期間安定な糖衣
用甘味料組成物である。さらに、この組成物を使用し
て、エリスリトールの微結晶を含有し、清涼感が高く、
しかも食感の改良された菓子や医薬品の糖衣生成物を製
造することが可能となる。The sugar-coating sweetener composition of the present invention contains low-calorie, non-cariogenic erythritol as a main component, and evenly contains erythritol in the form of microcrystals even in a concentration range exceeding the solubility of erythritol. And long-term stable sugar coating
It is a sweetener composition for use . Furthermore, using this composition, containing erythritol microcrystals, high refreshing feeling,
Moreover, it becomes possible to produce sugar-coated products of confectionery and pharmaceuticals with improved texture.
【図1】 (a)は実施例13で得られた糖衣生成物の
表面を観察(倍率:350倍)した顕微鏡写真であり、
(b)は比較例1で得られた糖衣生成物の表面を観察
(倍率:350倍)した顕微鏡写真である。FIG. 1 (a) is a micrograph of the surface of a sugar-coated product obtained in Example 13 observed (magnification: 350 times),
(B) is a micrograph of the surface of the sugar-coated product obtained in Comparative Example 1 observed (magnification: 350 times).
フロントページの続き (58)調査した分野(Int.Cl.7,DB名) A23L 1/22 - 1/236 A23G 3/30 A23L 1/00 A61K 9/28 Front page continued (58) Fields surveyed (Int.Cl. 7 , DB name) A23L 1/22-1/236 A23G 3/30 A23L 1/00 A61K 9/28
Claims (6)
5%(w/w)及びカラギーナン,寒天,ファーセレラ
ン,ペクチン,カードラン,ジェランガム,キサンタン
ガム,アルギン酸ナトリウム及びタマリンドガムよりな
る群から選ばれた少なくとも1種の多糖類の増粘安定剤
を0.03〜0.7%(w/w)含有し、かつエリスリ
トール以外の糖質を含まないか又はエリスリトール10
0重量部に対して43重量部以下の割合で含有し、かつ
エリスリトールの微結晶が均一に分散した液状の糖衣用
甘味料組成物。1. Erythritol is used as a main component in an amount of 35 to 6
5% (w / w) and 0.03 of at least one polysaccharide thickening stabilizer selected from the group consisting of carrageenan, agar, furceleran, pectin, curdlan, gellan gum, xanthan gum, sodium alginate and tamarind gum. ~ 0.7% (w / w) and contains no sugars other than erythritol or erythritol 10
The content is 43 parts by weight or less with respect to 0 parts by weight , and
A liquid sweetener composition for sugar coating, in which fine crystals of erythritol are uniformly dispersed .
0%(w/w)及び多糖類の増粘安定剤として寒天及び
/又はファーセレランを0.05〜0.5%(w/w)
含有する請求項1記載の糖衣用甘味料組成物。2. Erythritol 40 to 6 as a main component
0% (w / w) and 0.05 to 0.5% (w / w) of agar and / or furceleran as a thickening stabilizer for polysaccharides
The sweetener composition for sugar coating according to claim 1, which comprises.
物を糖衣パン内の芯材の表面に供給し、乾燥することを
特徴とする糖衣生成物の製造方法。3. A claim 1 or 2 sugar coating sweetener composition according to supplied to the surface of the core material in the glycocalyx pan method for producing a sugar-coated product, characterized by drying.
物を滴下あるいは噴霧させる請求項3記載の方法。4. The method according to claim 3, wherein the sweetener composition for sugar coating is dropped or sprayed while rotating the core material.
させる請求項3記載の方法。5. The method according to claim 3, which is dried at a temperature of room temperature to 60 ° C. for crystallization.
ガム,キャンディー及び医薬品のいずれかである請求項
3記載の方法。6. The method according to claim 3, wherein the core material is any one of chocolate, tablet confectionery, chewing gum, candy and medicine.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP15410195A JP3466779B2 (en) | 1995-05-30 | 1995-05-30 | Sweetener composition and method for producing sugar-coated product using the same |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP15410195A JP3466779B2 (en) | 1995-05-30 | 1995-05-30 | Sweetener composition and method for producing sugar-coated product using the same |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPH08322504A JPH08322504A (en) | 1996-12-10 |
| JP3466779B2 true JP3466779B2 (en) | 2003-11-17 |
Family
ID=15576948
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP15410195A Expired - Lifetime JP3466779B2 (en) | 1995-05-30 | 1995-05-30 | Sweetener composition and method for producing sugar-coated product using the same |
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| Country | Link |
|---|---|
| JP (1) | JP3466779B2 (en) |
Families Citing this family (15)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP3630900B2 (en) * | 1997-01-28 | 2005-03-23 | 株式会社ファンケル | Gummy candy composition |
| AU3008800A (en) * | 2000-04-20 | 2001-10-25 | Mars, Incorporated | Heat stable confectionery |
| JP2004137224A (en) * | 2002-10-18 | 2004-05-13 | Nikken Chem Co Ltd | Sugar coating liquid and sugar coating composition |
| US20040180110A1 (en) * | 2003-03-14 | 2004-09-16 | Atul Mistry | Chewing gum and confectionery compositions containing an endothermic agent |
| JP4559954B2 (en) * | 2005-11-14 | 2010-10-13 | 昭和産業株式会社 | Flavor improving composition, use thereof, and flavor improving method |
| JP2007185187A (en) * | 2005-12-16 | 2007-07-26 | Sanei Gen Ffi Inc | Method for preparing low calorie jelly |
| JP5046202B2 (en) * | 2006-10-25 | 2012-10-10 | 浜田食品工業株式会社 | Dragees and methods for producing the same |
| JP2010523161A (en) * | 2007-04-16 | 2010-07-15 | カーギル インコーポレイテッド | Reduce the sensory cooling effect of polyols |
| JP4775312B2 (en) * | 2007-04-27 | 2011-09-21 | 三菱商事フードテック株式会社 | Granules and tablets for direct compression |
| JP2010051234A (en) * | 2008-08-28 | 2010-03-11 | Kanro Kk | Cellulose-containing candy |
| JP6154095B2 (en) * | 2010-07-29 | 2017-06-28 | 帝人ファーマ株式会社 | Oral jelly preparation of bisphosphonic acid |
| WO2013138812A1 (en) * | 2012-03-16 | 2013-09-19 | Mp-Otha Corporation | Anhydrous mix for a food product coating |
| JP2013215119A (en) * | 2012-04-06 | 2013-10-24 | House Foods Corp | Snack food, and method of producing the same |
| JP5841564B2 (en) * | 2013-06-19 | 2016-01-13 | ソントン食品工業株式会社 | Icing material resistant to crying |
| CN117898440B (en) * | 2024-01-25 | 2026-01-13 | 橡果美健实业投资股份有限公司 | Satiety composition for obesity intervention and application thereof |
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1995
- 1995-05-30 JP JP15410195A patent/JP3466779B2/en not_active Expired - Lifetime
Also Published As
| Publication number | Publication date |
|---|---|
| JPH08322504A (en) | 1996-12-10 |
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